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Letteratura scientifica selezionata sul tema "Polymerization"

Autore: Grafiati

Pubblicato: 4 giugno 2021

Ultima modifica: 25 luglio 2025

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Articoli di riviste sul tema "Polymerization"

1

Chen, Mao, Honghong Gong, and Yu Gu. "Controlled/Living Radical Polymerization of Semifluorinated (Meth)acrylates." Synlett 29, no. 12 (2018): 1543–51. http://dx.doi.org/10.1055/s-0036-1591974.

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Fluorinated polymers are important materials for applications in many areas. This article summarizes the development of controlled/living radical polymerization (CRP) of semifluorinated (meth)acrylates, and briefly introduces their reaction mechanisms. While the classical CRP such as atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) polymerization and nitroxide-mediated radical polymerization (NMP) have promoted the preparation of semifluorinated polymers with tailor-designed architectures, recent development of photo-CRP has led to unpreceden

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2

Penczek, Stanislaw, Julia Pretula, and Stanislaw Slomkowski. "Ring-opening polymerization." Chemistry Teacher International 3, no. 2 (2021): 33–57. http://dx.doi.org/10.1515/cti-2020-0028.

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Abstract Ring-opening polymerization is defined by IUPAC (Penczek, S., Moad, G. (2008). Glossary of the terms related to kinetics, thermodynamics, and mechanisms of polymerization. (IUPAC Recommendations 2008), Pure and Applied Chemistry, 80(10), 2163–2193) as (cit.) “Ring-opening polymerization (ROP): Polymerization in which a cyclic monomer yields a monomeric unit that is either acyclic or contains fewer rings than the cyclic monomer”. The large part of the resulting polymerizations is living/controlled; practically all belong to chain polymerizations. After the introduction, providing basic

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3

Cheah, Pohlee, Caitlin N. Bhikha, John H. O’Haver, and Adam E. Smith. "Effect of Oxygen and Initiator Solubility on Admicellar Polymerization of Styrene on Silica Surfaces." International Journal of Polymer Science 2017 (2017): 1–7. http://dx.doi.org/10.1155/2017/6308603.

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Although admicellar polymerization has been termed the surface analog of emulsion polymerization, previous reports utilizing free radical-initiated admicellar polymerization relied on high levels of the free radical initiator when compared to emulsion polymerization, likely due to the presence of oxygen in the reported admicellar polymerization systems. Admicellar polymerizations of styrene on the surface of precipitated silica initiated by either a water-soluble or a water-insoluble initiator were studied to determine the effect of dissolved oxygen and free radical initiator solubility on the

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4

Prescott, S. W., M. J. Ballard, E. Rizzardo, and R. G. Gilbert. "RAFT in Emulsion Polymerization: What Makes it Different?" Australian Journal of Chemistry 55, no. 7 (2002): 415. http://dx.doi.org/10.1071/ch02073.

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Reversible addition-fragmentation chain transfer (RAFT) polymerization techniques have been the focus of a great deal of recent work, particularly in their application to emulsion polymerization, which is the method of choice for implementing most free-radical polymerizations on an industrial scale. RAFT/emulsion polymerizations have considerable technical potential: to 'tailor-make' material properties, to eliminate added surfactant from surface coatings, and so on. However, considerable difficulties have been experienced in using RAFT in emulsion polymerization systems. Here, progress in the

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5

Lowe, A. B., and C. L. McCormick. "Homogeneous Controlled Free Radical Polymerization in Aqueous Media." Australian Journal of Chemistry 55, no. 7 (2002): 367. http://dx.doi.org/10.1071/ch02053.

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The ability to conduct controlled radical polymerizations (CRP) in homogeneous aqueous media is discussed. Three main techniques, namely stable free radical polymerization (SFRP), with an emphasis on nitroxide-mediated polymerization (NMP), atom transfer radical polymerization (ATRP) and reversible addition-fragmentation chain transfer polymerization (RAFT) are examined. No examples exist of homogeneous aqueous NMP polymerization, but mixed water/solvent systems are discussed with specific reference to the NMP of sodium 4-styrenesulfonate. Aqueous ATRP is possible, although monomer choice is l

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6

HU, ZHIGANG, and DAN ZHAO. "POLYMERIZATION WITHIN CONFINED NANOCHANNELS OF POROUS METAL-ORGANIC FRAMEWORKS." Journal of Molecular and Engineering Materials 01, no. 02 (2013): 1330001. http://dx.doi.org/10.1142/s2251237313300015.

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Metal-organic frameworks (MOFs) have been increasingly investigated as templates for precise control of polymerization. Polymerizations within confined nanochannels of porous MOFs have shown unique confinement and alignment effect on polymer chain structures and thus are promising ways to achieve well-defined polymers. Herein, this review will focus on illustrating the recent progress of polymerization within confined nanochannels of MOFs, including radical polymerization, coordination polymerization, ring-opening polymerization, catalytic polymerization, etc. It will demonstrate how the heter

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7

Zhang, Xiaoqian, Wenli Guo, Yibo Wu, et al. "Cationic polymerization of p-methylstyrene in selected ionic liquids and polymerization mechanism." Polymer Chemistry 7, no. 32 (2016): 5099–112. http://dx.doi.org/10.1039/c6py00796a.

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8

Wang, Qiao, Jin Liang Li, Ai Ping Fu, and Hong Liang Li. "Effect Factors on the Preparation of Polystyrene Microspheres by Emulsifier-Free Emulsion Polymerization." Advanced Materials Research 926-930 (May 2014): 304–7. http://dx.doi.org/10.4028/www.scientific.net/amr.926-930.304.

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Abstract (sommario):

Emulsifier-free emulsion polymerization is a technique derived from conventional emulsion polymerization in which polymerization is carried out in the absence of emulsifiers. This technique is useful for the preparation of polymer colloids with narrow particle size distributions and well defined surface properties. Emulsifier-free emulsion polymerization eliminates the disadvantages of conventional emulsion polymerizations stemming from the use of emulsifiers, e.g. impurities in products caused by residual emulsifier and poor water-resistance of films induced by polymer latex.

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9

Jenkins, Aubrey D., Richard G. Jones, and Graeme Moad. "Terminology for reversible-deactivation radical polymerization previously called "controlled" radical or "living" radical polymerization (IUPAC Recommendations 2010)." Pure and Applied Chemistry 82, no. 2 (2009): 483–91. http://dx.doi.org/10.1351/pac-rep-08-04-03.

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Abstract (sommario):

This document defines terms related to modern methods of radical polymerization, in which certain additives react reversibly with the radicals, thus enabling the reactions to take on much of the character of living polymerizations, even though some termination inevitably takes place. In recent technical literature, these reactions have often been loosely referred to as, inter alia, "controlled", "controlled/living", or "living" polymerizations. The use of these terms is discouraged. The use of "controlled" is permitted as long as the type of control is defined at its first occurrence, but the

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10

Xie, Linghai, Rong Tong, Quanyou Feng, and Yongliang Zhong. "Recent Advances in Ring-Opening Polymerization of O-Carboxyanhydrides." Synlett 28, no. 15 (2017): 1857–66. http://dx.doi.org/10.1055/s-0036-1590841.

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Abstract (sommario):

Poly(α-hydroxy acids) are important biodegradable polymers with wide applications. Recently O-carboxyanhydrides (OCAs) have emerged as promising monomer equivalents of lactides to synthesize poly(α-hydroxy acids). We will highlight recent advances in controlled ring-opening polymerization of OCAs catalyzed by organocatalysts, enzymes, or organometallic complexes.1 Introduction2 Organocatalysts for O-Carboxyanhydride Polymerization2.1 Synthesis of O-Carboxyanhydride Monomers2.2 Ring-Opening Polymerization of O-Carboxyanhydrides Catalyzed by 4-Dimethylaminopyridine2.3 Epimerization in the Ring-O

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Più fonti

Tesi sul tema "Polymerization"

1

Hajime, Kammiyada. "Ring-Expansion Cationic Polymerization：A New Precision Polymerization for Cyclic Polymers." 京都大学 (Kyoto University), 2017. http://hdl.handle.net/2433/225628.

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2

Aran, Bengi. "Polymerization And Characterization Of Methylmethacrylate By Atom Transfer Radical Polymerization." Master's thesis, METU, 2004. http://etd.lib.metu.edu.tr/upload/12605042/index.pdf.

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In this work, methylmethacrylate, MMA was polymerized by ATRP method to obtain low molecular weight living polymers. The initiator was p-toluenesulfonylchloride and catalyst ligand complex system were CuCl-4,4&rsquo<br>dimethyl 2,2&rsquo<br>bipyridine. Polymers with controlled molecular weight were obtained. The polymer chains were shown by NMR investigation to be mostly syndiotactic. The molecular weight and molecular weight distribution of some polymer samples were measured by GPC method. The K and a constants in [h]=K Ma equation were measured as 9.13x10-5 and 0.74, respectively. FT-IR a

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3

Barnette, Darrell Thomas. "Continuous miniemulsion polymerization." Diss., Georgia Institute of Technology, 1987. http://hdl.handle.net/1853/12518.

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4

Endsor, Robert M. "Living cationic polymerization." Thesis, Aston University, 1997. http://publications.aston.ac.uk/9597/.

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The kinetics of the polymerization of styrene iniated by 1-chloro-1-phenyltehane/tin (IV) chloride in the presence of tetrabutylammonium chloride have been studied. Dilatometry studies at 25 °C were conducted and the orders of reaction were established. Molecular weight studies were conducted for these experiments using size exclusion chromatography. These studies indicated that transfer/termination reactions were present. The observed kinetics may be explained by a polymerization mechanism involving a single propagating species which is present in low concentrations. Reactions at 0 °C and -15

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5

Brodsky, Colin John. "Graft polymerization lithography." Access restricted to users with UT Austin EID Full text (PDF) from UMI/Dissertation Abstracts International, 2001. http://wwwlib.umi.com/cr/utexas/fullcit?p3024998.

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6

Vale, Hugo. "Population Balance Modeling of Emulsion Polymerization Reactors : applications to Vinyl Chloride Polymerization." Lyon 1, 2007. http://www.theses.fr/2007LYO10034.

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This thesis is a contribution to the development of population balance models of emulsion polymerization and, more particularly, to the modeling of particle formation and particle size distribution (PSD) in vinyl chloride emulsion polymerization. The rst part of the work is dedicated to the acquisition of experimental data. Ab initio polymerizations were done to obtain reliable data regarding the dependence of the particle number on the concentration of surfactant, as well as to analyze the effect of the initiator concentration, stirring rate, and monomer-to-water ratio upon the particle numbe

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7

Ding, Shijie. "Atom transfer radical polymerization." Laramie, Wyo. : University of Wyoming, 2006. http://proquest.umi.com/pqdweb?did=1225138911&sid=1&Fmt=2&clientId=18949&RQT=309&VName=PQD.

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8

Song, Zhiqiang. "Kinetics of emulsion polymerization." Diss., Georgia Institute of Technology, 1988. http://hdl.handle.net/1853/10148.

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9

Wong, Ji Sam. "Modeling polymerization-based amplification." Thesis, Massachusetts Institute of Technology, 2016. http://hdl.handle.net/1721.1/104123.

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Abstract (sommario):

Thesis: Ph. D., Massachusetts Institute of Technology, Department of Chemical Engineering, 2016.<br>This electronic version was submitted by the student author. The certified thesis is available in the Institute Archives and Special Collections.<br>Cataloged from student-submitted PDF version of thesis.<br>Includes bibliographical references (pages 117-120).<br>Eosin, a photoreducible xanthene derivative, acts as a Type II photoinitiator of free radical polymerizations when used in combination with alcohols or amines as co-initiators. Previous work utilizing eosin in polymerizations focused o

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10

Qi, Genggeng. "Unconventional radical miniemulsion polymerization." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2008. http://hdl.handle.net/1853/26547.

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Thesis (Ph.D)--Chemical Engineering, Georgia Institute of Technology, 2009.<br>Committee Chair: Jones, Christopher W.; Committee Chair: Schork, F. Joseph; Committee Member: Koros, William J.; Committee Member: Lyon, Andrew; Committee Member: Nenes, Athanasios. Part of the SMARTech Electronic Thesis and Dissertation Collection.

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Più fonti

Libri sul tema "Polymerization"

1

Hadjichristidis, Nikos, and Akira Hirao, eds. Anionic Polymerization. Springer Japan, 2015. http://dx.doi.org/10.1007/978-4-431-54186-8.

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2

Belfield, Kevin D., and James V. Crivello, eds. Photoinitiated Polymerization. American Chemical Society, 2003. http://dx.doi.org/10.1021/bk-2003-0847.

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3

Arjunan, Palanisamy, James E. McGrath, and Thomas L. Hanlon, eds. Olefin Polymerization. American Chemical Society, 1999. http://dx.doi.org/10.1021/bk-2000-0749.

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4

Faust, Rudolf, and Timothy D. Shaffer, eds. Cationic Polymerization. American Chemical Society, 1997. http://dx.doi.org/10.1021/bk-1997-0665.

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5

Qin, Anjun, and Ben Zhong Tang, eds. Click Polymerization. Royal Society of Chemistry, 2018. http://dx.doi.org/10.1039/9781788010108.

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6

Buchmeiser, Michael R., ed. Metathesis Polymerization. Springer Berlin Heidelberg, 2005. http://dx.doi.org/10.1007/b101315.

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7

R, Buchmeiser Michael, ed. Metathesis polymerization. Springer, 2005.

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8

1960-, Belfield Kevin, and Crivello James V. 1940-, eds. Photoinitiated polymerization. American Chemical Society, 2003.

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9

Kennedy, Joseph Paul. Carbocationic polymerization. Krieger Pub. Co., 1991.

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10

Yasuda, H. Plasma polymerization. Academic Press, 1985.

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Capitoli di libri sul tema "Polymerization"

1

Ambade, Ashootosh V. "Ring-Opening Polymerization and Metathesis Polymerizations." In Metal-Catalyzed Polymerization. CRC Press, 2017. http://dx.doi.org/10.1201/9781315153919-4.

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2

Tadros, Tharwat. "Polymerization." In Encyclopedia of Colloid and Interface Science. Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-20665-8_134.

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3

Gooch, Jan W. "Polymerization." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_9133.

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4

Mishra, Munmaya, and Biao Duan. "Polymerization." In The Essential Handbook of Polymer Terms and Attributes. CRC Press, 2024. http://dx.doi.org/10.1201/9781003161318-171.

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5

Dyson, R. W. "Polymerization." In Specialty Polymers. Springer US, 1987. http://dx.doi.org/10.1007/978-1-4615-7894-9_3.

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6

Dyson, R. W. "Polymerization." In Specialty Polymers. Springer Netherlands, 1998. http://dx.doi.org/10.1007/978-94-009-0025-7_3.

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7

MILLER, I. K., and J. ZIMMERMAN. "Condensation Polymerization and Polymerization Mechanisms." In ACS Symposium Series. American Chemical Society, 1985. http://dx.doi.org/10.1021/bk-1985-0285.ch008.

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8

Ratkanthwar, Kedar, Junpeng Zhao, Hefeng Zhang, Nikos Hadjichristidis, and Jimmy Mays. "Schlenk Techniques for Anionic Polymerization." In Anionic Polymerization. Springer Japan, 2015. http://dx.doi.org/10.1007/978-4-431-54186-8_1.

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9

Chen, Yougen, Keita Fuchise, Toshifumi Satoh, and Toyoji Kakuchi. "Group Transfer Polymerization of Acrylic Monomers." In Anionic Polymerization. Springer Japan, 2015. http://dx.doi.org/10.1007/978-4-431-54186-8_10.

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10

Li, Zhong, and Durairaj Baskaran. "Surface-Initiated Anionic Polymerization from Nanomaterials." In Anionic Polymerization. Springer Japan, 2015. http://dx.doi.org/10.1007/978-4-431-54186-8_11.

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Atti di convegni sul tema "Polymerization"

1

Liu, Rui, Xi Chen, and Antonios Armaou. "Accelerated Process Modelling for Light-Mediated Controlled Radical Polymerization." In The 35th European Symposium on Computer Aided Process Engineering. PSE Press, 2025. https://doi.org/10.69997/sct.128107.

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Mathematical modelling and simulation are pivotal components in process systems engineering. Focusing on polymerization process systems, identifying microscopic properties of polymers is highly sought after for advancing kinetic comprehension and facilitating industrial applications. Among various computational methods predicting polymeric properties microscopically, kinetic Monte Carlo (kMC) offers a stochastic framework to characterize individual polymer chains and track dynamic system evolution, providing mechanistic insights into complex polymerization kinetics. In this study, an accuratel

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2

Jaiswal, Arun, Sweta Rani, Gaurav Pratap Singh, et al. "Combining Single and Two -photon Polymerization: An Approach to Generate Laminated Anticounterfeiting Tags." In Frontiers in Optics. Optica Publishing Group, 2024. https://doi.org/10.1364/fio.2024.jd4a.81.

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Combination of single and two-photon polymerization have been exploited to generate laminated nanopatterned tags. A micro-QR code is fabricated using two-photon lithography, and the subsequent lamination is achieved via single-photon polymerization.

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3

Johnson, Jason E., Yijie Chen, Paul Somers, and Xianfan Xu. "Modeling of polymerization kinetics in femtosecond two photon polymerization." In Synthesis and Photonics of Nanoscale Materials XVIII, edited by Andrei V. Kabashin, Jan J. Dubowski, David B. Geohegan, and Maria Farsari. SPIE, 2021. http://dx.doi.org/10.1117/12.2581960.

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4

Cademartiri, Ludovico, Reihaneh Malakooti, Georg von Freymann, et al. "Nanocrystal Plasma Polymerization." In PHYSICS OF SEMICONDUCTORS: 28th International Conference on the Physics of Semiconductors - ICPS 2006. AIP, 2007. http://dx.doi.org/10.1063/1.2730258.

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5

Pojman, John. "Frontal polymerization in microgravity." In 36th AIAA Aerospace Sciences Meeting and Exhibit. American Institute of Aeronautics and Astronautics, 1998. http://dx.doi.org/10.2514/6.1998-813.

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6

Johnson, Heather F., Sahban N. Ozair, Andrew T. Jamieson, Brian C. Trinque, Colin C. Brodsky, and C. Grant Willson. "Cationic graft polymerization lithography." In Microlithography 2003, edited by Roxann L. Engelstad. SPIE, 2003. http://dx.doi.org/10.1117/12.484974.

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7

CENTELLAS, POLETTE, MOSTAFA YOURDKHANI, IAN D. ROBERTSON, JEFFREY S. MOORE, NANCY R. SOTTOS, and SCOTT R. WHITE. "Frontal Polymerization of Dicyclopentadiene." In American Society for Composites 2017. DEStech Publications, Inc., 2017. http://dx.doi.org/10.12783/asc2017/15291.

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8

Wang, Chunhong, and Ming Zhang. "Study on the Self-polymerization and Co-polymerization Properties of Gadolinium Methacrylate." In International Conference on Industrial Application Engineering 2017. The Institute of Industrial Applications Engineers, 2017. http://dx.doi.org/10.12792/iciae2017.022.

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9

Zhang, Yujuan, Jing Xu, Mengting Duan, et al. "An Investigation on Self-polymerization and Co-polymerization Properties of Lead Methacrylate." In International Conference on Industrial Application Engineering 2019. The Institute of Industrial Applications Engineers, 2019. http://dx.doi.org/10.12792/iciae2019.015.

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Liu, Ting, Shi-Jian Chen, and Bo-Quan Jiang. "Preparation of Methylphenylvinyl Raw Rubber by Bulk Polymerization and Ring-Opening Polymerization Methods." In 2015 International Conference on Material Science and Applications (icmsa-15). Atlantis Press, 2015. http://dx.doi.org/10.2991/icmsa-15.2015.61.

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Rapporti di organizzazioni sul tema "Polymerization"

1

Matyjaszewski, Krzysztof. Introduction of Living Polymerization. Living and/or Controlled Polymerization. Defense Technical Information Center, 1994. http://dx.doi.org/10.21236/ada280800.

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2

Taylor, C., and C. Wilkerson. Surface polymerization agents. Office of Scientific and Technical Information (OSTI), 1996. http://dx.doi.org/10.2172/442223.

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3

Schrock, Richard R. Ring Opening Metathesis Polymerization. Defense Technical Information Center, 1992. http://dx.doi.org/10.21236/ada244693.

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Tumas, W., K. Ott, and R. T. Baker. Heterogeneous oxidative and polymerization processes. Office of Scientific and Technical Information (OSTI), 1998. http://dx.doi.org/10.2172/672308.

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5

Grubbs, Robert H. Living Catalysts for Cyclohexdiene Polymerization. Defense Technical Information Center, 1996. http://dx.doi.org/10.21236/ada326125.

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6

Chen, Peng. Single-Molecule Visualization of Living Polymerization. Defense Technical Information Center, 2014. http://dx.doi.org/10.21236/ada606984.

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Adnani-Gleason, Z. Polymerization of Amino Acids on Kaolinite. Portland State University Library, 2000. http://dx.doi.org/10.15760/etd.2372.

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Katz, Thomas J. Polymer Syntheses and Mechanisms of Polymerization. Defense Technical Information Center, 1991. http://dx.doi.org/10.21236/ada233034.

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Hurlbutt, Katey. Silicone Resins for Vat Polymerization Printing. Office of Scientific and Technical Information (OSTI), 2024. http://dx.doi.org/10.2172/2318929.

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10

Waite, J. H. Polymerization of Quinone-Crosslinked Marine Bioadhesive Protein. Defense Technical Information Center, 1988. http://dx.doi.org/10.21236/ada200224.

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