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Letteratura scientifica selezionata sul tema "Silica polymerization"

Autore: Grafiati

Pubblicato: 4 giugno 2021

Ultima modifica: 11 febbraio 2022

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Articoli di riviste sul tema "Silica polymerization"

1

Cheah, Pohlee, Caitlin N. Bhikha, John H. O’Haver, and Adam E. Smith. "Effect of Oxygen and Initiator Solubility on Admicellar Polymerization of Styrene on Silica Surfaces." International Journal of Polymer Science 2017 (2017): 1–7. http://dx.doi.org/10.1155/2017/6308603.

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Although admicellar polymerization has been termed the surface analog of emulsion polymerization, previous reports utilizing free radical-initiated admicellar polymerization relied on high levels of the free radical initiator when compared to emulsion polymerization, likely due to the presence of oxygen in the reported admicellar polymerization systems. Admicellar polymerizations of styrene on the surface of precipitated silica initiated by either a water-soluble or a water-insoluble initiator were studied to determine the effect of dissolved oxygen and free radical initiator solubility on the

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2

Zhang, Zhenghe, Pengcheng Zhang, Yong Wang, and Weian Zhang. "Recent advances in organic–inorganic well-defined hybrid polymers using controlled living radical polymerization techniques." Polymer Chemistry 7, no. 24 (2016): 3950–76. http://dx.doi.org/10.1039/c6py00675b.

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Controlled living radical polymerizations, such as ATRP and RAFT polymerization, could be utilized for the preparation of well-defined organic–inorganic hybrid polymers based on POSS, PDMS, silica nanoparticles, graphene, CNTs and fullerene.

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3

Bailly, Bérangère, Anne-Carole Donnenwirth, Christèle Bartholome, Emmanuel Beyou, and Elodie Bourgeat-Lami. "Silica-Polystyrene Nanocomposite Particles Synthesized by Nitroxide-Mediated Polymerization and Their Encapsulation through Miniemulsion Polymerization." Journal of Nanomaterials 2006 (2006): 1–10. http://dx.doi.org/10.1155/jnm/2006/76371.

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Polystyrene (PS) chains with molecular weights comprised between 8000 and 64000g⋅mol-1and narrow polydispersities were grown from the surface of silica nanoparticles (Aerosil A200 fumed silica and Stöber silica, resp.) through nitroxide-mediated polymerization (NMP). Alkoxyamine initiators based on N-tert-butyl-1-diethylphosphono-2,2-dimethylpropyl nitroxide (DEPN) and carrying a terminal functional group have been synthesized in situ and grafted to the silica surface. The resulting grafted alkoxyamines have been employed to initiate the growth of polystyrene chains from the inorganic surface.

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4

YOSHITAKE, Hideaki. "Polymerization of Monodisperse Silica Particles." Hosokawa Powder Technology Foundation ANNUAL REPORT 22 (2014): 88–93. http://dx.doi.org/10.14356/hptf.12114.

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5

Li, Hua-Rong, Liming Che, and Zheng-Hong Luo. "Modeling intraparticle transports during propylene polymerizations using supported metallocene and dual function metallocene as catalysts: Single particle model." Chemical Industry and Chemical Engineering Quarterly 20, no. 2 (2014): 249–60. http://dx.doi.org/10.2298/ciceq120722006l.

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Two improved multigrain models (MGMs) for preparing homopolypropylene and long chain branched polypropylene via propylene polymerization using silica-supported metallocene or dual function metallocene as catalysts are presented in this paper. The presented models are used to predict the intraparticle flow fields involved in the polymerizations. The simulation results show that the flow field distributions involve dare basically identical. The results also show that both the two polymerization processes have an initiation stage and the controlling step for them is reaction-diffusion-reaction wi

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6

Belelli, Patricia G., Marı́a L. Ferreira, and Daniel E. Damiani. "Silica-supported metallocene for ethylene polymerization." Applied Catalysis A: General 228, no. 1-2 (March 2002): 189–202. http://dx.doi.org/10.1016/s0926-860x(01)00976-0.

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7

Chaimberg, Mark, Richard Parnas, and Yoram Cohen. "Graft polymerization of polyvinylpyrrolidone onto silica." Journal of Applied Polymer Science 37, no. 10 (May 20, 1989): 2921–31. http://dx.doi.org/10.1002/app.1989.070371011.

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8

Feuston, B. P., and S. H. Garofalini. "Onset of polymerization in silica sols." Chemical Physics Letters 170, no. 2-3 (July 1990): 264–70. http://dx.doi.org/10.1016/0009-2614(90)87126-c.

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9

Moraes, John, Kohji Ohno, Guillaume Gody, Thomas Maschmeyer, and Sébastien Perrier. "The synthesis of well-defined poly(vinylbenzyl chloride)-grafted nanoparticles via RAFT polymerization." Beilstein Journal of Organic Chemistry 9 (June 25, 2013): 1226–34. http://dx.doi.org/10.3762/bjoc.9.139.

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We describe the use of one of the most advanced radical polymerization techniques, the reversible addition fragmentation chain transfer (RAFT) process, to produce highly functional core–shell particles based on a silica core and a shell made of functional polymeric chains with very well controlled structure. The versatility of RAFT polymerization is illustrated by the control of the polymerization of vinylbenzyl chloride (VBC), a highly functional monomer, with the aim of designing silica core–poly(VBC) shell nanoparticles. Optimal conditions for the control of VBC polymerization by RAFT are f

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10

Stoiljkovic, Dragoslav, Branka Pilic, Misa Bulajic, Nebojsa Djurasovic, and Nikolaj Ostrovskii. "The charge percolation mechanism and simulation of Ziegler-Natta polymerizations, Part VII: Effects of the distribution of chromium active centers on silica on the polymerization of ethylene." Journal of the Serbian Chemical Society 73, no. 1 (2008): 97–111. http://dx.doi.org/10.2298/jsc0801097s.

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The charge percolation mechanism (CPM) of olefin polymerization in the presence of transition metal compounds has been applied to explain the polymerization of ethylene by silica supported chromium oxide. In the previous work of this series, the fundamental issues and mechanism of this polymeri?zation were presented. In this work the compatibility of the CPM with the em?pirical findings is confirmed. The CPM has been applied to explain: the appea?rance of an induction period; the deactivation of active centers and the forma?tion of oligomers; the effects of chromium concentration on the silica

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Tesi sul tema "Silica polymerization"

1

Yang, Minghua. "Silica supported metallocene catalysts and olefin polymerization." Thesis, University of Manchester, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.488443.

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2

Constable, Andrew N. "Functionalization of silica micro-capillaries and silica nanoparticles via polymber brushes." Akron, OH : University of Akron, 2008. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=akron1221746490.

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Dissertation (Ph. D.)--University of Akron, Dept. of Polymer Science, 2008.<br>"December, 2008." Title from electronic dissertation title page (viewed 12/28/2008) Advisor, Roderic P. Quirk; Committee members, Scott Collins, Ali Dhinojwala, Li Jia, Mark D. Soucek; Department Chair, Ali Dhinojwala; Dean of the College, Stephen Z. D. Cheng; Dean of the Graduate School, George R. Newkome. Includes bibliographical references.

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3

Kaßner, Lysann, Kevin Nagel, R. E. Grützner, Marcus Korb, Tobias Rüffer, Heinrich Lang, and Stefan Spange. "Polyamide 6/silica hybrid materials by a coupled polymerization reaction." Universitätsbibliothek Chemnitz, 2016. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-197628.

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Polyamide 6/SiO2 hybrid materials were produced by a coupled polymerization reaction of three monomeric components namely 1,1′,1′′,1′′′-silanetetrayltetrakis-(azepan-2-one) (Si(ε-CL)4), 6-aminocaproic acid (ε-ACA) and ε-caprolactam (ε-CL) within one process. Si(ε-CL)4 together with ε-ACA has been found suitable as a precursor monomer for the silica and PA6 components. The accurate adjustment of the molar ratio of both components, as well as the combination of the overall process for producing the polyamide 6/SiO2 hybrid material with the hydrolytic ring opening polymerization of ε-caprolactam

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4

堀内, 達郎, and Tatsuro HORIUCHI. "Effects of amide additives on polymerization of silica under acidic conditions." Elsevier, 1992. http://hdl.handle.net/2237/16357.

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5

McKittrick, Michael W. "Single-Site Olefin Polymerization Catalysts via the Molecular Design of Porous Silica." Diss., Georgia Institute of Technology, 2005. http://hdl.handle.net/1853/6871.

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The major goals of this work were to: develop a new methodology for the preparation of site-isolated catalytic sites on a silica surface, prepare the first truly single-site supported metallocene/CGC polymerization catalyst, and develop structure-reactivity relationships for these new systems. To synthesize these novel catalysts, the approach taken was to develop a protocol which allows for the synthesis of an aminosilica material with isolated, uniform amine sites. This patterned aminosilica was then used as a scaffold to support a constrained geometry catalyst. These functionalizations occ

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6

Liu, Yi. "Mesoporous silica/polymer nanocomposites." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2009. http://hdl.handle.net/1853/31739.

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Thesis (Ph.D)--Polymer, Textile and Fiber Engineering, Georgia Institute of Technology, 2010.<br>Committee Chair: Jacob. Karl; Committee Member: Griffin. Anselm; Committee Member: Tannenbaum. Rina; Committee Member: Thio. Yonathan S; Committee Member: Yao. Donggang. Part of the SMARTech Electronic Thesis and Dissertation Collection.

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7

Cheng, Xu. "The Use of Functionalized Zirconocenes as Precursors to Silica-Supported Zirconocene Olefin Polymerization Catalysts." Diss., Virginia Tech, 2001. http://hdl.handle.net/10919/30027.

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Deck and coworkers previously showed that Me3Si substituents adjacent to group 4 metallocene dichlorides (M = Ti, Zr, Hf) are converted to corresponding BrMe2Si groups using BBr3, and that these BrMe2Si substituents are highly reactive to nucleophilic reagents such as water. The high reactivity of the Si-Br bonds suggested that these substituents could react with hydroxyl groups on the surface of partially dehydroxylated silica, forming covalently immobilized metallocene catalysts. This dissertation concerns the synthesis of electrophile-functionalized zirconocene dihalide complexes and the u

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8

Qiao, Xiaoguang. "Synthesis of silica-polymer hybrid particles via controlled radical polymerization in aqueous dispersed media." Thesis, Lyon 1, 2013. http://www.theses.fr/2013LYO10332/document.

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Des polymères à base de méthacrylate de poly(oxyde d'éthylène) (PEOMA) avec des chaînes pendantes PEO (Mn = 300 ou 950 g mol-1) ou des copolymères de PEOMA300 et d'acide méthacrylique (AMA) ont été synthétisés par polymérisation radicalaire contrôlée par les nitroxydes en utilisant une alkoxyamine (BlocBuilder®) comme amorceur en présence de SG1 et d'une faible quantité de styrène. Les copolymères à base de PEOMA300 et d'AMA sont thermo- et pH-sensibles. Les deux types de macroalkoxyamines ont été utilisés pour amorcer la copolymérisation en émulsion du méthacrylate de n-butyle et du styrène e

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9

Fu, Anqiu. "Effect of the silica support on the reactivity and polymerization activity of organochromium complexes." Thesis, University of Ottawa (Canada), 2002. http://hdl.handle.net/10393/6159.

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The effect of the support in heterogeneous catalysis is very important but often poorly understood. The reaction of tetraneopentylchromium(IV) with Sylopol 952, a silica gel used industrially as a carrier for alpha-olefin polymerization catalysts, has been investigated and compared with the previously reported reaction on Aerosil 200, a fumed silica often used to model catalyst supports. Grafting, thermolysis, and metathetical exchange reactions of chromium(IV) neopentylidenes were found to be the same on either Aerosil 200 or Sylopol 952. However, reactivity of the grafted organochromium frag

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10

Hicks, Jason Christopher. "Organic/inorganic hybrid amine and sulfonic acid tethered silica materials synthesis, characterization and application /." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2007. http://hdl.handle.net/1853/26583.

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Thesis (Ph.D)--Chemical Engineering, Georgia Institute of Technology, 2008.<br>Committee Chair: Jones, Christopher; Committee Member: Koros, William; Committee Member: Lyon, Andrew; Committee Member: Nair, Sankar; Committee Member: Weck, Marcus. Part of the SMARTech Electronic Thesis and Dissertation Collection.

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Più fonti

Libri sul tema "Silica polymerization"

1

Zirkzee, Hendricus Franciscus. A novel approcah to the encapsulation of silica particles: Mechanisims and kinetics. Eindhoven: Technische Universiteit Eindhoven, 1997.

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2

Brewer, Nicholas Jason. The influence of preparing silica supported catalysts in various solvents on the rate of polymerization. Manchester: UMIST, 1998.

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3

United States. National Aeronautics and Space Administration., ed. Polysiloxanes derived from the controlled hydrolysis of tetraethoxysilane as precursors to silica for use in ceramic processing. [Washington, D.C: National Aeronautcs and Space Administration, 1990.

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4

1942-, Kricheldorf Hans Rytger, and Burger C, eds. Silicon in polymer synthesis. Berlin: Springer, 1996.

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5

T, Bhatt Ramakrishna, and United States. National Aeronautics and Space Administration., eds. The effect of polymer char on nitridation kinetics of silicon. [Washington, DC]: National Aeronautics and Space Administration, 1994.

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6

T, Bhatt Ramakrishna, and United States. National Aeronautics and Space Administration., eds. The effect of polymer char on nitridation kinetics of silicon. [Washington, DC]: National Aeronautics and Space Administration, 1994.

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Capitoli di libri sul tema "Silica polymerization"

1

Ebeling, Bastian. "Nanocomposites via Polymerization from Silica." In Springer Theses, 199–213. Cham: Springer International Publishing, 2015. http://dx.doi.org/10.1007/978-3-319-15245-5_7.

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2

Blitz, Jonathan P. "Model Silica Supported Olefin Polymerization Catalysts." In New Advances in Polyolefins, 1–14. Boston, MA: Springer US, 1993. http://dx.doi.org/10.1007/978-1-4615-2992-7_1.

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3

Liu, Zhen, and Boping Liu. "Computational Studies of Chromium/Silica Catalysts." In Handbook of Transition Metal Polymerization Catalysts, 131–60. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2018. http://dx.doi.org/10.1002/9781119242277.ch5.

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4

Pullukat, Thomas J., and Robert E. Patterson. "Porous Silica in Transition Metal Polymerization Catalysts." In Handbook of Transition Metal Polymerization Catalysts, 31–55. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2018. http://dx.doi.org/10.1002/9781119242277.ch2.

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Pullukat, Thomas J., and Robert E. Patterson. "Porous Silica in Transition Metal Polymerization Catalysts." In Handbook of Transition Metal Polymerization Catalysts, 29–52. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2010. http://dx.doi.org/10.1002/9780470504437.ch2.

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6

Cheng, Ruihua, Zhen Liu, Lei Zhong, Xuelian He, Pengyuan Qiu, Minoru Terano, Moris S. Eisen, Susannah L. Scott, and Boping Liu. "Phillips Cr/Silica Catalyst for Ethylene Polymerization." In Polyolefins: 50 years after Ziegler and Natta I, 135–202. Berlin, Heidelberg: Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/12_2013_222.

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7

Cann, Kevin. "Silica-Supported Silyl Chromate-Based Ethylene Polymerization Catalysts." In Handbook of Transition Metal Polymerization Catalysts, 447–57. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2010. http://dx.doi.org/10.1002/9780470504437.ch11.

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Cann, Kevin. "Silica-Supported Silyl Chromate-Based Ethylene Polymerization Catalysts." In Handbook of Transition Metal Polymerization Catalysts, 573–89. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2018. http://dx.doi.org/10.1002/9781119242277.ch14.

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9

Hardcastle, Franklin D., Jih-Mirn Jehng, Chung-Ku Chen, and Israel E. Wachs. "Raman Spectroscopy of Surface Rhenium Oxide on Alumina, Silica, Titania, Niobia, and Magnesia." In Olefin Metathesis and Polymerization Catalysts, 543. Dordrecht: Springer Netherlands, 1990. http://dx.doi.org/10.1007/978-94-011-3328-9_24.

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Tait, Peter J. T., and Johannes A. M. Awudza. "Prepolymerization and Copolymerization Studies Using Homogeneous and Silica-supported Cp2ZrCI2/MAO Catalyst Systems." In Organometallic Catalysts and Olefin Polymerization, 414–26. Berlin, Heidelberg: Springer Berlin Heidelberg, 2001. http://dx.doi.org/10.1007/978-3-642-59465-6_37.

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Atti di convegni sul tema "Silica polymerization"

1

Akhavan, B., K. Jarvis, and P. Majewski. "Development of hydrophobic silica powders using plasma polymerization technology." In 2012 IEEE 39th International Conference on Plasma Sciences (ICOPS). IEEE, 2012. http://dx.doi.org/10.1109/plasma.2012.6383876.

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2

Baicea, C., A. Ivan, C. Trisca-Rusu, A. C. Nechifor, D. I. Vaireanu, S. I. Voicu, and G. Nechifor. "Ionic conductive silica-polypyrrole composites obtained by in-situ polymerization." In 2010 International Semiconductor Conference (CAS 2010). IEEE, 2010. http://dx.doi.org/10.1109/smicnd.2010.5650655.

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3

Tajima, Shota, Tatsuya Kato, Shigeshi Fuchida, Takao Kitagawa, and Chiharu Tokoro. "Kinetic Modeling of pH and Temperature Effects on Silica Polymerization." In Goldschmidt2020. Geochemical Society, 2020. http://dx.doi.org/10.46427/gold2020.2529.

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4

Correa, Daniel S., Marcos R. Cardoso, Vinicius Tribuzi, Rafael H. Pacheco, and Cleber R. Mendonca. "Excitation of Microstructures Fabricated by Two-photon Polymerization Through Silica Nanowires." In Latin America Optics and Photonics Conference. Washington, D.C.: OSA, 2010. http://dx.doi.org/10.1364/laop.2010.wi4.

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Bhattacharyya, Arpita, and Catherine Klapperich. "Fabrication of Polymeric Microfluidic Device for On-Chip Isolation of Nucleic Acids." In ASME 3rd International Conference on Microchannels and Minichannels. ASMEDC, 2005. http://dx.doi.org/10.1115/icmm2005-75200.

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A microfluidic chip-based solid phase extraction method for isolation of nucleic acids is demonstrated. The chip was fabricated in a cyclic polyolefin by hot embossing with a master. The solid phase was made by in-situ UV polymerization of a monolithic column impregnated with silica particles, and separation was achieved due to irreversible binding of the nucleic acids to the silica particles in the monolith. The porous monolithic column was formed within the channels of the device by photoinitiated polymerization of a mixture of methacrylate and dimethacrylate monomers, UV sensitive free radi

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Reyes, Enrique Antonio. "Applications and Laboratory Studies of a New Class of Silica Polymerization Inhibitors of Biorenewable Origin." In Brasil Offshore. Society of Petroleum Engineers, 2011. http://dx.doi.org/10.2118/143662-ms.

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Onoda, M., T. Moritake, T. Matsuda, and H. Nakayama. "Physical properties and application of conducting polypyrrole-silica glass composite films prepared by electrochemical polymerization." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.835312.

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Jung, Hojoong, Yong Gon Seo, Woosung Ha, Seung Han Park, and Kyunghwan Oh. "New Type of Long-period Fiber Grating by Self-Assembled Periodic Polymerization in Silica Hollow Optical Fiber." In National Fiber Optic Engineers Conference. Washington, D.C.: OSA, 2009. http://dx.doi.org/10.1364/nfoec.2009.jtha15.

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Yan, Wei, B. T. Phung, Zhao Jun Han, and Kostya Ken Ostrikov. "Dielectric performance of nanocomposites synthesized by poly(ethylene oxide)-like film coated silica nanoparticles by plasma polymerization." In 2013 IEEE Electrical Insulation Conference (EIC). IEEE, 2013. http://dx.doi.org/10.1109/eic.2013.6554281.

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Li, Kuo-Tseng, and Cheng-Ni Yang. "Synthesis of uniform rod-like polymer particles via propylene polymerization using metallocene catalysts supported on Stober silica." In MATERIALS CHARACTERIZATION USING X-RAYS AND RELATED TECHNIQUES. Author(s), 2019. http://dx.doi.org/10.1063/1.5088275.

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Rapporti di organizzazioni sul tema "Silica polymerization"

1

Spoerke, Erik David, Sylvie Aubry, Pamela Lane, David B. Robinson, Christina A. Bauer, Frank Zendejas, Huu Tran, Todd W. Lane, and Blake Alexander Simmons. Understanding amine catalyzed silica polymerization : diatoms as bioarchitects. Office of Scientific and Technical Information (OSTI), October 2007. http://dx.doi.org/10.2172/922086.

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Ramamurthi, S. Molecular growth pathways in silica sol-gel polymerization. Office of Scientific and Technical Information (OSTI), January 1989. http://dx.doi.org/10.2172/6236739.

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3

Zhou, Steven Q., Young T. Park, Georges Manuel, and William P. Weber. Composite Materials with Improved Properties in Compression. Appendix 2. Anionic Ring Opening Polymerization of 1-Silacyclopent-3-ene. Characterization of Poly(1-sila-cis-pent-3-ene) by 1H, 13C, and 29Si NMR Spectroscopy. Fort Belvoir, VA: Defense Technical Information Center, May 1990. http://dx.doi.org/10.21236/ada221647.

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