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1

Ochinero, Tomoya Thomas. « Deformations of Unsymmetric Composite Panels ». Diss., Virginia Tech, 2001. http://hdl.handle.net/10919/29375.

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This work discusses the deformations of various unsymmetric composite panels due to thermal and mechanical loads. Chapter 2 focuses on the warpage of large unsymmetric curved composite panels due manufacturing anomalies. These panels are subjected to a temperature change of -280°F to simulate the cooling from the autoclave cure temperature. Sixteen layer quasi-isotropic, axial-stiff, and circumferentially-stiff laminates are considered. These panels are intended to be symmetric laminates, but are slightly unsymmetric due to the manufacturing anomalies. Rayleigh-Ritz and finite-element models are developed to predict the deformations. Initially, to serve as a basis for comparison, warpage effects due to orthotropic thermal expansion properties in perfect panels are investigated and are found to produce deformations not captured in two-dimensional theories. This is followed by the investigation of the effects of ply misalignments. Ply misalignments of 5° are incorporated into the laminate, one layer at a time, to produce unsymmetric laminates. It is found that ply misalignments produce warpages much larger than those induced by orthotropic thermal expansion properties. Next, unsymmetric laminates resulting from ply thickness variations are investigated. Layers 10% thicker than nominal are incorporated into the laminate, one layer at a time, while the remaining layers are of uniform thickness. Due to the change in fiber volume fraction of the thicker layers, corresponding material properties are modified to reflect this change. The results show that ply thickness variations cause warpages of about 25-50% of those induced by ply misalignments. Finally, warpage of panels due to nonuniform cooling due to inplane thermal gradients during cure is investigated. A thermal gradient of 0.1°F/in. is used to construct six inplane distributions. It is found that the warpages induced by thermal gradients are very small. The warpages are negligible with respect to those induced by ply thickness variations or ply misalignments. Deformations induced by thermal gradients depend primarily on the magnitude of the thermal gradient, but not on the pattern of distribution. Overall, ply misalignments cause the most warpage, followed by ply thickness variations. Important variables for these imperfections are, the through-thickness location of the imperfections, the orientation of the layer containing the imperfections, and the lamination sequence. All cases show that geometric nonlinearities are important to accurately predict the deformations induced by these imperfections. Chapter 3 discusses the deformations of composite plates that are intentionally fabricated to be unsymmetric. Such plates, if flat, might be considered in applications where bending-stretching coupling effects can be used to advantage. It is assumed the laminates are cured at an elevated temperature and then cooled 280°F. Significant deformations result because of the high level of asymmetry in the laminate construction. Accordingly, geometric nonlinearities are included in the models. Four cross-ply laminates and three angle-ply laminates are considered. Four-term and 14-term Rayleigh-Ritz models are developed, together with finite-element models to model the deformations. Actual specimens were constructed and the deformations measured to compare with predictions. The results show that agreement between predictions and the experimental results are good. The 14-term Rayleigh-Ritz model is found to be the most useful due to its ability to find multiple solutions, its physical basis, and computational efficiency. Chapter 4 discusses the deformations of initially flat aluminum, symmetric, and unsymmetric composite plates due to axial endshortening under various boundary conditions, the aluminum and symmetric plates serving as a baseline. Seven plates are considered, each with three boundary condition combinations, namely, clamped ends and sides (CL-CL), clamped ends with simply-supported sides (CL-SS), and simply-supported ends and sides (SS-SS). Generally, the boundary conditions play a key role in the deformation characteristics of the plates. The aluminum and symmetric cross-ply plates have no out-of-plane deformations until classic buckling, or primary instability, then each exhibits two stable solutions. Each also exhibits secondary instability that results in two stable solutions. The symmetric laminates show less of a dependence on the boundary conditions compared to the unsymmetric laminates. Unsymmetric laminates show a mixture of characteristics. Some cases exhibit primary instability, other cases do not. Some cases exhibit secondary instability, while some case do not. The unsymmetric cross-ply laminates have only one stable solution after secondary buckling, while most other laminates and boundary condition combinations have two stable solutions. It is interesting to note that for the unbalanced unsymmetric [302/90/0]2T laminate, the boundary conditions controlled the sign of the out-of-plane deflection from the onset of axial endshortening. Generally speaking, the CL-CL cases carry the most load, followed by the CL-SS, and then the SS-SS cases. Like all the problems discussed in Chapter 2 and 3, geometric nonlinearities are found to be important for this case as well.
Ph. D.
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2

Lamb, Brian Mathew. « Formation of unsymmetric 1-acyl-6-hydroxy fulvenes and high acylation selectivity of unsymmetric cyclopentapyridazines ». [Gainesville, Fla.] : University of Florida, 2006. http://purl.fcla.edu/fcla/etd/UFE0015840.

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3

Haque, Shabana R. « Unsymmetric dinucleating ligands as metallobiosite models ». Thesis, University of Sheffield, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.299573.

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4

Dano, Marie-Laure. « SMA-Induced Deformations In general Unsymmetric Laminates ». Diss., Virginia Tech, 1997. http://hdl.handle.net/10919/30390.

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General unsymmetric laminates exhibit large natural curvatures at room temperature. Additionally, inherent to most unsymmetric laminates is the presence of two stable configurations. Multiple configurations and stability issues arise because of the geometric nonlinearities associated with the large curvatures. The laminate can be changed from one stable configuration to the other by a simple snap-through action. This situation offers the opportunity to use shape memory alloys (SMA) attached to the laminate to generate the snap-through forces and change the shape of the laminate on command. Presented is a model which can predict SMA-induced deformations in general unsymmetric laminates and, particularly, the occurrence of the snap through. First, a methodology is developed to predict the deformations of flat general unsymmetric epoxy-matrix composite laminates as they are cooled from their elevated cure temperature. Approximations to the strain fields are used in the expression for the total potential energy, and the Rayleigh-Ritz approach is used to study equilibrium. To further study the laminate deformations, finite-element analyses are performed. Experimental results are presented which confirm the predictions of the developed theory and the finite-element analyses regarding the existence of multiple solutions and the magnitude of the deformations. Results are compared with those of several other investigators. Next, the deformation behavior of general unsymmetric laminates subjected to applied forces is studied. The principle of virtual work is used to derive the equilibrium equations relating the laminate deformations to the applied forces. By solving the equilibrium equations as a function of the force level, relations between the laminate deformations and the applied force are derived, and the force level at which the laminate changes shape is determined. Finally, an existing SMA constitutive model is implemented into the developed theory to predict the deformations of simple structures to SMA-induced forces. Experiments on a narrow aluminium plate with an externally attached SMA actuator are conducted. The experimental results show good agreement with the predictions from the developed theory. Next, the deformation behavior of general unsymmetric laminates subjected to SMA actuators is predicted using the developed theory. Experiments using SMA actuators to generate the snap through of nsymmetric laminates are conducted. Good correlation with the developed theory is obtained.
Ph. D.
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5

Dano, Marie-Laure. « SMA-induced deformations in unsymmetric cross-ply laminates ». Thesis, This resource online, 1993. http://scholar.lib.vt.edu/theses/available/etd-09122009-040504/.

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6

Adhikari, Narayan Prasad. « Interfacial properties and phase behavior of unsymmetric polymer blends ». [S.l. : s.n.], 2001. http://deposit.ddb.de/cgi-bin/dokserv?idn=964276852.

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7

Werner, Ulrich [Verfasser]. « Rotordynamische Analyse von Asynchronmaschinen mit magnetischen Unsymmetrien / Ulrich Werner ». Aachen : Shaker, 2006. http://d-nb.info/1170538614/34.

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8

Palmer, David W. « The effect of internal delamination on unsymmetric laminated composite plates ». Diss., Georgia Institute of Technology, 1995. http://hdl.handle.net/1853/12021.

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9

Rentschler, Alexander. « Dynamisches Modell der Asynchronmaschine mit Berücksichtigung von Fehlern und Unsymmetrien / ». Aachen : Shaker, 2008. http://d-nb.info/991010523/04.

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10

Rivers, Antony David. « Unsymmetric dithiolene comlexes relevant to the tungsten centre in acetylene hydratase ». Thesis, University of Manchester, 2009. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.498858.

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11

Shah, A. A. « Iteractive methods for the solution of unsymmetric linear systems of equations ». Thesis, University of Kent, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.333045.

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12

Cortes, Maria Angeles Amela. « Synthesis and physical properties of unsymmetric main-chain liquid crystal elastomers ». Thesis, University of Exeter, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.438746.

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13

Schuchert, Andreas. « Verfahren der digitalen Kompensation von Unsymmetrien der analogen Quadraturmischung in OFDM-Empfängern ». [S.l. : s.n.], 2001. http://deposit.ddb.de/cgi-bin/dokserv?idn=963282212.

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14

Rentschler, Alexander [Verfasser]. « Dynamisches Modell der Asynchronmaschine mit Berücksichtigung von Fehlern und Unsymmetrien / Alexander Rentschler ». Aachen : Shaker, 2008. http://d-nb.info/1161306242/34.

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15

Jensen, David Warren. « Buckling and postbuckling behavior of unbalanced and unsymmetric laminated graphite/epoxy plates ». Thesis, Massachusetts Institute of Technology, 1986. http://hdl.handle.net/1721.1/15102.

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Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Aeronautics and Astronautics, 1986.
MICROFICHE COPY AVAILABLE IN ARCHIVES AND AERO
Bibliography: v.1, leaves 287-291.
by David Warren Jensen.
Ph.D.
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16

Schultz, Marc Robert. « Use of Piezoelectric Actuators to Effect Snap-Through Behavior of Unsymmetric Composite Laminates ». Diss., Virginia Tech, 2003. http://hdl.handle.net/10919/27086.

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As a new concept for morphing structures, the use of piezoelectric actuators to effect snap-through behavior of simple unsymmetric cross-ply composite laminates is examined. Many unsymmetric laminates have more than one stable room-temperature shape and can be snapped through from one stable shape to another. In this new concept for morphing structures, one or more piezoelectric actuators are bonded to unsymmetric laminates, and are then used to snap the laminate from one shape to another. The actuator would be used to change shape, but would not be required to maintain the shape. Using the Rayleigh-Ritz technique, several models are developed to predict the interaction between the base laminate and the actuator. In particular, the voltage (applied to the actuator) needed to snap the laminate is predicted. The NASA-LaRC Macro-Fiber Composite&174; (MFC&174;) actuator is chosen as the actuator of choice for this work. A laminate is manufactured, an actuator is bonded to the laminate, and experiments are performed. Since the agreement between the initial models and experimental results was not good, the models were revised. Good agreement between the predictions of the revised model and experiment is reached. Suggestions for future research directions are presented.
Ph. D.
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17

Witt, Timo [Verfasser]. « Unsymmetric, Macrocyclic, and Ultra Long-Chain α,ω-Difunctional Building Blocks from Plant Oils / Timo Witt ». Konstanz : KOPS Universität Konstanz, 2017. http://d-nb.info/1190565390/34.

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18

Majeed, Majed A. « Deformations of In-plane Loaded Unsymmetrically Laminated Composite Plates ». Diss., Virginia Tech, 2005. http://hdl.handle.net/10919/26309.

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This study focuses on the response of flat unsymmetric laminates to an inplane compressive loading that for symmetric laminates are of sufficient magnitude to cause bifurcation buckling, postbuckling, and secondary buckling behavior. In particular, the purpose of this study is to investigate whether or not the concept of bifurcation buckling is applicable to unsymmetric laminates. Past work by other researchers has suggested that such a concept is applicable for certain boundary conditions. The study also has as an objective the determination of the response of flat unsymmetric laminates if bifurcation buckling does not occur. The finite-element program ABAQUS is used to obtain results, and a portion of the study is devoted to becoming familiar with the way ABAQUS handles such highly geometrically nonlinear problems, particularly for composite materials and particularly when instabilities and dynamic behavior are involved. Familiarity with the problem, in general, and with the use of ABAQUS, in particular, is partially gained by considering semi-infinite unsymmetrically laminated cross- and angle-ply plates, a one-dimensional problem that can be solve in closed form and with ABAQUS by making the appropriate approximations for the infinite geometry. In this portion of the study it is found that semi-infinite cross-ply laminates with clamped boundary conditions and semi-infinite angle-ply plates with simple-support boundary conditions remain flat under a compressive load until the load magnitude reaches a certain level, at which time the out-of-plane deflection become indeterminate, essentially an eigenvalue problem as encountered with classic bifurcation buckling analyses. Obviously, a linear analysis of such problems would not reveal this behavior and, in fact, there are other revealed significant differences between the predictions of linear and nonlinear analyses. Transversely-loaded and inplane-loaded finite isotropic plates are studied by way of semi-closed form Rayleigh-Ritz-based solutions and ABAQUS in a step to approaching the problem with unsymmetric laminates. A method to investigate the unloading behavior of postbuckled finite isotropic plates is developed that reveal multiple plate configurations in the postbuckled region of the response, and this method is then extended to the study of finite inplane-loaded unsymmetric laminates. To that end, two specific laminates, a symmetric and an unsymmetric cross-ply laminates, and a variety of boundary conditions are used to study the response of inplane-loaded unsymmetric laminates. The symmetric laminate is included to provide a familiar baseline case and a means of comparison. Plates with all four edges clamped and a variety of inplane boundary conditions are studied. Of course the symmetric cross-ply laminate exhibits bifurcation behavior, and when the tangential displacement on the loaded edges and the normal displacement on the unloaded edges are restrained, secondary buckling behavior occurs. For the unsymmetric cross-ply laminate, bifurcation buckling behavior does not occur unless the tangential displacement on the loaded edges and the normal displacement on the unloaded edges are restrained, or the tangential displacement on the loaded edges and the normal displacement on the unloaded edges are free. If either of these conditions are not satisfied, the unsymmetric cross-ply laminate exhibits what could be termed 'near-bifurcation' behavior. In all cases rather complex behavior occurs for high levels of inplane load, including asymmetric postbuckling and secondary buckling behavior. For clamped loaded edges and simply-supported unloaded edges, bifurcation buckling behavior does not occur unless the tangential displacement on the loaded edges and the normal displacement on the unloaded edges are restrained. For this case, rather unusual asymmetric bifurcation and associated limit point behavior occur, as well as secondary buckling. This is a very interesting boundary condition case and is studied further for other unsymmetric cross-ply laminates, including the use of a Rayleigh-Ritz-based solution in attempt to quantify the problem parameters responsible for the asymmetric response. The overall results of the study have led to an increased understanding of the role of laminate asymmetry and boundary conditions on the potential for bifurcation behavior, on the response of the laminate for loads beyond that level.
Ph. D.
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19

Haas, Ruth Marlen [Verfasser], Corinna [Akademischer Betreuer] Hess, Corinna [Gutachter] Hess et Klaus [Gutachter] Köhler. « Unsymmetric Redoxactive Ligands for Mono- and Bimetallic Complexes ; Synthesis and Characterisation / Ruth Marlen Haas ; Gutachter : Corinna Hess, Klaus Köhler ; Betreuer : Corinna Hess ». München : Universitätsbibliothek der TU München, 2018. http://d-nb.info/1177241390/34.

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20

Esiringu, Ilker. « Intermolecular Addition Of Aldehydes To Ketones Via Acyl Phosphonates ». Master's thesis, METU, 2008. http://etd.lib.metu.edu.tr/upload/3/12609441/index.pdf.

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This thesis presents a new developed method for first intermolecular aldehyde/ketone cross benzoin coupling. Protected &
#945
-keto tertiary alcohols are synthesized starting from easily available acyl phosphonates and ketones via Brook rearrangement in the presence of catalytic amount of cyanide ion. The scopes and the limitations of the methods for the synthesis of tertiary alcohols with &
#945
-keto group are discovered.
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21

Grisel, Julien. « Des cyclobutanones chirales vers la (-)-Salinosporamide A ». Phd thesis, Université de Grenoble, 2012. http://tel.archives-ouvertes.fr/tel-00922996.

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Le travail présenté dans ce manuscrit concerne le développement d'une nouvelle voie d'accès à une famille de butyrolactames naturels à fort potentiel thérapeutique basé sur une réaction de cycloaddition [2+2] suivie d'une expansion de cycle. Dans la partie principale, une méthodologie permettant l'accès aux cyclobutanones hautement fonctionnalisées par cycloaddition [2+2] entre des éthers d'énols chiraux et divers cétènes fonctionnalisés a été développée. Avec cette méthodologie, diverses cyclobutanones ont pu être obtenues de façon hautement chimio-, régio- et stéréosélective. L'expansion de cycle sur les cyclobutanones préparées précédemment afin d'obtenir le squelette butyrolactame de la (-)-Salinosporamide A a ensuite été étudiée. La dernière partie de ce travail consiste en une étude de la réaction de cycloaddition [2+2] entre un cétène et un éther d'énol activée par un acide de Lewis présent en quantité catalytique. Cette première étude semble indiquer qu'une activation avec un acide de Lewis est possible lorsqu'un éther d'énol encombré est utilisé.
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22

Foulquier, Jérémie. « Kompensation von Oberschwingungen der Netzspannung durch eine „Intelligente Ladesäule“ am Smart Grid für Hybride- und Elektrofahrzeuge ». 2017. https://monarch.qucosa.de/id/qucosa%3A21434.

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An der Schnittstelle zwischen Elektrofahrzeug und dem Niederspannungsnetz nimmt die Ladesäule eine Schlüsselposition beim Ausbau von intelligenten Stromnetzen in Synergie mit der Elektromobilität ein. Durch die Entwicklung einer frequenzselektiven Stromregelung des Wechselrichters der Ladesäule wurde die Reduktion der Netzrückwirkung bei hoher Ladeleistung ermöglicht und zusätzliche Netzdienstleistungen wie Netzstützung, Phasenschieberbetrieb, Netzsymmetrierung und Oberschwingungskompensation für eine aktive Verbesserung der Netzspannungsqualität realisiert. Ein neues Verfahren zur Optimierung der Phasenregelung erzielte eine höhere Effizienz der Kompensation der Oberschwingungen der Netzspannung. Diese Funktionen wurden an einem Prototyp der intelligenten Ladesäule in einem Inselnetz praktisch erforscht.
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23

Ferreira, Carla. « The unsymmetric tridiagonal eigenvalue problem ». Doctoral thesis, 2007. http://hdl.handle.net/1822/6761.

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Tese de doutoramento em Ciências - Área de Conhecimento Matemática.
The development of satisfactory methods for reducing an unsymmetric matrix to tridiagonal form has been greatly hampered by the fact that there is not an accepted good algorithm for exploiting this form. Nevertheless, recently, promising elimination techniques for achieving a stable reduction to this form have been developed. But the standard QR algorithm destroys it immediately. Our work aims to fill this gap in the armoury of software tools for the matrix eigenvalue problem and so encourage the refinement of methods to reduce a matrix to tridiagonal form. The progressive quotient difference algorithm with shifts (qds) was presented by Rutishauser as early as 1954. It is equivalent to the shifted LR algorithm written in a special notation for tridiagonals. The much more recent differential qds (dqds) is a sophisticated variant of qds. The first contribution of this thesis is a new algorithm, 3dqds, that consists of three dqds steps performed implicitly and such that real arithmetic is maintained in the presence of complex eigenvalues. One advantage of our algorithm over the Hessenberg QR algorithm is that it preserves the tridiagonal form and thus reduces both storage and time. We present some accuracy results comparing a Matlab implementation of 3dqds with the function eig of that software. These preliminary results suggest the robustness of 3dqds algorithm. In contrast to the symmetric case, unsymmetric matrices can have a mixture of eigenvalues, some robust in the face of perturbations while others extremely sensitive. We present several condition numbers, some new, that take advantage of tridiagonal form. Ideally an algorithm should report these numbers along with each computed eigenvalue. On the theoretical side, we present a rigorous proof of a surprising result. It is well known that the greater the ratio of adjacent eigenvalues, the faster LR converges. Nevertheless, in exact arithmetic, LR still converges even when all the eigenvalues are equal and the Jordan form is one big block.
O desenvolvimento de métodos satisfatórios para reduzir uma matriz não simétrica à forma tridiagonal tem sido fortemente travado pelo facto de que não existe um bom algoritmo aceite para explorar esta forma. Contudo, recentemente, promissoras técnicas de eliminação para realizar esta redução de maneira estável foram desenvolvidas. Mas o algoritmo QR standard destrói a forma tridiagonal imediatamente. O nosso trabalho pretende colmatar esta lacuna no conjunto das ferramentas computacionais para o problema de cálculo de valores próprios e assim encorajar o aperfeiçoamento de métodos para redução de uma matriz à forma tridiagonal. O algoritmo qds (progressive quotient difference with shifts) foi introduzido por Rutishauser e remonta a 1954. É equivalente à versão shifted do algoritmo LR escrita numa notação especial para matrizes tridiagonais. O muito mais recente algoritmo dqds (differential qds) é uma versão sofisticada do qds. Uma contribuição desta tese é um novo algoritmo, 3dqds, que consiste em três passos do dqds realizados implicitamente e tal que a aritmética real é mantida na presença de valores próprios complexos. Uma vantagem do nosso algoritmo em relação ao Hessenberg QR é que preserva a forma tridiagonal e assim reduz a necessidade de espaço em memória e o tempo de execução. Apresentamos alguns resultados numéricos comparando uma implementação do 3dqds em MATLAB com a função eig daquele software. Estes resultados preliminares sugerem a robustez do algoritmo 3dqds. Em contraste com o caso simétrico, matrizes não simétricas podem ter um misto de valores próprios, alguns resistentes em face de perturbações enquanto outros extremamente sensíveis. Apresentamos vários números de condição, alguns novos, que tiram partido da forma tridiagonal. Idealmente, um algoritmo deve fazer acompanhar com estes números cada valor próprio calculado. Do ponto de vista teórico, apresentamos também uma demonstração rigorosa de um resultado surpreendente. É bem conhecido que quanto maior for a razão entre valores próprios adjacentes, mais rapidamente o algoritmo LR converge. No entanto, em aritmética exacta, o algoritmo LR também converge mesmo quando todos os valores próprios são iguais e a forma de Jordan é um único bloco.
Center of Mathematics of the University of Minho.
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24

Chiu, Yi Ping, et 丘宜平. « A Study on Symmetric and Unsymmetric BEMs ». Thesis, 1999. http://ndltd.ncl.edu.tw/handle/49084142895803849829.

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碩士
國立海洋大學
河海工程學系
87
Based on the dual framework derived by Hong and Chen, we developed symmetric boundary element method, instead of conventional BEM. Using the symmetry properties for the four kernels in the dual BEM, the symmetric BE formulation can be derived through double integrations. The main advantages are (1).The unsymmetric influence matrix in the conventional BEM can be avoided, (2).The coupling use with FEM can be easily implemented, and (3).The storage space in memory can be saved, and the solutions can be obtained more efficiently and accurately. The main challenge is that double integrations for the singular and hypersingular kernels should be dealt with. Two approaches, coordinate transformation and separation of variables, are considered. For the former one, the two-point functions for the four kernel functions can be reduced to difference-type kernels by coordinate transformation. For the latter one, the kernel functions can be separated into dual series and the field point and source point in kernel can be uncoupled. Therefore, double integrations can be easily calculated by two single integrals. In order to check the influence matrices, not only the test of constant potential but also equilibrium condition will be employed. A general program was developed for the Laplace equation. In addition, the spectral properties for the four kernels are examined and their orders of pseudo-differential operatorare are determined by an circular example. Finally, several examples will be demonstrated. The comparisons with the conventional BEM and the symmetric BEM on memory storage, efficiency, and accuracy will be discussed.
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25

lin, chen may, et 陳美玲. « enzyme-catalyzed synthesis of unsymmetric cystine derivatives ». Thesis, 2000. http://ndltd.ncl.edu.tw/handle/86354081252795583089.

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碩士
國立東華大學
化學研究所
88
Abstract This thesis is to explore into enzyme-catalyzed coupling of cystine to generate cystine containing peptides. We found a-chymotrypsin catalyzed the condensation of ( L-Cys-OMe)2 with N-protected amino acid ester. The reactions were performed with 3.0 M, pH 6.0 buffer and shacked at 37 °C for 8 hr. Boc-L-Tyr-( L-Cys-OMe)2 was afforded in a yield of 63.1 %. The resulting monocoupled cystine-peptide was subsequently reacted with Cbz-L-Ala by using dicyclohexylcarbodiimide(DCC) to form unsymmetric cystine-peptide. In contrast, Aspergillus oryzae protease catalyzed the condensation of ( L-Cys-OMe )2 with several N-protected amino acids. The reaction was performed at 3.5 M, pH 7.5 and shacked at 37°C for 48 hr. Symmetric Cosine -peptide ( Boc-L-Tyr-L-Cys-OMe )2 was thus obtained. In addition, we carried out the esterification of ( Boc-L-Cys )2-L -Tyr-OMe to form ( Boc-L-Cys)2(OMe )-L-Tyr-OMe. This compound was able to couple with ( L-Cys-OMe )2 by enzyme catalysis to afford bis-cosine -peptide, which is difficult to synthesize by chemical means.
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26

Han-WenChang et 張瀚文. « Boundary Element Analysis of Unsymmetric Laminates with Corners ». Thesis, 2017. http://ndltd.ncl.edu.tw/handle/xsyadz.

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博士
國立成功大學
航空太空工程學系
105
For the boundary element analysis of the elastic bodies in the practical engineering problems, researchers in this field have explored into the many aspects of this numerical method when it is engaged with different applications and different kinds of materials. In their studies, some critical concerns had been paid attention to such as the need of an adequate fundamental solution, the singular integrals, and the corner discontinuities. All of these problems can be regarded as the “classical” topics in these days, and many applications had indeed been well treated in the literature. However, most of these studies were confined to the two dimensional problems, plate bending problems or three dimensional problems utilizing isotropic or metallic materials. In the industry, in order to meet some structural designs such as the criteria of the light weight, or the strengthening of the materials in the directions of applying force, today engineers are more willing to take advantages of the designable characteristics of the composite materials or laminates. With this understanding, over the past few decades some researches had been conducted for the types of laminates such as specially orthotropic materials, symmetric or antisymmetric laminates. Nevertheless, if an unsymmetric laminate is considered, the mechanical behaviors of the plates will become more complex in such a way that the coupling between the in-plane and out-of-plane bending problems will be unavoidable, and this problem was seldom received a thorough solution via the use of boundary elements. In this dissertation, to cover the complex mechanical behaviors of the composite laminates in response to all the possibility of symmetric, anti-symmetric, or unsymmetric stacking sequences and the corner discontinuities of a laminated plate, the coupled stretching-bending analysis of the general composite laminates via boundary elements has been developed with the help of the associated boundary integral equation, and the fundamental solution obtained via the Green’s function written in the form of Stroh-like complex variable formalism. To effectively treat the singular problem and the corner discontinuities which may result in dependent equations in the system of equations established via the discretization of the boundary integral equation, various methodologies were investigated to see their adequacies for the present application. And, the explicit solutions of the weakly and strongly singular integrals and the four auxiliary equations employed to replace the dependent equations are proposed in this study to solve the nodal displacements and tractions accurately and promptly. Besides, similar to the needs in the traditional boundary element analysis, the post-processing for the calculations of the complete components of the strains and stress resultants at or near the boundary nodes was also implemented and carried out in the present study. In order to obtain these results, we can make useful the already known nodal displacements through the method of finite difference, and all the other correct results of strains and stress resultants calculated via the derivatives of boundary integral equation at the points not so close to the boundary, and the use of the constitutive equation of laminates. Finally, by utilizing the moving least square method with these results, we can further approximate the solution in the vicinity of boundary nodes with good accuracy. In this process, we don’t need to tackle again the singular problems which involve hyper-singular and strongly singular integrals. Hence, based on all the works required at different stages, the full-domain solution can be obtained for the coupling analysis of composite laminated plates via boundary elements with accuracy and efficiency.
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27

Li, Henian. « Development and application of the Unsymmetric Lanczos Reduction method ». 1997. http://hdl.handle.net/1993/19438.

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28

Chang, Han-Wen, et 張瀚文. « BEM Design for the Analysis of Unsymmetric Composite Laminates ». Thesis, 2007. http://ndltd.ncl.edu.tw/handle/38557696633824059251.

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碩士
國立成功大學
航空太空工程學系碩博士班
95
A new algorithm has been developed to deal with the bending-stretching coupling problems of layered anisotropic plates in this thesis. By employing Stroh-like formalism for anisotropic elasticity, the fundamental solutions of displacements and tractions for the bending-stretching coupling analysis of composite laminates have been obtained. Moreover, according to the reciprocal theorem of Betti and Raleigh, the boundary integral equations for the bending-stretching coupling analysis have also been derived. Thus, the boundary element formulation for the bending-stretching coupling analysis of composite laminates is established. The aim of this thesis is focused not only on the treatment of the domain integrals and corner force, but also the position of boundary source points. Numerical results are demonstrated to show the accuracy and efficiency by comparing with either the exact solutions or with results from alternative numerical techniques. The present BEM algorithm is found to be efficient and accurate for the bending-stretching coupling analysis.
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29

Chen, Jian-De, et 陳建德. « System Identification and Testing of Symmetric and Unsymmetric Structures ». Thesis, 2010. http://ndltd.ncl.edu.tw/handle/2j723x.

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碩士
國立臺北科技大學
土木與防災研究所
98
First, the study numerically simulates a structure by use of SAP2000. According to the structural time response calculated from the simulation, the modal parameters are identified using ARX-model system identification, and then compared with the ones obtained from modal analysis. The comparison demonstrates the accuracy of the used system identification method. Next, we consider a unsymmetric structure which presents torsional behavior, and collect the time response of the structure in a real test. We find that the torsional mode can be detected by applying system identification to the collected data. Meanwhile,traditional accelerometers ( piezoelectric accelerometers ) and advanced accelerometers ( MEMS accelerometers ) are used in the test. The performance of the two sensors are compared. Finally, the modal parameters of a small-scale four-story steel frame structure are identified using ambient vibration records of the structure on which no external forces are acting. The results are compared with the ones obtained using the forced vibration records. Moreover, We conduct system identification for the structure with different damage combinations. Based on the identified mode shapes, the damage detection index ( inter-story drift mode shape, IDMS ) for each damaged structure is calculated. The results show that the system identification of ambient vibration records as well as the calculated damage detection index can effectively detect damage locations.
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30

Hsu, Chin-Kuang, et 許志光. « Preparation of novel phosphinated unsymmetric polyimides and low-dielectric benzoxazine ». Thesis, 2013. http://ndltd.ncl.edu.tw/handle/42538323204063630344.

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碩士
國立中興大學
化學工程學系所
101
[Part 1] Four novel diamines (9-12) were prepared by a two-step procedure from phosphinated phenols (1-4), which were prepared from acid-fragmentation of four bisphenols, including Bisphenol A, 4,4′-isopropylidenebis(2,6-dimethylphenol), 9,9’-bis(4-hydroxyphenyl)fluorene, and cis(4-hydroxyphenyl)cyclohexane, followed by nucleophilic addition of 9,10-dihydro-oxa-10-phosphaphenanthrene-10-oxide (DOPO). Copolyimides based on (9-12)/ 4, 4’-diaminodiphenyl ether /dianhydride were prepared. Due to the structure similiarity, (9)-containing copolyimides are compared with (10)-containing copolyimide, while (11)-containing copolyimides are compared with (12)-containing copolyimide. The structure-property relationship on the copolyimides was discussed. (10)-Containing copolyimides with the tetramethyl substitutent display higer Tg, modulus, dimensional stability, contact angle, and better solubility than (9)-containing copolyimides. The fluorene structure make (11)-containing copolyimides exhibit higher Tg than (12)-contaiing copolyimides. [Part 2] An aliphatic benzoxazine (2) was prepared via one-pot and two-pot. By analysis of 1H-NMR of monomer (2), we found that monomer (2) prepared via one-pot still have triazine in cosolvent. Monomer (2) and epoxy(CNE/DCPDE) copolymerized in the curing system. The (2)/DCPDE thermoset has the lowest moisture absorption and dielectric constant due to the aliphatic group.
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31

Shih-Kang, Fu, et 傅世剛. « Application of Unsymmetric Phosphorous-Imine Donor Ligands in Catalytic Polymerization ». Thesis, 2001. http://ndltd.ncl.edu.tw/handle/81385662934329616535.

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碩士
國立臺灣大學
化學研究所
89
Cationic palladium complex [Pd(P-N)Me(NCMe)](BF4) (4) with a chiral phosphine-imine donor ligand has been synthesized and characterized by spectroscopic methods. With the main objective of developing late-transition metal catalysts for polymerization and copolymerization of olefins and/or carbonmonoxide, catalytic activity of the above complex has been investigated. For convenience the present work has been divided into three parts.   Part 1: In this section alternating coplymerization of styrene and carbonmonoxide has been studied with catalysts (-)-4a or (+)-4a. We also investigated the step-wise insertion studies with styrene and CO to provide an example for migratory insertion mechanism for the coplymerization of styrene/CO. Stereochemistry (tacticity) of the resulting copolymer was investigated by changing various parameters viz., temperature, concentration and reaction time.   Part 2: This section deals with the polymerization of electronic rich olefins, particulary isobutyl-vinyl ether, ethyl vinyl ether and 2,3-dihydrofuran with (-)-4a or (+)-4a. Further studies reveal that polymerization process proceeds via cationic initiation rather than migratory insertion mechanism.   Part 3: Copolymerization studies of electron rich vinyl-ethers with (-)-4a or (+)-4a has been investigated in this section. The “living” nature of the copolymerization process has also been discussed.
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32

Chen, Zhong-Zhi, et 陳重志. « Optimization of Buckling Strength and Unsymmetric Laminated d to Various Loading ». Thesis, 1995. http://ndltd.ncl.edu.tw/handle/45593036022571577410.

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33

Chang, Chun-Chen, et 張君禎. « Azimuthal unsymmetric radiative transfer in a slab with variable refractive index ». Thesis, 2006. http://ndltd.ncl.edu.tw/handle/21027860192318294632.

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碩士
國立成功大學
機械工程學系碩博士班
94
The purpose of this work is to investigate azimuthally dependent radiative heat transfer in a medium with a continuous variation of refractive index. The boundary exposed to collimated iradiation is non-reflective, and the other is black. Then, azimuthally unsymmetric radiative transfer equation can be transformed to a set of azimuthally independent equations by expanding the intensity in a Fourier series in terms of azimuthal angle. Numerical solutions of these equations are calculated by discrete ordinates method. A collimated light illuminating into a medium with greater gradient of refractive index yields greater direction-hemispherical transmittance than that of a medium with a small gradient of refractive index. With increasing incident polar angle, the direction-hemispherical transmittance decreases. The effect of scattering phase function is that forward linear scattering gets greater direction-hemispherical transmittance. Bidirectional reflectance which is in the same azimuthal angle of incident ray is greater than that differs π-radian azimuthal angle from incident ray. Effect of backward scattering is reversal. Phase function does not affect the absorptance. Rayleigh scattering bidirectional reflectance in the same azimuthal angle of incident ray is lower than that differing π-radian from incident ray azimuthally. When the optical thickness increases, the direction-hemispherical transmittance decreases, and the direction-hemispherical reflectance increases. When the albedo is greater, direction-hemispherical transmittance and direction-hemispherical reflectance is larger and the absorptance is smaller.
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34

Lo, Wei-Hao, et 羅偉豪. « Ruthenium Complexes bearing Unsymmetric CNC' Pincer Ligands Synthesis, Structures and Photophysical Properties ». Thesis, 2014. http://ndltd.ncl.edu.tw/handle/64x4mf.

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35

Po-WeiHuang et 黃柏瑋. « Investigation of Singular Integrals in Boundary Element Formulation for Unsymmetric Composite Laminates ». Thesis, 2011. http://ndltd.ncl.edu.tw/handle/04139690082245534615.

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36

賴宏凱. « Kinetic Study of Synthesizing Unsymmetric Alkyl Sulfide Ether Under Phase Transfer Catalysis ». Thesis, 2004. http://ndltd.ncl.edu.tw/handle/21415552190184351311.

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碩士
東海大學
化學工程學系
92
The objective of this dissertation is to synthesize the alkyl sulfide ether in an organic solvent/aqueous solution two-phase medium by phase transfer catalysis. Thioethers can be used as perfume and inverse phase transfer catalyst. The primary purpose of this dissertation is to study the phase transfer catalytic reaction of thioether compounds, reaction mechanism, kinetics, and parameters in order to obtain the optimum reaction conditions. The experimental results prove the actuality of the reaction mechanism and confirm following the pseudo first-order rate law. Several rigid results were obtained from the expertmental work. A. Using phase transfer catalyst to synthesize unsymmetrical sulfide ether could improve the reaction rate, increase higher yield and elevate the conversion in mild reaction conditions. B. The hypothesis of the reaction mechanism, which is identified by the experimental results is correct. Using pseudo first-order rate law and pseudo steady-state hypothesis(PSSH) could be used to describe the reaction model successfully. C. Based on the experimental data, it is known that the reaction is enhanced with the increase in temperature, amount of catalyst and symmetric form of the catalyst. In addition, the rection is also affected by the amount of water, organic solvent and the molar ratio of the two reactants.
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37

Lin, I.-Ming, et 林義閔. « A Study on Ultimate Strength of Unsymmetric Steel Reinforced Concrete Beam-Columns ». Thesis, 1999. http://ndltd.ncl.edu.tw/handle/77101576561370399753.

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碩士
國立交通大學
土木工程系
87
Researches on steel reinforced concrete (SRC) columns during the past few decades were focused on the symmetrical structural steel shape. This research conducted experimental studies to investigate the behavior and ultimate strength of concrete-encased steel columns having unsymmetrical T-shape structural steel section. Twenty specimens including six short SRC columns and fourteen SRC beam-columns were designed and constructed. The short columns were loaded monotonically to failure while the beam-columns were subjected to axial load as well as flexural bending simultaneously. Variables to be studied included the shape of structural steel, the ratio of the area of structural steel shape to concrete section, the effect of axial load and the eccentricity of structural steel shape. Effects of various experimental parameters on the behavior were discussed. The experimental results were summarized and presented. The results indicate that ACI Building Code and AIJ SRC Standards can predict well the load carrying capacities of the SRC columns having unsymmetrical structural steel shape.
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38

Hsieh, Kuo-Ching, et 謝國卿. « On The Reduction Algorithms For Solving The Eigenvalues Of A Real Unsymmetric Matrix ». Thesis, 1997. http://ndltd.ncl.edu.tw/handle/69617666825175002323.

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39

Hong, Yi-Ching, et 洪意晴. « Identification of Story Stiffness and Location of Rigid Center for Unsymmetric-Plan Buildings ». Thesis, 2008. http://ndltd.ncl.edu.tw/handle/20778205332558946613.

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碩士
國立成功大學
土木工程學系碩博士班
96
When a building is subjected to a strong earthquake excitation, the yielding of structural elements and the brittle damage at column ends may cause the reduction of structural stiffness and then the instability of structural system. In order for effectively evaluating the level and location of damage, a system identification technique would be applied to buildings with measured data. The identified fundamental vibration period is the most accurate parameter among all the dynamic parameters of a structural system. However, such an identified value is valid only in judging the level of damage. It is the necessary to identify the variation of story stiffness and the movement of rigid center for locating the damage. A nonlinear regression analysis is performed in this study to identify the story stiffness and the location of rigid center for several moving time windows. It is shown that the identified results are almost identical to the exact ones for the cases of complete measurement without noise, in spite of where and how the damage is pre-assumed. When noises are added to the input and output data, the identified results in the strong-motion regions are also good enough to show the variation of story stiffness. Finally, our method is used to identify the story stiffness and the location of rigid center and then to evaluate the location and level of damage for a true building with recorded seismic data.
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40

Adhikari, Narayan Prasad [Verfasser]. « Interfacial properties and phase behavior of unsymmetric polymer blends / von Narayan Prasad Adhikari ». 2001. http://d-nb.info/964276852/34.

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41

謝志偉. « The Mechanical Behavior of Thin-Walled Tubes with Unsymmetric Moment under Cyclic Bending ». Thesis, 2001. http://ndltd.ncl.edu.tw/handle/20303412095394866354.

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42

LIU, JIA-RI, et 劉嘉日. « Parallel qd-alogrithm for computing the eigenvalues of unsymmetric tridiagonal matrices on ncube computer ». Thesis, 1992. http://ndltd.ncl.edu.tw/handle/26507285517695753196.

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43

Schuchert, Andreas [Verfasser]. « Verfahren der digitalen Kompensation von Unsymmetrien der analogen Quadraturmischung in OFDM-Empfängern / Andreas Schuchert ». 2001. http://d-nb.info/963282212/34.

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44

張高華. « Theoretical investigation on the mechanical behavior of thin-walled tubes under unsymmetric cyclic bending ». Thesis, 2001. http://ndltd.ncl.edu.tw/handle/26053531354889793278.

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45

Tsai, Wei-Lung, et 蔡慰龍. « The Effect of Unsymmetric Loads and Sidesway on Load-Carrying Capacity of Steel Scaffolds ». Thesis, 1995. http://ndltd.ncl.edu.tw/handle/10292760982975779673.

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碩士
國立中興大學
土木工程研究所
83
This research mainly focuses on the effect of unsymmetrical loads acting on the steel scaffolds and the effect of initial sidesway of steel scaffolds for high- clearance reinforced concrete structures. The research work includes two parts, namely experimental and theoretical parts. Studies three-story steel scaffolds were adopted in experimental in which the effects of unsymmetrically applied loads and the initial sidesway of the steel scaffold system were investigated in these tests. The commercial code NASTRAN providing both eigenvalue and second-order elastic analyses are used in the theoretical approach. It was found that the load-carrying capacity of tubes of the scaffold will control the failure of the entire system, even if the system has unsymmetrically applied loads and initial sidesway on steel scaffolds. The use of the traditional jack base and the stiffened jack base can increase the loading capacity of system up to 17% - 33% and about 59% respectively in comparison with that of steel scaffold system without jack bases.
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46

Dai, Yeong-Der, et 戴永德. « The study about the synthesis of the unsymmetric dicobalt complex and its catalytic reaction ». Thesis, 1994. http://ndltd.ncl.edu.tw/handle/27654137190563077727.

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47

Beuttenmüller, Eckart W. « Electronically unsymmetric and sterically biased bidentate diphosphines structure and spectroscopy of iridium and iron complexes / ». 1995. http://catalog.hathitrust.org/api/volumes/oclc/33086849.html.

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48

Chen, Hung-Ru, et 陳虹如. « Further studies on column behavior including singly symmetric sections, unsymmetric sections, nonlinear evaluation, and leaning columns ». Thesis, 2012. http://ndltd.ncl.edu.tw/handle/v8y9mr.

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碩士
國立中興大學
土木工程學系所
100
Compression members are structural elements that are subjected to only to axial compressive forces. For a long time, the compression members of steel structures are the focus of discussion. But most of the studies for I- shape section steel, and much less for a single symmetrical cross section. This study intends to use the AISC (2005) formulas to deal with the singly symmetric sections such as the built-up double angles, the WT sections and the single angles. The provided examples are furnished to indicate the analysis and design of the basic concepts of steel columns. This study explored the non-linear analysis of steel columns, the stiffness reduction factors being used in the LRFD (1999) and the AISC (2005) specifications. This study also explores leaning column theory proposed by Prof. Yura, and used beam-column interaction equations to verify leaning column theory. It will be very beneficial to practicing professions that the provided examples give the detailed procedure to deal with the provisions being used in the current AISC specifications.
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49

HO, FENG-CHENG, et 何夆政. « Synthesis of low symmetry hexaphenylbenzen derivstives by using unsymmetric diarylalkyne via [2+2+2] transition metal-catalyzed cyclotrmerization ». Thesis, 2016. http://ndltd.ncl.edu.tw/handle/52995628404571309180.

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碩士
國立高雄師範大學
化學系
104
In this thesis, a series of low symmetric hexaphenylbenzene (HPB) derivatives were synthesize by alkynes [2+2+2] cyclotrimerization which are the precursors of hexabenzocoronene (HBC) derivatives, and high regiospecific hexaphenylbenzene derivatives were obtained, only 1,2,4-regiomer or 1,3,5-regiomer, by controlling electron donating-withdrawing and steric hindrance effective. Depend on this method, low symmetric hexa-peri-hexabenzocornene derivatives were successfully gotten by simple steps, In general, it takes 30~40 steps to afford it. All compounds were characterized by 1H and 13C-NMR, and MALDI-MS spectrometry. The thermotropic liquid crystalline (LC) properties of the compounds were investigated by polarizing optical microscopy (POM), differential scanning calorimetry (DSC), and powder X-ray diffractometry (PXRD).
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50

LIN, CHUN-CHENG, et 林春成. « Planar Wide-Band Unsymmetry Semicircle Antenna for GSM 1800/UMTS 2100 4G LTE Applications ». Thesis, 2017. http://ndltd.ncl.edu.tw/handle/69597512194118515783.

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