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1

Tang, Jian She, Brian J. Brown, Steven Verhaverbeke, Han Wen Chen, Jim Papanu, Raymond Hung, Cathy Cai e Dennis Yost. "Aqueous Based Single Wafer Cu/Low-k Cleaning Process Characterization and Integration into Dual Damascene Process Flow". Solid State Phenomena 103-104 (aprile 2005): 353–56. http://dx.doi.org/10.4028/www.scientific.net/ssp.103-104.353.

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Abstract (sommario):
As device features scale down to 90nm and Cu/low-k films are employed for back end interconnects, post etch and ash residue cleaning becomes increasingly challenging due to the higher aspect ratio of the features, tighter CD control requirements, sensitivity of the low-k films, and the requirement for high wet etch selectivity between CuxO and Cu. Traditional solvent based cleaning in wet benches has additional issues such as wafer cross-contamination and high disposal cost [1, 2]. We have developed a novel aqueous solution (AQ) based single wafer cleaning process to address these challenges. The results of physical characterization, process integration electrical data, and process integration reliability data such as electromigration (EM) and stress migration data are presented. The main conclusions can be summarized as follows: (1) The single wafer cleaning process developed on the Oasis™ system can clean post etch residues and simultaneously clean the wafer front side and backside metallic contaminants; (2) In terms CuxO and Cu wet etch selectivity, CD loss control, the Oasis™ aqueous single wafer clean process is superior to the bench solvent cleaning process; (3)The Oasis aqueous cleaning process shows no undercut below etchstop due to the very low Cu etch amount in one cleaning pass, therefore the electromigration and stress migration performance of the aqueous Oasis processed wafers is clearly better than that of the solvent bench processed wafers.
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2

Jung, Chung Kyung, Sung Wook Joo, Sang Wook Ryu, S. Naghshineeh, Yang Lee e Jae Won Han. "Improved Cleaning Process for Etch Residue Removal in an Advanced Copper/Low-k Device without the Use of DMAC (Dimethylacetamide)". Solid State Phenomena 187 (aprile 2012): 245–48. http://dx.doi.org/10.4028/www.scientific.net/ssp.187.245.

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Abstract (sommario):
Plasma dry etching processes are commonly used to fabricate sidewalls of trenches and vias for copper / low-k dual damascene devices. Typically, some polymers remain in the trench and at the via top and sidewall. Other particulate etch residues are may remained in the bottom and on the sidewalls of vias. Generally, the particulate consists of mixtures of copper oxide with polymers. The polymers on the sidewalls and the particulate residues at the bottom of vias must be removed prior to the next process step. Small amounts of polymer are intentionally left on the sidewalls of trenches and vias during the etching in order to achieve a vertical profile and to protect the low-k materials under the etching mask. Until now, the industry has relied mainly on organic solvent containing mixtures to clean etch / ash residues from such devices. The effectiveness of available residue removers varies with the specific process and also depends on which new integration materials are used. New materials typically include Cu, TaN, low-k dielectrics and others [1-. Solvent content is thought to aid the removal of polymer residues and particulates produced during plasma dry etching processes. Therefore, in the past we have used a residue remover which contains DMAC (dimethylacetamide). But the use of DMAC is banned in microelectronic fabrication facilities in Europe because of its toxicity. Thus we wanted to find and evaluate a DMAC-free residue remover for removing polymer residues while maintaining high selectivity to the copper and ILD films.
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3

Perng, Dung-Ching, Jia-Feng Fang e Jhin-Wei Chen. "Single mask dual damascene processes". Microelectronic Engineering 85, n. 3 (marzo 2008): 599–602. http://dx.doi.org/10.1016/j.mee.2007.11.003.

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4

Ogawa, E. T., Ki-Don Lee, V. A. Blaschke e P. S. Ho. "Electromigration reliability issues in dual-damascene Cu interconnections". IEEE Transactions on Reliability 51, n. 4 (dicembre 2002): 403–19. http://dx.doi.org/10.1109/tr.2002.804737.

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5

Heo, Jung Shik, Jun Hwan Oh, Hong Jae Shin e Nae In Lee. "Cu Dendrite Formation in Post Trench Etch Cleaning". Solid State Phenomena 145-146 (gennaio 2009): 331–33. http://dx.doi.org/10.4028/www.scientific.net/ssp.145-146.331.

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Abstract (sommario):
Copper has been widely used as the interconnect material for integrated circuits because of the good electrical conductivity and electron migration resistance. Copper dual damascene structure has been adapted due to the impossibility of etching the copper. For via first dual damascene (VFDD) integration, via is opened after trench etch. Generally, diluted HF cleaning after trench etch is used to remove both etch residues and carbon depletion layer of low-k material. In this study, we investigated the characteristics of copper dendritic formation occurred in post trench etch cleaning with single wafer spin tool (SWST).
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6

Pyun, Jung Woo, Won-Chong Baek, Lijuan Zhang, Jay Im, Paul S. Ho, Larry Smith e Gregory Smith. "Electromigration behavior of 60 nm dual damascene Cu interconnects". Journal of Applied Physics 102, n. 9 (novembre 2007): 093516. http://dx.doi.org/10.1063/1.2805425.

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7

Hu, C. K., L. Gignac, E. Liniger e R. Rosenberg. "Electromigration in On-Chip Single/Dual Damascene Cu Interconnections". Journal of The Electrochemical Society 149, n. 7 (2002): G408. http://dx.doi.org/10.1149/1.1482057.

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8

Kriz, J., C. Angelkort, M. Czekalla, S. Huth, D. Meinhold, A. Pohl, S. Schulte, A. Thamm e S. Wallace. "Overview of dual damascene integration schemes in Cu BEOL integration". Microelectronic Engineering 85, n. 10 (ottobre 2008): 2128–32. http://dx.doi.org/10.1016/j.mee.2008.05.034.

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9

Oates, A. S., e S. C. Lee. "Electromigration failure distributions of dual damascene Cu /low – k interconnects". Microelectronics Reliability 46, n. 9-11 (settembre 2006): 1581–86. http://dx.doi.org/10.1016/j.microrel.2006.07.038.

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10

Wu, ZhenYu, YinTang Yang, ChangChun Chai, YueJin Li, JiaYou Wang, Jing Liu e Bin Liu. "Temperature-dependent stress-induced voiding in dual-damascene Cu interconnects". Microelectronics Reliability 48, n. 4 (aprile 2008): 578–83. http://dx.doi.org/10.1016/j.microrel.2007.12.001.

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11

Lee, Ki-Don, Ennis T. Ogawa, Hideki Matsuhashi, Patrick R. Justison, Kil-Soo Ko, Paul S. Ho e Volker A. Blaschke. "Electromigration critical length effect in Cu/oxide dual-damascene interconnects". Applied Physics Letters 79, n. 20 (12 novembre 2001): 3236–38. http://dx.doi.org/10.1063/1.1418034.

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12

Lee, K. D., e P. S. Ho. "Statistical Study for Electromigration Reliability in Dual-Damascene Cu Interconnects". IEEE Transactions on Device and Materials Reliability 4, n. 2 (giugno 2004): 237–45. http://dx.doi.org/10.1109/tdmr.2004.827679.

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13

Ogawa, Ennis T., Ki-Don Lee, Hideki Matsuhashi, Paul S. Ho, Volker A. Blaschke e Robert H. Havemann. "Reliability and early failure in Cu/oxide dual-damascene interconnects". Journal of Electronic Materials 31, n. 10 (ottobre 2002): 1052–58. http://dx.doi.org/10.1007/s11664-002-0042-6.

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14

Fayolle, M., J. Torres, G. Passemard, F. Fusalba, G. Fanget, D. Louis, M. Assous et al. "Integration of Cu/SiOC in Cu dual damascene interconnect for 0.1-μm technology". Microelectronic Engineering 64, n. 1-4 (ottobre 2002): 35–42. http://dx.doi.org/10.1016/s0167-9317(02)00769-4.

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15

Vairagar, A. V., S. G. Mhaisalkar, M. A. Meyer, E. Zschech e Ahila Krishnamoorthy. "Reservoir effect on electromigration mechanisms in dual-damascene Cu interconnect structures". Microelectronic Engineering 82, n. 3-4 (dicembre 2005): 675–79. http://dx.doi.org/10.1016/j.mee.2005.07.076.

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16

Hu, C.-K., L. Gignac, S. G. Malhotra, R. Rosenberg e S. Boettcher. "Mechanisms for very long electromigration lifetime in dual-damascene Cu interconnections". Applied Physics Letters 78, n. 7 (12 febbraio 2001): 904–6. http://dx.doi.org/10.1063/1.1347400.

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17

Lee, Ki-Don, Ennis T. Ogawa, Sean Yoon, Xia Lu e Paul S. Ho. "Electromigration reliability of dual-damascene Cu/porous methylsilsesquioxane low k interconnects". Applied Physics Letters 82, n. 13 (31 marzo 2003): 2032–34. http://dx.doi.org/10.1063/1.1564294.

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18

Gotkis, Y., e S. Guha. "Cu-CMP for dual damascene technology: Prestonian vs. non-prestonian regimes of Cu removal". Journal of Electronic Materials 30, n. 4 (aprile 2001): 396–99. http://dx.doi.org/10.1007/s11664-001-0050-y.

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19

Nagahara, Seiji, Masashi Fujimoto, Mitsuharu Yamana, Susumu Watanabe, Kazutoshi Shiba e Makoto Tominaga. "Elimination of Resist Poisoning in Via-First Dual Damascene Processes". Journal of Photopolymer Science and Technology 16, n. 3 (2003): 351–61. http://dx.doi.org/10.2494/photopolymer.16.351.

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20

Lau, J., P. Tzeng, C. Lee, C. Zhan, M. Li, J. Cline, K. Saito et al. "Redistribution Layers (RDLs) for 2.5D/3D IC Integration". Journal of Microelectronics and Electronic Packaging 11, n. 1 (1 gennaio 2014): 16–24. http://dx.doi.org/10.4071/imaps.406.

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Abstract (sommario):
Redistribution layer (RDL) is an integral part of 3D IC integration, especially for 2.5D IC integration with a passive interposer. The RDL allows for circuitry fan-outs of and allows for lateral communication between the chips attached to the interposer. There are at least two ways to fabricate the RDL, namely (1) polymers to make the passivation and Cu-plating to make the metal layer, and (2) semiconductor back-end-of-line Cu damascene. In this study, the materials and processes of these methods are presented. Emphasis is placed on the Cu damascene method.
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21

Lau, J., P. Tzeng, C. Lee, C. Zhan, M. Li, J. Cline, K. Saito et al. "Redistribution Layers (RDLs) for 2.5D/3D IC Integration". International Symposium on Microelectronics 2013, n. 1 (1 gennaio 2013): 000434–41. http://dx.doi.org/10.4071/isom-2013-wa12.

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Abstract (sommario):
Redistribution layer (RDL) is an integral part of 3D IC integration, especially for 2.5D IC integration with a passive interposer. The RDL allows for fans out of the circuitries and allows the lateral communication between the chips attached to the interposer. There are at least two ways to fabricate the RDL, namely (a) polymers to make the passivation and Cu-plating to make the metal layer, and (b) semiconductor back-end-of-line Cu damascene. In this study, the materials and processes of these methods are presented. Emphasis is placed on the Cu damascene method.
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22

Maestre Caro, A., Y. Travaly, G. Beyer, Z. Tokei, G. Maes, G. Borghs e S. Armini. "Selective self-assembled monolayer coating to enable Cu-to-Cu connection in dual damascene vias". Microelectronic Engineering 106 (giugno 2013): 76–80. http://dx.doi.org/10.1016/j.mee.2012.12.028.

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23

Vairagar, A. V., S. G. Mhaisalkar e Ahila Krishnamoorthy. "Electromigration behavior of dual-damascene Cu interconnects––Structure, width, and length dependences". Microelectronics Reliability 44, n. 5 (maggio 2004): 747–54. http://dx.doi.org/10.1016/j.microrel.2003.12.011.

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24

Li, H. Y., Y. J. Su, C. F. Tsang, S. M. Sohan, V. Bliznetsov e L. Zhang. "Process improvement of 0.13μm Cu/Low K (Black DiamondTM) dual damascene interconnection". Microelectronics Reliability 45, n. 7-8 (luglio 2005): 1134–43. http://dx.doi.org/10.1016/j.microrel.2004.11.057.

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25

Nagaishi, H., M. Fukui, H. Asakura e A. Sugimoto. "Defect reduction in Cu dual damascene process using short-loop test structures". IEEE Transactions on Semiconductor Manufacturing 16, n. 3 (agosto 2003): 446–51. http://dx.doi.org/10.1109/tsm.2003.815622.

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26

Ueki, M., M. Hiroi, N. Ikarashi, T. Onodera, N. Furutake, N. Inoue e Y. Hayashi. "Effects of Ti Addition on Via Reliability in Cu Dual Damascene Interconnects". IEEE Transactions on Electron Devices 51, n. 11 (novembre 2004): 1883–91. http://dx.doi.org/10.1109/ted.2004.837579.

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27

Jiang, P., F. G. Celii, W. W. Dostalik, K. J. Newton e H. Sakima. "Trench etch processes for dual damascene patterning of low-k dielectrics". Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films 19, n. 4 (luglio 2001): 1388–91. http://dx.doi.org/10.1116/1.1380717.

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28

Lee, Soo Geun, Yun Jun Kim, Seung Pae Lee, Hyeok-Sang Oh, Seung Jae Lee, Min Kim, Il-Goo Kim et al. "Low Dielectric Constant 3MS α-SiC:H as Cu Diffusion Barrier Layer in Cu Dual Damascene Process". Japanese Journal of Applied Physics 40, Part 1, No. 4B (30 aprile 2001): 2663–68. http://dx.doi.org/10.1143/jjap.40.2663.

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29

Yan, M. Y., K. N. Tu, A. V. Vairagar, S. G. Mhaisalkar e Ahila Krishnamoorthy. "A direct measurement of electromigration induced drift velocity in Cu dual damascene interconnects". Microelectronics Reliability 46, n. 8 (agosto 2006): 1392–95. http://dx.doi.org/10.1016/j.microrel.2005.11.004.

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30

Motte, P., J. Torres, J. Palleau, F. Tardif, O. Demolliens e H. Bernard. "Dielectric deposition process for Cu/SiO2 integration in a dual damascene interconnection architecture". Microelectronic Engineering 50, n. 1-4 (gennaio 2000): 487–93. http://dx.doi.org/10.1016/s0167-9317(99)00319-6.

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31

Vairagar, A. V., S. G. Mhaisalkar, M. A. Meyer, E. Zschech, Ahila Krishnamoorthy, K. N. Tu e A. M. Gusak. "Direct evidence of electromigration failure mechanism in dual-damascene Cu interconnect tree structures". Applied Physics Letters 87, n. 8 (22 agosto 2005): 081909. http://dx.doi.org/10.1063/1.2033136.

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32

Usui, Takamasa, Tadayoshi Watanabe, Masaaki Hatano, Sachiyo Ito, Junichi Wada e Hisashi Kaneko. "Electromigration of Al-0.5 wt%Cu with Nb-Based Liner Dual Damascene Interconnects". Japanese Journal of Applied Physics 43, n. 10 (8 ottobre 2004): 6957–62. http://dx.doi.org/10.1143/jjap.43.6957.

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33

Vairagar, A. V., Zhenghao Gan, Wei Shao, S. G. Mhaisalkar, Hongyu Li, K. N. Tu, Zhong Chen, E. Zschech, H. J. Engelmann e Sam Zhang. "Improvement of Electromigration Lifetime of Submicrometer Dual-Damascene Cu Interconnects Through Surface Engineering". Journal of The Electrochemical Society 153, n. 9 (2006): G840. http://dx.doi.org/10.1149/1.2217267.

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34

Yan, M. Y., J. O. Suh, F. Ren, K. N. Tu, A. V. Vairagar, S. G. Mhaisalkar e Ahila Krishnamoorthy. "Effect of Cu3Sn coatings on electromigration lifetime improvement of Cu dual-damascene interconnects". Applied Physics Letters 87, n. 21 (21 novembre 2005): 211103. http://dx.doi.org/10.1063/1.2132536.

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35

Ogawa, Ennis T., Alexander J. Bierwag, Ki-Don Lee, Hideki Matsuhashi, Patrick R. Justison, Anup N. Ramamurthi, Paul S. Ho et al. "Direct observation of a critical length effect in dual-damascene Cu/oxide interconnects". Applied Physics Letters 78, n. 18 (30 aprile 2001): 2652–54. http://dx.doi.org/10.1063/1.1365414.

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36

Vairagar, A. V., S. G. Mhaisalkar, Ahila Krishnamoorthy, K. N. Tu, A. M. Gusak, Moritz Andreas Meyer e Ehrenfried Zschech. "In situobservation of electromigration-induced void migration in dual-damascene Cu interconnect structures". Applied Physics Letters 85, n. 13 (27 settembre 2004): 2502–4. http://dx.doi.org/10.1063/1.1795978.

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37

Furusawa, Takeshi, Shuntaro Machida, Daisuke Ryuzaki, Kenji Sameshima, Takeshi Ishida, Kensuke Ishikawa, Noriko Miura, Nobuhiro Konishi, Tatsuyuki Saito e Hizuru Yamaguchi. "Dual-Damascene Cu/Low-k Interconnect Fabrication Scheme Using Dissoluble Hard Mask Material". Journal of The Electrochemical Society 153, n. 2 (2006): G160. http://dx.doi.org/10.1149/1.2149297.

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38

Rossnagel, S. M. "Filling dual damascene interconnect structures with AlCu and Cu using ionized magnetron deposition". Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures 13, n. 1 (gennaio 1995): 125. http://dx.doi.org/10.1116/1.588004.

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39

Weng, C. J. "Novel Approach of Semiconductor Manufacturing Process on Copper Dual Damascene Processes Integration". Strain 45, n. 3 (giugno 2009): 221–31. http://dx.doi.org/10.1111/j.1475-1305.2009.00599.x.

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40

Shao, W., S. G. Mhaisalkar, T. Sritharan, A. V. Vairagar, H. J. Engelmann, O. Aubel, E. Zschech, A. M. Gusak e K. N. Tu. "Direct evidence of Cu/cap/liner edge being the dominant electromigration path in dual damascene Cu interconnects". Applied Physics Letters 90, n. 5 (29 gennaio 2007): 052106. http://dx.doi.org/10.1063/1.2437689.

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41

Motoyama, K., O. van der Straten, J. Maniscalco e M. He. "PVD Cu Reflow Seed Process Optimization for Defect Reduction in Nanoscale Cu/Low-k Dual Damascene Interconnects". Journal of The Electrochemical Society 160, n. 12 (2013): D3211—D3215. http://dx.doi.org/10.1149/2.035312jes.

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42

Pipia, Francesco, Annamaria Votta, Alice C. Elbaz, Salvo Grasso, Enrica Ravizza, Simona Spadoni e Mauro Alessandri. "Cu Surface Characterization after Wet Cleaning Processes". Solid State Phenomena 145-146 (gennaio 2009): 371–75. http://dx.doi.org/10.4028/www.scientific.net/ssp.145-146.371.

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Abstract (sommario):
In damascene architecture, widely used both in flash memories and in DRAM as interconnect scheme since 90 nm node, copper surface is exposed after via etch. A deep understanding of the effect of different wet cleanings on Cu surface is therefore mandatory, not only to ensure an efficient post etch polymer removal, but also to provide a better surface termination, capable to minimize Cu oxidation kinetic and to reduce the growth of Cu-rich precipitates which may negatively effect contact resistance. In this work we have analyzed the Cu surface after processing with several cleaning chemistries -often present in BEOL cleaning processes- using XPS (X-ray Photoelectron Spectroscopy) and ToF-SIMS (Time of Flight – Secondary Ion Mass Spectroscopy), fast and powerful techniques widely used in Cu surface characterization [1]. In addition, the evolution of the surface with storage time has been monitored using the same techniques, in order to better understand the effect of the different cleaning chemistries. XPS has been proven to be very sensitive to monitor Cu oxidation, while ToF-SIMS has been used to reveal organic species adsorbed on the surface.
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43

Shao, W., Z. H. Gan, S. G. Mhaisalkar, Zhong Chen e Hongyu Li. "The effect of line width on stress-induced voiding in Cu dual damascene interconnects". Thin Solid Films 504, n. 1-2 (maggio 2006): 298–301. http://dx.doi.org/10.1016/j.tsf.2005.09.064.

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44

Gignac, L. M., C. K. Hu e E. G. Liniger. "Correlation of electromigration lifetime distribution to failure mode in dual Damascene Cu/SiLK interconnects". Microelectronic Engineering 70, n. 2-4 (novembre 2003): 398–405. http://dx.doi.org/10.1016/s0167-9317(03)00284-3.

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45

Ueki, Makoto, Munehiro Tada, Masayoshi Tagami, Mitsuru Narihiro, Fuminori Ito e Yoshihiro Hayashi. "A Robust Low-$k$/Cu Dual Damascene Interconnect (DDI) With Sidewall Protection Layer (SPL)". IEEE Transactions on Device and Materials Reliability 11, n. 1 (marzo 2011): 98–105. http://dx.doi.org/10.1109/tdmr.2011.2106130.

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46

Bana, F., L. Arnaud, D. Ney e Y. Wouters. "Investigation on the multi-voids formation during electromigration degradation in dual damascene Cu lines". Microelectronic Engineering 112 (dicembre 2013): 130–32. http://dx.doi.org/10.1016/j.mee.2012.11.028.

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47

Kabansky, A., S. S. H. Tan, E. A. Hudson, G. Delgadino, L. Gancs e J. Marks. "Effective Defect Control in TiN Metal Hard Mask Cu/Low-k Dual Damascene Process". ECS Transactions 58, n. 6 (31 agosto 2013): 143–50. http://dx.doi.org/10.1149/05806.0143ecst.

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48

Tagami, Masayoshi, e Yoshihiro Hayashi. "Thermal Stress Control in Cu Dual Damascene Interconnects with Low-k Organic Polymer Film". Journal of The Electrochemical Society 157, n. 12 (2010): H1071. http://dx.doi.org/10.1149/1.3486808.

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49

Izumitani, Junko, Daisuke Kodama, Shigenori Kido, Hiroyuki Chibahara, Yoshihiro Oka, Kinya Goto, Naohito Suzumura, Masahiko Fujisawa e Hiroshi Miyatake. "Cu Dual-Damascene Interconnects with Direct Chemical Mechanical Polishing Process on Porous Low-kFilm". Japanese Journal of Applied Physics 49, n. 5 (20 maggio 2010): 05FC02. http://dx.doi.org/10.1143/jjap.49.05fc02.

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50

Lee, Sang-Yun, Yong-Bae Kim e Jeong Soo Byun. "Inorganic Si-O-C Antireflection Coating at 193 nm for Cu Dual Damascene Process". Journal of The Electrochemical Society 150, n. 1 (2003): G58. http://dx.doi.org/10.1149/1.1528944.

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