Tesi sul tema "Mechanical equilibrium"
Cita una fonte nei formati APA, MLA, Chicago, Harvard e in molti altri stili
Vedi i top-50 saggi (tesi di laurea o di dottorato) per l'attività di ricerca sul tema "Mechanical equilibrium".
Accanto a ogni fonte nell'elenco di riferimenti c'è un pulsante "Aggiungi alla bibliografia". Premilo e genereremo automaticamente la citazione bibliografica dell'opera scelta nello stile citazionale di cui hai bisogno: APA, MLA, Harvard, Chicago, Vancouver ecc.
Puoi anche scaricare il testo completo della pubblicazione scientifica nel formato .pdf e leggere online l'abstract (il sommario) dell'opera se è presente nei metadati.
Vedi le tesi di molte aree scientifiche e compila una bibliografia corretta.
Jung, Sunghoon. "Nanomechanics model for static equilibrium". Thesis, Monterey, Calif. : Springfield, Va. : Naval Postgraduate School ; Available from National Technical Information Service, 2002. http://library.nps.navy.mil/uhtbin/hyperion-image/02sep%5FJung.pdf.
Testo completoEkoto, Isaac Wesley. "Supersonic turbulent boundary layers with periodic mechanical non-equilibrium". Texas A&M University, 2006. http://hdl.handle.net/1969.1/4709.
Testo completoWang, Yi Jenny. "Equilibrium molecular dynamics study of heat conduction in octane". Thesis, Massachusetts Institute of Technology, 2015. http://hdl.handle.net/1721.1/97858.
Testo completoCataloged from PDF version of thesis.
Includes bibliographical references (pages 73-79).
Fluids are important components in heat transfer systems. Understanding heat conduction in liquids at the atomic level would allow better design of liquids with specific heat transfer properties. However, heat transfer in molecular chain liquids is a complex interplay between heat transfer within a molecule and between molecules. This thesis studies the contribution of each type of atomic interaction to the bulk heat transfer in liquid octane to further the understanding of thermal transport between and within chain molecules in a liquid. The Green-Kubo formula is used to calculate thermal conductivity of liquid octane from equilibrium molecular dynamics, and the total thermal conductivity is split into effective thermal conductivities for the different types of atomic interactions in the system. It is shown that the short carbon backbone of octane does not dominate thermal transport within the system. Instead, the thermal resistance within a molecule is about the same as the resistance between molecules.
by Yi Jenny Wang.
S.M.
Ebadi, Alireza. "Transport of heat and momentum in non-equilibrium wall-bounded flows". Thesis, University of New Hampshire, 2017. http://pqdtopen.proquest.com/#viewpdf?dispub=10241615.
Testo completoTransport of momentum and heat in non-equilibrium wall-bounded flows is studied analytically and experimentally to better understand the underlying physics, transition dynamics, and appropriate flow scaling in non-equilibrium flows. Non-equilibrium flows, in which the mean flow time scales are comparable to turbulent flow time scales, do not exhibit universal behaviors and cannot be characterized only in terms of local parameters. Pressure gradients, fast transients and complex geometries are among the sources that can perturb a flow from an equilibrium state to a non-equilibrium state. Since all or some of these perturbation sources are present in many engineering application relevant flow systems and geophysical flows, understanding and predicting the non-equilibrium flow dynamics is essential to reliably analyze and control such flows.
Reynolds-averaged Navier-Stokes (RANS) simulations are extensively used to model and predict fluid transport across a wide range of disciplines. The shortcoming is that most turbulence models used in RANS simulations use almost exclusively wall-models based on equilibrium boundary layer behaviors, despite the fact that many basic assumptions required of equilibrium boundary layers are not satisfied in the majority of the flow systems in which RANS simulations are used. In particular, pressure gradients, dynamic walls, roughness, and large-scale flow obstacles produce boundary layers that are strongly non-equilibrium in nature. Often the prediction of RANS simulations in complex engineering systems (with perturbations that induce non-equilibrium flow behaviors) fail spectacularly primarily owing to the fact that the turbulence models do not incorporate the correct physics to accurately capture the transport behaviors in non-equilibrium boundary layers. These failures result in over-engineered and hence, less efficient designs. This lack of efficiency manifests in higher economic and environmental costs. The broad objective of this dissertation work is to develop analytical and experimental tools needed to better understand the underlying transport physics in non-equilibrium boundary layers.
The key scaling parameter in wall-bounded flows is the wall flux of momentum and heat. It follows that an accurate determination of the wall fluxes is essential to study the dynamics of non-equilibrium wall-bounded flows. As part of this dissertation research, an integral method to evaluate wall heat flux suitable for experimental data is developed. The method is exact and does not require any streamwise gradient measurements. The integral method is validated using simulation and experimental data. Complications owing to experimental limitations and measurement error in determining wall heat flux from the method are presented, and mitigating strategies are described. In addition to the ability to evaluate the wall heat flux, the method provides a means to connect transport properties at the wall to the mean flow dynamics.
The integral method is further developed to formulate a novel and robust validation technique of Reynolds-averaged Navier-Stokes (RANS) turbulence models. Validation of the turbulence models employed in RANS simulations is a critical part of model development and application. The integral based validation technique is used to evaluate the performance of two low-Reynolds-number and two high-Reynolds number RANS turbulence models of reciprocating channel flow, and results are compared to the so-called standard validation technique. While the standard validation technique indicates that the low-Reynolds-number models predict the wall heat flux well, the integral validation technique shows that the models do not accurately capture the correct physics of thermal transport in reciprocating channel flow. Moreover, it shows that the correct prediction of the wall heat flux by the models is owed to the serendipitous cancellation of model errors.
One of the identified failures of the RANS simulations of reciprocating channel flow is the inability to accurately predict the flow dynamics during the laminar-turbulence transition. The development of improved RANS turbulence models, therefore requires an improved understanding of the underlying laminar-turbulent transition mechanisms. As part of this dissertation work, the balance of the leading order terms in the phase-averaged mean momentum equation are used to study the transition mechanism in a reciprocating channel flow. It is concluded that the emergence of an internal layer in the late acceleration phase of the cycle triggers the flow to transition from a self-sustaining transitional regime to an intermittently turbulent regime. In the absence of this internal layer, the flow remains transitional throughout the cycle.
Lastly, since experimental studies of heat transfer in non-equilibrium wall-bounded flows are very limited, a unique experimental facility was developed to study non-equilibrium boundary layers with heat transfer. The facility consists of boundary layer wind tunnel that nominally measures 303×135 mm cross-section and 2.7m in length. A freestream heater and a thermal wall-plate are used to maintain the desired outer and inner thermal boundary conditions, respectively. A rotor-stator assembly is fabricated to generate a periodic pressure gradient used to produce pulsatile boundary layer flow. (Abstract shortened by ProQuest.)
Kuo, Long-Sheng 1969. "Non-equilibrium energy transfer and phase change during intense picosecond laser-metal interactions". Thesis, Massachusetts Institute of Technology, 2001. http://hdl.handle.net/1721.1/34346.
Testo completoIncludes bibliographical references (leaves 55-57).
Laser interactions with metals involve absorption of photon energy by electrons, energy coupling between electrons and the lattice, and energy transport by diffusion of electrons and lattice vibrations. During picosecond laser irradiation of metal films, electrons and the lattice are not in thermal equilibrium. On the other hand, rapid laser heating produces a large degree of superheating and undercooling during melting and solidification. First, this work investigates experimentally non-equilibrium heating processes during intense picosecond laser heating of metal films. Results show excellent agreement with predictions of the two-step radiation heating model. Second, this work develops a general model to characterize both non-equilibrium energy deposition and phase change processes. The predictions show that the non-equilibrium heating processes significantly increase the laser melting threshold, enlarge the thermal-affected region, reduce the lattice temperature rise, prolong the phase change duration, and reduce the solidification speed. These results are important for materials processing using ultrashort pulsed lasers.
by Long-Sheng Kuo.
S.M.
Laradji, Mohamed. "Ternary mixtures of water, oil and surfactants : equilibrium and dynamics". Thesis, McGill University, 1992. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=39483.
Testo completoFurthermore, we have studied the effects of surfactants on the dynamics of phase separation of two immiscible fluids, and found a drastic alteration in the kinetics. In particular, we found that surfactants slow down the growth to a non-algebraic one leading eventually to a microphase separation.
Karlsson, Jens Olof Mattias. "Non-equilibrium phase transformations of intracellular water : applications to the cryopreservation of living cells". Thesis, Massachusetts Institute of Technology, 1994. http://hdl.handle.net/1721.1/11623.
Testo completoCourtland, Hayden-William C. "Equilibrium mechanical properties of two noncollagenous cartilages in the sea lamprey, Petromyzon marinus". Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2001. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/MQ63256.pdf.
Testo completoO'Neill, Maura Rose. "Digital Rotating Unbalance Identification and Parametric Determination of Counterbalance Placement for Predictable Dynamic Behavior". The Ohio State University, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=osu1500563587083873.
Testo completoApte, Pankaj A. "Phase equilibria and nucleation in condensed phases a statistical mechanical study /". Columbus, Ohio : Ohio State University, 2005. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1135876018.
Testo completoCooper, Moogega Fridman Alexander A. "Elucidation of levels of bacterial viability post-non-equilibrium dielectric barrier discharge plasma treatment /". Philadelphia, Pa. : Drexel University, 2009. http://hdl.handle.net/1860/3181.
Testo completoCheluget, Eric Lanǵat. "Vapor-liquid equilibrium studies. Prediction for ill-defined mixtures and modification of a data collecting apparatus". Thesis, McGill University, 1988. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=61908.
Testo completoJones, Gareth Paul. "Acoustic sensitivity of the vestibular system and mechanical analysis of the tectorial membrane in mammals". Thesis, University of Sussex, 2012. http://sro.sussex.ac.uk/id/eprint/38740/.
Testo completoApte, Pankaj A. "Phase equilibria and nucleation in condensed phases: a statistical mechanical study". The Ohio State University, 2006. http://rave.ohiolink.edu/etdc/view?acc_num=osu1135876018.
Testo completoUenishi, Keisuke. "Formation of Non-equilibrium Phases in the Alloy Systems with Positive Heat of Mixing by Mechanical Alloying". Kyoto University, 1992. http://hdl.handle.net/2433/74609.
Testo completoRaghavan, Ashwin Ph D. Massachusetts Institute of Technology. "Multi-scale modeling tools for coupled reaction, phase equilibrium and two-phase mixing phenomena with application to supercritical water heavy oil upgrading process". Thesis, Massachusetts Institute of Technology, 2019. https://hdl.handle.net/1721.1/121848.
Testo completoCataloged from PDF version of thesis.
Includes bibliographical references (pages 253-261).
Supercritical water heavy oil upgrading, which has the potential for high distillate liquid yields with lower coke formation, is a complex process involving coupled reactions, phase equilibrium and two-phase mixing phenomena. This thesis presents the development of a range of models and tools to simulate such processes at different scales with varying levels of fidelity in describing the underlying physical phenomena. Over the past decade, a number of experiments have been performed in batch reactors to study the upgrading of various heavy oils and crude oil vacuum residua through both oil-phase pyrolysis and reaction in the presence of supercritical water (SCW). While these studies indicate that the presence of SCW can significantly affect the outcomes of the upgrading process, there remains a lack of clarity on whether thermolytic processing in the presence of SCW is indeed significantly beneficial as opposed to pure oil phase pyrolysis and if so, at what operating conditions.
In addition, modeling tools coupling the reaction kinetics and phase equilibrium, which can provide deeper insight into the process and the underlying phenomena have been lacking. The first part of this thesis describes the development and application of a two-phase stirred reactor (TPSR) model which couples sub-models for the phase-specific reaction kinetics and multi-component hydrocarbon-water phase equilibrium. Using this model, separate lumped kinetics rate parameters for the oil and SCW phases were inferred that best fit batch reactor experimental data. Analysis of the obtained kinetics parameters reveal the following crucial insights on the chemical pathways involved in the SCW upgrading process (i) the primary coke precursor formation pathway is not suppressed in the SCW phase and (ii) only the secondary pathway towards coke precursors from product distillate species is suppressed in the SCW phase, especially at higher operating temperatures.
The TPSR model was then applied to evaluate the performance of heavy oil upgrading using SCW in an oil-water co-flow (visbreaking) Next, an extractive upgrading reactor design was hypothesized to improve high-value distillate liquid product yields and reduce undesirable extrinsic coke formation by removing the distillate products safely out of the reactor in a SCW up-flow thereby preventing their further participation in secondary retrograde combination reactions towards more aromatic coke precursors and low-value gas. The TPSR model was used to evaluate the performance of the SCW extractive upgrading process in terms of distillate liquid yields and coke formation rates for heavy oil vacuum residue over a range of operating temperatures and water flow rates. The predictions demonstrate the significant potential of the extractive upgrading process to achieve the aforementioned objectives.
The effect of the extraction rate governed by the interphase mixing time-scale on the product yields and oil-inflow rate for steady-state operation was then quantified. The second part of the thesis describes the development of a computational fluid dynamics (CFD) framework and modeling tool for simulating the coupled two-phase flow and multi-component interphase mass transfer at near-critical/supercritical conditions in applications like SCW heavy oil upgrading. The CFD tool accounts for interface tracking in 2-D/3-D, intra-phase species diffusion, phase-equilibrium limited interphase species transfer and non-ideal thermodynamics. In this tool, the interface is tracked with a conservative sharp interface capturing Volume of Fluid (VoF) scheme using (i) a Piece-wise Linear Interface Reconstruction (PLIC) algorithm (ii) an unsplit geometrical advective flux calculation and (iii) a flux-polyhedron correction.
The intra-phase species diffusion is handled using a corrected face-normal gradient calculation accounting for the arbitrary shape and size of phase-specific sub-cells. The interphase mass transfer is computed as a source term consistent with the local phase equilibrium and transport flux constraints at the interface. Finally, the phase-volume change is rigorously accounted for in the discrete pressure equation. The tool was implemented on an open-source CFD platform ensuring compatibility with unstructured mesh information and parallel processing constraints. Finally, the developed CFD tool was applied to determine the two-phase mixing rates in an extractive upgrading configuration for water flow rates of interest. The predictions suggest that the earlier assumption of instantaneous phase-equilibration with respect to the time-scale of reactions relevant in the SCW heavy-oil upgrading process is a reasonable approximation for centimeter-scale reactors.
Furthermore, the scaling of the total oil-water interfacial area in the reactor and the average Sherwood number with the water inlet velocity and oil-water interfacial tension were established, providing insight into ways to manipulate the two-phase mixing rate to enable control of the extractive upgrading process at higher operating temperatures.
by Ashwin Raghavan.
Ph. D.
Ph.D. Massachusetts Institute of Technology, Department of Mechanical Engineering
Andrienko, Daniil. "Non-equilibrium Models for High Temperature Gas Flows". Wright State University / OhioLINK, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=wright1405505300.
Testo completoEssenhigh, Katherine Anne. "Energy transfer and chemistry of carbon monoxide in vibrational mode non-equilibrium". Connect to resource, 2005. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1124292824.
Testo completoTitle from first page of PDF file. Document formatted into pages; contains xiv, 172 p.; also includes graphics (some col.). Includes bibliographical references (p. 167-172). Available online via OhioLINK's ETD Center
Mehta, Rajeev. "A study of the mechanical properties and the equilibrium nature of the blend of thermotropic liquid crystalline copolyesters". Thesis, Virginia Polytechnic Institute and State University, 1989. http://hdl.handle.net/10919/53728.
Testo completoMaster of Science
Shanmugam, Rajesh Kumar. "Experimental Study of Non Equilibrium Electrodeposition of Nanostructures on Copper and Nickel Used for Fuel Cell Application". University of Toledo / OhioLINK, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=toledo1302294800.
Testo completoEckert, Zakari Sebastian. "Master Equation Modeling of a Nanosecond Pulsed Discharge in Nitrogen in Pin-to-Pin Geometry". The Ohio State University, 2015. http://rave.ohiolink.edu/etdc/view?acc_num=osu1429191278.
Testo completoGallagher, Michael J. Fridman Alexander A. "Partial oxidation and autothermal reforming of heavy hydrocarbon fuels with non-equilibrium gliding arc plasma for fuel cell applications /". Philadelphia, Pa. : Drexel University, 2010. http://hdl.handle.net/1860/3199.
Testo completoEckert, Zakari Sebastian. "Energy Transfer in Non-Equilibrium Reacting Gas Flows: Applications in Plasma Assisted Combustion and Chemical Gas Lasers". The Ohio State University, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=osu1515099058664013.
Testo completoGoldberg, Benjamin M. "Electric Field Measurements in Non-Equilibrium ElectricDischarge Plasmas Using Picosecond Four-Wave Mixing". The Ohio State University, 2015. http://rave.ohiolink.edu/etdc/view?acc_num=osu1449236861.
Testo completoHilts, Wade William. "Emulating Balance Control Observed in Human Test Subjects with a Neural Network". PDXScholar, 2018. https://pdxscholar.library.pdx.edu/open_access_etds/4499.
Testo completoPond, Ian. "Toward an Understanding of the Breakdown of Heat Transfer Modeling in Reciprocating Flows". ScholarWorks @ UVM, 2015. http://scholarworks.uvm.edu/graddis/477.
Testo completoReeder, Todd A. "Corrosion-related Gas Measurements and Analysis for a Suite of Coals in Staged Pulverized Coal Combustion". BYU ScholarsArchive, 2010. https://scholarsarchive.byu.edu/etd/2230.
Testo completoMittal, Arpit. "Prediction of Non-Equilibrium Heat Conduction in Crystalline Materials Using the Boltzmann Transport Equation for Phonons". The Ohio State University, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=osu1316471562.
Testo completoBotha, Jan. "The development of a device for the investigation of dorsiflexion range of the ankle with a capacity to measure pathology, recovery and pharmacological benefit". Thesis, Stellenbosch : University of Stellenbosch, 2005. http://hdl.handle.net/10019.1/2086.
Testo completoVarious ways exist whereby balance abilities of the individual can be assessed. However, most of these are subjective methods. This thesis strives to demonstrate the effectiveness of a new device, the Dorsiflexometer that can be used to objectively assess one’s balance abilities. The Dorsiflexometer was constructed and mathematically modelled using appropriate simplifying assumptions. After its construction, the Dorsiflexometer was tested using two experimental set-ups to obtain raw data. Both these set-ups consisted of the two tiltable platforms equipped with three load cells each, the bridge amplifiers and the personal computer (PC). The only difference in the two experimental set-ups is in the type of test that was performed as well as the bridge amplifiers used. Numerous parameters, such as the radius of movement and the Lyapunov number can be extracted from the raw data. A computer program was written to analyse the raw data and present the results in a user-friendly manner. A new parameter, the Sway Index, was used to obtain a single balance value for the tested individual. This parameter proved useful in quantifying balance. An advanced patent search was carried out before the device was constructed. This was necessary to provisionally patent the device – official application number: 2003/6702.
Baniahmad, Ata. "QUANTUM MECHANICAL Study and Modelling of MOLECULAR ELECTRONIC DEVICES". Master's thesis, Alma Mater Studiorum - Università di Bologna, 2017. http://amslaurea.unibo.it/13193/.
Testo completoMehta, Urmish R. "Optimal control of a high speed overhead crane including hoisting". Ohio : Ohio University, 1992. http://www.ohiolink.edu/etd/view.cgi?ohiou1172863064.
Testo completoSung, Dejun. "Design and simulation of the Broom-balance vehicle system". Ohio : Ohio University, 1993. http://www.ohiolink.edu/etd/view.cgi?ohiou1176236797.
Testo completoAllu, Pareekshith. "A Hybrid Ballistic-Diffusive Method to Solve the Frequency Dependent Boltzmann Transport Equation". The Ohio State University, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=osu1451998769.
Testo completoHassan, Mohamed K. I. "Novel Elastomers, Characterization Techniques, and Improvements in the Mechanical Properties of Some Thermoplastic Biodegradable Polymers and Their Nanocomposites". University of Cincinnati / OhioLINK, 2004. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1086633832.
Testo completoNadimi, Ebrahim. "Quantum Mechanical and Atomic Level ab initio Calculation of Electron Transport through Ultrathin Gate Dielectrics of Metal-Oxide-Semiconductor Field Effect Transistors". Doctoral thesis, Universitätsbibliothek Chemnitz, 2008. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-200800477.
Testo completoDie vorliegende Arbeit beschäftigt sich mit der Berechnung von Tunnelströmen in MOSFETs (Metal-Oxide-Semiconductor Field Effect Transistors). Zu diesem Zweck wurde ein quantenmechanisches Modell, das auf der selbstkonsistenten Lösung der Schrödinger- und Poisson-Gleichungen basiert, entwickelt. Die Gleichungen sind im Rahmen der EMA gelöst worden. Die Lösung der Schrödinger-Gleichung unter offenen Randbedingungen führt zur Berechnung von Ladungsverteilung und Lebensdauer der Ladungsträger in den QBSs. Der Tunnelstrom wurde dann aus diesen Informationen ermittelt. Der Tunnelstrom wurde in verschiedenen Proben mit unterschiedlichen Oxynitrid Gatedielektrika berechnet und mit gemessenen Daten verglichen. Der Vergleich zeigte, dass die effektive Masse sich sowohl mit der Schichtdicke als auch mit dem Stickstoffgehalt ändert. Im zweiten Teil der vorliegenden Arbeit wurde ein atomistisches Modell zur Berechnung des Tunnelstroms verwendet, welche auf der DFT und NEGF basiert. Zuerst wurde ein atomistisches Modell für ein Si/SiO2-Schichtsystem konstruiert. Dann wurde der Tunnelstrom für verschiedene Si/SiO2/Si-Schichtsysteme berechnet. Das Modell ermöglicht die Untersuchung atom-skaliger Verzerrungen und ihren Einfluss auf den Tunnelstrom. Außerdem wurde der Einfluss einer einzelnen und zwei unterschiedlich positionierter neutraler Sauerstoffleerstellen auf den Tunnelstrom berechnet. Zug- und Druckspannungen auf SiO2 führen zur Deformationen in den chemischen Bindungen und ändern den Tunnelstrom. Auch solche Einflüsse sind anhand des atomistischen Modells berechnet worden
Kakitani, Celina. "Estudo do equilíbrio de fases de hidratos de metano e da mistura metano e dióxido de carbono". Universidade Tecnológica Federal do Paraná, 2014. http://repositorio.utfpr.edu.br/jspui/handle/1/1035.
Testo completoHidratos são estruturas cristalinas constituídas por moléculas de água e gás ou líquido, sendo que a estabilização dessa estrutura cristalina requer condições de altas pressões e/ou baixas temperaturas. A formação e a aglomeração de hidratos podem causar o bloqueio de linhas de transporte de óleo e/ou gás, reduzindo a eficiência do processo, danificando os equipamentos e comprometendo a segurança da parte operacional. Neste cenário, no presente trabalho é apresentado o estudo numérico-experimental de equilíbrio de fases dos hidratos para identificar as regiões de formação e adequar as condições de operação na indústria petrolífera. Para a predição das condições de formação dos hidratos é desenvolvido um modelo termodinâmico baseado na teoria de sólido ideal de van der Waals e Platteeuw. O modelo é fundamentado na igualdade dos potenciais químicos de todas as espécies em todas as fases (água líquida, hidrato e vapor). Para os cálculos de equilíbrio da fase hidrocarboneto foi utilizada a equação de estado de Soave Redlich-Kwong e o método da secante foi utilizado para solucionar o modelo iterativamente. As medidas experimentais foram realizadas utilizando metano puro e a mistura metano (90 % em mol) e dióxido de carbono e os testes foram realizados em duas bancadas distintas, sendo os procedimentos realizados semelhantes, baseados no método isocórico pela monitoração da resposta da pressão do sistema com a variação da temperatura. Os resultados experimentais e numéricos obtidos foram comparados com dados da literatura com a finalidade de validar o modelo termodinâmico proposto, o aparato experimental e o procedimento adotado. O erro absoluto máximo entre os resultados obtidos experimentalmente e do modelo termodinâmico desenvolvido foi de 0,57%. Desta forma, nota-se os resultados apresentaram boa concordância entre os dados experimentais e os da modelagem numérica.
Hydrates are crystalline structures composed by molecules of water or liquid and gas, and the crystal structure that requires stabilization conditions of high pressure and/or low temperatures. The formation and agglomeration of hydrates can cause blockage of transmission lines oil and / or gas, reducing process efficiency, damaging the equipment and compromise the safety of the operating part. In this scenario, in this paper the numerical-experimental study of phase equilibria of hydrates is presented to identify the regions of formation and adjust the operating conditions in the oil industry. To predict hydrate formation conditions of a thermodynamic model based on the ideal solid solution theory by van der Waals and Platteeuw is developed. The model is based on the equality of the chemical potentials of all species in all phases (liquid water, vapor and hydrate). The SoaveRedlich-Kwong equation of state was employed for the phase equilibrium properties of the hydrocarbon fluid phase and the secant method was used to solve the model iteratively. Experimental measurements were performed using pure methane and methane mixture (90 mol%) and carbon dioxide, and the tests were performed on two separate stands, and similar procedures performed based on the isochoric method by monitoring the pressure response of the system with changes in the temperature. The experimental and numerical results were compared with literature data in order to validate the proposed thermodynamic model, the experimental apparatus and procedure adopted. The maximum absolute error between the experimental results and thermodynamic model was 0.57%. Thus, the results showed good agreement between experimental data and numerical modeling.
Evans, Allan Kenneth. "Foundations of non-equilibrium statistical mechanics". Thesis, University of Cambridge, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.389831.
Testo completoAL-AZMI, BADER SHABEEB. "ANALYSIS OF TRANSPORT MODELS AND COMPUTATION ALGORITHMS FOR FLOW THROUGH POROUS MEDIA". The Ohio State University, 2003. http://rave.ohiolink.edu/etdc/view?acc_num=osu1051059625.
Testo completoMerkli, Marco. "Positive commutator method in non-equilibrium statistical mechanics". Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2001. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/NQ58618.pdf.
Testo completoStapleton, Matthew Alexander. "Self-organised criticality and non-equilibrium statistical mechanics". Thesis, Imperial College London, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.443792.
Testo completoTavassoli, Zohreh. "Topics in statistical mechanics of non-equilibrium systems". Thesis, Brunel University, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.326896.
Testo completoHancock, Benjamin R. "Non-equilibrium Statistical Mechanics of Self-Propelled Particles". Thesis, Brandeis University, 2018. http://pqdtopen.proquest.com/#viewpdf?dispub=10929778.
Testo completoSelf-propelled particles (SPPs) are particles who, by themselves, are able to generate persistent motion by converting energy from an ambient reservoir into work. Collections of such particles form a class of intrinsically out-of-equilibrium fluids called active fluids which have energy input and dissipation at the scale of the particle constituents. Despite their non-equilibrium nature, large scale, cohesive structures will often spontaneously emerge. These structures can manifest in microscopic realizations such as collective cell motility but also in much larger objects like flocks of birds. In this work we apply the powerful tools of non-equilibrium statistical mechanics to study SPPs both at the single particle level and for collections of interacting particles.
The primary non-equilibrium characteristic of a SPP is the persistent correlation in its direction of motion. In the first theme, we address the following question: What is the effect of the details of the decorrelation process on long time properties of SPPs? This question is addressed in 2 parts. First, we compare the response of active Brownian particles and run-and-tumble particles when subject to external torques. Second, we investigate the nature of the non-equilibrium steady state by constructing the Smoluchowski equation. The second topic comes with the added feature that it allows us to address the validity of different approximation techniques available to deal with correlated stochastic processes.
In the second theme we construct a theoretical framework to characterize the non-equilibrium steady states of interacting SPPs. Starting from a microscopic model of self-propelled hard spheres we use tools of non-equilibrium statistical mechanics and the kinetic theory of hard spheres to derive a Smoluchowski equation for interacting active Brownian particles. We illustrate the utility of the statistical mechanics framework developed with two applications. First, we derive the steady state pressure of the hard sphere active fluid in terms of the microscopic parameters and second, we identify the critical density for the onset of motility-induced phase separation in this system. We show that both these quantities agree well with overdamped simulations of active Brownian particles with excluded volume interactions given by steeply repulsive potentials. The results presented in this section can be used to incorporate excluded volume effects in diverse models of self-propelled particles.
The final theme is an application of the self-propelled particle model to systems of motile cells. Some cells are able to deform the substrate they are adhered to and at the same time are able to sense and respond to their mechanical environment. For a collection of cells this can lead to a elastic interaction between them. In this study the cells are modeled as self-propelled “force dipoles” that deform the surface. We find that a combination of only activity and the medium mediated elastic interaction is enough to form the collective swarming, clustering, and streaming seen in some experiments. The numerical phenomenology is then rationalized using a mean-field hydrodynamic theory.
Nikoletopoulos, Theodore. "Equilibrium and non-equilibrium statistical mechanics of disordered Ising spin models with mixed range interactions". Thesis, King's College London (University of London), 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.412486.
Testo completoZhu, Wenbo. "Soldering interconnects through self-propagating reaction process". Thesis, Loughborough University, 2016. https://dspace.lboro.ac.uk/2134/23259.
Testo completoNowak, Sarah Alice. "Membrane mechanics and non-equilibrium transport in cell biology". Diss., Restricted to subscribing institutions, 2009. http://proquest.umi.com/pqdweb?did=1970611221&sid=7&Fmt=2&clientId=1564&RQT=309&VName=PQD.
Testo completoPrévost, Mireille. "Dynamical systems based non equilibrium statistical mechanics for Markov chains". Thesis, McGill University, 2011. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=104732.
Testo completoNous présentons une structure mathématique de la physique statistique hors d'équilibre appliquée aux chaînes de Markov. Cette structure comprend les théoremes de fluctuations de Evans-Searles et de Gallavotti-Cohen. Afin de supporter et enrichir ces concepts, plusieurs résultats sont presentés, notamment un théoreme central limite ainsi qu'un principe de grandes deviations. Il y a deux principales raisons d'étudier les chaînes de Markov. Premièrement, elles modélisent une grand variété de systèmes physiques. Ensuite, leur simplicité permet une introduction facile a un vaste champ comprenant la mécanique statistique des difféomorphismes d'Anosovet Axiome A. Nous présentons deux examples permettant de lier la structure présente a des cas physiques modelés par des chaînes de Markov. Un de ces examples concerne les réactions chimiques et établit un lien entre les concepts clés de la structure et leurs homologues physiques bien connus.
Ottobre, Michela. "Asymptotic analysis for Markovian models in non-equilibrium statistical mechanics". Thesis, Imperial College London, 2012. http://hdl.handle.net/10044/1/9797.
Testo completoChin, Chen-Shan. "Stochastic fluctuations far from equilibrium : statistical mechanics of surface growth /". Thesis, Connect to this title online; UW restricted, 2002. http://hdl.handle.net/1773/9759.
Testo completoŠtěpánek, Roman. "Studium substrukturních změn ultrajemnozrnných Mg-slitin při cyklickém zatěžování a teplotní expozici". Doctoral thesis, Vysoké učení technické v Brně. Fakulta strojního inženýrství, 2017. http://www.nusl.cz/ntk/nusl-263403.
Testo completoTurnbull, R. W. "Approximation schemes for statistical mechanics in the complex temperature plane". Thesis, University of Nottingham, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.376171.
Testo completo