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Tesi sul tema "Catalytic reforming"

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1

Shao, Huifang. "Bimetallic carbides as catalysts for dry reforming and steam reforming." Morgantown, W. Va. : [West Virginia University Libraries], 2006. https://eidr.wvu.edu/etd/documentdata.eTD?documentid=4761.

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Abstract (sommario):
Thesis (Ph. D.)--West Virginia University, 2006.<br>Title from document title page. Document formatted into pages; contains x, 174 p. : ill. (some col.). Includes abstract. Includes bibliographical references (p. 155-166).
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2

El-Bousiffi, M. A. "The dynamics of catalytic steam reforming." Thesis, Swansea University, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.636778.

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This thesis describes a study of catalysed steam methane reforming. A microreactor of 3 mm bore, operated and controlled by computer has been used. The catalyst employed was an industrial type steam reforming nickel oxide-alumina catalyst containing 15% nickel. The experiments were performed at temperatures of industrial interest in the range of 600-840°C. The pressure range was 2.5-9 bar, at hydrogen to methane ratios of 0.5-2 and steam to methane ratios of 2-3.1. The catalyst was initially activated at 700°C in a flow of steam and hydrogen (7:1) for 16 hours. Initially, the activity of the c
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3

Sotelo-Boyas, Rogelio. "Fundamental kinetic modeling of the catalytic reforming process." Texas A&M University, 2005. http://hdl.handle.net/1969.1/4670.

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In this work, a fundamental kinetic model for the catalytic reforming process has been developed. The complex network of elementary steps and molecular reactions occurring in catalytic reforming has been generated through a computer algorithm characterizing the various species by vectors and Boolean relation matrices. The algorithm is based on the fundamental chemistry occurring on both acid and metal sites of the catalyst. Rates are expressed for each of the elementary steps involved in the transformation of the intermediates. The Hougen-Watson approach is used to express the rates of the mol
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4

Nguyen, Minh Hoang. "Microwave Assisted Catalytic Dry Reforming of Methane." Thesis, Curtin University, 2019. http://hdl.handle.net/20.500.11937/77745.

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In this project, the active and stable catalysts were successfully developed for methane reforming reactions under microwave heating. The monometallic Co, Cu, and Mo catalysts supported on either AhO3 or TiO2 were inactive under all tested conditions whilst their respective bimetallic CoMo and CuMo catalysts were highly active and stable at low microwave powers to produce desirable syngas ratios. The activation mechanism of metallic­based catalysts for reforming reactions under microwave heating was explored.
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5

Praharso, Praharso School of Chemical Engineering &amp Industrial Chemistry UNSW. "The autothermal reforming of artificial gasoline." Awarded by:University of New South Wales. School of Chemical Engineering and Industrial Chemistry, 2003. http://handle.unsw.edu.au/1959.4/19294.

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Stringent legislation on control of vehicle exhaust emissions has led to consideration of alternative means of reducing emissions, with hydrogen fuel cell powered vehicles being accepted as one favoured possibility. However, the difficulties of storing and distributing hydrogen as a fuel are such that the conversion of more readily available fuels to hydrogen on board the vehicle may be required. The production of hydrogen by the partial oxidation of isooctane over Rh/Al2O3, Rh/CeO2-?l2O3 and Rh/CeO2-ZrO2 catalysts has been investigated. Oxidation was initiated at temperatures between 200 ?220
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6

Luk, Kar Tsun. "Dry reforming in a microwave plasma /." View abstract or full-text, 2004. http://library.ust.hk/cgi/db/thesis.pl?CENG%202005%20LUK.

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7

Araque, Marin Marcia Carolina. "Glycerol valorisation by catalytic steam reforming for hydrogen production." Strasbourg, 2011. https://publication-theses.unistra.fr/restreint/theses_doctorat/2011/ARAQUE_MARIN_Marcia_Carolina_2011.pdf.

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La thèse de doctorat avait comme objectif l’étude de la production d’hydrogène par vaporeformage catalytique du glycérol. Les catalyseurs développés dans ce travail sont des oxydes mixtes cérine-zircone de structure fluorite auxquels des oxydes de métaux de transition (Co) ou des métaux nobles (Ru/Rh) ont été ajoutés. L’effet de la nature de l’élément ajouté (Ru, Rh, Co-Rh, Co-Ru), de la quantité de métaux nobles (0,5 %, 1,2%) et du rapport massique CeO2/ZrO2 (0,65/0,35; 0,8/0,2; 0,2/0,8) a été étudié. Les caractérisations des catalyseurs avant test montrent que la présence de métaux nobles fa
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8

Evans, Samuel E. "Catalytic reforming of biogas using nickel based perovskite materials." Thesis, Keele University, 2017. http://eprints.keele.ac.uk/3529/.

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The utilisation of biogas as an energy source or as a feed stock for the chemical industry would help to lower the present wasteful and environmentally unfriendly venting of greenhouse gases to the atmosphere. One obstacle to this becoming a reality include finding a catalyst that is active towards carbon dioxide reforming of methane as well as resistance to carbon deposition and sulphur poisoning. As a potential alternative to supported nickel catalysts, a nickel doped perovskite has been produced via a hydrothermal synthesis method for reforming biogas. The selected perovskite, SrZrO3, was d
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9

Min, Zhenhua. "Catalytic steam reforming of biomass tar using iron catalysts." Thesis, Curtin University, 2010. http://hdl.handle.net/20.500.11937/184.

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Biomass has become an increasingly important renewable source of energy forenhanced energy security and reduced CO[subscript]2 emissions. Gasification is at the core of many biomass utilisation technologies for such purposes as the generation of electricity and the production of hydrogen, liquid fuels and chemicals. However, gasification faces a number of technical challenges to become a commercially feasible renewable energy technology. The most important one is the presence of tar in the gasification product gas. The ultimate purpose of this thesis was to investigate the catalytic reforming
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10

Emery, Adrian Pater. "A combined catalytic and FT-IR study of platinum rhenium catalysts." Thesis, University of Reading, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.363713.

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11

Torres, Rivero José Antonio. "Catalysts for steam reforming of Ethanol in a catalytic wall reactor." Doctoral thesis, Universitat Rovira i Virgili, 2008. http://hdl.handle.net/10803/8565.

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La energía se ha convertido en una necesidad vital para garantizar el desarrollo de las sociedades modernas. Entre las diferentes posibles alternativas para producir energía, el hidrogeno presenta varias características que lo convierten en un atractivo vector energético: primero, se trata de una tecnología más eficiente para transformar la energía química en electricidad -por ejemplo, utilizando pilas de-combustible, las cuales también reducen de manera significativa los niveles de emisión de CO2 -; en segundo lugar, el hidrogeno puede ser producido a partir de una amplia variedad de materias
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12

Ford, Evan D. "A Bayesian Approach to Reduced Order Modeling in Catalytic Steam Reforming." Thesis, West Virginia University, 2015. http://pqdtopen.proquest.com/#viewpdf?dispub=1596597.

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<p> An investigation was conducted to determine the feasibility of developing a reduced order model capable of accurately predicting the behavior of steam methane reforming. An emerging model reduction technique based on examining causal relationships was applied to the reaction network developed by Xu and Froment to eliminate unnecessary intermediate species[1]. A dynamic discrepancy term was included in the reduced network to quantify the error incurred from the network reduction. This discrepancy is stochastic in nature, and a Markov Chain Monte Carlo (MCMC) sampling routine coupled with Ba
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13

Carvalho, Davi Coelho de. "Catalytic properties of titanate nanotubes applied to dry reforming of methane." Universidade Federal do CearÃ, 2016. http://www.teses.ufc.br/tde_busca/arquivo.php?codArquivo=16535.

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CoordenaÃÃo de AperfeÃoamento de Pessoal de NÃvel Superior<br>Dry reforming of methane reaction was conducted in the presence of titanate nanotubes (TNTs) modified with Co, Ni and Pt. TNTs were synthesized by hydrothermal treatment and than these solids were either submitted to ion exchange for Ni and Co using hexahydrate nitrate solutions, or they were submitted to wet impregnation with H2Ptl6.6H2O (1% w/w of Pt) solution. The solids were characterized before and after the dry reforming of methane by elemental chemical analysis (CHN), X-ray diffraction (XRD), Raman spectroscopy, nitrogen adso
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14

Tao, Yongwen. "Catalytic transformation of crude bio-oil to valuable chemicals and fuels." Thesis, The University of Sydney, 2016. http://hdl.handle.net/2123/15906.

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Hydrogen has been regarded as the most environmental friendly energy carrier due to its easily-storage and high energy concentration. A variety of technologies have been studied to generate hydrogen. Ethanol steam reforming is one of the most promising ways to generate hydrogen since its high productivity. However, the high operating temperature is the main challenge for developing the process. Metallic catalysts have been widely investigated to improve the performance of ethanol steam reforming process. Ni-based catalysts are frequently studied due to their good catalytic performance and low
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15

Pashikanti, Kiran. "Predictive Modeling of Large-Scale Integrated Refinery Reaction and Fractionation Systems from Plant Data: Fluid Catalytic Cracking (FCC) and Continuous Catalyst Regeneration (CCR) Catalytic Reforming Processes." Diss., Virginia Tech, 2011. http://hdl.handle.net/10919/77181.

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This dissertation includes two accounts of rigorous modeling of petroleum refinery modeling using rigorous reaction and fractionation units. The models consider various process phenomena and have been extensively used during a course of a six-month study to understand and predict behavior. This work also includes extensive guides to allow users to develop similar models using commercial software tools. (1) Predictive Modeling of Large-Scale Integrated Refinery Reaction and Fractionation Systems from Plant Data: Fluid Catalytic Cracking (FCC) Process with Planning Applications: This work presen
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16

Gardner, Todd H. "Hexaaluminate catalysts for the partial oxidation of middle distillate fuels." Morgantown, W. Va. : [West Virginia University Libraries], 2007. https://eidr.wvu.edu/etd/documentdata.eTD?documentid=5116.

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Abstract (sommario):
Thesis (Ph. D.)--West Virginia University, 2007.<br>Title from document title page. Document formatted into pages; contains xii, 162 p. : ill. (some col.). Includes abstract. Includes bibliographical references (p. 139-150).
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17

Shi, Kaiqi. "Microwave-enhanced pyrolysis of biomass coupled with catalytic reforming for hydrogen production." Thesis, University of Nottingham, 2015. http://eprints.nottingham.ac.uk/30406/.

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Pyrolysis of biomass is a promising and sustainable approach to produce value-added chemicals and biofuels. In order to achieve a high yield of hydrogen-rich syngas from pyrolysis of biomass, the microwave-enhanced pyrolysis of biomass coupled with catalytic reforming was studied systematically in this research. Firstly, microwave-enhanced pyrolysis of biomass was carried out and compared with conventional pyrolysis under the same processing conditions. Characterisations of biomass, pyrolytic char, bio-oil and biogas were conducted to investigate the differences between microwave-enhanced and
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18

Robbins, Fletcher Alexi. "Integration of steam reforming and catalytic combustion in a single plate reactor." College Park, Md. : University of Maryland, 2004. http://hdl.handle.net/1903/2111.

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Thesis (M.S.) -- University of Maryland, College Park, 2004.<br>Thesis research directed by: Dept. of Mechanical Engineering. Title from t.p. of PDF. Includes bibliographical references. Published by UMI Dissertation Services, Ann Arbor, Mich. Also available in paper.
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19

Soames, Mark. "Sol-gel routes to platinum, platinum-tin and platinum-potassium reforming catalysts." Thesis, Brunel University, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.311280.

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20

Mahmood, Asad. "Thermochemical conversion of Brewers Spent Grain combined with catalytic reforming of pyrolysis vapours." Thesis, Aston University, 2015. http://publications.aston.ac.uk/26198/.

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The brewing process is an energy intensive process that uses large quantities of heat and electricity. To produce this energy requires a high, mainly fossil fuel consumption and the cost of this is increasing each year due to rising fuel costs. One of the main by-products from the brewing process is Brewers Spent Grain (BSG), an organic residue with very high moisture content. It is widely available each year and is often given away as cattle feed or disposed of to landfill as waste. Currently these methods of disposal are also costly to the brewing process. The focus of this work was to inves
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21

Hedayati, Ali. "On-site pure hydrogen production in a catalytic membrane reactor by ethanol steam reforming." Doctoral thesis, Universitat Politècnica de Catalunya, 2016. http://hdl.handle.net/10803/403840.

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Hydrogen is considered as a clean energy carrier that can be converted to electricity by fuel cell with high efficiency. To be economically feasible and comparable, hydrogen needs to be liquefied, compressed, or adsorbed in metallic hydrides in large scale prior to the transfer. This requires very high pressure or very low temperature, which make a very high risk during transfer and delivery. Hence, it is highly beneficial to produce and consume pure hydrogen at the same place/time. The use of renewable biofuels such as bio-ethanol as a source of hydrogen is highly beneficial due to the higher
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22

Luo, Xiang. "Hydrogen production from catalytic steam reforming of bio-oil over nano NixMgyO solid solution." Thesis, University of Nottingham, 2016. http://eprints.nottingham.ac.uk/37439/.

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Hydrogen production from bio-resource is a promising option. In order to economically and practically derive hydrogen from biomass on a sustainable scale, novel catalysts are needed to be developed with properties of effective and inexpensive. In this study, initial works include the preparation of Ni/MgO catalysts via different methods including co-precipitation, hydrothermal treatment and wet-impregnation. These catalysts formed solid solutions after calcination at 600 ℃. It was found that hydrothermal treatment increased the specific surface area of the catalyst from 49.7 m2/g to 79.8 m2/g.
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23

Enzenberger, Florian [Verfasser], and Peter [Akademischer Betreuer] Wasserscheid. "Catalytic Methanol Reforming Using Molten Salt Modified Reaction Systems / Florian Enzenberger. Betreuer: Peter Wasserscheid." Erlangen : Universitätsbibliothek der Universität Erlangen-Nürnberg, 2012. http://d-nb.info/1028392648/34.

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24

Elsayed, Nada. "Catalytic Upgrading of Biogas to Fuels: Role of Reforming Temperature, Oxidation Feeds, and Contaminants." Scholar Commons, 2017. http://scholarcommons.usf.edu/etd/6618.

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Global energy demands are constantly increasing and fossil fuels are a finite resource. The shift towards alternative, more renewable and sustainable fuels is inevitable. Furthermore, the increased emissions of greenhouse gases have forced a pressing need to find cleaner, more environmentally friendly sources of fuel. Biomass energy is a promising alternative fuel because it offers several important advantages. It is a renewable energy form, it comes from many sources and produces biogas (CH4 and CO2). Furthermore, it can have a zero carbon footprint; this is due to the fact that the carbon pr
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25

Wenzel, Jonathan E. Lee Sunggyu. "The kinetics of non-catalyzed supercritical water reforming of ethanol." Diss., Columbia, Mo. : University of Missouri--Columbia, 2008. http://hdl.handle.net/10355/7115.

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Title from PDF of title page (University of Missouri--Columbia, viewed on March 2, 2010). The entire thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file; a non-technical public abstract appears in the public.pdf file. Dr. Sunggyu Lee, Dissertation Advisor. Vita. Includes bibliographical references.
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26

Goodby, Brian Edward. "Characterization of copper/zinc-oxide catalysts for methanol reformation." Diss., The University of Arizona, 1988. http://hdl.handle.net/10150/184479.

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The research presented in this dissertation involved characterization of the Cu/ZnO solid catalyst system as applied to methanol/steam reformation. Thermogravimetry was used to investigate in-lab synthesized samples and a commercial product G66B (Cu/ZnO 33/67 wt. %). The 33% Cu sample contained Cu ions in the ZnO matrix. This phase required the highest temperatures (400°C) for H₂ reduction. The 50% Cu sample reduced at a lower temperature (220°C) but its complete reduction required the same maximum temperature. The higher temperature process was similar to the 33% case, while the lower one was
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27

Wollbrink, Alexander [Verfasser]. "Hydrogen-selective porous carbon-based membranes for catalytic steam reforming of bio-ethanol / Alexander Wollbrink." Hannover : Gottfried Wilhelm Leibniz Universität Hannover, 2021. http://d-nb.info/123055064X/34.

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28

Di, Felice Luca. "CO2 capture and catalytic steam reforming of tar produced in the fluidized bed gasification process." Strasbourg, 2010. https://publication-theses.unistra.fr/public/theses_doctorat/2010/DI_FELICE_Luca_2010.pdf.

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Le travail de doctorat avait pour objectif d’améliorer les performances de la gazéification de la biomasse en se focalisant sur deux aspects : qualité du gaz produit (élimination des goudrons) et captage de CO2 formé en vue d’une valorisation chimique ultérieure. Le travail de thèse a été divisé en quatre parties : 1. Tests de laboratoire sur la gazéification de la biomasse dans des conditions proches d’une utilisation effective avec la mise en place d’un élément catalytique filtrant dans la partie disponible du réacteur de gazéification en lit fluidisé. La présence de goudrons (hydrocarbures
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29

Soykal, Ibrahim Ilgaz I. "Characterization of cobalt and cerium coordination environments for catalytic steam reforming of bio-derived liquids." The Ohio State University, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=osu1378898730.

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30

Wang, Meng. "Steam reforming of model compounds of bio-oil with and without CO₂ sorbent." HKBU Institutional Repository, 2014. https://repository.hkbu.edu.hk/etd_oa/212.

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Hydrogen as a clean energy carrier has drawn great attention. Production of H2 from sustainable bio-oil is considered an alternative for conventional fossil fuel based energy system, since the overall process of bio-oil converting to H2 ideally is carbon-neutral and hence environmental friendly. This study focuses on developing an adequate catalyst for bio-oil steam reforming to produce H2. Ruthenium and/ or nickel based catalysts supported on alumina, ceria-alumina or ceria-silica were synthesized by sol-gel method or incipient wetness impregnation and characterized using BET Surface area an
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31

Hernandez-Gonzalez, Sergio Manuel. "Non-Catalytic Production of Hydrogen via Reforming of Diesel, Hexadecane and Bio-Diesel for Nitrogen Oxides Remediation." The Ohio State University, 2008. http://rave.ohiolink.edu/etdc/view?acc_num=osu1228317376.

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32

Natesakhawat, Sittichai. "Investigation of active sites and reaction networks in catalytic hydrogen production steam reforming of lower alkanes and the water-gas shift reaction /." Connect to this title online, 2005. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1110209339.

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Thesis (Ph. D.)--Ohio State University, 2005.<br>Title from first page of PDF file. Document formatted into pages; contains xiv, 194 p.; also includes graphics Includes bibliographical references (p. 178-188). Available online via OhioLINK's ETD Center
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33

Seelam, P. K. (Prem Kumar). "Hydrogen production by steam reforming of bio-alcohols:the use of conventional and membrane-assisted catalytic reactors." Doctoral thesis, Oulun yliopisto, 2013. http://urn.fi/urn:isbn:9789526202778.

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Abstract The energy consumption around the globe is on the rise due to the exponential population growth and urbanization. There is a need for alternative and non-conventional energy sources, which are CO2-neutral, and a need to produce less or no environmental pollutants and to have high energy efficiency. One of the alternative approaches is hydrogen economy with the fuel cell (FC) technology which is forecasted to lead to a sustainable society. Hydrogen (H2) is recognized as a potential fuel and clean energy carrier being at the same time a carbon-free element. Moreover, H2 is utilized in m
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34

Basson, Gert Wilhelm. "Non-catalytic plasma-arc reforming process of methane with carbon dioxide for hydrogen production / G.W. Basson." Thesis, North-West University, 2009. http://hdl.handle.net/10394/3698.

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35

Walker, Devin Mason. "Catalytic Tri-reforming of Biomass-Derived Syngas to Produce Desired H2:CO Ratios for Fuel Applications." Scholar Commons, 2012. http://scholarcommons.usf.edu/etd/4250.

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This study focuses on upgrading biomass derived syngas for the synthesis of liquid fuels using Fischer-Tropsch synthesis (FTS). The process includes novel gasification of biomass via a tri-reforming process which involves a synergetic combination of CO2 reforming, steam reforming, and partial oxidation of methane. Typical biomass-derived syngas H2:CO is 1:1 and contains tars that deactivate FT catalyst. This innovation allows for cost-effective one-step production of syngas in the required H2:CO of 2:1 with reduction of tars for use in the FTS. To maximize the performance of the tri-reform
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36

Goicoechea, Saioa [Verfasser]. "Design of a Catalytic System for Syngas Production via Steam Reforming of Acetic Acid / Saioa Goicoechea." München : Verlag Dr. Hut, 2017. http://d-nb.info/1135596484/34.

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Prabhu, Anil K. "Catalytic Transformation of Greenhouse Gases in a Membrane Reactor." Diss., Virginia Tech, 2003. http://hdl.handle.net/10919/26430.

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Supported Ni and Rh catalysts were developed for the reforming of two greenhouse gases, methane and carbon dioxide to syngas (a mixture of hydrogen and carbon monoxide). This is an endothermic, equilibrium limited reaction. To overcome the thermodynamic limitations, a commercially available porous membrane (Vycor glass) was used in a combined reactor-separator configuration. This was to selectively remove one or more of the products from the reaction chamber, and consequently shift the equilibrium to the right. However, the separation mechanism in this membrane involved Knudsen diffusion,
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Lee, Doo-hwan. "Studies on Hydrogen Selective Silica Membranes and the Catalytic Reforming of CH₄ with CO₂ in a Membrane Reactor." Diss., Virginia Tech, 2003. http://hdl.handle.net/10919/28543.

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In this work the synthesis, characterization, and gas transport properties of hydrogen selective silica membranes were studied along with the catalytic reforming of CH4 with CO2 (CH4 + CO z 2 CO + 2 H2) in a hydrogen separation membrane reactor. The silica membranes were prepared by chemical vapor deposition (CVD) of a thin SiO2 layer on porous supports (Vycor glass and alumina) using thermal decomposition of tetraethylorthosilicate (TEOS) in an inert atmosphere. These membranes displayed high hydrogen permeances (10-8 - 10-7 mol m-2 s-1 Pa-1) and excellent H2 selectivities (above 99.9 %) ov
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39

Li, Ling. "Catalytic methane reformation and aromatization reaction studies via cavity ringdown spectroscopy and time of flight mass spectrometry." Click to view the E-thesis via HKUTO, 2007. http://sunzi.lib.hku.hk/hkuto/record/B39707404.

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Li, Ling, and 李凌. "Catalytic methane reformation and aromatization reaction studies via cavity ringdown spectroscopy and time of flight mass spectrometry." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2007. http://hub.hku.hk/bib/B39707404.

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41

Fedotov, Alexey. "Conversion of methane and carbon dioxide on porous catalytic membranes." Thesis, Vandoeuvre-les-Nancy, INPL, 2009. http://www.theses.fr/2009INPL099N/document.

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L’étude concerne un nouveau procédé de reformage du gaz naturel en gaz de synthèse par le dioxyde de carbone (RSM), en vue de l'utilisation rationnelle des déchets carbonés industriels pour la production d'hydrocarbures et d'hydrogène. Cette méthode utilise des systèmes à membranes catalytiques inorganiques (SMC) qui favorisent des réactions catalytiques hétérogènes en phase gazeuse dans des micro-canaux céramiques. La surface active des catalyseurs formés à l'intérieur des canaux est faible en termes de superficie, mais elle est caractérisée par une valeur élevée du facteur Surface/Volume du
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42

Ozdogan, Ekin. "Steam Reforming Of Ethanol For Hydrogen Production Using Cu-mcm41 And Ni-mcm41 Type Mesoporous Catalytic Materials." Master's thesis, METU, 2007. http://etd.lib.metu.edu.tr/upload/12608680/index.pdf.

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The world&rsquo<br>s being alerted to the global warming danger and the depletion of fossil fuel resources, has increased the importance of the clean and renewable hydrogen energy. Bioethanol has high potential to be used as a resource of hydrogen since it is a non-petroleum feedstock and it is able to produce hydrogen rich mixture by steam reforming reactions. Discovery of mesoporous MCM-41 type high surface area silicate-structured materials with narrow pore size distributions (20-100 &Aring<br>) and high surface areas (up to 1500 m2/g) opened a new avenue in catalysis research. Catalytic ac
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43

Charlesworth, R. J. "The steam reforming and combustion of methane on micro-thin catalysts for use in a catalytic plate reactor." Thesis, University of Newcastle Upon Tyne, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.246682.

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Vilekar, Saurabh A. "Catalytic and Electrocatalytic Pathways in Fuel Cells." Digital WPI, 2010. https://digitalcommons.wpi.edu/etd-dissertations/125.

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A fundamental understanding of the kinetics and mechanisms of the catalytic reaction steps involved in the process of converting a fuel into hydrogen rich stream suitable for a fuel cell, as well as the electro-catalytic reactions within a fuel cell, is not only conceptually appealing, but could provide a sound basis for the design and development of efficient fuel processor/fuel cell systems. With the quantum chemical calculations on kinetics of elementary catalytic reaction steps becoming rather commonplace, and with increasing information now available in terms of electronic structures, vib
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45

Vecino, Mantilla Juan Sebastián. "Nickel exsolution effect on the catalytic behavior of ruddlesden-popper manganites in sofc conditions using colombian natural gas." Doctoral thesis, Universitat Politècnica de València, 2020. http://hdl.handle.net/10251/149474.

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[EN] Several major problems have to be solved before Solid Oxide Fuel Cells (SOFC) can operate continuously using hydrocarbon fuels such as natural gas. The risk of low catalytic behavior for fuel reforming, the carbon formation/deposition on the anode material at high operating temperatures and the presence of impurities in the fuel (in particular sulfides) can dramatically reduce the performance and durability of the cells. Taking all this into account, new anode materials with adequate (electro)catalytic properties are required. Recently, manganite compounds with Ruddlesden-Popper (R
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46

Enzenberger, Florian [Verfasser]. "Catalytic Methanol Reforming Using Molten Salt Modified Reaction Systems : Katalytische Methanol-Reformierung in durch Salzschmelzen modifizierten Reaktionssystemen / Florian Enzenberger." Aachen : Shaker, 2012. http://d-nb.info/1066197784/34.

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47

Liu, Luyi. "Molecular characterisation and modelling for refining processes." Thesis, University of Manchester, 2015. https://www.research.manchester.ac.uk/portal/en/theses/molecular-characterisation-and-modelling-for-refining-processes(2844bcd8-070c-4f91-ba83-1deb7f1600a7).html.

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The highly competitive market in the oil refining industry forces refiners look for more detailed information of both feedstocks and products to achieve the optimal economic performance. Due to stricter environmental legislations, the molecular level characterisation has been investigated by various researchers and shows promising advantages in modern refinery design and operation. Although various molecular characterisation methods have been developed, there is an unavoidable trade-off between keeping astronomical molecule details and practicality in industrial applications. In the meantime,
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48

Roussière, Thomas Luc [Verfasser], and O. [Akademischer Betreuer] Deutschmann. "Catalytic Reforming of Methane in the Presence of CO2 and H2O at High Pressure / Thomas Luc Roussière. Betreuer: O. Deutschmann." Karlsruhe : KIT-Bibliothek, 2013. http://d-nb.info/1046093509/34.

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49

Göransson, Kristina. "Internal Tar/CH4 Reforming in Biomass Dual Fluidised Bed Gasifiers towards Fuel Synthesis." Doctoral thesis, Mittuniversitetet, Avdelningen för kemiteknik, 2014. http://urn.kb.se/resolve?urn=urn:nbn:se:miun:diva-22984.

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Production of high-quality syngas from biomass gasification in a dual fluidised bed gasifier (DFBG) has made a significant progress in R&amp;D and Technology demonstration. An S&amp;M scale bio-automotive fuel plant close to the feedstock resources is preferable as biomass feedstock is widely sparse and has relatively low density, low heating value and high moisture content. This requires simple, reliable and cost-effective production of clean and good syngas. Indirect DFBGs, with steam as the gasification agent, produce a syngas of high content H2 and CO with 12-20 MJ/mn3 heating value. The M
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50

Rodrigues, Carolina May. "Desenvolvimento de modelo matemático do sistema reacional de uma unidade industrial de reforma catalítica de nafta com leito móvel." Universidade de São Paulo, 2014. http://www.teses.usp.br/teses/disponiveis/3/3137/tde-26122014-165542/.

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Reforma catalítica de nafta é um dos processos mais importantes para a produção de gasolina de alta octanagem, hidrocarbonetos aromáticos e hidrogênio na indústria de petróleo e petroquímica. Para predizer os rendimentos e as propriedades dos produtos ou mesmo melhorar as condições de processo é recomendado descrever o processo matematicamente em termos de modelos cinéticos. A nafta tem um grande número de compostos com número de carbonos variando de cinco a doze, assim, um modelo considerando todos os componentes e reações, é complexo. Modelos baseados em lumps costumam agrupar os compostos e
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