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1

Ghahri, Saman, Antonio Pizzi, and Reza Hajihassani. "A Study of Concept to Prepare Totally Biosourced Wood Adhesives from Only Soy Protein and Tannin." Polymers 14, no. 6 (2022): 1150. http://dx.doi.org/10.3390/polym14061150.

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This is a study of concept on the initial application for wood adhesives totally biosourced from the covalent reaction between soy protein isolate (SPI) and a commercial flavonoid tannin, namely quebracho tannin. The adhesive is composed exclusively of the two vegetable biomaterials mentioned and thus is totally biosourced and non-toxic, as tannin has been classified as being not at all toxic by the European Commission REACH program. The pre-reaction between the two yielded the best plywood bonding results when limited to a temperature of 40 °C, final cross-linking being achieved during the pl
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Abdelmoula, Maisa, Hajer Ben Hlima, Frédéric Michalet, et al. "Chitosan-Based Adhesive: Optimization of Tensile Shear Strength in Dry and Wet Conditions." Polysaccharides 2, no. 1 (2021): 110–20. http://dx.doi.org/10.3390/polysaccharides2010008.

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Commercial adhesives present a high bond strength and water resistance, but they are considered non-healthier products. Chitosan can be considered as an interesting biosourced and biodegradable alternative, despite its low water resistance. Here, its wood bonding implementation and its tensile shear strength in dry and wet conditions were investigated depending on its structural characteristics. Firstly, the spread rate, open assembly time, drying pressure, drying temperature, and drying time have been determined for two chitosans of European pine double lap specimens. An adhesive solution spr
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Monteiro, Sandra, Lina Nunes, Jorge Martins, Fernão D. Magalhães, and Luísa Carvalho. "Low-Density Cardoon (Cynara cardunculus L.) Particleboards Bound with Potato Starch-Based Adhesive." Polymers 12, no. 8 (2020): 1799. http://dx.doi.org/10.3390/polym12081799.

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In the present work, and for the first time, totally biosourced low-density particleboards were produced using cardoon particles (a no added value by-product from the Portuguese cheese making industry), bound with a potato starch adhesive. Different starch/cardoon ratios (0.6, 0.8, 1 and 1.2) were tested and the effect of different bio-based additives (chitosan, wood fiber and glycerol) on the performance of the adhesive system was evaluated. The best result was obtained for a formulation with a starch/cardoon mass ratio of 0.8, a chitosan/starch mass ratio of 0.05 and a water/starch mass rati
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Pizzi, Antonio, Antonios N. Papadopoulos, and Franco Policardi. "Wood Composites and Their Polymer Binders." Polymers 12, no. 5 (2020): 1115. http://dx.doi.org/10.3390/polym12051115.

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This review presents first, rather succinctly, what are the important points to look out for when preparing good wood composites, the main types of wood composites manufactured industrially, and the mainly oil-derived wood composite adhesives and binders that dominate and have been dominating this industry. Also briefly described are the most characteristic biosourced, renewable-derived adhesives that are actively researched as substitutes. For all these adhesives, synthetic and biosourced, the reviews expose the considerable progresses which have occurred relatively recently, with a host of n
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5

Droesbeke, Martijn A., Alexandre Simula, José M. Asua, and Filip E. Du Prez. "Biosourced terpenoids for the development of sustainable acrylic pressure-sensitive adhesives via emulsion polymerisation." Green Chemistry 22, no. 14 (2020): 4561–69. http://dx.doi.org/10.1039/d0gc01350a.

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Terpenoid-based (meth)acrylates are introduced in waterborne acrylic pressure-sensitive adhesives via emulsion polymerization. These materials showed good tack, peel strength and shear resistance properties, comparable to a petroleum-based benchmark.
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Ndiwe, Benoit, Antonio Pizzi, Beda Tibi, Raidandi Danwe, Noel Konai, and Siham Amirou. "African tree bark exudate extracts as biohardeners of fully biosourced thermoset tannin adhesives for wood panels." Industrial Crops and Products 132 (June 2019): 253–68. http://dx.doi.org/10.1016/j.indcrop.2019.02.023.

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7

Bensabeh, Nabil, Ana Jiménez-Alesanco, Ilme Liblikas, et al. "Biosourced All-Acrylic ABA Block Copolymers with Lactic Acid-Based Soft Phase." Molecules 25, no. 23 (2020): 5740. http://dx.doi.org/10.3390/molecules25235740.

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Lactic acid is one of the key biobased chemical building blocks, given its readily availability from sugars through fermentation and facile conversion into a range of important chemical intermediates and polymers. Herein, well-defined rubbery polymers derived from butyl lactate solvent were successfully prepared by reversible addition–fragmentation chain transfer (RAFT) polymerization of the corresponding monomeric acrylic derivative. Good control over molecular weight and molecular weight distribution was achieved in bulk using either monofunctional or bifunctional trithiocarbonate-type chain
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8

Badji, Célia, Ahmed Allal, Jean-Charles Dupin, and Frédéric Léonardi. "Impact of Sterilization on the Adhesion Properties of a Polyamide 11 Coating on Textured Metal Substrates." Coatings 14, no. 4 (2024): 424. http://dx.doi.org/10.3390/coatings14040424.

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Polyamide materials are widely used for medical device coating. However, despite the fragile area at the interface, these devices must conserve their physical and mechanical performance after the sterilization process. In this work, the impact of steam sterilization, widely used in the medical sector, on the adhesion properties of biocompatible and biosourced polyamide-11-coated copper substrates was assessed. The adhesion strength, a quantitative indicator of the coating performance, was assessed thanks to a laboratory-made bench test. The surface of metal substrates was microstructured with
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9

Bennour, Haythem, Mongia Said Zina, and Raouf Medimagh. "Synthesis and characterization of novel organosoluble biosourced poly(ester imide)s based on 1,4:3,6 -dianhydrohexitols suited for adhesives applications." Journal of Adhesion Science and Technology 32, no. 17 (2018): 1886–98. http://dx.doi.org/10.1080/01694243.2018.1453227.

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10

Awad, Mohamed M., Turki Alshehri, Ahmed M. Alqarni, et al. "Evaluation of the Bond Strength and Cytotoxicity of Alkasite Restorative Material." Applied Sciences 10, no. 18 (2020): 6175. http://dx.doi.org/10.3390/app10186175.

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Cention N (CN; Ivoclar Vivadent, Schaan, Liechtenstein), advertised as an alkasite, is a bioactive bulk-fill resin-based composite (BF-RBC) with alkaline fillers. This study evaluated the resin-dentin micro-tensile bond strength (μTBS) and cytotoxicity of CN. Methods: Flat dentin surfaces were obtained, bonded with a universal adhesive, and randomly distributed into two groups. CN (group I) and a flowable BF-RBC, namely, Tetric N-Flow Bulk Fill, Ivoclar Vivadent, Schaan, Liechtenstein (group II), were used. After thermocycling, bonded samples were sectioned into micro-beams for μTBS evaluation
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11

Kobayashi, Masahiko, Aous A. Abdulmajeed, Jongyun Moon, et al. "The Effect of Ultraviolet Treatment on TiO2 Nanotubes: A Study of Surface Characteristics, Bacterial Adhesion, and Gingival Fibroblast Response." Metals 12, no. 1 (2022): 80. http://dx.doi.org/10.3390/met12010080.

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Titanium dioxide (TiO2) nanotubes are emerging as a provocative target for oral implant research. The aim of this study was to evaluate the effect of UV on the wettability behavior, bacterial colonization, and fibroblast proliferation rate of TiO2 nanotube surfaces prepared using different anodization voltages and aimed for use as implant abutment materials. Four different experimental materials were prepared: (1) TiO2 nanotube 10 V; (2) TiO2 nanotube 15 V; (3) TiO2 nanotube 20 V; and (4) commercial pure titanium as a control group. TiO2 nanotube arrays were prepared in an aqueous electrolyte
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12

Moreira, Vitor B., Carlos Alemán, Jeroen Rintjema, Fernando Bravo, Arjan W. Kleij, and Elaine Armelin. "A Biosourced Epoxy Resin for Adhesive Thermoset Applications." ChemSusChem 15, no. 7 (2022). http://dx.doi.org/10.1002/cssc.202102624.

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13

van Zwieten, Ralph, Thijs V. Bierman, Peter G. L. Klinkhamer, T. Martijn Bezemer, Klaas Vrieling, and Thomas E. Kodger. "Mimicking natural deterrent strategies in plants using adhesive spheres." Proceedings of the National Academy of Sciences 121, no. 21 (2024). http://dx.doi.org/10.1073/pnas.2321565121.

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With a continuous increase in world population and food production, chemical pesticide use is growing accordingly, yet unsustainably. As chemical pesticides are harmful to the environment and developmental resistance in pests is increasing, a sustainable and effective pesticide alternative is needed. Inspired by nature, we mimic one defense strategy of plants, glandular trichomes, to shift away from using chemical pesticides by moving toward a physical immobilization strategy via adhesive particles. Through controlled oxidation of a biobased starting material, triglyceride oils, an adhesive ma
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14

Maalihan, Reymark D., Marcel Roy B. Domalanta, Andrea Clarisse C. Corrales, and Eugene B. Caldona. "Advances in interfacially engineered surface‐functionalized fillers for multifunctional polymer composite coatings." Polymer Composites, December 9, 2024. https://doi.org/10.1002/pc.29358.

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AbstractThe demand for multifunctional, high‐performance materials has driven advancements in surface‐functionalized fillers for polymer composite coatings. Despite progress, integrating multiple protective properties within a single hybrid formulation remains a challenge. This review explores recent developments in surface and interfacial engineering of biosourced fillers, including nanocellulose, and 2D materials like graphene oxide, MXenes, and layered double hydroxides, all of which have the potential to enhance the chemical resistance, mechanical strength, and thermal stability of polymer
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15

Langenbach, Jakob, Camille Bakkali-Hassani, Quentin-Arthur Poutrel, et al. "Adhesion and Stiffness Matching in Epoxy-Vitrimers/Strain Sensor Fiber Laminates." January 25, 2022. https://doi.org/10.1021/acsapm.1c01648.

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Hybrid networks, including physical and chemical cross-links, were synthesized from biosourced fatty acid fragments, linked to each other by a controlled number of nonexchangeable ether bonds, exchangeable ester bonds, and noncovalent hydrogen bonds. The mechanical properties of these networks are tuned by the ratio of di- versus tetraepoxide and the stoichiometry acid/ epoxy. Creep tests and insolubility demonstrated the vitrimer or vitrimer-like nature of the resulting materials. The thermostimulated welding ability of the materials was exploited to incorporate strain sensors by embedding el
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16

Vijayan, Jyothy G., and T. Niranjana Prabhu. "A Review on Seed Oil‐Based Polyurethane and Its Composites Derived from Biosources: Synthesis, Degradation, and Adsorption Studies." Macromolecular Symposia 413, no. 2 (2024). http://dx.doi.org/10.1002/masy.202300172.

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AbstractPolyurethanes (PUs) are versatile polymers used in industries at large scale. PUs are in used in the form of foam, elastomers, adhesives, fibers, thermosets, thermoplastics, etc. Polyols and isocyanates are the two compounds used to synthesize PU. Day by day increasing price of crude oil and its destructive impact on the environment motivate researchers to develop bio‐PU. Seed oils are attracting nowadays because of their renewability and low cost. They are the best substitutes for fossil fuel‐based polyol used in the preparation of PUs. However, these bio‐based PUs show lower thermal,
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17

Ucpinar, Bedriye, Taha Sivrikaya, and Ayse Aytac. "Sustainable hemp fiber reinforced polylactic acid/poly(butylene succinate) biocomposites: Assessing the effectiveness of MAH‐g‐PLA as a compatibilizer." Polymer Composites, February 7, 2025. https://doi.org/10.1002/pc.29569.

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AbstractThe unsustainability of petroleum resources and the growing issue of plastic pollution necessitate the development of sustainable biocomposites as alternatives to synthetic materials. On this basis, a blend of biosourced poly(lactic acid) (PLA)/poly(butylene succinate) was reinforced with hemp fibers (HF) in various amounts (5–10–20‐30 wt%). In order to facilitate the interaction between PLA/PBS and HFs, maleic anhydride grafted PLA (MAH‐g‐PLA) was added to the biocomposite containing 20 wt% HF at various ratios to produce compatibilized biocomposites. All samples were processed by mel
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