Bibliografías temáticas / Oxazine chemistry

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Literatura académica sobre el tema "Oxazine chemistry"

Autor: Grafiati
Publicado: 4 de junio de 2021
Última modificación: 15 de febrero de 2022

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Artículos de revistas sobre el tema "Oxazine chemistry"

1

Gaonkar, Santosh L., Vignesh U. Nagaraj, and Swarnagowri Nayak. "A Review on Current Synthetic Strategies of Oxazines." Mini-Reviews in Organic Chemistry 16, no. 1 (2018): 43–58. http://dx.doi.org/10.2174/1570193x15666180531092843.

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In the past three decades, the heterocyclic oxazine cores have been intensely concerned. Oxazine derivatives are promising vital heterocyclic motifs. They are eminent for their synthetic potential and extensive biological properties. Oxazines are versatile intermediates for the synthesis of a variety of heterocycles and bifunctional compounds. Researchers have reported several synthetic approaches for the preparation of oxazines. This review emphasises the recent approaches for the synthesis of oxazine derivatives.
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2

Kirila, Tatyana, Anna Smirnova, Vladimir Aseyev, Andrey Tenkovtsev, Heikki Tenhu, and Alexander Filippov. "Self-Organization in Dilute Aqueous Solutions of Thermoresponsive Star-Shaped Six-Arm Poly-2-Alkyl-2-Oxazines and Poly-2-Alkyl-2-Oxazolines." Polymers 13, no. 9 (2021): 1429. http://dx.doi.org/10.3390/polym13091429.

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The behavior of star-shaped six-arm poly-2-alkyl-2-oxazines and poly-2-alkyl-2-oxazolines in aqueous solutions on heating was studied by light scattering, turbidimetry and microcalorimetry. The core of stars was hexaaza [26] orthoparacyclophane and the arms were poly-2-ethyl-2-oxazine, poly-2-isopropyl-2-oxazine, poly-2-ethyl-2-oxazoline, and poly-2-isopropyl-2-oxazoline. The arm structure affects the properties of polymers already at low temperatures. Molecules and aggregates were present in solutions of poly-2-alkyl-2-oxazines, while aggregates of two types were observed in the case of poly-
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Kirila, Tatyana, Anna Smirnova, Alla Razina, Andrey Tenkovtsev, and Alexander Filippov. "Influence of Salt on the Self-Organization in Solutions of Star-Shaped Poly-2-alkyl-2-oxazoline and Poly-2-alkyl-2-oxazine on Heating." Polymers 13, no. 7 (2021): 1152. http://dx.doi.org/10.3390/polym13071152.

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The water–salt solutions of star-shaped six-arm poly-2-alkyl-2-oxazines and poly-2-alkyl-2-oxazolines were studied by light scattering and turbidimetry. The core was hexaaza[26]orthoparacyclophane and the arms were poly-2-ethyl-2-oxazine, poly-2-isopropyl-2-oxazine, poly-2-ethyl-2-oxazoline, and poly-2-isopropyl-2-oxazoline. NaCl and N-methylpyridinium p-toluenesulfonate were used as salts. Their concentration varied from 0–0.154 M. On heating, a phase transition was observed in all studied solutions. It was found that the effect of salt on the thermosensitivity of the investigated stars depen
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4

Farfán, Norberto, Rosa L. Santillan, Dolores Castillo, Reyna Cruz, Pedro Joseph-Nathan, and Jean-Claude Daran. "Fused heterocycles derived from pseudoephedrine and ephedrine." Canadian Journal of Chemistry 70, no. 11 (1992): 2764–70. http://dx.doi.org/10.1139/v92-351.

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The formation of heterobicycles by condensation of (1R, 2R)-(−)-pseudoephedrine or (1R, 2S)-(−)-ephedrine with glyoxal is reported. In the case of pseudoephedrine, the nuclear magnetic resonance data of the crude reaction mixture indicate the presence of three isomeric compounds (5, 6, and 7), which were separated by fractional crystallization, while ephedrine afforded the oxazino-oxazine 8 and the known (5S*,6R*)-4,5-dimethyl-6-phenyl-1,4-oxazin-2-one (9). Conclusive spectroscopic evidence for the structures of the new compounds having the cis-[1,4]oxazino[3,2-b]-1,4-oxazine (5 and 8) and the
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Dawood, Kamal M., Thoraya A. Farghaly, and Mohamed A. Raslan. "Heteroannulation Routes to Bioactive Pyrazolooxazines." Current Organic Chemistry 24, no. 17 (2020): 1943–75. http://dx.doi.org/10.2174/1570179417999200628035124.

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Pyrazolo-oxazine fused systems are interesting classes of heterocyclic compounds exhibiting pronounced biological applications such as anticancer, antitubercular, anti-inflammatory, antibacterial and antifungal activities as well as inhibiting COX-1 and COX-2 enzymes. Depending on the distribution position of the heteroatoms (N and O), there are fourteen different systems of pyrazolo-oxazine. Nine of them were biologically abundant in literature, for example, pyrazolo[3,4-e][1,3]oxazines are used as analogs of antibiotics Formycin, Formycin B, Oxoformycin B. This review article summarizes the
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Konstantinova, Lidia S., Mikhail A. Tolmachev, Vadim V. Popov, and Oleg A. Rakitin. "Ethyl 11a,12-Dihydrobenzo[b]benzo[5,6][1,4]oxazino[2,3-e][1,4]oxazine-5a(6H)-carboxylate." Molbank 2020, no. 3 (2020): M1149. http://dx.doi.org/10.3390/m1149.

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The 11a,12-dihydrobenzo[b]benzo[5,6][1,4]oxazino[2,3-e][1,4]oxazine heterocyclic system has been used in the construction of heteropropellanes, which attracted much attention not only on the possible modification of drugs, but also for novel materials with unusual and important physical properties. In this communication, the reaction of ethyl 2-(hydroxyimino)propanoate 1 with disulfur dichloride and o-aminophenol, which gave ethyl 11a,12-dihydrobenzo[b]benzo[5,6][1,4]oxazino[2,3-e][1,4]oxazine-5a(6H)-carboxylate in moderate yield, was described. The structure of the newly synthesized compound
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7

Sharma, Anupama, Sarita Khaturia, and Har Lal Singh. "Synthesis of New Schiff Base of 1,3-Oxazine and 1,3-Thiazine Derivatives Derived from 4-Phenyl Substituted Chalcones and Evaluation of their Antibacterial Activity." Asian Journal of Chemistry 33, no. 3 (2021): 531–36. http://dx.doi.org/10.14233/ajchem.2021.23050.

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Oxazine and thiazine heterocycles have distinctive interests due to their important class of natural and non-natural products and exhibit high biological activities in the pharmaceutical and biological fields. This work was planned to synthesize Schiff base of 1,3-oxazine and 1,3-thiazine derivative from 4-phenyl substituted chalcones. The structures of the newly synthesized targeted compounds were established from UV, IR, 1H NMR, 13C NMR and DFT calculations. The molecular properties HOMO-LUMO energy, energy gap, softness and harness were calculated using DFT/B3LYP/6-311G (d,p) basis set. in
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8

Mahmoud, Naglaa F. H., Eman A. El-Bordany, and Galal A. Elsayed. "Synthesis and Pharmacological Activities of Pyrano[2,3-d]pyrimidine and Pyrano[2,3-d]pyrimidine-5-one Derivatives as New Fused Heterocyclic Systems." Journal of Chemistry 2017 (2017): 1–7. http://dx.doi.org/10.1155/2017/5373049.

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Various fused oxazine such as 4-(4-methoxyphenyl)-3,7-dimethyl-1,4-dihydro-5H-pyrazolo [4′,3′:5,6]pyrano[2,3-d][1,3]oxazin-5-one2has been prepared and utilized as a starting material for novel pyrazolopyranopyrimidinones3,5,6, and7a–cand pyrazolopyranopyrimidines4,9,10, and11which are expected to possess considerable chemical and pharmacological activities. The structures of the new compounds have been elucidated by spectroscopic data and elemental analysis. The antioxidant and anticancer activities of synthesized products have been evaluated.
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Ochędzan-Siodłak, Wioletta, Dawid Siodłak, Aleksandra Piontek, and Karel Doležal. "Titanium and Vanadium Catalysts with 2-Hydroxyphenyloxazoline and Oxazine Ligands for Ethylene-Norbornene (co)Polymerization." Catalysts 9, no. 12 (2019): 1041. http://dx.doi.org/10.3390/catal9121041.

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A series of titanium and vanadium complexes with oxazoline 2-(4,5-dihydro-1,3-oxazol-2-yl)phenol (L1), 2-(4-methyl-4,5-dihydro-1,3-oxazol-2-yl)phenol (L2), and oxazine 2-(5,6-dihydro-4H-1,3-oxazin-2-yl)phenol (L3) ligands were synthesized, and their structures were determined by NMR and MS methods as (L)2MtCl2. The vanadium complexes were found to be highly active in ethylene (7300 kgPE/(molV·h)) and ethylene/norbornene (5300 kgCop/(molV·h)) (co)polymerization. The polyethylene characteristics were melting temperature (123–142 °C), crystallinity degree (49–75%), molecular weight (5.7–8.5 × 105
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Miri, Morteza, and Alireza Hassanabadi. "One-Pot and Three-Component Condensation of Kojic Acid with Aromatic Aldehydes and Methyl Carbamate: Synthesis of Pyrano-1,3-Oxazine Derivatives in Aqueous Media." Journal of Chemical Research 42, no. 8 (2018): 416–18. http://dx.doi.org/10.3184/174751918x15341755203029.

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A novel method for oxazine ring formation has been established using the reaction of kojic acid and aromatic aldehydes with methyl carbamate in the presence of p-toluenesulfonic acid in aqueous media to afford 4-aryl-6-hydroxymethyl-1,4-dihydropyrano[3,2-e][1,3] oxazine-2,8-diones in excellent yields. The present method does not involve any hazardous organic solvent. Therefore, this procedure could be classified as green chemistry.
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Tesis sobre el tema "Oxazine chemistry"

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Stretch, W. "The chemistry of 3-ethoxycarbonyl-5, 6-dihydro-4H-1, 2-oxazines : An approach to the synthesis of betagamma-deydroaminoacids." Thesis, University of Liverpool, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.370847.

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Han, Lu. "UNDERSTANDING THE VIBRATIONAL STRUCTURE, RING-OPENING KINETICS OF OXAZINE RING AND HYDROGEN BONDING EFFECTS ON FAST POLYMERIZATION OF 1,3-BENZOXAZINES." Case Western Reserve University School of Graduate Studies / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=case1523026767260573.

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Choi, Adam. "Illuminating Biology with Membrane Penetrating Sulfonate Delivery Scaffolds and Near-Infrared Azasiline Fluorophores." eScholarship@UMMS, 2018. https://escholarship.umassmed.edu/gsbs_diss/997.

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Near-infrared (NIR) light, with wavelengths of 650 to 900 nanometers, effectively penetrates tissues. The high signal to noise ratio and low phototoxicity of NIR light makes this wavelength range ideal for deep tissue imaging. However, current NIR fluorophores are generally large hydrophobic molecules that are prone to aggregation. Sulfonation can enhance aqueous solubility, but their anionic nature prevents membrane diffusion, and thus, restricts the applications of sulfonated molecules to in vitro or fixed cells. The repertoire of commercially available sulfonated NIR probes is mostly limite
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Tilliet, Mélanie. "Synthesis and study of new oxazoline-based ligands." Doctoral thesis, KTH, Organisk kemi, 2008. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-4858.

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This thesis deals with the study of oxazoline-based ligands in metal-catalyzed asymmetric reactions. The first part describes the synthesis of six new bifunctinal pyridine-bis(oxazoline) ligands and their applications in asymmetric metal-catalysis. These ligands, in addition to a Lewis acid coordination site, are equipped with a Lewis basic part in the 4-position of the oxazoline rings. Dual activation by means of this system was probed in cyanide addition to aldehydes. The second part is concerned with the synthesis of two pyridine-bis(oxazoline) ligands bearing bulky triazole groups in the 4
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Zocher, Eva Maria. "Gas-phase and solution-state chemistry of copper(I) bis-oxazoline complexes /." Zürich : ETH, 2008. http://e-collection.ethbib.ethz.ch/show?type=diss&nr=18009.

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Clarke, Richard John. "Mesopore immobilised bis(oxazoline) catalysts for enantioselective catalysis." Thesis, University of Birmingham, 2003. http://etheses.bham.ac.uk//id/eprint/3578/.

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Mesoporous silica materials have the potential to replace many conventional silicas for uses such as supports for heterogeneous catalysis and absorbents. The large pore size and high surface area make them ideal for supporting bulky organometallic catalysts for enantioselective reactions. We have immobilised chiral bis(oxazoline) metal complexes onto the surfaces of some of these versatile supports (MCM-41 and MCM-48) via different tethering strategies. The resulting heterogeneous catalysts were shown to be highly active in the enantioselective cyclopropanation of styrene with ethyl diazoaceta
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Herbert, Simon Anthony. "Oxazoline directed lithiation of Calix[4]arene and Ferrocene." Thesis, Stellenbosch : Stellenbosch University, 2011. http://hdl.handle.net/10019.1/17867.

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Thesis (PhD)--Stellenbosch University, 2011.<br>ENGLISH ABSTRACT: The use of chiral oxazoline directed lithiation provides a highly diastereoselective (up to >99% de) route to meta functionalised inherently chiral calixarenes. This methodology can be used on both the butylated and debutylated calixarene systems and is tolerant of a wide range of different electrophillic quenches allowing access to a structurally diverse range of inherently chiral metafunctionalised calixarenes. The oxazoline directing group can be removed via hydrolysis, generating a range of functionalised calixarene car
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8

Dixon, Wendy Jane. "Kinetic studies of the addition of water oxazines and the formation of ring opened products." Thesis, King's College London (University of London), 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.264933.

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9

Jordan, Rainer, and Dan Gieseler. "Poly(2-oxazoline) molecular brushes by grafting through of poly(2-oxazoline)methacrylates with aqueous ATRP." Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2015. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-188802.

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Molecular brushes of poly(2-oxazoline)s (POx) are an intriguing class of polymers as they combine a unique architecture with the properties of POx as a biomaterial. Here, the synthesis of several POx macromonomers with methacrylate end groups and consecutive grafting through polymerization by aqueous atom transfer radical polymerization (ATRP) at room temperature is reported. 1H-NMR spectroscopy and size exclusion chromatography (SEC) confirmed the synthesis of POx molecular brushes with maximum side chain grafting densities, narrow molar mass distributions (Đ ≤ 1.16) and final molar masses co
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10

Schneider, Nathanaëlle. "N-heterocyclic carbenes with an oxazoline unit : Synthesis, coordination chemistry and application in asymmetric catalysis." Strasbourg 1, 2008. http://www.theses.fr/2008STR13057.

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Le succès d’un catalyseur asymétrique n’est possible que si son ligand chiral est judicieusement conçu. La combinaison d’un carbène N-hétérocyclique avec un cycle oxazoline s’avère particulièrement prometteuse. Une nouvelle famille de sels d’imidazolium, où ces deux hétérocycles sont liés par un pont (diméthyl)méthylène a été générée. Les précurseurs imidazoliums sont obtenus par réaction d’un dérivé bromé avec un imidazole portant un cycle oxazoline. Sept différents précurseurs de carbènes ont pu être générés (rendements compris entre 60 et 90%), et les carbènes libres 1-(1-méthyl-1-((4S)-iso
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Libros sobre el tema "Oxazine chemistry"

1

1957-, Kumar M., and Gupta V. 1966-, eds. Heterocyclic chemistry. Springer, 1998.

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Gupta, Radha R., Vandana Gupta, and Mahendra Kumar. Heterocyclic Chemistry II: Five-Membered Heterocycles (Heterocyclic Chemistry). Springer, 1999.

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Capítulos de libros sobre el tema "Oxazine chemistry"

1

Van Thien, Tran. "Thiazine, Oxazine, and Phenazine Leuco Dyes." In Chemistry and Applications of Leuco Dyes. Springer US, 2002. http://dx.doi.org/10.1007/0-306-46906-5_3.

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McKee, R. L. "The 1,4-Oxazines." In Chemistry of Heterocyclic Compounds: A Series Of Monographs. John Wiley & Sons, Inc., 2008. http://dx.doi.org/10.1002/9780470186787.ch15.

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McKee, R. L. "1,3-Oxazines: Ring Index 237-38." In Chemistry of Heterocyclic Compounds: A Series Of Monographs. John Wiley & Sons, Inc., 2008. http://dx.doi.org/10.1002/9780470186787.ch14.

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McKee, R. L. "The 1,2-Oxazines: Ring Index 234-36." In Chemistry of Heterocyclic Compounds: A Series Of Monographs. John Wiley & Sons, Inc., 2008. http://dx.doi.org/10.1002/9780470186787.ch13.

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Zhang, Shuanming, Roberto Pattacini, and Pierre Braunstein. "Coordination Chemistry of Oxazoline/Thiazoline-Based P,N Ligands." In Advances in Organometallic Chemistry and Catalysis. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118742952.ch14.

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Chiu, Thomas T., Bruce P. Thill, and William J. Fairchok. "Poly(2-ethyl-2-oxazoline): A New Water- and Organic-Soluble Adhesive." In Advances in Chemistry. American Chemical Society, 1986. http://dx.doi.org/10.1021/ba-1986-0213.ch023.

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Bolton, R. "Phenazine, oxazine, thiazine and sulfur dyes." In Second Supplements to the 2nd Edition of Rodd's Chemistry of Carbon Compounds. Elsevier, 1991. http://dx.doi.org/10.1016/b978-044453347-0.50381-5.

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Taber, Douglass. "Best Synthetic Methods: Carbon-Carbon Bond Construction." In Organic Synthesis. Oxford University Press, 2011. http://dx.doi.org/10.1093/oso/9780199764549.003.0018.

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In the context of peptidyl ketone synthesis, Troels Skrydstrup of the University of Aarhus developed (J. Org. Chem. 2008, 73, 1088) the elegant SmI2-mediated conjugate addition of acyl oxazolidinones such as 1 to acceptors such as 2. Sadagopan Raghavan of the Indian Institute of Chemical Technology, Hyderabad reported (Tetrahedron Lett. 2008, 49, 1601) that the addition of a Pummerer intermediate, generated by exposure of 4 to TFAA, to the terminal alkene 5 and SnCl4 led to efficient C-C bond formation, to give the sulfide 6 as a single (unassigned) diastereomer. Pd-catalyzed carbonylation of aryl halides and triflates is a well-established process. Stephen L. Buchwald of MIT has now (J. Am. Chem. Soc. 2008, 130, 2754) extended this transformation to much less expensive tosylates and mesylates such as 7. β-Amino acids have often been prepared from α-amino acids by Arndt-Eistert homologation. Geoffrey W. Coates of Cornell University has devised (Angew. Chem. Int. Ed. 2008, 47, 3979) a more practical alternative, the direct Co-catalyzed carbonylation of an oxazoline 9 to the 2-oxazine-6-one 10. Eiji Shirakawa and Tamio Hayashi of Kyoto University also used (Chem. Lett . 2008, 37, 654) a Co catalyst to promote the coupling of aryl and alkenyl Grignard reagents with enol trifl ates such as 11. Alois Fürstner of the Max-Planck-Institut, Mülheim optimized (Chem. Commun. 2008, 2873) promoters for the Pd-catalyzed Stille-Migata coupling of iodo alkenes such as 14 with alkenyl stannanes such as 15 to give 16. It is particularly noteworthy that their system is fluoride free. The stereocontrolled construction of trisubstituted alkenes continues to be challenging. We described (J. Org. Chem. 2008, 73, 1605) the facile preparation of the diioide 18 from the inexpensive 2-butyn-1,4-diol 17 . Sequential coupling of 18 with an aryl Grignard followed by CH3 Li delivered 19. Brian S. J. Blagg of the University of Kansas established (Tetrahedron Lett . 2008, 49, 141) that Still-Genari homologation of 20 with 21 gave (E)- 22 with high geometric control. Biao Jiang of the Shangahi Institute of Organic Chemistry reported (Organic Lett. 2008, 10, 593) a convenient alternative protocol to give ( Z )-α- bromo unsaturated esters.
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DeRosa, Thomas F. "Oxazines." In Advances in Synthetic Organic Chemistry and Methods Reported in US Patents. Elsevier, 2006. http://dx.doi.org/10.1016/b978-008044474-1/50063-3.

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"Oxazines and Related Compounds." In Chemistry of Heterocyclic Compounds: A Series Of Monographs. John Wiley & Sons, Inc., 2008. http://dx.doi.org/10.1002/9780470186787.part3.

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Actas de conferencias sobre el tema "Oxazine chemistry"

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Prakash, Kunal, and Nainy Khera. "Anthracene-Oxazine based reversible ink." In The 23rd International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2019. http://dx.doi.org/10.3390/ecsoc-23-06457.

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STEINHURST, DANIEL A., ANDREW P. BARONAVSKI, and JEFFREY C. OWRUTSKY. "ULTRAFAST TRANSIENT SECOND HARMONIC GENERATION FROM OXAZINE DYES AT THE AIR/WATER INTERFACE." In With Foreword by Prof A H Zewail, Nobel Laureate in Chemistry, 1999. WORLD SCIENTIFIC, 2002. http://dx.doi.org/10.1142/9789812777980_0066.

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Li-Zhulanov, Nikolai, Alla Pavlova, Dina Korchagina, et al. "Synthesis of novel benzo[1,3]oxazines based on monoterpenoid (–)-isopulegol and study of their analgesic activity." In 6th International Electronic Conference on Medicinal Chemistry. MDPI, 2020. http://dx.doi.org/10.3390/ecmc2020-07380.

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Oberhauser, B., B. Grohmann, and H. Sperner. "Selective Epimerisation of a Fungal Cyclopeptolide via an 2-Amino-oxazole Intermediate - Conformational Consequences." In The 2nd International Electronic Conference on Synthetic Organic Chemistry. MDPI, 1998. http://dx.doi.org/10.3390/ecsoc-2-01702.

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Najera, Carmen, Rafael Chinchilla, Nuria Galindo, and Patricia Mazon. "Asymmetric Synthesis of Functionalized Prolines by Diastereoselective 1,3-Dipolar Cycloaddition Using Chiral Oxazinone Derivatives." In The 4th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2000. http://dx.doi.org/10.3390/ecsoc-4-01802.

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Bagnoli, Luana, Katja Berettoni, Francesca Marini, and Claudio Santi. "An efficient cascade reaction for the synthesis of oxazino[4,3-a]indoles and pyrano[3,4-b]indoles from vinyl selenones." In The 17th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2013. http://dx.doi.org/10.3390/ecsoc-17-a037.

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Douhal, A., F. Lahmani, A. Zehnacker-Rentien та F. Amat-Guerri. "Ultrafast excited-state H-atom transfer in jet-cooled 2-(2ʹ-hydroxyphenyl)-oxazole derivatives". У The 54th international meeting of physical chemistry: Fast elementary processes in chemical and biological systems. AIP, 1996. http://dx.doi.org/10.1063/1.50150.

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