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1

Hilinski, Michael, Shea Johnson und Logan Combee. „Organocatalytic Atom-Transfer C(sp3)–H Oxidation“. Synlett 29, Nr. 18 (27.06.2018): 2331–36. http://dx.doi.org/10.1055/s-0037-1610432.

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Predictably site-selective catalytic methods for intermolecular C(sp3)–H hydroxylation and amination hold great promise for the synthesis and late-stage modification of complex molecules. Transition-metal catalysis has been the most common approach for early investigations of this type of reaction. In comparison, there are far fewer ­reports of organocatalytic methods for direct oxygen or nitrogen insertion into C–H bonds. Herein, we provide an overview of early efforts in this area, with particular emphasis on our own recent development of an iminium salt that catalyzes both oxygen and nitrogen insertion.1 Introduction2 Background: C–H Oxidation Capabilities of Heterocyclic Oxidants3 Oxaziridine-Mediated Catalytic Hydroxylation4 Dioxirane-Mediated Catalytic Hydroxylation5 Iminium Salt Catalysis of Hydroxylation and Amination6 Conclusion and Outlook
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2

Zhang, Hua, und Li Wang. „Metal-Free Catalytic Aromatic C–H Borylation“. Synlett 31, Nr. 19 (11.08.2020): 1857–61. http://dx.doi.org/10.1055/s-0040-1707241.

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In recent decades, C–H borylation has undergone rapid development and has become one of the most important and efficient methods for the synthesis of organoboron compounds. Although transition-metal catalysis dominates C–H borylation, the metal-free approach has emerged as a promising alternative strategy. This article briefly summarizes the history of metal-free aromatic C–H borylation, including early reports on electrophilic C–H borylation and recent progress in metal-free catalytic intermolecular C–H borylation; it also highlights our recent work on BF3·Et2O-catalyzed C2–H borylation of hetarenes. Despite these recent advances, comprehensive mechanistic studies on various metal-free catalytic aromatic C–H borylations and novel processes with a wider substrate scope are eagerly expected in the near future.
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3

Kakiuchi, Fumitoshi, und Shinji Murai. „Catalytic C−H/Olefin Coupling“. Accounts of Chemical Research 35, Nr. 10 (Oktober 2002): 826–34. http://dx.doi.org/10.1021/ar960318p.

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4

Murai, S., F. Kakiuchi, S. Sekine, Y. Tanaka, Asayuki Kamatani, M. Sonoda und Naoto Chatani. „Catalytic C-H/olefin coupling“. Pure and Applied Chemistry 66, Nr. 7 (01.01.1994): 1527–34. http://dx.doi.org/10.1351/pac199466071527.

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5

Bach, T., A. Nörder, P. Herrmann und E. Herdtweck. „Diastereoselective Catalytic C-H Amination“. Synfacts 2010, Nr. 10 (22.09.2010): 1141. http://dx.doi.org/10.1055/s-0030-1258647.

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6

Chen, Qing-An, Wei-Song Zhang und Yan-Cheng Hu. „Isoprene: A Promising Coupling Partner in C–H Functionalizations“. Synlett 31, Nr. 17 (02.07.2020): 1649–55. http://dx.doi.org/10.1055/s-0040-1707172.

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Five-carbon dimethylallyl units, such as prenyl and reverse-prenyl, are widely distributed in natural indole alkaloids and terpenoids. In conventional methodologies, these valuable motifs are often derived from substrates bearing leaving groups, but these processes are accompanied by the generation of stoichiometric amounts of by-products. From an economical and environmental point of view, the basic industrial feedstock isoprene is an ideal alternative precursor. However, given that electronically unbiased isoprene might undergo six possible addition modes in the coupling reactions, it is difficult to control the selectivity. This article summarizes the strategies we have developed to achieve regioselective C–H functionalizations of isoprene under transition-metal and acid catalysis.1 Introduction2 Catalytic Coupling of Indoles with Isoprene3 Catalytic Coupling of Formaldehyde, Arenes and Isoprene4 Catalytic Coupling of 4-Hydroxycoumarins with Isoprene5 Catalytic Coupling of Cyclic 1,3-Diketones with Isoprene6 Conclusion and Outlook
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7

Nishii, Yuji, und Masahiro Miura. „Construction of Benzo-Fused Polycyclic Heteroaromatic Compounds through Palladium-Catalyzed Intramolecular C-H/C-H Biaryl Coupling“. Catalysts 13, Nr. 1 (22.12.2022): 12. http://dx.doi.org/10.3390/catal13010012.

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Dibenzo-fused five-membered heteroaromatic compounds, including dibenzofuran, carbazole, and dibenzothiophene, are fundamental structural units in various important polycyclic heteroaromatic compounds. The intramolecular C-H/C-H biaryl coupling of diaryl (thio)ethers and amines based on palladium(II) catalysis under oxidative conditions is known to be one of the most effective, step-economic methods for their construction. Representative examples for the construction of structurally intriguing π-extended polycyclic heteroaromatics through catalytic coupling reactions are briefly summarized in this mini-review.
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8

Collet, Florence, Camille Lescot, Chungen Liang und Philippe Dauban. „Studies in catalytic C–H amination involving nitrene C–H insertion“. Dalton Transactions 39, Nr. 43 (2010): 10401. http://dx.doi.org/10.1039/c0dt00283f.

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9

Bedford, Robin B., Charlotte J. Mitchell und Ruth L. Webster. „Solvent free catalytic C–H functionalisation“. Chemical Communications 46, Nr. 18 (2010): 3095. http://dx.doi.org/10.1039/c003074k.

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10

Young, Andrew J., und M. Christina White. „Catalytic Intermolecular Allylic CH Alkylation“. Journal of the American Chemical Society 130, Nr. 43 (29.10.2008): 14090–91. http://dx.doi.org/10.1021/ja806867p.

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11

Reed, Sean A., und M. Christina White. „Catalytic Intermolecular Linear Allylic C−H Amination via Heterobimetallic Catalysis“. Journal of the American Chemical Society 130, Nr. 11 (März 2008): 3316–18. http://dx.doi.org/10.1021/ja710206u.

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12

Futatsugi, Kentaro. „Recent Progress in Catalytic C-H Aminations“. Journal of Synthetic Organic Chemistry, Japan 66, Nr. 6 (2008): 629–30. http://dx.doi.org/10.5059/yukigoseikyokaishi.66.629.

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13

Tosi, Eleonora, Renata Marcia de Figueiredo und Jean-Marc Campagne. „Enantioselective Catalytic C-H Amidations: An Highlight“. Catalysts 11, Nr. 4 (06.04.2021): 471. http://dx.doi.org/10.3390/catal11040471.

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The crucial role played by compounds bearing amide functions, not only in biological processes but also in several fields of chemistry, life polymers and material sciences, has brought about many significant discoveries and innovative approaches for their chemical synthesis. Indeed, a plethora of strategies has been developed to reach such moieties. Amides within chiral molecules are often associated with biological activity especially in life sciences and medicinal chemistry. In most of these cases, their synthesis requires extensive rethinking methodologies. In the very last years (2019–2020), enantioselective C-H functionalization has appeared as a straightforward alternative to reach chiral amides. Therein, an overview on these transformations within this timeframe is going to be given.
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14

Collet, Florence, Camille Lescot und Philippe Dauban. „Catalytic C–H amination: the stereoselectivity issue“. Chemical Society Reviews 40, Nr. 4 (2011): 1926. http://dx.doi.org/10.1039/c0cs00095g.

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15

Cheng, Chen, und John F. Hartwig. „Catalytic Silylation of Unactivated C–H Bonds“. Chemical Reviews 115, Nr. 17 (25.02.2015): 8946–75. http://dx.doi.org/10.1021/cr5006414.

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16

Doyle, Michael P., Richard Duffy, Maxim Ratnikov und Lei Zhou. „Catalytic Carbene Insertion into C−H Bonds“. Chemical Reviews 110, Nr. 2 (10.02.2010): 704–24. http://dx.doi.org/10.1021/cr900239n.

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17

Gephart, Raymond T., Daria L. Huang, Mae Joanne B. Aguila, Graham Schmidt, Andi Shahu und Timothy H. Warren. „Catalytic CH Amination with Aromatic Amines“. Angewandte Chemie 124, Nr. 26 (15.05.2012): 6594–98. http://dx.doi.org/10.1002/ange.201201921.

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18

Kakiuchi, Fumitoshi, und Shinji Murai. „ChemInform Abstract: Catalytic C-H/Olefin Coupling.“ ChemInform 33, Nr. 51 (18.05.2010): no. http://dx.doi.org/10.1002/chin.200251254.

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19

Gephart, Raymond T., Daria L. Huang, Mae Joanne B. Aguila, Graham Schmidt, Andi Shahu und Timothy H. Warren. „Catalytic CH Amination with Aromatic Amines“. Angewandte Chemie International Edition 51, Nr. 26 (15.05.2012): 6488–92. http://dx.doi.org/10.1002/anie.201201921.

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20

MURAI, S., F. KAKIUCHI, S. SEKINE, Y. TANAKA, A. KAMATANI, M. SONODA und N. CHATANI. „ChemInform Abstract: Catalytic C-H/Olefin Coupling“. ChemInform 25, Nr. 42 (18.08.2010): no. http://dx.doi.org/10.1002/chin.199442300.

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21

Zhang, Lin, und En-Qing Gao. „Catalytic C(sp)-H carboxylation with CO2“. Coordination Chemistry Reviews 486 (Juli 2023): 215138. http://dx.doi.org/10.1016/j.ccr.2023.215138.

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22

Völler, Jan-Stefan. „Catalytic borylation of tertiary C–H bonds“. Nature Catalysis 6, Nr. 4 (26.04.2023): 287. http://dx.doi.org/10.1038/s41929-023-00953-0.

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23

Bähr, Susanne, und Martin Oestreich. „The electrophilic aromatic substitution approach to C–H silylation and C–H borylation“. Pure and Applied Chemistry 90, Nr. 4 (28.03.2018): 723–31. http://dx.doi.org/10.1515/pac-2017-0902.

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AbstractSeveral approaches toward electrophilic C–H silylation of electron-rich arenes are discussed, comprising transition-metal-catalyzed processes as well as Lewis-acid- and Brønsted-acid-induced protocols. These methods differ in the catalytic generation of the silicon electrophile but share proton removal in form of dihydrogen. With slight modifications, these methods are often also applicable to the related electrophilic C–H borylation.
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24

Mango, Frank D., Daniel M. Jarvie und Eleanor Herriman. „Natural catalytic activity in a marine shale for generating natural gas“. Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences 466, Nr. 2124 (21.04.2010): 3527–37. http://dx.doi.org/10.1098/rspa.2010.0032.

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Many organic-rich rocks are major sources of oil and gas in sedimentary basins presumably through high-temperature thermal cracking. This view was brought into question with recent reports of marine shales generating catalytic gas in the laboratory at 50 ° C, 300 ° C below thermal-cracking temperatures. Gas forms under natural conditions without artificial stimulation. Compositions of methane, ethane and propane are near thermodynamic equilibrium (2C 2 H 6 =CH 4 +C 3 H 8 ) mirroring those in natural deposits. It is significant because thermal cracking can neither generate hydrocarbons at equilibrium nor can it bring them to equilibrium over geological time. Thus, catalysis must be the source of equilibrium in natural gas habitats and in marine shales. There is experimental evidence for metathesis ( ) as the catalytic path to equilibrium. However, it is without example in contemporary catalysis, and therefore, calls for extraordinary empirical support. Here, we report independent and unequivocal evidence of natural catalytic activity in a marine shale linking metathesis and thermodynamic equilibrium. A Cretaceous Mowry shale catalysed the dimerization of propylene (C 3 H 6 ) to methyl cyclopentane (MCP, C 6 H 12 ) and n -hexane ( n -C 6 , C 6 H 14 ) at 50 ° C in greater than 99 per cent selectivity. Propylene increased the rate of n -C 6 generation by a factor of 100 with 100 per cent selectivity to the straight-chain hexane ( n -C 6 ). Propylene also suppressed the generation of all hydrocarbons except cyclopentane, MCP and n -C 6 . The ratio MCP/ n -C 6 , which swung chaotically between 1 and 25 before propylene addition, was rendered invariant with propylene addition ( R 2 =0.99; MCP/ n -C 6 =1.20±0.034 s.d.). These uniquely catalytic reactions confirm natural catalytic activity in this shale. It appears to be ‘palaeoactivity’ possibly conceived in early diagenesis and sustained over geological time.
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25

Benfatti, Fides, Montse Guiteras Capdevila, Luca Zoli, Elena Benedetto und Pier Giorgio Cozzi. „Catalytic stereoselective benzylic C–H functionalizations by oxidative C–H activation and organocatalysis“. Chemical Communications, Nr. 39 (2009): 5919. http://dx.doi.org/10.1039/b910185c.

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26

Lee, Sun Hwa, Serge I. Gorelsky und Georgii I. Nikonov. „Catalytic H/D Exchange of Unactivated Aliphatic C–H Bonds“. Organometallics 32, Nr. 21 (09.10.2013): 6599–604. http://dx.doi.org/10.1021/om4009372.

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27

Mantry, Lusina, Rajaram Maayuri, Vikash Kumar und Parthasarathy Gandeepan. „Photoredox catalysis in nickel-catalyzed C–H functionalization“. Beilstein Journal of Organic Chemistry 17 (31.08.2021): 2209–59. http://dx.doi.org/10.3762/bjoc.17.143.

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Catalytic C‒H functionalization has become a powerful strategy in organic synthesis due to the improved atom-, step- and resource economy in comparison with cross-coupling or classical organic functional group transformations. Despite the significant advances in the metal-catalyzed C‒H activations, recent developments in the field of metallaphotoredox catalysis enabled C‒H functionalizations with unique reaction pathways under mild reaction conditions. Given the relative earth-abundance and cost-effective nature, nickel catalysts for photoredox C‒H functionalization have received significant attention. In this review, we highlight the developments in the field of photoredox nickel-catalyzed C‒H functionalization reactions with a range of applications until summer 2021.
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28

Li, Yanjun, Yan-Cheng Liou, Xinran Chen und Lutz Ackermann. „Thioether-enabled palladium-catalyzed atroposelective C–H olefination for N–C and C–C axial chirality“. Chemical Science 13, Nr. 14 (2022): 4088–94. http://dx.doi.org/10.1039/d2sc00748g.

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29

Guillemard, Lucas, und Joanna Wencel-Delord. „When metal-catalyzed C–H functionalization meets visible-light photocatalysis“. Beilstein Journal of Organic Chemistry 16 (21.07.2020): 1754–804. http://dx.doi.org/10.3762/bjoc.16.147.

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While aiming at sustainable organic synthesis, over the last decade particular attention has been focused on two modern fields, C–H bond activation, and visible-light-induced photocatalysis. Couplings through C–H bond activation involve the use of non-prefunctionalized substrates that are directly converted into more complex molecules, without the need of a previous functionalization, thus considerably reduce waste generation and a number of synthetic steps. In parallel, transformations involving photoredox catalysis promote radical reactions in the absence of radical initiators. They are conducted under particularly mild conditions while using the visible light as a cheap and economic energy source. In this way, these strategies follow the requirements of environment-friendly chemistry. Regarding intrinsic advantages as well as the complementary mode of action of the two catalytic transformations previously introduced, their merging in a synergistic dual catalytic system is extremely appealing. In that perspective, the scope of this review aims to present innovative reactions combining C–H activation and visible-light induced photocatalysis.
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30

Li, Jing, Huanan Huang, Weihong Liang, Qun Gao und Zheng Duan. „Catalytic C–H and C–S Bond Activation of Thiophenes“. Organic Letters 15, Nr. 2 (28.12.2012): 282–85. http://dx.doi.org/10.1021/ol303136x.

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31

Brunard, Erwan, Vincent Boquet, Elsa Van Elslande, Tanguy Saget und Philippe Dauban. „Catalytic Intermolecular C(sp3)–H Amination: Selective Functionalization of Tertiary C–H Bonds vs Activated Benzylic C–H Bonds“. Journal of the American Chemical Society 143, Nr. 17 (26.04.2021): 6407–12. http://dx.doi.org/10.1021/jacs.1c03872.

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32

Ma, Jun-An, und Shen Li. „Catalytic fluorination of unactivated C(sp3)–H bonds“. Org. Chem. Front. 1, Nr. 6 (2014): 712–15. http://dx.doi.org/10.1039/c4qo00078a.

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33

Davies, Huw M. L., und Rohan E. J. Beckwith. „Catalytic Enantioselective C−H Activation by Means of Metal−Carbenoid-Induced C−H Insertion“. Chemical Reviews 103, Nr. 8 (August 2003): 2861–904. http://dx.doi.org/10.1021/cr0200217.

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34

Davies, Huw M. L., Qihui Jin, Pingda Ren und Andrey Yu Kovalevsky. „Catalytic Asymmetric Benzylic C−H Activation by Means of Carbenoid-Induced C−H Insertions“. Journal of Organic Chemistry 67, Nr. 12 (Juni 2002): 4165–69. http://dx.doi.org/10.1021/jo016351t.

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35

Al-Fatesh, Ahmed, Kenit Acharya, Ahmed I. Osman, Ghzzai Almutairi, Anis Hamza Fakeeha, Ahmed Elhag Abasaeed, Yousef A. Al-Baqmaa und Rawesh Kumar. „Kinetic Study of Zirconia-Alumina-Supported Ni-Fe Catalyst for Dry Reforming of Methane: Impact of Partial Pressure and Reaction Temperature“. International Journal of Chemical Engineering 2023 (11.05.2023): 1–11. http://dx.doi.org/10.1155/2023/8667432.

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A better understanding of the reaction mechanism and kinetics of dry reforming of methane (DRM) remains challenging, necessitating additional research to develop robust catalytic systems with high catalytic performance, low cost, and high stability. Herein, we prepared a zirconia-alumina-supported Ni-Fe catalyst and used it for DRM. Different partial pressures and temperatures are used to test the dry reforming of methane reaction as a detailed kinetic study. The optimal reaction conditions for DRM catalysis are 800°C reaction temperature, 43.42 kPa CO2 partial pressure, and 57.9 kPa CH4 partial pressure. At these optimal reaction conditions, the catalyst shows a 0.436 kPa2 equilibrium constant, a 0.7725 m o l C H 4 /gCat/h rate of CH4 consumption, a 0.00651 m o l C H 4 /m2/h arial rate of CH4 consumption, a 1.6515 m o l H 2 /gCat/h rate of H2 formation, a 1.4386 molCO/gCat/h rate of CO formation. This study’s findings will inspire the cost-effective production of robust catalytic systems and a better understanding of the DRM reaction’s kinetics.
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36

Gauchot, V., D. R. Sutherland und A. L. Lee. „Dual gold and photoredox catalysed C–H activation of arenes for aryl–aryl cross couplings“. Chemical Science 8, Nr. 4 (2017): 2885–89. http://dx.doi.org/10.1039/c6sc05469b.

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37

Chiusoli, Gian Paolo, Marta Catellani, Mirco Costa, Elena Motti, Nicola Della Ca’ und Giovanni Maestri. „Catalytic C–C coupling through C–H arylation of arenes or heteroarenes“. Coordination Chemistry Reviews 254, Nr. 5-6 (März 2010): 456–69. http://dx.doi.org/10.1016/j.ccr.2009.07.023.

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38

Yan, Ming, Li-Wei Yang, Wen-Hao Hu, Fu-Yao Zhang und Albert S. C. Chan. „ChemInform Abstract: Catalytic Asymmetric Formation of C-H and C-C Bonds“. ChemInform 32, Nr. 23 (26.05.2010): no. http://dx.doi.org/10.1002/chin.200123264.

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39

Monguchi, Daiki, Taiki Fujiwara, Hirotoshi Furukawa und Atsunori Mori. „Direct Amination of Azoles via Catalytic C−H, N−H Coupling“. Organic Letters 11, Nr. 7 (02.04.2009): 1607–10. http://dx.doi.org/10.1021/ol900298e.

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40

Matsuda, Takanori. „Catalytic Functionalization of Unactivated sp3 C-H Bonds“. Journal of Synthetic Organic Chemistry, Japan 64, Nr. 7 (2006): 780–81. http://dx.doi.org/10.5059/yukigoseikyokaishi.64.780.

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41

Santoro, Stefano, Sergei I. Kozhushkov, Lutz Ackermann und Luigi Vaccaro. „Heterogeneous catalytic approaches in C–H activation reactions“. Green Chemistry 18, Nr. 12 (2016): 3471–93. http://dx.doi.org/10.1039/c6gc00385k.

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42

Bae, Seri, Ha-Lim Jang, Haeun Jung und Jung Min Joo. „Catalytic C–H Allylation and Benzylation of Pyrazoles“. Journal of Organic Chemistry 80, Nr. 1 (17.12.2014): 690–97. http://dx.doi.org/10.1021/jo5025317.

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43

Toutov, Anton A., Wen-Bo Liu, Kerry N. Betz, Brian M. Stoltz und Robert H. Grubbs. „Catalytic C–H bond silylation of aromatic heterocycles“. Nature Protocols 10, Nr. 12 (29.10.2015): 1897–903. http://dx.doi.org/10.1038/nprot.2015.118.

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44

Johnson, S. A. „Nickel complexes for catalytic C–H bond functionalization“. Dalton Transactions 44, Nr. 24 (2015): 10905–13. http://dx.doi.org/10.1039/c5dt00032g.

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45

Xu, Liang, Guanghui Wang, Shuai Zhang, Hong Wang, Linghua Wang, Li Liu, Jiao Jiao und Pengfei Li. „Recent advances in catalytic C−H borylation reactions“. Tetrahedron 73, Nr. 51 (Dezember 2017): 7123–57. http://dx.doi.org/10.1016/j.tet.2017.11.005.

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46

Huang, Xiongyi, und John T. Groves. „Taming Azide Radicals for Catalytic C–H Azidation“. ACS Catalysis 6, Nr. 2 (31.12.2015): 751–59. http://dx.doi.org/10.1021/acscatal.5b02474.

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47

Bedford, Robin B., Charlotte J. Mitchell und Ruth L. Webster. „ChemInform Abstract: Solvent-Free Catalytic C-H Functionalization.“ ChemInform 41, Nr. 38 (26.08.2010): no. http://dx.doi.org/10.1002/chin.201038085.

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48

Badiei, Yosra M, Adriana Dinescu, Xuliang Dai, Robert M Palomino, Frank W Heinemann, Thomas R Cundari und Timothy H Warren. „Copper-Nitrene Complexes in Catalytic CH Amination“. Angewandte Chemie International Edition 47, Nr. 51 (08.12.2008): 9961–64. http://dx.doi.org/10.1002/anie.200804304.

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49

Badiei, Yosra M, Adriana Dinescu, Xuliang Dai, Robert M Palomino, Frank W Heinemann, Thomas R Cundari und Timothy H Warren. „Copper-Nitrene Complexes in Catalytic CH Amination“. Angewandte Chemie 120, Nr. 51 (08.12.2008): 10109–12. http://dx.doi.org/10.1002/ange.200804304.

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Tomin, Anna, Seema Bag und Bela Torok. „ChemInform Abstract: Catalytic C-H Bond Activation Reactions“. ChemInform 44, Nr. 18 (11.04.2013): no. http://dx.doi.org/10.1002/chin.201318231.

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