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Artykuły w czasopismach na temat „Ion multivalent”

Autor: Grafiati

Data publikacji: 9 listopada 2024

Data aktualizacji: 31 lipca 2025

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1

Proffit, Danielle L., Albert L. Lipson, Baofei Pan, et al. "Reducing Side Reactions Using PF6-based Electrolytes in Multivalent Hybrid Cells." MRS Proceedings 1773 (2015): 27–32. http://dx.doi.org/10.1557/opl.2015.590.

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ABSTRACTThe need for higher energy density batteries has spawned recent renewed interest in alternatives to lithium ion batteries, including multivalent chemistries that theoretically can provide twice the volumetric capacity if two electrons can be transferred per intercalating ion. Initial investigations of these chemistries have been limited to date by the lack of understanding of the compatibility between intercalation electrode materials, electrolytes, and current collectors. This work describes the utilization of hybrid cells to evaluate multivalent cathodes, consisting of high surface a

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Palacin, M. Rosa, Patrik Johansson, Robert Dominko, et al. "Roadmap on Multivalent Batteries." JPhys Energy 6, no. 3 (2024): 031501. https://doi.org/10.1088/2515-7655/ad34fc.

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Battery technologies based in multivalent charge carriers with ideally two or three electrons transferred per ion exchanged between the electrodes have large promises in raw performance numbers, most often expressed as high energy density, and are also ideally based on raw materials that are widely abundant and less expensive. Yet, these are still globally in their infancy, with some concepts (e.g., Mg metal) being more technologically mature. The challenges to address are derived on one side from the highly polarizing nature of multivalent ions when compared to single valent concepts such as

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3

Greene, Samuel M., and Donald J. Siegel. "Computational Investigations of Features for Predicting Ionic Conductivity in Multivalent Solid Electrolytes." ECS Meeting Abstracts MA2024-02, no. 9 (2024): 1428. https://doi.org/10.1149/ma2024-0291428mtgabs.

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A significant challenge hindering the development of batteries based on the redox of multivalent ions is the sluggish mobility of such ions in most solids. Computational methods for efficiently predicting conductivity can accelerate the discovery of faster ion conductors. Direct first-principles calculations of conductivity are expensive and difficult to automate, which has prompted a search for other properties related to conductivity that are easier to calculate or measure. Previous studies have identified features related to the electronic charge density and phonon spectrum that are correla

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4

Rutt, Ann, and Kristin A. Persson. "Expanding the Materials Search Space for Multivalent Cathodes." ECS Meeting Abstracts MA2022-02, no. 4 (2022): 446. http://dx.doi.org/10.1149/ma2022-024446mtgabs.

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Multivalent batteries are an energy storage technology with the potential to surpass lithium-ion batteries, however their performance has been limited by the low voltages and poor solid-state ionic mobility of available cathodes. A computational screening approach to identify high-performance multivalent intercalation cathodes among materials that do not contain the working ion of interest has been developed which greatly expands the search space that can be considered for materials discovery. This approach has been applied to magnesium cathodes as a proof of concept and resulting candidate ma

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5

Iton, Zachery W. B., and Kimberly A. See. "Multivalent Ion Conduction in Inorganic Solids." Chemistry of Materials 34, no. 3 (2022): 881–98. http://dx.doi.org/10.1021/acs.chemmater.1c04178.

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6

Dong, Liubing, Wang Yang, Wu Yang, Yang Li, Wenjian Wu, and Guoxiu Wang. "Multivalent metal ion hybrid capacitors: a review with a focus on zinc-ion hybrid capacitors." Journal of Materials Chemistry A 7, no. 23 (2019): 13810–32. http://dx.doi.org/10.1039/c9ta02678a.

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Schauser, Nicole S., Ram Seshadri, and Rachel A. Segalman. "Multivalent ion conduction in solid polymer systems." Molecular Systems Design & Engineering 4, no. 2 (2019): 263–79. http://dx.doi.org/10.1039/c8me00096d.

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8

Gates, Leslie, and Niya Sa. "Investigation of Suitability of Electrolytes in a Trivalent System." ECS Meeting Abstracts MA2023-01, no. 1 (2023): 425. http://dx.doi.org/10.1149/ma2023-011425mtgabs.

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As lithium-ion batteries (LIB) start to approach their theoretical limit, researchers are focusing on alternatives such as nonaqueous multivalent systems. There are many advantages of multivalent systems such as higher natural abundance, low cost and possible high volumetric capacity. Suitable electrolytes are vital for the development of such multivalent battery systems which offer compatibility of utilizing metal anode. To create a better understanding of the opportunities and challenges of the trivalent electrolytes in aluminum batteries, this work investigates the reaction mechanisms and S

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9

Li, Zhong-Qiu, Yang Wang, Zeng-Qiang Wu, Ming-Yang Wu, and Xing-Hua Xia. "Bioinspired Multivalent Ion Responsive Nanopore with Ultrahigh Ion Current Rectification." Journal of Physical Chemistry C 123, no. 22 (2019): 13687–92. http://dx.doi.org/10.1021/acs.jpcc.9b02279.

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10

Hasnat, Abul, and Vinay A. Juvekar. "Dynamics of ion-exchange involving multivalent cations." Chemical Engineering Science 52, no. 14 (1997): 2439–42. http://dx.doi.org/10.1016/s0009-2509(97)00047-x.

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KC, Bilash, Jinglong Guo, Robert Klie, et al. "TEM Analysis of Multivalent Ion Battery Cathode." Microscopy and Microanalysis 26, S2 (2020): 3170–72. http://dx.doi.org/10.1017/s1431927620024058.

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12

Imanaka, Nobuhito, and Shinji Tamura. "Development of Multivalent Ion Conducting Solid Electrolytes." Bulletin of the Chemical Society of Japan 84, no. 4 (2011): 353–62. http://dx.doi.org/10.1246/bcsj.20100178.

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13

Kim, Chaewon, Useul Hwang, Sangjin Lee, and Young-Kyu Han. "First-Principles Dynamics Investigation of Germanium as an Anode Material in Multivalent-Ion Batteries." Nanomaterials 13, no. 21 (2023): 2868. http://dx.doi.org/10.3390/nano13212868.

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Germanium, a promising electrode material for high-capacity lithium ion batteries (LIBs) anodes, attracted much attention because of its large capacity and remarkably fast charge/discharge kinetics. Multivalent-ion batteries are of interest as potential alternatives to LIBs because they have a higher energy density and are less prone to safety hazards. In this study, we probed the potential of amorphous Ge anodes for use in multivalent-ion batteries. Although alloying Al and Zn in Ge anodes is thermodynamically unstable, Mg and Ca alloys with Ge form stable compounds, Mg2.3Ge and Ca2.4Ge that

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14

Wang, Bangda, Natsume Koike, Kenta Iyoki, et al. "Insights into the ion-exchange properties of Zn(ii)-incorporated MOR zeolites for the capture of multivalent cations." Physical Chemistry Chemical Physics 21, no. 7 (2019): 4015–21. http://dx.doi.org/10.1039/c8cp06975a.

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15

Islam, Shakirul M., Ryan J. Malone, Wenlong Yang, et al. "Nanographene Cathode Materials for Nonaqueous Zn-Ion Batteries." Journal of The Electrochemical Society 169, no. 11 (2022): 110517. http://dx.doi.org/10.1149/1945-7111/ac9f72.

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Robust multivalent ion interaction in electrodes is a grand challenge of next-generation battery research. In this manuscript, we design molecularly-precise nanographene cathodes that are coupled with metallic Zn anodes to create a new class of Zn-ion batteries. Our results indicate that while electrodes with graphite or flat nanographenes do not support Zn-ion intercalation, the larger intermolecular spacing in a twisted peropyrene enables peropyrene electrodes to facilitate reversible Zn-ion intercalation in an acetonitrile electrolyte. While most previous Zn-ion batteries utilize aqueous el

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16

Jing, Benxin, Jie Qiu, and Yingxi Zhu. "Organic–inorganic macroion coacervate complexation." Soft Matter 13, no. 28 (2017): 4881–89. http://dx.doi.org/10.1039/c7sm00955k.

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17

Liu, Yiyang, Guanjie He, Hao Jiang, Ivan P. Parkin, Paul R. Shearing, and Dan J. L. Brett. "Multivalent Ion Batteries: Cathode Design for Aqueous Rechargeable Multivalent Ion Batteries: Challenges and Opportunities (Adv. Funct. Mater. 13/2021)." Advanced Functional Materials 31, no. 13 (2021): 2170089. http://dx.doi.org/10.1002/adfm.202170089.

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18

Naughton, Elise M., Mingqiang Zhang, Diego Troya, Karen J. Brewer, and Robert B. Moore. "Size dependent ion-exchange of large mixed-metal complexes into Nafion® membranes." Polymer Chemistry 6, no. 38 (2015): 6870–79. http://dx.doi.org/10.1039/c5py00714c.

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19

Besha, Abreham Tesfaye, Misgina Tilahun Tsehaye, David Aili, Wenjuan Zhang, and Ramato Ashu Tufa. "Design of Monovalent Ion Selective Membranes for Reducing the Impacts of Multivalent Ions in Reverse Electrodialysis." Membranes 10, no. 1 (2019): 7. http://dx.doi.org/10.3390/membranes10010007.

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Reverse electrodialysis (RED) represents one of the most promising membrane-based technologies for clean and renewable energy production from mixing water solutions. However, the presence of multivalent ions in natural water drastically reduces system performance, in particular, the open-circuit voltage (OCV) and the output power. This effect is largely described by the “uphill transport” phenomenon, in which multivalent ions are transported against the concentration gradient. In this work, recent advances in the investigation of the impact of multivalent ions on power generation by RED are sy

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20

Dai, Fangfang, Risheng Yu, Ruobing Yi, et al. "Ultrahigh water permeance of a reduced graphene oxide nanofiltration membrane for multivalent metal ion rejection." Chemical Communications 56, no. 95 (2020): 15068–71. http://dx.doi.org/10.1039/d0cc06302a.

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Ma, Xinpei, Junye Cheng, Liubing Dong, et al. "Multivalent ion storage towards high-performance aqueous zinc-ion hybrid supercapacitors." Energy Storage Materials 20 (July 2019): 335–42. http://dx.doi.org/10.1016/j.ensm.2018.10.020.

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Li, Matthew, Jun Lu, Xiulei Ji, et al. "Design strategies for nonaqueous multivalent-ion and monovalent-ion battery anodes." Nature Reviews Materials 5, no. 4 (2020): 276–94. http://dx.doi.org/10.1038/s41578-019-0166-4.

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23

Ma, Lin, Marshall Schroeder, Glenn Pastel, et al. "(Invited) Promises and Challenges of Multivalent Ion Battery Chemistries." ECS Meeting Abstracts MA2022-02, no. 5 (2022): 552. http://dx.doi.org/10.1149/ma2022-025552mtgabs.

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Extensive efforts have been made to seek new battery chemistries based on multivalent working ions, with the aim to replace the mature lithium-ion batteries. These efforts were initially driven by the pursuit of higher capacity/energy, better safety and lower cost, and more recently have significantly intensified with the increasing concerns over the climate change, the limited resources of Co and Ni, and the anxieties over geopolitical as well as ethical risks of the corresponding supply chain. But how far are we from a practical multivalent battery? This talk rigorously examines the achievem

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24

Srivastava, Sunita, Anuj Chhabra, and Oleg Gang. "Effect of mono- and multi-valent ionic environments on the in-lattice nanoparticle-grafted single-stranded DNA." Soft Matter 18, no. 3 (2022): 526–34. http://dx.doi.org/10.1039/d1sm01171e.

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Lužanin, Olivera, Jože Moškon, Tjaša Pavčnik, Robert Dominko, and Jan Bitenc. "Unveiling True Limits of Electrochemical Performance of Organic Cathodes in Multivalent Batteries through Cyclable Symmetric Cells." Batteries & Supercaps 6, no. 2 (2022): e202200437. https://doi.org/10.1002/batt.202200437.

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Multivalent batteries are often hyped as a next-generation high-energy density battery technology, but in reality, both literature reports and practical research are plagued by poor reproducibility of electrochemical results. Within the present work, we take a look at the electrochemical testing of organic cathodes that can be used with a variety of mono- and multivalent cations and propose a cyclable symmetric cell approach, already applied to the field of lithium-ion batteries. By using a model organic system based on poly(anthraquinonyl sulfide) (PAQS) active material, we demonstrate that t

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26

Park, Haesun, and Peter Zapol. "Thermodynamic and kinetic properties of layered-CaCo2O4 for the Ca-ion batteries: a systematic first-principles study." Journal of Materials Chemistry A 8, no. 41 (2020): 21700–21710. http://dx.doi.org/10.1039/d0ta07573f.

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Kim, Kwangnam, and Donald J. Siegel. "Multivalent Ion Transport in Anti-Perovskite Solid Electrolytes." Chemistry of Materials 33, no. 6 (2021): 2187–97. http://dx.doi.org/10.1021/acs.chemmater.1c00096.

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Liu, Chaofeng. "Aqueous Multivalent Ion Batteries Built on Hydrated Vanadates." ECS Meeting Abstracts MA2020-01, no. 2 (2020): 226. http://dx.doi.org/10.1149/ma2020-012226mtgabs.

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Park, Min Je, Hooman Yaghoobnejad Asl, and Arumugam Manthiram. "Multivalent-Ion versus Proton Insertion into Battery Electrodes." ACS Energy Letters 5, no. 7 (2020): 2367–75. http://dx.doi.org/10.1021/acsenergylett.0c01021.

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Quinn, J. F., and F. Caruso. "Multivalent-Ion-Mediated Stabilization of Hydrogen-Bonded Multilayers." Advanced Functional Materials 16, no. 9 (2006): 1179–86. http://dx.doi.org/10.1002/adfm.200500530.

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Wang, Chunlei, Zibing Pan, Huaqi Chen, Xiangjun Pu, and Zhongxue Chen. "MXene-Based Materials for Multivalent Metal-Ion Batteries." Batteries 9, no. 3 (2023): 174. http://dx.doi.org/10.3390/batteries9030174.

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Multivalent metal ion (Mg2+, Zn2+, Ca2+, and Al3+) batteries (MMIBs) emerged as promising technologies for large-scale energy storage systems in recent years due to the abundant metal reserves in the Earth’s crust and potentially low cost. However, the lack of high-performance electrode materials is still the main obstacle to the development of MMIBs. As a newly large family of two-dimensional transition metal carbides, nitrides, and carbonitrides, MXenes have attracted growing focus in the energy storage field because of their large specific surface area, excellent conductivity, tunable inter

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Dai, Fangfang, Feng Zhou, Junlang Chen, Shanshan Liang, Liang Chen, and Haiping Fang. "Ultrahigh water permeation with a high multivalent metal ion rejection rate through graphene oxide membranes." Journal of Materials Chemistry A 9, no. 17 (2021): 10672–77. http://dx.doi.org/10.1039/d1ta00647a.

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Yao, Long, Shunlong Ju, and Xuebin Yu. "Rational surface engineering of MXene@N-doped hollow carbon dual-confined cobalt sulfides/selenides for advanced aluminum batteries." Journal of Materials Chemistry A 9, no. 31 (2021): 16878–88. http://dx.doi.org/10.1039/d1ta03465k.

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Rechargeable aluminum batteries (RABs) based on multivalent ion transfer have attracted great attention due to their large specific capacities, natural abundance, and high safety of metallic Al anodes.

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Zhang, Jiaxu, Xiang Wang, Jing Lv, Dong-Sheng Li, and Tao Wu. "A multivalent mixed-metal strategy for single-Cu+-ion-bridged cluster-based chalcogenide open frameworks for sensitive nonenzymatic detection of glucose." Chemical Communications 55, no. 45 (2019): 6357–60. http://dx.doi.org/10.1039/c9cc02905b.

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Chen, Mei, Jinxing Ma, Zhiwei Wang, Xingran Zhang, and Zhichao Wu. "Insights into iron induced fouling of ion-exchange membranes revealed by a quartz crystal microbalance with dissipation monitoring." RSC Advances 7, no. 58 (2017): 36555–61. http://dx.doi.org/10.1039/c7ra05510b.

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Pavlovic, Marko, Robin Huber, Monika Adok-Sipiczki, Corinne Nardin, and Istvan Szilagyi. "Ion specific effects on the stability of layered double hydroxide colloids." Soft Matter 12, no. 17 (2016): 4024–33. http://dx.doi.org/10.1039/c5sm03023d.

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Liu, Yi, and Rudolf Holze. "Metal-Ion Batteries." Encyclopedia 2, no. 3 (2022): 1611–23. http://dx.doi.org/10.3390/encyclopedia2030110.

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Metal-ion batteries are systems for electrochemical energy conversion and storage with only one kind of ion shuttling between the negative and the positive electrode during discharge and charge. This concept also known as rocking-chair battery has been made highly popular with the lithium-ion battery as its most popular example. The principle can also be applied with other cations both mono- and multivalent. This might have implications and advantages in terms of increased safety, lower expenses, and utilizing materials, in particular metals, not being subject to resource limitations.

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Liu, Zhexuan, Liping Qin, Xinxin Cao, et al. "Ion migration and defect effect of electrode materials in multivalent-ion batteries." Progress in Materials Science 125 (April 2022): 100911. http://dx.doi.org/10.1016/j.pmatsci.2021.100911.

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Izdebska, Natalia, Klaudia Kierepka, Maciej Marczewski, and Wladyslaw Wieczorek. "Bivalent Metal-Organic Batteries: Optimisation of Electrolytes By Next-Generation Additives." ECS Meeting Abstracts MA2024-02, no. 9 (2024): 1412. https://doi.org/10.1149/ma2024-0291412mtgabs.

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Li-Ion batteries, despite their commonness, suffer in Europe form poor raw material availability and the ever-raising price, observed most often in consumer electronics prices. Now more than ever novel battery technologies are on a rise. Bivalent metal-organic batteries are of cutting-edge nature, not yet researched thoroughly. They have emerged as promising candidates for next-generation energy storage systems due to their high energy density, cost-effectiveness, and environmental sustainability. However, several challenges hinder their commercialization, including poor cycling stability and

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Karapidakis, Emmanuel, and Dimitra Vernardou. "Progress on V2O5 Cathodes for Multivalent Aqueous Batteries." Materials 14, no. 9 (2021): 2310. http://dx.doi.org/10.3390/ma14092310.

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Research efforts have been focused on developing multivalent ion batteries because they hold great promise and could be a major advancement in energy storage, since two or three times more charge per ion can be transferred as compared with lithium. However, their application is limited because of the lack of suitable cathode materials to reversibly intercalate multivalent ions. From that perspective, vanadium pentoxide is a promising cathode material because of its low toxicity, ease of synthesis, and layered structure, which provides huge possibilities for the development of energy storage de

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Li, Yuqi, Yaxiang Lu, Philipp Adelhelm, Maria-Magdalena Titirici, and Yong-Sheng Hu. "Intercalation chemistry of graphite: alkali metal ions and beyond." Chemical Society Reviews 48, no. 17 (2019): 4655–87. http://dx.doi.org/10.1039/c9cs00162j.

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This review compares the intercalation behaviors of alkali metal ions in graphite, offers insight for the host-guest interaction mechanisms, and expands the intercalation chemistry of pure ions to complex anions, ion-solvent, and multivalent ions.

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Hao, Qing-Hai, Qian Chen, Zhen Zheng, et al. "Molecular dynamics simulations of cylindrical polyelectrolyte brushes in monovalent and multivalent salt solutions." Journal of Theoretical and Computational Chemistry 15, no. 03 (2016): 1650026. http://dx.doi.org/10.1142/s0219633616500267.

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Molecular dynamics simulations are applied to investigate the cylindrical polyelectrolyte brushes in monovalent and multivalent salt solutions. By varying the salt valence and concentration, the brush thickness, shape factor of grafted chains, and distributions of monomers and ions in the solutions are studied. The simulation results show that the single osmotic pressure effect in the brush leads to changes in conformation in the presence of monovalent salt, while the ion exchange effect induces the collapse of the brushes in the multivalent salt solutions. Furthermore, the snapshots combined

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Gao, Qiang, Jeremy Come, Michael Naguib, Stephen Jesse, Yury Gogotsi, and Nina Balke. "Synergetic effects of K+and Mg2+ion intercalation on the electrochemical and actuation properties of the two-dimensional Ti3C2MXene." Faraday Discussions 199 (2017): 393–403. http://dx.doi.org/10.1039/c6fd00251j.

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Two-dimensional materials, such as MXenes, are attractive candidates for energy storage and electrochemical actuators due to their high volume changes upon ion intercalation. Of special interest for boosting energy storage is the intercalation of multivalent ions such as Mg<sup>2+</sup>, which suffers from sluggish intercalation and transport kinetics due to its ion size. By combining traditional electrochemical characterization techniques with electrochemical dilatometry and contact resonance atomic force microscopy, the synergetic effects of the pre-intercalation of K<sup>+</sup>ions are dem

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Li, Le, Weizhuo Zhang, Weijie Pan, et al. "Application of expanded graphite-based materials for rechargeable batteries beyond lithium-ions." Nanoscale 13, no. 46 (2021): 19291–305. http://dx.doi.org/10.1039/d1nr05873h.

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In this review, we evaluate and summarize the application of expanded graphite-based materials in rechargeable batteries, including alkaline ions (such as Na+, K+) storage and multivalent ion (such as Mg2+, Zn2+, Ca2+ and Al3+) storage batteries.

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Stadie, Nicholas P. "(Invited) Zeolite-Templated Carbon As a Model Material for Electrochemical Energy Storage in Nanometre-Spaced Carbon Channels." ECS Meeting Abstracts MA2022-01, no. 7 (2022): 659. http://dx.doi.org/10.1149/ma2022-017659mtgabs.

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Beyond lithium-ion battery (LIB) chemistries demand new electrode materials exhibiting unique features to accommodate the larger and/or multivalent active ions. Zeolite-templated carbon (ZTC) is an ordered microporous carbon scaffold that is molecularly thin, electrically conductive, and covalently connected in three dimensions. Its narrow pore size distribution is centered at 1.2 nm, permitting the introduction and ultrafast conduction of large molecular guests. In this work, we demonstrate the serviceability of ZTC as a stable cathode material across wide voltage ranges for both bulky, polya

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Fu, Wangqin, Marliyana Aizudin, Pooi See Lee, and Edison Huixiang Ang. "Recent Progress in the Applications of MXene‐Based Materials in Multivalent Ion Batteries." Small, August 13, 2024. http://dx.doi.org/10.1002/smll.202404093.

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AbstractMultivalent‐ion batteries have garnered significant attention as promising alternatives to traditional lithium‐ion batteries due to their higher charge density and potential for sustainable energy storage solutions. Nevertheless, the slow diffusion of multivalent ions is the primary issue with electrode materials for multivalent‐ion batteries. In this review, the suitability of MXene‐based materials for multivalent‐ion batteries applications is explored, focusing onions such as magnesium (Mg2+), aluminum (Al3+), zinc (Zn2+), and beyond. The unique structure of MXene offers large interl

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Xu, Zikang, Ruiqi Ren, Hang Ren, et al. "Potassium ion pre-intercalated MnO2 for aqueous multivalent ion batteries." Frontiers of Optoelectronics 16, no. 1 (2023). http://dx.doi.org/10.1007/s12200-023-00093-0.

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AbstractManganese dioxide (MnO2), as a cathode material for multivalent ion (such as Mg2+ and Al3+) storage, is investigated due to its high initial capacity. However, during multivalent ion insertion/extraction, the crystal structure of MnO2 partially collapses, leading to fast capacity decay in few charge/discharge cycles. Here, through pre-intercalating potassium-ion (K+) into δ-MnO2, we synthesize a potassium ion pre-intercalated MnO2, K0.21MnO2·0.31H2O (KMO), as a reliable cathode material for multivalent ion batteries. The as-prepared KMO exhibits a high reversible capacity of 185 mAh/g

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Guo, Juchen, Jennifer L. Schaefer, and Yuyan Shao. "Rechargeable Multivalent-Ion Batteries." Energy Material Advances, July 8, 2024. http://dx.doi.org/10.34133/energymatadv.0112.

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Tong, Zhongqiu, Xing Zhu, Hongbo Xu, et al. "Multivalent‐Ion Electrochromic Energy Saving and Storage Devices." Advanced Functional Materials, January 4, 2024. http://dx.doi.org/10.1002/adfm.202308989.

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AbstractElectrochromic devices (ECDs) show promising applications in various fields including energy‐saving smart windows, energy‐recycling batteries/supercapacitors, displays, thermal management, etc. Compared to monovalent cations (H+, Li+, Na+, and K+), multivalent‐ion carriers (Mg2+, Ca2+, Zn2+, and Al3+) can enable the ECDs with high optical contrast, high energy‐recycling capability, and attractive long‐term stability because of the multiple‐electron transfer redox. Additionally, Mg2+, Zn2+, and Al3+‐based ECDs assembled with metal anodes are exploited for applications in EC electronics,

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Tang, Xiao, Dong Zhou, Bao Zhang, et al. "A universal strategy towards high–energy aqueous multivalent–ion batteries." Nature Communications 12, no. 1 (2021). http://dx.doi.org/10.1038/s41467-021-23209-6.

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AbstractRechargeable multivalent metal (e.g., Ca, Mg or, Al) batteries are ideal candidates for large–scale electrochemical energy storage due to their intrinsic low cost. However, their practical application is hampered by the low electrochemical reversibility, dendrite growth at the metal anodes, sluggish multivalent–ion kinetics in metal oxide cathodes and, poor electrode compatibility with non–aqueous organic–based electrolytes. To circumvent these issues, here we report various aqueous multivalent–ion batteries comprising of concentrated aqueous gel electrolytes, sulfur–containing anodes

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