Auswahl der wissenschaftlichen Literatur zum Thema „Macromolecules“

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Zeitschriftenartikel zum Thema "Macromolecules"

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Yashchuk, V. M., I. V. Lebedyeva та O. M. Navozenko. "Manifestations of triplet electronic excitations migration in π-electron containing polymers". Bulletin of Taras Shevchenko National University of Kyiv. Series: Physics and Mathematics, № 1 (2019): 242–45. http://dx.doi.org/10.17721/1812-5409.2019/1.55.

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The results of spectral studies of polymers with aromatic side groups are considered and analyzed. In particular, the phosphorescence spectra of polyvinylcarbazole (PVCa) polyvinyl-7-benzocarbazole (PV7BK) polypropylcarbazole (PEPC) are presented and analyzed. The phosphorescence of these polymers has been shown to be related to the migration of triplet excitons in macromolecules. The phosphorescence of PVC is determined at 77by deep traps (oxides), at 4.2 -shallow traps (monomer units of PVCa). The spreading length of triplet excitons in PVCa macromolecules is 600 A – that corresponds to the
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Bazunova, Marina, Valentina Chernova, Roman Lazdin, et al. "Cosolvents Impact on some Properties of the Solutions and the Films of Succinamide Chitosan." Chemistry & Chemical Technology 14, no. 4 (2020): 481–86. http://dx.doi.org/10.23939/chcht14.04.481.

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The article deals with the method of the medical purpose materials creation with the controlled physico-chemical and mechanical deformation properties on the basis of water-soluble derivative of amino polysaccharide chitosan – succinamide chitosan. The essence of the method is the macromolecules aggregation processes regulation in the initial solutions by the injection of organic cosolvents – acetone and ethanol. It has been stated that in a mixed solvent succinamide chitosan molecules are not in the form of the isolated macromolecular balls but as the macromolecules interacting (aggregated) s
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Sharp, Kim A. "Analysis of the size dependence of macromolecular crowding shows that smaller is better." Proceedings of the National Academy of Sciences 112, no. 26 (2015): 7990–95. http://dx.doi.org/10.1073/pnas.1505396112.

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The aqueous milieu inside cells contains as much as 30–40% dissolved protein and RNA by volume. This large concentration of macromolecules is expected to cause significant deviations from solution ideality. In vivo biochemical reaction rates and equilibria might differ significantly from those measured in the majority of in vitro experiments that are performed at much lower macromolecule concentrations. Consequently crowding, a nonspecific phenomenon believed to arise from the large excluded volume of these macromolecules, has been studied extensively by experimental and theoretical methods. H
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Hudder, Alice, Lubov Nathanson, and Murray P. Deutscher. "Organization of Mammalian Cytoplasm." Molecular and Cellular Biology 23, no. 24 (2003): 9318–26. http://dx.doi.org/10.1128/mcb.23.24.9318-9326.2003.

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ABSTRACT Although the role of macromolecular interactions in cell function has attracted considerable attention, important questions about the organization of cells remain. To help clarify this situation, we used a simple protocol that measures macromolecule release after gentle permeabilization for the examination of the status of endogenous macromolecules. Treatment of Chinese hamster ovary cells with saponin under carefully controlled conditions allowed entry of molecules of at least 800 kDa; however, there were minimal effects on internal cellular architecture and protein synthesis remaine
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Li, Chao, Xiangxiang Zhang, Mingdong Dong, and Xiaojun Han. "Progress on Crowding Effect in Cell-like Structures." Membranes 12, no. 6 (2022): 593. http://dx.doi.org/10.3390/membranes12060593.

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Several biological macromolecules, such as proteins, nucleic acids, and polysaccharides, occupy about 30% of the space in cells, resulting in a crowded macromolecule environment. The crowding effect within cells exerts an impact on the functions of biological components, the assembly behavior of biomacromolecules, and the thermodynamics and kinetics of metabolic reactions. Cell-like structures provide confined and independent compartments for studying the working mechanisms of cells, which can be used to study the physiological functions arising from the crowding effect of macromolecules in ce
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Mohapatra, Somesh, Joyce An, and Rafael Gómez-Bombarelli. "Chemistry-informed macromolecule graph representation for similarity computation, unsupervised and supervised learning." Machine Learning: Science and Technology 3, no. 1 (2022): 015028. http://dx.doi.org/10.1088/2632-2153/ac545e.

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Abstract The near-infinite chemical diversity of natural and artificial macromolecules arises from the vast range of possible component monomers, linkages, and polymers topologies. This enormous variety contributes to the ubiquity and indispensability of macromolecules but hinders the development of general machine learning methods with macromolecules as input. To address this, we developed a chemistry-informed graph representation of macromolecules that enables quantifying structural similarity, and interpretable supervised learning for macromolecules. Our work enables quantitative chemistry-
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Mormann, W., and K. H. Hellwich. "Structure-based nomenclature for cyclic organic macromolecules (IUPAC Recommendations 2008)." Pure and Applied Chemistry 80, no. 2 (2008): 201–32. http://dx.doi.org/10.1351/pac200880020201.

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A structure-based nomenclature system for monocyclic and polycyclic organic macromolecules is presented. Single-strand mono- and polycyclic macromolecules as well as spiro macrocyclic compounds are covered. However, rotaxanes and catenanes, which contain interlocked rings, and rings or ring systems formed by noncovalent bonds are excluded. Also, polypeptides and carbohydrate polymers are not included. The nomenclature of cyclic macromolecules is based on the existing nomenclature of regular and irregular macromolecules, which in turn is based on the nomenclature of organic chemistry also publi
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Wang, Yang, Yan Dai, Qiang Luo, et al. "Tumor Environment-Responsive Degradable Branched Glycopolymer Magnetic Resonance Imaging Contrast Agent and Its Tumor-Targeted Imaging." Journal of Biomedical Nanotechnology 15, no. 7 (2019): 1384–400. http://dx.doi.org/10.1166/jbn.2019.2759.

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Branched macromolecules have been used as carriers for imaging probes and drug delivery systems because of their tunable molecular structures, as well as their regular nanoscale structures and dimensions. We designed and synthesized two tumor environment-responsive branched and gadolinium (Gd)-based glycopolymer conjugates and investigated their potency as highly effective and safe magnetic resonance imaging (MRI) contrast agents. These branched macromolecules were prepared by one-pot reversible addition fragmentation chain transfer (RAFT) polymerization and conjugating chemistry. A biodegrada
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Pramod Kumar Mishra. "Theoretical estimate of the probability for macromole formation." JOURNAL OF ADVANCED APPLIED SCIENTIFIC RESEARCH 2, no. 4 (2021): 1–8. http://dx.doi.org/10.46947/joaasr242020103.

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We estimate the polymerization probability of a macromolecule, where the macromolecule is made of distinct monomers; and there are different values of the fugacity for the addition of the monomers in the chain to form an infinitely long linear macromolecule of distinct monomers. The lattice model of the random walk has been used to mimic the conformations of an ideal chain in two and three dimensions, and this ideal chain is the macromolecules of distinct monomers. It has been shown through analytical estimates that the flexible macromolecules may be easily formed than the stiff macromolecules
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Pawlak, Andrzej, and Justyna Krajenta. "Entanglements of Macromolecules and Their Influence on Rheological and Mechanical Properties of Polymers." Molecules 29, no. 14 (2024): 3410. http://dx.doi.org/10.3390/molecules29143410.

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Flexible macromolecules easily become entangled with neighboring macromolecules. The resulting network determines many polymer properties, including rheological and mechanical properties. Therefore, a number of experimental and modeling studies were performed to describe the relationship between the degree of entanglement of macromolecules and polymer properties. The introduction presents general information about the entanglements of macromolecule chains, collected on the basis of studies of equilibrium entangled polymers. It is also shown how the density of entanglements can be reduced. The
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Dissertationen zum Thema "Macromolecules"

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Larsericsdotter, Helén. "Macromolecules at Interfaces." Doctoral thesis, Uppsala University, Centre for Surface Biotechnology, 2004. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-4661.

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<p>In this thesis, the structure and stability of globular proteins adsorbed onto nanometer-sized hydrophilic silica particles were investigated using differential scanning calorimetry (DSC), hydrogen/deuterium exchange (HDX), and mass spectrometry (MS). The adsorption process itself was characterized with fluorescence and absorption spectroscopy and surface plasmon resonance (SPR). The combination of these methods offered a unique insight into adsorption-induced changes within proteins related to their adsorption characteristics. DSC contributed with thermodynamic information on the overall s
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Larsericsdotter, Helén. "Macromolecules at interfaces /." Uppsala : Acta Universitatis Upsaliensis : Univ.-bibl. [distributör], 2004. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-4661.

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Ambrogi, Marcela. "Suplementação do meio de transporte com antioxidantes e moduladores de AMP cíclico como estratégia para melhorar a qualidade de oócitos bovinos destinados à produção in vitro de embriões /." Jaboticabal, 2016. http://hdl.handle.net/11449/142002.

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Orientador: Gisele Zoccal Mingoti<br>Banca: Fernanda da Cruz Landim<br>Banca: Joaquim Mansano Garcia<br>Resumo: O objetivo desse estudo foi avaliar os efeitos da suplementação do meio com diferentes fontes de macromoléculas, com bloqueadores da meiose e com antioxidantes durante o transporte de oócitos bovinos por 6 horas sobre: 1) progressão da maturação nuclear; 2) maturação citoplasmática e 3) competência no desenvolvimento e criotolerância dos embriões produzidos. Para tanto, o meio de transporte de oócitos foi suplementado com bloqueadores da meiose (forscolina e IBMX; Experimento 1) ou c
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Stacklies, Wolfram. "Force Distribution in Macromolecules." Doctoral thesis, Universitätsbibliothek Leipzig, 2010. http://nbn-resolving.de/urn:nbn:de:bsz:15-qucosa-39367.

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All living organisms utilize thousands of molecular building blocks to perform mechanical tasks. These building blocks are mostly proteins, and their mechanical properties define the way they can be utilized by the cell. The spectrum ranges from rope like structures that give hold and stability to our bodies to microscopic engines helping us to perform or sense mechanical work. An increasing number of biological processes are revealed to be driven by force and well-directed distribution of strain is the very base of many of these mechanisms. We need to be able to observe the distribution of st
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Darmani, Homa. "Erythrocyte adhesion by macromolecules." Thesis, Cardiff University, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.278681.

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Leute, Maria. "Macromolecules with phosphorus functionalities." [S.l. : s.n.], 2007. http://nbn-resolving.de/urn:nbn:de:bsz:289-vts-60833.

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Li, Youyong Kuppermann Aron. "Atomistic simulation of macromolecules /." Diss., Pasadena, Calif. : California Institute of Technology, 2005. http://resolver.caltech.edu/CaltechETD:etd-12072004-021118.

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Petraglio, Gabriele Carlo Luigi. "Large scale motions in macromolecules /." Zürich : ETH, 2006. http://e-collection.ethbib.ethz.ch/show?type=diss&nr=16786.

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Obermayer, Benedikt. "Mechanics and information of macromolecules." Diss., lmu, 2010. http://nbn-resolving.de/urn:nbn:de:bvb:19-119656.

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Tang, Yi-wen. "Surface modifying macromolecules for biomaterials." Thesis, University of Ottawa (Canada), 1995. http://hdl.handle.net/10393/10318.

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In this thesis, new biomaterials were developed by incorporating surface modifying macromolecules (SMMs) that enriched the surface with a fluoro-chemistry. The SMMs contained a linear polyurethane as the prepolymer component and the prepolymer was end-capped by a fluorinated alcohol. The SMM materials and the blend of these SMMs with the polyester-urea-urethane base polymer were characterized with respect to their bulk and the surface properties, response to their biodegradation in the presence of enzyme and their fibrinogen adsorption characteristics. The SMMs were found to have selectively m
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Bücher zum Thema "Macromolecules"

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Elias, Hans-Georg. Macromolecules. Wiley-VCH Verlag GmbH, 2005. http://dx.doi.org/10.1002/9783527627219.

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Elias, Hans-Georg. Macromolecules. Wiley-VCH Verlag GmbH, 2006. http://dx.doi.org/10.1002/9783527627226.

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Elias, Hans-Georg. Macromolecules. Wiley-VCH Verlag GmbH, 2008. http://dx.doi.org/10.1002/9783527627233.

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Elias, Hans-Georg. Macromolecules. Wiley-VCH Verlag GmbH & Co. KGaA, 2009. http://dx.doi.org/10.1002/9783527627240.

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Elias, H. G. Macromolecules. Wiley-VCH, 2005.

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A, Jurnak Frances, and McPherson Alexander, eds. Biological macromolecules and assemblies. Wiley, 1987.

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Hendrickson, Wayne A., and Kurt Wüthrich. Macromolecular structures 2000: Atomic structures of biological macromolecules reported during 1999. Elsevier Science London, 2000.

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Privalov, Peter L. Microcalorimetry of Macromolecules. John Wiley & Sons, Inc., 2012. http://dx.doi.org/10.1002/9781118337509.

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Russo, Maria Vittoria, ed. Advances in Macromolecules. Springer Netherlands, 2010. http://dx.doi.org/10.1007/978-90-481-3192-1.

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A, Moore James, ed. Macromolecular syntheses: A periodic publication for the preparation of macromolecules. Wiley, 1985.

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Buchteile zum Thema "Macromolecules"

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Cropper, William H. "Macromolecules." In Mathermatica® Computer Programs for Physical Chemistry. Springer New York, 1998. http://dx.doi.org/10.1007/978-1-4612-2204-0_7.

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Schwarzbauer, Jan, and Branimir Jovančićević. "Macromolecules." In From Biomolecules to Chemofossils. Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-25075-5_6.

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Mishra, Munmaya, and Biao Duan. "Macromolecules." In The Essential Handbook of Polymer Terms and Attributes. CRC Press, 2024. http://dx.doi.org/10.1201/9781003161318-97.

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Elias, Hans-Georg. "Survey." In Macromolecules. Wiley-VCH Verlag GmbH, 2014. http://dx.doi.org/10.1002/9783527627219.ch1.

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Elias, Hans-Georg. "Free-Radical Polymerization." In Macromolecules. Wiley-VCH Verlag GmbH, 2014. http://dx.doi.org/10.1002/9783527627219.ch10.

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Elias, Hans-Georg. "Polymerization by Radiation or in Ordered States." In Macromolecules. Wiley-VCH Verlag GmbH, 2014. http://dx.doi.org/10.1002/9783527627219.ch11.

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Elias, Hans-Georg. "Copolymerization." In Macromolecules. Wiley-VCH Verlag GmbH, 2014. http://dx.doi.org/10.1002/9783527627219.ch12.

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Elias, Hans-Georg. "Polycondensation and Polyaddition." In Macromolecules. Wiley-VCH Verlag GmbH, 2014. http://dx.doi.org/10.1002/9783527627219.ch13.

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Elias, Hans-Georg. "Biological Polymerization." In Macromolecules. Wiley-VCH Verlag GmbH, 2014. http://dx.doi.org/10.1002/9783527627219.ch14.

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Elias, Hans-Georg. "Reactions of Macromolecules." In Macromolecules. Wiley-VCH Verlag GmbH, 2014. http://dx.doi.org/10.1002/9783527627219.ch15.

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Konferenzberichte zum Thema "Macromolecules"

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Buckley, A., G. W. Calundann, and A. J. East. "Multifunctional Macromolecules." In 1988 Los Angeles Symposium--O-E/LASE '88, edited by Robert L. Gunshor. SPIE, 1988. http://dx.doi.org/10.1117/12.943961.

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Yan, Karen Chang, Michael Rossini, Michael Sebok, and John Sperduto. "Concentration Characterization of Encapsulated Macromolecules in Electrospun Alginate Fibers Using Image Analysis." In ASME 2015 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2015. http://dx.doi.org/10.1115/imece2015-52585.

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Electrospun fibers made of biocompatible polymers have been used as scaffolds in tissue engineering to mimic the fibrous environment found in the extracellular matrix (ECM) of biological tissue; and bioactive macromolecules can also be encapsulated in the electrospun fibers. In order to control the release of these encapsulated macromolecules, it is of great interest to understand how the release rate is affected by the sizes of molecules, cross-linking as well as electrospinning configuration (single axial versus co-axial). Fluorescein imaging technique has been applied in quantifying molecul
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Perkins, F. Keith, L. M. Tender, S. J. Fertig, and Martin C. Peckerar. "Sensing macromolecules with microelectronics." In Workshop on Nanostructure Science, Metrology, and Technology, edited by Martin C. Peckerar and Michael T. Postek, Jr. SPIE, 2002. http://dx.doi.org/10.1117/12.465477.

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Long, Timothy E., Casey L. Elkins, Lars Kilian, et al. "“Reversible Macromolecules” as Scaffolds for Adaptive Structures." In ASME 2003 International Mechanical Engineering Congress and Exposition. ASMEDC, 2003. http://dx.doi.org/10.1115/imece2003-43010.

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Self-healing macromolecular structures, submicron capsules and fibers with molecular recognition, stimuliresponsive molecules, solvent-free rheological reversibility, multivalency in rational drug design, and the emergence of new fields of adaptive and evolutive chemistry will require a predictive synergy of tailored non-covalent and covalent bonding in molecular design. Supramolecular chemistry has emerged as a stimulating focal point that will enable these scientific and technological discoveries, and biorecognition and biomolecular organization often serve as the inspiration for the future
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Singer, Wolfgang, Timo A. Nieminen, Norman R. Heckenberg, and Halina Rubinsztein-Dunlop. "Optical micromanipulation of synthetic macromolecules." In SPIE Optics + Photonics, edited by Kishan Dholakia and Gabriel C. Spalding. SPIE, 2006. http://dx.doi.org/10.1117/12.680187.

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Pecora, Robert. "Dynamic light scattering from macromolecules." In OE/LASE'93: Optics, Electro-Optics, & Laser Applications in Science& Engineering, edited by Ralph J. Nossal, Robert Pecora, and Alexander V. Priezzhev. SPIE, 1993. http://dx.doi.org/10.1117/12.148340.

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Ryall, Rosemary L., Alison F. Cook, Lauren A. Thurgood, and Phulwinder K. Grover. "Macromolecules Relevant to Stone Formation." In RENAL STONE DISEASE: 1st Annual International Urolithiasis Research Symposium. AIP, 2007. http://dx.doi.org/10.1063/1.2723569.

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Odell, J. A., and A. Keller. "Macromolecules in elongational flow-fields." In AIP Conference Proceedings Volume 137. AIP, 1986. http://dx.doi.org/10.1063/1.35515.

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Chikishev, Andrey Y., Werner Ebeling, Alexei V. Netrebko, Nina V. Netrebko, Yury M. Romanovsky, and L. Schimansky-Geier. "Stochastic cluster dynamics of macromolecules." In International Workshop on Nonlinear Dynamics and Structures in Biology and Medicine: Optical and Laser Technologies, edited by Valery V. Tuchin. SPIE, 1997. http://dx.doi.org/10.1117/12.266255.

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Dantras, E. "Dielectric study of dendritic macromolecules." In Eighth International Conference on Dielectric Materials, Measurements and Applications. IEE, 2000. http://dx.doi.org/10.1049/cp:20000486.

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Berichte der Organisationen zum Thema "Macromolecules"

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Guin, J. A., C. W. Curtis, A. R. Tarrer, et al. Configurational diffusion of coal macromolecules. Office of Scientific and Technical Information (OSTI), 1991. http://dx.doi.org/10.2172/5932140.

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Guin, J. A., C. W. Curtis, and A. R. Tarrer. Configurational diffusion of coal macromolecules. Office of Scientific and Technical Information (OSTI), 1990. http://dx.doi.org/10.2172/6132844.

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Guin, J. A., C. W. Curtis, and A. R. Tarrer. Configurational diffusion of coal macromolecules. Office of Scientific and Technical Information (OSTI), 1989. http://dx.doi.org/10.2172/5752643.

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Guin, J. A., C. W. Curtis, and A. R. Tarrer. Configurational diffusion of coal macromolecules. Office of Scientific and Technical Information (OSTI), 1990. http://dx.doi.org/10.2172/6579694.

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Guin, J., C. Curtis, and A. Tarrer. Configurational diffusion of coal macromolecules. Office of Scientific and Technical Information (OSTI), 1990. http://dx.doi.org/10.2172/6933197.

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Guin, J. A., C. W. Curtis, and A. R. Tarrer. Configurational diffusion of coal macromolecules. Quarterly progress report. Office of Scientific and Technical Information (OSTI), 1990. http://dx.doi.org/10.2172/7089749.

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Allcock, Harry R. Organometallic and Bioactive Cyclophosphazenes, and the Relationship to Inorganic Macromolecules. Defense Technical Information Center, 1989. http://dx.doi.org/10.21236/ada204603.

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Hammel, Michal. Structural analyses of macromolecules by solution scattering (CRADA Final Report). Office of Scientific and Technical Information (OSTI), 2021. http://dx.doi.org/10.2172/1874024.

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Niedenzu, Kurt. Studies on Macromolecules Derived from Polypyrazolylboron and Related Boron-Nitrogen Species. Defense Technical Information Center, 1991. http://dx.doi.org/10.21236/ada242588.

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FRINK, LAURA J. D., SUSAN L. REMPE, SHAWN A. MEANS, et al. Predicting Function of Biological Macromolecules: A Summary of LDRD Activities: Project 10746. Office of Scientific and Technical Information (OSTI), 2002. http://dx.doi.org/10.2172/805869.

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