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Littérature scientifique sur le sujet « DIMETHYLSILOXANE »

Auteur : Grafiati

Publié le 26 octobre 2023

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Articles de revues sur le sujet "DIMETHYLSILOXANE"

1

Antic, Vesna, Marija Vuckovic et Milutin Govedarica. « Synthesis of ester-siloxane multiblock copolymers ». Chemical Industry 58, n^o 11 (2004) : 499–504. http://dx.doi.org/10.2298/hemind0411499a.

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It was shown that the two-stage transesterification/polycondensation reaction in the melt, can successfully be applied for the preparation of poly(butylene terephtalate-dimethylsiloxane) multiblock copolymers. Three series of co-polymers were synthesized, using poly(dimethylsiloxanes) bearing ester (two series) and hydroxy -end groups as reactants. The structure and composition of the obtained copolymers were determined by 1H NMR spectroscopy A mechanism, i.e. an order of reaction steps, involved in the preparation of the copolymers, was suggested.

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Wilczek, Lech, Munmaya K. Mishra et Joseph P. Kennedy. « The Synthesis of Poly(Dimethylsiloxane-b-Isobutylene-b-Dimethylsiloxane) and Poly-(Dimethylsiloxane-b-Isobutylene-b-Dimethylsiloxane) from Alcohol-Telechelic Polyisobutylenes ». Journal of Macromolecular Science : Part A - Chemistry 24, n^o 9 (septembre 1987) : 1033–49. http://dx.doi.org/10.1080/00222338708078141.

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Mukbaniani, O. V., M. G. Karchkhadze, L. M. Khananashvili et N. A. Koiava. « Arylenecyclosiloxane-dimethylsiloxane copolymers ». International Journal of Polymeric Materials and Polymeric Biomaterials 52, n^o 10 (janvier 2003) : 877–89. http://dx.doi.org/10.1080/713743639.

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Mukbaniani, O., N. Koiava, M. Karchkhadze, R. Tkeshelashvili, M. Shengelia et L. Khananashvili. « Arylenecyclosiloxane-dimethylsiloxane copolymers ». Journal of Applied Polymer Science 82, n^o 13 (2001) : 3142–48. http://dx.doi.org/10.1002/app.2171.

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Wang, Baoyu, et Sonja Krause. « Properties of dimethylsiloxane microphases in phase-separated dimethylsiloxane block copolymers ». Macromolecules 20, n^o 9 (septembre 1987) : 2201–8. http://dx.doi.org/10.1021/ma00175a026.

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Escutia-Guadarrama, Lidia, Genaro Vázquez-Victorio, David Martínez-Pastor, Brenda Nieto-Rivera, Marcela Sosa-Garrocho, Marina Macías-Silva et Mathieu Hautefeuille. « Fabrication of low-cost micropatterned polydimethyl-siloxane scaffolds to organise cells in a variety of two-dimensioanl biomimetic arrangements for lab-on-chip culture platforms ». Journal of Tissue Engineering 8 (1 janvier 2017) : 204173141774150. http://dx.doi.org/10.1177/2041731417741505.

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We present the rapid-prototyping of type I collagen micropatterns on poly-dimethylsiloxane substrates for the biomimetic confinement of cells using the combination of a surface oxidation treatment and 3-aminopropyl triethoxysilane silanisation followed by glutaraldehyde crosslinking. The aim of surface treatment is to stabilise microcontact printing transfer of this natural extracellular matrix protein that usually wears out easily from poly-dimethylsiloxane, which is not suitable for biomimetic cell culture platforms and lab-on-chip applications. A low-cost CD-DVD laser was used to etch biomimetic micropatterns into acrylic sheets that were in turn replicated to poly-dimethylsiloxane slabs with the desired features. These stamps were finally inked with type I collagen for microcontact printing transfer on the culture substrates in a simple manner. Human hepatoma cells (HepG2) and rat primary hepatocytes, which do not adhere to bare poly-dimethylsiloxane, were successfully seeded and showed optimal adhesion and survival on simple protein micropatterns with a hepatic cord geometry in order to validate our technique. HepG2 cells also proliferated on the stamps. Soft and stiff poly-dimethylsiloxane layers were also tested to demonstrate that our cost-effective process is compatible with biomimetic organ-on-chip technology integrating tunable stiffness with a potential application to drug testing probes development where such cells are commonly used.

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Kim, Bo-Yeol, Hwan-Moon Song, Young-A. Son et Chang-Soo Lee. « Rapid Topological Patterning of Poly(dimethylsiloxane) Microstructure ». Textile Coloration and Finishing 20, n^o 1 (27 février 2008) : 8–15. http://dx.doi.org/10.5764/tcf.2008.20.1.008.

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Grabowska, K., A. Wieczorek, D. Bednarska et M. Koniorczyk. « The effect of silanes as integral hydrophobic admixture on the physical properties of cement based materials ». Journal of Physics : Conference Series 2069, n^o 1 (1 novembre 2021) : 012045. http://dx.doi.org/10.1088/1742-6596/2069/1/012045.

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Abstract The paper explores the possibility of using organosilicon compounds (e.g., poly(dimethylsiloxane) and triethoxyoctylsilane) in commercial admixtures as internal hydrophobization agents for porous cement-based materials. The study involved the cement mortar with five different hydrophobic admixtures. Four of them is based on triethoxyoctylsilane, but with various concentration of the main ingredient, and one of them on poly(dimethylsiloxane). Mechanical properties, capillary water absorption, as well as microstructure were investigated. The organosilicon admixtures efficiently decrease the capillary water absorption even by 81% decreasing mechanical strength of cement mortar at the same time even by 55%. Only one admixture, based on poly(dimethylsiloxane) caused significant changes in microstructure of cement mortar.

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Lu, Zhou, Joji Ohshita, Daiki Tanaka, Tomonobu Mizumo, Yuki Fujita et Yoshihito Kunugi. « Synthesis of oligo(dimethylsiloxane)–oligothiophene alternate polymers from α,ω-dibromooligo(dimethylsiloxane) ». Journal of Organometallic Chemistry 731 (mai 2013) : 73–77. http://dx.doi.org/10.1016/j.jorganchem.2013.02.011.

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Urayama, Kenji, Keisuke Yokoyama et Shinzo Kohjiya. « Viscoelastic Relaxation of Guest Linear Poly(dimethylsiloxane) in End-Linked Poly(dimethylsiloxane) Networks ». Macromolecules 34, n^o 13 (juin 2001) : 4513–18. http://dx.doi.org/10.1021/ma010167s.

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Thèses sur le sujet "DIMETHYLSILOXANE"

1

Ê¿AziÌ„z, TÌ£aÌ„riq. « Development of a poly (dimethylsiloxane) maxillofacial prosthetic material ». Thesis, Cardiff University, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.490389.

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Lewicki, James P. « The ageing behaviour of novel poly (dimethylsiloxane) nanocomposites ». Thesis, University of Strathclyde, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.487855.

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This thesis reports the formulation, characterisation and investigation of the ageing behaviour using a combination of dielectric spectroscopy and thermal analysis techniques of a series of novel polysiloxane nanocomposite elastomers which incorporate the organically modified Montmorillonite nano-clay Cloisite 6A and polyhedral oligomeric silsequioxane (POSS) as nano-scale fillers.

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Brown, David Alexander. « Ultrasonically assisted synthesis and degradation of poly(dimethylsiloxane) ». Thesis, University of Bath, 1999. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.635432.

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Singh, Shanti. « Studies of the crystallization and morphology of poly(dimethylsiloxane) ». Thesis, McGill University, 2001. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=38284.

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A detailed analysis of the crystallization behaviour of poly(dimethylsiloxane) (PDMS) was undertaken. Determination of the equilibrium melting temperature showed a six degree difference between the equilibrium melting of a hydroxy terminated polymer (PDMS-OH, Tmo = 266 K, M w = 92.9 kg mol-1) over that of a trimethylsilyl terminated polymer (PDMS-CH3, Tmo = 260 K, Mw = 100 kg mol-1). The inherent flexibility of the Si-O linkage of these polymers caused crystallization to be first detected at Tmo - 35 K, and was recorded down to 177 K, i.e., Tg + 30 K. Both systems followed well behaved regime III surface nucleation kinetics. The average fold interfacial surface free energy, sigmae, was calculated to be 17.6 erg cm -2 and resulted in a very low value for the work of chain folding, q, calculated to be 14.6 kJ mol-1. This is in accord with the small rotational barrier of the siloxane backbone. In addition, PDMS-OH crystallized with slower kinetics than PDMS-CH3, verified by chemical conversion from the hydroxy to trimethylsilyl end group.
The first reported detection of two different PDMS solid state morphologies is presented. A small population of very low birefringent (Deltan ) spherulites was observed to nucleate simultaneously with a majority of bright positive Deltan spherulites throughout the accessible crystallization temperature range. The sign of Deltan of these darker spherulites varied with growth, and this growth rate was depressed from that of the bright spherulites. Calorimetric annealing experiments indicate that the PDMS system attains very high percent crystallinities very early after nucleation. Coupled with the results of small angle laser light scattering (SALLS) during slow (1 deg/min) melting, secondary crystallization processes were observed to be non-negligible very soon after primary crystallization.
SALLS of the crystallizing PDMS system was sensitive to the concurrent effects of (i) the presence of dark spherulites, (ii) secondary crystallization, and (iii) the distribution of spherulite sizes. These combined effects generated significant non-ideality within V v and Hv scattering envelopes. The effects of (i) and (ii) caused both the Vv pattern to remain circularly symmetric throughout the entire crystallization timeframe, and the 4-leaf clover pattern of the Hv mode scattering to contain multiple intensity maxima not restricted to an azimuthal angle of 45°. The effect of (iii) was to lower the calculated SALLS average radial growth rate relative to that observed optically.

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Waugaman, Marlene. « Synthesis and characterization of 3-[Oligo(dimethylsiloxane] thiophene macromonomers ». DigitalCommons@Robert W. Woodruff Library, Atlanta University Center, 1998. http://digitalcommons.auctr.edu/dissertations/1293.

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Electronic conductive polymers such as polyacetylenes, polyanilines and polythiophenes, are not easy to process due to lack of tractability and solubility. Chemical modifications of the polythiophenes backbone have been utilized to improve the processibility. Our goal is to synthesize and characterize 3-[oligo(dimethylsiloxane)]- thiophene macromonomers as precursors for potentially processible, conductive derivatives of polythiophene. The precursor will be used in the preparation of various poly {[3- oligo(dimethylsiloxane)]thiophene-co-3-methylthiophene} random copolymers. By increasing the chain length of the low glass transition (Tg) side chain, we hope to produce processible elastomeric material. w-(Si-H)-DMS, 3-propenylthiophene (i.e. precursors for the macromonomers), and the macromonomer were characterized (as appropriate) by 'HNMR, SiNMR, C NMR, DSC, IR, UV-VIS, GPC, and GC-MS.

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Alonso, Bruno. « Materiaux hybrides poly-dimethylsiloxane-vanadate synthese, caracterisation et proprietes ». Paris 6, 1998. http://www.theses.fr/1998PA066383.

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Cette these a eu pour objet principal la synthese, la caracterisation et l'etude de proprietes mecaniques et optiques de materiaux poly-dimethylsiloxane-vanadate, gels ou reseaux polymeres resultant de l'hydrolyse d'alcoxydes de silicium et de vanadium (v). Les principaux resultats concernent l'etude des interactions entre unites dimethylsiloxane et unites vanadate tout au long des processus de formation et de degradation des gels, la description de la structure du gel et l'identication de correlations entre cette structure et les proprietes. Nous avons pu montre que la co-hydrolyse des precurseurs conduit a des materiaux plus stables que ceux obtenus par pre-hydrolyse du precurseur silice pour des rapports molaires v/si proches de 0,1. Cette particularite est liee aux roles oxophile et catalytique du vanadium (v) mais aussi a des affinites chimiques importantes avec les unites dimethylsiloxane qui permettent de contrecarrer dans un premier temps les processus de separation de phases. Les gels obtenus sont constituees de segments dimethylsiloxane courts (5 a 6 unites en moyenne) lies des unites vanadate tri-fonctionnelles isolees. Malgre cette homogeneite chimique, nous avons pu a maintes reprises distinguer deux types de sites. Ils ont ete associes aux effets disjoints de la reticulation et de la terminaison des chaines.

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Preston, Christopher M. L. « Poly(dimethylsiloxane) : blends with poly(urethane) & ; radiation chemistry / ». [St. Lucia, Qld.], 2000. http://www.library.uq.edu.au/pdfserve.php?image=thesisabs/absthe16169.pdf.

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Wang, Dan. « Surface modification of poly(dimethylsiloxane) with a perfluorinated alkoxysilane for selectivity toward fluorous tagged peptides ». Kingston, Ont. : [s.n.], 2008. http://hdl.handle.net/1974/1205.

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Taori, Vijay Purushottam. « Synthesis and properties of bioinspired silica filled poly(dimethylsiloxane) networks ». Cincinnati, Ohio : University of Cincinnati, 2005. http://www.ohiolink.edu/etd/view.cgi?acc%5Fnum=ucin1116248554.

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Choi, Jae Won. « The plasma treatment of poly(dimethylsiloxane) for enhanced surface properties ». Thesis, University of Surrey, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.402622.

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Livres sur le sujet "DIMETHYLSILOXANE"

1

Watson, J. M. The pervaporation process through poly(dimethylsiloxane). Manchester : UMIST, 1993.

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2

Chaudhry, Amiya Nur. Characterisation and degradation of a typical RTV silica filled poly(dimethylsiloxane) (PDMS) foam. 2004.

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Chapitres de livres sur le sujet "DIMETHYLSILOXANE"

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Stepto, R. F. T., D. J. R. Taylor, T. Partchuk et M. Gottlieb. « Poly(dimethylsiloxane) Gelation Studies ». Dans ACS Symposium Series, 194–203. Washington, DC : American Chemical Society, 2000. http://dx.doi.org/10.1021/bk-2000-0729.ch012.

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Wohlfarth, Ch. « Solubility parameter of poly(dimethylsiloxane) ». Dans Polymer Solutions, 1556. Berlin, Heidelberg : Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-02890-8_907.

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Garrido, Leoneio, Jerome L. Ackerman et James E. Mark. « Self-Diffusion of Poly(Dimethylsiloxane) Chains ». Dans New Trends in Physics and Physucal Chemistry of Polymers, 355–65. Boston, MA : Springer US, 1989. http://dx.doi.org/10.1007/978-1-4613-0543-9_28.

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Wohlfarth, Ch. « Partial specific volume of poly(dimethylsiloxane) ». Dans Polymer Solutions, 452. Berlin, Heidelberg : Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-02890-8_230.

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Wohlfarth, Ch. « Second virial coefficient of poly(dimethylsiloxane) ». Dans Polymer Solutions, 804. Berlin, Heidelberg : Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-02890-8_488.

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Gädda, Thomas M., et William P. Weber. « Copolymers Based on Dimethylsiloxane and Diphenylsiloxane Units ». Dans ACS Symposium Series, 82–99. Washington, DC : American Chemical Society, 2007. http://dx.doi.org/10.1021/bk-2007-0964.ch007.

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She, H., M. K. Chaudhury et Michael J. Owen. « Surface Properties of Thin Film Poly(dimethylsiloxane) ». Dans ACS Symposium Series, 322–31. Washington, DC : American Chemical Society, 2000. http://dx.doi.org/10.1021/bk-2000-0729.ch021.

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Wohlfarth, Ch. « pVT data of poly(dimethylsiloxane) in benzene ». Dans Polymer Solutions, 33. Berlin, Heidelberg : Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-02890-8_32.

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Wohlfarth, Ch. « pVT data of poly(dimethylsiloxane) in chlorobenzene ». Dans Polymer Solutions, 35. Berlin, Heidelberg : Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-02890-8_34.

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Wohlfarth, Ch. « pVT data of poly(dimethylsiloxane) in cyclohexane ». Dans Polymer Solutions, 36. Berlin, Heidelberg : Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-02890-8_35.

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Actes de conférences sur le sujet "DIMETHYLSILOXANE"

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Cadarso, Victor Javier, Jose Antonio Plaza, Kirill Zinoviev, Carlos Dominguez, Sandra de Pedro, Stephanus Buttgenbach et Andreu Llobera. « Cantilever-based poly(dimethylsiloxane) Microoptoelectromechanical Systems ». Dans 2009 IEEE Sensors. IEEE, 2009. http://dx.doi.org/10.1109/icsens.2009.5398254.

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Yoshino, Katsumi, et Werner F. Schmidt. « Ion Mobilities in poly-dimethylsiloxane silicone oils ». Dans 2014 IEEE 18th International Conference on Dielectric Liquids (ICDL). IEEE, 2014. http://dx.doi.org/10.1109/icdl.2014.6893099.

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Nickmans, K., et A. P. H. J. Schenning. « Smectic hybrid oligo(dimethylsiloxane) liquid crystal for nanopatterning ». Dans SPIE OPTO, sous la direction de Liang-Chy Chien. SPIE, 2017. http://dx.doi.org/10.1117/12.2266586.

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Hartney, M. A., et A. E. Novembre. « Poly (Methylstyrene - Dimethylsiloxane) Block Copolymers As Bilevel Resists ». Dans 1985 Microlithography Conferences, sous la direction de Larry F. Thompson. SPIE, 1985. http://dx.doi.org/10.1117/12.947820.

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Kee, J. S., D. P. Poenar, P. Neuzil et L. Yobas. « Poly(dimethylsiloxane) Waveguides Integrated with Microfluidics for Absorbance Measurement ». Dans 2008 IEEE PhotonicsGlobal@Singapore (IPGC). IEEE, 2008. http://dx.doi.org/10.1109/ipgc.2008.4781396.

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Zhou, Jinwen, Steven J. P. McInnes, Abdul Mutalib Md Jani, Amanda V. Ellis et Nicolas H. Voelcker. « One-step surface modification of poly(dimethylsiloxane) by undecylenic acid ». Dans Smart Materials, Nano-and Micro-Smart Systems, sous la direction de Nicolas H. Voelcker et Helmut W. Thissen. SPIE, 2008. http://dx.doi.org/10.1117/12.810101.

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Gao, Shaorui, Wing-Tai Tung, Dexter S. Wong, Liming Bian et A. Ping Zhang. « Direct optical patterning of poly(dimethylsiloxane) microstructures for microfluidic chips ». Dans Eighth International Symposium on Advanced Optical Manufacturing and Testing Technology (AOMATT2016), sous la direction de Xiangang Luo, Tianchun Ye, Tingwen Xin, Song Hu, Minghui Hong et Min Gu. SPIE, 2016. http://dx.doi.org/10.1117/12.2243464.

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Bhagat, Ali Asgar S., Preetha Jothimuthu et Ian Papautsky. « Photosensitive Poly(Dimethylsiloxane) (Photopdms) for Rapid and Simple Polymer Fabrication ». Dans TRANSDUCERS 2007 - 2007 International Solid-State Sensors, Actuators and Microsystems Conference. IEEE, 2007. http://dx.doi.org/10.1109/sensor.2007.4300186.

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Stone, Sawyer D., et Bryant C. Hollins. « Doping Poly (dimethylsiloxane) for Intentional Leaching of Small Molecules into Microdevices ». Dans 2016 32nd Southern Biomedical Engineering Conference (SBEC). IEEE, 2016. http://dx.doi.org/10.1109/sbec.2016.59.

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Kato, Fumihito, Hiroyuki Noguchi, Yukinari Kodaka, Naoki Chiku, Hiroto Shibata, Fuyuki Abe et Hirotsugu Ogi. « Multi-channel wireless quartz crystal microbalance biosensor fabricated with poly(dimethylsiloxane) ». Dans 2017 19th International Conference on Solid-State Sensors, Actuators and Microsystems (TRANSDUCERS). IEEE, 2017. http://dx.doi.org/10.1109/transducers.2017.7994384.

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Rapports d'organisations sur le sujet "DIMETHYLSILOXANE"

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Mabry, Joseph M., et William P. Weber. Preparation of Benzophenone Modified Poly(dimethylsiloxane) Thermosets. Fort Belvoir, VA : Defense Technical Information Center, mars 2004. http://dx.doi.org/10.21236/ada422515.

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Veith, C. A., et R. E. Cohen. Synthesis of Poly(dimethylsiloxane) - Nylon 6 Diblock Copolymers. Fort Belvoir, VA : Defense Technical Information Center, décembre 1989. http://dx.doi.org/10.21236/ada216850.

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Samara, M., et D. A. Loy. Shrinkage and recyclability of poly(1,2-ethylene-bis(dimethylsiloxane)). Office of Scientific and Technical Information (OSTI), août 1998. http://dx.doi.org/10.2172/661467.

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Low cost hydrogen/novel membranes technology for hydrogen separation from synthesis gas, Phase 1. [Palladium-silver/poly(etherimide), polysulfone/poly(dimethylsiloxane)/poly(ether-esteramide)composite membranes]. Office of Scientific and Technical Information (OSTI), janvier 1987. http://dx.doi.org/10.2172/5045913.

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