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Artículos de revistas sobre el tema "Wacker"

Autor: Grafiati

Publicado: 4 de junio de 2021

Última modificación: 29 de marzo de 2025

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1

Naraynsingh, Vijay y Michael J. Ramdass. "Missile Injury by A Weed Wacker Resulting in a False Aneurysm of the Brachial Artery". Open Cardiovascular Medicine Journal 5, n.º 1 (3 de noviembre de 2011): 218–19. http://dx.doi.org/10.2174/1874192401105010218.

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A novel now commonly used device in many countries called a “weed-wacker” is a mechanical rotating device with a cord used to trim lawns and grass. A case of a 14-year old boy with a false aneurysm of the brachial artery is presented; he sustained a missile injury by a piece of rusty steel projected by use of a weed wacker. Missile injuries by nail guns and bullets have been documented in the literature; however, this mechanism of injury by a weed-wacker has never been previously described and is presented as a unique mechanism of injury and brings attention the issue of safety with the use of the weed-wacker.

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2

Braman, George N. "Wacker Revisited". Annals of Internal Medicine 128, n.º 1 (1 de enero de 1998): 69. http://dx.doi.org/10.7326/0003-4819-128-1-199801010-00012.

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3

Qin, Shuhao, Lei Dong, Zhuqi Chen, Sicheng Zhang y Guochuan Yin. "Non-redox metal ions can promote Wacker-type oxidations even better than copper(ii): a new opportunity in catalyst design". Dalton Transactions 44, n.º 40 (2015): 17508–15. http://dx.doi.org/10.1039/c5dt02612a.

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4

Han, Wei y Binbin Liu. "Iron-Catalyzed Wacker-Type Oxidation". Synlett 29, n.º 04 (29 de enero de 2018): 383–87. http://dx.doi.org/10.1055/s-0036-1591532.

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Compared with the widespread use of Pd-catalyzed Wacker-type oxidation of olefins, iron catalysis for this transformation is almost virgin territory. Our work on an iron-catalyzed Wacker-type oxidation through reductive activation of dioxygen is discussed here. This novel single-electron-transfer process not only addresses the issues of the Pd-catalyzed two-electron Wacker-type oxidation, but also possesses unprecedented functional-group tolerance and chemoselectivity. Importantly, the catalytic system uses ambient air as the sole oxidant, and it permits late-stage oxidations of complex molecules.

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5

Barboza, Amanda Aline, Juliana Arantes Dantas, Guilherme Augusto de Melo Jardim, Marco Antonio Barbosa Ferreira, Mateus Oliveira Costa y Attilio Chiavegatti. "Recent Advances in Palladium-Catalyzed Oxidative Couplings in the Synthesis/Functionalization of Cyclic Scaffolds Using Molecular Oxygen as the Sole Oxidant". Synthesis 54, n.º 09 (19 de noviembre de 2021): 2081–102. http://dx.doi.org/10.1055/a-1701-7397.

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AbstractOver the past years, Pd(II)-catalyzed oxidative couplings have enabled the construction of molecular scaffolds with high structural diversity via C–C, C–N and C–O bond-forming reactions. In contrast to the use of stoichiometric amounts of more common oxidants, such as metal salts (Cu and Ag) and benzoquinone derivatives, the use of molecular oxygen for the direct or indirect regeneration of Pd(II) species presents itself as a more viable alternative in terms of economy and sustainability. In this review, we describe recent advances on the development of Pd-catalyzed oxidative cyclizations/functionalizations, where molecular oxygen plays a pivotal role as the sole stoichiometric oxidant.1 Introduction2 Oxidative C–C and C–Nu Coupling2.1 Intramolecular Oxidative C–Nu Heterocyclization Reactions2.1.1 C–H Activation2.1.2 Wacker/Aza-Wacker-Type Cyclization2.1.3 Tandem Wacker/Aza-Wacker and Cyclization/Cross-Coupling Reactions2.2 Intermolecular Oxidative C–Nu Heterocoupling Reactions2.3 Intramolecular Oxidative (C–C) Carbocyclization Reactions2.4 Intermolecular Oxidative C–C Coupling Reactions2.4.1 Cyclization Reactions2.4.2 Cross-Coupling Reactions2.4.3 Homo-Coupling Reactions3 Aerobic Dehydrogenative Coupling/Functionalization4 Oxidative C–H Functionalization5 Summary

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6

Schlienkamp, Christoph. "Wacker Neuson SE". Die Aktiengesellschaft 67, n.º 13-14 (1 de julio de 2022): r199—r200. http://dx.doi.org/10.9785/ag-2022-6713-1441.

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7

Bulmahn, Maren. "Bilanz 2020: Wacker". Nachrichten aus der Chemie 69, n.º 6 (junio de 2021): 43. http://dx.doi.org/10.1002/nadc.20214110457.

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8

VOITH, MELODY. "TASTE OF WACKER". Chemical & Engineering News 88, n.º 15 (12 de abril de 2010): 20. http://dx.doi.org/10.1021/cen-v088n015.p020.

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9

Nussenblatt, Robert. "Waldon Wacker, PhD". Ophthalmic Research 27, n.º 6 (1995): 366–67. http://dx.doi.org/10.1159/000267749.

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10

Reynolds, N. J. "Weed wacker dermatitis". Archives of Dermatology 127, n.º 9 (1 de septiembre de 1991): 1419–20. http://dx.doi.org/10.1001/archderm.127.9.1419.

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11

Reynolds, N. J. "Weed Wacker Dermatitis". Archives of Dermatology 127, n.º 9 (1 de septiembre de 1991): 1419. http://dx.doi.org/10.1001/archderm.1991.01680080159028.

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12

Bulmahn, Maren. "Bilanz 2016: Wacker". Nachrichten aus der Chemie 65, n.º 6 (junio de 2017): 651. http://dx.doi.org/10.1002/nadc.20174061442.

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13

Ummah, Khoirotul, Robby Gus Mahardika y Ana Mardliyah. "Sintesis Senyawa Vanilil Metil Keton dan Uji Aktivitas Antiinflamasi terhadap Enzim COX-1 dan COX-2 melalui Analisis In Silico". ALCHEMY 8, n.º 2 (23 de noviembre de 2020): 1–11. http://dx.doi.org/10.18860/al.v8i2.10863.

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This study reports the synthesis of vanillyl methyl ketone from eugenol through Wacker oxidation and anti-inflammatory activity test toward COX-1 and COX-2 through in silico analysis. Wacker oxidation process was catalyzed by PdCl2 and CuCl2 using DMF solvent under the aerobic condition at room temperature for 48 hours. The product of the synthesis was purified by column chromatography and was characterized by NMR, IR, and MS spectroscopy. Characterization by spectroscopic methods showed that vanillyl methyl ketone was formed with a yield of 45% and vanillin (3%) was produced as a by-product. The anti-inflammatory activity of vanillyl methyl ketone was carried out by molecular docking toward COX-1 and COX-2 obtained from PDB. The analysis showed that the anti-inflammatory activity and selectivity toward COX-2 of vanillyl methyl ketone was higher than eugenol. This was shown by the low binding energy affinity and the number of hydrogen bonds formed between the vanillyl methyl ketone and the active site of the enzyme. Keywords: eugenol, Wacker, vanillyl methyl ketone, antiinflammatory, in silico Pada penelitian ini dilakukan sintesis senyawa vanilil metil keton dari eugenol melalui oksidasi Wacker serta dilakukan uji aktivitas antiinflamasi terhadap enzim COX-1 dan COX-2 melalui analisis in silico. Proses oksidasi Wacker dikatalisis oleh PdCl2 dan CuCl2 menggunakan pelarut DMF dalam kondisi aerob pada suhu ruang selama 48 jam. Senyawa hasil sintesis dipisahkan menggunakan kolom kromatografi dan dikarakterisasi menggunakan spektroskopi NMR, IR dan MS. Hasil karakterisasi menunjukkan bahwa senyawa vanilil metil keton telah terbentuk dengan randemen sebanyak 45% dan juga dihasilkan senyawa vanillin (3%) sebagai produk samping. Aktivitas antiinflamasi senyawa vanilil metil keton dilakukan dengan docking molekuler terhadap enzim COX-1 dan COX-2 yang diperoleh dari PDB. Hasil analisis menunjukkan bahwa aktivitas antiinflamasi dan selektivitas terhadap COX-2 pada senyawa vanilil metil keton lebih tinggi dibandingkan eugenol. Hal ini ditunjukkan melalui rendahnya afinitas energi pengikatan dan banyaknya ikatan hidrogen yang terbentuk antara vanilil metil keton dengan sisi aktif enzim. Kata kunci : eugenol, Wacker, vanilil metil keton, antiinflamasi, in silico

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14

Marey Mahmoud, Hussein Hassan. "The Efficiency of Polymeric Coatings for the Conservation of Ancient Egyptian Wall Paintings, El-Qurna Necropolis, Upper Egypt". Ge-conservacion 3 (14 de diciembre de 2012): 89–104. http://dx.doi.org/10.37558/gec.v3i0.97.

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The present work aims at studying the long-term protection of damaged Egyptian wall paintings (tomb of Ameneminet, No. TT277, Ramesside Period), El-Qurna necropolis, Upper Egypt. To achieve this, the efficiency of some polymeric materials for the consolidation of laboratory samples similar to the ancient murals was evaluated. The climatic conditions of the area play an important role in accelerating the damages process of the paintings. Crystallization cycles of salts exert additional pressure by producing cracking, powdering and flaking, in addition to pulverization of the pictorial layers. Different commercial products based on acrylic and silicone consolidation materials were tested in this study. The evaluation of the consolidation process was performed using the visual observation, scanning electron microscopy (SEM), contact angle values, color measurements and determining the physical and mechanical properties. The results showed that the superior behavior of water repellency was obtained by the micro emulsion Wacker VP 1311. Moreover, the application of the stone strengthener Wacker OH and the acrylic co-polymer Paraloid B82 helped in improving the physical and mechanical properties of the treated samples. In conclusion, Wacker OH could be used to enhance the durability of the inner matrix; however, the application of the microemulsion Wacker VP 1311 as a protective layer will increase the material’s water repellency in areas subjected to moisture or ground water attack.

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15

Schilter, David. "Wacker mole of ethylene". Nature Reviews Chemistry 4, n.º 5 (31 de marzo de 2020): 226. http://dx.doi.org/10.1038/s41570-020-0181-4.

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16

Kulkarni, Mukund G., Yunnus B. Shaikh, Ajit S. Borhade, Sanjay W. Chavhan, Attrimuni P. Dhondge, Dnyaneshwar D. Gaikwad, Mayur P. Desai, Deekshaputra R. Birhade y Nagorao R. Dhatrak. "Greening the Wacker process". Tetrahedron Letters 54, n.º 19 (mayo de 2013): 2293–95. http://dx.doi.org/10.1016/j.tetlet.2013.01.082.

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17

SHORT, PATRICIA L. "SUN’S WARMTH CUSHIONS WACKER". Chemical & Engineering News 87, n.º 14 (6 de abril de 2009): 18–19. http://dx.doi.org/10.1021/cen-v087n014.p018.

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18

Engl, Heinz W. "Hansjörg Wacker (1939–1991)". Computing 46, n.º 4 (diciembre de 1991): 275–78. http://dx.doi.org/10.1007/bf02257772.

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19

Engl, Heinz W. "In memorial Hansjörg Wacker". ZOR Zeitschrift für Operations Research Methods and Models of Operations Research 36, n.º 1 (enero de 1992): 1–2. http://dx.doi.org/10.1007/bf01541027.

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20

DEDIEU, A. "ChemInform Abstract: Wacker Reactions". ChemInform 27, n.º 15 (12 de agosto de 2010): no. http://dx.doi.org/10.1002/chin.199615332.

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21

Nussenblatt, Robert. "In Memoriam: Waldon Wacker". Experimental Eye Research 62, n.º 2 (febrero de 1996): 129–30. http://dx.doi.org/10.1006/exer.1996.0016.

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22

Bulmahn, Maren. "Bilanz 2018: Wacker Chemie". Nachrichten aus der Chemie 67, n.º 6 (junio de 2019): 33. http://dx.doi.org/10.1002/nadc.20194088728.

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23

Feringa, Ben L. "ChemInform Abstract: Wacker Oxidation". ChemInform 30, n.º 6 (17 de junio de 2010): no. http://dx.doi.org/10.1002/chin.199906290.

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24

Ragaišytė, Ieva, Mindaugas Daukšys y Albertas Klovas. "THE INFLUENCE OF SILANE BASED CHEMICAL ADMIXTURES ON THE PROPERTIES OF CEMENT STONE". Engineering Structures and Technologies 3, n.º 4 (31 de diciembre de 2011): 157–68. http://dx.doi.org/10.3846/skt.2011.18.

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The article accurately describes the influence of water repellent and silane based concrete admixtures on the technological, physical, mechanical and porosity properties of fine - concrete specimens. To obtain the expected results by changing the amount and type of the silane based chemical admixture, six compositions of concrete slurries were designed using six cube shaped (70,7 × 70,7 × 70,7 mm) and six plate shaped (250 × 250 × 30 mm) specimens. In order to get technological, physical and mechanical properties of concrete (concrete slurry), tests on the rigidity of concrete slurries, compression, bending and splitting strength were performed. In addition, experiments on porosity, frost resistance and water penetration were conducted. On the basis of the obtained results and using different amounts and types of silane based chemical admixtures, the rigidity of concrete (Vebe test) decreased up to 1.78 times in respect to the control specimen. On the other hand, when applying the above introduced silane based chemical admixtures, the results show that the density of concrete specimens (70,7 × 70,7 × 70,7 mm and 250 × 250 × 30 mm) varies accordingly (in respect to control specimen) from −1.69% (using WACKER BS 1001 0.1% in respect to the amount of cement used) to 0.84% (using SILRES BS 290 0.2%) and from −2.03% (using WACKER BS 1001 0.1%) to 0.71% (using SILRES BS 290 0.2%). Bending strength (testing plate shaped specimens) has decreased by 27.4% (using SILRES BS 209 0.2%), compression strength (testing cube shaped specimens) - by 34.6% (using WACKER BS 1701 0.2%) and finally, splitting strength - by 34.7% (by using SILRES BS 290 0.2%) in respect to the control specimen. Water absorption of concrete specimens (cube and plate shaped) without chemical silane based admixtures makes accordingly 2.61% and 4.09%. On the other hand, water absorption of concrete specimens (cube and plate shaped) with chemical silane based admixtures varies from 1.49% (using WACKER BS SMK 2101 0.1%) to 3.71% (using WACKER BS 1001 0.1%) and from 2.03% (using SILRES BS 3003 0.4%) to 4.14% (using WACKER BS 1001 0.1%) in respect to control specimens. The results achieved when conducting the water penetration test show that only the specimens without chemical silane based admixtures have failed the experiment. The results obtained following 100 cycles of freezing-thaw show that all specimens have passed the test and heir surfaces do not contain any cracks.

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25

Albarghouti, Ghassan, Ramesh Kotikalapudi, David Lankri, Viviana Valerio y Dmitry Tsvelikhovsky. "Cascade Pd(ii)-catalyzed Wacker lactonization–Heck reaction: rapid assembly of spiranoid lactones". Chemical Communications 52, n.º 15 (2016): 3095–98. http://dx.doi.org/10.1039/c5cc09923d.

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26

Thomas, Annu Anna, Someshwar Nagamalla y Shyam Sathyamoorthi. "Salient features of the aza-Wacker cyclization reaction". Chemical Science 11, n.º 31 (2020): 8073–88. http://dx.doi.org/10.1039/d0sc02554b.

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27

Zhao, JinWu, Li Liu, ShiJian Xiang, Qiang Liu y HuoJi Chen. "Direct conversion of allyl arenes to aryl ethylketones via a TBHP-mediated palladium-catalyzed tandem isomerization–Wacker oxidation of terminal alkenes". Organic & Biomolecular Chemistry 13, n.º 20 (2015): 5613–16. http://dx.doi.org/10.1039/c5ob00586h.

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28

Yang, Hongling, Xun Zhang, Yi Yu, Zheng Chen, Qinggang Liu, Yang Li, Weng-Chon Cheong et al. "Manganese vacancy-confined single-atom Ag in cryptomelane nanorods for efficient Wacker oxidation of styrene derivatives". Chemical Science 12, n.º 17 (2021): 6099–106. http://dx.doi.org/10.1039/d1sc00700a.

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29

Imbao, Jerick, Jeroen A. van Bokhoven y Maarten Nachtegaal. "Optimization of a heterogeneous Pd–Cu/zeolite Y Wacker catalyst for ethylene oxidation". Chemical Communications 56, n.º 9 (2020): 1377–80. http://dx.doi.org/10.1039/c9cc08835k.

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30

Hall, Steve y Dennis A. Vincenzi. "Software: SPSS for Windows SPSS Inc. 233 S. Wacker Dr., 11th Floor Chicago, IL 60606 (312) 651-3000 www.spss.com". Ergonomics in Design: The Quarterly of Human Factors Applications 9, n.º 3 (julio de 2001): 27–29. http://dx.doi.org/10.1177/106480460100900307.

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31

Brück, Mario. "Biermarkt erholt sich nur kurz". Lebensmittel Zeitung 76, n.º 42 (2024): 10. http://dx.doi.org/10.51202/0947-7527-2024-42-010-1.

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32

Bulmahn, Maren. "Bilanz Wacker 2023: Silikone, Polymere, Biopharmazeutika". Nachrichten aus der Chemie 72, n.º 6 (31 de mayo de 2024): 40. http://dx.doi.org/10.1002/nadc.20244140777.

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33

Wang, Shao-Rong, Pedro A. Sánchez-Murcia, Federico Gago y Wei-Shuo Fang. "A novel C,D-spirodioxene taxoid synthesized through an unexpected Pd-mediated ring cyclization". Organic & Biomolecular Chemistry 14, n.º 1 (2016): 345–52. http://dx.doi.org/10.1039/c5ob02131f.

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34

Unseld, Robert. "Wacker in die falsche Richtung". ATZelektronik 16, n.º 1-2 (febrero de 2021): 3. http://dx.doi.org/10.1007/s35658-020-0578-3.

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35

Matt Blois. "Wacker plans US silicone plant". C&EN Global Enterprise 100, n.º 27 (8 de agosto de 2022): 13. http://dx.doi.org/10.1021/cen-10027-buscon8.

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36

Michael McCoy. "Wacker opens labs in Michigan". C&EN Global Enterprise 100, n.º 18 (23 de mayo de 2022): 14. http://dx.doi.org/10.1021/cen-10018-buscon8.

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37

Bulmahn, Maren. "Wacker: Mit Silicium und Ethylen". Nachrichten aus der Chemie 70, n.º 5 (29 de abril de 2022): 54. http://dx.doi.org/10.1002/nadc.20224124206.

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38

Gouverneur, V., F. Silva, M. Reiter, R. Mills-Webb, M. Sawicki, D. Klär, N. Bensel y A. Wagner. "Palladium-Catalyzed Wacker-Heck Reactions". Synfacts 2007, n.º 3 (marzo de 2007): 0255. http://dx.doi.org/10.1055/s-2007-968258.

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39

Yeston, J. S. "CHEMISTRY: Building a Better Wacker". Science 310, n.º 5755 (16 de diciembre de 2005): 1743b. http://dx.doi.org/10.1126/science.310.5755.1743b.

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40

Keith, John A., Robert J. Nielsen, Jonas Oxgaard y William A. Goddard. "Unraveling the Wacker Oxidation Mechanisms". Journal of the American Chemical Society 129, n.º 41 (octubre de 2007): 12342–43. http://dx.doi.org/10.1021/ja072400t.

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41

Uozumi, Yasuhiro, Kazuhiko Kato y Tamio Hayashi. "Catalytic Asymmetric Wacker-Type Cyclization". Journal of the American Chemical Society 119, n.º 21 (mayo de 1997): 5063–64. http://dx.doi.org/10.1021/ja9701366.

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42

Kaufmann, Werner y Luigi M. Venanzi. "The Wacker-type oxidation allylamine". Journal of Organometallic Chemistry 417, n.º 1-2 (octubre de 1991): 205–9. http://dx.doi.org/10.1016/0022-328x(91)80174-i.

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43

Michel, Brian W., Laura D. Steffens y Matthew S. Sigman. "ChemInform Abstract: The Wacker Oxidation". ChemInform 46, n.º 41 (24 de septiembre de 2015): no. http://dx.doi.org/10.1002/chin.201541246.

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44

Schorsch, Gilbert. "Was Wacker Chemie leistungsfähig macht". Nachrichten aus der Chemie 56, n.º 12 (diciembre de 2008): 1266–67. http://dx.doi.org/10.1002/nadc.200858579.

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45

Bulmahn, Maren. "Wacker: Körperpflege, Trockenmörtel und Pharmaproteine". Nachrichten aus der Chemie 64, n.º 6 (30 de mayo de 2016): 629. http://dx.doi.org/10.1002/nadc.20164050024.

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46

Monflier, Eric y Andre Mortreux. "ChemInform Abstract: Wacker-type Oxidations". ChemInform 30, n.º 7 (17 de junio de 2010): no. http://dx.doi.org/10.1002/chin.199907305.

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47

Rick Mullin. "Wacker will buy ADL BioPharma". C&EN Global Enterprise 101, n.º 16 (22 de mayo de 2023): 11. http://dx.doi.org/10.1021/cen-10116-buscon14.

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48

Nakaoka, Sonoe, Yuka Murakami, Yasutaka Kataoka y Yasuyuki Ura. "Maleimide-assisted anti-Markovnikov Wacker-type oxidation of vinylarenes using molecular oxygen as a terminal oxidant". Chemical Communications 52, n.º 2 (2016): 335–38. http://dx.doi.org/10.1039/c5cc06746d.

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49

Huang, Guanwang, Lianyue Wang, Huihui Luo, Sensen Shang, Bo Chen, Shuang Gao y Yue An. "Isopropanol as a hydrogen source for single atom cobalt-catalyzed Wacker-type oxidation". Catalysis Science & Technology 10, n.º 9 (2020): 2769–73. http://dx.doi.org/10.1039/d0cy00409j.

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50

Fernandes, Rodney A., Amit K. Jha y Praveen Kumar. "Recent advances in Wacker oxidation: from conventional to modern variants and applications". Catalysis Science & Technology 10, n.º 22 (2020): 7448–70. http://dx.doi.org/10.1039/d0cy01820a.

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