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Artículos de revistas sobre el tema "Electron donor-acceptor complexes"

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Publicado: 4 de junio de 2021
Última modificación: 25 de julio de 2025

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1

Hurst, DT, UB Thakrar, CHJ Wells, and J. Wyer. "An N.M.R. Study of Electron Donor-Electron Acceptor Interaction Between Aromatic Hydrocarbons and Diazines." Australian Journal of Chemistry 42, no. 8 (1989): 1313. http://dx.doi.org/10.1071/ch9891313.

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Equilibrium constants have been measured by n.m.r , spectroscopy for the electron donor- electron acceptor interaction between a number of aromatic hydrocarbons and diazines . The values obtained have shown that the interaction is weak, and that the aromatic hydrocarbon acts as the electron donor and the diazine as the electron acceptor in the systems studied. Chemical-shift data have provided evidence for the relative positioning of the donor and acceptor components within the various complexes. The effect of temperature on the equilibrium constant for complex formation between (1H6)benzene a
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2

Rubtsov, I. V., and K. Yoshihara. "Vibrational Coherence in Electron Donor−Acceptor Complexes." Journal of Physical Chemistry A 103, no. 49 (1999): 10202–12. http://dx.doi.org/10.1021/jp991998r.

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3

Postigo, Al. "Electron Donor-Acceptor Complexes in Perfluoroalkylation Reactions." European Journal of Organic Chemistry 2018, no. 46 (2018): 6391–404. http://dx.doi.org/10.1002/ejoc.201801079.

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4

Zhong, Cheng, Jinwei Zhou, and Charles L. Braun. "Electron-transfer absorption of sterically bulky donor–acceptor pairs: electron donor–acceptor complexes or random pairs?" Journal of Photochemistry and Photobiology A: Chemistry 161, no. 1 (2003): 1–9. http://dx.doi.org/10.1016/s1010-6030(03)00233-8.

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5

Sakuda, Eri. "(Invited) Synthesis and Photophysical Properties of Linear Coordination Type Complexes Having Electron Donor/Acceptor Moieties." ECS Meeting Abstracts MA2024-01, no. 13 (2024): 1064. http://dx.doi.org/10.1149/ma2024-01131064mtgabs.

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The energy and electron transfer processes in the organic / inorganic D–A connection system can be freely manipulated by vibronic interaction.Until now, we synthesized the complexes having acceptor moiety was introduced as a substituent to induce electrostatic/coulomb interaction, but from now on, donor and acceptor moieties should be introduced intramolecular or intermolecular in order to induced a donor-acceptor interaction and express dynamic exciton. Then, we synthesized a platinum complex with phenothiazine as a donor and an organoboron compound as an acceptor. Unfortunately, the charge s
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6

Yang, Zhonglie, Yutong Liu, Kun Cao, Xiaobin Zhang, Hezhong Jiang, and Jiahong Li. "Synthetic reactions driven by electron-donor–acceptor (EDA) complexes." Beilstein Journal of Organic Chemistry 17 (April 6, 2021): 771–99. http://dx.doi.org/10.3762/bjoc.17.67.

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The reversible, weak ground-state aggregate formed by dipole–dipole interactions between an electron donor and an electron acceptor is referred to as an electron-donor–acceptor (EDA) complex. Generally, upon light irradiation, the EDA complex turns into the excited state, causing an electron transfer to give radicals and to initiate subsequent reactions. Besides light as an external energy source, reactions involving the participation of EDA complexes are mild, obviating transition metal catalysts or photosensitizers in the majority of cases and are in line with the theme of green chemistry. T
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7

Dobrowolski, Jan Cz, and Michał H. Jamróz. "Infrared evidence for CO2 electron donor—acceptor complexes." Journal of Molecular Structure 275 (December 1992): 211–19. http://dx.doi.org/10.1016/0022-2860(92)80196-o.

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8

Schreiber, Michael, Barbara Kirchner, and Christofer Fuchs. "Dynamics of electron transfer in donor-acceptor complexes." Journal of Luminescence 66-67 (December 1995): 506–10. http://dx.doi.org/10.1016/0022-2313(95)00199-9.

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9

Singh, Joaquín O., Jorge D. Anunziata та Juana J. Silber. "n–π Electron donor–acceptor complexes. II. Aliphatic amines with dinitrobenzenes". Canadian Journal of Chemistry 63, № 4 (1985): 903–7. http://dx.doi.org/10.1139/v85-150.

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The interaction of several aliphatic amines as n-donors and dinitrobenzenes (DNB) as π-acceptors has been studied in n-hexane. The formation of electron donor – acceptor (EDA) complexes is proposed to explain the spectroscopic behaviour of the mixtures. The stability constants (Ks) for these complexes have been calculated by an iterative procedure. For a given acceptor, the donor strength of RNH2 > R2NH > R3N was found. This order is explained by considering the role that steric effect may play in the EDA complex formation. On the other hand, the fact that for a given donor Ks follows th
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10

Opitz, Andreas, Giuliano Duva, Marius Gebhardt, et al. "Thin films of electron donor–acceptor complexes: characterisation of mixed-crystalline phases and implications for electrical doping." Materials Advances 3, no. 2 (2022): 1017–34. http://dx.doi.org/10.1039/d1ma00578b.

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11

Zhu, Chen, Serik Zhumagazy, Huifeng Yue, and Magnus Rueping. "Metal-free C–Se cross-coupling enabled by photoinduced inter-molecular charge transfer." Chemical Communications 58, no. 1 (2022): 96–99. http://dx.doi.org/10.1039/d1cc06152f.

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12

Amitava, Das, D. Shukla Atindra, and C. Bajaj H. "Role of bridging ligand in tuning metal-metal interaction in mixed valence complexes." Journal of Indian Chemical Society Vol. 77, Feb 2000 (2000): 51–58. https://doi.org/10.5281/zenodo.5862052.

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Central Salt and Marine Chemicals Research Institute, Bhavnagar-364 002, India <em>Manuscript received 14 June 1999, accepted 28 August 1999</em> Optical intervalence electron depends both on the nature of the donor/acceptor and on the bridging ligand which joins donor and acceptor sites. The ability to control electronic and magnetic interactions between metal centers with the change in conjugation, conformation and length of BL is of fundamental importance in inorganic and material chemistry. In this article, we review recent reports on the effect of different parameters on intramolecular el
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13

Zon, M. A., H. Fernandez, L. Sereno, and J. J. Silber. "The kinetics of formation of electron donor–acceptor complexes. A temperature-jump study." Canadian Journal of Chemistry 68, no. 2 (1990): 278–81. http://dx.doi.org/10.1139/v90-038.

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The kinetics of the Electron Donor–Acceptor (EDA) complex between N,N,N′,N′-tetramethyl-p-phenylenediamine and m-dinitrobenzene in acetonitrile has been studied by the temperature-jump technique. The magnitude of the rate constants of association and dissociation, although relatively large, is well below the diffusion control values. The calculated rates closely coincide with those obtained by chronoamperometry. An entropy control is suggested for this reaction. The results obtained in this work are useful to demonstrate that the concept about EDA complexes being formed by diffusion-controlled
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14

Tian, Tian, Tingjuan Qian, Tingting Jiang, et al. "A donor–acceptor type macrocycle: toward photolyzable self-assembly." Chemical Communications 56, no. 28 (2020): 3939–42. http://dx.doi.org/10.1039/d0cc01350a.

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15

Konarev, D. V., G. Zerza, M. Scharber, N. S. Sariciftci, and R. N. Lyubovskaya. "Photoinduced electron transfer in solid C60 donor/acceptor complexes." Synthetic Metals 121, no. 1-3 (2001): 1127–28. http://dx.doi.org/10.1016/s0379-6779(00)00972-3.

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16

Sheka, Elena F. "Intermolecular interaction in C60-based electron donor-acceptor complexes." International Journal of Quantum Chemistry 100, no. 4 (2004): 388–406. http://dx.doi.org/10.1002/qua.20063.

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17

Li, Zebiao, Shan Wang, Yumei Huo, Bing Wang, Jun Yan, and Quanping Guo. "Visible light-driven fluoroalkylthiocyanation of alkenes via electron donor–acceptor complexes." Organic Chemistry Frontiers 8, no. 12 (2021): 3076–81. http://dx.doi.org/10.1039/d1qo00126d.

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18

Mohammed, Haider Shanshool, and Nuha Hussain Al-Saadawy. "Synthesis, Characterization, and Theoretical Study of Novel Charge-Transfer Complexes Derived from 3,4-Selenadiazobenzophenone." Indonesian Journal of Chemistry 22, no. 6 (2022): 1663. http://dx.doi.org/10.22146/ijc.76537.

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In the current study, a direct method was used to synthesize a new series of charge-transfer complex compounds. Reaction of different quinones with 3,4-selenadiazo benzophenone in a 1:1 mole ratio by acetonitrile gave a unique charge-transfer complex compound in a good yield. All compounds were characterized by UV-Vis, FTIR, 1H-NMR, and 13C-NMR. The analysis findings agreed with the produced compound’s proposed chemical structures. The molecular structure of the produced charge-transfer complex compounds has been investigated using density functional theory. The basis set of 3–21G geometrical
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19

K., SUJATHA, RAVICHANDRAN G., and GOVINDAN K. "Spectrophotometric Studies of Electron Donor-Acceptor Complexes between Polynitro Compounds and Certain Aromatic Bases at 302 K." Journal of Indian Chemical Society Vol. 75, Jan 1998 (1998): 37–38. https://doi.org/10.5281/zenodo.5913138.

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Department of Chemistry, Centre for P. G. Studies, Pondicherry-605 008 Raman School of Physics, Pondicherry University, Pondicherry-605 014 <em>Manuscript received 31 August 1995, revised 12 June 1996, accepted 17 January 1997</em> Spectrophotometric Studies of Electron Donor-Acceptor Complexes between Polynitro Compounds and Certain Aromatic Bases at 302 K.
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20

Zhu, Da-Liang, Shan Jiang, David James Young, Qi Wu, Hai-Yan Li, and Hong-Xi Li. "Visible-light-driven C(sp2)–H arylation of phenols with arylbromides enabled by electron donor–acceptor excitation." Chemical Communications 58, no. 22 (2022): 3637–40. http://dx.doi.org/10.1039/d1cc07127k.

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21

Russegger, Andreas, Lisa Eiber, Andreas Steinegger, and Sergey M. Borisov. "Zinc Donor–Acceptor Schiff Base Complexes as Thermally Activated Delayed Fluorescence Emitters." Chemosensors 10, no. 3 (2022): 91. http://dx.doi.org/10.3390/chemosensors10030091.

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Four new zinc(II) Schiff base complexes with carbazole electron donor units and either a 2,3-pyrazinedicarbonitrile or a phthalonitrile acceptor unit were synthesized. The donor units are equipped with two bulky 2-ethylhexyl alkyl chains to increase the solubility of the complexes in organic solvents. Furthermore, the effect of an additional phenyl linker between donor and acceptor unit on the photophysical properties was investigated. Apart from prompt fluorescence, the Schiff base complexes show thermally activated delayed fluorescence (TADF) with quantum yields up to 47%. The dyes bearing a
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22

Suga, Takuya. "Organic Transformations Utilizing Photo-Induced Electron Transfer of Electron-Donor-Acceptor Complexes." Journal of Synthetic Organic Chemistry, Japan 77, no. 4 (2019): 367–68. http://dx.doi.org/10.5059/yukigoseikyokaishi.77.367.

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23

Zheng, Lvyin, Liuhuan Cai, Kailiang Tao, Zhen Xie, Yin‐Long Lai, and Wei Guo. "Progress in Photoinduced Radical Reactions using Electron Donor‐Acceptor Complexes." Asian Journal of Organic Chemistry 10, no. 4 (2021): 711–48. http://dx.doi.org/10.1002/ajoc.202100009.

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24

Eremina, Olga E., Mariia V. Samodelova, Mariia V. Ferree, Tatyana N. Shekhovtsova, and Irina A. Veselova. "Capturing polycyclic aromatic sulfur heterocycles in electron donor–acceptor complexes." Mendeleev Communications 31, no. 3 (2021): 326–29. http://dx.doi.org/10.1016/j.mencom.2021.04.015.

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25

Eremina, Olga E., Mariia V. Samodelova, Mariia V. Ferree, Tatyana N. Shekhovtsova, and Irina A. Veselova. "Capturing polycyclic aromatic sulfur heterocycles in electron donor–acceptor complexes." Mendeleev Communications 31, no. 3 (2021): 326–29. http://dx.doi.org/10.1016/j.mencom.2021.05.015.

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26

Takahashi, Yasutake, Hitoshi Ohaku, Naoki Nishioka, et al. "Charge–transfer excitation of electron donor–acceptor complexes of arylcyclopropanes." Journal of the Chemical Society, Perkin Transactions 2, no. 2 (1997): 303–8. http://dx.doi.org/10.1039/a604565k.

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27

Seshadri, Ram, Francis D’Souza, Varadachari Krishnan, and C. N. R. Rao. "Electron Donor-Acceptor Complexes of the Fullerenes C60and C70with Amines." Chemistry Letters 22, no. 2 (1993): 217–20. http://dx.doi.org/10.1246/cl.1993.217.

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28

Liu, Jia-Li, Ze-Fan Zhu, and Feng Liu. "Cyanofluorination of vinyl ethers enabled by electron donor–acceptor complexes." Organic Chemistry Frontiers 6, no. 2 (2019): 241–44. http://dx.doi.org/10.1039/c8qo01143e.

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The reaction is operationally simple and conducted under ambient conditions, allowing the access to highly functionalized α-alkoxy-β-fluoronitriles bearing quaternary carbons that are difficult to access by existing methods.
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29

Notoya, Reiko. "Electron Donor-Acceptor Aspect of Superconductivity in Metal-C60 Complexes." Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 285, no. 1 (1996): 193–98. http://dx.doi.org/10.1080/10587259608030800.

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30

Merriam, M. J., R. Rodriguez, and Jeanne L. McHale. "Charge-transfer transitions of 2:1 electron donor-acceptor complexes." Journal of Physical Chemistry 91, no. 5 (1987): 1058–63. http://dx.doi.org/10.1021/j100289a011.

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31

Roeggen, I., and T. Dahl. "Analysis of electron donor-acceptor complexes: H3N.cntdot.F2, H3N.cntdot.Cl2, and H3N.cntdot.ClF." Journal of the American Chemical Society 114, no. 2 (1992): 511–16. http://dx.doi.org/10.1021/ja00028a017.

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32

Endicott, John F., Xiaoqing Song, Murielle A. Watzky, and Tione Buranda. "Photoinduced electron transfer in linked transition metal donor—acceptor complexes." Journal of Photochemistry and Photobiology A: Chemistry 82, no. 1-3 (1994): 181–90. http://dx.doi.org/10.1016/1010-6030(94)02002-7.

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33

Røeggen, Inge. "An analysis of electron donor-acceptor complexes: BH3CO and BH3NH3." Chemical Physics 162, no. 2-3 (1992): 271–84. http://dx.doi.org/10.1016/0301-0104(92)85005-f.

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34

Ciarrocchi, Carlo, Guido Colucci, Massimo Boiocchi, et al. "Interligand Charge-Transfer Processes in Zinc Complexes." Chemistry 4, no. 3 (2022): 717–34. http://dx.doi.org/10.3390/chemistry4030051.

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Electron donor–acceptor (EDA) complexes are characterized by charge-transfer (CT) processes between electron-rich and electron-poor counterparts, typically resulting in a new absorption band at a higher wavelength. In this paper, we report a series of novel 2,6-di(imino)pyridine ligands with different electron-rich aromatic substituents and their 1:2 (metal/ligand) complexes with zinc(II) in which the formation of a CT species is promoted by the metal ion coordination. The absorption properties of these complexes were studied, showing the presence of a CT absorption band only in the case of ar
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35

Shi, Ya-Rui, and Yu-Fang Liu. "Theoretical study on the charge transport and metallic conducting properties in organic complexes." Physical Chemistry Chemical Physics 21, no. 24 (2019): 13304–18. http://dx.doi.org/10.1039/c9cp02170a.

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The charge transfer process between substrate molecular and dopant always appears in doped organic semiconductors, so that molecular doping is a common method to improve the electrical properties by combining appropriate complexes of electron acceptor and donor molecules.
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36

Sun, Jingjing, Yanyan He, Xiao-De An, Xu Zhang, Lei Yu, and Shouyun Yu. "Visible-light-induced iminyl radical formation via electron-donor–acceptor complexes: a photocatalyst-free approach to phenanthridines and quinolines." Organic Chemistry Frontiers 5, no. 6 (2018): 977–81. http://dx.doi.org/10.1039/c7qo00992e.

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A visible light-induced synthesis of nitrogen-containing arenes from O-2,4-dinitrophenyl oximes has been reported. This photochemical strategy is photocatalyst-free and enabled by electron-donor–acceptor (EDA) complexes of O-2,4-dinitrophenyl oximes and Et3N.
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37

Stasyuk, Anton J., Olga A. Stasyuk, Miquel Solà, and Alexander A. Voityuk. "Hypsochromic solvent shift of the charge separation band in ionic donor–acceptor Li+@C60⊂[10]CPP." Chemical Communications 55, no. 75 (2019): 11195–98. http://dx.doi.org/10.1039/c9cc05787k.

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Photoinduced electron transfer in CPP-based donor–acceptor complexes C<sub>60</sub>⊂[10]CPP and Li<sup>+</sup>@C<sub>60</sub>⊂[10]CPP was studied using DFT/TDDFT. Unusual blue shift of charge separated states for Li<sup>+</sup>@C<sub>60</sub>⊂[10]CPP complexes in the polar medium is predicted.
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38

Wang, Wei, Wei Wu, and Peifeng Su. "Radical Pairing Interactions and Donor–Acceptor Interactions in Cyclobis(Paraquat-P-Phenylene) Inclusion Complexes." Molecules 28, no. 5 (2023): 2057. http://dx.doi.org/10.3390/molecules28052057.

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Understanding molecular interactions in mechanically interlocked molecules (MIMs) is challenging because they can be either donor–acceptor interactions or radical pairing interactions, depending on the charge states and multiplicities in the different components of the MIMs. In this work, for the first time, the interactions between cyclobis(paraquat-p-phenylene) (abbreviated as CBPQTn+ (n = 0–4)) and a series of recognition units (RUs) were investigated using the energy decomposition analysis approach (EDA). These RUs include bipyridinium radical cation (BIPY•+), naphthalene-1,8:4,5-bis(dicar
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39

Pryalkin, Boris S., and Yulia S. Bodagova. "Molecular Complexes of p-Chloranil with Aniline, Phenol and their Derivatives." Key Engineering Materials 670 (October 2015): 89–94. http://dx.doi.org/10.4028/www.scientific.net/kem.670.89.

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Classification of simple supramolecular structures (for example molecular complexes), which has been introduced and described by Mulliken [1], is based on types of molecular orbitals of the components. In the paper [2], disadvantages of such classification are shown, which motivate us to return to the re-examination properties of molecular complexes. By this reason, there is a need to research the molecular complexes of one electron acceptor with a wide range of electron donor molecules. This paper have continued work (Part I [3]) on the chloranil complexes by studying the spectral properties
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40

Nalewajski, Roman F. "Information-Theoretic Descriptors of Molecular States and Electronic Communications between Reactants." Entropy 22, no. 7 (2020): 749. http://dx.doi.org/10.3390/e22070749.

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The classical (modulus/probability) and nonclassical (phase/current) components of molecular states are reexamined and their information contributions are summarized. The state and information continuity relations are discussed and a nonclassical character of the resultant gradient information source is emphasized. The states of noninteracting and interacting subsystems in the model donor-acceptor reactive system are compared and configurations of the mutually-closed and -open equidensity orbitals are tackled. The density matrices for subsystems in reactive complexes are used to describe the e
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41

Feskov, Sergey. "Numerical Simulation of Coherent Optical Transitions in Electron-Donor-Acceptor Complexes." Vestnik Volgogradskogo gosudarstvennogo universiteta. Serija 1. Mathematica. Physica, no. 3 (September 2016): 84–91. http://dx.doi.org/10.15688/jvolsu1.2016.3.8.

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42

Dahl, T., and I. Røeggen. "An Analysis of Electron Donor−Acceptor Complexes: H2O·F2, H2O·Cl2, and H2O·ClF." Journal of the American Chemical Society 118, no. 17 (1996): 4152–58. http://dx.doi.org/10.1021/ja9537890.

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43

Crisenza, Giacomo E. M., Daniele Mazzarella, and Paolo Melchiorre. "Synthetic Methods Driven by the Photoactivity of Electron Donor–Acceptor Complexes." Journal of the American Chemical Society 142, no. 12 (2020): 5461–76. http://dx.doi.org/10.1021/jacs.0c01416.

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44

Ziessel, Raymond, Alberto Juris, and Margherita Venturi. "Intramolecular Photoinduced Electron Transfer in Multicomponent Rhenium(I) Donor−Acceptor Complexes." Inorganic Chemistry 37, no. 20 (1998): 5061–69. http://dx.doi.org/10.1021/ic980570o.

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45

Danten, Y., T. Tassaing, and M. Besnard. "Vibrational Spectra of CO2-Electron Donor−Acceptor Complexes from ab Initio." Journal of Physical Chemistry A 106, no. 48 (2002): 11831–40. http://dx.doi.org/10.1021/jp021598v.

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46

Hsu, Chien-Wei, та Henrik Sundén. "α-Aminoalkyl Radical Addition to Maleimides via Electron Donor–Acceptor Complexes". Organic Letters 20, № 7 (2018): 2051–54. http://dx.doi.org/10.1021/acs.orglett.8b00597.

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47

Müller-Wegener, U. "Electron donor acceptor complexes between organic nitrogen heterocycles and humic acid." Science of The Total Environment 62 (January 1987): 297–304. http://dx.doi.org/10.1016/0048-9697(87)90513-4.

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48

Jin, Shengye, Robert C. Snoeberger, Abey Issac, David Stockwell, Victor S. Batista, and Tianquan Lian. "Single-Molecule Interfacial Electron Transfer in Donor-Bridge-Nanoparticle Acceptor Complexes†." Journal of Physical Chemistry B 114, no. 45 (2010): 14309–19. http://dx.doi.org/10.1021/jp911662g.

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49

May, V., and E. G. Petrov. "Few-electron transfer reactions in donor–acceptor complexes and molecular wires." physica status solidi (b) 241, no. 9 (2004): 2168–78. http://dx.doi.org/10.1002/pssb.200404791.

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50

Kinoshita, Yo, Kouki Oka, Hiromi Nakajima, and Norimitsu Tohnai. "Control of Relative Positions of Electron‐Donor and Electron‐Acceptor Molecules in Charge‐Transfer Complexes for Luminescent Property Modulation." Chemistry – A European Journal, October 24, 2023. http://dx.doi.org/10.1002/chem.202302965.

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Charge‐transfer complexes can exhibit various physical properties, which depend on the relative positions of electron‐donor and electron‐acceptor molecules. Several studies have investigated the relationship between the relative positions of electron‐donor and electron‐acceptor molecules and their luminescence properties. However, elucidating the pure correlation between the relative positions and detailed luminescence processes without changing their molecular structures has been unexplored. Herein, we report the relative‐position‐control based on charge‐assisted hydrogen bonds between sulfo
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