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Rozprawy doktorskie na temat „Coordination Chemistry - Non-Transition Metals”

Autor: Grafiati

Data publikacji: 7 września 2023

Data aktualizacji: 31 lipca 2025

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1

Sze-To, Lap, and 司徒立. "The structural chemistry of coordination compounds containing d-block or f-block metals." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2010. http://hub.hku.hk/bib/B45204470.

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2

Aucott, Stephen Mark. "Coordination chemistry of aminophosphine ligands." Thesis, Loughborough University, 1999. https://dspace.lboro.ac.uk/2134/34492.

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The reaction of [MCl2(cod)] (M = Pt, Pd) with two equivalents of 2-(diphenylphosphinoamino)pyridine, Ph2PNHpy, in warm acetonitrile led to cationic complexes of the type cis-[MCl(Ph2PNHpy-P,N){Ph2PNHpy-P}][Cl] (M = Pt, Pd) which exhibit broad single 31P{1H} NMR resonances due to their dynamic pyridyl exchange behaviour in solution. A single crystal X-ray diffraction study of the platinum species confirmed the proposed structure and revealed that adjacent complex molecules were held together by hydrogen bonding to the same chloride counter-ion. The bromo- and iodo-cis[MX(Ph2PNHpy-P,N){Ph2PNHpy-

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3

Chotalia, Rohit. "The synthesis and coordination chemistry of novel oligopyridine ligands." Thesis, University of Cambridge, 1993. https://www.repository.cam.ac.uk/handle/1810/272580.

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4

Baisya, Siddhartha Sankar. "Coordination chemistry of pteridine ligands with transition and d10 metals." Thesis, University of North Bengal, 2016. http://ir.nbu.ac.in/handle/123456789/2555.

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5

Reinhardt, Maxwell James. "Metal complexes containing non-innocent ligands for functional materials." Thesis, University of Edinburgh, 2013. http://hdl.handle.net/1842/11723.

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The existence of complexes of that display non-innocence has been of interest in the field of coordination chemistry since the investigations of square-planar dithiolene complexes of the late transition metals in the 1960s. The ligands used in these systems are termed “non-innocent” when bound to a number of the late transition metals, because the orbital energy levels are similar to those of the central metal ion. This allows there to be significant electron delocalisation over the complex with the potential for the complexes to exist in a number of electronic states due to the combined elect

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6

McCart, Mark Kevin. "Some diphosphine chemistry of the transition metals ruthenium, palladium, platinum and nickel." Thesis, University of Liverpool, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.263849.

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7

Moneo, Corcuera Andrea. "Bistable molecular materials: triazole-based coordination chemistry of first row transition metals." Doctoral thesis, Universitat Rovira i Virgili, 2019. http://hdl.handle.net/10803/668881.

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En la present tesi doctoral presentem el magnetisme molecular bàsic de compostos de coordinació basats en un lligant di-anionico: (L-2 = 4- (1,2,4-triazole-4-il) etanosulfonato). En particular, vam estudiar el fenomen de transició d'espín d'un trímer de ferro (II) poli-aniònic en diferents escales, des d'una escala macroscòpica ("bulk") fins a nivells moleculars, acabant amb la deposició en superfície. D'una banda, el comportament SCO "macroscòpic" es va modular canviant l'empaquetatge de vidre i la connectivitat entre els trímers amb una estratègia d'intercanvi catiònic. D'altra banda, hem tr

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8

Jafarpour, Laleh. "New ligands, design and coordination chemistry with the transition metals and lanthanides." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1999. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape7/PQDD_0009/NQ38903.pdf.

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9

Holmes, Nicholas J. "Synthesis and coordination of stibine and bismuthine ligands with transition metals." Thesis, University of Southampton, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.299499.

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10

Haque, Nadera. "Coordination Chemistry of Barbituric Acid, its Diethyl Derivative and Benzildiimine with Transition Metals." Diss., lmu, 2009. http://nbn-resolving.de/urn:nbn:de:bvb:19-115621.

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11

De, Jongh Leigh-Anne. "Imine-donor complexes with group 6 and group 11 transition metals : coordination and dynamics." Thesis, Stellenbosch : Stellenbosch University, 2008. http://hdl.handle.net/10019.1/2001.

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Thesis (MSc (Chemistry and Polymer Science))--Stellenbosch University, 2008.<br>In this study the coordination of ligands with several coordination sites, 2-aminoazoles (2- amino-4-methylthiazole), 2-aminobenzothiazole, 2-aminobenzoimidazole and 2- aminothiazoline and a biguanidine (N-(2-methylphenyl)imidodicarbonimidic diamide) to soft metal centres [gold(I) (group 11), chromium(0) (group 6) and tungsten (0) (group 6)] was investigated. The aminoazoles have three coordination sites, an exocyclic amine nitrogen, an endocyclic imine nitrogen and an endocyclic thioether sulphur. The biguan

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12

Castañeda-Perea, Luis Raúl. "Imidoyl Amidine Ligands: A Versatile Framework to Build Homo and Heterometallic Complexes." Thesis, Université d'Ottawa / University of Ottawa, 2020. http://hdl.handle.net/10393/40712.

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Ligand design in general enables the formation of coordination compounds with multiple functionalities within a single framework. To date, two of the most widely studied ligands are 2,2′:6′,2′′-terpyridine (terpy) and acetylacetone (acac), whose tridentate and bidentate coordination pockets, respectively, enables the formation of metallic complexes with various geometries. The Brusso group had been incorporating imidoyl amidine (ImAm) ligands to build different materials such as organic radicals and fluorescent materials. In particular, the ligands N-2-pyridylimidoyl-2-pyridylamidine (Py2ImAm)

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13

Garon, Christian N. "TANTALUM(V) AND ZIRCONIUM(IV) : Coordination Chemistry of Boronates and Carboxylates to Early Transition Metals." Thesis, Université Laval, 2011. http://www.theses.ulaval.ca/2011/28751/28751.pdf.

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14

Shrestha, Sweta. "Application of Transition Metal Coordination for Energy Efficient Processes: Catalysis and Separation." The Ohio State University, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=osu1502975499629018.

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15

Clough, Benjamin. "New scandium and titanium borylimido chemistry." Thesis, University of Oxford, 2017. https://ora.ox.ac.uk/objects/uuid:1a9dbfb3-98c3-4fd6-96ac-5fba09f3ffcd.

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This Thesis reports the synthesis and reactivity of scandium and titanium borylimides. New, versatile synthetic routes to such complexes of these two metals were targeted, and their reactions with small, unsaturated compounds were explored, with a particular focus being the reactivity of alkynes with these systems. <b>Chapter One</b> provides a background on Group 4 imido and hydrazido complexes. Group 4 alkoxyimides are also reviewed, as well as the developing field of rare earth imides. The Chapter focuses on the synthesis, structure, and stoichiometric and catalytic reactions of these compl

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16

Carson, Cantwell G. "Noble and transition metal aromatic frameworks synthesis, properties, and stability /." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2009. http://hdl.handle.net/1853/29657.

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Thesis (Ph. D.)--Materials Science and Engineering, Georgia Institute of Technology, 2009.<br>Committee Chair: Rina Tannenbaum; Committee Co-Chair: Rosario A. Gerhardt; Committee Member: E. Kent Barefield; Committee Member: Karl I. Jacob; Committee Member: Preet Singh; Committee Member: R. Bruce King. Part of the SMARTech Electronic Thesis and Dissertation Collection.

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17

Kuchenbeiser, Glenn Richard. "Reactivity of bis(amino)cyclopropenylidenes (BACs) and cyclic (alkyl)(amino)carbenes (CAACs) coordination chemistry, catalysis, and small molecule activation /." Diss., [Riverside, Calif.] : University of California, Riverside, 2009. http://proquest.umi.com/pqdweb?index=0&did=1899480521&SrchMode=2&sid=4&Fmt=2&VInst=PROD&VType=PQD&RQT=309&VName=PQD&TS=1269286714&clientId=48051.

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Thesis (Ph. D.)--University of California, Riverside, 2009.<br>Includes abstract. Available via ProQuest Digital Dissertations. Title from first page of PDF file (viewed March 10, 2010). Includes bibliographical references. Also issued in print.

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18

Cuevas-Chávez, Cynthia. "Synthèse, structure et réactivité de complexes de platine et d'iridium à ligands phosphinodi(benzylsilanes)." Thesis, Toulouse 3, 2019. http://www.theses.fr/2019TOU30196.

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Une chimie riche et des possibilités d'applications dans un large éventail de domaines (par exemple, l'activation de petites molécules, les transformations sélectives, y compris les développements catalytiques, etc.) des composés de type pince à base de silicium avec des métaux de transition ont été attestés par des progrès remarquables en chimie de coordination ainsi qu'en organométallique. Cela est dû aux propriétés remarquables des atomes de Si qui génèrent des centres métalliques riches en électrons labellisant de manière concomitante les substituants trans. Cependant, malgré la pléthore d

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19

Ruffray, Kévin. "Synthèse et étude physico-chimique de systèmes d-f hétérométalliques moléculaires et auto-assemblés." Thesis, Montpellier, Ecole nationale supérieure de chimie, 2015. http://www.theses.fr/2015ENCM0025/document.

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Les interactions qu’un métal f entretient avec son environnement sont étudiées dans de nombreux domaines (industrie nucléaire, électronique, …). Pourtant, ces phénomènes sont souvent mal compris d’un point de vue fondamental. Les interactions qui peuvent s’établir entre métaux d et métaux f ont déjà été en partie étudiées, principalement dans le domaine du magnétisme. Les phénomènes de transfert de charge ont cependant été beaucoup moins analysés, malgré une importance croissante dans de nombreux systèmes. Cette étude se propose de développer des systèmes moléculaires permettant d’étudier un c

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20

Clarisse, Jade. "Croissance cristalline de polymères de coordination : synthèse, suivi calorimétrique et caractérisation structurale." Thesis, Lyon 1, 2013. http://www.theses.fr/2013LYO10269/document.

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Les polymères de coordination poreux appelés Metal Organic Frameworks (MOF) sont envisagés pour des développements et applications prometteuses dans la catalyse par exemple. La compréhension des mécanismes de synthèse et leurs croissances cristallines restent cependant un défi. Actuellement, seules quelques études in-situ ont été réalisées pour rationnaliser la synthèse des MOFs, comme des suivis par résonance magnétique nucléaire, par spectroscopie de masse ou par diffraction des rayons X en dispersion d'énergie. Nous proposons, l'analyse thermodifférentielle qui est une technique plus aisée

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21

ORBISAGLIA, SERENA. "From pyrazole- to imidazole-based N-donor Ligands: Coordination Chemistry and Applications of New Late Transition Metals Complexes with Scorpionates, Poly(pyrazolyl)alkanes and NHCs." Doctoral thesis, Università degli Studi di Camerino, 2014. http://hdl.handle.net/11581/401839.

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The nature of ligands coordinated to the metal ion mostly determines the properties of the inorganic, organometallic or bioinorganic model compounds. The pyrazole is one of the most studied heterocyclic aromatic compounds in coordination chemistry as single ligand or incorporated in polidentate ligands, such as in poly(pyrazolyl)borates (â€˜scorpionates'), poly(pyrazolyl)alkanes, etc. The great versatility of the pyrazole allows the formation of several ligands with different functionalizations, which mainly influence the geometry and nuclearity of the diverse coordination complexes afforded b

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22

Lake, Andrew J. "Advances in polyaromatic and ferrocenyl phosphine chemistry." Thesis, Loughborough University, 2010. https://dspace.lboro.ac.uk/2134/6329.

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Condensation of Ph2PCH2OH with a range of polyaromatic substituted secondary amines afforded a new set of 'hybrid' phosphine ligands of the type {RCH2N(CH2PPh2)CH2}2 and RCH2N(CH2PPh2)CH2CH3 (R = various planar aromatic groups). The coordination chemistry of these new mono and bidentate ligands towards a range of transition metal centres including Mo(0), Au(I), Rh(I), Ni(II), Pd(II), Pt(II) and Ru(II) was investigated. Ditertiary phosphines of the form {RCH2N(CH2PPh2)CH2}2 were found to be capable of bridging two transition metal centres in addition to forming rare examples of nine-membered ci

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23

Iasco, Olga. "Aimants moléculaires à base de clusters polymétalliques : synthèse, structures cristallines et étude des propriétés magnétiques." Phd thesis, Université Claude Bernard - Lyon I, 2011. http://tel.archives-ouvertes.fr/tel-00838606.

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Les molécules-aimants, ou Single-Molecule Magnets en anglais, sont des complexes polymétalliques qui possèdent la propriété remarquable de se comporter individuellement comme des aimants. Synthétisées selon les méthodes de la chimie de coordination elles sont devenues l'objet d'une intense activité de recherche multidisciplinaire à l'interface de la chimie et de la physique. C'est dans ce contexte que se situe notre travail de thèse qui nous a conduit à synthétiser plusieurs séries de complexes polynucléaires nouveaux puis a les caractériser cristallographiquement et étudier leurs propriétés m

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24

Parrott, Suzanne J. "The coordination chemistry of hydrazide and diazenide complexes of rhenium." Thesis, University of Essex, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.315728.

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25

Quirk, Jeffrey. "Coordination chemistry of selenoether macrocyclic ligands with transition metal ions." Thesis, University of Southampton, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.242624.

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26

Hall, Christopher. "The coordination of alkanes to transition metal fragments." Thesis, University of York, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.331939.

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27

Hall, Andrew J. "Transition metal ion coordination in hydrophilic polymer membranes." Thesis, Aston University, 1994. http://publications.aston.ac.uk/9746/.

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The research described within this thesis is concerned with the investigation of transition metal ion complexation within hydrophilic copolymer membranes. The membranes are copolymers of 4-methyl-4'-vinyl-2,2'-bipyridine, the 2-hydroxyethyl ester of 4,4'- dicarboxy-2,2'-bipyridine & bis-(5-vinylsalicylidene)ethylenediamine with 2-hydroxyethyl methacrylate. The effect of the polymer matrix on the formation and properties of transition metal iron complexes has been studied, specifically Cr(III) & Fe(II) salts for the bipyridyl- based copolymer membranes and Co(II), Ni(II) & Cu(II) salts for the

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28

Anderson, Carly Elizabeth. "Synthesis of multidentate PNE ligands and their late transition metal coordination chemistry." Thesis, Durham University, 2007. http://etheses.dur.ac.uk/2598/.

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This thesis describes the synthesis of a family of potentially tridentate PNE (E = NMe, О, S, СН(_2), NPh) ligands comprising a six-membered diheteroatomic saturated ring system bearing a pendent phosphine donor arm and studies on their coordination chemistry with a selection of late transition metals. Chapter 1 comprises an overview of the nature of the bonding of phosphine, amine, ether and thioether donors to metals and reviews the dynamic behaviour of saturated heteroatom-containing ring systems in solution. Selected examples of the coordination chemistry and catalytic applications of comp

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29

Bajwa, Somia Ehsan. "Hybrid multidentate phosphine-alkene ligands for transition metal coordination chemistry and catalysis." Thesis, University of York, 2012. http://etheses.whiterose.ac.uk/2633/.

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The development of a new class of phosphine-alkene and thio-phosphine-alkene ligands based on a chalcone ferrocene framework, represents the primary focus of this study. The synthesis and characterisation of novel ligands, ferrochalcone 32 and thio-ferrochalcone 33, are described. The related alkene-phosphine ligands, the Lei ligand 17 and novel thio-Lei ligand 46, are further detailed. The coordination chemistry of four ligands (17, 32, 33 and 46) with various transition metals (Pt, Pd, Cu, Rh and Au) has been investigated in a comprehensive spectroscopis study. Single crystal X-ray analysis

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30

Atkinson, Nigel Anthony. "Transition metal complexes with sulphur/nitrogen donor macrocycles and related ligands." Thesis, University of Huddersfield, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.290395.

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31

Custer, Paul D. "Transition Metal Coordination for the Construction of Supramolecular Molecules." University of Akron / OhioLINK, 2008. http://rave.ohiolink.edu/etdc/view?acc_num=akron1226957658.

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32

Ansari, Nasrin. "Coordination properties of aminophosphine with first row transition metal nitrosyl complexes." Thesis, University of Ottawa (Canada), 1994. http://hdl.handle.net/10393/6862.

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The synthesis of the new thermolabile ironnitrosylhydride complex FeH(NO)(CO)(dppf) is reported. (dppf = 1,1$\sp\prime$-bisdiphenyl phosphino-ferrocene). The facile decomposition of FeH(NO)(CO)(dppf) is interpreted in terms of a homolysis of the Fe-H bond and of a nitrosyl transfer reaction. The synthesis of the structurally characterized iron complex Fe(O=PPh$\sb2$(2-Py))$\sb3\sp2\sp+\cdot$2BF$\sb4\sp-$, by the reaction of Fe(NO)$\sb2$(THF)$\sb2\sp+$ with PPh$\sb2$(2-Py) is described. The proposed mechanism for the formation of Fe(O=PPh$\sb2$(2-Py))$\sb3\sp2\sp+\cdot$2BF$\sb4\sp-$ involves a

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33

Sheng, Xia. "Competitive transport, extraction and coordination chemistry of a number of ligands with selected transition and post-transition metal ions." Thesis, Link to the online version, 2008. http://hdl.handle.net/10019/1488.

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34

Cordes, David B., and n/a. "Supramolecular transition metal architectures." University of Otago. Chemistry Department, 2005. http://adt.otago.ac.nz./public/adt-NZDU20060705.144929.

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This thesis describes the investigation of the coordination and supramolecular chemistry of three different types of pyridine-containing ligand with a selection of Ag(I), Cu(I), Cu(II) and Cd(II) salts. The ligand types are flexible and four-armed, rigid and four-armed and bent with two rigid arms. All the ligands also display the ability to form additional supramolecular interactions. Chapter one introduces supramolecular chemistry and crystal engineering and covers background on several areas of current interest in these fields. Network structures, both coordination polymers and hydrogen-bo

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35

Rooke, Stephanie Jane. "Transition metal coordination polymers of novel siloxanes bearing N- donor groups." Thesis, Imperial College London, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.271532.

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36

Gibson, Alexander. "Syntheses and studies on transition metal complexes involving phosphine and thioether ligands." Thesis, University of Southampton, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.243147.

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37

Jackson, N. R. C. "The chemistry of transition metals in binary non-aqueous solvents containing carbon halides." Thesis, University of Leeds, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.233995.

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38

Habtu, Michael M. "A study of the transport, extraction and co-ordination chemistry of a number of thiourea ligands with a series of transition and post-transition metal ions." Thesis, Stellenbosch : Stellenbosch University, 2003. http://hdl.handle.net/10019.1/97374.

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Thesis (MSc)--Stellenbosch University, 2003.<br>ENGLISH ABSTRACT: In this study, a number of mono- and di-substituted acyl(aroyl)thioureas were investigated for potential application as specific carriers (ionophores) for the transport and extraction of Ag(l) from a mixture of Co(II), Ni(II), Cu(II), Zn(II), Cd(II), and Pb(lI) ions. The experimental arrangement for the transport experiments employed a liquid membrane set up involving a 3-phase system - 2 aqueous phases (source and receiving phase) separated by a chloroform membrane incorporating the ligand. Competitive metal ion transport

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39

Cetin, Anil. "TRANSITION METAL COMPLEXES OF PORPHYRIN ANALOGS AND BORATE-BASED COORDINATION COMPLEXES." University of Akron / OhioLINK, 2007. http://rave.ohiolink.edu/etdc/view?acc_num=akron1176390111.

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40

Ghebregziabiher, Berhe Haile. "Synthesis of chiral thiourea ligands and their transition metal complexes." Thesis, Stellenbosch : Stellenbosch University, 2003. http://hdl.handle.net/10019.1/53610.

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Thesis (MSc)--Stellenbosch University, 2003.<br>ENGLISH ABSTRACT: Modification of chitosan with benzoylisothiocyanate was attempted, however due to solvent problem the study was left incomplete till appropriate solvent is designed. N,N-diethyl-N -camphanoylthiourea (HL8), N-piperidyl-N '-camphanoylthiourea (HL9), N-pyrrolidyl-N -camphanoylthiourea (HL10) and N,N-diethyl-N -adamantylcarbonyl thiourea (HL11)have been synthesised and characterised for the first time. Two of these ligands HL8 and HL11, were used to form a number of transition metal complexes, namely H30+{fae-[Co(L8-S,Obn, c

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41

Ahmed, Ejaz, and Michael Ruck. "Chemistry of polynuclear transition-metal complexes in ionic liquids." Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2014. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-138716.

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Transition-metal chemistry in ionic liquids (IL) has achieved intrinsic fascination in the last few years. The use of an IL as environmental friendly solvent, offers many advantages over traditional materials synthesis methods. The change from molecular to ionic reaction media leads to new types of materials being accessible. Room-temperature IL have been found to be excellent media for stabilising transition-metal clusters in solution and to crystallise homo- and heteronuclear transition-metal complexes and clusters. Furthermore, the use of IL as solvent provides the option to replace high-te

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42

Ahmed, Ejaz, and Michael Ruck. "Chemistry of polynuclear transition-metal complexes in ionic liquids." Royal Society of Chemistry, 2011. https://tud.qucosa.de/id/qucosa%3A27774.

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Transition-metal chemistry in ionic liquids (IL) has achieved intrinsic fascination in the last few years. The use of an IL as environmental friendly solvent, offers many advantages over traditional materials synthesis methods. The change from molecular to ionic reaction media leads to new types of materials being accessible. Room-temperature IL have been found to be excellent media for stabilising transition-metal clusters in solution and to crystallise homo- and heteronuclear transition-metal complexes and clusters. Furthermore, the use of IL as solvent provides the option to replace high-te

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43

Hager, Emma. "The design and synthesis of new transition metal coordination complexes as potential anti-malarial agents." Doctoral thesis, University of Cape Town, 2011. http://hdl.handle.net/11427/10667.

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44

Moleko, Pulleng. "The coordination and extractive chemistry of the later 3d transition metal ions with N, N'-donor imidazole-based ligands." Thesis, Nelson Mandela Metropolitan University, 2014. http://hdl.handle.net/10948/8382.

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The application of bidentate N,N'-donor ligands, such as 2,2'-biimidazole (BIIMH2) and 2,2'-pyridylimidazole (PIMH) and (1H-benzimidazol-2yl)-N-methylmethanamine (BIMAH), in the solvent extraction of base metal ions from an acidic sulfate/sulfonate medium was investigated. PIMH and BIMAH showed selectivity for Ni(II) with the only interfering ion being Cu(II) in the pH range 1.2-1.8 but BIIMH2 lacked selectivity. The extraction patterns observed were influenced by stereochemical aspects, and this agreed well with the envisaged design of nickel(II)-specific extractants through stereochemical “t

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Olson, Justine Rose. "Early transition metal and actinide coordination chemistry of a bicyclic guanidinate ligand: synthesis, characterization, and luminescence." Diss., University of Iowa, 2017. https://ir.uiowa.edu/etd/5588.

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The bicyclic guanidinate 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidinate (hpp–) has been recognized as an excellent stabilizing ligand for low oxidation state metals for about a decade. It has been used as a dinucleating anionic ligand in the synthesis of complexes containing the ‘paddlewheel’ structure motif (which often contain metal-metal multiple bonds) and is resistant to reductive cleavage by low-valent metal centers. One drawback to the ligand is that its metal complexes often have reduced solubility. This can be problematic in isolation and characterization. One solution to this p

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Fleming, Kathleen. "The Gas-Phase Ligand Exchange of Select Alkaline Earth and Transition Metal ß-diketonate Complexes." Youngstown State University / OhioLINK, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1465062889.

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Hashiguchi, Ryota. "Studies on Polynuclear Metal Complexes and Low-Dimensional Mixed-Valence Halogen-Bridged Transition Metal Complexes Based on them." 京都大学 (Kyoto University), 2017. http://hdl.handle.net/2433/225426.

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Shi, Qi. "Synthesis, coordination chemistry and reactivity of 1H-pyridin-(2E)-ylidenes and application of their transition metal complexes." Thesis, University of York, 2010. http://etheses.whiterose.ac.uk/875/.

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This thesis describes the synthesis of 1H-pyridin-(2E)-ylidenes (PYE) ligands, their coordination chemistry with late transition metals and the application of their metal complexes in selected catalytic reactions and anticancer activity. The preparation of mono- and bidentate PYE ligands was achieved from reactions between pyridinium salts and primary amines in the presence of a base. A variety of PYE ligands including chiral and bulky examples were fully characterised by a number of techniques, including single crystal X-ray diffraction. A range of transition metal precursors were tested with

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Cheaib, Khaled. "Synthesis, characterization and photochemical properties of 3d transition metal supported by aroyl-hydrazone ligands." Thesis, Strasbourg, 2013. http://www.theses.fr/2013STRAF062/document.

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Ce travail de thèse explorait certains aspects de la chimie de coordination de complexes moléculaires à bases de métaux 3d (Fe, Cu, Mn et Ni) supportés par des ligands azotés de type aroyle-hydrazone. Le travail de cette thèse était plus particulièrement centré sur le développement des nouveaux ligands et la photo chimie des complexes ferriques, afin d’élucider en particulier les mécanismes de la photo réduction qui valorise un brevet du laboratoire sur la production et le stockage d’énergie solaire via la photo réduction d’ions ferriques. Les complexes mis en jeu dans le processus ont été tot

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Grachvogel, David Anthony. "The synthesis and structural characterisation of the lanthanide and transition metal coordination polymers formed with novel multinucleating ligands." Thesis, Imperial College London, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.391760.

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