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1

Michou, M., and V. H. Peuch. "Échanges en surface dans le modèle de chimie transport multi-échelles MOCAGE." Revue des sciences de l'eau 15 (April 12, 2005): 173–203. http://dx.doi.org/10.7202/705492ar.

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Les échanges en surface dans le Modèle de Chimie Transport (MCT) multi-échelles MOCAGE de Météo-France comprennent à la fois les flux d'émissions et de dépôt sec d'espèces gazeuses. Une interface 2D a été développée entre MOCAGE et le modèle de prévisions météorologiques opérationnel français ARPEGE dans le but de calculer des flux à la surface réalistes Pour les émissions, un inventaire global est employé pour le moment; cet inventaire a été construit essentiellement à partir des inventaires des programmes IGAC/GEIA (International Global Atmospheric Chemistry / Global Emission Inventory Activ
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2

Solladié-Cavallo, Arlette. "Chimie organique aux interfaces." Comptes Rendus Chimie 6, no. 5-6 (2003): 515–16. http://dx.doi.org/10.1016/s1631-0748(03)00093-6.

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Mucci, Alfonso. "Chimie des Milieux aquatiques. Chimie des eaux naturelles et des interfaces dans l'environment." Geochimica et Cosmochimica Acta 61, no. 10 (1997): 2158–59. http://dx.doi.org/10.1016/s0016-7037(97)83239-5.

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Tardy, Yves. "Chimie des milieux aquatiques. Chimie des eaux naturelles et des interfaces dans l'environnement." Geochimica et Cosmochimica Acta 57, no. 7 (1993): 1638. http://dx.doi.org/10.1016/0016-7037(93)90028-u.

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Vialetto, Jacopo. "Novel Insights on the Three-dimensional Shape of Microgels at Fluid Interfaces." CHIMIA 76, no. 10 (2022): 852. http://dx.doi.org/10.2533/chimia.2022.852.

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Mechanically soft colloids (microgels) adsorbed at the interface between two fluids offer superior advantages over hard counterparts for a variety of applications ranging from foams/emulsion stabilization to the assembly of two-dimensional (2D) materials. Particle deformability and compressibility impart additional responses to microgel-laden interfaces that can be controlled on-demand by varying single-particle properties (e.g. crosslinking content and polymer density profile) and/or external parameters (e.g. interfacial compression and tension, temperature, oil polarity). In order to underst
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6

Schaming, Delphine, Imren Hatay, Fernando Cortez, et al. "Artificial Photosynthesis at Soft Interfaces." CHIMIA International Journal for Chemistry 65, no. 5 (2011): 356–59. http://dx.doi.org/10.2533/chimia.2011.356.

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Hennig, Andreas, Sheshanath Bhosale, Naomi Sakai, and Stefan Matile. "CD Methods Development at the Bio-Nano Interface." CHIMIA International Journal for Chemistry 62, no. 6 (2008): 493–96. http://dx.doi.org/10.2533/chimia.2008.493.

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8

Kaldre, Dainis, Fabrice Gallou, Christof Sparr, and Michael Parmentier. "Interface-rich Aqueous Systems for Sustainable Chemical Synthesis." CHIMIA International Journal for Chemistry 73, no. 9 (2019): 714–19. http://dx.doi.org/10.2533/chimia.2019.714.

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Mimicking an enzyme's exquisite activity and selectivity is a long-standing goal for sustainable chemical method development in aqueous media. The use of interface-rich aqueous systems, such as single-chain polymers, micelles and vesicle membranes recently emerged as strategy to emulate the compartmentalization of natural systems. In aqueous solution, aggregates such as micelles or microemulsion droplets are formed, providing reaction environments different from bulk solutions that frequently improve selectivity and accelerate reaction rates for a wide array of chemical transformations. We pre
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9

Bobisch, Christian A., and Rolf Möller. "Electron Transport at Surfaces and Interfaces." CHIMIA International Journal for Chemistry 66, no. 1 (2012): 23–30. http://dx.doi.org/10.2533/chimia.2012.23.

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10

Schwanitz, Konrad, Eric Mankel, Ralf Hunger, Thomas Mayer, and Wolfram Jaegermann. "Photoelectron Spectroscopy at the Solid–Liquid Interface of Dye–Sensitized Solar Cells: Unique Experiments with the Solid–Liquid Interface Analysis System SoLiAS at BESSY." CHIMIA International Journal for Chemistry 61, no. 12 (2007): 796–800. http://dx.doi.org/10.2533/chimia.2007.796.

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Schlüter, Dieter A. "Progress in Synthetic 2D Polymers Obtained at the Air/Water Interface." CHIMIA International Journal for Chemistry 73, no. 6 (2019): 487–92. http://dx.doi.org/10.2533/chimia.2019.487.

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12

Bürgi, Thomas. "Shining Light at Working Interfaces and Chiral Nanoparticles." CHIMIA International Journal for Chemistry 65, no. 3 (2011): 157–67. http://dx.doi.org/10.2533/chimia.2011.157.

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13

Amstad, Esther. "Leveraging Liquid–Liquid Interfaces to Assemble Responsive Vesicles." CHIMIA International Journal for Chemistry 68, no. 11 (2014): 819. http://dx.doi.org/10.2533/chimia.2014.819.

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14

Nüesch, Frank A. "Interface Dipoles for Tuning Energy Level Alignment in Organic Thin Film Devices." CHIMIA International Journal for Chemistry 67, no. 11 (2013): 796–803. http://dx.doi.org/10.2533/chimia.2013.796.

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15

Natterodt, JensC, Alke Petri-Fink, Christoph Weder, and JustinO Zoppe. "Cellulose Nanocrystals: Surface Modification, Applications and Opportunities at Interfaces." CHIMIA International Journal for Chemistry 71, no. 6 (2017): 376–83. http://dx.doi.org/10.2533/chimia.2017.376.

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16

Wu, Shang-Jung, and ArdemisA Boghossian. "Living on the Edge: Re-shaping the Interface of Synthetic Biology and Nanotechnology." CHIMIA International Journal for Chemistry 70, no. 11 (2016): 773–79. http://dx.doi.org/10.2533/chimia.2016.773.

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17

Zhang, Seraphine B. X. Y., and Christophe Copéret. "Non-Oxidative Coupling of Methane: Interplay of Catalyst Interface and Gas Phase Mechanisms." CHIMIA 77, no. 4 (2023): 206. http://dx.doi.org/10.2533/chimia.2023.206.

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Non-oxidative coupling of methane (NOCM) is a sought-after reaction that has been studied for decades. Harsh reaction conditions (T >800°C) in the face of limited catalyst stability lead to rapid catalyst deactivation and strong coking, preventing application thus far. Recent reports have shown the significance of an interplay of catalyst nature and reaction conditions, whereas metal carbides have prevailed to play a crucial role which involves incorporation of carbidic carbon in C2Hx and aromatic products. This perspective gives an overview of proposed mechanistic pathways and consideratio
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18

Popa, Ionel, Rémi Longtin, Plinio Maroni, Georg Papastavrou, and Michal Borkovec. "Adsorption and Self-Organization of Dendrimers at Water–Solid Interfaces." CHIMIA International Journal for Chemistry 63, no. 5 (2009): 279–82. http://dx.doi.org/10.2533/chimia.2009.279.

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19

Treu, Sigfried, D. Peter Sanderson, Roman Rozin, and Ravi Sharma. "Design process and decision rationale models for the N-Chime interface system." ACM SIGCHI Bulletin 22, no. 1 (1990): 73–79. http://dx.doi.org/10.1145/101288.101304.

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20

Treu, S., DP Sanderson, R. Rozin, and R. Sharma. "High-level, three-pronged design methodology for N-CHIME interface system software." Information and Software Technology 33, no. 5 (1991): 306–20. http://dx.doi.org/10.1016/0950-5849(91)90099-w.

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21

Godineau, Edouard, Fabrice Gallou, Olivier Enger, et al. "How Can Academia Help Industry Reduce the Footprint of Chemicals Manufacture?" CHIMIA 77, no. 3 (2023): 159. http://dx.doi.org/10.2533/chimia.2023.159.

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Industrial representatives from the Swiss chemistry ecosystem met to formulate unmet needs in the field of sustainability and share the content of the exchange. The aim is to spark inspiration and trigger ambitious and pre-competitive projects collectively at the interface of the academic and industrial worlds, with the hope to profoundly change the current practices and provide an answer to some of the most urgent environmental challenges.
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22

Rühs, Patrick A., R. Fredrik Inglis, and Peter Fischer. "Interfacial Rheology of Bacterial Biofilms at Air/Water and Oil/Water Interfaces." CHIMIA International Journal for Chemistry 68, no. 4 (2014): 273. http://dx.doi.org/10.2533/chimia.2014.273.

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23

De Feyter, Steven, Hong Xu, and Kunal Mali. "Dynamics in Self-assembled Organic Monolayers at the Liquid/Solid Interface Revealed by Scanning Tunneling Microscopy." CHIMIA International Journal for Chemistry 66, no. 1 (2012): 38–43. http://dx.doi.org/10.2533/chimia.2012.38.

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24

Cléry, Antoine, Laurent Gillioz, Cristina K. X. Nguyen, and Frédéric H. T. Allain. "A Step-by-Step Guide to Study Protein–RNA Interactions." CHIMIA International Journal for Chemistry 73, no. 5 (2019): 406–14. http://dx.doi.org/10.2533/chimia.2019.406.

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Protein–RNA complex formation is at the center of RNA metabolism and leads to the modulation of protein and RNA functions. We propose here a step-by-step guide to investigate these interactions including the identification of the protein and RNA parts involved in complex formation, the determination of the affinity of the complex and the characterization of the protein–RNA interface at amino acid and nucleotide level. Moreover, we briefly review the methods that are the most often used to obtain this information using primarily examples from our lab and finally mention what we perceive as the
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25

Stegemann, Bert, Daniel Sixtensson, Thomas Lussky, Ulrike Bloeck, and Manfred Schmidt. "Ultrahigh Vacuum Preparation and Passivation of Abrupt SiO2/Si(111) Interfaces." CHIMIA International Journal for Chemistry 61, no. 12 (2007): 826–30. http://dx.doi.org/10.2533/chimia.2007.826.

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26

Pham, Duc T., Hubert Keller, Stephan Breuer, et al. "Anion/Cation Layers at Electrified Interfaces: A Comprehensive STM, XRD and XPS Case Study." CHIMIA International Journal for Chemistry 63, no. 3 (2009): 115–21. http://dx.doi.org/10.2533/chimia.2009.115.

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27

Isa, Lucio, Esther Amstad, Marcus Textor, and Erik Reimhult. "Self-Assembly of Iron Oxide-Poly(ethylene glycol) Core–Shell Nanoparticles at Liquid–Liquid Interfaces." CHIMIA International Journal for Chemistry 64, no. 3 (2010): 145–49. http://dx.doi.org/10.2533/chimia.2010.145.

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28

Isa, Lucio. "Adsorption and Microstructure of Core-Shell Nanoparticles at Liquid-Liquid Interfaces: An X-ray Reflectivity Study." CHIMIA International Journal for Chemistry 67, no. 4 (2013): 297. http://dx.doi.org/10.2533/chimia.2013.297.

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29

Fedoseeva, Marina, Jakob Grilj, Oksana Kel, et al. "Photoinduced Electron Transfer Reactions: From the Elucidation of Old Problems in Bulk Solutions Towards the Exploration of Interfaces." CHIMIA International Journal for Chemistry 65, no. 5 (2011): 350–52. http://dx.doi.org/10.2533/chimia.2011.350.

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30

Castiglioni, Luca, Michael Greif, Dominik Leuenberger, Silvan Roth, Jürg Osterwalder, and Matthias Hengsberger. "Time-Resolved Photoelectron Spectroscopy to Probe Ultrafast Charge Transfer and Electron Dynamics in Solid Surface Systems and at Metal- Molecule Interfaces." CHIMIA International Journal for Chemistry 65, no. 5 (2011): 342–45. http://dx.doi.org/10.2533/chimia.2011.342.

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31

Isa, Lucio. "Freeze-fracture Shadow-casting (FreSCa) Cryo-SEM as a Tool to Investigate the Wetting of Micro- and Nanoparticles at Liquid–Liquid Interfaces." CHIMIA International Journal for Chemistry 67, no. 4 (2013): 231–35. http://dx.doi.org/10.2533/chimia.2013.231.

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32

Foppa, Lucas, Kim Larmier, and Aleix Comas-Vives. "What Can We Learn from First Principles Multi-Scale Models in Catalysis? The Role of the Ni/Al2O3 Interface in Water-Gas Shift and Dry Reforming as a Case Study." CHIMIA International Journal for Chemistry 73, no. 4 (2019): 239–44. http://dx.doi.org/10.2533/chimia.2019.239.

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33

Pujal, Josep-Maria, Santiago Roura, Ana M. Muñoz-Marmol, Jose-Luis Mate, and Antoni Bayes-Genis. "Fetal-maternal interface: A chronicle of allogeneic coexistence." Chimerism 3, no. 1 (2012): 18–23. http://dx.doi.org/10.4161/chim.19439.

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Dufrêche, Jean-François. "Preface." Pure and Applied Chemistry 85, no. 1 (2013): iv. http://dx.doi.org/10.1351/pac20138501iv.

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The 32nd International Conference on Solution Chemistry (ICSC-32) was held 28 August-2 September 2011 in La Grande Motte, France. This conference series covers a wide range of topics related to solution chemistry, such as- thermodynamics, kinetics, and structure- polymers, colloids, interfaces, and membranes- bioinorganic, biophysical, and pharmaceutical problems- supramolecular assemblies and nanostructures- analytical and environmental aspects- solvents and solutions under extreme conditionsFive plenary lectures were given: “Electrochemistry, the challenge of 21st century: From living cells
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35

Sanctis, Shawn, Rudolf C. Hoffmann, Michael Bruns, and Jörg J. Schneider. "Metal Oxide Semiconductors: Direct Photopatterning of Solution-Processed Amorphous Indium Zinc Oxide and Zinc Tin Oxide Semiconductors-A Chimie Douce Molecular Precursor Approach to Thin Film Electronic Oxides (Adv. Mater. Interfaces 15/2018)." Advanced Materials Interfaces 5, no. 15 (2018): 1870073. http://dx.doi.org/10.1002/admi.201870073.

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36

Bandura, K., A. N. Bender, J. F. Cliche, et al. "ICE: A Scalable, Low-Cost FPGA-Based Telescope Signal Processing and Networking System." Journal of Astronomical Instrumentation 05, no. 04 (2016): 1641005. http://dx.doi.org/10.1142/s2251171716410051.

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We present an overview of the ‘ICE’ hardware and software framework that implements large arrays of interconnected field-programmable gate array (FPGA)-based data acquisition, signal processing and networking nodes economically. The system was conceived for application to radio, millimeter and sub-millimeter telescope readout systems that have requirements beyond typical off-the-shelf processing systems, such as careful control of interference signals produced by the digital electronics, and clocking of all elements in the system from a single precise observatory-derived oscillator. A new gene
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37

"Methods for Characterizing Polymer Surfaces and Interfaces." CHIMIA 44, no. 10 (1990): 312. http://dx.doi.org/10.2533/chimia.1990.312.

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The behavior of polymer molecules at surfaces and interfaces has been receiving a considerable amount of attention over the past few years. Numerous developments have been made theoretically using simulations and analytic approaches. Experimentally, advances have been made in the development of new techniques and the use of old techniques not commonly used in the investigation of polymers to probe the interfacial and near surface behavior of polymers. In this article, some of the experimental developments that have been made recently will be discussed. The approach will be to focus on the beha
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38

"Polymers, Colloids & Interfaces: Abstracts PCI01?PCI65." CHIMIA International Journal for Chemistry 67, no. 7 (2013): 589–605. http://dx.doi.org/10.2533/chimia.2013.589.

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"Research at the Laboratory for Photonics and Interfaces." CHIMIA 50, no. 12 (1996): 583. http://dx.doi.org/10.2533/chimia.1996.583.

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"Structure and Activity of Microbial Communities in Sediments." CHIMIA 51, no. 12 (1997): 878. http://dx.doi.org/10.2533/chimia.1997.878.

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Mineralization of organic matter in sediments are driven by a dense microbial population. Large chemical concentration gradients perpendicular to the interface are developed. Concentration profiles at the sediment-water interface can be measured in situ with miniaturized ion-selective electrodes and fluxes, and reaction rates can be calculated with this information. Direct flux measurements in benthic chambers are performed with isotope tracers to investigate the cycling of nutrients such as nitrogen and sulfur. With the development of molecular genetics new tools have become available to obta
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41

Colombo, Luciano. "TRASPORTO DI CALORE ATTRAVERSO UN’INTERFACCIA: UN PROBLEMA CLASSICO RIVISITATO IN CHIAVE MODERNA." Istituto Lombardo - Accademia di Scienze e Lettere - Rendiconti di Scienze, March 26, 2020. http://dx.doi.org/10.4081/scie.2017.601.

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I describe a set of computational experiments using molecular dynamics simulations, showing that the interface between two solid materials can be described as an autonomous thermodynamical system. By making use of the Gibbs description for such an interface, I discuss a robust nonequilibrium thermodynamics theoretical framework providing information about its corresponding thermal boundary resistance. In particular, I show that the termal resistance of a junction between two pure solid materials can be regarded as an interface property, depending solely on the interface temperature.
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42

"Electrochemical Sensor Research at the Laboratoire d'Electrochimie of the EPFL." CHIMIA 53, no. 3 (1999): 103. http://dx.doi.org/10.2533/chimia.1999.103.

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This review presents some recent developments in the field of electroanalytical sensors. We first explain the working principle of electrochemistry at the interface between two immiscible electrolyte solutions (ITIES), illustrated by the example of copper transferring through a water/1,2-dichloroethane interface when the ionophore 1,4,7,10-tetrathiacyclododecane is present in the organic phase. The obtained results show that assisted ion-transfer reactions take place with both CuI and CuII, but that the interfacial process is complicated by the fact that CuI disproportionates in water and that
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43

"Using Structural Information of Peptides, Derived from NMR Spectroscopy, in Pharmaceutical Chemistry." CHIMIA 54, no. 11 (2000): 627. http://dx.doi.org/10.2533/chimia.2000.627.

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The significance of information gained from the solution structure of peptides for pharmaceutical research is demonstrated with two examples: the neuropeptide Y (NPY) hormone system and a undecapeptide designed for use as a chemical sensor. In the case of NPY, the structure of the homodimer and the mode of membrane association was determined. Thereby, it was discovered that the membrane/NPY interface is formed by the same hydrophobic residues that constitute the homodimer interface. Furthermore, in the membrane-bound state, the C-terminal helix is stabilized, which is of special functional imp
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44

"Self-replicating Reverse Micelles." CHIMIA 45, no. 9 (1991): 266. http://dx.doi.org/10.2533/chimia.1991.266.

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Conditions are described, under which the hydrolysis of octyl octanoate (O-OA) takes place at the interface of reverse micelles fanned by sodium octanoate (OA) in isooctane. Since the micelle-mediated hydrolysis affords fresh OA, which spontaneously assemble into new micelles, the reaction can be seen as a self-replicating process. The kinetics and the spectroscopy of this self-replication process are presented.
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"Microstructure-Property Control in Functional Materials by Multilayer Design." CHIMIA 76, no. 3 (2022): 223. http://dx.doi.org/10.2533/chimia.2022.223.

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Smart microstructure and interface design in nanomultilayers allows to tailor physical properties like thermal stability, thermal conductivity and directional metal outflow for targeted applications. In this work, selected examples of nanomultilayer systems, constituted of alternating nanolayers of metals and/or nitrides, as precisely fabricated with variable textures, microstructures, grain sizes and internal stresses are presented. The role of the microstructure and stress state on selected functional properties is shown.
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46

"Characterization of Low Temperature Soluble Polyaniline." CHIMIA 47, no. 12 (1993): 490. http://dx.doi.org/10.2533/chimia.1993.490.

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Because the charging of polyaniline films occurs in the bulk of the material rather than exclusively at the polymer-electrolyte interface, the use of thick polymer films for battery applications is justifiable. Here, we present a method for producing soluble polyaniline which can be cast to form free-standing films. Investigation by scanning electron microsopy (SEM) has shown that these films are significantly more compact than those made by standard electropolymerization.
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47

"Role of Particle-Matrix Interface in the Deformation and Fracture Behaviour of Filled Epoxy Resins." CHIMIA 44, no. 11 (1990): 354. http://dx.doi.org/10.2533/chimia.1990.354.

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As a result of their superior mechanical, chemical, and electrical properties particulate-filled epoxies are finding widespread use in the fabrication of a large number of engineering components, one important example being as electrical insulators for the power industry. Since these materials are mainly subjected to continuous mechanical loads (in addition to a continuous dielectrical stress), there is an apparent need first to understand and then to predict the processes of deformation and fracture during long-term loading conditions. A few years ago, the respective material science knowledg
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48

"Stereochemistry at the Interface between Crystals and Biology: Extended Abstract of the 1998 Prelog Lecture." CHIMIA 53, no. 4 (1999): 157. http://dx.doi.org/10.2533/chimia.1999.157.

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"Atmospheric Pollution: The Role of Heterogeneous Chemical Reactions." CHIMIA 50, no. 5 (1996): 199. http://dx.doi.org/10.2533/chimia.1996.199.

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The chemical kinetics of heterogeneous chemical reactions of importance in the atmosphere are discussed using six examples: 1) water vapor and 2) HCl interacting with ice, 3) ClONO2 + HCl on ice, 4) HONO + HCl on H2SO4 and ice, 5) HNO3 reacting on dry CaCO3 powder and 6) reactions of HNO3, N2O5; ClONO2, ClNO2 on salts such as NaCl and KBr. Quantitative results of uptake coefficients are presented and the importance of ionic displacement reactions at the interface is stressed.
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"IR Spectra Simulation and Information Processing on the WWW." CHIMIA 52, no. 11 (1998): 678. http://dx.doi.org/10.2533/chimia.1998.678.

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Substance identification by IR-spectroscopic methods generally is performed by comparing the measured spectrum with a reference spectrum from a database. If the desired spectrum is not contained in the database, another method of substance identification has to be found.Based on neural network techniques, we have developed a method which provides rapid access to simulated reference spectra. Within the scope of the 'TeleSpec-Telecooperation in Spectroscopy'-Project, this algorithm has been made available through a WWW interface. With a JAVA-enabled Web browser, interactive spectra prediction ex
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