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Artykuły w czasopismach na temat „H/D isotope separation”

Autor: Grafiati
Data publikacji: 4 czerwca 2021
Data aktualizacji: 1 lutego 2022

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1

Trequattrini, Francesco, Oriele Palumbo, Silvano Tosti, Alessia Santucci, and Annalisa Paolone. "Promising Isotope Effect in Pd77Ag23 for Hydrogen Separation." ChemEngineering 5, no. 3 (2021): 51. http://dx.doi.org/10.3390/chemengineering5030051.

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Pd–Ag alloys are largely used as hydrogen separation membranes and, as a consequence, the Pd–Ag–H system has been intensively studied. On the contrary, fewer information is available for the Pd–Ag–D system; thus, the aim of this work is to improve the knowledge of the isotope effect on the commercial Pd77Ag23 alloy, especially for temperature above 200 °C. In particular, deuterium absorption measurements are carried out in the Pd77Ag23 alloy in the temperature range between 79 and 400 °C and in the pressure range between 10−2 and 16 bar. In this exploited pressure (p) and composition (c) range
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2

Miljanic, Scepan, Aleksandar Maksic, and Zoran Lausevic. "Isotope effects in: a) Catalytic generation of hydrogen from sodium tetrahydridoborate and b) Oxidation of hydrogen in fuel cells." Chemical Industry and Chemical Engineering Quarterly 11, no. 3 (2005): 124–28. http://dx.doi.org/10.2298/ciceq0503124m.

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We have investigated deuterium/hydrogen (D/H) isotope effects a) during catalytic evolution of hydrogen gas from the water solution of sodium tetrahydridoborate (NaBH4), the sodium borohydride fueled hydrogen generator HGen-E, Fractal Carbon, with the carbon monolith supported platinum reactor was used; b) oxidation of hydrogen in a PEM-type fuel cell to produce electrical energy. We used the E-TEK membrane electrode assemblies with an active area of 4 cm2, assembled in a two fuel cell stack. Both processes are important as possible parts of an energy-hydrogen-energy cycle. Any transfer of ene
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3

Miljanić, Šćepan S., Aleksandar D. Maksić, Nebojša I. Potkonjak, and Milica P. Marčeta Kaninski. "Electrolytic D/H isotope separation efficiency and electrocatalytic activity of Mo–Pt intermetallic phases." Electrochemistry Communications 9, no. 9 (2007): 2179–84. http://dx.doi.org/10.1016/j.elecom.2007.05.017.

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4

Sarkar, S. K., A. K. Nayak, V. Parthasarathy, K. V. S. RamaRao, and J. P. Mittal. "Infrared multiphoton dissociation in focused laser beams: II. Application to T/D/H isotope separation." Infrared Physics 33, no. 6 (1992): 505–10. http://dx.doi.org/10.1016/0020-0891(92)90066-3.

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5

STOJIC, D., S. MILJANIC, T. GROZDIC, D. GOLOBOCANIN, S. SOVILI, and M. JAKSIC. "D/H isotope separation efficiency in water electrolysis. Improvement by in situ activation at different temperatures." International Journal of Hydrogen Energy 19, no. 7 (1994): 587–90. http://dx.doi.org/10.1016/0360-3199(94)90216-x.

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6

Fu, Jiashun, Hai-Dong Yu, Long Wu, Chenghui Zhang, Yong-Huan Yun, and Weimin Zhang. "Authentication of Geographical Origin in Hainan Partridge Tea (Mallotus obongifolius) by Stable Isotope and Targeted Metabolomics Combined with Chemometrics." Foods 10, no. 9 (2021): 2130. http://dx.doi.org/10.3390/foods10092130.

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Partridge tea (Mallotus oblongifolius (Miq.) Müll.Arg.) is a local characteristic tea in Hainan, the southernmost province of China, and the quality of partridge tea may be affected by the producing areas. In this study, stable isotope and targeted metabolomics combined chemometrics were used as potential tools for analyzing and identifying partridge tea from different origins. Elemental analysis—stable isotope ratio mass spectrometer and liquid chromatography-tandem mass spectrometrywas used to analyze the characteristics of C/N/O/H stable isotopes and 54 chemical components, including polyph
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7

Wardlaw, David M. "Reaction path Hamiltonian for the association reactions CH3 + H and CH3 + D." Canadian Journal of Chemistry 70, no. 7 (1992): 1897–904. http://dx.doi.org/10.1139/v92-237.

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Coupling coefficients and normal mode frequencies appearing in the reaction path Hamiltonian formulated by Miller, Handy, and Adams have been calculated for the title reactions as a function of distance along the reaction path. The calculation of the coupling coefficients requires the use of symmetry coordinates which are described herein. It is found that the carbon–hydrogen separation provides an excellent representation of the reaction path coordinate, being linearly related to it. The coupling coefficients for CH3 + H and CH3 + D are approximately the same in the region of variational tran
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8

Dorset, Douglas L., and Robert G. Snyder. "H-D Isotope and Chain-Length Dependence of Phase Separation in Quenched n-Alkane Binary Combinations in the Crystalline State." Macromolecules 28, no. 24 (1995): 8412–18. http://dx.doi.org/10.1021/ma00128a061.

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9

Hu, Sheng, Liangping Xiong, Jingwei Hou, Kuiping Weng, Yangming Luo, and Tongzai Yang. "The roles of metals and their oxide species in hydrophobic Pt–Ru catalysts for the interphase H/D isotope separation." International Journal of Hydrogen Energy 35, no. 19 (2010): 10118–26. http://dx.doi.org/10.1016/j.ijhydene.2010.08.009.

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10

Stojic, D. "Electrochemical H/D isotope separation efficiencies on Ti–Ni intermetallic phases and alloys in relation to their hydridic and catalytic properties." International Journal of Hydrogen Energy 25, no. 9 (2000): 819–23. http://dx.doi.org/10.1016/s0360-3199(99)00106-8.

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11

Xing, Yanlong, Jinjun Cai, Liangjun Li, Menglong Yang, and Xuebo Zhao. "An exceptional kinetic quantum sieving separation effect of hydrogen isotopes on commercially available carbon molecular sieves." Phys. Chem. Chem. Phys. 16, no. 30 (2014): 15800–15805. http://dx.doi.org/10.1039/c4cp00709c.

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12

Ye, Linsen, Deli Luo, Wan Yang, Wensheng Guo, Qinying Xu, and Lizhu Luo. "Preparation and characterization of hydrophobic carbon-supported Pt3M (M = Fe, Co, Ni and Cr) bimetals for H/D isotope separation between hydrogen and water." International Journal of Hydrogen Energy 39, no. 25 (2014): 13793–99. http://dx.doi.org/10.1016/j.ijhydene.2014.04.029.

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13

Li, Peilong, Min Chen, Zexuan Zhang, et al. "Thermodynamics Study on Liquid Phase Catalytic Exchange for Water Detritiation." E3S Web of Conferences 299 (2021): 01007. http://dx.doi.org/10.1051/e3sconf/202129901007.

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Liquid phase catalytic exchange (LPCE) is one of the key technologies for tritium removal of tritiated water, such as effluents from Fukushima nuclear power plant. Although former researchers have widely studied this process theoretically, the reported results differ from each other due to different assumptions and parameters adopted. In this work, the principle of Gibbs free energy minimization is applied, with only basic physical properties and no more other assumptions involved. The predictions of isotope exchange are more accurate, and the average error between calculation results and expe
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14

Renger, G., HJ Eckert, A. Bergmann, et al. "Fluorescence and Spectroscopic Studies of Exciton Trapping and Electron Transfer in Photosystem II of Higher Plants." Functional Plant Biology 22, no. 2 (1995): 167. http://dx.doi.org/10.1071/pp9950167.

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Measurements of time-resolved fluorescence decay, laser-flash-induced absorption changes in the UV and at 820 nm and of the relative fluorescence quantum yield in different preparations (thylakoids, photosystem II (PSII) membrane fragments and PSII core complexes) from spinach led to a number of conclusions. (1) Light is transformed into Gibbs energy with trapping times of 250 ps and 130 ps in open reaction centres of PSII membrane fragments and PSII core complexes, respectively. Assuming rapid Boltzmann distribution of excitation energy and taking into account the antenna properties (size and
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15

Whalen, Joann K., Shamim Gul, Vincent Poirier, et al. "Transforming plant carbon into soil carbon: Process-level controls on carbon sequestration." Canadian Journal of Plant Science 94, no. 6 (2014): 1065–73. http://dx.doi.org/10.4141/cjps2013-145.

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Whalen, J. K., Gul, S., Poirier, V., Yanni, S. F., Simpson, M. J., Clemente, J. S., Feng, X., Grayston, S. J., Barker, J., Gregorich, E. G., Angers, D. A., Rochette, P. and Janzen, H. H. 2014. Transforming plant carbon into soil carbon: Process-level controls on carbon sequestration. Can. J. Plant Sci. 94: 1065–1073. Plants figure prominently in efforts to promote C sequestration in agricultural soils, and to mitigate greenhouse gas (GHG) emissions. The objective of the project was to measure the transformations of plant carbon in soil through controlled laboratory experiments, to further unde
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16

Li, Liang, Haotian Liu, Changbing Wang, et al. "Metallogeny of the Dagangou Au-Ag-Cu-Sb Deposit in the Eastern Kunlun Orogen, NW China: Constraints from Ore-Forming Fluid Geochemistry and S-H-O Isotopes." Geofluids 2021 (July 19, 2021): 1–26. http://dx.doi.org/10.1155/2021/1162498.

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A study of ore-forming fluid geochemistry and S-H-O isotopes has been conducted to reveal the metallogeny of the Dagangou Au-Ag-Cu-Sb deposit, NW China. Three mineralization stages are identified within Dagangou, including ankerite-quartz-pyrite (Ank-Qz-Py), quartz-Au-sulfide (Qz-Au-Sul), and quartz-calcite (Qz-Cal) stages. Four types of primary fluid inclusions (FIs) and various fluid inclusion assemblages (FIAs) are identified by petrographic observations, including pure CO2, CO2-bearing, vapour-liquid and halite-bearing FIs, most of which are distributed randomly or along growth zones. Rama
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17

Hu, Xiaoyu, Peilong Li, Xin Zhang, et al. "Ni-Based Catalyst Derived from NiAl Layered Double Hydroxide for Vapor Phase Catalytic Exchange between Hydrogen and Water." Nanomaterials 9, no. 12 (2019): 1688. http://dx.doi.org/10.3390/nano9121688.

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A high-efficient and low-cost catalyst on hydrogen isotope separation between hydrogen and water is an essential factor in industrial application for heavy water production and water detritiation. In past studies, Pt-based catalysts were developed but not practical for commercial use due to their high cost for vapor phase catalytic exchange (VPCE), while for impregnated nickel catalysts with a lower cost the problems of agglomeration and low Ni utilization existed. Therefore, to solve these problems, in-situ grown Ni-based catalysts (NiAl-LDO) derived from a layered double hydroxide (LDH) prec
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18

Oganessian, Yuri. "Synthesis and decay properties of superheavy elements." Pure and Applied Chemistry 78, no. 5 (2006): 889–904. http://dx.doi.org/10.1351/pac200678050889.

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A fundamental outcome of modern nuclear theory is the prediction of the "island of stability" in the region of hypothetical superheavy elements. A significant enhancement in nuclear stability at approaching the closed shells with Z = 114 (possibly 120 and 122) and N = 184 is expected for the nuclei with large neutron excess. For this reason, for the synthesis of nuclei with Z = 112-116 and 118, we chose the reactions 238U, 242,244Pu, 243Am, 245,248Cm, and 249Cf + 48Ca, which are characterized by fusion products with a maximal neutron excess. The formation and decay properties of the heaviest n
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19

Sobczyk, Lucjan, Monika Obrzud, and Aleksander Filarowski. "H/D Isotope Effects in Hydrogen Bonded Systems." Molecules 18, no. 4 (2013): 4467–76. http://dx.doi.org/10.3390/molecules18044467.

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20

Jungblut, B., and G. Sicking. "The H — D Isotope Exchange Reaction on ZrMn2Hx*." Zeitschrift für Physikalische Chemie 164, Part_2 (1989): 1177–84. http://dx.doi.org/10.1524/zpch.1989.164.part_2.1177.

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21

Nakano, Ryo, Hisashi Honda, Taiki Kimura, et al. "Anomalous H/D Isotope Effect on35Cl NQR Frequencies and H/D Isotope Effect on1H MAS NMR Spectra in Pyrrolidiniump-Chlorobenzoate." Bulletin of the Chemical Society of Japan 83, no. 9 (2010): 1019–29. http://dx.doi.org/10.1246/bcsj.20090300.

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22

Lynch, Gillian C., Donald G. Truhlar, Franklin B. Brown, and Jian-guo Zhao. "Kinetic isotope studies of the gas-phase reaction (H,D,Mu)+HBr→(H,D,Mu)H+Br." Hyperfine Interactions 87, no. 1 (1994): 885–98. http://dx.doi.org/10.1007/bf02068479.

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23

Lutz, H. D., and H. Möller. "H/D isotope enrichment effects in partially deuterated hydrates SrCl2·2(H,D)2)O and BaCl2·(H,D)2O." Journal of Molecular Structure 295 (May 1993): 147–53. http://dx.doi.org/10.1016/0022-2860(93)85016-n.

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24

Leblond, T., V. Paul-Boncour, and M. Guillot. "Large (H,D) isotope effect on the metamagnetic transition in Y0.9R0.1Fe2(H,D)4.3 compounds." Journal of Applied Physics 99, no. 8 (2006): 08F505. http://dx.doi.org/10.1063/1.2172204.

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25

Bonanos, N., A. Huijser, and F. W. Poulsen. "H/D isotope effects in high temperature proton conductors." Solid State Ionics 275 (July 2015): 9–13. http://dx.doi.org/10.1016/j.ssi.2015.03.028.

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26

Chakoumakos, B. C., J. Horita, and V. O. Garlea. "H/D isotope effects in brucite at low temperatures." American Mineralogist 98, no. 1 (2012): 1–6. http://dx.doi.org/10.2138/am.2013.4202.

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27

SCHERBAN, T., Y. BAIKOV, and E. SHALKOVA. "H+/D+ isotope effect in Y-doped BaCeO3 crystals." Solid State Ionics 66, no. 1-2 (1993): 159–64. http://dx.doi.org/10.1016/0167-2738(93)90039-6.

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28

Cool, Terrill A., Peter M. Goodwin, and Charles E. Otis. "H/D isotope effect in the predissociation of C2HD." Journal of Chemical Physics 93, no. 5 (1990): 3714–15. http://dx.doi.org/10.1063/1.458801.

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29

Matveev, D., P. Hansen, T. Dittmar, H. R. Koslowski, and Ch Linsmeier. "Modeling of H/D isotope-exchange in crystalline beryllium." Nuclear Materials and Energy 20 (August 2019): 100682. http://dx.doi.org/10.1016/j.nme.2019.100682.

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30

OI, TAKAO, and SATOSHI YANASE. "D/H isotope fractionation in the aqueous hydroxide ion." GEOCHEMICAL JOURNAL 43, no. 6 (2009): 441–45. http://dx.doi.org/10.2343/geochemj.1.0040.

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31

Kar, Sabyasachi, and Y. K. Ho. "Isotope shift for the1Deautodetaching resonance in H−and D−." Journal of Physics B: Atomic, Molecular and Optical Physics 42, no. 5 (2009): 055001. http://dx.doi.org/10.1088/0953-4075/42/5/055001.

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32

Good, Stephen P., David Noone, Naoyuki Kurita, Marion Benetti, and Gabriel J. Bowen. "D/H isotope ratios in the global hydrologic cycle." Geophysical Research Letters 42, no. 12 (2015): 5042–50. http://dx.doi.org/10.1002/2015gl064117.

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33

Friedman, Harold L., and Marshall D. Newton. "H/D isotope effect on outer sphere electron exchange." Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 204, no. 1-2 (1986): 21–29. http://dx.doi.org/10.1016/0022-0728(86)80504-6.

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34

Grishin, Yu K., R. K. Mazitov, and A. N. Panov. "Solvent-induced H/D isotope effect on129Xe chemical shifts." Applied Magnetic Resonance 14, no. 2-3 (1998): 357–66. http://dx.doi.org/10.1007/bf03161901.

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35

Kaninski, Milica P. Marceta, Vladimir M. Nikolic, Aleksandar D. Maksic, Gvozden S. Tasic, and Scepan S. Miljanic. "Electrochemical H/D isotope effects in PEM fuel cell." Electrochemistry Communications 10, no. 10 (2008): 1463–66. http://dx.doi.org/10.1016/j.elecom.2008.07.031.

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36

Morasch, Barbara, Hans H. Richnow, Bernhard Schink, and Rainer U. Meckenstock. "Stable Hydrogen and Carbon Isotope Fractionation during Microbial Toluene Degradation: Mechanistic and Environmental Aspects." Applied and Environmental Microbiology 67, no. 10 (2001): 4842–49. http://dx.doi.org/10.1128/aem.67.10.4842-4849.2001.

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ABSTRACT Primary features of hydrogen and carbon isotope fractionation during toluene degradation were studied to evaluate if analysis of isotope signatures can be used as a tool to monitor biodegradation in contaminated aquifers. D/H hydrogen isotope fractionation during microbial degradation of toluene was measured by gas chromatography. Per-deuterated toluene-d 8 and nonlabeled toluene were supplied in equal amounts as growth substrates, and kinetic isotope fractionation was calculated from the shift of the molar ratios of toluene-d 8 and nondeuterated toluene. The D/H isotope fractionation
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37

Zhai, Hongsheng, Guanglei Liang, Junxia Ding, and Yufang Liu. "Isotope effect and Coriolis coupling effect for the Li + H(D)Cl $\to $ LiCl + H(D) reaction." Chinese Physics B 28, no. 5 (2019): 053401. http://dx.doi.org/10.1088/1674-1056/28/5/053401.

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38

Dóbé, S., C. Oehlers, F. Temps, H. Gg Wagner, and H. Ziemer. "Observation of an H/D-isotope exchange channel in the reaction D + H2CO." Berichte der Bunsengesellschaft für physikalische Chemie 98, no. 5 (1994): 754–57. http://dx.doi.org/10.1002/bbpc.19940980517.

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39

Anick, D. J. "Positional Isotope Effect for the Water Tetramer." Computing Letters 1, no. 4 (2005): 145–51. http://dx.doi.org/10.1163/157404005776611411.

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Ab initio studies are carried out for the water tetramer with a single H replaced by D, (H2O)3(HDO). The isomer with D in a free position, H7DfO4, has ZPE 0.17 kcal/mol higher than the isomer with D in an H-bond, H7DbO4. The same ZPE difference is found for HbD7O4 vs HfD7O4. The difference may be large enough for a preference for H rather than D in a free position to be experimentally measurable. Exploration of the components of ZPE shows that the stretch component alone favors H7DfO4, but this is more than compensated by the bend and torsion components.
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40

Tsidilkovski, V. "Thermodynamic isotope effect H/D/T in proton-conducting oxides." Solid State Ionics 162-163 (September 2003): 47–53. http://dx.doi.org/10.1016/s0167-2738(03)00234-0.

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41

Spörkel, Lasse, Ganglong Cui, Axel Koslowski, and Walter Thiel. "Nonequilibrium H/D Isotope Effects from Trajectory-Based Nonadiabatic Dynamics." Journal of Physical Chemistry A 118, no. 1 (2013): 152–57. http://dx.doi.org/10.1021/jp4120749.

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42

Rahman, Faridur, Nobuyuki Ohnishi, Fouzia Khanom, Shoji Inanaga, and Akira Namiki. "Isotope Effects on H and D Coadsorptions on Si Surfaces." Japanese Journal of Applied Physics 43, no. 2 (2004): 726–29. http://dx.doi.org/10.1143/jjap.43.726.

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43

Saueressig, G., P. Bergamaschi, J. N. Crowley, H. Fischer, and G. W. Harris. "D/H kinetic isotope effect in the reaction CH4+Cl." Geophysical Research Letters 23, no. 24 (1996): 3619–22. http://dx.doi.org/10.1029/96gl03292.

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44

Junk, Thomas, and W. James Catallo. "Hydrogen isotope exchange reactions involving C–H (D, T) bonds." Chem. Soc. Rev. 26, no. 5 (1997): 401–6. http://dx.doi.org/10.1039/cs9972600401.

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45

Shi, Zhengshuang, C. Anders Olson, Neville R. Kallenbach та Tobin R. Sosnick. "D/H Amide Isotope Effect in Model α-Helical Peptides". Journal of the American Chemical Society 124, № 47 (2002): 13994–95. http://dx.doi.org/10.1021/ja027740n.

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46

Kolbe, Alfred. "H/D isotope effects in the self-association of alcohols." Journal of Molecular Liquids 46 (October 1990): 141–50. http://dx.doi.org/10.1016/0167-7322(90)80050-t.

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47

Brouard, Mark, and Michael J. Pilling. "An apparent isotope anomaly in the reaction CH3 + H/D." Chemical Physics Letters 129, no. 5 (1986): 439–45. http://dx.doi.org/10.1016/0009-2614(86)80225-1.

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48

Lim, Dae-Woon, Junsu Ha, Yasaswini Oruganti, and Hoi Ri Moon. "Hydrogen separation and purification with MOF-based materials." Materials Chemistry Frontiers 5, no. 11 (2021): 4022–41. http://dx.doi.org/10.1039/d1qm00234a.

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This review provides a comprehensive understanding of the fundamental theories and strategies for MOF-based H<sub>2</sub> separation and purification, including hydrogen isotope separation with representative examples.
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49

Smith, Mary Foster, and W. Alexander Van Hook. "Some Measurements of H/D Polarizability Isotope Effects Using Differential Refractometry." Zeitschrift für Naturforschung A 44, no. 5 (1989): 371–75. http://dx.doi.org/10.1515/zna-1989-0504.

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Refractive index differences between the H and D isomers of some common molecules in the liquid phase were measured between 404.7 and 690.0 nm. The data are combined with information on molar volume isotope effects to yield values for H/D isotope effects on the static polarizability, the vibrational contribution to the static and frequency dependent parts of the polarizability, and the H/D isotope effect on the second moment of the electronic charge distribution. The present results suffice to demonstrate the practicability of this technique to measure the components of the polarizability list
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50

SODA, Kazuo, Emi IIZUKA, Bun TSUCHIYA, Kenji MORITA, and Hiroyasu IWAHARA. "Isotope Effects in Diffusions of H and D in Hydrogen Isotope Exchange in Oxide Ceramics." Journal of Nuclear Science and Technology 39, no. 4 (2002): 359–62. http://dx.doi.org/10.1080/18811248.2002.9715203.

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