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Artykuły w czasopismach na temat "Free radicals (Chemistry)"

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Ionita, Petre. "The Chemistry of DPPH· Free Radical and Congeners." International Journal of Molecular Sciences 22, no. 4 (February 3, 2021): 1545. http://dx.doi.org/10.3390/ijms22041545.

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Since the discovery in 1922 of 2,2-diphenyl-1-(2,4,6-trinitrophenyl) hydrazyl stable free radical (DPPH·), the chemistry of such open-shell compounds has developed continuously, allowing for both theoretical and practical advances in the free radical chemistry area. This review presents the important, general and modern aspects of the chemistry of hydrazyl free radicals and the science behind it.
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Nagendrappa, G. "An appreciation of free radical chemistry Part 4. Free radicals in atmospheric chemistry." Resonance 10, no. 7 (July 2005): 61–72. http://dx.doi.org/10.1007/bf02867108.

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Nagendrappa, G. "An appreciation of free radical chemistry 6. Experiments involving free radicals." Resonance 10, no. 9 (September 2005): 79–84. http://dx.doi.org/10.1007/bf02896323.

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[Sbreve]imkovic, Ivan. "FREE RADICALS IN WOOD CHEMISTRY." Journal of Macromolecular Science, Part C: Polymer Reviews 26, no. 1 (February 1986): 67–80. http://dx.doi.org/10.1080/07366578608081969.

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Halliwell, Barry. "The Chemistry of Free Radicals." Toxicology and Industrial Health 9, no. 1-2 (January 1993): 1–21. http://dx.doi.org/10.1177/0748233793009001-203.

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Pryor, W. A. "Free radicals in organic chemistry." Free Radical Biology and Medicine 21, no. 2 (January 1996): 253–54. http://dx.doi.org/10.1016/0891-5849(96)90038-6.

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Murphy, John A. "Free radicals in synthesis. Clean reagents affording oxidative or reductive termination." Pure and Applied Chemistry 72, no. 7 (January 1, 2000): 1327–34. http://dx.doi.org/10.1351/pac200072071327.

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Neurotoxic organotin reagents currently play a key role in radical chemistry. As a result, this is an important area for development of new clean replacement reactions. The pharmaceutical industry in particular has had to avoid use of radical methodology for the formation of carbon_carbon bonds for this reason. With the current dawn in green chemistry, a host of new clean radical methods is beginning to flourish. Our aim has been to develop new nontoxic methodology for carbon_carbon bond formation by radical chemistry, which would provide either reductive termination (giving a hydrogen atom to
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Lemaire, M. T. "Recent developments in the coordination chemistry of stable free radicals." Pure and Applied Chemistry 76, no. 2 (January 1, 2004): 277–93. http://dx.doi.org/10.1351/pac200476020277.

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Several advances in the coordination chemistry of stable free-radical species over the past six years are documented in this review article. Specifically, a number of recent reports focused on the coordination chemistry of chelating nitroxide ligands are highlighted, with an emphasis on enhanced magnetic or optical properties in these complexes. Furthermore, very intriguing recent magnetic and optical studies with one-dimensional nitroxide chain complexes (new "Glauber" chains and chiral magnets) are also discussed. The verdazyls are another family of stable radicals whose coordination chemist
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Yañez Jaramillo, Lina M., Joy H. Tannous, and Arno de Klerk. "Persistent Free Radicals in Petroleum." Processes 11, no. 7 (July 11, 2023): 2067. http://dx.doi.org/10.3390/pr11072067.

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The persistent free radical content in petroleum is of the order 1018 spins/g (1 μmol/g), with higher and lower values found depending on origin and in different distillation fractions. The field of persistent free radicals in petroleum was reviewed with the aim of addressing and explaining apparent inconsistencies between free radical persistence and reactivity. The macroscopic average free radical concentration in petroleum is persistent over geological time, but individual free radical species in petroleum are short-lived and reactive. The persistent free radical concentration in petroleum
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Van Lente, Frederick. "Free Radicals." Analytical Chemistry 65, no. 12 (June 15, 1993): 374–77. http://dx.doi.org/10.1021/ac00060a601.

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Rozprawy doktorskie na temat "Free radicals (Chemistry)"

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Qureshi, Tariq. "Spin chemistry." Thesis, University of Oxford, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.365292.

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Mills, Tim. "Studies in free radical chemistry." Thesis, University of Nottingham, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.342465.

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Imrie, Christopher. "The chemistry of free radicals containing a ferrocenyl moiety." Thesis, University of Strathclyde, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.390393.

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梁韻詩 and Wan-sze Leung. "High resolution spectroscopy of free radicals." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1998. http://hub.hku.hk/bib/B31237319.

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Leung, Wan-sze. "High resolution spectroscopy of free radicals /." Hong Kong : University of Hong Kong, 1998. http://sunzi.lib.hku.hk/hkuto/record.jsp?B19737610.

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Crockett, Rowena. "Generation of free radicals from heterocyclic compounds." Thesis, University of Aberdeen, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.290239.

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Tetrazolinones, thiatriazole 1-oxides and meso-ionic oxatriazoles were investigated as sources of free radicals. Mono-substituted tetrazolinones decomposed at their melting points. Nitrosation and nitration of the tetrazolinone ring was unsuccessful, although alkoxyalkylation of the ring took place in ether in the presence of nitrosomium and nitronium tetrafluoroborate. The tetrazolinone ring was photolytically unstable, and both eliminated nitrogen and cycloreverted. γ-irradiation of the naphthyl deivative caused cleavage of the nitrogen-hydrogen bond to give a radical which was identified by
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Robles, Eric San Jose. "Electronic spectroscopy of jet-cooled organometallic free radicals /." The Ohio State University, 1992. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487776801323524.

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Towle, Jonathan Peter. "The LMR spectra of free radicals." Thesis, University of Oxford, 1992. http://ora.ox.ac.uk/objects/uuid:7ac8e9e4-33e8-428b-962d-943bf07d5f94.

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Laser Magnetic Resonance (LMR) is a very sensitive, accurate and high resolution spectroscopic technique. Transitions of paramagnetic species are brought into coincidence with a fixed frequency laser using Zeeman tuning. Three different LMR spectrometers are described, two of which use the CO laser as a radiation source and the other used optically pumped far-infrared lasers. These LMR spectrometers have been used to study four radicals, germanium hydride (GeH), tellurium deuteride (TeD), iron hydride (FeH) and iron deuteride (FeD). Transitions in the fundamental and first hot bands of the GeH
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Hon, Nyok-Sai. "Formation, characterization, and chemical reactions of free radicals in lignin." Diss., Virginia Polytechnic Institute and State University, 1985. http://hdl.handle.net/10919/54437.

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Free radicals are produced in lignin during mechanical treatment and irradiation with light of various wavelengths. During mechanical treatment, the lignin macromolecule is degraded severely as revealed by ESR and viscosity measurements. Several types of mechano-radicals are produced in lignin during the mechanical process. Among these the phenoxy radicals are rather stable, where carbon-radicals are labile at ambient conditions. Transient mechano-radicals reacted readily with oxygen molecules to produce peroxy radicals even at 77°K, but they decayed rapidly at ambient temperature. Photodegr
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Wood, Geoffrey Paul Farra. "Theoretical Investigations of Radical-Mediated Protein Oxidation." Thesis, The University of Sydney, 2006. http://hdl.handle.net/2123/1413.

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This thesis primarily details the application of high-level ab initio quantum chemistry techniques in order to understand aspects of free-radical mediated protein oxidation. Traditionally, product analysis and electron paramagnetic resonance (EPR) spectroscopy are the primary means for elucidating the chemistry of protein oxidation. However, in experiments involving relatively small proteins reacting with a controlled radical-flux, a vast array of compounds can be produced, which are often difficult to analyse. Quantum chemical techniques on the other hand, can calculate the properties of any
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Książki na temat "Free radicals (Chemistry)"

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Perkins, M. John. Radical chemistry. New York: Ellis Horwood, 1994.

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Walling, Cheves. Fifty years of free radicals. Washington, DC: American Chemical Society, 1995.

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Paulauskas, Irena O. Radical polymerization: New developments. Hauppauge, N.Y: Nova Science Publishers, 2011.

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A, Lund, and Rhodes Christopher J, eds. Radicals on surfaces. Dordrecht: Kluwer Academic Publishers, 1995.

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Francesco, Minisci, North Atlantic Treaty Organization. Scientific Affairs Division., and NATO Advanced Research Workshop on Free Radicals in Biology and Environment (1996 : Bardolino, Italy), eds. Free radicals in biology and environment. Dordrecht: Kluwer, 1997.

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Leffler, John E. An introduction to free radicals. New York: Wiley, 1993.

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Postigo, J. Alberto. Organic radical reactions in water and alternative media. Hauppauge, N.Y: Nova Science Publishers, 2011.

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A, Punchard Neville, and Kelly Frank J, eds. Free radicals: A practical approach. Oxford: IRL Press at Oxford University Press, 1996.

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P, Yu Byung, ed. Free radicals in aging. Boca Raton: CRC Press, 1993.

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Catherine, Rice-Evans, ed. Free radicals: Chemistry, pathology and medicine. London: Richelieu Press, 1988.

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Części książek na temat "Free radicals (Chemistry)"

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Dolbier, William R. "Fluorinated free radicals." In Organofluorine Chemistry, 97–163. Berlin, Heidelberg: Springer Berlin Heidelberg, 1997. http://dx.doi.org/10.1007/bfb0119266.

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Lappert, M. F. "Aspects of Organometallic Free Radical Chemistry." In Organic Free Radicals, 101–2. Berlin, Heidelberg: Springer Berlin Heidelberg, 1988. http://dx.doi.org/10.1007/978-3-642-73963-7_50.

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Scaiano, J. C. "Two Photon Processes in Free Radical Chemistry." In Organic Free Radicals, 183–84. Berlin, Heidelberg: Springer Berlin Heidelberg, 1988. http://dx.doi.org/10.1007/978-3-642-73963-7_91.

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de Montellano, Paul R. Ortiz. "Free Radicals in the Catalytic Chemistry of Hemoproteins." In Organic Free Radicals, 151. Berlin, Heidelberg: Springer Berlin Heidelberg, 1988. http://dx.doi.org/10.1007/978-3-642-73963-7_75.

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Baumann, U., and M. Schmittel. "Solution Chemistry of Keto and Enol Cation Radicals." In Organic Free Radicals, 189. Berlin, Heidelberg: Springer Berlin Heidelberg, 1988. http://dx.doi.org/10.1007/978-3-642-73963-7_94.

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Mattay, J. "Radical Ions and Photochemical Charge Transfer Phenomena in Organic Chemistry." In Organic Free Radicals, 119–20. Berlin, Heidelberg: Springer Berlin Heidelberg, 1988. http://dx.doi.org/10.1007/978-3-642-73963-7_59.

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Niki, Etsuo. "Free Radicals in Chemistry and Biochemistry." In Food and Free Radicals, 1–10. Boston, MA: Springer US, 1997. http://dx.doi.org/10.1007/978-1-4899-1837-6_1.

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Joseph, Jomy, and Andrey P. Antonchick. "Free Radicals in Heterocycle Functionalization." In Topics in Heterocyclic Chemistry, 93–149. Cham: Springer International Publishing, 2017. http://dx.doi.org/10.1007/7081_2017_8.

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Stein, Stephen E. "Free Radicals in Coal Conversion." In Chemistry of Coal Conversion, 13–44. Boston, MA: Springer US, 1985. http://dx.doi.org/10.1007/978-1-4899-3632-5_2.

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Platt, U., B. Alicke, R. Dubois, A. Geyer, A. Hofzumahaus, F. Holland, M. Martinez, et al. "Free Radicals and Fast Photochemistry during BERLIOZ." In Tropospheric Chemistry, 359–94. Dordrecht: Springer Netherlands, 2002. http://dx.doi.org/10.1007/978-94-010-0399-5_15.

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Streszczenia konferencji na temat "Free radicals (Chemistry)"

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Pfaendtner, Jim, Linda J. Broadbelt, and Q. Jane Wang. "Quantum Chemical Studies of Free-Radical, Hindered Phenol Stabilizers." In World Tribology Congress III. ASMEDC, 2005. http://dx.doi.org/10.1115/wtc2005-64007.

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Quantum chemical investigations of the action of hindered phenol radical stabilizers in lubricant degradation chemistry have been completed. We are currently developing the first mechanistic models of lubricant degradation with the aim of including the chemistry of additives such as radical stabilizers that are found in commercial lubricant formulations. A key component of development of these models is obtaining reliable estimates of the kinetic parameters for all reactions. Specifically, rate constants and structure-reactivity correlations for the interaction of hindered phenol radical stabi
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Hudgens, Jeffrey W., and David S. Green. "Degenerate Four Wave Mixing Spectroscopy of Free Radicals in Low-Pressure Plasmas." In Modern Spectroscopy of Solids, Liquids, and Gases. Washington, D.C.: Optica Publishing Group, 1995. http://dx.doi.org/10.1364/msslg.1995.ssab2.

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Four wave mixing spectroscopies offer new ways to measure chemical species in extremely hostile environments. Among the most demanding of these applications is the measurement of radical chemistry within plasmas. Most plasmas are highly luminous and are characterized by steep gradients in temperature and concentration. These hostile properties thwart fluorescence and absorption diagnostics. In addition, in many useful plasma reactors the electrodes and associated electronics impose cumbersome optical geometries. We are using degenerate four-wave mixing (DFWM) spectroscopy to sidestep these imp
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Moore, C. B., R. G. Bergman, I.-C. Chen, D. C. Darwin, H. S. Johnston, Y. Guo, E. P. Wasserman, and A. T. Young. "Infrared flash kinetic spectroscopy of free radicals." In OSA Annual Meeting. Washington, D.C.: Optica Publishing Group, 1988. http://dx.doi.org/10.1364/oam.1988.thr1.

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Two IR flash kinetic spectrometers are described. Both use nanosecond pulsed UV lasers to produce high concentrations of reactive species. These are then probed by tunable cw IR lasers. High-resolution spectra of singlet and triplet states of CH2 and of HCO are presented. Measurements of reaction rates and of product quantum yields are described for several reactions important in atmospheric and combustion chemistry with particular emphasis on the dynamics of radical-radical reactions. The reactivity of the coordinatively unsaturated organometallic intermediate cyclopentadienylcobaltmonocarbon
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Gámez-Montaño, Rocío, Pedro A. Cano, and Alejandro Islas-Jácome. "Synthesis of spiro-cyclohexendienone-gamma-lactams via free-radicals and study of thermal regioselective spirocyclization." In The 21st International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2017. http://dx.doi.org/10.3390/ecsoc-21-04779.

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Mulyani, Hani, Yati Maryati, Euis Filailla, Agustine Susilowati, Puspa D. N. Lotulung, and Aspiyanto Aspiyanto. "Benefits of fermented beet (Beta vulgaris L.) against digestive infection Escherichia coli and free radicals prevention." In PROCEEDINGS OF THE 5TH INTERNATIONAL SYMPOSIUM ON APPLIED CHEMISTRY 2019. AIP Publishing, 2019. http://dx.doi.org/10.1063/1.5134589.

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Wu, Hanqing. "Organic and Drug Molecules Spin Traps and Free Radicals Multi-frequency EPR Spectra Simulation by Fast Fourier Transform (FFT)." In The 1st International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 1997. http://dx.doi.org/10.3390/ecsoc-1-02058.

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Wylde, Jonathan J. "The Challenges Associated with Reaction Products Left in Scale Inhibitor Species after Radical Polymerization." In SPE International Oilfield Scale Conference and Exhibition. SPE, 2014. http://dx.doi.org/10.2118/spe-169778-ms.

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Abstract The use of polymeric scale inhibitors has been ubiquitously accepted by the oil and gas industry for many years. There are many benefits to the use of this type of chemistry that include aspects such as high performance, scale species selectivity, enhanced brine compatibility, favorable environmental properties and high thermal stability. A very common way to manufacture polymeric scale inhibitors is via free radical polymerization. Here an initiator is used to propagate the generation of free radicals from a species, such as hydrogen peroxide. The initiator chemistry can be very vari
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Werle, Peter. "Fast sub-ppb Trace Gas Detection by Infrared Diode-Laser FM-Spectroscopy." In Modern Spectroscopy of Solids, Liquids, and Gases. Washington, D.C.: Optica Publishing Group, 1995. http://dx.doi.org/10.1364/msslg.1995.ssaa5.

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Sensitivity, specifity, high time resolution and cost effective simultaneous measurements of several components using operational systems are the main requirements for atmospheric research and air pollution monitoring1 Tunable diode lasers absorption spectroscopy (TDLAS) is increasingly being used to measure atmospheric trace gas concentrations down to low ppb-levels (10-9 volume mixing ratio). Semiconductor lead salt diode lasers give access to the mid infrared spectral region, where the most important atmospheric constituents have strong rotational vibrational absorption bands. The applicati
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Fackler, K. Boyd, Megan Karalus, Igor Novosselov, John Kramlich, and Philip Malte. "NOx Behavior for Lean-Premixed Combustion of Alternative Gaseous Fuels." In ASME Turbo Expo 2015: Turbine Technical Conference and Exposition. American Society of Mechanical Engineers, 2015. http://dx.doi.org/10.1115/gt2015-42069.

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Gaseous fuels other than pipeline natural gas are of interest in high-intensity premixed combustors (e.g., lean-premixed gas turbine combustors) as a means of broadening the range of potential fuel resources and increasing the utilization of alternative fuel gases. An area of key interest is the change in emissions that accompanies the replacement of a fuel. The work reported here is an experimental and modeling effort aimed at determining the changes in NOx emission that accompany the use of alternative fuels. Controlling oxides of nitrogen (NOx) from combustion sources is essential in non-at
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Lulan, Theodore Y. K., Sri Fatmawati, Mardi Santoso, and Taslim Ersam. "Free radical scavenging activity of Artocarpus champeden extracts." In THE 3RD INTERNATIONAL SEMINAR ON CHEMISTRY: Green Chemistry and its Role for Sustainability. Author(s), 2018. http://dx.doi.org/10.1063/1.5082460.

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Raporty organizacyjne na temat "Free radicals (Chemistry)"

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Lampe, F. W. The free-radical and ion chemistry of volatile silanes, germanes and phosphines. Office of Scientific and Technical Information (OSTI), January 1990. http://dx.doi.org/10.2172/6290400.

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Lampe, F. W. The free-radical and ion chemistry of silanes, germanes, phosphines, and related compounds. Final report, 1965--1994. Office of Scientific and Technical Information (OSTI), December 1995. http://dx.doi.org/10.2172/135060.

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