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Littérature scientifique sur le sujet « Telechelic polymers »

Auteur : Grafiati

Publié le 4 juin 2021

Mis à jour le 6 septembre 2023

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Articles de revues sur le sujet "Telechelic polymers"

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Farah, Abdiaziz A., et William J. Pietro. « Telechelic poly(ε-caprolactones) with tethered mixed ligand ruthenium(II) chromophores ». Canadian Journal of Chemistry 82, n^o 5 (1 mai 2004) : 595–607. http://dx.doi.org/10.1139/v03-215.

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Well-characterized templates of polymer-forming ligands and their ruthenium tris(α,α′-diimine) initiators were utilized to divergently ring open an ε-caprolactone monomer. The same polymers were also obtained through the synthesis of quinoline and bipyridine diimine ligands incorporating poly(ε-caprolactone) (PCL) chains. These polymers contain vacant molecular recognition sites, enabling subsequent chelation of these macroligands to metal precursors. Both methods provided telechelic (ε-caprolactone) ruthenium(II)-centered polyesters of various hierarchy. Solution properties and thermal behaviour of such polyesters are described.Key words: redox polymers, poly(ε-caprolactone), telechelics, metalpolymer complexes, macroligands, ring-opening polymerization (ROP).

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Tezuka, Yasuyuki. « Telechelic polymers ». Progress in Polymer Science 17, n^o 3 (janvier 1992) : 471–514. http://dx.doi.org/10.1016/0079-6700(92)90022-q.

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Li, Song Tao, Dan Li et Chun Ju He. « Synthesis of Allyl Functionalized Telechelic PVP by Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization ». Materials Science Forum 789 (avril 2014) : 235–39. http://dx.doi.org/10.4028/www.scientific.net/msf.789.235.

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Telechelic polymers have been explored widely because they are precursors for preparing multi-block copolymers, grafted polymers, star polymers, and polymer networks [1-2]. A variety of telechelic polymers with terminals like hydroxy, carboxylic, epoxy groups and carbon–carbon double bond have been prepared by controlled radical polymerization (CRP) techniques including nitroxide-mediated polymerization (NMP), atom transfer radical polymerization (ATRP) and reversible addition-fragmentation chain transfer polymerization (RAFT)[3-5].The CRP techniques can not only control the molecular weight but also can be carried out in the presence of many functional groups from monomers, initiators, or chain transfer agents (CTA).

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Adrian Figg, C., Ashton N. Bartley, Tomohiro Kubo, Bryan S. Tucker, Ronald K. Castellano et Brent S. Sumerlin. « Mild and efficient synthesis of ω,ω-heterodifunctionalized polymers and polymer bioconjugates ». Polymer Chemistry 8, n^o 16 (2017) : 2457–61. http://dx.doi.org/10.1039/c7py00225d.

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Tasic, Aleksandra, Marija Pergal, Malisa Antic et Vesna Antic. « Synthesis, structure and thermogravimetric analysis of α,ω-telechelic polydimethylsiloxanes of low molecular weight ». Journal of the Serbian Chemical Society 82, n^o 12 (2017) : 1395–416. http://dx.doi.org/10.2298/jsc170427082t.

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A series of ?,?-telechelic polydimethylsiloxanes (PDMS), with predetermined molecular weights of about 2500 g mol-1, was synthesized by siloxane equilibration reaction. Syntheses were performed using octamethylcyclotetrasiloxane (D4) and various disiloxanes: hexamethyldisiloxane (HMDS), 1,1,3,3-tetramethyldisiloxane (TMDS), 1,3-divinyltetramethyldisiloxane (DVTMDS), 1,3-bis(3-carboxypropyl)tetramethyldisiloxane (DCPTMDS) and 1,3-bis(3-aminopropyl)tetramethyldisiloxane (DAPTMDS). The role of the disiloxane was to introduce terminal functional groups at the end of the polymer chains and to control the molecular weight of the polymers. Polymers with trimethyl, hydrido, vinyl, carboxypropyl and aminopropyl end-groups were obtained in this way. The structure of the ?,?-telechelic PDMSs was confirmed by NMR and IR spectroscopy. The molecular weights of the polymers were determined by 1H-NMR, gel permeation chromatography (GPC) and dilute solution viscometry. Thermogravimetric analysis (TGA) under nitrogen and air showed that the type of the terminal groups significantly influenced the thermal and thermo-oxidative stability, as well as the degradation mechanism of the ?,?-telechelic PDMSs.

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Buss, Bonnie L., Logan R. Beck et Garret M. Miyake. « Synthesis of star polymers using organocatalyzed atom transfer radical polymerization through a core-first approach ». Polymer Chemistry 9, n^o 13 (2018) : 1658–65. http://dx.doi.org/10.1039/c7py01833a.

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Kumar, Aatish, Christopher P. Lowe, Martien A. Cohen Stuart et Peter G. Bolhuis. « Trigger sequence can influence final morphology in the self-assembly of asymmetric telechelic polymers ». Soft Matter 12, n^o 7 (2016) : 2095–107. http://dx.doi.org/10.1039/c5sm01453k.

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We report on a numerical study of polymer network formation of asymmetric biomimetic telechelic polymers with two reactive ends based on a self-assembling collagen, elastin or silk-like polypeptide sequence.

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Baudis, Stefan, Andreas Lendlein et Marc Behl. « Robot Assisted Synthesis and Characterization of Polyester-based Polyurethanes ». MRS Proceedings 1718 (2015) : 109–15. http://dx.doi.org/10.1557/opl.2015.493.

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ABSTRACTDihydroxy telechelics are precursors for the synthesis of multiblock copolymers. In order to synthesize high molecular weight polymers with good elastic properties it is necessary to gain detailed knowledge of the reaction behavior of these precursors. Therefore it was explored whether the polyaddition reaction of polyester-diols can be established in a robotic synthesizer platform to facilitate the elucidation of reaction characteristics. A series of 16 reactions was performed using a telechelic polyester and trimethylhexamethylene diisocyanate. The chain extension behavior of the building block was compared with respect to the Carothers equation. It was found, that the chain extension behavior follows the expected trend. The molecular weight of the polymers increased when the optimal ratio of reactive groups was approached.

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Volianiuk, Kateryna, Nataliya Mitina, Nataliya Kinash, Khrystyna Harhay, Larysa Dolynska, Zoriana Nadashkevich, Orest Hevus et Alexander Zaichenko. « Telechelic Oligo(N-Vinylpyrolydone)swith Cumene Based Terminal Groups for Block-Copolymer and Nanoparticle Obtaining ». Chemistry & ; Chemical Technology 16, n^o 1 (20 février 2022) : 34–41. http://dx.doi.org/10.23939/chcht16.01.034.

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Polymers with terminal epoxy, phosphate, fluoroalkyl groups were obtained by radical polymerization in the presence of chain transfer agents derived from isopropylbenzene. The structure of polymers was confirmed by NMR spectra and functional analysis. Polymers with functional fragment were used for synthesis of polymer-inorganic particles and copolymers with poly(2-ethyl-2-oxazoline) fragment.

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Milner, Scott T., et Thomas A. Witten. « Bridging attraction by telechelic polymers ». Macromolecules 25, n^o 20 (septembre 1992) : 5495–503. http://dx.doi.org/10.1021/ma00046a057.

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Thèses sur le sujet "Telechelic polymers"

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Xu, Jinghui. « Field effect on Zwitterionic telechelic polymers (ZTPs) nanostructure ». Thesis, University of Oxford, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.437005.

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O'Bryan, Gregory J. « Preparation of telechelic polymers via nitroxide mediated polymerization / ». Diss., Digital Dissertations Database. Restricted to UC campuses, 2007. http://uclibs.org/PID/11984.

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Torron, Timhagen Susana. « Telechelic polymers derived from natural resources as building blocks for polymer thermosets ». Licentiate thesis, KTH, Ytbehandlingsteknik, 2015. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-162128.

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Warwick, Michelle. « Association in mixed telechelic polymers through charge transfer interaction ». Thesis, Heriot-Watt University, 1995. http://hdl.handle.net/10399/741.

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Pfukwa, Rueben. « Synthesis and characterization of telechelic hydroxyl functional poly (N-vinylpyrrolidone) ». Thesis, Link to the online version, 2008. http://hdl.handle.net/10019/890.

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Shohi, Hajime. « SYNTHESIS OF TELECHELIC AND TRI-ARMED POLYMERS BY LIVING CATIONIC POLYMERIZATION ». Kyoto University, 1992. http://hdl.handle.net/2433/168764.

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本文データは平成22年度国立国会図書館の学位論文(博士)のデジタル化実施により作成された画像ファイルを基にpdf変換したものである
Kyoto University (京都大学)
0048
新制・論文博士
博士(工学)
乙第7878号
論工博第2588号
新制||工||878(附属図書館)
UT51-92-K378
(主査)教授東村敏延, 教授今西幸男, 教授宮本武明
学位規則第4条第2項該当

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Marin, Angel Juan Camilo. « Development of Ion-Containing Polymers and Study of their Molecular, Mechanical, and Flexoelectric Properties ». University of Akron / OhioLINK, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=akron1627232468950217.

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Barqawi, Haitham [Verfasser], Wolfgang H. [Akademischer Betreuer] Binder et Manfred [Akademischer Betreuer] Schmidt. « Multidimensional liquid chromatography coupled to soft ionization techniques : analysis of telechelic polymers ; [kumulative Dissertation] / Haitham Barqawi. Betreuer : Wolfgang H. Binder ; Manfred Schmidt ». Halle, Saale : Universitäts- und Landesbibliothek Sachsen-Anhalt, 2015. http://d-nb.info/1066645000/34.

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Billen, Joris. « Simulated Associating Polymer Networks ». Scholarship @ Claremont, 2012. http://scholarship.claremont.edu/cgu_etd/51.

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Telechelic associating polymer networks consist of polymer chains terminated by endgroups that have a different chemical composition than the polymer backbone. When dissolved in a solution, the endgroups cluster together to form aggregates. At low temperature, a strongly connected reversible network is formed and the system behaves like a gel. Telechelic networks are of interest since they are representative for biopolymer networks (e.g. F-actin) and are widely used in medical applications (e.g. hydrogels for tissue engineering, wound dressings) and consumer products (e.g. contact lenses, paint thickeners). In this thesis such systems are studied by means of a molecular dynamics/Monte Carlo simulation. At first, the system in rest is studied by means of graph theory. The changes in network topology upon cooling to the gel state, are characterized. Hereto an extensive study of the eigenvalue spectrum of the gel network is performed. As a result, an in-depth investigation of the eigenvalue spectra for spatial ER, scale-free, and small-world networks is carried out. Next, the gel under the application of a constant shear is studied, with a focus on shear banding and the changes in topology under shear. Finally, the relation between the gel transition and percolation is discussed.

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Lidster, Benjamin John. « Synthesis and characterisation of block copolymers and cyclic polymers containing poly(p-phenylenevinylene)s ». Thesis, University of Manchester, 2015. http://www.manchester.ac.uk/escholar/uk-ac-man-scw:247427.

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Conjugated organic polymers have attracted immense interest for use in the active layer of photovoltaic cells, electroluminescent displays and diagnostic sensors. Precise control of the chemical structure of these conjugated materials is essential to achieve better device performance and certain structural aspects which have received minimal investigation include; the nature of the end groups, the precise control of the molecular weight and the formation of novel polymer topologies. Absolute control of these factors, in particular the end groups, has the potential to further tune the electro-optical properties, eliminate charge trapping and reactive sites, and facilitate block copolymer formation. The ring opening metathesis polymerisation of highly strained cyclophanediene monomers has proven to be an advantageous route to obtain soluble poly(p-phenylenevinylene)s (PPVs). In an extension of this previous work PPVs with both a pristine polymer backbone microstructure and a range of well-defined functional end groups have been prepared. These polymers exhibited excellent degrees of functionality, relatively narrow unimodal distributions and degrees of polymerisation much higher than those attainable by alternate routes. In particular the incorporation of an α-bromoester end group directly resulted in PPVs which were effective macroinitiators in the atom transfer radical polymerisation of methyl methacrylate. The diblock copolymers prepared by this route were isolated with narrow polydispersities, unimodal distributions and were free from homopolymer impurities. This method of preparing rod-b-coil diblock copolymers, where the properties of the two segments can readily be modified, provides access to materials which are of interest for both their self-assembly ability and for the development of a much required phase diagram in this area. Cyclic PPVs are of synthetic interest both for the absence of any end groups and for an infinitely long π-conjugated backbone, both of which are expected to contribute to unique electro-optical properties. The preparation of these target polymers was investigated by the ring expansion metathesis polymerisation of the cyclophanediene monomers. The formation of purely cyclic, low molecular weight PPVs was found to be highly dependent on both the reaction conditions used and the nature of the solubilising substituents. For example the preparation of purely cyclic PPVs with alkoxy side chains was unsuccessful, however the incorporation of alkyl side chains allowed for the successful isolation of the desired cyclic polymers.

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Livres sur le sujet "Telechelic polymers"

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J, Goethals E., dir. Telechelic polymers : Synthesis and applications. Boca Raton, Fla : CRC Press, 1989.

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Goethals, Eric J. Telechelic Polymers : Synthesis and Applications. Taylor & Francis Group, 2018.

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Goethals, Eric J. Telechelic Polymers : Synthesis and Applications. Sous la direction de Eric J. Goethals. CRC Press, 2018. http://dx.doi.org/10.1201/9781351077095.

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Goethals, Eric J. Telechelic Polymers : Synthesis and Applications. Taylor & Francis Group, 2018.

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Goethals, Eric J. Telechelic Polymers : Synthesis and Applications. Taylor & Francis Group, 2018.

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Goethals, Eric J. Telechelic Polymers : Synthesis and Applications. Taylor & Francis Group, 2018.

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Goethals, Eric J. Telechelic Polymers : Synthesis and Applications. CRC Press, 1988.

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Telechelic Polymers : Synthesis and Applications. Taylor & Francis Group, 2017.

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Handbook of Telechelic Polyesters, Polycarbonates, and Polyethers . Taylor & Francis Group, 2017.

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Guillaume, Sophie M. Handbook of Telechelic Polyesters, Polycarbonates, and Polyethers. Jenny Stanford Publishing, 2017.

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Chapitres de livres sur le sujet "Telechelic polymers"

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Gooch, Jan W. « Telechelic Polymers ». Dans Encyclopedic Dictionary of Polymers, 731. New York, NY : Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_11598.

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Hanik, Nils, et Andreas F. M. Kilbinger. « Telechelic Polymers ». Dans Handbook of Metathesis, 44–70. Weinheim, Germany : Wiley-VCH Verlag GmbH & Co. KGaA, 2015. http://dx.doi.org/10.1002/9783527674107.ch29.

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Jerome, R. « Halato-Telechelic Polymers as Models of Ion-Containing Polymers and Thermoreversible Polymer Networks ». Dans Integration of Fundamental Polymer Science and Technology, 242–45. Dordrecht : Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-4185-4_33.

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Yekta, Ahmad, Bai Xu et Mitchell A. Winnik. « The Structure of Telechelic Associating Polymers in Water ». Dans Solvents and Self-Organization of Polymers, 319–30. Dordrecht : Springer Netherlands, 1996. http://dx.doi.org/10.1007/978-94-009-0333-3_15.

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Entelis, S. G., V. V. Evreinov et A. V. Gorshkov. « Functionality and molecular weight distribution of Telechelic polymers ». Dans Advances in Polymer Science, 129–75. Berlin, Heidelberg : Springer Berlin Heidelberg, 1986. http://dx.doi.org/10.1007/3-540-15830-8_4.

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Lai, John, Dave Egan, Raymond Hsu, Carole Lepilleur, Alex Lubnin, Anthony Pajerski et Ronald Shea. « Applications of Telechelic Reversible Addition Fragmentation Chain Transfer Polymers ». Dans ACS Symposium Series, 547–63. Washington, D C : American Chemical Society, 2006. http://dx.doi.org/10.1021/bk-2006-0944.ch037.

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Kricheldorf, Hans R., Olaf Stöber, Gerd Löhden, Thomas Stuckenbrock et Dierk Lübbers. « Syntheses of Telechelic, Star-Shaped, and Hyperbranched Aromatic Polyesters ». Dans Step-Growth Polymers for High-Performance Materials, 156–85. Washington, DC : American Chemical Society, 1996. http://dx.doi.org/10.1021/bk-1996-0624.ch009.

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Jérôme, R. « Gelation and Phase Separation of Solutions of Halato Telechelic Polymers ». Dans Structure and Properties of Ionomers, 399–414. Dordrecht : Springer Netherlands, 1987. http://dx.doi.org/10.1007/978-94-009-3829-8_32.

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Indei, Tsutomu. « Effects of Surfactants on the Linear Rheology of Telechelic Associating Polymers ». Dans Gels : Structures, Properties, and Functions, 23–29. Berlin, Heidelberg : Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-00865-8_4.

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Vlaic, Gilberto. « The Exafs Spectroscopy Applied to the Ionic Aggregates of Halato-Telechelic Polymers ». Dans Structure and Properties of Ionomers, 51–72. Dordrecht : Springer Netherlands, 1987. http://dx.doi.org/10.1007/978-94-009-3829-8_5.

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Actes de conférences sur le sujet "Telechelic polymers"

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Hasegawa, Makoto, Nanae Kobayashi, Yoshiyuki Kohno et Hiroshi Ando. « An Experimental Study on Contact Resistance Characteristics of Relay Contacts Operated in the Vicinity of New Telechelic Polyacrylate Polymers ». Dans 2012 IEEE 58th Holm Conference on Electrical Contacts (Holm 2012). IEEE, 2012. http://dx.doi.org/10.1109/holm.2012.6336570.

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