Tesi sul tema "Iron ores – Geology – South Africa"

M.Sc.
Biofuels have the potential to reduce a country’s dependence on imported oil, to ensure diversity of energy sources, to increase the availability of renewable energy sources and to address global environmental issues. In recognition of the potential benefits of the production and use of biofuels, the Department of Minerals and Energy released the Draft Biofuels Industrial Strategy in December 2006 with the aim to increase the use of biofuels in South Africa to replace 4.5% of conventional transport fuels by 2013. However, there are several barriers that need to be overcome before South Africa can establish a large-scale biofuel industry to achieve the DME’s biofuel target. This includes environmental barriers, such as the availability of land for the cultivation of biofuel feedstocks and potential threats to food security. This study focuses on these environmental barriers and aims to determine the potential for bioethanol production from maize in South Africa to 2013. To this purpose, a bioethanol potential model is developed to simulate the potential for bioethanol production from maize in South Africa between 2008 and 2013. The model incorporates four key elements that all impact on the availability of maize for bioethanol production, namely: maize demand; maize supply; the demand for maize as biomaterial; and the available land area for the cultivation of maize. The study makes further use of the scenario planning method to determine the potential for bioethanol production from maize in South Africa. Four unique bioethanol potential scenarios are designed and simulated within the bioethanol potential model developed for this purpose. Each scenario plays out a different Abstract storyline for the future social, economic and natural environment that will impact on the availability of maize for bioethanol production. The results of the bioethanol potential scenario simulations show that South Africa will be able to produce enough maize to meet the DME’s biofuel target of 1.2 billion liters of bioethanol for all scenarios between 2009 and 2010. From 2011 onwards, the bioethanol potential decreases below the DME’s target value in both the worst case and rapid change scenarios. The study concludes that the production of bioethanol from maize in South Africa will have various social, economic and environmental consequences for the country’s agricultural sector. The depletion of domestic maize supplies will seriously threaten food security and consequently, increase the country’s dependence on maize imports. This will not only affect the country’s maize producing regions, but spread throughout South Africa as the demand for agriculturally productive land for maize production increases. Domestic food security is therefore at risk and South Africa will have to resort to other energy technologies to achieve a sustainable and renewable energy future for road transport.

M.Sc. (Geology)
Nel, B.P. (2013). Petrography and geochemistry of iron formations of the Paleoproterozoic Koegas Subgroup, Transvaal Supergroup, Griqualand West, South Africa. MSc thesis (unpublished), University of Johannesburg, Aucklandpark, pp. 133. The Early Paleoproterozoic Koegas Subgroup comprises a succession of siltstone, mudstone, iron-­‐formation, chert and carbonate rocks that overlies the iron-­‐formations of the Asbestos Hills Subgroup with sharp contact. It is overlain with erosional unconformable contact by glaciogenic diamictites of the Makaganyene Formation. This study focused on the lithostratigraphy, mineralogy and geochemistry of the iron-­‐ formations of the Koegas Subgroup based on fresh diamond drill core samples obtained during the Agouron scientific drilling project in South Africa in 2004. The iron formations the Koegas Subgroup are represented by a few important lithotypes, occurring in distinct sedimentary facies, which formed in unique depositional and diagenetic environments. The iron formations consist essentially of four facies, namely silicate lutite, mixed silicate-­‐siderite lutite, siderite lutite and siderite peloidstone A repetitive sedimentary cycle consisting of fine-­‐grained chemical lithotypes grading upward into reworked chemical lithotypes is evident throughout the Koegas Subgroup iron formations. Silicate lutite formed in deep water settings well below the wave base along a chemocline. Siderite lutite formed in shallower parts of the basin through transformation of primary ferric iron precipitate by iron respiration in presence of organic carbon. Peloidstone formed above normal wave base in shallow water by reworking of earlier siderite lutite deposits. The REE geochemistry provides important clues as to the depositional environment of the iron formation as follows. Depletion in LREE and enrichment in HREE combined with positive Y are typical of ocean water indicate that the iron formations were deposited in a marine environment. Positive Eu anomaly suggest the presence of a hydrothermal component in the ocean water from which the iron formations were deposited. Negative Ce anomalies indicate that somewhere in the marine system Ce3+ was oxidized to Ce4+ oxide, probably in the presence of free oxygen in the ocean water column (Bau and Dulski, 1996). The negative Ce anomalies seen in the Koegas iron formations are the oldest currently known from iron formations. As such the Ce anomalies most probably signify an increase in the oxygenation state of the ocean immediately prior to the rise of atmospheric oxygen as defined by Guo et al. (2009).

M. Sc.
The Pering Pb-Zn deposit is hosted in the stromatolitic dolomites of the Campbellrand Subgroup of the Ghaap Group, Transvaal Supergroup. The deposit is situated 20 km northeast of the town Reivilo in the semi-arid region of the Northwest Province, South Africa. It has been classified as a Mississippi Valley type deposit and is, together with the Bushy Park Pb-Zn deposit and F-Pb-Zn deposits near Zeerust, the only known MVT deposit of Paleoproterozoic age. The Pering open cast mine has been operational since 1986, yielding 18 Mt at an average ore grade of 3.6 wt.% Zn and 0.6 wt.% Pb. The aim of this study is to devise a metallogenetic model by integrating core logging, petrography, fluid inclusion and stable C-0-S isotope studies. The mineralogy includes sphalerite, galena and minor chalcopyrite as ore minerals, with diagenetic pyrite, hydrothermal dolomite, quartz and calcite as gangue minerals. Sphalerite predominates over galena. Mineralisation occurs as (a) disseminated stratabound replacements sheets restricted mainly to stromatolitic zones of the Steekdorings Member of the Reivilo Formation, and as (b) open space infill in breccia bodies that cross-cut the stratigraphy. Three events of hydrothermal brecciation, resultant of prolonged pulses of fluid infiltration, and mineralisation are recognised. The first brecciation event is marked by the cementation of the dolomite host rock by sparry dolomite, closely associated with finegrained disseminated sphalerite and galena. The second brecciation event is of minor importance, and is marked by the formation of small amounts of the second sphalerite generation, while the third, and final, brecciation event is marked by the formation of euhedral sphalerite, galena, quartz, sparry dolomite, and calcite as open space fill.

Ph.D.
The economically important sedimentary manganese deposits of the Paleoproterozoic Kalahari and Postmasburg manganese fields, are situated in close geographic vicinity to each other in the Griqualand West region of the Northern Cape Province, South Africa. This thesis describes aspects of mineralogy, petrography and geochemistry of the manganese ores with the purpose to establish genetic models for genesis and alteration of manganese ores of both manganese fields. The Kalahari manganese field, situated some 60 km northwest of Kuruman, is the largest known land-based manganese deposit. Manganese ores occur interbedded with iron-formations of the Hotazel Formation of the Voelwater Subgroup of the Late Archean-Paleoproterozoic Transvaal Supergroup. The sediments of the Voelwater Subgroup are preserved in five erosional relics, of which the Kalahari manganese deposit is by far the largest and the only one of economic importance. Two types of ore are mined, low-grade sedimentary Mamatwan-type ore and high-grade Wesselstype ore. Mamatwan-type ore is represented by microcrystalline laminated braunite-lutite composed of kutnahorite, Mn-calcite, braunite and hematite, modified by the occurrence of late diagenetic or metamorphic hausmannite, partridgeite, manganite and calcite. Mamatwan-type ore contains up to 38 mass % Mn and constitutes about 97 % of the ore reserves in the Kalahari manganese deposit. High-grade Wessels-type ore, with a manganese content of between 42 to 48 mass % Mn (on average), constitutes about 3 % of the ore reserves. It occurs only in the northwestern part of the main Kalahari deposit, and in small deposits at Hotazel and Langdon, in association with a system of north-south striking normal faults. The Wessels alteration event is thought to be related to the Kibaran orogenetic event (about 1.1 Ga). Fault zones are ferruginized and alongside faults sedimentary Mamatwan-type ore has been hydrothermally upgraded to Wessels-type ore. Metasomatic fronts are defined by changing mineral associations. These associations clearly illustrate that decreasing degrees of alteration relate to increasing distance from the fluid feeders. Areas of unaltered Mamatwan-type ore are preserved in the core of fault blocks. Wessels-type ore consists mostly of hausmannite, bixbyite, braunite II and manganite and subordinate gangue minerals such as clinochlore and andradite but the mineral assemblage associated with the Wessels alteration event is unusually diverse. More than 100 minerals have been identified, amongst them 8 new mineral species and an unusual, ferrimagnetic, Fe-rich variety of hausmannite. Mass balance calculations illustrate that the upgrading of the Wessels-type manganese ore is a consequence of leaching of CaO, MgO, CO 2, and Si02 from a low-grade Mamatwan-type precursor. This metasomatic process results in increasing secondary porosities, compaction of the orebody to two thirds of its original thickness and consequently residual enrichment of manganese in the ores. Three younger alteration events are observed in the Kalahari manganese deposit. These are only of minor economic importance. Wallrock alteration associated with the Mamatwan alteration event is characterized by reductive leaching of Fe and Mn around syntectonic veins and joints with pyritechalcopyrite- carbonate mineralization. The alteration is explained by infiltration of epithermal solutions that were introduced along veins or joints. The timing of the alteration event has tentatively been placed into the Pre-Karoo era. The Smartt alteration event is associated with intensive faulthosted brecciation and replacement of braunite and carbonates of the Mamatwan-type ore by todorokite and manganomelane, a process that causes considerable upgrading of the manganese ore next to a fault breccia at Mamatwan mine, and the formation of stratiform cross-fibre todorokite veins at Smartt mine. The Smartt alteration event postdates the Mamatwan alteration event and has tentatively been correlated with Pre-Kalahari groundwater circulation. Supergene alteration of the ores took place in Kalahari and Post-Kalahari times. It is characterized by the occurrence of cryptomelane, pyrolusite and other typically supergene manganese oxides along the suboutcrop of the Hotazel Formation beneath the Cenozoic Kalahari Formation. The Postmasburg manganese field is situated about 120 km to the south of the Kalahari manganese field on the Maremane dome. Two arcuate belts of deposits extend from Postmasburg in the south to Sishen in the north. Two major ore types are present. The ferruginous type of ore is composed mainly of braunite, partridgeite and bixbyite and occurs along the centre of the Gamagara Ridge, or Western belt. The siliceous type of ore consists of braunite, quartz and minor partridgeite and occurs in small deposits along the Klipfontein Hills (or Eastern belt) and the northern and southern extremities of the Gamagara Ridge. Geological and geochemical evidence suggest that the manganese ores represent weakly metamorphosed wad deposits that accumulated in karst depressions during a period of lateritic weathering and karstification in a supergene, terrestrial environment during the Late Paleoproterozoic. The dolomites of the Campbellrand Group of the Transvaal Supergroup are host and source for the wad accumulations. Contrasting geological settings are suggested for the accumulation of the siliceous and the ferruginous types of ore respectively. The former originated as small pods and lenses of wad in chert breccia that accumulated in a karst cave system capped by the hematitized Manganore iron-formation of the Transvaal Supergroup. The cave system finally collapsed and the hematitized iron-formation slumped into the sinkhole structures. The ferruginous type of ore accumulated as mixed wad-clay sediment trapped in surficial sinkhole depressions in the paleokarst surface. The orebodies are conformably overlain by the Doornfontein hematite pebble conglomerate or aluminous shales belonging to the Gamagara Formation of the Late Paleoproterozoic Olifantshoek Group. Well preserved karst laterite paleosol profiles, described from the basal section of the Gamagara Formation, provide a strong argument for the terrestrial, supergene origin of the manganese ores. The manganese ores in the Postmasburg manganese field were affected by diagenesis and lower greenschist facies metamorphism. Metamorphism resulted in recrystallization to braunite in the siliceous ores of the Eastern belt, and to massive or mosaic textured braunite and idioblastic partridgeite in the ferruginous environment of the Western belt. Secondary karstification and supergene weathering are evidence for renewed subaerial exposure of the manganese ore and their host rocks. The metamorphic mineral assemblage is replaced by abundant romanechite, lithiophorite and other supergene manganese oxides. Comparison between the Kalahari- and the Postmasburg manganese field shows that sedimentary manganese accumulation took place in entirely different depositional environments and owing to different mechanisms. Their close geographic relationship appears to be coincidental. Apparent similarities arise as a consequence of regional geological events that postdate the deposition of the manganese ores. These similarities include the lower greenschist facies metamorphic overprint, an event tentatively related to thrusting and crustal thickening during the Kheis orogenetic event, and syn- to Post-Kalahari supergene alteration. The correlation of structurally controlled hydrothermal alteration events in the Kalahari manganese field and the Postmasburg manganese field remains difficult due to the absence of the necessary geochronological constraints.

A dissertation submitted to the Faculty of Science, University of the Witwatersrand, Johannesburg, for the Degree of Doctor of Philosophy Johannesburg, 1995
A different class of mesothermal gold deposit at Sabie-Pilgrim’s Rest is described which is probably associated with the Bushveld igneous event in South Africa. Pressure and temperature estimates indicate that the ore-fluids of the Sabie-Pilgrim's Rest Goldfield, which occurs within the early Proterozoic Transvaal Supergroup, were similar to those of mesothermal gold deposits. [Abbreviated abstract. Open document ot view full version]

M.Sc.
High-grade hematite ores at the Thabazimbi Mine, Limpopo Province, occur as stratabound bodies in the Early Paleoproterozoic Penge Iron Formation of the Transvaal Supergroup. Iron ores occur at three distinct positions in the Penge Iron Formation (i) basal ore bodies located immediately above a thin oxidised shale unit that marks the base of the Penge Iron Formation in the Thabazimbi area and that may be interpreted as a structural contact towards the underlying dolostones of the Malmani Subgroup; (ii) ore bodies developed immediately above a prominent mafic sill in the Penge Iron Formation; (iii) small, lenticular ore bodies developed in the iron-formation without apparent structural control. Ore bodies in all three stratigraphic positions formed on the expense of the Penge Iron Formation protore, they share very similar mineralogical and textural attributes and can be subdivided into three major ore types with respect to their mineralogy and physical characteristics, namely, (a) carbonate-hematite ore; (b) hard hematite ore; (c) supergene modified ore. Further subdivision into subtypes is possible based on textural attributes. The first stage of iron ore formation at the Thabazimbi deposit is marked by oxidation of ferrous minerals (carbonates and grunerite) and their replacement by hematite. Efficient leaching and replacement of chert in the iron-formation to produce high-grade hematite ores characterizes the second stage of alteration. Stable isotope and fluid inclusion evidence point to a hydrothermal origin of the iron ores. Two hydrothermal fluids were identified, namely a highly saline Ca-Mg-rich brine (S = 27 wt% NaClequiv, TH = 160ºC) and a Nadominated fluid of intermediate salinity (S = 10 wt% NaClequiv, TH = 130ºC) that is possibly of meteoric origin. The results obtained in this study are used to propose the following sequence of mineralising events for the Thabazimbi iron ore deposit: (i) Deposition of iron-formation and diagenesis; (ii) contact metamorphic alteration related to the intrusion of the Bushveld igneous complex; (iii) metasomatic oxidation, leaching and residual upgrading that is tentatively linked to structurallycontrolled hydrothermal fluid flow; (iv) supergene modification of existing high-grade ore bodies in post-Gondwana times along the old African land surface.

D. Phil.
The Kalahari Manganese Deposit (KMD) is the largest of five erosional relics of the Hotazel Formation that are located near Kuruman in the Northern Cape Province of South Africa. Manganese ores are exploited from the lowermost of three manganiferous beds that are interbedded with banded iron-formation (BIF) and hematite lutite, that together constitute the Hotazel Formation. Two major ore types have been delineated previously, viz. low grade braunite lutite of the Mamatwan-type, and high grade oxidic ores of the Wessels-type, with the latter spatially restricted to the northern KMD. Genesis of the ores was temporally distinct, with the Mamatwan-type ore considered as a sedimentary-diagenetic precursor to the hydrothermally altered Wessels-type ore. Drill core samples from the Nchwaning-Gloria area of the northern KMD were analysed, with the aim to better characterise ore genesis, with emphasis on ore alteration. A second part of the study aimed at the application of mineralogical and geochemical information to aspects of ore smelting for the production of Mn alloy for use in the steel industry. Methods employed were drill core logging, X-ray diffraction (XRD), petrography, electron probe microanalysis (EPMA), major and trace element (including REE) analysis (employing artificial neural networks for evaluation of elemental trends), and stable isotope (C and O) analysis. Significant effort was invested in method development for quantitative mineralogical modal analysis using Rietveld refinement of XRD data. The study shows that a number of ore types can be differentiated in the northern KMD on the basis of mineral assemblage, grade, texture and geochemical characteristics. The ores are broadly classified into least altered (LA), partially altered (PA) and advanced altered (AA) types. The LA ores are low grade (<40 wt%Mn) Mn lutites, with dolomite-group carbonate a significant component in addition to braunite. Serpentine is a ubiquitous trace mineral, and boron is a characteristic trace element hosted predominantly by braunite in these ores. Ores of the PA type comprise either braunite-hausmannite-calcite or hausmannite-calcite assemblages, are fine to coarse grained, and display intermediate Mn grades (40-45 wt%Mn). They exhibit a transitional trace element signature. Advanced altered ores may be classified into five different types, based on mineral assemblages that contain hausmannite and/or braunite as significant minerals. Carbonates occur predominantly in the form of calcite, present in minor to trace proportions. Textures vary from fine to very coarse grained, and high Mn grades (typically >45 wt%Mn), are recorded. Trace elements of significance include Zn, associated with hausmannite, B, associated with massive braunite and a number of trace minerals, and P, typically present in trace quantities of apatite. In terms of ore genesis, mineralogical, geochemical and geological considerations suggest that Mn (and Fe) originated from submarine hydrothermal vents, from which it travelled in hydrothermal plumes, prior to rapid deposition ~2.2 Ga ago. Diagenesis followed soon after deposition, through redox reactions involving organic matter and higher oxides of Mn to produce the braunite-carbonate assemblage primarily observed in LA ores. The carbonate:oxide ratio and nature of the carbonates varied slightly depending on fluctuations in organic matter flux to the sediment, as well as marine bicarbonate concentrations. Metamorphism, in relation to diagenesis and metasomatism, is poorly understood, but is perceived to have resulted in serpentine formation, as observed in LA and PA ores.

A thesis submitted to the Faculty of Science, University of the Witwatersrand, Johannesburg, in fulfilment of the requirements for the degree of Doctor of Philosophy,
The Ventersdorp Contact Reef(VCR) is a major gold-bearing reef in the Witwatersrand Basin. It occurs between the overlying Klipriviersberg Group lavas and the underlying Central Rand Group sediments, and was strongly altered by hydrothermal fluids circulating in the Witwatersrand Basin. A detailed study of the mineralogy, geochemistry of rocks and minerals, physicochemical conditions, stable isotopes and ages of hydrothermal alteration zones associated with the VCR were carried out at Western Deep Levels South Mine, South Africa. ( Abbreviation abstract)
Andrew Chakane 2019

M.Sc.
This dissertation describes the N1 manganese ore bed at Gloria Mine in the Kalahari Manganese Field, Northern Cape Province. It also compares the ore bed at Gloria Mine with the correlative bed further to the south at Mamatwan Mine. The ore bed at Gloria Mine can be subdivided into ten texturally distinct zones that are laterally consistent throughout the mine lease area. The mineralogy and geochemistry of the various lithostratigraphic zones are described from two drill cores (GL28 and GL24), situated away from any known structural features or unconformities that could have affected the properties of the Ore. The ore in drill core GL28 has a mineralogical composition similar to that of typical Mamatwan-type ore described at Mamatwan Mine with braunite and kutnahorite as the main minerals. However, in drill core GL24 the ore has a very different mineralogical composition although it is texturally and geochemically rather similar to Mamatwan-type ore. The ore is composed of hausmannite, calcite and jacobsite and is apparently related to a post-depositional alteration event that did not effect Mamatwan-type ore in the Mamatwan Mine area. This altered ore is similar in composition to low-grade leastaltered manganese ores in the cores of fault blocks at Wessels and N’Chwaning Mines i.e. the area known for its hydrothermally altered high-grade manganese ores in the northern part of the Kalahari Manganese Field. In addition to the above, the N1 manganese ore bed at Gloria Mine also underwent ferruginisation close to certain joints and normal faults. No obvious alteration could be detected where the ore bed is unconformably overlain by Dwyka diamictite, nor associated with a thrust fault displacing the ore.

The ~2.98 - 2.87 Ga Pongola Supergroup in South Africa is subdivided into the lower volcano-sedimentary Nsuze Group, and the upper sedimentary Mozaan Group, the latter comprising a several kilometres thick succession of fluvial to shallow marine sandstones and shales. Thin beds of gold and uranium-bearing conglomerates are locally present in the Mandeva Formation near the base of the Mozaan Group and have been mined at Denny Dalton in northern KwaZulu-Natal. The style of mineralization strongly resembles that of the Witwatersrand goldfields, however appears to be of low grade and limited tonnage. The ~1 m thick basal conglomerate, the “Mozaan Contact Reef” (MCR, herein referred to as CG 1), at Denny Dalton hosts erratic gold and uranium mineralization. The conglomerate is laterally discontinuous and occupies east-northeast trending scour channels. Polymict, matrix-supported conglomerates are common, while clast-supported conglomerates are rare. Well rounded, pebble to cobble-sized clasts of vein quartz and chert are hosted in a sandy matrix of quartz, pyrite and sericite. Where mineralized, the CG 1 hosts abundant rounded pyrite grains, interpreted as detrital in origin, with subordinate U-bearing minerals, such as brannerite and uraniferous leucoxene. Rounded detrital pyrite occurs in three phases, compact, porous and radial. Gold forms inclusions within massive pyrite grains, which are concentrated in shoots associated with the basal parts of the channel scours. SEM-EDX results, as well as the high reflectivity of the gold show a high Ag content, indicative of a primary origin for the gold within the pyrite grains. Uranium within CG 1 is hosted primarily as secondary inclusions of uranium within black chert pebbles within the basal cobble-sized regions of the conglomerate. Geochemical comparison of the chert pebbles at Denny Dalton with similar chert from the Nondweni Greenstone Belt indicates that the uranium is secondary in origin as no U anomalies occur in the Nondweni chert. Geochemical and SEM analysis of the uppermost conglomerate (CG 4) indicate the presence of uraninite and coffinite within the uppermost horizon as both fillings of voids within, and coatings on, detrital pyrite grains. Palaeocurrent data indicate a likely source terrain for the detrital material to the west of the inlier. This orientation, as well as differing mineralogical and sedimentological aspects between the Mandeva Formation and the correlative Sinqeni Formation within the main Pongola basin, indicate a separate and more proximal provenance for the auriferous conglomerates of the White Umfolozi Inlier. The Mandeva Formation is a fluvial to shallow marine sequence that has been affected by cyclic sea-level changes. The basal conglomerates of the Denny Dalton Member were deposited in a proximal braided alluvial plain environment. The conglomerates fine upwards into trough cross-bedded quartz arenites which appear to have been deposited as shallow marine sands in a shoreface environment. They are overlain with a sharp contact by a laterally extensive unit of polymictic conglomerate which represents a transgressive ravinement surface within the wave zone and marks the onset of a major marine transgression into the Pongola basin. The conglomerate is overlain by massive grits and coarse-grained quartz arenite. This unit is overlain with a sharp and locally sheared contact by shales and subordinate banded iron formation which can be traced into other parts of the Pongola basin and indicates continued rapid transgression onto large parts of the Kaapvaal Craton with deeper marine, sub-storm wave base sediments being deposited in quiet-water environments on a sediment-starved shelf. The heavy mineral assemblage as well as bulk geochemical data is consistent with a granitoid-greenstone source terrain for the conglomerates and sandstones. The geochemical composition of chert pebbles from the CG 1 is similar to the composition of cherts present in the Nondweni Greenstone Belt that is situated ~30 km west of the White Umfolozi Inlier. Multiple sulphur isotope (ä34S, ä33S) values for detrital pyrite from the MCR are consistent with an origin from mantle-like rocks, such as hydrothermal sulphide-quartz veins in a granitoid-greenstone setting. Palaeocurrent, mineralogical and geochemical data all point to a likely granitoid-greenstone provenance to the west of the White Umfolozi Inlier.
Thesis (M.Sc.)-University of KwaZulu-Natal, 2009.

The Mount Ayliff Complex (MAC) is situated on the border between Kwa-Zulu Natal and the Eastern Cape provinces in the Republic of South Africa, approximately 90 km due west of Port Shepstone. The Complex forms part of the Karoo Igneous Province and includes five lobes (Ingeli, Insizwa, Tonti, Tabankulu, and Horseshoe) that are the remnants of a single continuous intrusive sheet that had an original extent of 18,000km2• The current outcrop is estimated at 800km2• The lobes all show extensive internal differentiation, from basal ultramafic cumulates to diorites and monzonites at the top, while most other intrusions in the Karoo Igneous Province cooled rapidly enough to produce relatively homogenous dolerites. Most work conducted on the Complex thus far has centered on the Insizwa lobe due to the presence of a Ni-sulphide occurrence near the base of the lobe at Waterfall Gorge. The setting of the ores has analogies to the Noril'sk-Talnakh deposits, which has raised considerable exploration interest on the Mount Ayliff Complex over the last century. The current study investigates the Ni-Cu sulphide potential of the Ingeli and Horseshoe lobes, which have been poorly studied in the past. To this effect, a stream sediment survey was conducted around the Ingeli lobe to try and detect potentially hidden magmatic sulphide ores. Further, the five lobes of the Complex have been compared in terms of lithology and lithogeochemistry. Analytical techniques used for the current study include: XRF, ICP-MS and electron microprobe. Stream sediment samples were analysed using XRF and ICP-OES. Olivines from the ultramafic cumulates of the Ingeli and Insizwa lobes are undepleted in Ni, whereas olivines from the Horseshoe and Tabankulu lobes are strongly depleted in Ni. This suggests that the rocks of the latter two lobes crystallized from parental magmas that interacted with a sulphide liquid and that the magmatic flow direction was from the north to the south. The data indicate that the ultramafic rocks of the Complex plot on or near control lines between olivine and Karoo dolerite indicating that the rocks are mixtures of cumulus olivine and trapped melt of Karoo dolerite composition. There appears to be a copper enrichment towards the top of the ultramafic package in the Ingeli lobe. This pattern corresponds to other studies conducted in the InsiZWa lobe and suggests that the two lobes had originally been connected. The lowermost cumulates of the Ingeli lobe contain an enhanced crustal component suggesting some in situ contamination. No significant sulphide enrichments were encountered in the Basal Zone rocks of the Ingeli lobe. However, the stream sediment data indicate localized PGE enrichment indicating the possible presence of a localized hidden sulphide occurrence of the type found at Waterfall Gorge. Small amounts of sulphides were found associated with the Basal Zone rocks in the Horseshoe lobe consistent with the trends of Ni-depletion of olivines. However, a lack of Co depletion in the ultramafic rocks of this lobe suggests that any sulphide segregation event that did take place was of a relatively small scale.
Dissertation (MSc)--University of Pretoria, 2006.
Geology
MSc
Unrestricted

D.Phil.
The Ongeluk Formation is a laterally extensive sequence of ≈2200 Ma tholeiitic basaltic andesites in the upper Griqualand West Sequence of the northern Cape Province. The stratigraphic thickness is about 500 m and the Ongeluk Formation underlies the ore-bearing strata of the Kalahari Manganese Field. The formation comprises massive lavas, pillow lavas and hyaloclastite beds in close association. These rocks were extruded under water in a marginal basin within the continental setting of the Kaapvaal Craton. The Hekpoort Basalt Formation of the Transvaal is magmatically cogenetic with the Ongeluk, having indistinguishable geochemistry and sharing a stratigraphically related hiatus in Cr values. The best age estimate for the two formations is 2193 ± 71 Ma, from Rb-Sr data of two previous workers for Hekpoort samples. The Ongeluk Formation shows a mild "regional" geochemical alteration and a profound "Kalahari" alteration beneath the Kalahari Manganese Field. Geochemical screening was used to reconstruct the magmatic composition from a selected dataset. Three stages in the development of regional alteration are ascribed to sea water-rock interaction at different temperatures, and have distinct geochemical signatures. The pervasive Kalahari alteration is characterised by a purple colouration and the decoupled alteration of alkali and high field strength elements. It is due to the development of major hydrothermal systems close to a volcanic vent which are analogous to modern mid-ocean ridge systems. A multi-system isotopic study showed that most of the isotope systems were modified by sea-floor alteration. The similarity of the 2237 ± 23 Ma Pb-Pb errorchron age with the Rb-Sr Hekpoort age reflects changes in U-Pb ratios with minor changes in Pb isotope ratio. Evidence was found in the Rb-Sr system for a minor disturbance at ≈ 1100 Ma, also reported by previous workers. This event is related to the Namaqua tectogenesis, while no isotopic evidence was found for the enigmatic ≈ 2200 to 1750 Ma Kheis orogeny, regarded as the cause of thrust faulting in the region. A genetic connection between the Ongeluk lava and the Kalahari Manganese deposits was established. The manganese ores contain evidence for both marine and hydrothermal contributions to chemical sedimentation. Negative Ce anomalies characterise an oxygenated sea in which the interaction between global oceanic and continental influences is seen. Heavy rare earth enrichment reflects volcanic hydrothermal exhalations from the Kalahari Ongeluk system. Mass balance calculations show that the entire 9 billion tons of Kalahari Manganese ore could have been derived from the Ongeluk Formation. A new model describing the origin and evolution of the Kalahari Manganese Field places a strong emphasis on the role of the syngenetic hydrothermal exhalation and upgrading.

M.Sc.
An estimated 98% of the iron ore exploited in the world is used in the manufacture of pig iron and steel, which are non-substitutable backbones of modern society. The rapid increase of world steel production over the last few years, driven mainly by economic growth in China, have required an equal increase in iron ore production, from 876.8 Mt in 2006 to 948.1 Mt in 2007. The increased rate of exploitation of iron ores has resulted in a rapid depletion of known high-grade iron ore deposits. This, in turn, has led to a dramatic increase of prices, especially for highly thought-after high-grade lumpy iron ores from BIF-hosted deposits. In the absence of any major new discoveries of high-grade iron ore deposits, mining companies have turned to lower-grade materials to assess their beneficiation potential to expand their production base and beneficiation capacity, in order to satisfy future demand. Within this existing framework, this research project was initiated to assess the beneficiation potential of low-grade lumpy stockpiles and high-grade iron ore fines at Beeshoek Iron Ore Mine, owned by Assmang Ltd. The mine is located 7 km West of Postmasburg, in the Northern Cape Province of South-Africa, and processes currently 5.60 million tons of uncontaminated run-of-mine ore per annum. Crushing, washing, classification and jigging are used to produce 2.12 million tons of (37.8% of ROM) of lumpy iron ore product. The balance (3.48 million tons) is currently not used, but is stockpiled or discarded. This includes 0.90 million tons (16.2% of ROM) of ore-grade fines, 0.86 million tons (15% of ROM) of tailings sludge and 1.74 million tons (31% of ROM) of lumpy low grade material. Both ore-grade fines and low-grade lumpy material are discarded separately; they are currently considered as waste. The low-grade lumpy is stockpiled while the fines are used to fill-in mined-out open pits. The evaluation of the beneficiation potential of these two material streams is the main goal of this study. Representative samples were collected from ore-grade fines and the current stockpile for low-grade lumpy material. Hand sorting and lithological categorization of the lumpy material facilitated petrographic and mineralogical studies using light and scanning electron microscopy, as well as X-ray powder diffraction studies. Major and trace element geochemistry were determined using X-ray fluorescence spectrometry and titrimetry (to accurately determine the concentration of iron). Whole rock densities were determined for all lithotypes recognized in the low-grade lumpy material. The grain size distribution was determined for the lumpy materials by actual measurement of the diameter of a representative number of particles, and for fines by sieve analysis. Fines beneficiation tests were conducted using spiral separation and simple classification tests. Washing was used as additional beneficiation method on the fines.

M.Sc. (Geology)
The Witwatersrand Supergroup is host to a number of auriferous and uraniferous conglomeratic reefs, which have been extensively exploited along the Witwatersrand Basin margins. The current study investigates the Vaal Reef, in the Klerksdorp gold field with particular focus on conducting a geometallurgical characterization of the ore which may ultimately enhance the recovery of gold and uranium and our understanding of how the ore responds to processing. Six samples were collected from AngloGold Ashanti’s Moab Khotsong mine and prepared for a chemical and mineralogical deportment study. These samples were milled and crushed down to 80% passing -75μm and processed for head chemistry assays, grading analysis as well as heavy liquid separation analysis as part of the chemical deportment. The samples were also submitted for gold cyanide, acid uranium and diagnostic leach tests.....

M.Sc.
It is the focus of the study to qualitatively describe and then quantify the mineralogical and geochemical changes associated with the supergene alteration of carbonate-rich braunite lutite (Mamatwan-type ore) immediately below the Kalahari unconformity along the southeastern suboutcrop perimeter of the Hotazel Formation in the Kalahari deposit. It was also the objective of this study to determine the timing and duration of supergene alteration. Samples for polished thin sections were carefully selected from eight representative boreholes to be representative of all the lithostratigraphic zones and ore types. The thin sections were used to study mineralogy by means of reflected light microscopy and scanning electron microscopy. X-ray powder diffractometry on representative powder samples were used to study the mineralogy and geochemistry of the samples. Microprobe analyses were also performed on the representative samples. Finally the samples were submitted for 40Ar/39Ar geochronology. In this supergene enrichment zone carbonates are leached (associated with an increase in porosity) and Mn2+/Mn3+ -bearing minerals (kutnahorite, Mn-calcite an braunite) are altered to supergene Mn4+-bearing mineral phases (todorokite and manganomelane) and minor quartz. This process upgrades ore from 38 wt% Mn to ore with more than 40 wt% Mn. Element fluxes, enrichment and depletion of major and trace elements were quantified by mass balance calculations. Na2O, K2O, Sr, Ba, Zn and H2O were enriched, while Mn3O4, Fe2O3, CaO, MgO, P, B and CO2 were leached from the ore during supergene alteration. Results of this study suggest that the development of Post African I erosional surface may have taken place 45 Ma ago. The bottom of the weathering profile gives a well-defined peak at ca. 5 Ma that may possible coincide with the development of Post African II erosional surface. The major characteristics of the alteration process of the unaltered Mamatwan-type ore to supergene altered braunite lutite can be summarized as follow: • Leaching of Mn carbonates and Mn2+/Mn3+-oxides. • Formation of Mn4+-oxyhydroxides and quartz. • Decrease in relative density of the ore. • Increase in porosity of the ore. • Leaching of Mn3O4, Fe2O3, CaO, MgO, P, B, CO2. • Enrichment of Na2O, K2O, Sr, Ba, Zn, H2O. Chemical weathering processes along the Cenozoic Kalahari unconformity appear to have affected the manganiferous lithologies of the Hotazel Formation from 45 Ma onwards to 5 Ma. The weathering front processes very slowly through the Mn-rich braunite lutite (<10m in 40 Ma; <0.25m/Ma); producing a very uniform and microcrystalline supergene mineral assemblage with distinct characteristics.

Ph.D. (Geology)
Shear zone controlled hydrothermal alteration zones in the northern Kaapvaal craton (NKC) are developed in host rocks of vastly different chemical composition and metamorphic grade. Some carry appreciable Au and base metals and some are barren. Alteration zones in three different distinctive crustal zones were examined in detail to determine the controls of these two types of alteration. 1. The Matok Complex is situated in the southern marginal zone (SMZ) of the Limpopo Belt (LB), close to the zone of rehydration. Two major stages of hydrothermal alteration could be identified in local shear zones, a pervasive propylitization and a subsequent vein controlled quartzalbite alteration. The two-stage alteration occurred sometimes between the emplacement of the Matok Complex (2670 Ma) and the intrusion of unaltered mafic dykes (1900 Ma). Calculated isotopic compositions of the hydrothermal fluids indicate that magmatic ± meteoric waters as well as juvenile C02 were responsible for the establishment of the alteration zones. The fluids most probably were late magmatic fluids associated with the Matok magmatism. The propylitic alteration was accompanied by introduction of small amounts of CU + Au and represents an alteration type identical to that developed in porphyry copper deposits. The subsequent quartz-albite alteration was caused by extremely saline fluids which depleted the rocks of all the major and trace elements with exception of Si, Al, Na and Zr. 2. This chemical alteration pattern' contrasts with those developed in two alteration zones associated with economic gold mineralization in greenstone belts of the NKC (Sutherland and Pietersburg belts). At the Birthday and Eersteling gold mines, a biotite-calcite-quartz alteration is developed. The chemical pattern of the alteration is...