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Articles de revues sur le sujet « Clathrate compounds »

Auteur : Grafiati

Publié le 4 juin 2021

Mis à jour le 30 juillet 2024

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1

Celli, Milva, Daniele Colognesi, Alessandra Giannasi, Lorenzo Ulivi, Marco Zoppi, Victoria Garcia Sakai, and Aníbal Javier Ramírez-Cuesta. "Simple and Binary Hydrogen Clathrate Hydrates: Synthesis and Microscopic Characterization through Neutron and Raman Scattering." Advances in Science and Technology 72 (October 2010): 196–204. http://dx.doi.org/10.4028/www.scientific.net/ast.72.196.

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The search for efficient hydrogen-storage materials has led to an increasing interest in hydrogen clathrate hydrates, since it has been demonstrated that an appreciable amount of molecular hydrogen can be stored in the water cages and released at melting. Different synthetic routes have been followed to maximize the quantity of trapped hydrogen and to speed up the kinetics of the clathrate formation. Here, we describe two different synthetic routes for the production of hydrogen clathrate hydrates. Then we present the results of inelastic neutron scattering and Raman light scattering experimen

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2

Li, De Cong, and Hai Rong Wang. "Structural and Electrical Transport Properties of the Type-I Clathrate Phase Ba₈Ga₁₆In_xGe_30-x." Advanced Materials Research 833 (November 2013): 343–48. http://dx.doi.org/10.4028/www.scientific.net/amr.833.343.

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Thermoelectric (TE) devices are increasingly being seen as having the potential to make important contributions to reducing greenhouse gas emissions and providing cleaner forms of energy. A number of articles have been devoted to the thermoelectric properties of materials. From the search for novel and effective thermoelectric materials the clathrate structures has emerged as one of the most promising candidates for achieving very high thermoelectric figure of merit: ZT= α2σT/κ, where α, T, σ and κ are the Seebeck coefficient, absolute temperature, electrical conductivity, and total thermal co

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3

Momma, Koichi. "Clathrate compounds of silica." Journal of Physics: Condensed Matter 26, no. 10 (February 19, 2014): 103203. http://dx.doi.org/10.1088/0953-8984/26/10/103203.

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Tsapko, Yu L. "Discussion problems of humus nature." Fundamental and Applied Soil Science 16, no. 3-4 (October 25, 2015): 83–89. http://dx.doi.org/10.15421/041521.

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The article is based on a generalization of the author's prior research and review of scientific sources, discussion questions about the nature of humus are put and in particular the latest structural views on the structure of humus are given. Is emphasized that despite the long experience of studying soil humus question its structural buildings has not been studied. Nowadays the scientific community there are a number of different and often antagonistic hypotheses on which the structure of humus is significantly different. Based on the features of genetic connection between fulvic and humic a

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Huang, Yingying, Chongqin Zhu, Lu Wang, Xiaoxiao Cao, Yan Su, Xue Jiang, Sheng Meng, Jijun Zhao, and Xiao Cheng Zeng. "A new phase diagram of water under negative pressure: The rise of the lowest-density clathrate s-III." Science Advances 2, no. 2 (February 2016): e1501010. http://dx.doi.org/10.1126/sciadv.1501010.

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Ice and ice clathrate are not only omnipresent across polar regions of Earth or under terrestrial oceans but also ubiquitous in the solar system such as on comets, asteroids, or icy moons of the giant planets. Depending on the surrounding environment (temperature and pressure), ice alone exhibits an exceptionally rich and complicated phase diagram with 17 known crystalline polymorphs. Water molecules also form clathrate compounds with inclusion of guest molecules, such as cubic structure I (s-I), cubic structure II (s-II), hexagonal structure H (s-H), tetragonal structure T (s-T), and tetragon

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Belosludov, V. R., O. S. Subbotin, D. S. Krupskii, O. V. Prokuda, R. V. Belosludov, and Y. Kawazoe. "Microscopic model of clathrate compounds." Journal of Physics: Conference Series 29 (January 1, 2006): 1–7. http://dx.doi.org/10.1088/1742-6596/29/1/001.

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Nagao, Jiro. "C151 Research on Clathrate Compounds." Proceedings of the Thermal Engineering Conference 2006 (2006): 103–4. http://dx.doi.org/10.1299/jsmeted.2006.103.

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Bock, Hans, Norbert Nagel, and Peter Eller. "Wechselwirkungen in Molekülkristallen, 153 [1 - 3]. Wirt/Gast-Einschlußverbindungen von N,N'-Ditosyl-p-phenylendiamin-Derivaten: Die Kristallstrukturen von N,N'-Di(4-ethyl-benzosulfuryl)-p-phenylendiamin und seinen Aggregaten mit Aceton und Cyclopentanon / Interactions in Molecular Crystals, 153 [1 - 3]. Host/Guest-Inclusion Compounds of N,N'-Ditosyl-p-phenylenediamine Derivatives: The Crystal Structures of N,N'-Di(4-ethyl-benzosulfuryl)-p-phenylenediamine and its Aggregates with Acetone and Cyclopentanone." Zeitschrift für Naturforschung B 54, no. 4 (April 1, 1999): 491–500. http://dx.doi.org/10.1515/znb-1999-0413.

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A class of novel inclusion compounds based on the hydrogen-bonded host lattice of N,N′- ditosyl-p-phenylenediamine is the starting point for the investigation of derivatives such as N,N′- di(4-ethyl-benzosulfuryl)-p-phenylenediamine. Structures of both the guest-free compound and of its clathrates with acetone as well as cyclopentanone suggest a considerable enthalpy of formation contribution from the conformational change of the sulfonamide backbone on adaption of the guest molecules. The host channels of the N,N′-ditosyl-p-phenylenediamine inclusion compounds are compared to those of the eth

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Yan, X., E. Bauer, P. Rogl, and S. Paschen. "Influence of Sn on the structural and thermoelectric properties of the type-I clathrates Ba8Cu5Si6Ge35-xSnx (0 ≤ x ≤ 0.6)." MRS Proceedings 1490 (2013): 19–26. http://dx.doi.org/10.1557/opl.2013.23.

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ABSTRACTOn the search for cost-competitive thermoelectric clathrates we have investigated the influence of Sn substitutions for Ge on the structural and thermoelectric properties of the type-I clathrate Ba8Cu5Si6Ge35. The solid solubility of Sn was found to be limited to 0.6 atoms per unit cell. A series of compounds with the nominal compositions Ba8Cu5Si6Ge35-xSnx (x = 0.2, 0.4, 0.6) was synthesized in a high-frequency furnace. The samples were annealed, and subsequently ball milled and hot pressed. The hot pressed samples were characterized by X-ray powder diffraction, energy-dispersive X-ra

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Iskineyeva, A. S., A. K. Mustafayeva, R. E. Bakirova, S. D. Fazylov та O. A. Nurkenov. "COMBINED IN SILICO AND EXPERIMENTAL INVESTIGATIONS OF VITAMIN D3 ENCAPSULATION BY STARCH β-OLIGOSACCHARIDE". HERALD OF SCIENCE OF S SEIFULLIN KAZAKH AGRO TECHNICAL RESEARCH UNIVERSITY, № 1(116) (13 березня 2023): 317–26. http://dx.doi.org/10.51452/kazatu.2023.1(116).1327.

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The relevance of the research lies in the need to develop methods for encapsulating fat-soluble vitamins with natural oligosaccharides to increase their water solubility and use in the production of functional foods. The production ofnanostructured encapsulated vitamins is a new innovative direction in the food industry. This article presents the results of theoretical and experimental studies on the production of a clathrate complex of fat-soluble vitamin D3 (ViD3, cholecalciferol) with β-cyclodextrin (β-CD). The interaction of fat-soluble ViD3 with β-oligosaccharide was carried out by microw

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Zhu, Li, Gustav M. Borstad, Hanyu Liu, Piotr A. Guńka, Michael Guerette, Juli-Anna Dolyniuk, Yue Meng, et al. "Carbon-boron clathrates as a new class of sp3-bonded framework materials." Science Advances 6, no. 2 (January 2020): eaay8361. http://dx.doi.org/10.1126/sciadv.aay8361.

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Carbon-based frameworks composed of sp3 bonding represent a class of extremely lightweight strong materials, but only diamond and a handful of other compounds exist despite numerous predictions. Thus, there remains a large gap between the number of plausible structures predicted and those synthesized. We used a chemical design principle based on boron substitution to predict and synthesize a three-dimensional carbon-boron framework in a host/guest clathrate structure. The clathrate, with composition 2Sr@B6C6, exhibits the cubic bipartite sodalite structure (type VII clathrate) composed of sp3-

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Donnelly, Mary-Ellen, Craig Bull, Athina Frantzana, Stefan Klotz, and John Loveday. "Hydrogen-rich Inclusion Compounds at High-pressure." Acta Crystallographica Section A Foundations and Advances 70, a1 (August 5, 2014): C754. http://dx.doi.org/10.1107/s2053273314092456.

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Molecular hydrogen (H2) has been proposed as an alternative fuel source for vehicles. Though H2has many benefits, such as clean combustion and the highest known energy density by mass, there are issues in how to store it in a safe and cost effective way. One solution is to store hydrogen in a chemical compound, and gas clathrates (crystalline inclusion compounds) have shown promising results. Pressure provides a powerful means to tune the properties of such compounds and its effects on potential hydrogen storage materials are widely explored. We have recently developed a hydrogen-compatible ga

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Zhou, Yuanyuan, Qiang Xu, Chunye Zhu, Qian Li, Hanyu Liu, Hui Wang, and John S. Tse. "Predicted lithium–iron compounds under high pressure." RSC Advances 6, no. 71 (2016): 66721–28. http://dx.doi.org/10.1039/c6ra11064a.

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Maniwa, Yutaka, Hirokazu Sakamoto, Hideki Tou, Yuji Aoki, Hideyuki Sato, Fumihiko Shimizu, Hitoshi Kawaji, and Sroji Yamanaka. "NMR Studies of Silicon Clathrate Compounds." Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 341, no. 2 (April 1, 2000): 497–502. http://dx.doi.org/10.1080/10587250008026188.

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Mesbah, Mohammad, Sanaz Abouali Galledari, Ebrahim Soroush, and Masumeh Momeni. "Modeling Phase Behavior of Semi-Clathrate Hydrates of CO2, CH4, and N2 in Aqueous Solution of Tetra-n-butyl Ammonium Fluoride." Journal of Non-Equilibrium Thermodynamics 44, no. 2 (April 26, 2019): 155–67. http://dx.doi.org/10.1515/jnet-2018-0079.

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AbstractSemi-clathrate hydrates are members of the class of clathrate compounds. In comparison with clathrate hydrates, where the networks are formed only by H2O molecules, the networks of semi-clathrate hydrates are formed by mixtures of H2O and quaternary ammonium salts (QASs). The addition of QASs to the solution enables to improve the formation of semi-clathrate hydrates at much milder conditions comparing to clathrate hydrates. In this work, we study the phase equilibria of semi-clathrate hydrates of CH4, CO2, and N2gas in an aqueous solution of tetra-n-butyl ammonium fluoride (TBAF). An

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Manakov, A. Yu, and S. S. Skiba. "Application of clathrate compounds for hydrogen storage." Russian Journal of General Chemistry 77, no. 4 (April 2007): 740–51. http://dx.doi.org/10.1134/s1070363207040354.

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Takasu, Y., T. Hasegawa, N. Ogita, M. Udagawa, M. A. Avila, and T. Takabatake. "Raman scattering of type-I clathrate compounds." Physica B: Condensed Matter 383, no. 1 (August 2006): 134–36. http://dx.doi.org/10.1016/j.physb.2006.03.079.

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Yamanaka, S., H. Kawaji, and M. Ishikawa. "Preparation and Superconductivity of Silicon Clathrate Compounds." Materials Science Forum 232 (November 1996): 103–18. http://dx.doi.org/10.4028/www.scientific.net/msf.232.103.

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Nemoto, Yuichi, Tatsuya Yanagisawa, Yuri Yasumoto, Haruki Kobayashi, Akio Yamaguchi, Seiji Tsuduku, Terutaka Goto, et al. "Rattling in Clathrate Compounds of ROs4Sb12and R3Pd20Ge6." Journal of the Physical Society of Japan 77, Suppl.A (January 3, 2008): 153–58. http://dx.doi.org/10.1143/jpsjs.77sa.153.

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Takasu, Yuichi, Takumi Hasegawa, Norio Ogita, Masayuki Udagawa, Marcos A. Avila, Koichiro Suekuni, and Toshiro Takabatake. "Raman Scattering of Type-I Clathrate Compounds." Journal of the Physical Society of Japan 77, Suppl.A (January 3, 2008): 254–56. http://dx.doi.org/10.1143/jpsjs.77sa.254.

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Zhang, Xinyue, Yuhuan Li, Hongfu Wang, Miao Zhang, and Yonghui Du. "Superconductivity in (Sr, Ba)B3Si3 clathrate compounds." Computational Materials Science 233 (January 2024): 112755. http://dx.doi.org/10.1016/j.commatsci.2023.112755.

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Zhang, Wei, Qing Yun Chen, Bin Li, Zhao Yi Zeng, and Ling Cang Cai. "First-principles calculations for thermodynamic properties of type-I silicon clathrate intercalated by sodium atoms." Modern Physics Letters B 29, no. 27 (October 7, 2015): 1550166. http://dx.doi.org/10.1142/s0217984915501663.

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The ground state properties of the silicon clathrate [Formula: see text] intercalated by alkali metal sodium atoms [Formula: see text] are investigated by first-principle methods. Birch–Murnaghan equation of state is fitted to two sets of the [Formula: see text]–[Formula: see text] data calculated by density functional theory based on the plane-wave basis set within both the local density approximation (LDA) and the generalized gradient approximation (GGA). Through quasi-harmonic Debye model, some thermodynamic properties comprise the heat capacity, the thermal expansion coefficient, Debye tem

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Courville, Samuel W., Julie C. Castillo-Rogez, Mohit Melwani Daswani, Elodie Gloesener, Mathieu Choukroun, and Joseph G. O’Rourke. "Timing and Abundance of Clathrate Formation Control Ocean Evolution in Outer Solar System Bodies: Challenges of Maintaining a Thick Ocean within Pluto." Planetary Science Journal 4, no. 9 (September 1, 2023): 179. http://dx.doi.org/10.3847/psj/acf377.

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Abstract Clathrate hydrates may represent a sizable fraction of material within the icy shells of Kuiper Belt objects and icy moons. They influence the chemical and thermal evolution of subsurface oceans by locking volatiles into the ice shell and by providing more thermal insulation than pure water ice. We model the formation of these crystalline compounds in conditions relevant to outer solar system objects, using Pluto as an example. Although Pluto may have hosted a thick ocean in its early history, Pluto’s overall heat budget is probably insufficient to preserve liquid today if its outer s

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Kuznetsov, V. L., L. A. Kuznetsova, A. E. Kaliazin, and D. M. Rowe. "Preparation and thermoelectric properties of A8IIB16IIIB30IV clathrate compounds." Journal of Applied Physics 87, no. 11 (June 2000): 7871–75. http://dx.doi.org/10.1063/1.373469.

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Hashizume, D., H. Uekusa, Y. Ohashi, R. Matsukawa, K. Miyamoto та F. Toda. "Structures of isomorphous clathrate compounds of α-oxamide". Acta Crystallographica Section A Foundations of Crystallography 49, s1 (21 серпня 1993): c170. http://dx.doi.org/10.1107/s0108767378095136.

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Olejniczak, Anna, Anna Katrusiak, Marcin Podsiadło, and Andrzej Katrusiak. "Crystal design by CH...N and N...N interactions: high-pressure structures of high-nitrogen-content azido-triazolopyridazines compounds." Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials 76, no. 6 (November 20, 2020): 1136–42. http://dx.doi.org/10.1107/s2052520620014493.

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High-nitrogen-content compounds 6-azido-1,2,4-triazolo[4,3-b]pyridazine (C5H3N7) and its 3-methyl derivative (C6H5N7) have been in situ crystallized in a diamond-anvil cell and their structures determined by single-crystal X-ray diffraction. Under ambient and high-pressure conditions the crystallizations yield the same phases: the C5H3N7 anhydrate and C6H5N7 hydrated clathrate. In both the structures there are clearly distinguished regions of short CH...N and N...N intermolecular contacts, the latter involving exclusively the azide groups. High pressure initially increases the contents of wate

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Cao, Xiaoxiao, Yingying Huang, Wenbo Li, Zhaoyang Zheng, Xue Jiang, Yan Su, Jijun Zhao, and Changling Liu. "Phase diagrams for clathrate hydrates of methane, ethane, and propane from first-principles thermodynamics." Physical Chemistry Chemical Physics 18, no. 4 (2016): 3272–79. http://dx.doi.org/10.1039/c5cp06570d.

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Natural gas hydrates are inclusion compounds composed of major light hydrocarbon gaseous molecules (CH<sub>4</sub>, C<sub>2</sub>H<sub>6</sub>, and C<sub>3</sub>H<sub>8</sub>) and a water clathrate framework.

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Michalski, Darek, Mary Anne White, Pradip K. Bakshi, T. Stanley Cameron, and Ian Swainson. "Crystal structure and thermal expansion of hexakis(phenylthio)benzene and its CBr4 clathrate." Canadian Journal of Chemistry 73, no. 4 (April 1, 1995): 513–21. http://dx.doi.org/10.1139/v95-066.

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The crystal structures of hexakis(phenylthio)benzene (HPTB) and its CBr4 clathrate have been determined by single crystal X-ray diffraction data collected at T = 18 °C and refined to final Rw of 0.036 and 0.047, respectively. Pure HPTB is triclinic, space group [Formula: see text] (No. 2), with a = 9.589(2) Å, b = 10.256(1) Å, c = 10.645(2) Å, α = 68.42(1)°, β = 76.92(2)°, γ = 65.52(1)°, and Z = 1. The CBr4 clathrate of HPTB is rhombohedral, space group [Formula: see text] (No. 148), with a = 14.327(4) Å, b = 20.666(8) Å, and Z = 3. The host–guest mole ratio of HPTB–CBr4 is 1:2. Neutron powder

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Lucken, E. A. C., and D. Rupp. "Nuclear quadrupole resonance investigations of clathrate compounds: I. The35Cl resonance ofp-dichlorobenzene in various clathrate systems." Journal of Inclusion Phenomena 3, no. 2 (June 1985): 157–61. http://dx.doi.org/10.1007/bf00687989.

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Kim, Chang Oh, Jin Heung Kim, and Nak Kyu Chung. "A Study on Supercooling Characteristics of Clathrate Compounds with Concentration of TMA." Materials Science Forum 544-545 (May 2007): 645–48. http://dx.doi.org/10.4028/www.scientific.net/msf.544-545.645.

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Ice storage system that water is used as low temperature latent heat storage material, refrigerator capacity is increased and COP is decreased because refrigerator is operated at low temperature due to supercooling of water in the course of phase change from solid to liquid. This study is investigated the cooling characteristics of the TMA-water clathrate compound including TMA (Tri-methyl-amine, (CH3)3N) of 20~25 wt% as a low temperature latent heat storage material at -5°C, cooling source temperature. The results showed that the phase change temperature, the specific heat is increased and th

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Shimizu, F., Y. Maniwa, K. Kume, H. Kawaji, S. Yamanaka, and M. Ishikawa. "NMR in the silicon clathrate compounds NaxBaySi46 and NaxSi136." Synthetic Metals 86, no. 1-3 (February 1997): 2141–42. http://dx.doi.org/10.1016/s0379-6779(97)81066-1.

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Plumridge, T. H., G. Steele, and R. D. Waigh. "Predicting formation of hydrate inclusion compounds: Furan clathrate hydrate." Journal of Pharmacy and Pharmacology 50, S9 (September 1998): 239. http://dx.doi.org/10.1111/j.2042-7158.1998.tb02439.x.

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Nozue, Yasuo, Gentaro Hosaka, Eiji Enishi, and Shoji Yamanaka. "Optical Reflection Spectra of Silicon Clathrate Compounds Ba8AgxSi46−x." Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 341, no. 2 (April 1, 2000): 509–14. http://dx.doi.org/10.1080/10587250008026190.

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KUME, Tetsuji. "Raman Studies of Silicon Clathrate Compounds under High Pressure." Review of High Pressure Science and Technology 14, no. 2 (2004): 167–72. http://dx.doi.org/10.4131/jshpreview.14.167.

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Gryko, Jan, Paul F. McMillan, and Otto F. Sankey. "NMR studies of Na atoms in silicon clathrate compounds." Physical Review B 54, no. 5 (August 1, 1996): 3037–39. http://dx.doi.org/10.1103/physrevb.54.3037.

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Gavrilova, G. V., N. V. Kislykh, and V. A. Logvinenko. "Study of the thermal decomposition processes of clathrate compounds." Journal of Thermal Analysis 33, no. 1 (March 1988): 229–35. http://dx.doi.org/10.1007/bf01914605.

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Nohako, Kanyisa L., Priscilla GL Baker, and Emmanuel I. Iwuoha. "Organic Clathrate Compounds as Suitable Transducers in Electrochemical Sensing." International Journal of Electrochemical Science 10, no. 9 (September 2015): 6959–74. http://dx.doi.org/10.1016/s1452-3981(23)17322-6.

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Sidhu, Paul S., Jason Bell, Glenn H. Penner, and Kenneth R. Jeffrey. "A deuterium NMR study of guest molecular dynamics of acetone in two organic inclusion compounds." Canadian Journal of Chemistry 73, no. 12 (December 1, 1995): 2196–207. http://dx.doi.org/10.1139/v95-273.

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Deuterium nuclear magnetic resonance (NMR) spectra and spin-lattice relaxation times (T1) are used to investigate the dynamics of the guest molecule, acetone, in tris(5-acetyl-3-thienyl)methane (TATM) and cyclotriveratrylene (CTV) inclusion compounds. 13C CPMAS powder NMR spectra were obtained for each clathrate, to verify inclusion. In acetone: TATM, the guest molecule is undergoing twofold reorientation about the CO bond, exchanging the two methyl groups. An activation energy of 20 (± 1.4) kJ/mol, for the two-site jump motion, was found, independently, from deuterium NMR spectra an T1 measur

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Davies, J. Eric D., and Vivienne A. Tabner. "Clathrate and inclusion compounds. Part 11 [1]. A pre-resonance Raman study of the ?-quinol/SO2 clathrate." Journal of Inclusion Phenomena and Molecular Recognition in Chemistry 11, no. 4 (December 1991): 389–96. http://dx.doi.org/10.1007/bf01041416.

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Saito, Susumu. "Electronic Structure of Clathrate Compounds, Amorphous Silicon, and Si20 Cluster." Materia Japan 37, no. 7 (1998): 601–5. http://dx.doi.org/10.2320/materia.37.601.

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Uemura, Takashi, Koji Akai, Kenji Koga, Terumitsu Tanaka, Hiroki Kurisu, Setsuo Yamamoto, Kengo Kishimoto, Tsuyoshi Koyanagi, and Mitsuru Matsuura. "Electronic structure and thermoelectric properties of clathrate compounds Ba8AlxGe46−x." Journal of Applied Physics 104, no. 1 (July 2008): 013702. http://dx.doi.org/10.1063/1.2947593.

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Horie, Hiro-omi, Takashi Kikudome, Kyosuke Teramura, and Shoji Yamanaka. "Controlled thermal decomposition of NaSi to derive silicon clathrate compounds." Journal of Solid State Chemistry 182, no. 1 (January 2009): 129–35. http://dx.doi.org/10.1016/j.jssc.2008.10.007.

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Fukuoka, Hiroshi, Junichi Kiyoto, and Shoji Yamanaka. "Superconductivity of Metal Deficient Silicon Clathrate Compounds, Ba8-xSi46(0." Inorganic Chemistry 42, no. 9 (May 2003): 2933–37. http://dx.doi.org/10.1021/ic020676q.

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Takasu, Y., T. Hasegawa, N. Ogita, M. Udagawa, M. A. Avila, and T. Takabatake. "Raman scattering study of type-I clathrate compounds: (, Sr, Ba)." Journal of Magnetism and Magnetic Materials 310, no. 2 (March 2007): 954–56. http://dx.doi.org/10.1016/j.jmmm.2006.10.161.

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Lee, Jong-Won, Pratik Dotel, Jeasung Park, and Ji-Ho Yoon. "Separation of CO2 from flue gases using hydroquinone clathrate compounds." Korean Journal of Chemical Engineering 32, no. 12 (August 18, 2015): 2507–11. http://dx.doi.org/10.1007/s11814-015-0101-3.

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Bishop, Roger. "Design of Clathrate Compounds that Use Only Weak Intermolecular Attractions." Australian Journal of Chemistry 65, no. 10 (2012): 1361. http://dx.doi.org/10.1071/ch12038.

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Résumé :

Intermolecular attractive forces that are considerably weaker than hydrogen bonding and coordination complexation may be used in the design of new molecules that function as host molecules in the solid-state. Known literature examples of accidentally discovered hosts (clathrands), which do not involve strong interactions in their crystals, are identified and discussed. Their molecular symmetry and supramolecular interactions are analysed in order to identify structural features that facilitate and promote molecular inclusion. The solid-state properties of a family of designed compounds that em

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Koga, K., K. Suzuki, M. Fukamoto, H. Anno, T. Tanaka, and S. Yamamoto. "Electronic Structure and Thermoelectric Properties of Si-Based Clathrate Compounds." Journal of Electronic Materials 38, no. 7 (March 4, 2009): 1427–32. http://dx.doi.org/10.1007/s11664-009-0730-6.

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Liu, Yi, Li-Ming Wu, Long-Hua Li, Shao-Wu Du, John D Corbett, and Ling Chen. "The Antimony-Based Type I Clathrate Compounds Cs8Cd18Sb28 and Cs8Zn18Sb28." Angewandte Chemie International Edition 48, no. 29 (June 17, 2009): 5305–8. http://dx.doi.org/10.1002/anie.200806158.

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Liu, Yi, Li-Ming Wu, Long-Hua Li, Shao-Wu Du, John D Corbett, and Ling Chen. "The Antimony-Based Type I Clathrate Compounds Cs8Cd18Sb28 and Cs8Zn18Sb28." Angewandte Chemie 121, no. 29 (June 17, 2009): 5409–12. http://dx.doi.org/10.1002/ange.200806158.

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Davies, J. Eric D., and Vivienne A. Knott. "Clathrate and inclusion compounds. Part 10 [1]. Solid state 13C NMR studies of inclusion compounds." Journal of Molecular Structure 174 (May 1988): 229–34. http://dx.doi.org/10.1016/0022-2860(88)80162-5.

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