Bibliografie tematiche / Copper antimonite

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Letteratura scientifica selezionata sul tema "Copper antimonite"

Autore: Grafiati

Pubblicato: 4 giugno 2021

Ultima modifica: 10 febbraio 2022

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Articoli di riviste sul tema "Copper antimonite"

Focke, Walter W., Sfiso S. Mkhize, Rowan Storey, Olinto Del Fabbro e Elmar Muller. "FACILE SYNTHESIS OF COPPER ANTIMONITE". Chemical Engineering Communications 201, n. 2 (6 novembre 2013): 153–59. http://dx.doi.org/10.1080/00986445.2012.762629.

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Farias, Pedro, Christophe Espírito Santo, Rita Branco, Romeu Francisco, Susana Santos, Lars Hansen, Soren Sorensen e Paula V. Morais. "Natural Hot Spots for Gain of Multiple Resistances: Arsenic and Antibiotic Resistances in Heterotrophic, Aerobic Bacteria from Marine Hydrothermal Vent Fields". Applied and Environmental Microbiology 81, n. 7 (30 gennaio 2015): 2534–43. http://dx.doi.org/10.1128/aem.03240-14.

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ABSTRACTMicroorganisms are responsible for multiple antibiotic resistances that have been associated with resistance/tolerance to heavy metals, with consequences to public health. Many genes conferring these resistances are located on mobile genetic elements, easily exchanged among phylogenetically distant bacteria. The objective of the present work was to isolate arsenic-, antimonite-, and antibiotic-resistant strains and to determine the existence of plasmids harboring antibiotic/arsenic/antimonite resistance traits in phenotypically resistant strains, in a nonanthropogenically impacted environment. The hydrothermal Lucky Strike field in the Azores archipelago (North Atlantic, between 11°N and 38°N), at the Mid-Atlantic Ridge, protected under the OSPAR Convention, was sampled as a metal-rich pristine environment. A total of 35 strains from 8 different species were isolated in the presence of arsenate, arsenite, and antimonite. ACR3 andarsBgenes were amplified from the sediment's total DNA, and 4 isolates also carried ACR3 genes. Phenotypic multiple resistances were found in all strains, and 7 strains had recoverable plasmids. Purified plasmids were sequenced by Illumina and assembled by EDENA V3, and contig annotation was performed using the “Rapid Annotation using the Subsystems Technology” server. Determinants of resistance to copper, zinc, cadmium, cobalt, and chromium as well as to the antibiotics β-lactams and fluoroquinolones were found in the 3 sequenced plasmids. Genes coding for heavy metal resistance and antibiotic resistance in the same mobile element were found, suggesting the possibility of horizontal gene transfer and distribution of theses resistances in the bacterial population.

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Liu, Hong, Chao Qin, Yong-Ge Wei, Lin Xu, Guang-Gang Gao, Feng-Yan Li e Xiao-Shu Qu. "Copper-Complex-Linked Polytungsto-Bismuthate (-Antimonite) Chain Containing Sandwich Cu(II) Ions Partially Modified with Imidazole Ligand". Inorganic Chemistry 47, n. 10 (maggio 2008): 4166–72. http://dx.doi.org/10.1021/ic7022264.

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Askarova, Gulzhan, Mels Shautenov e Kulzhamal Nogaeva. "Flotation enrichment of resistant gold ores". E3S Web of Conferences 168 (2020): 00005. http://dx.doi.org/10.1051/e3sconf/202016800005.

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Ores of the Vasilkovsky deposit include arsenopyrite, pyrite, pyrrhotite, marcasite, gold, chalcopyrite, sphalerite, galena, faded ore (tennantite)S, bismuthine, native bismuth, lellingite, molybdenite, cubanite, bornite, antimonite, relict minerals, magnetite, apatite and apatite chromite, sericite, chlorite, potassium feldspar, tourmaline), quartz, carbonates (siderite, ankerite, calcite), fluorite, barite. Arsenopyrite is the main ore mineral. It contains the bulk of gold, as well as impurities - copper, cobalt, nickel, bismuth, zirconium, titanium, lead, zinc, antimony, silver, molybdenum. Bismuth and its minerals are widespread, they are constantly associated with arsenopyrite, forming intergrowths with native gold, less often with chalcopyrite and faded ore. Native gold is distributed very unevenly, forms the finest precipitates ranging in size from tenths of a micron to 0.063 mm, grows together with quartz, arsenopyrite, pyrite and bismuth minerals. Rich ores were formed by combining bismuthcontaining associations with arsenopyrite. The role of gold in arsenopyrite increases with depth. Ores are of the gold-quartz-sulfide type. Quartz in ore up to 90 %, sulfides from 3 to 5 %. The content of harmful impurities (arsenic) reaches 2 % or more. Ores are refractory, require special technology for the beneficiation and extraction of gold.

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Olmi, Filippo, Alessandrο Santucci e Renza Trosti-Ferroni. "Sabelliite, a new copper-zinc arsenate-antimonate mineral from Sardinia, Italy". European Journal of Mineralogy 7, n. 6 (27 dicembre 1995): 1325–30. http://dx.doi.org/10.1127/ejm/7/6/1325.

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Singh, Satyendra, Archana Singh, Ajendra Singh e Poonam Tandon. "An efficient room-temperature liquefied petroleum gas sensor based on trirutile copper antimonate nano-polygons". New Journal of Chemistry 44, n. 28 (2020): 11949–58. http://dx.doi.org/10.1039/d0nj02528c.

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Poirier, Gaël, Michel Poulain e Marcel Poulain. "Copper and lead halogeno-antimoniate glasses". Journal of Non-Crystalline Solids 284, n. 1-3 (maggio 2001): 117–22. http://dx.doi.org/10.1016/s0022-3093(01)00389-1.

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Xue-Wen, Wang, Chen Qi-Yuan, Yin Zhou-Lan e Xiao Lian-Sheng. "Identification of arsenato antimonates in copper anode slimes". Hydrometallurgy 84, n. 3-4 (novembre 2006): 211–17. http://dx.doi.org/10.1016/j.hydromet.2006.05.013.

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Font, J. M., e R. G. Reddy. "Modelling of antimonate capacity in copper and nickel smelting slags". Mineral Processing and Extractive Metallurgy 114, n. 3 (settembre 2005): 160–64. http://dx.doi.org/10.1179/037195505x63349.

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Jackson, Everett D., e Amy L. Prieto. "Copper Antimonide Nanowire Array Lithium Ion Anodes Stabilized by Electrolyte Additives". ACS Applied Materials & Interfaces 8, n. 44 (31 ottobre 2016): 30379–86. http://dx.doi.org/10.1021/acsami.6b08033.

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Più fonti

Tesi sul tema "Copper antimonite"

Ramoroka, Morongwa Emmanuel. "Photophysics of Thiophenosalicylaldimine-functionalized G1-Polyprolyleniminato-Copper Telluride/Antimonide core-shell Nanomaterials". University of the Western Cape, 2018. http://hdl.handle.net/11394/6262.

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Magister Scientiae - MSc (Chemistry)
This work involves the synthesis of copper telluride-polypropylenimine tetra(5-(2-thienyl) salicylaldimine) (CuTe@PPI) and copper antimonide-polypropylenimine tetra(5-(2-thienyl) salicylaldimine) (CuSb@PPI) core-shell nanoparticles (NPs), using two-pots and one-pot synthesis methods, respectively. Their morphology was studied by X-ray diffraction spectroscopy (XRD), high resolution transmission electron microscopy (HRTEM) and high resolution scanning electron microscopy (HRSEM); while their structures were characterized by Fourier transform infrared spectroscopy (FTIR) and elemental analysis. Photophysical properties of the core-shell NPs were determined from ultraviolet-visible absorption spectroscopy (UV-Vis) and photoluminescence spectroscopy (PL). For core-shell NPs produced via two-pots method only CuTe@PPI exhibited ? ? ?* and n ? ?* which indicate that CuSb@PPI produced via two-pots method was unsuccessfully synthesized. The ? ? ?* and n ? ?* transitions indicate the presence of polypropylenimine tetra(5-(2-thienyl) salicylaldimine) (PPI) on the surface of CuTe NPs and CuSb NPs. FTIR confirmed coordination of PPI on the surface of CuTe NPs and CuSb NPs by showing a shift in wavenumber of C=N group bands from PPI. HR-TEM showed that the CuTe@PPI synthesized via one-pot method have a wide particles sizes distribution with an average particles size of 13.60 nm while for CuTe@PPI synthesized via two-pots it was impossible to determine the particles size due to aggregation. CuSb@PPI synthesized via twopots method and one-pot method has a wide particles sizes distribution with an average size of 7.98 nm and 11.61 nm respectively. The average particles sizes determined by HR-SEM were found to be 35.24 nm (CuTe@PPI two-pots method), 33.90 nm (CuTe@PPI one-pot method), 18.30 nm (CuSb@PPI two-pots method), and 16.18 nm (CuSb@PPI one pot method).
2021-08-31

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Zeier, Wolfgang G. [Verfasser]. "High temperature thermoelectric transport in quaternary copper selenides and ternary Zintl-antimonides / Wolfgang G. Zeier". Mainz : Universitätsbibliothek Mainz, 2015. http://d-nb.info/1075617022/34.

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Yakhshi, Tafti Mohsen. "Nanostructured Bulk Thermoelectrics : Scalable Fabrication Routes, Processing and Evaluation". Doctoral thesis, KTH, Skolan för informations- och kommunikationsteknik (ICT), 2016. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-186124.

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Current fossil fuel based energy sources have a huge shortcoming when one discusses their efficiency. The conversion efficiency of fossil fuel-based technologies is less than 40% in best cases. Therefore, until the renewable energy section is mature enough to handle all the energy demand one has to research and develop the technologies available to harvest the energy from the waste heat generated in fossil fuel-based supply sources. One of these emerging technologies is the use of thermoelectric (TE) devices to achieve this goal, which are solid-state devices capable of directly interconverting between heat and electrical energy. In the past decade there has been a significant scientific and financial investment within the field to enhance their properties and result in time/energy efficient fabrication processes of TE materials and devices for a more sustainable environment. In this thesis with use of chemical synthesis routes for nanostructured bulk thermoelectric materials iron antimonide (FeSb2), skutterudites (based on general formula of RzMxCo1-xSb3-yNy) and copper selenide (Cu2Se) are developed. These materials are promising candidates for use in thermoelectric generators (TEG) or for sensing applications. Using chemical synthesis routes such as chemical co-precipitation, salt melting in marginal solvents and thermolysis, fabrication of these TE materials with good performance can be performed with high degree of reproducibility, in a much shorter time, and easily scalable manner for industrial processes. The TE figure of merit ZT of these materials is comparable to, or better than their conventional method counterparts to ensure the applicability of these processes in industrial scale. Finally, through thorough investigation, optimized consolidation parameters were generated for compaction of each family of materials using Spark Plasma Sintering technique (SPS). As each family of TE nanomaterial investigated in this thesis had little to no prior consolidation literature available, specific parameters had to be studied and generated. The aim of studies on compaction parameters were to focus on preservation of the nanostructured features of the powder while reaching a high compaction density to have positive effects on the materials TE figure of merit.
Dagens fossilbränslebaserade energikällor har en enorm brist gällande effektivitet. Effektiviteten av fossilbränslebaserade teknologiers omvandling är mindre än 40 % i bästa fall. Därför tills förnybar energi är mogen nog att hantera alla energibehov, måste man forska och utveckla teknik för att skörda energi från spillvärme i fossilbränslebaserade försörjningskällor. En av dessa nya tekniker är tillämpning av termoelektriska (TE) material för att uppnå målet. Nämnde material är Soldi-State materialer som kan transformera mellan värme och elektrisk energi. Under det senaste decenniet har det pågått en stor vetenskaplig och ekonomisk investering inom området för att förbättra termoelektriska materials egenskaper. Dessutom ville man ta fram tid/energieffektiva TE material och komponenter för en mer hållbar miljö. I denna avhandling utvecklades och producerades termoelektriska material såsom järn antimonid (FeSb2), skutterudit (baserat på allmänna formeln RzMxCo1-xSb3-YNY) och koppar selenid (Cu2Se) med hjälp av kemiska syntesmetoder. Genom att Använda kemiska syntesmetoder som kemisk samutfällning, salt smältning i marginella lösningsmedel och termolys, kan material med hög grad av reproducerbarhet och ställbar för industriella processer tillverkas. Termoelektrisk omvandling effektivitet hos uppnådde material är betydligt högre än resultat av andra studier. I och med detta kan man säga att materialet kan användas inom industri. Slutligen, genom en grundlig undersökning optimerades packningsparametrar som genererades för packning av varje materialgrupp med hjälp av Spark Plasma Sintring teknik (SPS). Eftersom ingen relevant studie finns för varje grupp av termoelektriska nanomaterial som undersökts i denna avhandling, studerades och genererades dessa specifika parametrar. Syftet med studien är att fokusera på bevarande av nanostrukturerade egenskaperna hos pulvret och att samtidigt nå en hög packningstäthet för att ha positiva effekter på materialens termoelektriska omvandlingseffektivitet.

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Soria, Rodríguez Erick Santiago. "Estudio teórico experimental de la extracción de antimonio a partir de una solución electrolítica de cobre de nivel de planta piloto en la refinería de Ilo Southern Perú Copper Corporation". Universidad Nacional de Ingeniería. Programa Cybertesis PERÚ, 2009. http://cybertesis.uni.edu.pe/uni/2009/soria_re/html/index-frames.html.

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Runtti, H. (Hanna). "Utilisation of industrial by-products in water treatment:carbon-and silicate-based materials as adsorbents for metals and sulphate removal". Doctoral thesis, Oulun yliopisto, 2016. http://urn.fi/urn:isbn:9789526212630.

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Abstract Pollutant (such as metals and sulphate) contamination exists in the wastewaters of many industries, including mining operations, metal plating facilities, and tanneries. Adsorption is one of the most commonly used processes for the removal of pollutants from waters and wastewaters due to its high efficiency and simple operation. Activated carbon is the most frequently used adsorbent material, although its high cost inhibits its widespread use in wastewater treatment. Therefore, there is a need to develop other adsorbents from alternative inexpensive raw materials such as locally available industrial and mineral waste and by-products. The aim of this thesis was to study the possibility of using industrial waste materials such as carbon residue, metakaolin, blast-furnace slag and analcime as an inexpensive sorbent for iron, copper, nickel, arsenic, antimony and sulphate removal from aqueous solutions. To enhance their adsorption capacity, different chemical treatments (i.e. activation, modification, geopolymerisation) were performed. As a result, the level of removal of iron, copper and nickel by carbon residue and zinc chloride activated carbon residue was higher than that by the commercial activated carbon. Iron chloride modified carbon residue was the most effective sorbent material for sulphate removal when compared to the other studied chemically modified/activated carbon residues. Blast-furnace slag and metakaolin geopolymers as well as their raw materials, were examined for the simultaneous removal of nickel, arsenic and antimony from the spiked mine effluent. In the case of blast-furnace slag, geopolymerisation clearly increased the efficiency of nickel, arsenic and antimony removal to a beneficial level. The barium chloride modified blast-furnace-slag geopolymer was a very efficient sorbent material for sulphate removal and it could thus be a technically feasible sulphate sorbent for wastewater treatment (e.g. in the mining industry in applications in which very low sulphate levels are desired). Barium chloride modified acid washed analcime could also be a potential sorbent for sulphate removal
Tiivistelmä Teollisuuden jätevedet kuten kaivosvedet ja metalliteollisuuden prosessien jätevedet voivat sisältää monenlaisia haitallisia ja jopa myrkyllisiä aineita kuten metalleja ja sulfaattia. Adsorptiota käytetään yleisesti esimerkiksi metallien ja orgaanisten yhdisteiden poistossa vesiliuoksista, koska se on tehokas ja yksinkertainen menetelmä. Aktiivihiili on yleisimmin käytetty adsorbenttimateriaali vedenpuhdituksessa, mutta sen hinta joissain tapauksissa rajoittaa sen käyttöä. Tämän vuoksi on tarvetta kehittää vaihtoehtoisia adsorbenttimateriaaleja edullisista raaka-aineista. Viime vuosien aikana on raportoitu mm. teollisuus- ja mineraalijätteistä, joita voidaan hyödyntää vesien ja jätevesien puhdistuksessa. Tämän työn tavoitteena oli hyödyntää teollisuudesta muodostuvia jätemateriaaleja (hiilijäännös, metakaoliini, masuunikuona ja analsiimi) raudan, kuparin, nikkelin, arseenin, antimonin tai sulfaatin poistossa malli- ja jätevesistä. Materiaaleja käsiteltiin erilaisilla kemikaaleilla (aktivointi, modifiointi tai geopolymerointi), jotta niiden adsorptiotehokkuudet paranisivivat poistettavia aineita kohtaan. Tulokset osoittivat, että raudan, kuparin ja nikkelin poisto oli sekä käsittelemättömällä että sinkkikloridilla aktivoidulla hiilijäännöksellä korkeampi kuin kaupallisella aktiivihiilellä. Arseenin, nikkelin ja antimonin poistoa kaivosvedestä tutkittiin masuunikuona- ja metakaoliinigeopolymeereillä, joista masuunikuonageopolymeeri osoittautui tehokkaimmaksi metallien poistajaksi. Bariumkloridilla modifioitu masuunikuonageopolymeeri puolestaan poisti erittäin tehokkaasti sulfaattia kaivoksen jätevedestä. Rautakloridilla modifioitu hiilijäännös ja happopesty bariumkloridilla modifioitu analsiimi osoittatuivat myös lupaavaksi materiaaliksi sulfaatin poistossa

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Ricco, Isabel Maria Moreira. "Alternative oxidants and processing procedures for pyrotechnic time delays". Diss., 2004. http://hdl.handle.net/2263/27915.

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This study was directed at the pyrotechnic time delay compositions that are used in detonator assemblies. The objectives were to: --Investigate effective alternatives for the barium and lead-based oxidants currently used, maintaining the use of silicon as fuel --Develop easy to use, realistic measurement techniques for burn rates and shock tube ignitability --Determine the variables that affect burn rate, and --Evaluate alternative processing routes to facilitate intimate mixing of the component powders. Lead chromate and copper antimonite were found to be suitable oxidants for silicon in time delay compositions. They were ignitable by shock tubing, a relatively weak ignition source. The measured burn speeds for these systems showed a bimodal dependence on stoichiometry. Measured burn rates varied between 6-28 mm/s. Lead chromate is potentially a suitable alternative to the oxidant currently used in the medium burn rate commercial composition. It burns faster than copper antimonite. The latter is potentially a suitable replacement oxidant for the slow and medium compositions. Antimony trioxide-based compositions exhibited unreliable performance with respect to ignition with shock tubing. The addition of aluminium powder or fumed silica was found to reduce the burn rate. Increasing the silicon particle size (<3,5mm) also decreased the burn speed for copper antimonite and lead chromate compositions. Addition of fumed silica improved the flow properties of the lead chromate, copper antimonite and antimony trioxide powders allowing for easier mixing. The silicon powder was found to react violently with water in alkaline solutions. This makes particle dispersion in a wet-mixing process problematic.
Dissertation (MEng (Chemical Engineering))--University of Pretoria, 2006.
Chemical Engineering
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Capitoli di libri sul tema "Copper antimonite"

"antimonial copper (glance)". In Dictionary Geotechnical Engineering/Wörterbuch GeoTechnik, 56. Berlin, Heidelberg: Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-642-41714-6_12169.

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Newman, William R. "Extracting Our Venus". In Newton the Alchemist, 347–66. Princeton University Press, 2018. http://dx.doi.org/10.23943/princeton/9780691174877.003.0016.

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This chapter discusses Newton's attempt to purify his antimonial sublimate of copper vitriol from excess antimony and sal ammoniac to obtain a material that he calls “our Venus.” The project of “extracting our Venus” can be tracked from its origins up until February 1695/6, the last date in CU Add. 3973. It is possible that Newton's goal was to arrive not merely at a salt of copper in the modern sense, where the metal combines with other elements to yield a compound, but rather in the traditional alchemical sense whereby the copper is decomposed and its internal, constituent salt is released. Whether “our Venus” meant an internal constituent of the metal copper, or rather a compound of the metal, Newton spent years of effort trying to arrive at the substance in pure form.

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Atti di convegni sul tema "Copper antimonite"

Gamayunova, N. V., D. L. Bashlakov, O. E. Kvitnitskaya, A. V. Terekhov, Yu G. Naidyuk, Z. Bukowski e M. Babij. "Electron-phonon interaction in ternary rare-earth copper antimonides LaCuSb2 and La(Cu0.8Ag0.2)Sb2 probed by Yanson point-contact spectroscopy". In 2017 IEEE 7th International Conference "Nanomaterials: Application & Properties" (NAP). IEEE, 2017. http://dx.doi.org/10.1109/nap.2017.8190169.

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Westhoff, Kevin, e Todd M. Bandhauer. "Multi-Functional Electrolyte for Thermal Management of Lithium-Ion Batteries". In ASME 2016 14th International Conference on Fuel Cell Science, Engineering and Technology collocated with the ASME 2016 Power Conference and the ASME 2016 10th International Conference on Energy Sustainability. American Society of Mechanical Engineers, 2016. http://dx.doi.org/10.1115/fuelcell2016-59460.

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The high thermal conduction resistances of lithium-ion batteries severely limits the effectiveness of conventional external thermal management systems. To remove heat from the insulated interior portions of the cell, a large temperature difference is required across the cell, and the center of the electrode stack can exceed the thermal runaway onset temperature even under normal cycling conditions. One potential solution is to remove heat locally inside the cell by evaporating a volatile component of the electrolyte. In this system, a high vapor pressure co-solvent evaporates at a low temperature prior to triggering thermal runaway. The vapor generated is transported to the skin of the cell, where it is condensed and transported back to the internal portion of the cell via surface tension forces. For this system to function, a co-solvent that has a boiling point below the thermal runaway onset temperature must also allow the cell to function under normal operating conditions. Low boiling point hydrofluoroethers (HFE) were first used by Arai to reduce LIB electrolyte flash points, and have been proven to be compatible with LIB chemistry. In the present study, HFE-7000 and ethyl methyl carbonate (EMC) 1:1 by volume are used to solvate 1.0 M LiTFSI to produce a candidate electrolyte for the proposed cooling system. Copper antimonide (Cu2Sb) and lithium iron phosphate (LiFePO4) are used in a full cell architecture with the candidate electrolyte in a custom electrolyte boiling facility. The facility enables direct viewing of the vapor generation within the full cell and characterizes the galvanostatic electrochemical performance. Test results show that the LFP/Cu2Sb cell is capable of operation even when a portion of the more volatile HFE-7000 is continuously evaporated.

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