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Littérature scientifique sur le sujet « Lithium alkyls »

Auteur : Grafiati

Publié le 9 mars 2023

Mis à jour le 31 juillet 2025

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Articles de revues sur le sujet "Lithium alkyls"

1

Charrier, Claude, Nicole Maigrot, Francois Mathey, Francis Robert, and Yves Jeannin. "Reactions of 1,2-diphosphetenes with lithium and lithium alkyls." Organometallics 5, no. 4 (1986): 623–30. http://dx.doi.org/10.1021/om00135a002.

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Jutzi, Peter, and Bernd Hielscher. "Reaction of decamethylstannocene with lithium alkyls." Organometallics 5, no. 12 (1986): 2511–14. http://dx.doi.org/10.1021/om00143a018.

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Martínez-Martínez, Antonio J., Alan R. Kennedy, Valerie Paprocki, et al. "Selective mono- and dimetallation of a group 3 sandwich complex." Chemical Communications 55, no. 65 (2019): 9677–80. http://dx.doi.org/10.1039/c9cc03825f.

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While lithium alkyls and lithium amides do not metallate the scandium compound [(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)Sc(η<sup>8</sup>-C<sub>8</sub>H<sub>8</sub>)], a synergistic lithium–aluminium base-trap partnership cannot resist taking a bite with one C–H bond selectively cleaved from both Cp and COT rings.

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Ballard, D. G. H., R. J. Bowles, D. M. Haddleton, S. N. Richards, R. Sellens, and D. L. Twose. "Controlled polymerization of methyl methacrylate using lithium aluminum alkyls." Macromolecules 25, no. 22 (1992): 5907–13. http://dx.doi.org/10.1021/ma00048a008.

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Sirsch, P., W. Scherer, M. Gardiner, S. A. Mason, and G. S. McGrady. "Electron delocalization in lithium alkyls: negative hyperconjugation and agostic bonding." Acta Crystallographica Section A Foundations of Crystallography 58, s1 (2002): c352. http://dx.doi.org/10.1107/s0108767302099063.

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Schumann, Herbert, and Gerald Jeske. "Metallorganische Verbindungen der Lanthanoide, XXXIII [1] Dicyclopentadienyllanthanoid-alkyle und -hydride von Neodym, Samarium und Lutetium [2] / Organometallic Compounds of the Lanthanides, XXXIII [1] Dicyclopentadienyllanthanide Alkyls and Hydrides of Neodymium, Samarium and Lutetium [2]." Zeitschrift für Naturforschung B 40, no. 11 (1985): 1490–94. http://dx.doi.org/10.1515/znb-1985-1112.

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Tricyclopentadienylneodymium and -lutetium react with sec-butyl lithium and terf-butyl lithium to form sec-butyl- and tert-butyl(dicyclopentadienyl)neodymium and -lutetium, which decompose to the corresponding dicyclopentadienyllanthanide hydride complexes. Dicyclopentadienyl-bis-(trimethylsilyl)methylsamarium and -lutetium are made from dicyclopentadienylsamarium or -lutetium chloride and bis(trimethylsilyl)methyl lithium. They react with hydrogen to form the corresponding dicyclopentadienyllanthanide hydride complexes.

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Seyam, Afif M. "Observations on the reaction of uranium tetrachloride and dichlorodioxouranium(VI) with lithium alkyls." Inorganica Chimica Acta 110, no. 2 (1985): 123–26. http://dx.doi.org/10.1016/s0020-1693(00)84567-3.

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Galliani, Guido, Bruno Rindone, Ricardo Suarez-Bertoa, Francesco Saliu, and Alberto Terraneo. "Stereoselective Addition of Grignard Reagents and Lithium Alkyls onto 3,5-Disubstituted-1,3-oxazolidine-2,4-diones." Synthetic Communications 43, no. 5 (2012): 749–57. http://dx.doi.org/10.1080/00397911.2011.609301.

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Kershenbaum, I. L., I. A. Oreshkin, and B. A. Dolgoplosk. "Formation of carbene species in the reaction of lithium alkyls with molybdenum, tungsten, and cobalt chlorides." Bulletin of the Russian Academy of Sciences Division of Chemical Science 41, no. 1 (1992): 172–74. http://dx.doi.org/10.1007/bf00863939.

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Galliani, Guido, Bruno Rindone, Ricardo Suarez-Bertoa, Francesco Saliu, and Alberto Terraneo. "ChemInform Abstract: Stereoselective Addition of Grignard Reagents and Lithium Alkyls onto 3,5-Disubstituted-1,3-oxazolidine-2,4-diones." ChemInform 44, no. 24 (2013): no. http://dx.doi.org/10.1002/chin.201324114.

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Thèses sur le sujet "Lithium alkyls"

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Park, Bongjin. "Single electron transfer in reactions involving alkyl halides with lithium alkylamide, lithium alkyl and lithium metal." Diss., Georgia Institute of Technology, 1988. http://hdl.handle.net/1853/27052.

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Antolini, Floria. "Complexes of novel chiral alkyl and Câ†1-symmetric amido ligands." Thesis, University of Sussex, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.367353.

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Thornton, Terry L. (Terry Lee) 1962. "Mixed Alkyllithim/Lithium Alkoxide Aggregates with Less Sterically Crowded Alkyl Groups." Thesis, University of North Texas, 1997. https://digital.library.unt.edu/ark:/67531/metadc278441/.

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Mixed alkyllithium / lithium alkoxide aggregates in the form (RLi)n(ROLi)m were formed by addition of corresponding alcohol compounds at different Li/O ratios. Variable temperature 13C and 6Li NMR spectroscopy were used to verify the formation of the mixed aggregates and to study their behavior in hydrocarbon solution. Spectra for the lithium n-propoxide / n-propyllithium and iso-butyllithium / lithium iso-butoxide systems each indicated at least one mixed aggregate.

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Welder, Catherine Owens. "A mechanistic evaluation of the reactions of lithium aluminum hydride with alkyl halides." Diss., Georgia Institute of Technology, 1996. http://hdl.handle.net/1853/25958.

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SUAREZ, BERTOA RICARDO. "Sustainable procedures in organic synthesis." Doctoral thesis, Università degli Studi di Milano-Bicocca, 2009. http://hdl.handle.net/10281/7474.

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O-acyl-N-benzyllactamides are obtained in good yield by reaction of 4-benzyl-5-methyl-1,3-oxazolidine-2,4-diones with Grignards reagents and with lithium alkyls. Three alkanes and two ethers were oxidised with ozone in dichloromethane solution or in aqueous pH 3 suspension. Cyclodecane and cyclododecane were converted into the corresponding cycloalkanones. n-decane was converted into a mixture of isomeric n-decanones and carboxylic acids. An ester was formed from the ethers. Hence, one of the methylene groups of these substrates is generally converted into a carbonyl group. Some of these react

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Ullrich, Steven A. "Synthesis and Characterization of some Flourine-containing Lithium Alkyl Sulfonates: Flourinated Sulfonates and SF5-containing Sulfonates." PDXScholar, 1994. https://pdxscholar.library.pdx.edu/open_access_etds/4880.

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Lithium salts of pentafluorothio alkyl sulfonic acids and perfluoroalkyl disulfonic acids were prepared for testing for possible use as polymer electrolytes. Most of these lithium salts were made from the corresponding sodium, potassium or calcium salts. Aqueous solutions of these salts were passed through polystyrene sulfonate ion exchange resin in the acid form to obtain aqueous solutions of the corresponding acids. The acids were then neutralized with lithium hydroxide using a pH meter. One salt was made by reacting the barium salt of the corresponding acid with lithium sulfate. A sulfonyl

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Millard, Marcus J. "Effects of Lithium Nitrate Admixture on Early Age Concrete Behavior." Thesis, Georgia Institute of Technology, 2006. http://hdl.handle.net/1853/11615.

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Alkali silica reaction (ASR), a reaction which occurs between reactive siliceous mineral components in the aggregate and the alkaline pore solution in concrete, is responsible for substantial damage to concrete structures in the U. S. and across the world. Lithium admixtures, including lithium nitrate (LiNO3), have been demonstrated to mitigate ASR damage, and are of particular interest for use in concrete airfield pavement construction, where ASR damage has been recently linked to the use of certain de-icing chemicals. Although the effectiveness of lithium admixtures at ASR-mitigation is we

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Collins, Courtney Lloyd. "Examination of the mechanism by which lithium additives inhibit alkali-silica reaction gel expansion." Thesis, Georgia Institute of Technology, 2002. http://hdl.handle.net/1853/21295.

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Robertson, Alan. "Elaboration and expansion of the chemistry of alkali metal primary amide complexes." Thesis, University of Strathclyde, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.248701.

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Murphy, Denissa Tjiadarma. "Structural Investigation of Electrodes for Rechargeable Alkali Ion Batteries." Thesis, The University of Sydney, 2017. http://hdl.handle.net/2123/17699.

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This thesis describes the in-depth characterisation of the structure, including detailed cation distributions, of positive electrode materials for lithium and sodium ion batteries. As the crystal chemistry influences the mobility of lithium and sodium ions, the structure and electrochemical property relationships for select compounds have been established. The majority of this thesis is focused on the structural characterisation of LiMn2-xTixO4 (0.2 ≤ x ≤ 1.5). A combination of X-ray and neutron powder diffraction studies along with spectroscopic techniques and physical property measurements w

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Livres sur le sujet "Lithium alkyls"

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A, Thomas Michael D., Kurtis Kimberly E, Transtec Group Inc, United States. Federal Highway Administration. Office of Infrastructure Research and Development., and Turner-Fairbank Highway Research Center, eds. Guidelines for the use of lithium to mitigate or prevent alkali-silica reaction (ASR). U.S. Dept. of Transportation, Federal Highway Administration, Research, Development, and Technology, Turner-Fairbank Highway Research Center, 2003.

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Folliard, Kevin J. Guidelines for the use of lithium to mitigate or prevent alkali-silica reaction (ASR). U.S. Department of Transportation, Federal Highway Administration, Office of Infrastructure R&D, Turner-Fairbank Highway Research Center, 2003.

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Lew, Kristi. Alkali Metals Lithium, Sodium, Potassium, Rubidium, Cesium, Francium. Rosen Publishing Group, 2009.

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Alkali Metals: Lithium, Sodium, Potassium, Rubidium, Cesium, Francium. Rosen Publishing Group, 2009.

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The alkali metals: Lithium, sodium, potassium, rubidium, cesium, francium. Rosen Central, 2010.

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6

Klein, Klaus-Dieter. Reaktionen von Methylencyclopropanen und Methylencyclobutanen unter Alkyl- und Arylsubstituenteneinfluss mit Lithium-Synthesepotential und Stabilität des 2,4-Dilithio-1-butens. 1990.

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Chapitres de livres sur le sujet "Lithium alkyls"

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Mota de Freitas, Duarte, Brian D. Leverson, and Jesse L. Goossens. "Lithium in Medicine: Mechanisms of Action." In The Alkali Metal Ions: Their Role for Life. Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-21756-7_15.

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Li, Wei-bang, Ngoc Thanh Thuy Tran, and Shih-Yang Lin. "Diverse Phenomena in Stage-n Graphite Alkali-Intercalation Compounds." In Lithium-Ion Batteries and Solar Cells. CRC Press, 2020. http://dx.doi.org/10.1201/9781003138327-2.

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Rösch, L. "From Germyl-Alkali Metal Reagent with Lithium Aluminum Hydride." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145241.ch127.

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Tong, Colin. "Flexible Lithium–Sulfur and Analogous Alkali Metal–Chalcogen Batteries." In Springer Series in Materials Science. Springer Nature Switzerland, 2025. https://doi.org/10.1007/978-3-031-83971-9_5.

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Bartoli, Giuseppe, Marcella Bosco, Renato Dalpozzo, and Loris Grossi. "Polar Versus Electron Transfer Pathway in the Reaction of Alkyl Lithium and Alkyl Grignard Reagents with Mononttroarenes: Factors Affecting Product Distribution." In Paramagnetic Organometallic Species in Activation/Selectivity, Catalysis. Springer Netherlands, 1989. http://dx.doi.org/10.1007/978-94-009-0877-2_34.

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Nojima, M., and S. Kusabayashi. "Reaction of Alkyl Halides with Lithium and Magnesium Reagents. Nucleophilic Substitution vs. Single Electron Transfer." In Paramagnetic Organometallic Species in Activation/Selectivity, Catalysis. Springer Netherlands, 1989. http://dx.doi.org/10.1007/978-94-009-0877-2_35.

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Zagrtdenov, Nail R., Yves Thibault, Joanne Gamage McEvoy, and Dominique Duguay. "Synthetic Alkali Aluminosilicate-Hydroxide Systems as an Analogue to Optimize Lithium Recovery from LCT Pegmatites." In Rare Metal Technology 2024. Springer Nature Switzerland, 2024. http://dx.doi.org/10.1007/978-3-031-50236-1_16.

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Bochmann, Manfred. "Organometallic Compounds of Transition Metals." In Organometallics and Catalysis. Oxford University Press, 2014. http://dx.doi.org/10.1093/hesc/9780199668212.003.0002.

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This chapter looks at the synthesis of lithium. It emphasizes that lithium alkyls are made by reacting alkyl halides with lithium metal. The reaction is facilitated by a solvent that can stabilize the lithium ion, such as diethyl ether. The chapter also demonstrates the synthesis of lithium alkyls by transmetallation, then outlines the structure of lithium alkyls. As strong bases, lithium alkyls are used extensively for the deprotonation of C–H bonds. The addition of chelating donor ligands such as TMEDA has proved beneficial and greatly increases reactivity. Next, the chapter examines the ort

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Bochmann, Manfred. "Organometallic Compounds of Main Group Elements." In Organometallics and Catalysis. Oxford University Press, 2014. http://dx.doi.org/10.1093/hesc/9780199668212.003.0001.

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This chapter discusses the main group of organometallic compounds which contain metal–carbon σ-bonds generated by orbital overlap along the M–C axis. It reviews the possibility of interaction of the metal with the π-electron systems of unsaturated organic compounds, in particular, when the unsaturated moiety carries a negative charge. The chapter also looks at one important aspect that governs the reactivity of organometallic species: the polarity of the Mδ+ Cδ-bond. It explicates the nature of bond polarity, then studies the concept of electronegativity and ‘group electronegativity’. Towards

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Eysseltová, J., and M. Salomon. "Lithium Phosphate." In Alkali Metal Orthophosphates. Elsevier, 1988. http://dx.doi.org/10.1016/b978-0-08-035937-3.50007-x.

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Actes de conférences sur le sujet "Lithium alkyls"

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Clear, Kenneth C. "A “New”, High Current Output, Galvanic (Sacrificial) Anode, Electrochemical Rehabilitation System for Reinforced & Prestressed Concrete Structures." In CORROSION 1999. NACE International, 1999. https://doi.org/10.5006/c1999-99556.

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Abstract This paper summarizes 1995 through 1998 laboratory, outdoor exposure facility, and field data on the subject concrete “rehab” system. The system shows promise as a means of providing cathodic protection to the reinforcing, as a chloride removal process, as a re-alkalization process, and/or as a lithium injection procedure to minimize alkali-aggregate reactions in the concrete. Unique characteristics of the system include: Surrounding each galvanic anode with a highly corrosive liquid which maintains it (the anode) at peak output voltage throughout its life; andPlacing an ionic transfe

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Loubriel, G. M., T. A. Green, N. H. Tolk, and R. F. Haglund. "The Role of F-Centers in Electron- and Photon-Stimulated Desorption from Alkali Halides." In Microphysics of Surfaces, Beams, and Adsorbates. Optica Publishing Group, 1987. http://dx.doi.org/10.1364/msba.1987.wc9.

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Bienert, Walter B., Peter C. Cologer, Karen J. Fenzi, David A. Wolf, Mohamed S. El-Genk, and Mark D. Hoover. "Containment of Lithium Hydride in Alkali Metal Heat Pipes." In SPACE NUCLEAR POWER AND PROPULSION: Eleventh Symposium. AIP, 1994. http://dx.doi.org/10.1063/1.2950295.

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Saldin, Vitaly, and Vasily Sukhovey. "Study of alkali tetrahydroborate—lithium tetrafluoroborate mixtures at heating." In International Conference on Environment and Sustainability. WIT Press, 2014. http://dx.doi.org/10.2495/ices140091.

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"Lithium alkali halides - New thermal neutron detectors with n-γ discrimination." In 2013 IEEE Nuclear Science Symposium and Medical Imaging Conference (2013 NSS/MIC). IEEE, 2013. http://dx.doi.org/10.1109/nssmic.2013.6829581.

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Albers, Dylan, and Mileva Radonjic. "Prevention of Alkali-Silica Reaction (ASR) in Light-Weight Wellbore Cement Comprising Silicate-Based Microspheres." In ASME 2017 36th International Conference on Ocean, Offshore and Arctic Engineering. American Society of Mechanical Engineers, 2017. http://dx.doi.org/10.1115/omae2017-62015.

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Drilling through low pressure formations, either offshore or through depleted formations, requires the use of low density fluids to prevent lost circulation and as well as to properly place cement during cementing applications. Achieving these densities in cements can be done through foaming the cement, increasing water content, or through the addition of silica based microspheres. Each of these methods have individual limitations, and in the case of silica based microspheres, their specific fallback is a chemical instability with the microsphere itself reacting with the cement pore fluid. Thi

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D’Hooghe, Matthias, and Norbert De Kimpe. "Reactivity of 1-arenesulfonyl- and 1-alkyl-2-(bromomethyl)aziridines towards Lithium Cuprate Reagents." In The 9th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2005. http://dx.doi.org/10.3390/ecsoc-9-01474.

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M. Prasad, Abhilash, Elena Torres, Nandhini Raju, et al. "Investigation of SPS Tungsten-Lithium Heat Pipe for Primary Heat Exchanger Applications." In ASME Turbo Expo 2024: Turbomachinery Technical Conference and Exposition. American Society of Mechanical Engineers, 2024. http://dx.doi.org/10.1115/gt2024-122070.

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Abstract The demand to reduce carbon emissions and establish sustainable sources of clean energy has increased the interest infusion reactors. Fusion reactors are devices that generate enormous amounts of energy. The result of the thermal energy needs to be transported to improve the reliability and safety of the reactor. One of the potential solutions is a heat pipe. Heat pipes are devices that can efficiently transport heat as well as cool the core of the reactor. Also, it helps for power generation by integrating it with power cycles. In this research, an alkali metal heat pipe, and a Super

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Mohd, Isneini, Sagawa Yasutaka, Hamada Hidenori, and Daisuke Yamamoto. "An experimental study on mitigating alkali silica reaction by using lithium hydroxide monohydrate." In PROCEEDINGS OF THE 3RD INTERNATIONAL CONFERENCE ON CONSTRUCTION AND BUILDING ENGINEERING (ICONBUILD) 2017: Smart Construction Towards Global Challenges. Author(s), 2017. http://dx.doi.org/10.1063/1.5011512.

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"Practical Implications of Lithium-Based Chemicals and Admixtures in Controlling Alkali-Aggregate Reactions." In SP-148: Fourth CANMET/ACI International Conference on Superplasticizers and chemical admixtures in Concrete. American Concrete Institute, 1994. http://dx.doi.org/10.14359/4111.

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Rapports d'organisations sur le sujet "Lithium alkyls"

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Ullrich, Steven. Synthesis and Characterization of some Flourine-containing Lithium Alkyl Sulfonates: Flourinated Sulfonates and SF5-containing Sulfonates. Portland State University Library, 2000. http://dx.doi.org/10.15760/etd.6756.

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Hsu, H. S., J. H. DeVan, and M. Howell. Equilibrium solubilities of LiFeO/sub 2/ and (Li,K)/sub 2/CrO/sub 4/ in molten alkali carbonates at 650/sup 0/C. [Lithium and potassium chromates]. Office of Scientific and Technical Information (OSTI), 1986. http://dx.doi.org/10.2172/5279867.

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