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Tesis sobre el tema "Ketones"

Autor: Grafiati

Publicado: 4 de junio de 2021

Última modificación: 25 de julio de 2025

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1

Stubbs, Brianna. "Metabolism of exogenous ketones." Thesis, University of Oxford, 2016. https://ora.ox.ac.uk/objects/uuid:3a3f65b4-4442-415e-b4bc-e0175adf65b5.

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As metabolic substrates, ketone bodies provide an alternative to glucose in order to pro- long survival during starvation. A low carbohydrate, high fat diet can be used to promote ketogenesis without fasting, but long-term compliance can be difficult. Dietary ketone bod- ies may be an alternative method to induce ketosis, so the aim of the work in this Thesis was to investigate the metabolism of exogenous ketones. In the first experimental Chap- ter, the effects of ketone ester and salt drinks on blood β-hydroxybutyrate (Î²HB), glucose, lipids, electrolytes and pH were determined in healt

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2

Lateef, Juma. "The reactions of fluorinated ketones." Thesis, Brunel University, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.286819.

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3

Smith, Athene Rachael Cecilia. "Catalytic asymmetric reduction of ketones." Thesis, University of Warwick, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.302649.

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4

Gemmell, Natasha. "Diastereocontrolled modifications of sugar ketones." Thesis, University of Reading, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.342107.

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5

Studley, John Richard. "The asymmetric reduction of ketones." Thesis, University of Bath, 1996. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.307117.

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6

Zhu, Jia Liang. "Reductive alkylation of Ã-cyano ketones." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1999. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/nq39611.pdf.

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7

Zinovyeva, Lyudmyla. "Darstellung und Reaktionen einiger ß,Y-ungesättigter Ketone - Preparation and reactivity of some ß,Y-unsaturated ketones." Gerhard-Mercator-Universitaet Duisburg, 2003. http://www.ub.uni-duisburg.de/ETD-db/theses/available/duett-09182003-170256/.

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The reactivity of the polycyclic ß,Y-unsaturated ketones under different conditions were investigated. The titled ketons were reacted with Lithiumaluminiumhidrid and Grignard reagents with following dehydratation of the resulted secondary and tertiary alkohol. The Bucherer reaction, thermolysis and photolysis of these ketones were carried out.

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8

Earlywine, Arthur Dale. "The stereochemistry and mechanism of the iron pentacarbonyl-promoted coupling of strained olefins to carbon monoxide : a NMR-facilitated study of the equilibrium constants between and collision complex of a 10,11-diphenyl-1,4:5,8-dimethano-1,4,4a,4b,5,8,8a, 8b-octahydrofluorene-9-one stereoisomer and the lanthanide shift reagent Eu(fod), the electrophilic aromatic thallation of some selected biomolecules, and the synthesis and high resolution NMR study of the two series of 1,4,4a,8a-tetrahydro-endo-1,4-methanonaphthalene-5 ,8-diones and pentacyclo[5.4.0.0,.0." Full-text version available from OU Domain via ProQuest Digital Dissertations, 1985.

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9

Canbolat, Eylem. "Organocatalytic Resolution Of Racemic Alpha Azido Ketones." Master's thesis, METU, 2012. http://etd.lib.metu.edu.tr/upload/12614602/index.pdf.

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Chiral cyclic alpha azido ketones are very important compounds in organic chemistry. Because, the reduced forms of them are amino alcohols and these amino alcohols are interesting compounds for their biological activities. They have some pharmaceutical activities such as: potassium channel open up properties, treatment of central nervous system, antihypertensive properties, the agent of dopamin receptor activator, hypolipemic agent and dopamine agonist. These types of compounds have highly acidic alpha-protons, and many kinds of reactions can be performed with them. In this study, mainly, sel

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10

Bena, Luvuyo Clifford. "Investigations into the asymmetric reduction of ketones." Thesis, University of Port Elizabeth, 2003. http://hdl.handle.net/10948/323.

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A six-step synthesis of salbutamol from methyl salicylate with an overall yield of 17% has been completed, although the yield was not optimised. In the process, Zn(BH4)2 was found to selectively reduce a ketone carbonyl group in the presence of an ester unit. In contrast, borane was found to reduce both the ketone and ester carbonyl groups. Reduction of phenacyl bromide with borane in the presence of chiral catalysts based on (R)-alaninol and (R,S)-ephidrine resulted a measure of enantioselectivity in the product. However, the configuration of the alcohol obtained in the case of (R)-alaninol w

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11

Lively, Sarah Elizabeth. "Catalytic asymmetric synthesis of #alpha#-hydroxy ketones." Thesis, University of Sheffield, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.388709.

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12

Wu, Luis Eduardo. "Synthesis of unnatural sugars from unsaturated ketones." Thesis, University of Liverpool, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.368669.

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13

Silvanus, Andrew. "Exploring the synthetic utility of divinyl ketones." Thesis, University of Bath, 2010. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.535271.

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Divided into three distinct research areas, this thesis investigates the synthetic utility of divinyl ketones as versatile substrates in the construction of novel cyclic structures. The first volume of work (Chapter 2) examines the one-pot Brønsted acid-catalysed tandem double alkylation of indole with non-symmetrical divinyl ketones. The [6,5,7] tricyclic indole products are often furnished in excellent yield, with complete regioselectivity and high levels of syn-diastereoselectivity. Optimisation, a thorough substrate investigation and initial results are all discussed within. An in-depth me

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14

Matsuda, Tomoko. "Asymmetric Reduction of Ketones by Geotrichum candidum." 京都大学 (Kyoto University), 2000. http://hdl.handle.net/2433/157209.

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本文データは平成22年度国立国会図書館の学位論文(博士)のデジタル化実施により作成された画像ファイルを基にpdf変換したものである<br>Kyoto University (京都大学)<br>0048<br>新制・論文博士<br>博士(理学)<br>乙第10364号<br>論理博第1380号<br>新制||理||1182(附属図書館)<br>UT51-2000-F430<br>(主査)助教授中村薫, 教授林民生, 教授大須賀篤弘<br>学位規則第4条第2項該当

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15

Camerino, Eugene. "Trifluoromethyl ketones: Potential insecticides towards Anopheles gambiae." Thesis, Virginia Tech, 2013. http://hdl.handle.net/10919/54015.

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Malaria continues to cause significant mortality in sub-Saharan Africa and elsewhere, and existing vector control measures are being threatened by growing resistance to pyrethroid insecticides. With the goal of developing new human-safe, resistance-breaking insecticides we have explored several classes of acetylcholinesterase inhibitors. In vitro assay studies have shown that trifluoromethyl ketones (TFK\'s) are potent inhibitors of An. gambiae AChE (AgAChE), that inhibit the enzyme by making a covalent adduct with the catalytic serine of the enzyme. However research in the Carlier group ha

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16

Moody, Catherine Laura. "Improved routes to unsaturated ketones and heterocycles." Thesis, University of York, 2012. http://etheses.whiterose.ac.uk/2409/.

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The work herein comprises two distinct projects: the first involves the construction of allylic ketones and enones directly from primary alcohols, using a novel one-pot procedure. Following development of this methodology, its application to the synthesis of indolizidine alkaloid elaeokanidine A was investigated. The second research area concerns the development of a copper(II)-catalysed radical cyclisation reaction to form spirocyclic oxindoles directly from linear anilides, along with subsequent preliminary studies towards to the synthesis of spirotryprostatin A.

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17

Drumright, Ray E. "Radical anion rearrangements. aryl cyclopropyl ketyl anions." Diss., This resource online, 1991. http://scholar.lib.vt.edu/theses/available/etd-07282008-134853/.

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18

Tang, Man-wai Simon. "Novel cyclic ketones for catalytic epoxidation of olefins /." Hong Kong : University of Hong Kong, 1997. http://sunzi.lib.hku.hk/hkuto/record.jsp?B1853871X.

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19

Karabacak, Elife Ozlem. "Aspergillus Niger Mediated A-hydroxylation Of Cyclic Ketones." Master's thesis, METU, 2006. http://etd.lib.metu.edu.tr/upload/3/12608088/index.pdf.

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Chiral a -hydroxy ketones are important structural units in many natural products, biologically active compounds and the hydroxyl group has frequently been used as a reagent directing group, such as for the selective elaboration of aldol products. In this work, enzymatic synthesis of both enantiomers of the a -hydroxy ketones (2-hydroxy indanone, 2-hydroxy tetralone) using Aspergillus niger by selective &amp<br>#945<br>-oxidation of ketones (1-indanone, 1-tetralone) was studied. The &amp<br>#945<br>-oxidation of ketones was carried out by using whole cells of Aspergillus niger in different gro

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20

Aybey, Ayse. "Oxidative Ring Opening Reactions Of A-hydroxy Ketones." Master's thesis, METU, 2008. http://etd.lib.metu.edu.tr/upload/3/12609279/index.pdf.

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Chiral polyfunctionalized 1,5-dicarbonyl compounds are important synthetic intermediates and starting materials for many biologically active compounds so their synthesis has a great importance in the literature. In the first step, 1,3-cyclohexandione and other b-diketone derivatives are protected under acid catalyzation and their corresponding b-keto enol ether derivatives are obtained. These b-keto enol ethers are then converted to a-acetoxy enones in racemic form by Mn(OAc)3 mediated oxidation. Enzymatic kinetic resolution is applied to the racemic acetoxy enones by using different lipases

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21

Fairhurst, Robin A. "Stereochemical aspects in the aminoalkylation reactions of ketones." Thesis, Loughborough University, 1991. https://dspace.lboro.ac.uk/2134/28437.

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A simple "one-pot" method has been developed for the amino-methylation of ketones possessing an α-hydrogen under aprotic conditions. The procedure utilises chlorotrimethylsilane in the sequential formation of the intermediate trimethylsilyl enol ether and methylene iminium species. The methylene iminium ion intermediate is generated either from a dialkylaminoalkoxymethane or a bis-(dialkylamino)methane.

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22

鄧文偉 and Man-wai Simon Tang. "Novel cyclic ketones for catalytic epoxidation of olefins." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1997. http://hub.hku.hk/bib/B31214654.

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23

鄧陽招 and Yeung-chiu Dennis Tang. "Accelerated decomposition of peroxynitrite by Ketones and Aldehydes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1999. http://hub.hku.hk/bib/B31221701.

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24

Cunningham, Anthony. "Catalytic enantioselective reductions and allylations of prochiral ketones." Thesis, University of Nottingham, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.251974.

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25

Sandey, Helen Jane. "Biotransformations of bicyclic ketones to lactones by microorganisms." Thesis, University of Exeter, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.293978.

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26

Allan, John Fraser. "Reactions of amidomagnesium compounds with ketones and aldehydes." Thesis, University of Strathclyde, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.415132.

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27

Fullbrook, Jeremy Jon. "Generating structural diversity in α,α-difluoromethyl ketones". Thesis, University of Birmingham, 2003. http://etheses.bham.ac.uk//id/eprint/98/.

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This thesis describes attempts to use palladium-catalysed cross-coupling methodology in the synthesis of α,α-difluoroketones contained within a diverse array of molecular motifs. 1-(N,N-Diethylcarbamoyloxy)-2,2-difluoro-1-(tributylstannyl)ethene undergoes Stille cross coupling with a variety of aryl, heteroaryl, vinyl and allyl organic electrophiles. Conditions, which promote in situ transmetallation to a more reactive copper intermediate, were essential for obtaining significant quantities of product. 1-(N,N-Diethylcarbamoyloxy)-2,2-difluoro-1-iodoethene also underwent coupling with a range o

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28

Phillips, Janice Paige. "Rearrangements of Radical Anions Generated from Cyclopropyl Ketones." Diss., Virginia Tech, 1998. http://hdl.handle.net/10919/40178.

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Cyclopropyl-containing substrates have been frequently utilized as "probes" for the detection of SET pathways in organic and biorganic systems. These reactions are based on the cyclorpropylcarbinyl - homoallyl rearrangement, which is fast and essentially irreversible. The implicit assumption in such studies is that if a "radical" species is produced, it will undergo ring opening. We have found that there are two important factors to consider in the design of SET probes: 1) ring strain, the thermodynamic driving force for the rearrangement, and 2) resonance energy, which may

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29

Tang, Yeung-chiu Dennis. "Accelerated decomposition of peroxynitrite by Ketones and Aldehydes /." Hong Kong : University of Hong Kong, 1999. http://sunzi.lib.hku.hk/hkuto/record.jsp?B20897145.

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30

Yamanaka, Rio. "Biocatalytic Asymmetric Reduction of Ketones by Photosynthetic Organisms." 京都大学 (Kyoto University), 2003. http://hdl.handle.net/2433/149105.

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31

Mathis, Tiffaney M. "Synthesis and characterization of o-Acylnaphthols a thesis presented to the faculty of the Graduate School, Tennessee Technological University /." Click to access online, 2008. http://proquest.umi.com/pqdweb?index=0&did=1679676631&SrchMode=1&sid=2&Fmt=6&VInst=PROD&VType=PQD&RQT=309&VName=PQD&TS=1268416679&clientId=28564.

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32

呂幹雄 and Kon-hung Lui. "Complementary approaches to 2,2-disubstituted 1,4-diketones, and the preparation and properties of 3H- and 3H-pyrroles derived from them." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1988. http://hub.hku.hk/bib/B31231299.

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33

Walker, Louise F. "Synthetic applications of alkylidene carbenes." Thesis, University of Warwick, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.343952.

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34

Masters, Susannah Jane. "Studies towards the synthesis of the squalestatins." Thesis, University of Sheffield, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.298950.

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35

Grocock, Estella Louise. "Novel catalysts and mechanistic investigation in dioxirane-mediated oxidations." Thesis, Loughborough University, 2000. https://dspace.lboro.ac.uk/2134/33767.

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The work described in this thesis follows the development of a family of achiral trifluoroketones, which were studied for use as ketone catalysts for the in situ generation of dioxiranes. One of the ketones investigated was a novel solid phase polymer-bound ketone, which led to a new area for dioxirane generation that could be of particular use in industry. Oxidations were run under monophasic and biphasic solvent reaction systems, with emphasis on the former. Ranges of reactions, including epoxidation and alcohol oxidations were examined to test the efficiency of each ketone. It was found tha

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36

Wong, Man-kin. "Design and synthesis of chiral ketones for catalytic asymmetric epoxidation of unfunctionalized olefins /." Hong Kong : University of Hong Kong, 1996. http://sunzi.lib.hku.hk/hkuto/record.jsp?B1815623X.

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37

Yip, Yiu-chung. "Asymmetric epoxidation of unfunctionalized olefins catalyzed by chiral ketones /." Hong Kong : University of Hong Kong, 1996. http://sunzi.lib.hku.hk/hkuto/record.jsp?B18156502.

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38

Lui, Kon-hung. "Complementary approaches to 2,2-disubstituted 1,4-diketones, and the preparation and properties of 3H- and 3H-pyrroles derived from them /." [Hong Kong : University of Hong Kong], 1988. http://sunzi.lib.hku.hk/hkuto/record.jsp?B12349367.

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39

Torok, Daniel Seth 1963. "Diastereoselective cyclopropanations of alpha,beta-unsaturated ketals derived from chiral hydrobenzoin." Thesis, The University of Arizona, 1988. http://hdl.handle.net/10150/276784.

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2-Cycloalken-1-one-(-)-erythro-hydrobenzoin ketals undergo efficient and diastereoselective cyclopropanation when treated with an excess of Simmons-Smith reagent. The resulting crystalline products yield enantiomerically pure cyclopropyl compounds upon recrystallization. For example, 2-cyclohexen-1-one-(-)-erythro-hydrobenzoin ketal gave, in 90% yield, a 19:1 mixture of diastereomeric cyclopropanes as established by 62.9 MHz ¹³C NMR spectroscopy. Upon one recrystallization, diastereomerically pure cyclopropane was obtained in 78% recovery. Hydrolysis gave (+)-norcaranone of greater than 99% ee

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40

Ucak-Astarlioglu, Mine Gunes. "The electronic structure and spectroscopy of diarylidene-cycloalkanones and their protonated cations." Link to electronic thesis, 2003. http://www.wpi.edu/Pubs/ETD/Available/etd-0506103-160044.

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Thesis (Ph. D.)--Worcester Polytechnic Institute.<br>Keywords: polyene ketones; diarylidene-cycloalkanones; spectroscopy; electronic structure; protonated cations; photochemistry; electronic states. Includes bibliographical references (p. 189-191).

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41

Esiringu, Ilker. "Intermolecular Addition Of Aldehydes To Ketones Via Acyl Phosphonates." Master's thesis, METU, 2008. http://etd.lib.metu.edu.tr/upload/3/12609441/index.pdf.

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This thesis presents a new developed method for first intermolecular aldehyde/ketone cross benzoin coupling. Protected &amp<br>#945<br>-keto tertiary alcohols are synthesized starting from easily available acyl phosphonates and ketones via Brook rearrangement in the presence of catalytic amount of cyanide ion. The scopes and the limitations of the methods for the synthesis of tertiary alcohols with &amp<br>#945<br>-keto group are discovered.

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42

Tsuchiya, Tomoki. "Novel chiral ketones as catalysts for asymmetric epoxidation reactions." Thesis, Imperial College London, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.419713.

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43

Wailes, J. Steven. "Novel chiral ketones as catalysts for asymmetric oxidation reactions." Thesis, University of Nottingham, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.364652.

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44

Lewis, John David. "An investigation of the enzymatic reduction of bicyclic ketones." Thesis, Cardiff University, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.316234.

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45

Heal, William. "Polyleucine catalysed asymmetric epoxidation of Î±,Î²-unsaturated ketones." Thesis, University of Liverpool, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.272718.

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46

Parsy, Christophe C. "Flavin and electron deficient ketones as hydrogen peroxide activators." Thesis, University of Liverpool, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.343927.

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47

Fang, Zhijia. "Asymmetric reduction of functionalized ketones and their synthetic applications." Thesis, University of Warwick, 2013. http://wrap.warwick.ac.uk/59696/.

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Asymmetric transfer hydrogenation (ATH) represents a powerful methodology for the synthesis of chiral secondary alcohols. The synthesis of chiral propargylic alcohols by asymmetric transfer hydrogenation of acetylenic ketones has been applied to a number of applications including target oriented synthesis. In this thesis, the asymmetric transfer hydrogenation of a large number of functionalized alkyones and dialkyones has been fully investigated. Basic principles as well as detailed reaction conditions for the ATH of acetylenic ketones have been established. Chiral propargylic alcohols have be

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48

Carr, Sheryl Teresa. "Insulin and Ketones: Their Roles in Brain Mitochondrial Function." BYU ScholarsArchive, 2017. https://scholarsarchive.byu.edu/etd/6810.

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The prevalence of both Type 2 diabetes mellitus (T2DM) and Alzheimer's disease (AD) is increasing worldwide, and the trends are unfortunately expected to continue. AD has recently been tied with mitochondrial dysfunction and insulin resistance, creating a mechanistic tie between AD and T2DM. Unfortunately, insulin resistance is often increased with aging and therefore, all individuals are at risk of brain mitochondrial dysfunction. Without proper mitochondrial function, the brain will degenerate, causing impaired cognitive function and reduced quality of life. The purpose of this study is two-

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49

葉耀宗 and Yiu-chung Yip. "Asymmetric epoxidation of unfunctionalized olefins catalyzed by chiralketones." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1996. http://hub.hku.hk/bib/B31236406.

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50

黃文健 and Man-kin Wong. "Design and synthesis of chiral ketones for catalytic asymmetric epoxidation of unfunctionalized olefins." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1996. http://hub.hku.hk/bib/B31236285.

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