Literatura académica sobre el tema "Membrane d’ultrafiltration en PES"

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Artículos de revistas sobre el tema "Membrane d’ultrafiltration en PES"

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Hatoum, Maher, Jean François Fabre, Joel Albet, Claire Vialle, Caroline Sablayrolles, and Pierre Yves Pontalier. "Intégration de la simulation de l’ingénierie des processus et de l’évaluation du cycle de vie pour la modélisation de l’impact environnemental de la filtration membranaire." MATEC Web of Conferences 407 (2025): 02001. https://doi.org/10.1051/matecconf/202540702001.

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Le développement des procédés de bioraffinerie nécessite des outils d’éco-conception efficaces afin de démontrer leur réel intérêt écologique tout en minimisant le temps d’acquisition des données permettant l’extrapolation industrielle. L’objet de cet article concerne un de ces outil combinant l’ingénierie des systèmes de procédés (ISP) avec la méthodologie de l’analyse de cycle de vie (ACV) afin d’optimiser un procédé ou une opération unitaire en tenant compte des performances techniques et environnementales. En effet, l’ISP ne permet pas la simulation de toutes les opérations unitaires impli
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Chevereau, Élodie, Lionel Limousy, Patrick Dutournié, and Patrick Bourseau. "Réalisation et modification des propriétés de sélectivité d’une membrane minérale d’ultrafiltration : étude de la rétention de solutions salines." Revue des sciences de l’eau 25, no. 1 (2012): 21–30. http://dx.doi.org/10.7202/1008533ar.

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De par leurs caractéristiques structurales bien connues, les zéolithes sont fréquemment utilisées pour leur capacité à catalyser, à échanger des ions ou à adsorber certaines molécules. Ces matériaux sont également utilisés comme phase active pour réaliser des membranes. Dans ce travail, une membrane céramique d’ultrafiltration a été réalisée en imprégnant de la Mordenite (phase active) sur un support en alumine. La structure et les caractéristiques morphologiques de cette membrane ont été étudiées (diffraction de rayons X, BET / BJH (Brunauer-Emmett-Teller et Brunauer-Joyner-Hallenda), microsc
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Li, Ying-Na, Han Li, Hui Ye, Yu-Zhong Zhang, and Ying Chen. "Preparation and characterization of poly(ether sulfone)/fluorinated silica organic–inorganic composite membrane for sulfur dioxide desulfurization." High Performance Polymers 31, no. 1 (2018): 72–85. http://dx.doi.org/10.1177/0954008317752072.

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The highly hydrophobic poly(ether sulfone)/fluorinated silica (PES/fSiO2) organic–inorganic composite membrane for sulfur dioxide (SO2) desulfurization was prepared by incorporating the fSiO2 particles on the PES membrane via sol–gel process and fluorination. The formation of PES/fSiO2 organic–inorganic composite membrane was examined by attenuated total reflectance Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, thermal gravimetric analysis, field-emission scanning electron microscopy, and water contact angle. The experimental results showed that the fSiO2 inorganic
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Arahman, Nasrul, Cut Meurah Rosnelly, Yusni Yusni, et al. "Effect of Chemical Cleaning of Hypochlorite Solution on the Properties of Polyethersulfone Blend Membrane." Materials Science Forum 1136 (December 13, 2024): 53–59. https://doi.org/10.4028/p-mmm4k8.

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Ultrafiltration membranes have been widely used in industrial technology due to their high removal effectiveness. Long-term use of membranes will reduce membrane performance, so cleaning is required to maintain stable membrane performance. Chemical cleaning has proven to be effective for removing impurities but can also have a negative impact on membrane life. Polyethersulfone (PES) is proven to have strong mechanical properties due to its hydrophobic nature, but this hydrophobic nature makes PES membrane performance less than optimal so a hydrophilic pluronic co-polymer is needed. The combina
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Ayub, Nur Adlin, Keat Long Low, and Nazlee Faisal Ghazali. "Application of Membrane Filtration for Microalgae Harvesting and Protein Separation." Journal of Bioprocessing and Biomass Technology 3, no. 2 (2024): 91–96. https://doi.org/10.11113/bioprocessing.v3n2.56.

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The seek for sustainable protein sources has led to the exploration of microalgae as an alternative. Membrane filtration, known for its environmental friendliness, holds promise for purifying protein from microalgae. This research focuses on the protein purification from Chlorella vulgaris microalgae using polyethersulfone (PES) membrane. This research aims to investigate the effect of membrane composition for enhanced microalgae harvesting and protein purification, as well as evaluating the effects of membrane pore sizes and porosity on the performance. Three membrane compositions were evalua
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Ghadhban, Maryam Y., Hasan Shaker Majdi, Khalid T. Rashid, et al. "Removal of Dye from a Leather Tanning Factory by Flat-Sheet Blend Ultrafiltration (UF) Membrane." Membranes 10, no. 3 (2020): 47. http://dx.doi.org/10.3390/membranes10030047.

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In this work, a flat-sheet blend membrane was fabricated by a traditional phase inversion method, using the polymer blends poly phenyl sulfone (PPSU) and polyether sulfone (PES) for the ultrafiltration (UF) application. It was hypothesized that adding PES to the PPSU polymer blend would improve the properties of the PPSU membrane. The effect of the PES concentration on the blend membrane properties was investigated extensively. The characteristics of PPSU-PES blend membranes were investigated using atomic force microscopy (AFM), scanning electron microscopy (SEM), contact angle measure, and co
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Rohani, Rosiah, Pettymilonna Anak Michael, Khalefa Faneer, Nurul Izzati Izni Md Yusof, and Puteri Mimie Isma Nordin. "Development of Polyethersulfone Nanofiltration Membrane with Layer-by-Layer Method for Xylitol Purification." Journal of Biochemistry, Microbiology and Biotechnology 10, SP2 (2022): 61–66. http://dx.doi.org/10.54987/jobimb.v10isp2.730.

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This work is aimed to develop polyethersulfone (PES) nanofiltration (NF) membrane with layer-by-layer (LBL) polyelectrolytes of chitosan (CHI) and poly(acrylic acid) (PAA) for xylitol purification from fermentation broth. Different number of bilayers and type of terminating layer were manipulated for producing more hydrophilicity, negatively charged with improved performance compared to pristine PES membrane. Successful deposition of polyelectrolyte layers onto PES membrane was able to be proven using various tests such as contact angle, Zetasizer and FT-IR. The results obtained have proven th
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Yin, Jun. "Fabrication of a Modified Polyethersulfone Membrane with Anti-Fouling and Self-Cleaning Properties from SiO2-g-PHEMA NPs for Application in Oil/Water Separation." Polymers 14, no. 11 (2022): 2169. http://dx.doi.org/10.3390/polym14112169.

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To prepare anti-fouling and self-cleaning membrane material, a physical blending modification combined with surface grafting modification has been carried out; first, poly (2-hydroxyethyl methacrylate) grafted silica nanoparticles (SiO2-g-PHEMA NPs) were synthesized using surface-initiated activators regenerated by electron transfer atom transfer radical polymerization (ARGET ATRP) and used as a blending modifier to fabricate a polyethersulfone (PES)/SiO2-g-PHEMA organic–inorganic membrane by the phase-inversion method. During the membrane formation process, hydrophobic PES segments coagulated
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Kalugin, Denis, Jumanah Bahig, Ahmed Shoker, and Amira Abdelrasoul. "Heparin-Immobilized Polyethersulfone for Hemocompatibility Enhancement of Dialysis Membrane: In Situ Synchrotron Imaging, Experimental, and Ex Vivo Studies." Membranes 13, no. 8 (2023): 718. http://dx.doi.org/10.3390/membranes13080718.

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The goal of the current study is to enhance the hemocompatibility of polyethersulfone (PES) membranes using heparin immobilization. Heparin was immobilized covalently and via electrostatic interaction with the positively charged PES surface (pseudo-zwitterionic (pZW) complex) to investigate the influence of each method on the membrane hemocompatibility. In situ synchrotron radiation micro-computed tomography (SR-µCT) imaging, available at the Canadian Light Source (CLS), was used to critically assess the fibrinogen adsorption to the newly synthesized membranes qualitatively and quantitatively
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Mannan, Hafiz Abdul, Hilmi Mukhtar, and Thanabalan Murugesan. "Polyethersulfone (PES) Membranes for CO2/CH4 Separation: Effect of Polymer Blending." Applied Mechanics and Materials 625 (September 2014): 172–75. http://dx.doi.org/10.4028/www.scientific.net/amm.625.172.

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Effect of polymer blending on physico-chemical and gas permeation properties of polyethersulfone (PES) membrane was studied. PES was chosen as base polymer and polysulfone (PSF) and polyvinyl acetate (PVAc) were added as glassy and rubbery polymer additives respectively. The morphology, thermal stability and miscibility of PES membranes were characterized by FESEM, TGA and DSC respectively to observe the effect of polymer blending. The prepared membranes were tested for permeation of CO2 and CH4 at a feed pressure of 2 to 10 bar. PES-PSF membrane exhibits the separation properties identical to
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Tesis sobre el tema "Membrane d’ultrafiltration en PES"

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Kavugho, Mission Sophie. "Formulation et étude de nouveaux détergents enzymatiques pour le nettoyage des membranes d'ultrafiltration de l'industrie laitière : développement et validation de méthodologies associées." Electronic Thesis or Diss., Université de Rennes (2023-....), 2024. http://www.theses.fr/2024URENS005.

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L’ultrafiltration (UF) du lait écrémé pour la standardisation de la teneur en protéines pour la fabrication des fromages est un procédé membranaire très répandu à l’échelle industrielle. Cependant, le colmatage des membranes par des protéines du lait écrémé provoque une baisse de la productivité et constitue un verrou de ce procédé.Ainsi, l’étape de nettoyage/désinfection bi-quotidienne est indispensable afin de restaurer les performances de la membrane et d’assurer la sécurité sanitaire ainsi que la qualité des produits. Elle est en général réalisée avec des détergents formulés alcalins et ac
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Bigliardi, Brando. "Study of PVAm-graphene selective layer on PES membrane for gas separation." Master's thesis, Alma Mater Studiorum - Università di Bologna, 2021.

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Many studies focused on the improvement of membrane performance by addition of nanofiller creating the so-called mixed matrix membranes. In this work, the feasibility of producing a multi-layer selective membrane for carbon dioxide separation is analysed. Two different deposition technique, 2-D printing and Mayer bar deposition, were explored. The multi-layer membranes were composed by a support layer of polyethersulfone and a selective layer of polyvinyl amine and graphene. Some consideration about ink formulation for 2-D printing were also developed in this work.
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Belmejdoub, Jihane. "Sur l’intégrité des protéines et la valorisation des effluents pour une production durable par membrane d’ultrafiltration : application à l’industrie laitière." Rennes 1, 2010. http://www.theses.fr/2010REN1S220.

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Les protéines solubles du lait de vache ont un intérêt reconnu dans les industries agro-alimentaire en raison de leur valeur nutritionnelle et de leurs propriétés techno-fonctionnelles. A condition de valider que les protéines ne sont pas dénaturées par les procédés membranaires, ceci pourraient être utilisés à l’échelle industrielle pour la préparation de fractions protéiques à fonctions ciblées. Cette thèse propose une première partie sur la mise au point d’une méthodologie pour étudier la possibilité de dénaturation des protéines par des membranes fortement rétentives en comparant avec des
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Wu, Dongzhu. "SUBSTRATE DESIGN AND MEMBRANE STABILITY OF MULTILAYER COMPOSITE MEMBRANE FOR CO2 SEPARATION." The Ohio State University, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=osu1510429230811329.

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Diagne, Ndeye Wemsy. "Le nettoyage : une étape-clef pour une production durable par procédé à membrane : réflexion sur le lien entre conditions de production et nettoyabilité d'une membrane PES de l'industrie laitière." Phd thesis, Université Rennes 1, 2013. http://tel.archives-ouvertes.fr/tel-01019725.

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Le nettoyage en place des membranes en industrie agro-alimentaire est une opération cruciale qui, outre les exigences de sécurité sanitaire des installations et des produits traités doit permettre de restaurer les performances de la filtration (sélectivité, flux) en éliminant le colmatage formé pendant l'étape de production. Malheureusement cette étape repose encore sur des bases empiriques et non optimisées. A cause d'un manque de notions fondamentales, elle est encore pressentie comme un frein à l'utilisation massive des procédés membranaires. Une démarche originale a été menée dans le cadre
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Pellegrin, Bastien. "Analyse multi-échelle de la dégradation de membranes d'ultrafiltration en polyethersulfone - poly(N-vinyl pyrrolidone) en conditions d'usage." Toulouse 3, 2013. http://thesesups.ups-tlse.fr/2084/.

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Ces travaux portent sur l'étude du vieillissement de membranes d'ultrafiltration en PES / PVP. Ils sont motivés par le constat industriel de l'endommagement des membranes au cours de leur utilisation. Il est démontré que l'hypochlorite de sodium utilisé lors des procédures de lavages sur site de production d'eau potable est le principal responsable du vieillissement des membranes. Cette dégradation chimique conduit à une oxydation radicalaire de la PVP (avec et sans rupture de chaînes), entraînant son élimination partielle de la structure de la membrane. Ce phénomène provoque une augmentation
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Wang, Di. "Ιnnοvative cοmpοsite pοlymer materials fοr CΟ2 separatiοn". Electronic Thesis or Diss., Normandie, 2024. http://www.theses.fr/2024NORMIR09.

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Actuellement, les émissions de CO₂, principal responsable du réchauffement climatique, augmentent à un rythme alarmant. Par conséquent, il existe un besoin mondial croissant de technologies de pointe capables de séparer et de capturer efficacement le CO₂. Dans ce travail, une série de membranes composites PSF/IL et PES/IL pour la séparation du CO₂ ont été étudiées. Six IL ([Meim][TFSO₃], [Vim][TFSO₃], [Meim][Tf₂N], [Vim][Tf₂N], Li(DOBA)[Tf₂N] et Li(HDA)[Tf₂N]) ont été synthétisés avec succès et caractérisés par FT-IR, 1H RMN, TGA et DSC. Des membranes composites avec différentes quantités d'IL
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Morizur, Vincent. "Fonctionnalisation de polymères et applications dans les domaines de l’énergie, de la catalyse, de la cosmétique et de la santé." Thesis, Nice, 2014. http://www.theses.fr/2014NICE4102.

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Les polymères sont à l’heure actuelle étudiés dans de nombreux domaines comme la chimie, la biochimie, les nanotechnologies, l'électronique, la médecine ou encore les sciences des matériaux et trouvent des applications dans des domaines comme l’industrie automobile, la chimie fine. L’objectif de cette thèse est de réaliser la fonctionnalisation de polymères et de modifier les propriétés de ces matériaux afin d’envisager des nouvelles applications. Nous nous sommes intéressés à des polymères de la famille des poly(aryle éther) et plus particulièrement au poly(éther éther cétone) (PEEK). Ce poly
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Lin, Jian-De, and 林建德. "Nano-titania (TiO2)/polyethersulfone (PES) ultrafiltration membrane preparation and antifouling capability analyses." Thesis, 2018. http://ndltd.ncl.edu.tw/handle/jas35s.

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碩士<br>淡江大學<br>化學工程與材料工程學系碩士班<br>106<br>In this research, we introduce TiO2 sol (synthesized via the sol-gel procedure) and polyvinylpyrrolidone (PVP) into the casting dope for polyethersulfone (PES)/TiO2 composite membrane formation. The former additive is used to enhance the hydrophilicity, whereas the latter functions as a pore former to engender pore-pore interconnection. Prepared membranes (termed mixed matrix membrane, MMM) can be divided into 3 series: P0, P1.5 and P5, according to the amount of added PVP. Each series consists of several membranes with TiO2 contents. To disperse TiO2 fin
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Mthethwa, Velinjani. "Investigation of polyethersulfone (PES) hollow fiber membrane for the treatment of acid mine drainage." Thesis, 2015. http://hdl.handle.net/10539/17675.

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Efforts in treatment of acid mine drainage (AMD) have been fraught with limitations for the mining industry. Membrane filtration technology is a new alternative employed to treat AMD in this work. A commercially available polyethersulfone (PES) hollow fibre nanofiltration membrane was investigated for its likelihood for the treatment of AMD. The system was configured in a cross flow set up and effects of pH, feed flowrate and operation time were explored in relation to the membrane performance (rejection and flux). Acid mine collected from site had a very high concentration of Iron (1.055 mg/L
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Capítulos de libros sobre el tema "Membrane d’ultrafiltration en PES"

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Zhang, Yuzhong. "SPS/PES Asymmetric Blend Nanofiltration Membrane." In Encyclopedia of Membranes. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-44324-8_1049.

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Zhang, Yuzhong. "SPS/PES Asymmetric Blend Nanofiltration Membrane." In Encyclopedia of Membranes. Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-642-40872-4_1049-6.

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Wang, Aiai, and Zhonghua Sun. "Preparation and Characterization of Non-woven Blend Membrane from CA and PES in DMAc/LiCl." In Advances in Graphic Communication, Printing and Packaging. Springer Singapore, 2019. http://dx.doi.org/10.1007/978-981-13-3663-8_117.

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Alkindy, Maryam B., Munirasu Selvaraj, Fawzi Banat, and Shadi Wajih Hasan. "Preparation of PES/GO/APTES-SiO2 Mixed Matrix Membrane for the Treatment of Oily Wastewater." In Frontiers in Water-Energy-Nexus—Nature-Based Solutions, Advanced Technologies and Best Practices for Environmental Sustainability. Springer International Publishing, 2019. http://dx.doi.org/10.1007/978-3-030-13068-8_112.

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Sadare, Olawumi Oluwafolakemi, Molly Katlo Keitemoge, and Kapil Moothi. "Fabrication and Characterization of Functionalized Cellulose Nanocrystals (CNCs)-Infused Polyethersulfone (PES) Polymer Membrane for Enhanced Antifouling Property." In Recent Advances in Environmental Science from the Euro-Mediterranean and Surrounding Regions (4th Edition). Springer Nature Switzerland, 2024. http://dx.doi.org/10.1007/978-3-031-51904-8_53.

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Kanwal, Ansa, Asim Ali Yaqoob, Affia Siddique, Mohamad Nasir Mohamad Ibrahim, and Akil Ahmad. "Polyethersulfone (PES) nanofiltration membrane for treatment of toxic metal contaminated water." In Emerging Techniques for Treatment of Toxic Metals from Wastewater. Elsevier, 2023. http://dx.doi.org/10.1016/b978-0-12-822880-7.00004-2.

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Zhi, Lunhao, Shudong Sun, and Changsheng Zhao. "Blood Purification Membranes Used in Liquid–Gas Environments: Artificial Lungs." In Blood Purification Materials. Royal Society of Chemistry, 2025. https://doi.org/10.1039/9781839165412-00125.

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Extracorporeal membrane oxygenation (ECMO), the key component of which is a membrane oxygenator, known as the artificial lung, could provide irreplaceable respiratory support for patients with cardiopulmonary failure. The membrane oxygenator serves as a barrier between blood and gas, and offers a means of CO2 and O2 exchange. This chapter systematically reviews the evolution of the membrane oxygenator, from blood-film to hollow-fiber membranes, and from silicone to the present polymethylpentene. In particular, the dilemma faced by membrane oxygenators in balancing antifouling, anticoagulation,
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"Studying the role of magnetite (Fe O) colloids functionality on PES membrane in removing of humic acid foulant using QCM-D." In Membrane Technology for Water and Wastewater Treatment, Energy and Environment. CRC Press, 2016. http://dx.doi.org/10.1201/b19702-4.

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Actas de conferencias sobre el tema "Membrane d’ultrafiltration en PES"

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Kumar, Purushottam, and Sanjib Ganguly. "Development and Parameter Extraction of Simplified Empirical Polarization Curve Model for Polymer Electrolyte Membrane Fuel Cell." In 2024 IEEE PES Innovative Smart Grid Technologies - Asia (ISGT Asia). IEEE, 2024. https://doi.org/10.1109/isgtasia61245.2024.10876222.

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Haubrock, J., G. Heideck, and Z. Styczynski. "Dynamic Investigation on Proton Exchange Membrane Fuel Cell Systems." In 2007 IEEE Power Engineering Society General Meeting. IEEE, 2007. http://dx.doi.org/10.1109/pes.2007.385869.

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Rozafia, A. I., K. Roziqin, Y. L. Ni'mah, W. P. Utomo, M. Zainuri, and D. Hartanto. "Utilization of modified ZSM-5 as filler for polyethersulfone (PES) membrane." In THE 8TH INTERNATIONAL CONFERENCE OF THE INDONESIAN CHEMICAL SOCIETY (ICICS) 2019. AIP Publishing, 2020. http://dx.doi.org/10.1063/5.0001693.

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Yang, Cheng-Kang, Chia-Hao Lin, Sarah A. Ward, Eric D. Conte, and Shing-Yi Suen. "Preparation of PES/Banana Peel Mixed Matrix Membrane and its Application." In 14th Asia Pacific Confederation of Chemical Engineering Congress. Research Publishing Services, 2012. http://dx.doi.org/10.3850/978-981-07-1445-1_332.

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Buasri, P., and Z. M. Salameh. "An electrical circuit model for a proton exchange membrane fuel cell (PEMFC)." In 2006 IEEE Power Engineering Society General Meeting. IEEE, 2006. http://dx.doi.org/10.1109/pes.2006.1709093.

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Gu, Ye, and Norihisa Miki. "Microfilter Fabricated with PDMS and PES Membrane Applicable for Implantable Artificial Kidney." In 2007 2nd IEEE International Conference on Nano/Micro Engineered and Molecular Systems. IEEE, 2007. http://dx.doi.org/10.1109/nems.2007.352138.

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Kusworo, Tutuk D., Nita Aryanti, Enny Nurmalasari, and Dani Puji Utomo. "PVA coated nano hybrid PES-ZnO membrane for natural rubber wastewater treatment." In PROCEEDINGS OF 2ND INTERNATIONAL CONFERENCE ON CHEMICAL PROCESS AND PRODUCT ENGINEERING (ICCPPE) 2019. AIP Publishing, 2020. http://dx.doi.org/10.1063/1.5140925.

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Johary, Fasihah, Nur Adibah Jamaluddin, Rosiah Rohani, Abdul Rahman Hassan, Syazrin Syima Sharifuddin, and Mohd Hafez Mohd Isa. "Development of polyethersulfone (PES)/silver nanoparticles (AgNPs)/polyethylene glycol (PEG) nanofiltration membrane." In RECENT ADVANCEMENT ON APPLIED PHYSICS, INDUSTRIAL CHEMISTRY AND CHEMICAL TECHNOLOGY: Proceedings of the International Conference on Recent Advancements in Science and Technology 2017 (ICoRAST2017). Author(s), 2018. http://dx.doi.org/10.1063/1.5041243.

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Borduin, Russell, and Wei Li. "Development of Foamed PES-Zeolite Mixed Matrix Membranes for PEM Fuel Cell Humidification." In ASME 2016 11th International Manufacturing Science and Engineering Conference. American Society of Mechanical Engineers, 2016. http://dx.doi.org/10.1115/msec2016-8786.

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Polymer electrolyte membrane (PEM) fuel cell efficiency must be improved in order to become cost-competitive with fossil fuel based technologies. Approaches to increasing cost efficiency include raising fuel cell operating temperature, reducing component cost and properly controlling fuel cell humidification. We sought to fulfill all three requirements by developing a new low-cost, high-temperature humidification membrane material. Currently Nafion dominates the membrane humidifier market due to its excellent water transport characteristics, but its high price (∼$1000/m2) and low maximum opera
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Liu, Shuo, Hongjun Han, Yanping Liu, and Baozhen Wang. "An atomic force microscopy study on fouling characteristics of modified PES membrane in submerged membrane bioreactor for domestic wastewater treatment." In International Symposium on Instrumentation Science and Technology, edited by Jiubin Tan and Xianfang Wen. SPIE, 2008. http://dx.doi.org/10.1117/12.810707.

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Informes sobre el tema "Membrane d’ultrafiltration en PES"

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Husson, Scott M., Viatcheslav Freger, and Moshe Herzberg. Antimicrobial and fouling-resistant membranes for treatment of agricultural and municipal wastewater. United States Department of Agriculture, 2013. http://dx.doi.org/10.32747/2013.7598151.bard.

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This research project introduced a novel membrane coating strategy to combat biofouling, which is a major problem for the membrane-based treatment of agricultural and municipal wastewaters. The novelty of the strategy is that the membrane coatings have the unique ability to switch reversibly between passive (antifouling) and active (antimicrobial) fouling control mechanisms. This dual-mode approach differs fundamentally from other coating strategies that rely solely on one mode of fouling control. The research project had two complementary objectives: (1) preparation, characterization, and tes
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