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Artykuły w czasopismach na temat „EDA complex”

Autor: Grafiati

Data publikacji: 25 stycznia 2025

Data aktualizacji: 31 lipca 2025

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1

Sima, Jian, Zhijiang Yan, Yaohui Chen, et al. "Eda-activated RelB recruits an SWI/SNF (BAF) chromatin-remodeling complex and initiates gene transcription in skin appendage formation." Proceedings of the National Academy of Sciences 115, no. 32 (2018): 8173–78. http://dx.doi.org/10.1073/pnas.1800930115.

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Ectodysplasin A (Eda) signaling activates NF-κB during skin appendage formation, but how Eda controls specific gene transcription remains unclear. Here, we find that Eda triggers the formation of an NF-κB–associated SWI/SNF (BAF) complex in which p50/RelB recruits a linker protein, Tfg, that interacts with BAF45d in the BAF complex. We further reveal that Tfg is initially induced by Eda-mediated RelB activation and then bridges RelB and BAF for subsequent gene regulation. The BAF component BAF250a is particularly up-regulated in skin appendages, and epidermal knockout of BAF250a impairs skin a

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Dutt, Shantanu, Dinesh Mehta, and Gi-Joon Nam. "New Algorithmic Techniques for Complex EDA Problems." VLSI Design 2014 (April 27, 2014): 1–2. http://dx.doi.org/10.1155/2014/134946.

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Jorge, C. Herrera-Luna, Carmen Pérez-Aguilar María, Gerken Leon, García Mancheño Olga, Consuelo Jiménez M., and Pérez-Ruiz Raúl. "Effective Formation of New C(sp2)−S Bonds via Photoactivation of Alkylamine-based Electron Donor-Acceptor Complexes." Chem. Eur. J. 29, no. 6 (2023): e202203353. https://doi.org/10.1002/chem.202203353.

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An effective approach for the direct thiolation of five-membered heteroarenes involving visible-light-absorbing EDA complexes is reported. The reaction takes place from an EDA complex between an alkylamine and the heteroarene halide. Selective photolysis to the EDA complex has allowed to generate the heteroarene radical that is suitably trapped by disulfide derivatives, providing a potent synthetic versatility.

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4

Asaad, Adel N., and Gunnar Aksnes. "Kinetics and Mechanism of the 2+ 2 Cycloaddition of Tetracyanoethylene to 2,5-Dimethyl-2,4-Hexadiene." Zeitschrift für Naturforschung A 43, no. 5 (1988): 435–41. http://dx.doi.org/10.1515/zna-1988-0507.

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The kinetics of the 2 + 2 cycloaddition reaction between tetracyanoethylene and 2,5-dimethyl- 2,4-hexadiene in different solvents has been studied by following the disappearance of the intermediate EDA-complex spectrophotometrically. It is concluded that the EDA-complex is transformed through a concerted cyclicpolar transition state to give the vinyl cyclobutane derivative (III). The effects of various solvents on the reaction rates have been analysed using a multiparameter approach. The thermodynamic parameters (ΔH0 and ΔS0), of EDA-complex formation and the activation parameters (ΔH# and ΔS#

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5

Yang, Zhonglie, Yutong Liu, Kun Cao, Xiaobin Zhang, Hezhong Jiang, and Jiahong Li. "Synthetic reactions driven by electron-donor–acceptor (EDA) complexes." Beilstein Journal of Organic Chemistry 17 (April 6, 2021): 771–99. http://dx.doi.org/10.3762/bjoc.17.67.

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The reversible, weak ground-state aggregate formed by dipole–dipole interactions between an electron donor and an electron acceptor is referred to as an electron-donor–acceptor (EDA) complex. Generally, upon light irradiation, the EDA complex turns into the excited state, causing an electron transfer to give radicals and to initiate subsequent reactions. Besides light as an external energy source, reactions involving the participation of EDA complexes are mild, obviating transition metal catalysts or photosensitizers in the majority of cases and are in line with the theme of green chemistry. T

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6

Liu, Lu, Robert M. Ward, and Jennifer M. Schomaker. "Regioselective Intramolecular Allene Amidation Enabled by an EDA Complex**." Chemistry – A European Journal 26, no. 61 (2020): 13783–87. http://dx.doi.org/10.1002/chem.202002533.

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Theuerkauf, Martin, and John Couwenberg. "The extended downscaling approach: A new R-tool for pollen-based reconstruction of vegetation patterns." Holocene 27, no. 8 (2016): 1252–58. http://dx.doi.org/10.1177/0959683616683256.

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The extended downscaling approach (EDA) is a quantitative method in palynology that aims to detect past vegetation patterns and communities in the landscape. The EDA uses iterative forward modelling to fit vegetation composition to robust landscape patterns by comparing simulated with actually observed pollen deposition. The approach employs a set of pollen records, preferably from medium sized to large lakes or peatlands, as well as maps of robust landscape patterns, such as soils and relief. So far, the EDA has been applied in simple settings with only few taxa. To be able to apply the model

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8

Kwiecień, Anna, Jana Ruda-Kucerova, Kamil Kamiński, et al. "Improved Pharmacokinetics and Tissue Uptake of Complexed Daidzein in Rats." Pharmaceutics 12, no. 2 (2020): 162. http://dx.doi.org/10.3390/pharmaceutics12020162.

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The pharmacokinetic profile and tissue uptake of daidzein (DAI) was determined in rat serum and tissues (lungs, eyes, brain, heart, spleen, fat, liver, kidney, and testes) after intravenous and intraperitoneal administration of DAI in suspension or complexed with ethylenediamine-modified γ-cyclodextrin (GCD-EDA/DAI). The absolute and relative bioavailability of DAI suspended (20 mg/kg i.v. vs. 50 mg/kg i.p.) and complexed (0.54 mg/kg i.v. vs. 1.35 mg/kg i.p.) was determined. After i.p. administration, absorption of DAI complexed with GCD-EDA was more rapid (tmax = 15 min) than that of DAI in s

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9

Jeliński, Tomasz, Maciej Przybyłek, Magdalena Mianowana, Kinga Misiak, and Piotr Cysewski. "Deep Eutectic Solvents as Agents for Improving the Solubility of Edaravone: Experimental and Theoretical Considerations." Molecules 29, no. 6 (2024): 1261. http://dx.doi.org/10.3390/molecules29061261.

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In this study, both practical and theoretical aspects of the solubility of edaravone (EDA) in Deep Eutectic Solvents (DESs) were considered. The solubility of edaravone in some media, including water, can be limited, which creates the need for new efficient and environmentally safe solvents. The solubility of EDA was measured spectrophotometrically and the complex intermolecular interactions within the systems were studied with the COSMO-RS framework. Of the four studied DES systems, three outperformed the most efficient classical organic solvent, namely dichloromethane, with the DES comprisin

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10

Lin, Li, Zhonglie Yang, Jianchen Liu, et al. "Visible-light-induced surfactant-promoted sulfonylation of alkenes and alkynes with sulfonyl chloride by the formation of an EDA-complex with NaI in water at room temperature." Green Chemistry 23, no. 15 (2021): 5467–73. http://dx.doi.org/10.1039/d1gc00956g.

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We report an efficient visible-light-induced iodosulfonyl reaction of alkenes in water using an EDA complex strategy at room temperature. The addition of a cationic surfactant allows for the easy formation of colored EDA complexes in water.

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11

Jose, Nidhin. "Innovations in Real Time Inventory Management: Leveraging Event Driven Architecture in Modern Retail Supply Chains." European Journal of Computer Science and Information Technology 13, no. 49 (2025): 32–43. https://doi.org/10.37745/ejcsit.2013/vol13n493243.

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This article examines the transformative impact of Event Driven Architecture (EDA) on retail inventory management. As consumer expectations shift toward omnichannel fulfillment and immediate availability, traditional batch processing approaches increasingly fail to meet market demands. It explores how EDA reimagines inventory management through real time event processing, enabling continuous visibility and automated decision making across complex supply networks. It investigates the stream processing technologies powering these systems, primarily Apache Kafka and Apache Flink, alongside the in

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12

Visnovcova, Zuzana, Lucia Bona Olexova, Nikola Sekaninova, et al. "Spectral and Nonlinear Analysis of Electrodermal Activity in Adolescent Anorexia Nervosa." Applied Sciences 10, no. 13 (2020): 4514. http://dx.doi.org/10.3390/app10134514.

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Anorexia nervosa (AN) is an eating disorder with increasing prevalence in childhood and adolescence. Sympathetic dysregulation is supposed to be the underlying mechanism of increased cardiovascular risk in AN. Thus, we assess the electrodermal activity (EDA) as a non-invasive index of sympathetic cholinergic activity using linear and nonlinear analysis in adolescent AN with the aim of detecting potential biomarkers for AN-linked cardiovascular risk. We examined 25 adolescent girls with AN and 25 age-matched controls. EDA was continuously recorded during a 5-min resting phase. Evaluated paramet

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13

Lavezzo, Laura, Andrea Gargano, Enzo Pasquale Scilingo, and Mimma Nardelli. "Zooming into the Complex Dynamics of Electrodermal Activity Recorded during Emotional Stimuli: A Multiscale Approach." Bioengineering 11, no. 6 (2024): 520. http://dx.doi.org/10.3390/bioengineering11060520.

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Physiological phenomena exhibit complex behaviours arising at multiple time scales. To investigate them, techniques derived from chaos theory were applied to physiological signals, providing promising results in distinguishing between healthy and pathological states. Fractal-like properties of electrodermal activity (EDA), a well-validated tool for monitoring the autonomic nervous system state, have been reported in previous literature. This study proposes the multiscale complexity index of electrodermal activity (MComEDA) to discern different autonomic responses based on EDA signals. This met

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14

Murray, Elizabeth L., and Tyrrell Conway. "Multiple Regulators Control Expression of the Entner-Doudoroff Aldolase (Eda) of Escherichia coli." Journal of Bacteriology 187, no. 3 (2005): 991–1000. http://dx.doi.org/10.1128/jb.187.3.991-1000.2005.

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ABSTRACT The Escherichia coli eda gene, which encodes the Entner-Doudoroff aldolase, is central to the catabolism of several sugar acids. Here, we show that Eda synthesis is induced by growth on gluconate, glucuronate, or methyl-β-d-glucuronide; phosphate limitation; and carbon starvation. Transcription of eda initiates from three promoters, designated P1, P2, and P4, each of which is responsible for induction under different growth conditions. P1 controls eda induction on gluconate and is regulated by GntR. P2 controls eda induction on glucuronate and galacturonate and is regulated by KdgR. P

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15

Pérez-Ramos, Paula, Patrícia I. C. Godinho, Raquel G. Soengas, and Humberto Rodríguez-Solla. "Electron donor–acceptor complex-driven photocatalyst-free synthesis of nitrocyclopropanes." RSC Advances 15, no. 19 (2025): 15155–63. https://doi.org/10.1039/d5ra02540k.

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16

Pophali, Amey. "Leveraging Event-Driven Architectures for Enhanced Real-Time Inventory Management in E-Commerce Systems." European Journal of Computer Science and Information Technology 13, no. 30 (2025): 122–28. https://doi.org/10.37745/ejcsit.2013/vol13n30122128.

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This article examines the implementation and impact of Event-Driven Architecture (EDA) in real-time inventory management systems for e-commerce platforms. The article explores how EDA transforms traditional inventory management through its core components: event producers, event routers, and event consumers. The article analyzes the architectural design considerations, implementation strategies, and integration patterns necessary for successful deployment. It demonstrates how EDA enables improved system scalability, reduced latency, enhanced data consistency, and better operational efficiency

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17

Ma, X. Y., B. Wang, and E. J. Gao. "SYNTHESIS, STRUCTURE AND ELECTROCHEMICAL PROPERTIES OF COPPER(II) COMPLEX WITH 3-PHENYLPROPYLMALONIC ACID." Журнал структурной химии 65, no. 5 (2024): 127050. http://dx.doi.org/10.26902/jsc_id127050.

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A 0D Cu-based complex {[(Complex 1, Complex 1 = Cu(L)2(EDA)2]n, L = 3-phenylpropylmalonic acid, EDA = ethylenediamine) was synthesized by solvent-thermal synthesis using 3-phenylpropylmalonic acid as the ligands. It is characterized and analyzed by PXRD, infrared spectrum, ultraviolet diffuse reflection spectrum and other means. Complex 1 is crystallized in triclinic crystal system with space group P-1, and each Cu2+ was coordinated with two ligands and a water molecule, respectively. Cyclic voltammogram curve of Complex 1 modified electrode (1+CPE) was tested in the PBS buffer solution (pH =

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18

Chen, Wei. "Design and Improvement of Digital Communication System Based on EDA Platform." Journal of Physics: Conference Series 2396, no. 1 (2022): 012052. http://dx.doi.org/10.1088/1742-6596/2396/1/012052.

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Abstract The design of digital circuit systems based on EDA tools can greatly improve design efficiency. In this paper, a multi-mode communication signal modulation and demodulation system are designed with FPGA as the hardware carrier. Furthermore, this paper puts forward a teaching and experimental scheme of communication circuits, that is, using the EDA platform to realize different modulation and demodulation modes. The advantage of this scheme is that it can not only be realized in hardware, but also can analyze the performance accurately and that the waveform is intuitive. This scheme ca

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19

Ghosh, Soumen, Gautam Kumar, Naveen Naveen, Suman Pradhan, and Indranil Chatterjee. "EDA complex directed N-centred radical generation from nitrosoarenes: a divergent synthetic approach." Chemical Communications 55, no. 90 (2019): 13590–93. http://dx.doi.org/10.1039/c9cc07277b.

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20

Lim, B. T., S. Okajima, and E. C. Lim. "Spectroscopic and dynamical differences between exciplex and electronically excited EDA complex." Journal of Chemical Physics 84, no. 3 (1986): 1937–39. http://dx.doi.org/10.1063/1.450446.

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21

Sopov, E. "Hybrid binary GA-EDA algorithms for complex “black-box” optimization problems." IOP Conference Series: Materials Science and Engineering 173 (February 2017): 012019. http://dx.doi.org/10.1088/1757-899x/173/1/012019.

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22

Snyder, R., W. Trotter, and A. C. Testa. "Phosphorescence from an EDA complex with nitrobenzene as an electron donor." Journal of Luminescence 33, no. 3 (1985): 327–32. http://dx.doi.org/10.1016/0022-2313(85)90007-9.

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Pelzl, G., M. Novak, W. Weissflog, and D. Demus. "Binary systems with induced smectic phases due to EDA complex formation." Crystal Research and Technology 22, no. 8 (1987): K125—K128. http://dx.doi.org/10.1002/crat.2170220819.

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Koteswara Rao Yarlagadda. "Cross-platform integration using event-driven architecture." World Journal of Advanced Engineering Technology and Sciences 15, no. 1 (2025): 1292–99. https://doi.org/10.30574/wjaets.2025.15.1.0280.

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Event-driven architecture (EDA) has revolutionized cross-platform integration across multiple industries, transforming how organizations handle real-time data processing and system responsiveness. EDA implementations have demonstrated remarkable improvements in operational efficiency and service delivery, from telecommunications to financial services and healthcare to smart cities. The architecture enables seamless handling of complex event streams, allowing organizations to instantaneously process and respond to critical data points. EDA has enhanced network management and service provisionin

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Reid, Clodagh, Conor Keighrey, Niall Murray, Rónán Dunbar, and Jeffrey Buckley. "A Novel Mixed Methods Approach to Synthesize EDA Data with Behavioral Data to Gain Educational Insight." Sensors 20, no. 23 (2020): 6857. http://dx.doi.org/10.3390/s20236857.

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Whilst investigating student performance in design and arithmetic tasks, as well as during exams, electrodermal activity (EDA)-based sensors have been used in attempts to understand cognitive function and cognitive load. Limitations in the employed approaches include lack of capacity to mark events in the data, and to explain other variables relating to performance outcomes. This paper aims to address these limitations, and to support the utility of wearable EDA sensor technology in educational research settings. These aims are achieved through use of a bespoke time mapping software which iden

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Manabe, Ri-ichiroh, Naoko Oh-e, Toshinaga Maeda, Tomohiko Fukuda, and Kiyotoshi Sekiguchi. "Modulation of Cell-adhesive Activity of Fibronectin by the Alternatively Spliced EDA Segment." Journal of Cell Biology 139, no. 1 (1997): 295–307. http://dx.doi.org/10.1083/jcb.139.1.295.

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Fibronectin (FN) has a complex pattern of alternative splicing at the mRNA level. One of the alternatively spliced segments, EDA, is prominently expressed during biological processes involving substantial cell migration and proliferation, such as embryonic development, malignant transformation, and wound healing. To examine the function of the EDA segment, we overexpressed recombinant FN isoforms with or without EDA in CHO cells and compared their cell-adhesive activities using purified proteins. EDA+ FN was significantly more potent than EDA− FN in promoting cell spreading and cell migration,

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27

XING, LIUDONG. "RELIABILITY MODELING AND ANALYSIS OF COMPLEX HIERARCHICAL SYSTEMS." International Journal of Reliability, Quality and Safety Engineering 12, no. 06 (2005): 477–92. http://dx.doi.org/10.1142/s0218539305001963.

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In this paper we consider the problem of reliability modeling and analysis of hierarchical computer-based systems (HS) with modular imperfect coverage (MIPC) and common-cause failures (CCF). The MIPC and CCF can cause vertical dependence that runs through different levels of the system as well as horizontal dependence that runs across components or modules on the same system level. The consideration of these dependencies poses unique challenges to existing HS reliability analysis methods. We propose an efficient decomposition and aggregation approach named EDA-HS to the reliability evaluation

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28

Chu, Aixuan, Lay Hoon Ang, and Hazlina Abdul Halim. "Systematic Literature Review of Ecological Discourse Analysis From 2014 to 2023." Theory and Practice in Language Studies 14, no. 11 (2024): 3431–42. http://dx.doi.org/10.17507/tpls.1411.12.

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One of the crucial foci of contemporary linguistics is upon the complex human-nature relationship within the Anthropocene. An essential methodology of eco-linguistics is Ecological Discourse Analysis (EDA), a field which combines linguistics and ecology. The philosophical underpinning of EDA is rooted in an ecological thematic framework, emphasising the significance of biodiversity and sustainability in the natural world. Despite gaining attention over the past decade, EDA still lacks a comprehensive explanation to adequately and accurately explain the fundamental assertion of its philosophica

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Winter, Michael, Rüdiger Pryss, Thomas Probst, and Manfred Reichert. "Towards the Applicability of Measuring the Electrodermal Activity in the Context of Process Model Comprehension: Feasibility Study." Sensors 20, no. 16 (2020): 4561. http://dx.doi.org/10.3390/s20164561.

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Process model comprehension is essential in order to understand the five Ws (i.e., who, what, where, when, and why) pertaining to the processes of organizations. However, research in this context showed that a proper comprehension of process models often poses a challenge in practice. For this reason, a vast body of research exists studying the factors having an influence on process model comprehension. In order to point research towards a neuro-centric perspective in this context, the paper at hand evaluates the appropriateness of measuring the electrodermal activity (EDA) during the comprehe

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30

Zeng, Yining, Rongxing Duan, Shujuan Huang, and Tao Feng. "Reliability analysis for complex systems based on generalized stochastic petri nets and EDA approach considering common cause failure." Engineering Computations 37, no. 5 (2019): 1513–30. http://dx.doi.org/10.1108/ec-05-2019-0241.

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Purpose This paper aims to deal with the problems of failure dependence and common cause failure (CCF) that arise in reliability analysis of complex systems. Design/methodology/approach Firstly, a dynamic fault tree (DFT) is used to capture the dynamic failure behaviours and converted into an equivalent generalized stochastic petri net (GSPN) for quantitative analysis. Secondly, an efficient decomposition and aggregation (EDA) theory is combined with GSPN to deal with the CCF problem, which exists in redundant systems. Finally, Birnbaum importance measure (BIM) is calculated based on the EDA a

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31

Kumar, Vikash, and Shideh Mehr. "Enhancing Electronic Design Automation Tools with an ML-Based Information Retrieval System." International Journal of Intelligent Information Systems 13, no. 3 (2024): 53–58. http://dx.doi.org/10.11648/j.ijiis.20241303.12.

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Over the past fifty years, Electronic Design Automation (EDA) tools have played a crucial role in the semiconductor industry, assisting in the design, simulation, and manufacturing of integrated circuits (ICs). However, the sophisticated nature of these tools often demands extensive expertise, which can be a barrier for many users. Mastery of these tools necessitates specialized knowledge and skills, including comprehension of complex algorithms, design methodologies, and tool-specific workflows. To address this challenge, this paper introduces a machine learning (ML) based information retriev

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Liang, Xin, Yufei Li, Qing Xia, et al. "Visible-light-driven electron donor–acceptor complex induced sulfonylation of diazonium salts with sulfinates." Green Chemistry 23, no. 22 (2021): 8865–70. http://dx.doi.org/10.1039/d1gc03239a.

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Tian, Zeyu. "Introduction to machine leaning in electronic design automation (EDA)." Applied and Computational Engineering 6, no. 1 (2023): 520–26. http://dx.doi.org/10.54254/2755-2721/6/20230849.

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The rapid growth of the intergraded circuit industry as predicted by Moores law has significantly increased the importance of efficient design processes. In addition, due to physical constraint, we will soon reach the limit of how small the size of the transistor can become, and the design processes will become more complex than ever. In order to cope with those challenges and introduce the product to the market within the time to market, the industry has been developing ways to apply machine learning to concurrent EDA tools. This paper will aim to introduce how machine learning is applied to

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Zhou, Zhuoyi, Yufeng Zhang, Zhiqiang Yu, et al. "Visible-Light-Mediated Synthesis of Anomeric S-Aryl Glycosides via Electron Donor–Acceptor Complex Using Thianthrenium Salts." Molecules 30, no. 6 (2025): 1315. https://doi.org/10.3390/molecules30061315.

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S-Aryl glycosides are not only popular glycosyl donors in carbohydrate chemistry but also serve as valuable tools in various biological studies, which has brought significant attention to their preparation. However, there remains a pressing need for greener synthesis methods in this area. In response, a mild, sustainable, and metal- and photocatalyst-free electron donor–acceptor (EDA)-mediated approach for synthesizing S-Aryl glycosides using 1-thiosugar and aryl thianthrenium salt was developed. Our strategy utilizes 1-thiosugar as the donor, overcoming the traditional reliance on electron-ri

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35

Gilbert, Audrey, Mélodie Birepinte, and Jean-François Paquin. "Electron donor-acceptor (EDA)-complex enabled SF5Cl addition on alkenes and alkynes." Journal of Fluorine Chemistry 243 (March 2021): 109734. http://dx.doi.org/10.1016/j.jfluchem.2021.109734.

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Leyva, Elisa, Agobardo Cárdenas-Chaparro, Silvia E. Loredo-Carrillo, Lluvia I. López, Fernanda Méndez-Sánchez, and Antonio Martínez-Richa. "Ultrasound-assisted reaction of 1,4-naphthoquinone with anilines through an EDA complex." Molecular Diversity 22, no. 2 (2018): 281–90. http://dx.doi.org/10.1007/s11030-018-9820-9.

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Kijeński, Jacek, and Ryszard Hombek. "Step by Step Modeling of Superbasic Catalysts of the EDA Complex Type." Journal of Catalysis 167, no. 2 (1997): 503–12. http://dx.doi.org/10.1006/jcat.1997.1561.

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Visnovcova, Zuzana, Marek Kozar, Zuzana Kuderava, Mirko Zibolen, Nikola Ferencova, and Ingrid Tonhajzerova. "Entropy Analysis of Neonatal Electrodermal Activity during the First Three Days after Birth." Entropy 24, no. 3 (2022): 422. http://dx.doi.org/10.3390/e24030422.

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The entropy-based parameters determined from the electrodermal activity (EDA) biosignal evaluate the complexity within the activity of the sympathetic cholinergic system. We focused on the evaluation of the complex sympathetic cholinergic regulation by assessing EDA using conventional indices (skin conductance level (SCL), non-specific skin conductance responses, spectral EDA indices), and entropy-based parameters (approximate, sample, fuzzy, permutation, Shannon, and symbolic information entropies) in newborns during the first three days of postnatal life. The studied group consisted of 50 he

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Li, Wuke, Xiaoxiao Chen, and Hector Chimeremeze Okere. "MSAO-EDA: A Modified Snow Ablation Optimizer by Hybridizing with Estimation of Distribution Algorithm." Biomimetics 9, no. 10 (2024): 603. http://dx.doi.org/10.3390/biomimetics9100603.

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Metaheuristic algorithms provide reliable and effective methods for solving challenging optimization problems. The snow ablation algorithm (SAO) performs favorably as a physics-based metaheuristic algorithm. Nevertheless, SAO has some shortcomings. SAO is overpowered in its exploitation, has difficulty in balancing the proportion of global and local search, and is prone to encountering local optimum traps when confronted with complex problems. To improve the capability of SAO, this paper proposes a modified snow ablation algorithm hybrid distribution estimation algorithm named MSAO-EDA. In thi

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Manatkar, Abhijit, Ashlesha Akella, Krishnasuri Narayanam, and Sameep Mehta. "Question-guided Insights Generation for Automated Exploratory Data Analysis." Proceedings of the AAAI Conference on Artificial Intelligence 39, no. 28 (2025): 29664–66. https://doi.org/10.1609/aaai.v39i28.35360.

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Exploratory Data Analysis (EDA) derives meaningful insights from extensive and complex datasets. This process typically involves a series of analytical operations to identify the patterns within the data. However, the effectiveness of EDA is often limited by the user's domain knowledge and proficiency in data exploration methods. To overcome these challenges, we developed QUIS, a fully automated EDA system that uncovers insights by generating data-related questions and exploring subspaces in the dataset without prior training. QUIS allows users to control key system parameters such as beam wid

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Biasutti, M. A., and Juana J. Silber. "Interaction between tetracyanoethylene and naphthalene in reverse micelles of AOT in n-hexane. The electron-donor properties of AOT." Canadian Journal of Chemistry 74, no. 9 (1996): 1603–8. http://dx.doi.org/10.1139/v96-177.

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The electron donor–acceptor (EDA) interaction between TCNE and naphthalene (Naph) in n-hexane and reverse micelles of AOT in n-hexane was studied by UV–visible spectroscopy with the aim of determining the influence of the micellar media on the EDA interaction. The spectra of the mixtures of TCNE–Naph in n-hexane show two typical maxima at 418 and 534 nm, assigned to the formation of a π–π EDA complex. In the micellar media a new band is observed at 398 nm. When the spectra of TCNE in n-hexane are studied in the presence of AOT two new bands at 398 and 418 nm are detected. These bands are consi

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Shabani, Mozhdeh, Reza Ghiasi, Karim Zare, and Reza Fazaeli. "The interaction between carboplatin anticancer drug and B12N12 nano-cluster: A computational investigation." Main Group Chemistry, July 29, 2021, 1–10. http://dx.doi.org/10.3233/mgc-210051.

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This study investigated the interaction between B12N12 nano-cluster and carboplatin complex using B3P86 functional. Two interaction modes between B12N12 nano-cluster and carboplatin complex were considered. The bonding interaction between the B12N12 nano-cluster and carboplatin complex was examined through energy decomposition analysis (EDA). Also, Shubin Liu’s energy decomposition analysis (EDA-SBL) is used to study the source of energy differences between various isomers of B12N12 ... carboplatin complex. Charge transfer between fragments were illustrated with electrophilicity-based charge t

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Costa, Rodrigo, Gabriel M. F. Batista, Timothy J. Brocksom, and Kleber de Oliveira. "Discovery of EDA‐Complex Photochemical Reactions Using Computational Vision." Advanced Synthesis & Catalysis, October 29, 2024. http://dx.doi.org/10.1002/adsc.202401045.

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Herein, we report a multidimensional screening strategy to discover Electron Donor‐Acceptor (EDA) complex photochemical reactions using only simple photographic devices, such as webcams or cellphones, combined with TLC analysis. An algorithm was designed to automatically identify EDA‐complex reactive mixtures in solution by processing digital images from a 96‐well microplate, alongside TLC results. The code detects the absorption region of the mixture in the visible spectrum and quantifies color changes through grayscale values. Integrated automatic TLC analysis further classifies mixtures as

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Stevenson, Bernard G., Amanada V. Prascsak, Annemarie A. Lee, Eric D. Talbott, Lisa A. Fredin, and John R. Swierk. "Enhanced basicity of an electron donor–acceptor complex." Chemical Communications, 2023. http://dx.doi.org/10.1039/d2cc05985a.

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Li, Yufei, Jie Hou, Pei Zhang, et al. "Electron Donor‐Acceptor Complex Driven Photocatalyst‐Free Trifluoromethylation of Heterocycles." Chemistry – A European Journal, March 31, 2024. http://dx.doi.org/10.1002/chem.202400237.

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Heterocyclic trifluoromethylation is efficiently initiated through a photochemical reaction utilizing an electron donor–acceptor (EDA) complex, proceeding smoothly without the use of photocatalysts, transition‐metal catalysts, or additional oxidants. This method has been optimized through extensive experimentation, demonstrating its versatility and efficacy across various substrates, including quinoxalinones, coumarins, and indolones. Notably, this approach enables the practical synthesis of trifluoromethylated quinoxalinones on a gram scale. Mechanistic investigations that incorporate radical

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Huang, Lei, Chaodong Wang, Zhi Chen, et al. "Photoinduced EDA Complex‐initiated Synthesis of Fluoroalkylated Isoquinolinonediones." Chemistry – A European Journal, November 6, 2024. http://dx.doi.org/10.1002/chem.202403286.

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A visible‐light‐induced radical tandem difluoroalkylation/cyclization to construct CF2‐containing isoquinolinonedione skeletons with methacryloyl benzamides is developed. Broad substrate scopes are compatible with metal‐, oxidant‐ and photocatalyst‐free conditions under room temperature in good‐to‐excellent yields. Mechanistic analysis revealed that the transformation is initiated by photoinduced electron donor‐acceptor (EDA) complexes formation.

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Yan, Tingtao, Jianjing Yang, Kelu Yan, Zhonglei Wang, Bingwen Li, and Jiangwei Wen. "A General Photoactive H‐Bonding EDA Complex Model Drives the Selective Hydrothiolation and Hydroxysulfenylation of Carbonyl Activated Alkenes." Angewandte Chemie, July 2, 2024. http://dx.doi.org/10.1002/ange.202405186.

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Excitation of photoactive electron donor−acceptor (EDA) complexes to generate radical is a promising approach in radical chemistry. In this study, we introduce a new model of H‐bonding EDA complexes for the selective hydrothiolation and hydroxysulfenylation of carbonyl‐activated alkenes with diverse thiols under visible light conditions. The reliability of this H‐bonding EDA complex model has been confirmed by meticulous experimental and theoretical calculations. Mechanistic investigations have revealed the significant influence of the solvent in determining whether the excitation of photoacti

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Yan, Tingtao, Jianjing Yang, Kelu Yan, Zhonglei Wang, Bingwen Li, and Jiangwei Wen. "A General Photoactive H‐Bonding EDA Complex Model Drives the Selective Hydrothiolation and Hydroxysulfenylation of Carbonyl Activated Alkenes." Angewandte Chemie International Edition, July 2, 2024. http://dx.doi.org/10.1002/anie.202405186.

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Excitation of photoactive electron donor−acceptor (EDA) complexes to generate radical is a promising approach in radical chemistry. In this study, we introduce a new model of H‐bonding EDA complexes for the selective hydrothiolation and hydroxysulfenylation of carbonyl‐activated alkenes with diverse thiols under visible light conditions. The reliability of this H‐bonding EDA complex model has been confirmed by meticulous experimental and theoretical calculations. Mechanistic investigations have revealed the significant influence of the solvent in determining whether the excitation of photoacti

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Kürschner, Julian, Martin Utikal, Lena Lezius, Rubaishan Jeyaseelan, and Line Dahl Næsborg. "EDA complexation of two donor molecules initiating radical cation cyclizations." Synthesis, January 16, 2025. https://doi.org/10.1055/a-2518-0987.

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We present a catalyst-free EDA complexation of two donor molecules using an acidic solvent. The electron-rich aromatic compound E-anethole is slowly protonated by the solvent hexafluoroisopropanol (HFIP), leading to the rapid formation of a photoactive EDA complex between a protonated E-anethole and another E-anethole molecule. This resulting EDA complex initiates radical chain cyclization reactions under green light irradiation.

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Paul, Aditya, Arunava Sengupta, and Somnath Yadav. "Visible-Light Driven Acetoxylation and Dioxygenation of Indoles via Electron Donor-Acceptor Complexes." Chemical Communications, 2023. http://dx.doi.org/10.1039/d3cc01683h.

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A photoresponsive electron donor-acceptor (EDA) complex, formed by indole and hypervalent iodine such as diacetoxyiodobenzene (DAIB/PIDA, etc.) was detectable through absorption and emission spectroscopy. Irradiation of the EDA complex with...

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