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Articles de revues sur le sujet « Ruthenium phosphide nanoparticles »

Auteur : Grafiati

Publié le 10 mars 2023

Mis à jour le 19 juillet 2025

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1

Guo, Long, Fang Luo, Fei Guo, et al. "Robust hydrogen evolution reaction catalysis by ultrasmall amorphous ruthenium phosphide nanoparticles." Chemical Communications 55, no. 53 (2019): 7623–26. http://dx.doi.org/10.1039/c9cc03675j.

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Si, Chong-Dian, Ze-Xing Wu, Jing Wang, Zhi-Hua Lu, Xiu-Feng Xu, and Ji-Sen Li. "Enhanced the Hydrogen Evolution Performance by Ruthenium Nanoparticles Doped into Cobalt Phosphide Nanocages." ACS Sustainable Chemistry & Engineering 7, no. 11 (2019): 9737–42. http://dx.doi.org/10.1021/acssuschemeng.9b00817.

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3

Wang, Jing, Yuzhe Cao, Mingyang Wei, et al. "Boosting the Hydrogen Evolution Performance of Ultrafine Ruthenium Electrocatalysts by a Hierarchical Phosphide Array Promoter." Catalysts 14, no. 8 (2024): 491. http://dx.doi.org/10.3390/catal14080491.

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Tuning the chemical and structural environment of Ru-based nanomaterials is a major challenge for achieving active and stable hydrogen evolution reaction (HER) electrocatalysis. Here, we anchored ultrafine Ru nanoparticles (with a size of ~4.2 nm) on a hierarchical Ni2P array (Ru/Ni2P) to enable highly efficient HER. The Ni2P promoter weakened the adsorption of proton on Ru sites by accepting electrons from Ru nanoparticles. Moreover, the hierarchical Ni2P endowed Ru catalysts with a large surface area and stable open structure. Consequently, the as-fabricated Ru/Ni2P electrode displayed a low

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4

Guan, Xiya, Yu Sun, Simeng Zhao, et al. "Selectively nucleotide‐derived RuP on N,P‐codoped carbon with engineered mesopores for energy‐efficient hydrogen production assisted by hydrazine oxidation." SusMat 4, no. 1 (2024): 166–77. http://dx.doi.org/10.1002/sus2.186.

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AbstractIntegrating hydrogen evolution reaction (HER) with hydrazine oxidation reaction (HzOR) has an encouraging prospect for the energy‐saving hydrogen production, demanding the high‐performance bifunctional HER/HzOR electrocatalyst. Ruthenium phosphide/doped carbon composites have exhibited superior activity toward multiple electrocatalytic reactions. To explore the decent water‐soluble precursors containing both N and P elements is highly attractive to facilely prepare metal phosphide/doped carbon composites. Herein, as one kind ecofriendly biomolecules, adenine nucleotide was first employ

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Liu, Xiaofei, Yanglong Guo, Wangcheng Zhan, and Tian Jin. "Ball Milling-Assisted Synthesis of Ultrasmall Ruthenium Phosphide for Efficient Hydrogen Evolution Reaction." Catalysts 9, no. 3 (2019): 240. http://dx.doi.org/10.3390/catal9030240.

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The development of scalable hydrogen production technology to produce hydrogen economically and in an environmentally friendly way is particularly important. The hydrogen evolution reaction (HER) is a clean, renewable, and potentially cost-effective pathway to produce hydrogen, but it requires the use of a favorable electrocatalyst which can generate hydrogen with minimal overpotential for practical applications. Up to now, ruthenium phosphide Ru2P has been considered as a high-performance electrocatalyst for the HER. However, a tedious post-treatment method as well as large consumption of sol

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6

Xiao, X., X. Wang, B. Li, et al. "Regulating the electronic configuration of ruthenium nanoparticles via coupling cobalt phosphide for hydrogen evolution in alkaline media." Materials Today Physics 12 (March 2020): 100182. http://dx.doi.org/10.1016/j.mtphys.2020.100182.

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7

Luo, Qian, Caili Xu, Qian Chen, et al. "Synthesis of ultrafine ruthenium phosphide nanoparticles and nitrogen/phosphorus dual-doped carbon hybrids as advanced electrocatalysts for all-pH hydrogen evolution reaction." International Journal of Hydrogen Energy 44, no. 47 (2019): 25632–41. http://dx.doi.org/10.1016/j.ijhydene.2019.08.028.

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8

Wu, Zhifeng, and Heyan Jiang. "Efficient palladium and ruthenium nanocatalysts stabilized by phosphine functionalized ionic liquid for selective hydrogenation." RSC Advances 5, no. 44 (2015): 34622–29. http://dx.doi.org/10.1039/c5ra01893e.

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Bresó-Femenia, Emma, Cyril Godard, Carmen Claver, Bruno Chaudret, and Sergio Castillón. "Selective catalytic deuteration of phosphorus ligands using ruthenium nanoparticles: a new approach to gain information on ligand coordination." Chemical Communications 51, no. 91 (2015): 16342–45. http://dx.doi.org/10.1039/c5cc06984j.

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Selective deuteration of phenyl rings in phenyl-alkyl phosphines, including diphosphines, was achieved using Ru/PVP nanoparticles and D<sub>2</sub>, which enables the comprehension of how different phosphorus ligands coordinate to the nanoparticle surface.

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Jiang, He-yan, and Xu-xu Zheng. "Tuning the chemoselective hydrogenation of aromatic ketones, aromatic aldehydes and quinolines catalyzed by phosphine functionalized ionic liquid stabilized ruthenium nanoparticles." Catalysis Science & Technology 5, no. 7 (2015): 3728–34. http://dx.doi.org/10.1039/c5cy00293a.

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Ma, Ge, Na Yang, Yafei Xue, Guofu Zhou, and Xin Wang. "Ethylene Glycol Electrochemical Reforming Using Ruthenium Nanoparticle-Decorated Nickel Phosphide Ultrathin Nanosheets." ACS Applied Materials & Interfaces 13, no. 36 (2021): 42763–72. http://dx.doi.org/10.1021/acsami.1c10971.

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12

González-Gálvez, David, Pau Nolis, Karine Philippot, Bruno Chaudret, and Piet W. N. M. van Leeuwen. "Phosphine-Stabilized Ruthenium Nanoparticles: The Effect of the Nature of the Ligand in Catalysis." ACS Catalysis 2, no. 3 (2012): 317–21. http://dx.doi.org/10.1021/cs200633k.

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13

Sun, Peng, Xiangdong Long, Hao He, Chungu Xia, and Fuwei Li. "Conversion of Cellulose into Isosorbide over Bifunctional Ruthenium Nanoparticles Supported on Niobium Phosphate." ChemSusChem 6, no. 11 (2013): 2190–97. http://dx.doi.org/10.1002/cssc.201300701.

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14

Alassad, Nebal, Ravindra S. Phatake, Mark Baranov, Ofer Reany, and N. Gabriel Lemcoff. "Tuning the Latency by Anionic Ligand Exchange in Ruthenium Benzylidene Phosphite Complexes." Catalysts 13, no. 11 (2023): 1411. http://dx.doi.org/10.3390/catal13111411.

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Recently discovered cis-dichloro benzylidene phosphite complexes are latent catalysts at room temperature and exhibit exceptional thermal and photochemical activation behavior in olefin metathesis reactions. Most importantly, the study of these catalysts has allowed their introduction in efficient 3-D printing applications of ring-opening metathesis derived polymers and the control of chromatically orthogonal chemical processes. Moreover, their combination with plasmonic Au-nanoparticles has given rise to novel smart materials that are responsive to light. Given the importance of the ligand sh

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15

Ganji, Prasad, та Piet W. N. M. van Leeuwen. "Phosphine Supported Ruthenium Nanoparticle Catalyzed Synthesis of Substituted Pyrazines and Imidazoles from α-Diketones". Journal of Organic Chemistry 82, № 3 (2017): 1768–74. http://dx.doi.org/10.1021/acs.joc.6b03032.

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16

Gutmann, Torsten, Eric Bonnefille, Hergen Breitzke, et al. "Investigation of the surface chemistry of phosphine-stabilized ruthenium nanoparticles – an advanced solid-state NMR study." Physical Chemistry Chemical Physics 15, no. 40 (2013): 17383. http://dx.doi.org/10.1039/c3cp52927d.

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17

Durap, Feyyaz, Salim Caliskan, Saim Özkar, Kadir Karakas, and Mehmet Zahmakiran. "Dihydrogen Phosphate Stabilized Ruthenium(0) Nanoparticles: Efficient Nanocatalyst for The Hydrolysis of Ammonia-Borane at Room Temperature." Materials 8, no. 7 (2015): 4226–38. http://dx.doi.org/10.3390/ma8074226.

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18

Zhang, Ge, Jingwen Liu, Chengying Liu, et al. "Phosphate Group-Derivated Bipyridine–Ruthenium Complex and Titanium Dioxide Nanoparticles for Electrochemical Sensing of Protein Kinase Activity." ACS Sensors 6, no. 12 (2021): 4451–60. http://dx.doi.org/10.1021/acssensors.1c01908.

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19

Sun, Peng, Xiangdong Long, Hao He, Chungu Xia, and Fuwei Li. "Back Cover: Conversion of Cellulose into Isosorbide over Bifunctional Ruthenium Nanoparticles Supported on Niobium Phosphate (ChemSusChem 11/2013)." ChemSusChem 6, no. 11 (2013): 2198. http://dx.doi.org/10.1002/cssc.201301044.

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20

Sodreau, Alexandre, Hooman Ghazi Zahedi, Rıza Dervişoğlu, et al. "A Simple and Versatile Approach for the Low‐Temperature Synthesis of Transition Metal Phosphide Nanoparticles from Metal Chloride Complexes and P(SiMe₃)₃." Advanced Materials, September 28, 2023. http://dx.doi.org/10.1002/adma.202306621.

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AbstractMetal chloride complexes react with tris(trimethylsilyl)phosphine under mild condition to produce metal phosphide nanoparticles, and chlorotrimethylsilane as a byproduct. The formation of Si‐Cl bonds that are stronger than the starting M‐Cl bonds acts as a driving force for the reaction. The potential of this strategy is illustrated through the preparation of ruthenium phosphide nanoparticles using [RuCl2(cymene)] and tris(trimethylsilyl)phosphine at 35°C. Characterization with a combination of techniques including electron microscopy, X‐ray absorption spectroscopy, and solid‐state NMR

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21

Popp, Lukas, Philipp Kampe, Birk Fritsch, et al. "Supported ruthenium phosphide as a promising catalyst for selective hydrogenation of sugars." European Journal of Inorganic Chemistry, April 26, 2024. http://dx.doi.org/10.1002/ejic.202400117.

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This work demonstrates that ruthenium phosphides (RuP2) are attractive catalysts for selective production of alditols by sugar hydrogenation. In our studies, carbon supported RuP2 with a ruthenium content of 5 wt.‐% led to the highest activity in xylose hydrogenation and to nearly 100 % yield for xylitol. ICP‐OES and XRD measurements revealed the stability of this novel RuP2/C catalyst under typical hydrogenation conditions (50 barH2, 120 °C) in aqueous phase. Furthermore, STEM‐EDX illustrated the close proximity of ruthenium and phosphorous on the catalyst site and the formation of nanopartic

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22

"Sulfur-Tolerant Reductive Amination by Ruthenium Phosphide Nanoparticles Supported on Carbon." Synfacts 20, no. 07 (2024): 0737. http://dx.doi.org/10.1055/s-0043-1774876.

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23

"Ruthenium Phosphide Nanoparticles Supported on SiO2 for Hydrogenation of Sulfur-Containing Nitroarenes." Synfacts 19, no. 07 (2023): 0705. http://dx.doi.org/10.1055/s-0042-1752603.

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24

Abu Sufyan, Sayed, Paul F. Oblad, Brian van Devener, et al. "Bio‐inspired In Situ Tuning of the Hydrophobic Environment Around Catalytically Active Organic Ligand‐Stabilized Ruthenium Nanoparticles." ChemCatChem, February 22, 2025. https://doi.org/10.1002/cctc.202500275.

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The organic ligand environment surrounding enzymatic and homogeneous catalytic active sites often determines catalytic activity. Ruthenium nanoparticles, ≤ 1 nm in diameter, are synthesized using monodentate thiol, monodentate phosphine, and bidentate bisphosphine ligands. Even though some of the ruthenium surface is blocked by the ligands, catalytic activity is still observed for CO oxidation and H2O2 decomposition. All three ligand‐stabilized ruthenium nanoparticles have similar CO oxidation rates; however, the bisphosphine‐stabilized Ru nanoparticles are approximately 2.5 times less active

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25

Dmowski, Wojtek, Takeshi Egami, Karen E. Swider-Lyons, Wen-Fu Yan, Sheng Dai, and Steven H. Overbury. "Local atomic structure in disordered and nanocrystalline catalytic materials." Zeitschrift für Kristallographie - Crystalline Materials 222, no. 11/2007 (2007). http://dx.doi.org/10.1524/zkri.2007.222.11.617.

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The power of the atomic pair density function method to study the local atomic structure of dispersed materials is discussed for three examples (I) supercapacitor hydrous ruthenia, (II) electroctalyst platinum-iron phosphate and (III) nanoparticle gold catalyst. Hydrous ruthenia appears to be amorphous, but was found to be nanocomposite with RuO

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26

Li, Yanqiang, Xuan Liu, Junlong Xu, and Siru Chen. "Ruthenium‐Based Electrocatalysts for Hydrogen Evolution Reaction: from Nanoparticles to Single Atoms." Small, July 27, 2024. http://dx.doi.org/10.1002/smll.202402846.

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AbstractBenefiting from similar hydrogen bonding energy to Pt and much lower price compare with Pt, Ru based catalysts are promising candidates for electrocatalytic hydrogen evolution reaction (HER). The catalytic activity of Ru nanoparticles can be enhanced through improving their dispersion by using different supports, and the strong metal supports interaction can further regulate their catalytic performance. In addition, single‐atom catalysts (SACs) with almost 100% atomic utilization attract great attention and the coordinative atmosphere of single atoms can be adjusted by supports. Moreov

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27

Doherty, S., J. G. Knight, T. Backhouse, et al. "Highly efficient and selective aqueous phase hydrogenation of aryl ketones, aldehydes, furfural and levulinic acid and its ethyl ester catalyzed by phosphine oxide-decorated polymer immobilized ionic liquid-stabilized ruthenium nanoparticles." Catalysis Science & Technology, 2022. http://dx.doi.org/10.1039/d2cy00205a.

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Phosphine oxide-decorated polymer immobilized ionic liquid stabilized RuNPs catalyse the hydrogenation of aryl ketones with remarkable selectivity for the CO bond, complete hydrogenation to the cyclohexylalcohol and hydrogenation of levulinic acid to γ-valerolactone.

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28

Paterson, Reece, Hussam Alharbi, Corinne Wills, et al. "Highly Efficient and Selective Reduction of Nitroarenes to N-Arylhydroxylamines Catalysed by Phosphine Oxide-Decorated Polymer Immobilized Ionic Liquid Stabilized Ruthenium Nanoparticles." SSRN Electronic Journal, 2022. http://dx.doi.org/10.2139/ssrn.4253029.

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29

Paterson, Reece, Husam Y. Alharbi, Corinne Wills, et al. "Highly Efficient and Selective Partial Reduction of Nitroarenes to N-Arylhydroxylamines Catalysed by Phosphine Oxide-Decorated Polymer Immobilized Ionic Liquid Stabilized Ruthenium Nanoparticles." Journal of Catalysis, November 2022. http://dx.doi.org/10.1016/j.jcat.2022.11.023.

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