Thèses sur le sujet « Fluxus – Histoire »
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Clavez, Bertrand. « Fluxus, l'histoire, la théorie, pour une histoire des évènements quelconques ». Paris 10, 2003. http://www.theses.fr/2003PA100089.
Texte intégralOur dissertation examines the relationships between Fluxus artists and their history though their texts relating their history and the conservatory strategies they used. Through the study of the historical literature dedicated to Fluxus, we analyse the our discipline's relations to this object : confronted to the difficulty expressed in these texts, we explain why history is defeated when trying to work on Fluxus through the temporality and event notions that are structural elements in Fluxus. They reveal its fundamentally rhizomatic basis, and allow us to understand the appropriation of their history by the artists through their editorial activities. If auto-history is often selflegitimisation, Fluxus shows an attraction to it that overpasses this frame to reach an autonomy vis-à-vis the art world and an absolute control on the sources of the history-making. We propose some cues for a methodological approach which try to avoid the linearity of the historical narration to reach a form more alike to reflect Fluxus' complexity
Schnakenbourg, Christian. « L'immigration indienne en Guadeloupe (1848-1923) : histoire d'un flux migratoire ». Aix-Marseille 1, 2005. http://www.theses.fr/2005AIX10012.
Texte intégralValerio, Pedro Henrique Martins. « Capoeira : fluxos originários em rotas marginais ». Universidade de São Paulo, 2014. http://www.teses.usp.br/teses/disponiveis/39/39134/tde-29072014-193947/.
Texte intégralBy using the classical Phenomenological approach to cultural events, this study aims to comprehend the genesis of \"capoeira lived experiences\". Aiming to deepen the theory on our subject, this work also intends to organize methodological substracts as a solid basis for developing a Phenomenological method of describing a \"capoeira way of living\" that can be less abstract, closer to the way that capoeira is experienced by those in whom capoeira manifests itself, as well as closer to the capoeira experiences of the researcher himself (some of which are constitutive parts of the results). 15 capoeira masters, from different lineages, were interviewed. After transcription, these testimonials underwent the methodological procedures from the Phenomenological Archaeology of the Culture and also Edmund Husserl\'s (1859-1938) Genetic Phenomenology. Intentional sucessive data crossings, pervaded by the sensibility of the bodies situated on the very basis of the experiences, revealed different and strong purport of bonding (union) between the capoeiristas, considered the peak of an ultimate realization, of a creative and free action, conducted by a whole new dimension that was unknown before. Making an incursion on the search of possible connections between historical, social and cultural events on one side and a matrix of meanings (structured on the lived-experiences shown on the first part of the results) on the other, this study elaborates a possible historical genesis for capoeira that can be revealed on this crossroad of meanings
Rodrigues, Ester Fatima Vargem. « Imigrantes africanos no Brasil contemporâneo : fluxos e refluxos da diáspora ». Pontifícia Universidade Católica de São Paulo, 2014. https://tede2.pucsp.br/handle/handle/12848.
Texte intégralThe present work on African immigration to Brazil in contemporary presents some aspects of my involvement with insertion in this subject, and brings up the question of the various forms and strategies that some African populations are able to cross the Atlantic, reviving diasporas. Was based on analysis of information from newspaper that made references to African immigrants , found in various forms to enter the ships anchored on the African coast, and thus achieve maximize their life chances . It also establishes dialogues with African immigrants who arrived here, in many different ways and times, with varying personal characteristics about their impressions about meanings that traverse the twenty-first century. Concludes with an overview of the political situation in Africa as well as the relationships that Brazil has established with African countries
O presente trabalho sobre a imigração africana no Brasil na contemporaneidade apresenta alguns aspectos da minha inserção no envolvimento com esta temática, e traz à tona a questão das diversas formas e estratégias que algumas populações africanas encontram para conseguir atravessar o Atlântico, revivendo diásporas. Baseou-se em análise de informações de notícias de jornais que fizessem referencias a imigrantes africanos, nas diversas formas encontradas para adentrar os navios ancorados no litoral africano, e desta forma conseguir potencializar suas possibilidades de vida. Também estabelece diálogos com imigrantes africanos que aqui chegaram, das mais diversas formas e épocas, com características pessoais variadas sobre suas impressões a respeito de significações dessa travessia no século XXI. Finaliza com um apanhado da situação política na África, bem como das relações que o Brasil vem estabelecendo com os países africanos
Rogiers, Nele. « Impact of site history and land-management on CO₂ fluxes at a grassland in the Swiss Pre-Alps / ». Bern : [s.n.], 2005. http://www.zb.unibe.ch/download/eldiss/05rogiers_n.pdf.
Texte intégralAsgarov, Vazeh. « L'immigration des Azerbaïdjanais en France : histoire et perspectives ». Phd thesis, Université de Strasbourg, 2012. http://tel.archives-ouvertes.fr/tel-00834990.
Texte intégralReeves, Chris M. « United Front and Action vs. Beautiful Coffee Cups : Fluxus Through the Publications of George Maciunas and Dick Higgins ». University of Cincinnati / OhioLINK, 2012. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1337715265.
Texte intégralKhimoun, Aurélie. « Histoire évolutive, contexte spatial et écologique de la divergence de deux sous-espèces d'Antirrhinum majus ». Toulouse 3, 2012. http://thesesups.ups-tlse.fr/2280/.
Texte intégralThis thesis sought at understanding how evolutionary and ecological processes lead to population divergence and ultimately speciation. To this aim, i integrated the different components of speciation - ecological, spatial and matting isolation - ina temporal framework to gain a better understanding of their dynamicinteraction through time. I studied the ongoing divergence of two snapdragon subspecies of Antirrhiunum majus pseudomajus and A. M striatum. I tested the relative role of historical processes of colonasation (post-glacial colonisation scenario), contemporary barriers to gene flow and local adaptation to explain the current patterns of subspecies distribution and the distribution of their genetic diversity. I also investigated the extent of gene flaw between the two subspecies in the contact zones and the role of environmental factors on the direction of gene flow and the maintenance of disjunct distributions despite gene flow. Finally, i studied the relative roles of neutral processesof dispersal and selective processes in the maintenance of a stable hybrid zone between the two subspecies
Farmer, Mindy J. « Politics in Flux : The Georgians Behind the Republicanization of the South ». The Ohio State University, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=osu1322075208.
Texte intégralMassingill, Robert Derryl Jr. « Mixing energy analysis of Bingham plastic fluids for severe lost circulation prevention using similitude ». Texas A&M University, 2005. http://hdl.handle.net/1969.1/3339.
Texte intégralViller-Hamon, Isabelle. « Flux financiers, flux d'informations et reseaux internationaux : l'agence havas et le jeu des echanges, 1850-1914 ». Paris 3, 2000. http://www.theses.fr/2000PA030175.
Texte intégralBezuidenhout, Johannes Jurie. « Convective heat flux determination using surface temperature history measurements and an inverse calculation method ». Thesis, Virginia Tech, 2000. http://hdl.handle.net/10919/35706.
Texte intégralThe objective of this study is therefore to develop a cost-effective single gage that can be used to measure both skin friction and heat flux. The method proposed in this study is to install a coaxial thermocouple into an existing skin friction gage to measure the unsteady temperature on the surface of the gage. By using the temperature history and a computer program the heat flux through the surface can be obtained through an iterative guessing method. To ensure that the heat flux through the gage is similar to the heat flux through the rest of the surface, the gage is manufactured of a material very similar to the rest of the surface.
Walker developed a computer program capable of predicting the heat flux through a surface from the measured surface temperature history. The program is based on an inverse approach to calculate the heat flux through the surface. The biggest advantages of this method are its stability and the small amount of noise induced into the system. The drawback of the method is that it is limited to semi-infinite objects. For surfaces with a finite thickness, a second thermocouple was installed into the system some distance below the first thermocouple. By modifying the computer program these two unsteady temperatures can be used to predict the heat flux through a surface of finite thickness.
As part of this study, the effect of noise induced by the Cook-Felderman technique, found in the literature were investigated in detail and it was concluded that the method proposed in this study is superior to this Cook-Felderman method. Heat flux measurements compared well with measurements recorded with heat flux gages. In all cases evaluated the difference was less than 20%. It can therefore be concluded that heat flux gages on their own can measure surface heat flux very accurately. These gages are however too large to install in a skin-friction gage. The method introduced in this study is noisier than the heat flux gages on their own, but the size which is very important, is magnitudes smaller when using a coaxial thermocouple, to measure the surface temperature history.
Master of Science
Mills, Keely. « Ugandan crater lakes : limnology, palaeolimnology and palaeoenvironmental history ». Thesis, Loughborough University, 2009. https://dspace.lboro.ac.uk/2134/13219.
Texte intégralHadden, Nancy. « From Swiss flutes to consorts : history, music and playing techniques of the transverse flute in Switzerland, Germany and France ca. 1470-1640 ». Thesis, University of Leeds, 2010. http://etheses.whiterose.ac.uk/2581/.
Texte intégralRougemont, Quentin. « Évolution de la divergence entre la lamproie fluviatile (Lampetra fluviatilis) et la lamproie deplaner (Lampetra planeri) inférée par approches expérimentales et de génomique des populations ». Thesis, Rennes 1, 2015. http://www.theses.fr/2015REN1S141/document.
Texte intégralThis thesis investigates the process of speciation between the European lampreys Lampetra fluviatilis and L. planeri. The two species have drastically different life history strategies: L. fluviatilis is parasitic and anadromous while L. planeri is non-parasitic and strictly freshwater resident. Yet their level of reproductive isolation and history of divergence remain poorly understood. A multidisciplinary approach including experiments, population genomics analyses and historical reconstruction was undertaken to address these issues. Experimental crosses revealed a very low level of reproductive isolation, partially mirrored by variable levels of gene flow in wild populations. Genetic analyses revealed that the two taxa were best described as partially reproductively isolated ecotypes suggesting that endogenous genetic barriers partially reduced effective migration between ecotypes. Genome wide analyses showed the importance of the current and ancient geographical context of speciation. In particular, parapatric L. planeri populations diverged mostly through drift and displayed a reduced genetic diversity . Demographic inferences suggested that divergence have likely emerged in allopatry and then secondary contacts resulted in partial parallelism between replicate population pairs. A strong heterogeneity of divergence across the genome was revealed by sympatric populations suggesting that genomic islands of differentiation were not linked to ongoing ecological divergence. Further investigations showed that the genetic diversity of L. planeri populations was weakly affected by human-induced river fragmentation. Resident populations displayed a higher diversity when gene flow was possible with L. fluviatilis populations in downstream sections of rivers. Overall this thesis showed that parasitic and non-parasitic lamprey ecotypes represent a promising model for studying speciation and notably the genomic architecture of divergence
Fisher, Andrew Bryan. « Worlds in flux, identities in motion : a history of the Tierra Caliente of Guerrero, Mexico, 1521-1821 / ». Diss., Connect to a 24 p. preview or request complete full text in PDF format. Access restricted to UC campuses, 2002. http://wwwlib.umi.com/cr/ucsd/fullcit?p3057349.
Texte intégralFaucher, Leslie. « Histoire évolutive de deux espèces d’amphibiens pionnières, le Pélodyte ponctué et le Crapaud calamite, en milieu fortement anthropisé ». Thesis, Lille 1, 2017. http://www.theses.fr/2017LIL10159/document.
Texte intégralHuman activities induce habitat loss and fragmentation that have an erosive effect on the level of intraspecific genetic diversity, decreasing the individual fitness and jeopardizing populations’ adaptive capability. Conversely, new human-made areas, such as spoil heaps of northern France, can provide suitable habitats for pioneering species. Spoil heaps being part of a highly human-fragmented landscape, the likelihood of population persistence is questioned given the scarcity of suitable habitats and the occurrence of potential barriers to dispersal. We studied the intraspecific genetic diversity of two anurans, Pelodytes punctatus and Bufo calamita, located in coalfield areas and semi-natural coastal habitats. We focused on the effects of micro-evolutionary processes of genetic drift and gene flow in shaping genetic structure. We studied (i) the biogeographical history of colonization of coalfield areas in B. calamita, (ii) the landscape connectivity using a multispecies approach, and (iii) the evolutionary determinants of variance in breeding success in B. calamita. In coalfield areas, B. calamita populations showed high levels of genetic diversity suggesting several independent colonization events. Nonetheless, marked local genetic discontinuities were observed within coalfield areas for both species, suggesting occurrence of environmental barriers impeding gene flow that may compromise population viability. Within a B. calamita population, we observed a polygynous mating system involving a possible decrease in genetic diversity. Our results suggested that variance in male mating success was linked to male-male competition and may imply distinct mating strategies
Grabska, Katarzyna. « In-flux:(re)negotiations of gender, identity and ‘home’ in post-war Southern Sudan ». Thesis, University of Sussex, 2010. http://sro.sussex.ac.uk/id/eprint/2525/.
Texte intégralMelo, Luciene dos Santos. « Da retorica a pratica : estudo da proposta de historia em classes do projeto ensinar e aprender (Correção de fluxo - da SEE/SP (1999-2001) ». [s.n.], 2003. http://repositorio.unicamp.br/jspui/handle/REPOSIP/253352.
Texte intégralDissertação (mestrado) - Universidade Estadual de Campinas, Faculdade de Educação
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Mestrado
Ward, Jessica D. « Conjugal Rights in Flux in Medieval Poetry ». Thesis, University of North Texas, 2014. https://digital.library.unt.edu/ark:/67531/metadc500176/.
Texte intégralFerguson, Sophia Margaretha. « Voortrekker Road palimpsest : A study in social, spatial and temporal flux in the city ». University of the Western Cape, 2020. http://hdl.handle.net/11394/7237.
Texte intégralWith its Afrikaner Nationalist past and its current status as an Afropolitan hub, Voortrekker Road simultaneously constitutes a place of separation and transgression, resulting in a quotidian tableau of urban life that could in some ways be read as a microcosm of social dynamics in contemporary South Africa. This thesis is a study on the intersecting microhistories at play in Voortrekker Road as a site of fractured negotiation within South Africa as a transitional society, and a place where multiple historical narratives intersect and become rewritten. In interpreting and portraying the layered, entangled histories, attention will be paid to microhistories and the fragment in order to steer away from totalising perspectives. Furthermore, the study draws heavily on the theories of Walter Benjamin in order to position a montage approach to history at the center of interpreting the historical layers enveloped along the road. A montage approach to historical thinking aims to deviate from the deterministic method of Hegelianism. Gyanendra Pandey emphasises how ‘part of the importance of the “fragmentary” point of view lies in that it resists the drive for a shallow homogenization and for other, potentially richer definitions of the “nation” and the future political community.’ Particular attention is paid to the microhistories and intimate business praxis amongst migrant entrepreneurs and informal businesses in order to consider the explosive creative refunctioning of Voortrekker Road in relation to its socially engineered segregationist history. In consideration of Voortrekker Road as a startling respite from xenophobic violence, the study considers the infusions of affect into the cityscape. As AbdouMaliq Simone aptly prompts ‘What are some of the ways in which urban residents are building a particular emotional field in the city, trying to restore a very physical sense of connection to one another?’
Buffington, Adam. « In Relation to the Immense : Experimentalism and Transnationalism in 20th-Century Reykjavik ». The Ohio State University, 2020. http://rave.ohiolink.edu/etdc/view?acc_num=osu1587637102245713.
Texte intégralPaixão, Milena. « Entre la medusa y el unicornio. Manifestaciones de écriture féminine en Tu não te moves de ti y Fluxo-Floema de Hilda Hilst ». Tesis, Universidad de Chile, 2014. http://repositorio.uchile.cl/handle/2250/131584.
Texte intégralAutor no autoriza el acceso a texto completo de su documento.
El presente trabajo tiene como objetivo analizar dos novelas de la escritora brasileña Hilda Hilst, específicamente indagar en ellas cómo se constituyen los sujetos -desplegados en personajes y narradores- y la arquitectura textual. Desde mi punto de vista, estamos en presencia de una escritura con rasgos singulares y que a mi parecer se inscriben en lo que Hélène Cixous en un momento denominó escritura femenina. El corpus seleccionado corresponde a dos obras claves, de la tardía trayectoria de Hilst, en el territorio de la prosa: Flujo-Floema y Tu não te moves de ti. En la primera me concentraré en la complejidad de la experimentación que la autora despliega en su narrativa: la multiplicidad de los narradores y la arquitectura textual per se; mientras que en el segundo me enfocaré en el contenido simbólico y la oposición propuesta entre Razón y Fantasía, y como la autora parece asociar estas dos dimensiones a una binaridad sui generis masculino/femenino. Asimismo, también trabajaré cómo se constituye la diferencia en la representación de lo corpóreo en ambas novelas
The present work aims at analyzing two novels by the Brazilian author Hilda Hilst, especifically at venturing into the process of construction of the subjects -split into characters and narrators- and the textual architecture. From my point of view, her writing is one of very particular characteristics that may correspond to what Hélène Cixous has once called feminine writing. The corpus selected is composed of two key works of her late experiences with prose writing: Fluxo-Floema and Tú não te moves de ti. In the former I will concentrate in the complexity of the structural games the writer inscribes in her narrative: the multiplicity of narrators and the textual architecture per se; while in the latter I will focus on the symbolic contents and the opposition between Reason and Fantasy, and how the author seems to associate these two dimensions with a sui generis duplicity male/female. Besides, I will also work on how the difference is constituted in the representation of the body in both novels.
Tsang, Shui-lung 1960. « War and peace in northern Sung China : Violence and strategy in flux, 960-1104 A.D ». Diss., The University of Arizona, 1997. http://hdl.handle.net/10150/282422.
Texte intégralGalloro, Piero-Dominique. « La main-d'oeuvre des usines sidérurgiques de Lorraine : 1880-1939 : étude des flux : l'exemple des Forges de Joeuf ». Metz, 1996. http://docnum.univ-lorraine.fr/public/UPV-M/Theses/1996/Galloro.Piero_Dominique.LMZ9603_1.pdf.
Texte intégralWith the help of documents from public archives (archives of the departements of Moselle and Meurthe-et-Moselle) and from the private collections of the companies wich have been studied (de Wendel's forges in Joeuf, metallurgic societies of Knutange, forges of the navy and of Homecourt, Chatillon-Commentry at Neuves-Maisons and the rolling mills of Thionville), the study was further supported by convincing elements thanks to both qualitative and quantitative research. Therefore, the use of such scientific tools as statistics, as well as the use of a powerful computer medium, contributed to the rigour and accuracy of the research. Rather than developping an argumentation with samples taken at random, the dissertation includes the entire population of workers from several factories during the closen period. No doubt can be cast on the representativeness of the sources used and knowledge about workers in the iron and steel industries grew richer as new elements were discovered. The demonstration aims at better understanding of the movements of the labour force wich passed in transit through the industrial factories of Moselle and Meurthe-et-Moselle, two French departements (administrative divisions) at a crossroads between southern and northern Europe. This study starts at the end of the 19th century, a major stage in the economic development of eastern France and of the iron and steel industry as a whole. It ends with the Second World War. Factory workers where analysed so as better follow and understand their spatiotemporal trajectories their behaviours in work teams and their professional evolution. Particular attention was paid to the question of the relations of the workers with the employers and to the intervention of the state
Souza, Francine Beatriz de. « Historic pollen and seed dispersal in fragmented populations of Cariniana estrellensis (Raddi) Kuntze and Cariniana legalis (Mart.) Kuntze ». Universidade Estadual Paulista (UNESP), 2018. http://hdl.handle.net/11449/153203.
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
Cariniana estrellensis e Cariniana legalis são uma das maiores árvores dos biomas florestais da Amazônia e Mata Atlântica, sendo atualmente vulneráveis à extinção devido ao intenso desmatamento desses biomas. Estratégias para conservação in situ e ex situ são urgentes e estudos de diversidade genética e fluxo de genes são chaves e para esses propósitos. Assim, investigamos a diversidade genética, a estrutura genética espacial (SGS) e o fluxo histórico de genes em populações fragmentadas de ambas as espécies, utilizando marcadores de microssatélites. Todas as árvores encontradas nas populações foram mapeadas, medidas para o diâmetro na altura do peito (DAP) e amostrado o cambio de casca. O índice de fixação (F), em alguns casos, foi significativamente maior em árvores com menor DAP, indicando que as árvores menores apresentam um maior parentesco do que as maiores. Foi detectada SGS significativa para populações de ambas as espécies (60-350 m), indicando um padrão de dispersão de genes de isolamento pela distância (IBD). Para ambas as espécies, foi observada alta imigração de semente (38,5-61,5%) e pólen (80,1-100%), mostrando que as populações não são isoladas geneticamente. Não foi detectada autofecundação, mas o cruzamento entre árvores relacionadas foi detectado nas espécies (8,9-12,5%), sugerindo uma seleção mais forte contra árvores de autofecundação do que se originou do cruzamento entre árvores relacionadas. A distância de dispersão de pólen e sementes em C. estrellensis atingiu longa distância (> 3 km) do que em C. legalis (máximo de 385 m). No entanto, o pólen e as sementes em C. estrellensis e o pólen em C. legalis foram dispersos em um padrão de IBD. Os resultados sugerem que as populações estudadas são adequadas para conservação in situ e ex situ.
Cariniana estrellensis and Cariniana legalis, two of the largest trees in the Amazon and Atlantic Forest biomes, are currently vulnerable to extinction due to the intense deforestation of these biomes. Strategies for in and ex situ conservation are urgent, and studies of genetic diversity and gene flow are key aspects needed to develop these strategeis. Thus, we investigate the genetic diversity, spatial genetic structure (SGS), and historical gene flow in fragmented populations of both species, using microsatellite markers. All trees found in the study populations were mapped, measured for diameter at breast height (DBH), and sampled for bark cambium. Our results show that in some cases, fixation index (F) was significantly higher in trees with lower DBH, indicating that smaller trees have higher levels of inbreeding than larger ones. Significant SGS was detected in populations of both species (60-350 m), indicating a gene dispersal pattern of isolation by distance (IBD). For both species, we found high seed (38.5-61.5%) and pollen (80.1-100%) immigration demonstrating that populations are not genetically isolated. No self-fertilization was detected, but we did find evidence of mating among related trees (8.9-12.5%), suggesting stronger selection against selfed individuals than those originated from mating among relatives. Pollen and seed dispersal distance for C. estrellensis reached longer distances (> 3 km) than for C. legalis (maximum of 385 m). However, pollen and seeds of C. estrellensis and pollen of C. legalis were dispersed in an IBD pattern. The results suggest that the studied populations are suitable for in and ex situ conservation.
Lakis, Ghayas. « Dynamique évolutive de la durée du cycle de mil : effet des flux de gènes et des pratiques paysannes ». Thesis, Paris 11, 2012. http://www.theses.fr/2012PA112166.
Texte intégralDomestication of pearl millet (Pennisetum glaucum) in the Sahel of Africa has produced a wide range of diversity in cycle duration of landraces. This diversity allows Sahelian farmers to outface the precipitation fluctuation and to ensure regularity in grain production. Due to ecological and social recent changes, modifications of farmer’s practices could be a factor promoting gene flow between the early and late flowering varieties by increasing the opportunity of neighboring and flowering overlap between them. Such a situation raises questions about the past and current evolutionary dynamics of phenological diversity in this crop.In the first part of my thesis I tried to evaluate the possibility of gene flow between pearl millet varieties in South-West Niger, through a comparative approach among contrasting situations pertaining to the spatial distribution of early and late landraces. Therefore I conducted: 1) a field study where we observed flowering periods, for two types of varieties (early type (Haïni Kiré): 75 to 95 days and late type (Somno): 105 to 125 days of cycle length) in several pearl millet fields, and in two villages 2) a molecular study that allows the assessment of the level of genetic differentiation between late and early flowering populations sampled from four villages (including the two where the field study was conducted) of the same region (Dallol Bosso), using microsatellite markers. I was able to demonstrate the occurrence of pollen flow between the two types of landraces and I also showed evidence of genetic introgression between early and semi-late landraces. Potential mechanisms that would allow for the maintenance of the phenological differentiation between these two varieties and despite the gene flow are discussed.In the second part of this work I used a candidate gene and a population genetics approach, to try to identify genes that may have contributed to the cycle length diversity in pearl millet. I focused on three flowering candidate genes, PgHd3a, PgDwarf8 and PgPHYC which have been shown to be involved in the cycle length genetic diversity in several species, in order to estimate the differentiation between wild and domestic pearl millets and between early and late landraces, on the basis of theses candidate genes. I also tried to track for the fingerprint of eventual past selective events within these candidate genes. To be able to distinguish the effects of selection from the effect of demographic events that occurred during the domestication process, I used 8 neutral STS loci and an Approximate Bayesian Computation approach.My results strongly suggest that PgHd3a and PgDwarf8 were likely targeted by selection during domestication. However, a potential role of any of the three candidate genes in the phenological differentiation between early and late landraces was not supported by our data. The Bayesian approach confirmed the idea, suggested by many authors, that the gene flow from the wild to the domestic genetic pool has contributed significantly to the genetic diversity of the domestic pearl millet
Galian, Gay Laura. « Estenosis aórtica severa de bajo flujo y bajo gradiente con fracción de eyección normal : Prevalencia, características, pronóstico e historia natural ». Doctoral thesis, Universitat Autònoma de Barcelona, 2020. http://hdl.handle.net/10803/670516.
Texte intégralIntroducción: La estenosis aórtica (EAo) de bajo flujo y bajo gradiente (BF/BG) con fracción de eyección del ventrículo izquierdo (FEVI) normal es una entidad que se ha asociado con un peor pronóstico que la EAo de elevado gradiente (EG); a pesar de ello, distintos estudios y recientes meta-análisis ponen en duda los resultados previos. Objetivo: Determinar el riesgo de mortalidad y/o necesidad de cirugía/TAVI en los pacientes con EAo severa con BF/BG y FEVI conservada en comparación con la EAo severa con flujo normal con bajo gradiente (NF/BG) y con EG. Materiales y métodos: Estudio observacional longitudinal retrospectivo de pacientes diagnosticados entre 2008 y 2016 de EAo severa (AVA < 1,0 cm2) con FEVI normal (≥ 50%) de 14 hospitales terciarios. Se clasificaron los pacientes en función del ecocardiograma basal en: EG (gradiente medio ≥ 40 mmHg), NF/BG (VEi > 35 ml/m² y gradiente medio < 40 mmHg y) y BF/BG (VEi ≤ 35 ml/m² y gradiente medio < 40 mmHg). Se recogieron variables clínicas, demográficas y ecocardiográficas basales y a largo plazo. Resultados: Se incluyeron 1391 pacientes: 147 (10,5%) BF/BG, 752 (54,1%) EG y 492 (35,4%) NF/BG. A lo largo del seguimiento (59,0 meses; RIC 39,7 - 82,9), 899 pacientes (64,6%) recibieron remplazo valvular aórtico o TAVI, 551 con EG (73,3%; mediana tiempo: 12,3 meses, RIC 3,5-32,6), 81 pacientes con EAo BF/BG (55,1%; mediana tiempo: 28,7 meses, RIC 6,8-44,6), y 267 con NF/BG (54,3%; mediana tiempo: 29,9 meses, RIC: 14,1-49,4) objetivando que la EAo EG requirió cirugía/TAVI de forma más precoz que la EAo NF/BG (p<0,001) y que la EAo BF/BG (p<0,001), sin diferencias entre la EAo BF/BG y la EAo NF/BG (p=0,358). Durante el seguimiento se registraron 385 fallecimientos (mortalidad global del 27,7%): 46 del grupo BF/BG (31,3%; mediana de tiempo: 50,8 meses, RIC: 29,6-75,8), 205 del grupo EG (27,3%; mediana de tiempo: 56,1 meses, RIC: 33,8-83,7) y 134 del grupo NF/BG (27,2%; mediana de tiempo: 53,19 meses, RIC: 31,0-76,9) sin observarse diferencias significativas entre los 3 grupos (p=0,319). Asimismo, se observó que el beneficio de la cirugía/TAVI en términos de reducción de mortalidad global en toda la población con EAo fue importante, siendo los pacientes con EAo EG los que más se beneficiaron (HR: 0,17; IC 95%: 0,12-0,23; p < 0,001), seguidos de los pacientes BF/BG (HR: 0,25; IC 95%: 0,13-0,49; p < 0,001) y en último lugar los NF/BG (HR: 0,29; IC 95%: 0,20-0,44; p < 0,001). Se observó que la progresión del gradiente medio a lo largo del seguimiento fue mayor en los grupos con bajo gradiente en comparación con el grupo EG (BF/BG vs. EG: p=0,022; NF/BG vs. EG: p=0,013) y respecto al AVA no se observaron diferencias significativas entre el grupo BF/BG y el grupo EG (p=0,452), siendo mayor la disminución en el grupo NF/BG que en el grupo EG y BF/BG (NF/BG vs. EG: p=0,007; NF/BG vs. BF/BG: p=0,013). Conclusiones: La EAo BF/BG es una entidad poco frecuente que afecta al 10,5% de la población. La indicación de cirugía/TAVI en el grupo BF/BG fue menor que en el grupo EG y similar al grupo NF/BG, sin diferencias significativas en la mortalidad. El beneficio de la cirugía en relación a la reducción de la mortalidad global fue menor en los pacientes con EAo BF/BG en comparación con los pacientes EAo EG. El estudio de la evolución del AVA y el gradiente medio del grupo BF/BG mostró un patrón intermedio entre el grupo EG y NF/BG. Los hallazgos del presente estudio nos hacen concluir que la EAo BF/BG tiene un comportamiento clínico intermedio entre los grupos EG y NF/BG.
Introduction: Severe paradoxical low-flow/low-gradient (LF/LG) aortic stenosis (AS) with preserved left ventricular ejection fraction (LVEF) has been associated with worse prognosis than high gradient (HG) AS. However, different studies and recent meta-analyses question the previous results. Aim: To determine the mortality risk and the need for surgery in patients with severe LF/LG AS and preserved LVEF compared to severe AS with normal flow and high (HG) and low gradient (NF/LG). Materials and methods: A retrospective longitudinal observational study of patients diagnosed of severe AS (AVA < 1,0 cm2) with normal LVEF (≥ 50%) from 14 reference hospitals between 2008 and 2016. Patients were classified according to baseline echocardiography as: HG (mean gradient ≥ 40 mmHg), NFLG (SVi> 35 ml/m² and mean gradient <40 mmHg) and LF/LG (SVi ≤ 35 ml / m² and mean gradient <40 mmHg). Baseline and long-term clinical, demographic and echocardiographic variables were collected. Results: A total of 1,391 patients were included and classified as: 147 (10.5%) LF/LG, 752 (54 0.1%) HG and 492 (35.4%) NF/LG. Throughout follow-up (59.0 months; IQR 39.7 - 82.9 months), 899 patients (64.6%) received aortic valve replacement or TAVI, 551 with HG (73.3%; median time: 12.3 months, IQR 3.5-32.6), 81 with LF/LG AS (55.1%; median time: 28.7 months, IQR 6.8-44.6), and 267 with NF/LG (54.3%; median time: 29.9 months, IQR: 14,1-49,4), with HG AS patients requiring surgery/TAVI earlier than NF/LG (Log-Rank p <0.001) and LF/LG AS patients (p <0.001), without significant differences between the LF/LG and NF/LG (p=0.358). During follow-up, 385 patients died (overall mortality 27.7%): 46 in LF/LG group (31.3%; median time: 50.8 months, IQR: 29.6-75.8), 205 in HG group (27.3%; median time: 56.1 months, IQR: 33.8-83.7) and 134 in NF/LG group (27.2%; median time: 53.19 months, IQR: 31.0 -76.9) with no significant differences among groups (p=0.319). It was observed that the benefit of surgery (in terms of overall mortality risk reduction) in the whole AS population was significant, with HG AS patients benefiting the most (HR: 0.17; 95% CI: 0.12-0.23; p <0.001) followed by LF/LG patients (HR: 0.25; 95% CI: 0.13-0.49; p <0.001) and finally NF/LG (HR: 0.29, 95% CI: 0.20-0.44; p <0.001). Progression of the mean gradient throughout follow-up was greater in low gradient groups: LF/LG and NF/LG compared to HG (LF/LG vs. HG: p=0.022; NF/LG vs. HG: p=0.013) with no significant differences between LF/LG and NF/LG (p=0.426) and considering AVA progression, no significant differences were observed between the LF/LG and HG groups (p=0.452), with this decrease being greater in the NF/LG group than in others (NF/LG vs. HG: p = 0.007; NF/LG vs. LF/LG: p = 0.013). LVEF progression did not differ significantly among groups (LF/LG vs. HG: p = 0.353; NF/LG vs. HG: p = 0.626, LF/LG vs. NF/LG: p = 0.212). Conclusions: Paradoxical LF/LG AS is a rare entity that affects 10.5% of the population. The need for surgery/TAVI in the LF/LG group was lower than in the HG group and similar to NF/LG group, without significant differences in overall and cardiovascular mortality. All patients with significant AS benefited from aortic valve surgery in terms of overall mortality reduction, which was less beneficial in LF/LG AS compared to HG AS. Study of AVA and mean gradient progression revealed an intermediate pattern of LF/LG between the HG and NF/LG groups. Therefore, the findings of the present study conclude that LF/LG has an intermediate clinical profile between the HG and NF/HG groups.
Sousa, Alexandre Medeiros Correia de. « Estudo de uma experiência de fluxo informacional científico no Instituto Oswaldo Cruz : a "Mesa das Quartas-Feiras" ». reponame:Repositório Institucional da FIOCRUZ, 2006. https://www.arca.fiocruz.br/handle/icict/6336.
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Fundação Oswaldo Cruz. Instituto de Comunicação e Informação Científica e Tecnológica em Saúde. Rio de Janeiro, RJ, Brasil.
No início do século XX, a Documentação apresentou um grande avanço por meio da reflexão e ação sobre o tratamento da informação existente nas instituições científicas. Em 1909, foi implementado na Biblioteca doInstituto Oswaldo Cruz, um sistema de disseminação de informação entre seus cientistas que se baseava na leitura sistemática e resumo semanal de artigos deperiódicos científicos recém chegados à instituição, que tivessem relação com suasfrentes de pesquisa. Esses resumos eram apresentados e debatidos em uma reunião semanal e, posteriormente, eram classificados pelo próprio pesquisador para que servissem ao bibliotecário na alimentação de um catálogo analítico de assunto, presente na biblioteca e disponível aos pesquisadores locais. Este trabalho procura identificar e traçar o fluxo da informação, a partir de um estoque informacional até o pesquisador, ocorrido através da prática institucional intitulada “Mesa das Quartas-Feiras”. Dessa forma, foi possível analisar e fomentar o estudo das experiências de atividades, fluxo e sistematização da informação em um ambiente científico podendo levar à discussão sobre o papel das bibliotecas e dos bibliotecários diante das necessidades modernas de uso, formas de acesso e disseminação da informação no ambiente das instituições de pesquisa em Ciência e Tecnologia em Saúde, assim como seus papéis estratégicos na produção científica em instituições de pesquisa.
In the beginning of the 20th century, Documentation presented a great advance by means of reflection and action on the treatment of the existing information in the scientific institutions. In 1909, in the Library of the Oswaldo Cruz Institute, a system of dissemination of information between its scientists was implemented. It consisted of systematically reading and summarizing anarticle of a weekly scientific periodical that had recently arrived at the institute and that related to the scientist’s area of research. These summaries were presented and discussed in a weekly meeting and latterly classified by the researchers themselves, useful for the librarian when feeding an analytical catalogue of subject, located at the library and available to local researchers. This work aims at identify and trace the flow of information from an informational source to the researcher, which occurred through the institutional practice, entitled “The Wednesday roundtables”. In this way, it was possible to analyze and foment the study of regency experiences, flow and systematization of information in a scientific environment, making it possible to discuss the roles of libraries and librarians before the modern necessities of use, forms of access and dissemination of information in the environment of research institutions in science and technology in health, as well as strategic roles in scientific production.
Cheymol, Jean-Bernard. « De la brieveté dans les émissions télévisuelles courtes sur les arts plastiques ». Thesis, Paris 3, 2009. http://www.theses.fr/2009PA030062.
Texte intégralThis doctoral thesis aims at describing the phenomenon of brevity in short television programmes about plastic arts. First, we will construct the problem constituted by the presence of such programmes on television and by the threat their insertion in the television flood represents for the existence of the brief discourse. Then, a notional analysis of brevity, clearly distinguished from shortness, will enable us to pick out several strategies of brevity in the media. In a rhetorical perspective, these programmes aim at getting adapted to the constraint of brevity, whereas in a pragmatic perspective, their target is to make the relation to the work of art easier. First, through the description of the process used in two programmes, D’Art d’art on France 2 and Suivez l’artiste on France 3, we will study the multiple strategies the programme resorts to in order to try to fight against the television flood, suggesting restraint in speech! or operating retention via various techniques of condensation. Then, we will concentrate on the changes brought by brevity in its efficiency to the relation to the work of art. It can be actualized, reduced to distant contact or to its effects. Finally, its possibility is increased since it is formed in an occasional and contingent encounter. In this form of short television communication, creative of possibilities, the brevity of discourse redefines the terms, moves the stakes in the relation of communication and introduces flexibility, giving the possibility to the work of art to open to multiform contact
Silva, Fabio Mascarenhas e. « Um estudo das contribui??es do hipertexto para o fluxo da informa??o em meio eletr?nico ». Pontif?cia Universidade Cat?lica de Campinas, 2003. http://tede.bibliotecadigital.puc-campinas.edu.br:8080/jspui/handle/tede/761.
Texte intégralPontif?cia Universidade Cat?lica de Campinas
Research on the functions of hypertext in the informational flow in the electronic media. One first argues the concept of information in the areas of the Mathematics, Semiotics and Communication. They are presented, after that, the concepts of hypertext, one is traced retrospect historical considering it a mobilizador device of the knowledge, proceeding from the evaluative process of register and dissemination of knowing, its importance is approached to relate the users and the supplies of knowledge, and is analyzed it scientific production of the Science of the Information on hypertext during the understood period enters the years of 1990 the 2002. It has been struggled viability of use of the pertextuais resources in the processes of the information and is concluded presenting resulted and.
Pesquisa sobre as fun??es do hipertexto no fluxo informacional em meio eletr?nico. Discute-se primeiramente o conceito de informa??o nas ?reas da Matem?tica, Semi?tica e Comunica??o. Apresentam-se, em seguida, os conceitos de hipertexto, tra?a-se um retrospecto hist?rico considerando-o um dispositivo mobilizador do conhecimento, proveniente do processo evolutivo de registro e dissemina??o do saber, aborda-se sua import?ncia para relacionar os usu?rios e os estoques de conhecimento, e analisa-se a produ??o cient?fica da Ci?ncia da Informa??o sobre o hipertexto durante o per?odo compreendido entre os anos de 1990 a 2002. Debate-se a viabilidade de uso dos recursos hipertextuais nos processos da informa??o e conclui-se apresentando resultados e sugerindo linha de estudos futuros.
Jordi, Emmanuelle. « Histone post-translational modifications in the nuclei of striatal D1 and D2 neurons : development of a novel method of study and effects of cocaine ». Phd thesis, Université Pierre et Marie Curie - Paris VI, 2012. http://tel.archives-ouvertes.fr/tel-00831656.
Texte intégralHenricksen, Richard A. « The Flux of Agency : Unsettling Objects in Contemporary Spanish Civil War Novels (1998-2008) ». The Ohio State University, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=osu1470585727.
Texte intégralLamour, Christian. « L’essentiel et le “super-flux” : mouvements et tremblements dans la civilisation métropolitaine des gratuits sur les marges étatiques et démocratiques de l’Europe ». Thesis, Université de Lorraine, 2014. http://www.theses.fr/2014LORR0223/document.
Texte intégralThe free dailies like the penny press in the late 19th century portray an urban civilisation experiencing a time of economic, social, cultural and political turmoils. The current research consists in understanding contemporary metropolitan transitions through the production and the reception of this type of press. Today metropolises are nodes of a world-wide liquid space of goods, people and capitals. Therefore, this commercial press could be essentially the mirror of a global civilisation unrelated to the inherited cities. However, this media depicts and is instrumental in the definition of locally-based territories which concentrate specific fears and expectations. Free dailies are parts of a localised risks Gesellschaft/Gemeinschaft implying two territorial phenomenons : 1) the perpetuation of borders closing the communicational ties between one state power and the metropolitan population, 2) the presence of transitional frontiers showing the ability of the state-civil society communication container to include parts of other territorial states. To understand these interactions, the research takes into consideration three free newspapers located in metropolises whose urban development crosses over state borders: L’essentiel in Luxembourg and the editions of 20 Minutes in Geneva (Switzerland) and in Lille (France)
Pinto, Victor Hugo. « Linking tectonic evolution with fluid history in hyperextended rifted margins : examples from the fossil Alpine and Pyrenean rift systems, and the present-day Iberia rifted margin ». Thesis, Strasbourg, 2014. http://www.theses.fr/2014STRAH018/document.
Texte intégralThis thesis focus in the identification of geochemical tracers and effects of fluid that interact with basement and sedimentary rocks in hyperextended systems. The investigation of such fluids is based on geological observation, geochemical analyses and geophysical data from fossil hyperextended rift systems exposed in the Alps and in the West Pyrenees, and the present-day distal margins of Iberia and Newfoundland. Two types of fluids were identified during this study. The first type, referred to as continental crust-related fluids, has a signature of Si and Ca. The second type, referred to as mantle-related fluids, has a signature of Si, Mg, Fe, Mn, Ca, Ni, Cr and V. The fluid percolation is strongly related to the formation of extensional detachment faults and the evolution of hyperextended systems. Fluid flow in these systems has major implications for the nature of sediments, rheological changes and chemical modifications of the Earth’s reservoirs throughout its evolution
Anderson, Simon. « Re-flux action : concerning the Fluxshoe exhibition tour of 1972-73, and the subsequent attempt to catalogue the residual collection, held in the Tate Gallery Archive : including general problems of performance art history which this raised ». Thesis, Royal College of Art, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.600806.
Texte intégralQuéméré, Erwan. « Génétique du paysage de populations fragmentées de lémuriens à Madagascar : conservation du propithèque à couronne dorée (Propithecus tattersalli) dans la région de Daraina ». Toulouse 3, 2009. http://thesesups.ups-tlse.fr/642/.
Texte intégralSince habitat fragmentation reduces the size of habitat patches and decreases their level of connectivity, this process is among the greatest threats faced by species in tropical regions. Here, we studied the case of the golden-crowned sifaka (Propithecus tattersalli), a rare and threatened species of lemur from northeastern Madagascar, whose populations are only found in a small and highly fragmented forest habitat. This socially-organized species, endemic to the Daraina area, was only discovered twenty years ago (Simons, 1988) and little is know about its resiliency to the growing habitat openness. To provide relevant information to set up appropriate conservation strategies for this species, we 1) studied its distribution and assessed the density of its main populations and 2) characterized its global genetic structure isolating new specific microsatellites and collecting faeces from 403 putative individuals (118 social groups) sampling in the whole distribution area. The results of the demographic analyses suggest a large heterogeneity of density among surveyed forest patches (between 34 and 90 individuals/km²) and a total species size between 11,000 and 26,000 individuals and most likely above 18,000 individuals. Combining spatial and genetic analyses, we showed that the Manankolana River is the main geographical feature shaping P. Tattersalli 's genetic diversity, and that it probably played a role as a barrier to gene flow whereas the national road does not seem to strongly impede the dispersal of individuals. Our results also suggested a strong influence of the isolation by distance and a weak influence of the forest habitat structural connectivity on dispersal patterns at the landscape scale even though one of the population in north of the distribution area is highly differentiated suggesting a strong local impact of habitat fragmentation. At the resource patch scale, we found that individuals within social groups are closely related and that most of the dispersal events occur between adjacent social groups as suggested by behavioural information (Meyers, 1993). Lastly, the study of the P. Tattersalli demographic history revealed that the populations underwent a bottleneck at a period between 1500 and 3000 years ago leading to a drastic reduction of effective population size (from several thousand individuals to a few hundred individuals per population). .
Lauvin, Grégoire. « Split Soundscape, le diorama sonore : la reconstitution de l'espace sonore en temps réel ». Thesis, Aix-Marseille, 2018. http://www.theses.fr/2018AIXM0591.
Texte intégralSplit Soundscape is a practice based research project that revisits the concepts of Soundscape and Schizophonia originally introduced by the composer R. Murray Schafer. The artistic practice consists of a series of sound installations that focus on the reconstitution of sound space in real time. A number of “Open” microphones located in given territories are employed to transmit the local sonic environment via the internet in real time (using audio streaming technologies). A new soundscape is composed from these transmitted soundscapes and played through loudspeakers in a dedicated (exhibition) listening space. The theoretical research investigates geographical, sociological and philosophical definitions of space. The concept of soundscape as defined by Schafer is called into question and reconsidered from the perspective of sound archeology and as a social construct. This in turn, leads to the positioning of listening as being central in the construction of soundscape. The notion of Schizophonia (the separation of an original sound from his technical reproduction) is examined in detail and compared with Pierre Schaeffer’s definition of the sound object or objet sonore as an alternative consequence of mechanical reproduction. The artistic practice is contextualized in relation to the field of contemporary sound art and more specifically the concepts of flux, indeterminism in composition. The tools developed to facilitate the practice are described, and the evolution of the art project is presented as a succession of experiments informed by the academic research
Mitchell, Stephanie Bianca. « Sediment Dispersal Processes and Anthropogenic Impacts at Rex Lake, Summit County, Ohio ». University of Akron / OhioLINK, 2015. http://rave.ohiolink.edu/etdc/view?acc_num=akron1442416877.
Texte intégralZastepa, Arthur. « Fate and Persistence of Microcystin Congeners in Lakes and Lake Sediments ». Thesis, Université d'Ottawa / University of Ottawa, 2014. http://hdl.handle.net/10393/30453.
Texte intégralKinouchi, Renato Rodrigues. « Consciência não-linear : de William James aos sistemas dinâmicos ». Universidade Federal de São Carlos, 2004. https://repositorio.ufscar.br/handle/ufscar/4746.
Texte intégralUniversidade Federal de Minas Gerais
William James’s scientific psychology was developed in order to surpass precedent approaches such as both Rationalism and Associationism. His masterpiece, The Principles of Psychology (1890), has been a mark in the history of psychological science because James already took cognitive processes as relations between the organisms and their environments. In this doctoral work, three contemporaneous cognitive theories are interpreted through James’s ideas: Artificial Intelligence, Connectionism and Dynamical Systems. This analysis, however, neither concerns scientific psychology nor philosophy of mind — in precise terms, the former examines psychological facts, and the later categorizes mental phenomena. Notwithstanding, we have done a conceptualcomparative study that categorizes the explanations proposed by those three cognitive theories. To be sure, this work should be labelled as a Philosophy of Cognitive Science. It examines theories concerned with cognition; so it is a philosophical analysis on cognitive science
A psicologia científica de William James procurava superar perspectivas precedentes oriundas do Racionalismo e do Associacionismo. Sua obra-prima, conhecida como Os Princípios de Psicologia, de 1890, é um marco na história da psicologia porque nesse livro James já toma os processos cognitivos como relações entre o organismo e seu meio ambiente. Nesta tese de doutoramento, três teorias cognitivas modernas — a saber, Inteligência Artificial, Conexionismo e Dinamicismo — são interpretadas via as idéias de James. Tal análise, entretanto, não deve ser tomada como sendo ciência psicológica no sentido positivo, nem tampouco deve ser enquadrada no que se convenciona chamar de filosofia da mente. No primeiro caso, fatos psicológicos propriamente ditos seriam examinados. Já no segundo, ou seja, se este fosse um trabalho em filosofia da mente, então se deveria estabelecer as categorias dos fenômenos mentais. Aqui, o que se procura formular, mediante uma espécie de estudo comparativo-conceitual, é uma categorização das explicações propostas pelas três linhas teóricas a serem examinadas. Então, para sermos precisos, esta tese se enquadra no que se poderia chamar de Filosofia das Ciências Cognitivas, pois discorre sobre como diversas teorias científicas explicam a cognição. Trata-se de um exame de teorias, uma categorização das explicações científicas sobre a cognição
Hanas, Erin. « Wolf Vostell's Fluxus Zug, Model Museum, Academy, Archive ». Diss., 2013. http://hdl.handle.net/10161/8244.
Texte intégralThis dissertation analyzes Wolf Vostell's
Dissertation
Alves, Tânia Cristina de Pinho. « Uma Proposta Pedagógica em História e Geografia - A Revolução de Transportes no Século XIX. Sistemas de Transportes : Transportes Terrestres e Fluxos Associados em Portugal Continental ». Master's thesis, 2013. http://hdl.handle.net/10316/36017.
Texte intégralPinheiro, Daniela Ribeiro. « Synthesis, photophysical and electrochemical studies on tryptanthrin and indigo derivatives. Historic molecules with modern applications ». Doctoral thesis, 2021. http://hdl.handle.net/10316/95405.
Texte intégralIndigo, an iconic molecule of colour, is included in the most ancient and important natural dyes used by mankind. The longevity as a colourant and unique properties of this compound are related with its high (photo)stability which is linked to a rapid proton transfer in the excited state (ESPT). In the past few years, indigo and its derivatives have gained renewed interest due to applications in several fields such as photoswitches, electronic devices and sensors. The study and development of an improved and fast approach for the synthesis of mono- and di-substituted indigo derivatives combined with a comprehensive characterization of their electronic spectral and photophysical properties in different solvents and temperatures was undertaken and constitutes the first part of this thesis. The study was further rationalized with density functional theory (DFT) and time-dependent density functional theory (TDDFT) calculations. The second part of this thesis reports the synthesis of tryptanthrin and tryptanthrin derivatives, important compounds with a variety of biological and pharmacological applications as well as redox properties. Tryptanthrin was synthesized from indigo under mild conditions using microwave irradiation. A comprehensive study of the excited state of these compounds was also undertaken. In contrast with indigo, emission of the triplet state of tryptanthrin and its derivatives, with the exception of 2-aminotryptanthrin, where fluorescence dominates, was observed with a very efficient singlet oxygen sensitization quantum yield. These results indicate intersystem crossing (ISC) to be the dominant deactivation channel in tryptanthrin and its derivatives, with high quantum yields. Time-resolved fluorescence and femtosecond transient absorption (fs-TA) data, further supported with TDDFT calculations, show for tryptanthrin, two species, a locally excited (LE) and a charge transfer (CT) with a highly reversible inter-conversion rate constant (LE to CT state). A pratical and modern application of storage of chemical energy with, an aqueous organometallic and an all-organic redox flow battery (RFB) with sulfonated tryptanthrin, working at neutral pH and with long-term stability, was further developed. The single cell tests showed reproducible charge-discharge cycles with significant improvement results for the aqueous all-organic RFB, with higth coulombic, voltaic and energetic efficiencies stabilized over several working cycles. The work paves the way to the promising development of new tryptanthrin based structures for environmentally friendly aqueous all-organic RFBs working at neutral pH values.
O índigo, uma icónica molécula da cor, é um dos corantes mais antigos e importantes usados pela humanidade. A longevidade deste corante assim como as suas propriedades únicas estão relacionadas com a sua elevada (foto)estabilidade que esta ligada a uma rápida transferência de protão no estado excitado. Nos últimos anos, o índigo e os seus derivados ganharam um interesse renovado devido a aplicações em diversos campos, tais como, interruptores fotónicos, dispositivos elétricos e sensores. O estudo e desenvolvimento de uma abordagem mais rápida e aprimorada da síntese de derivados mono- e di-substituídos do índigo combinados com uma caracterização abrangente das suas propriedades eletrónicas, espectrais e fotofísicas, em diferentes solventes e temperaturas foi realizada e constitui a primeira parte desta tese. O estudo foi racionalizado com cálculos teóricos através da teoria do funcional da densidade (DFT) e da teoria do funcional da densidade dependente do tempo (TDDFT). A segunda parte desta tese relata a síntese da triptantrina e seus derivados. Estes compostos são importantes pois para além de apresentarem uma vasta aplicação biológica e farmacológica possuem também propriedades de oxidação-redução. A triptantrina foi sintetizada a partir do índigo sob condições suaves utilizando radiação de micro-ondas como fonte de energia. Um estudo abrangente do estado excitado destes compostos foi também realizado. Em contraste com o índigo, na triptantrina e seus derivados, com exceção da 2-aminotriptantrina, onde a fluorescência domina, foi observada emissão do estado tripleto com rendimentos quânticos de formação de oxigénio singleto muito eficientes. Estes resultados indicam que a conversão intersistemas (ISC) é a principal via de desativação na triptantrina e seus derivados, com elevados rendimentos quântico. Os dados de fluorescência resolvida no tempo e absorção transiente de femtosegundos (fs-TA), complementados com cálculos TDDFT, mostram que no caso da triptantrina, existem duas espécies, uma excitada localmente (LE) e uma com transferência de carga (CT), com uma constante de interconversão altamente reversível (LE para o estado CT). Uma aplicação prática e moderna de armazenamento de energia química com, uma bateria redox de fluxo aquoso organometálico e exclusivamente orgânico com triptantrina sulfonada, trabalhando em pH neutro com estabilidade a longo prazo foi desenvolvida. Os testes de célula única demostraram ciclos de carga-descarga reprodutíveis, com melhores resultados no sistema exclusivamente orgânico, com eficiências coulômbica, voltaica e enérgicas estáveis e elevadas ao longo de vários ciclos. Este trabalho fornece uma nova perspetiva sobre o desenvolvimento de derivados da triptantrina solúveis em água com potencial aplicação em baterias de fluxo aquoso de sistemas exclusivamente orgânico que trabalham em pH neutro e são mais sustentáveis em termos ambientais.
Schegg, Roland. « Thermal maturity and history of sediments in the North Alpine Foreland Basin (Switzerland, France) ». Phd thesis, 1993. http://tel.archives-ouvertes.fr/tel-00923333.
Texte intégralVillescas, Joseph Paul-Anthony. « Exploring the influence of an American Latina/o intellectural formation in flux : an analysis of the multiform capital and protocultural agency accumulated by the avowed raza mezclada vanguard ». Thesis, 2005. http://hdl.handle.net/2152/2228.
Texte intégralWeinert, Friedel. « The March of Time : Evolving Conceptions of Time in the Light of Scientific Discoveries ». 2013. http://hdl.handle.net/10454/6282.
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