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Thèses sur le sujet « Adsorption »

Auteur : Grafiati

Publié le 4 juin 2021

Mis à jour le 25 juillet 2025

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1

Bruce, L. J. "Hydrodynamics and adsorption within an expanded bed adsorption column." Thesis, University of Cambridge, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.597027.

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In this thesis, relationships between the hydrodynamics and adsorption behaviour within EBA columns were examined and methods to improve EBA performance in terms of productivity, reproducibility and control were provided. The effect of column verticality was quantified and identified as a significant source of process variability. Column misalignment of only 0.15° off vertical resulted in a greater increase in liquid dispersion in 1 cm diameter columns compared to 5 cm diameter columns. Protein breakthrough curves for vertical and 0.15° off-vertical runs performed using a 5 cm diameter column

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2

Borthwick, D. S. "Adsorption kinetics and thermodynamics from single crystal adsorption calorimetry." Thesis, University of Cambridge, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.596784.

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The interactions of CO, NO and O<sub>2</sub> with Pt{111}, pt{211}, and Pt{411} have been investigated with Single Crystal Adsorption Calorimetry (SCAC). Coverage-dependent heat of adsorption and sticking probability data for 300 K are presented, and are discussed with respect to the kinetics and thermodynamics of adsorption and desorption. CO adsorption proceeds molecularly on both Pt{111} and Pt{411}, with initial sticking probabilities of 0.78 and 0.80, and initial heats of adsorption of 176 kJ mol<sup>-1</sup> and 196 kJ mol<sup>-1</sup>, respectively. Both adsorbate layers are found to be

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3

Mahle, John J. "Adsorption humidity effects, microparticle rate behavior, and thermal swing adsorption." College Park, Md. : University of Maryland, 2005. http://hdl.handle.net/1903/3202.

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Thesis (Ph. D.) -- University of Maryland, College Park, 2005.<br>Thesis research directed by: Chemical Engineering. Title from t.p. of PDF. Includes bibliographical references. Published by UMI Dissertation Services, Ann Arbor, Mich. Also available in paper.

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4

Enarsson, Lars-Erik. "Polyelectrolyte adsorption on oppositely charged surfaces - Conformation and adsorption kinetics." Licentiate thesis, Stockholm : Royal Institute of Technology, 2006. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-4059.

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5

Edström, Emelie. "Solvent adsorption in SFC : Adsorption of methanol under supercritical conditions." Thesis, Karlstads universitet, Institutionen för ingenjörs- och kemivetenskaper, 2015. http://urn.kb.se/resolve?urn=urn:nbn:se:kau:diva-35185.

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Chromatography is a widely used separation technique including many different modes, for example supercritical fluid chromatography (SFC) which uses a supercritical fluid as mobile phase. A supercritical fluid is achieved when a substance is subjected to a temperature and pressure above the critical point and the boundary between the liquid phase and gas phase is erased. The interest for SFC has increased in recent years, mainly for separation of chiral molecules in the pharmaceutical industry. What makes SFC interesting is that it is a quick, cost-efficient and green method. This is in part d

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6

Lang, Matthew H. "Polyelectrolyte adsorption kinetics." Diss., Georgia Institute of Technology, 1994. http://hdl.handle.net/1853/5792.

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7

Kim, Hyunho Ph D. Massachusetts Institute of Technology. "Experimental characterization of adsorption and transport properties for advanced thermo-adsorptive batteries." Thesis, Massachusetts Institute of Technology, 2014. http://hdl.handle.net/1721.1/93826.

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Thesis: S.M., Massachusetts Institute of Technology, Department of Mechanical Engineering, 2014.<br>Cataloged from PDF version of thesis.<br>Includes bibliographical references (pages 77-79).<br>Thermal energy storage has received significant interest for delivering heating and cooling in both transportation and building sectors. It can minimize the use of on-board electric batteries for heating, ventilation and air-conditioning (HVAC) in electric vehicles (EVs) or reduce electricity consumption during peak demand in residential and commercial buildings. A compact and lightweight advanced ther

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8

Eve, Jemimah Kate. "Adsorption and co-adsorption on metal single crystals at cryogenic temperatures." Thesis, University of York, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.313949.

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9

Schurger, Uwe. "Investigation into solar powered adsorption cooling systems : adsorption technology and system analysis." Thesis, De Montfort University, 2007. http://hdl.handle.net/2086/4122.

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Due to the fact that the worldwide energy consumption caused by cooling devices in buildings has been increasing steadily and also the fact that the pressure has been rising to provide this cooling energy with environmentally friendly technology, solar powe.re~ DEC-systems (Desiccative and Evaporative Cooling) have begun capturing increasing interest over the past few years. , However, up to now little experience has been gained in the operation of these systems and thus currently little information is available about the performance, the efficiency, the control strategy and the best component

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10

Carlisle, C. "Atomic-scale imaging of adsorption, oxidation and co-adsorption on Ag{111}." Thesis, University of Cambridge, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.597289.

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The work presented in this thesis draws upon several uses of STM, from structural determination, when used in conjunction with theoretical simulations, to the observation of surface reactions and surface mediated interactions. Simulations have been used here for the first time to allow the complete structural determination of a complex reconstruction. The determination of the reconstruction's structure and composition has enabled further experiments involving the oxidation of the Ag{111} surface as well as adsorbate-oxygen interactions mediated by the surface. The source of inspiration for the

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11

Haskaraman, Feyza. "Thermal and hydraulic analysis of the adsorption bed of the adsorptive thermal battery." Thesis, Massachusetts Institute of Technology, 2016. http://hdl.handle.net/1721.1/105706.

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Thesis: S.B., Massachusetts Institute of Technology, Department of Mechanical Engineering, 2016.<br>Cataloged from PDF version of thesis.<br>Includes bibliographical references (page 23).<br>Electric vehicles (EVs) have a drawback of relatively short drive range that affects their adoption rate. In order to increase the drive range of EVs, replacing heating, ventilation and air conditioning (HVAC) system with a novel absorbent system of materials and methods is widely investigated. This work focuses on the analysis of the design of such a system to suggest efficiency improvements. The thermal

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12

Klingberg, Carlos Jiménez. "Selektive Adsorption von Immunglobulinen." Köln Deutsche Zentralbibliothek für Medizin, 2010. http://d-nb.info/1000935701/34.

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13

Scheuch, Sven. "Die Adsorption argonhaltiger Gasgemische." [S.l. : s.n.], 2002. http://deposit.ddb.de/cgi-bin/dokserv?idn=966284232.

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14

Nassara, Ramiel. "Adsorption separation of ethyleneethane." Thesis, University of Ottawa (Canada), 2008. http://hdl.handle.net/10393/27721.

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To offset rising energy costs, it is becoming a necessity to lower energy usage within industrial processes. Such can be said for the separation of olefin/paraffin mixtures. An example of such a mixture is ethylene/ethane. This highly energy intensive industrial separation employs cryogenic distillation to achieve a high purity product. Subsequently, the energy cost to run such a system is extremely high. Hybrid scenarios have been explored, with adsorption being a potential candidate. This work studied the potential of three adsorbents for the separation of ethylene/ethane: AgNO3/SiO2, CuCl/S

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15

Goren, Michal. "Nanoparticle adsorption onto surfaces." Thesis, McGill University, 2003. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=84250.

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The ability to produce materials in unique morphologies and structures is of great importance as a strategy in micro-and nanomaterial fabrication. Nanosized materials in particular are of great interest because of limited possibilities of producing them from their corresponding bulk materials ("top-down" approach). To a chemist, challenges lie in the synthesis of these nanostructures, as well as in producing them in a parallel fashion. One possible way of directly synthesizing a confined morphology is by templating, where the material to be synthesized is selectively grown on a surface

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16

Battrum, M. J. "Gas separation by adsorption." Thesis, University of Bath, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.376289.

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17

Bird, Christopher E. "Single crystal adsorption microcalorimetry." Thesis, University of Liverpool, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.316775.

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18

Shukla, Lalita. "Polymer adsorption in pores." Thesis, University of Bristol, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.333958.

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19

Valiullin, Rustem, Jörg Kärger, and Peter Monson. "Adsorption hysteresis in nanopores." Universitätsbibliothek Leipzig, 2016. http://nbn-resolving.de/urn:nbn:de:bsz:15-qucosa-196715.

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20

Navaei, Milad. "Quartz crystal microbalance adsorption apparatus for high pressure gas adsorption measurements in nanomaterials." Thesis, Georgia Institute of Technology, 2011. http://hdl.handle.net/1853/41057.

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The primary objective of this study was to develop a sensitive and cost-effective sorption system to analyze adsorption and diffusion of different gases on micro porous materials and nanotubes. A high pressure Quartz Crystal Microbalance (QCM) based adsorption apparatus for single-component gas was developed. A QCM is an acoustic-wave resonator in which the acoustic wave propagates through the crystal. Therefore, it is highly responsive to addition or removal of small amounts of mass adsorbed or deposited on the surface of the crystal. This mass sensitivity makes the QCM an ideal tool for the

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21

Uner, Murat. "Adsorption Calorimetry In Supported Catalyst Characterization: Adsorption Structure Sensitivity On Pt/y-al2o3." Master's thesis, METU, 2004. http://etd.lib.metu.edu.tr/upload/2/12605511/index.pdf.

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In this study, the structure sensitivity of hydrogen, oxygen and carbon monoxide adsorption was investigated by changing the metal particle size of Pt/Al2O3 catalysts. 2 % Pt/Al2O3 catalysts were prepared by incipient wetness method<br>the particle size of the catalysts was manipulated by calcining at different temperatures. The dispersion values for the catalysts calcined in air at 683K, 773K and 823K were measured as 0.62, 0.20 and 0.03 respectively. The differential heats of adsorption of hydrogen, carbon monoxide and oxygen were measured using a SETARAM C80 Tian-Calvet calorimeter. No st

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22

Edström, Lena. "Adsorption Studies with Liquid Chromatography : Experimental Preparations for Thorough Determination of Adsorption Data." Doctoral thesis, Uppsala universitet, Analytisk kemi, 2014. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-216235.

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Analytical chemistry is a field with a vast variety of applications. A robust companion in the field is liquid chromatography, the method used in this thesis, which is an established workhorse and a versatile tool in many different disciplines. It can be used for identification and quantification of interesting compounds generally present in low concentrations, called analytical scale chromatography. It can also be used for isolation and purification of high value compounds, called preparative chromatography. The latter is usually conducted in large scale with high concentrations. With high co

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23

Christie, Emma Louise. "Deconstructing adsorption variability : investigating controls on pesticide adsorption in soil and modelling Koc." Thesis, Durham University, 2013. http://etheses.dur.ac.uk/7347/.

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Due to potential environmental risks of pesticides, it is important that the fate of pesticides is known and that safer pesticides are developed in the future. This thesis focused on identifying controls on the Koc of pesticides in soil based on their structural parameters. This thesis also developed quantitative structure-activity relationship (QSAR) models to predict the environmental fate of new pesticides. To understand the controls on Koc, a range of multivariate statistical techniques were used including; principal component analysis, and analysis of variance. Predictive models were crea

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24

Ibrahim, Jamal Mohamad Bin Mohamad. "Establishing scale inhibitor retention mechanisms in pure adsorption and coupled adsorption/precipitation treatments." Thesis, Heriot-Watt University, 2012. http://hdl.handle.net/10399/2583.

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One of the most common and efficient ways for preventing formation of inorganic solids deposition such as carbonate and sulphate scales in reservoir and near wellbore formation is by applying scale inhibitor (SI) squeeze treatments. The two main mechanisms that govern the scale inhibitor retention and release process in the formation are by adsorption/desorption and precipitation/dissolution. They are described by different but related modelling approaches, and there is not complete agreement in the literature about when to use one mechanistic description or another. The equilibrium adsorption

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25

Papakokkinos, Giorgos. "Computational modeling of adsorption packed bed reactors and solar-driven adsorption cooling systems." Doctoral thesis, Universitat Politècnica de Catalunya, 2021. http://hdl.handle.net/10803/672099.

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Environmental concerns regarding climate change and ozone depletion urge for a paradigm shift in the cooling production. The cooling demand exhibits an alarmingly increasing trend, thus its satisfaction in a sustainable manner is imperative. Adsorption cooling systems (ACSs) are a potential candidate for a sustainable future of cooling production, since they can utilize solar energy or waste heat, as well as they can employ substances with zero ozone depletion and global warming potential. The objective of this thesis is to contribute to the investigation and improvement of ACSs, through the d

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26

Diao, Rui. "Fundamental Study of Simple Gas Adsorption and Adsorption-Induced Deformation in Carbonaceous Materials." Thesis, Curtin University, 2017. http://hdl.handle.net/20.500.11937/56504.

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This thesis has presented a fundamental study of simple gas adsorption and adsorption-induced deformation in carbonaceous materials including both graphite and porous carbon. Monte Carlo simulation was conducted to obtain the behaviours of adsorption and adsorption-induced solid deformation that are comparable to experimental studies including the adsorption isotherm, the strain isotherm and the isosteric heat, as well as the relevant microscopic properties that facilitate the understanding of underlying mechanisms.

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27

PIGNON, METIVIER HELENE. "Procedes de traitement d'eau par adsorption sur tissus de carbone active couplage ultrafiltration - adsorption." Nantes, 2001. http://www.theses.fr/2001NANT2038.

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L'etude presentee porte sur les procedes d'adsorption en milieu aqueux mettant en uvre des materiaux recents : les tissus de carbone active. Le couplage de ces derniers avec l'ultrafiltration est envisage pour le traitement d'effluents complexes. Dans un premier temps, l'adsorption de pesticides et de colorants sur tissu de carbone active est etudiee en reacteur discontinu, par le biais de cinetiques et d'equilibres d'adsorption en systeme mono- et multicompose. Les vitesses et capacites d'adsorption des pesticides sont d'autant plus importantes que la solubilite du micropolluant est faible. E

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28

Naden, Benjamin John. "Polymer adsorption to titania surfaces studied by adsorption isotherm, rheology and atomic force microscopy." Thesis, Imperial College London, 2008. http://hdl.handle.net/10044/1/4257.

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This Ph.D. study investigates the adsorption of monomeric (isostearic acid, ISA) and oligomeric fatty acids (poly(hydroxystearic acid), PHS 1400 and PHS 3500) to nanoparticles of industrial interest in carriers with different solvent properties. It was found that it was necessary to apply a number of methods to study the adsorption and subsequent stabilisation of the particles by the dispersing molecules, namely adsorption isotherm methods, rheological techniques, atomic force microscopy and UV/vis spectroscopy. The particles (surface) studied consist of uncoated titania and a commercially ava

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29

Gil, Girol Stefanie. "Adsorption von Maleinsäureanhydrid auf Zinkoxid." [S.l.] : [s.n.], 2004. http://deposit.ddb.de/cgi-bin/dokserv?idn=971701741.

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30

Meier, Robert. "Adsorption von Sauerstoff auf Lanthanidmetallen." [S.l. : s.n.], 1999. http://www.diss.fu-berlin.de/1999/39/index.html.

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31

Matsson, Maria. "Adsorption of polyhydroxyl based surfactants." Doctoral thesis, KTH, Chemistry, 2005. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-421.

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<p>Adsorption on solid surfaces from solution is a fundamental property of a surfactant. It might even be the most important aspect of surfactant behavior, since it influences many applications, such as cleaning, detergency, dispersion, separation, flotation, and lubrication. Consequently, fundamental investigations of surfactant adsorption are relevant to many areas.</p><p>The main aim of this thesis has been to elucidate the adsorption properties, primarily on the solid/water interface, of a particular class of polyhydroxyl based surfactants: the alkyl glucosides. By the use of ellipsometry,

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32

Lundstedt, Evert. "Adsorption av Sb på zeolit." Thesis, Växjö University, School of Technology and Design, 2007. http://urn.kb.se/resolve?urn=urn:nbn:se:vxu:diva-1591.

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<p>Detta examensarbete är en förundersökning till Glafos undersökning angående rening av glasbrukens processvatten från antimon med zeolit.</p><p>Förundersökningen gick ut på att via experiment ta reda på hur mycket antimon som adsorberas av behandlad (för optimering: dels med NaNO3 och dels med NaCl) och obehandlad zeolit (porstorlek 0.4 nm). pH mättes och ställdes eftersom det har betydelse för adsorptionen, åtminstone vid väldigt lågt pH. När lösningarna hade filtrerats mättes den kvarvarande antimonhalten med atomabsorptionsspektrofotometri. Mätningarna visade att i genomsnitt 53 % av Sb-h

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33

Mathes, Johannes. "Protein Adsorption to Vial Surfaces." Diss., lmu, 2010. http://nbn-resolving.de/urn:nbn:de:bvb:19-121255.

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34

Rasmussen, Inger-Anne. "Numerical study of hydrogen adsorption." Thesis, Norges teknisk-naturvitenskapelige universitet, Institutt for energi- og prosessteknikk, 2012. http://urn.kb.se/resolve?urn=urn:nbn:no:ntnu:diva-18589.

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The main objective of this thesis is to describe the transient thermodynamics during physisorption of hydrogen gas using a commercial numerical software.Simulations of thermal effects during adsorption are valuable tools for the efficient design of hydrogen adsorption storage systems. Transient mass and energy equations are used for describing the adsorption process. For this purpose, experimental adsorption data has to be presented analytically. Several models have been developed for this objective.The thesis consists of two parts. In the first, a literature study on adsorption theories and t

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35

Horstmann, Brenda Joan. "Affinity adsorption on agarose matrices." Thesis, University of Cambridge, 1989. https://www.repository.cam.ac.uk/handle/1810/250951.

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36

Janzen, Johan. "Fibrinogen adsorption to human erythrocytes." Thesis, University of British Columbia, 1985. http://hdl.handle.net/2429/25820.

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Fibrinogen adsorption to human erythrocytes has been implicated as the mechanism responsible for the reversible aggregation of red cells. The object of this thesis was to measure the binding of fibrinogen to human erythrocytes and to compare the binding with aggregation behaviour. The binding of isolated ¹²⁵I-fibrinogen to red cells was estimated from the amount of radiolabel removed from solution upon addition of cells, from the amount of radiolabel retained in cell pellets produced by ultracentrifugation and corrected for intracellular radiolabel, and from radiolabel retained by cells af

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37

Vovk, Gregory. "Adsorption studies of tin chalcogenides." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp04/mq28761.pdf.

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38

Matsson, Maria K. "Adsorption of polyhydroxyl based surfactants /." Stockholm : Chemical Science and Engineering, KTH, 2005. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-421.

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39

Alpay, Esat. "Rapid pressure swing adsorption processes." Thesis, University of Cambridge, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.333256.

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40

Manning-Benson, Samantha. "The dynamics of surfactant adsorption." Thesis, University of Oxford, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.298708.

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41

Hart, J. "Separation of gases by adsorption." Thesis, University of Bath, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.234617.

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42

Hassaballah, A. A. "Drying of alcohol by adsorption." Thesis, University of Nottingham, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.376626.

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43

Newell, Helen E. "Alkane adsorption on metal surfaces." Thesis, University of Nottingham, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.243748.

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44

Steele, Carl James. "Gold adsorption on active carbon." Thesis, University of Newcastle Upon Tyne, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.321858.

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45

Lewis, D. "Enzyme adsorption to polystyrene latex." Thesis, University of Strathclyde, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.382347.

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46

Naumov, Sergej, Rustem Valiullin, and Jörg Kärger. "Adsorption hysteresis phenomena in mesopores." Universitätsbibliothek Leipzig, 2016. http://nbn-resolving.de/urn:nbn:de:bsz:15-qucosa-194077.

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47

Walter, Andrew John. "Interfacial recognition and adsorption processes." Thesis, University of Leicester, 2006. http://hdl.handle.net/2381/29975.

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The design and function of receptors for molecular recognition is of vital importance for the construction of novel sensors. Initially the project has investigated the relationship between the shape of the active site of the receptor and its sensitivity and selectivity for analytes in solution. The techniques of electrochemistry, NMR and molecular modelling have been used to study materials interactions. An optimum receptor design was established for a range of analytes so that the surface of an electrode could be modified to create an analytical sensor. The specific adsorption of both the rec

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48

Murphy, Emma F. "Reduced protein adsorption on biomaterials." Thesis, University of Surrey, 1999. http://epubs.surrey.ac.uk/844207/.

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The adsorption of lysozyme, bovine serum albumin (BSA) and fibrinogen onto the surfaces of a number of poly (methacrylate) based, phosphorylcholine (PC)-containing polymer films has been characterised by neutron reflection and spectroscopic ellipsometry. The work represents the first systematic study of these biocompatible materials, attempting to establish the relationship between the structure of the films and their effectiveness in reducing protein adsorption. The polymer surface was formed by dip-coating a thin film of polymer onto the polished silicon oxide. As the extent of reduction in

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49

Dalton, James Spencer. "The kinetics of surfactant adsorption." Thesis, University of Bristol, 1999. http://hdl.handle.net/1983/d2ce527d-0373-4191-b2d9-8e9e7d81dd9f.

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50

Naumov, Sergej, Rustem Valiullin, and Jörg Kärger. "Adsorption hysteresis phenomena in mesopores." Diffusion fundamentals 6 (2007) 67, S. 1-2, 2007. https://ul.qucosa.de/id/qucosa%3A14247.

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