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Artykuły w czasopismach na temat „La2Ce2O7”

Autor: Grafiati

Data publikacji: 2 czerwca 2025

Data aktualizacji: 31 lipca 2025

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1

Chao, Jiameng, Hui Lin, Dechao Yu, et al. "Optical Temperature-Sensing Performance of La2Ce2O7:Ho3+ Yb3+ Powders." Materials 17, no. 7 (2024): 1692. http://dx.doi.org/10.3390/ma17071692.

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In this paper, La2Ce2O7 powders co-activated by Ho3+ and Yb3+ were synthesized by a high temperature solid-state reaction. Both Ho3+ and Yb3+ substitute the La3+ sites in the La2Ce2O7 lattice, where the Ho3+ concentration is 0.5 at.% and the Yb3+ concentration varies in the range of 10~18% at.%. Pumped by a 980 nm laser, the up-conversion (UC) green emission peak at 547 nm and the red emission at 661 nm were detected. When the doping concentration of Ho3+ and Yb3+ are 0.5 at.% and 14% at.%, respectively, the UC emission reaches the strongest intensity. The temperature-sensing performance of La

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2

Zhou, Zeling, Chao Li, Junfeng Zhang, et al. "Dry Reforming of Methane over Pyrochlore-Type La2Ce2O7-Supported Ni Catalyst: Effect of Particle Size of Support." Molecules 29, no. 8 (2024): 1871. http://dx.doi.org/10.3390/molecules29081871.

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The properties of supports (such as oxygen vacancies, oxygen species properties, etc.) significantly impact the anti-carbon ability due to their promotional effect on the activation of CO2 in dry reforming of methane (DRM). Herein, pyrochlore-type La2Ce2O7 compounds prepared using co-precipitation (CP), glycine nitrate combustion (GNC) and sol–gel (S-G) methods, which have highly thermal stability and unique oxygen mobility, are applied as supports to prepare Ni-based catalysts for DRM. The effect of the calcining temperature (500, 600 and 700 °C) on La2Ce2O7(CP) has also been investigated. Ba

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3

Fung, Kuan-Zong, and Shu-Yi Tsai. "Evaluation of La2Ce2O7 (LCO) Protection Layer for Proton Conducting Electrolyte." ECS Meeting Abstracts MA2022-02, no. 47 (2022): 1787. http://dx.doi.org/10.1149/ma2022-02471787mtgabs.

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Due to the susceptible reaction BaCeO3-based proton-conductors toward steam and carbon dioxide, La2Ce2O7(LCO) is proposed as a protect layer on top of solid electrolyte since LCO has shown high proton conductivity with adequate stability against steam. In the study, La(NO3)3·6H₂O and Ce(NO3)3·6H₂O were used as precursors to obtain La2Ce2O7(LCO). Particle size analyzer and XRD are applied to analysis this result. From the XRD analysis, it can be seen at the temperature range above 900°C, the reflections representing fluorite-structured LCO appeared with other reflections from BaCe0.5Zr0.3Y0.2O3

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4

Wang, Xue Ying, Yong Ping Zhu, and Wei Gang Zhang. "Preparation of La₂Ce₂O₇ Nano-Powders by Molten Salts Method." Advanced Materials Research 79-82 (August 2009): 337–40. http://dx.doi.org/10.4028/www.scientific.net/amr.79-82.337.

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La2Ce2O7 nano-powders with cubic fluorite structure have been firstly prepared by Molten Salts method. These nano-powders were prepared at relatively low temperatures(800°C and 900 °C) at different time, using La(NO3)3•6H2O and La(NO3)3•6H2O as raw materials, as well as K2SO4 (anhydrous) and Na2SO4 (anhydrous) as molten salts and dispersant. XRD, SEM were used to characterize the composition, morphology and size of prepared products. The procedure is facile and suitable for the synthesis of the La2Ce2O7 nano-particles and it will be an excellent method for preparation of other pyrochlore type

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5

Vieri, Hizkia Manuel, Arash Badakhsh, and Sun Hee Choi. "Comparative Study of Ba, Cs, K, and Li as Promoters for Ru/La2Ce2O7-Based Catalyst for Ammonia Synthesis." International Journal of Energy Research 2023 (May 13, 2023): 1–11. http://dx.doi.org/10.1155/2023/2072245.

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Ammonia is one of the promising carriers for hydrogen and a critical ingredient in many industries including fertilizers and pharmaceuticals. In the KAAP process, ruthenium- (Ru-) based catalysts showed 10-20 more activity compared with iron- (Fe-) based catalysts. The modifications that are applied to Ru-based catalysts revolve around changing the material of its support and/or promoters. This study compares the performance of a Ru-based catalyst for ammonia synthesis supported by La2Ce2O7 using barium (Ba), cesium (Cs), potassium (K), and lithium (Li) as promoters. Based on structural, physi

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6

Lashmi, P. G., N. Balaji, S. Senthil Kumar, and S. T. Aruna. "Hot corrosion properties of plasma sprayed La2Ce2O7/YSZ vis-à-vis La2Ce2O7/cluster paired zirconia thermal barrier coatings." Surface and Coatings Technology 409 (March 2021): 126902. http://dx.doi.org/10.1016/j.surfcoat.2021.126902.

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7

Yoon, So-Young, Sung-Min Lee, Kwang-Bo Shim, and Hyung-Tae Kim. "High Temperature Thermal Conductivities in La2Ce2O7−Gd2Ce2O7−Y2Ce2O7Pyrochlore System for Thermal Barrier Coatings." Journal of the Korean Ceramic Society 44, no. 7 (2007): 387–92. http://dx.doi.org/10.4191/kcers.2007.44.7.387.

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8

Zhang, F. X., C. L. Tracy, M. Lang, and R. C. Ewing. "Stability of fluorite-type La2Ce2O7 under extreme conditions." Journal of Alloys and Compounds 674 (July 2016): 168–73. http://dx.doi.org/10.1016/j.jallcom.2016.03.002.

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9

Xu, Ya-Xin, Tao Liu, Guan-Jun Yang, and Chang-Jiu Li. "Thermal stability of plasma-sprayed La2Ce2O7/YSZ composite coating." Ceramics International 42, no. 7 (2016): 7950–61. http://dx.doi.org/10.1016/j.ceramint.2016.01.179.

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10

Khademinia, Shahin, and Mahdi Behzad. "Lanthanum cerate (La2Ce2O7): hydrothermal synthesis, characterization and optical properties." International Nano Letters 5, no. 2 (2015): 101–7. http://dx.doi.org/10.1007/s40089-015-0143-x.

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11

Zhu, Zhiwen, Bitao Liu, Jianxing Shen, Youxin Lou, and Yuexia Ji. "La2Ce2O7: A promising proton ceramic conductor in hydrogen economy." Journal of Alloys and Compounds 659 (February 2016): 232–39. http://dx.doi.org/10.1016/j.jallcom.2015.11.041.

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12

Song, Daheoi, and Miewon Jung. "Ni-coated La2Ce2O7/SiC Membrane via DC Magnetron Sputtering." Bulletin of the Korean Chemical Society 37, no. 6 (2016): 970–73. http://dx.doi.org/10.1002/bkcs.10789.

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13

Parchovianská, Ivana, Milan Parchovianský, Beáta Pecušová, Ondrej Hanzel, and Amirhossein Pakseresht. "Synthesis and Characterization of Fluorite-Type La2Ce2O7 Plasma Sprayable Powder for TBCs Application." Materials 15, no. 11 (2022): 4007. http://dx.doi.org/10.3390/ma15114007.

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This work focuses on the fabrication of lanthanum cerate (La2Ce2O7, LC) powders via two chemical routes: modified Pechini sol-gel method and solid-state synthesis. The synthesized LC powders were heat treated in the temperature range of 1000–1400 °C for 6 h and investigated as a material for thermal barrier coating (TBC) applications. For this purpose, the powder morphology, chemical composition, crystal structure and thermal stability were studied. Scanning electron microscopy (SEM) of the synthesized powders revealed an agglomerated structure consisting of fine and uniformly distributed grai

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14

YAMAMURA, Hiroshi, Hanako NISHINO, and Katsuyoshi KAKINUMA. "Ac Conductivity for Eu2Zr2O7 and La2Ce2O7 with Pyrochlore-Type Composition." Journal of the Ceramic Society of Japan 112, no. 1310 (2004): 553–58. http://dx.doi.org/10.2109/jcersj.112.553.

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15

Han, Wenfeng, Zhi Li, and Huazhang Liu. "La2Ce2O7 supported ruthenium as a robust catalyst for ammonia synthesis." Journal of Rare Earths 37, no. 5 (2019): 492–99. http://dx.doi.org/10.1016/j.jre.2018.09.010.

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16

Tu, Taiping, Bo Zhang, Jian Liu, Kewen Wu, and Kaiping Peng. "Synthesis and conductivity behaviour of Mo-doped La2Ce2O7 proton conductors." Electrochimica Acta 283 (September 2018): 1366–74. http://dx.doi.org/10.1016/j.electacta.2018.07.032.

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17

Yi, Hao, Junwei Che, Zihui Xu, Gongying Liang, and Xiangyang Liu. "Sintering resistance of La2Ce2O7, La2Zr2O7, and yttria stabilized zirconia ceramics." Ceramics International 47, no. 3 (2021): 4197–205. http://dx.doi.org/10.1016/j.ceramint.2020.09.298.

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18

Dong, Hongying, Dongxing Wang, Yanling Pei, Houyang Li, Peng Li, and Wen Ma. "Optimization and thermal cycling behavior of La2Ce2O7 thermal barrier coatings." Ceramics International 39, no. 2 (2013): 1863–70. http://dx.doi.org/10.1016/j.ceramint.2012.08.034.

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19

Dehkharghani, A. M. Fathi, M. R. Rahimipour, and M. Zakeri. "Improving the thermal shock resistance and fracture toughness of synthesized La2Ce2O7 thermal barrier coatings through formation of La2Ce2O7/YSZ composite coating via air plasma spraying." Surface and Coatings Technology 399 (October 2020): 126174. http://dx.doi.org/10.1016/j.surfcoat.2020.126174.

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20

Zhao, Xianli, Qianwen Wang, Wei Liu, et al. "Biaxial stress in La2Ce2O7/YSZ thermal barrier coatings for oxidation evolution." Surface and Coatings Technology 447 (October 2022): 128809. http://dx.doi.org/10.1016/j.surfcoat.2022.128809.

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21

Kalland, Liv-Elisif, and Chris E. Mohn. "First principles calculations on order and disorder in La2Ce2O7 and Nd2Ce2O7." Physical Chemistry Chemical Physics 22, no. 25 (2020): 13930–41. http://dx.doi.org/10.1039/d0cp00921k.

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22

Zhao, Cong, Wenting He, Liangliang Wei, and Hongbo Guo. "Microstructures of La2Ce2O7 coatings produced by plasma spray-physical vapor deposition." Journal of the European Ceramic Society 40, no. 4 (2020): 1462–70. http://dx.doi.org/10.1016/j.jeurceramsoc.2019.11.042.

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23

Zhao, Cong, Wenting He, Jia Shi, Qian Guo, Jimeng Li, and Hongbo Guo. "Deposition mechanisms of columnar structured La2Ce2O7 coatings via plasma spray-PVD." Ceramics International 46, no. 9 (2020): 13424–32. http://dx.doi.org/10.1016/j.ceramint.2020.02.125.

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24

Feng, Bei-Bei, Yi Wang, Qiang Jia, Wei Huang, Hong-Li Suo, and Wen Ma. "Thermophysical properties of solution precursor plasma-sprayed La2Ce2O7 thermal barrier coatings." Rare Metals 38, no. 7 (2019): 689–94. http://dx.doi.org/10.1007/s12598-019-01286-3.

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25

Xia, Jie, Xuelin Du, Yiqi Xiao, Ling Zhang, Rudder Tse Wu, and Yoshitaka Matsushita. "Mechanisms of La2Ce2O7/YSZ Double-Ceramic-Layer Thermal Barrier Coatings against Volcanic Ash Corrosion." Coatings 14, no. 7 (2024): 877. http://dx.doi.org/10.3390/coatings14070877.

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To tackle the ever-increasing operating temperature of aero-engines, a La2Ce2O7 (LCO)/yttria partially stabilized zirconia (YSZ) double-layer thermal barrier coating (TBC) was investigated. The LCO/YSZ double-layer samples were annealed with volcanic ash (VA) at 1250 °C to assess their stability in comparison with that of standard single-layer YSZ. The findings showed that the double-layer system exhibited greater resistance to VA damage than the single-layer YSZ coating. The corrosion mechanism was characterized by a rapid crystallization reaction between LCO and VA, where the kinetics of the

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26

Choudhary, Bishnu, Sharmistha Anwar, Dmitry A. Medvedev, Laxmidhar Besra, and Shahid Anwar. "Effect of sintering temperature on the transport properties of La2Ce2O7 ceramic materials." Ceramics International 48, no. 5 (2022): 6758–66. http://dx.doi.org/10.1016/j.ceramint.2021.11.227.

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27

Ismail, Sara Adeeba, Lulu Jiang, Peng Zhong, Truls Norby, and Donglin Han. "La2Ce2O7 doped with alkaline earth elements: Phase behavior, hydration and electrical properties." Journal of Alloys and Compounds 899 (April 2022): 163306. http://dx.doi.org/10.1016/j.jallcom.2021.163306.

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28

Gao, Lihua, Fang Jia, and Xiaoliang Lu. "Preparation and Thermal Shock Resistance of Gd2O3 Doped La2Ce2O7 Thermal Barrier Coatings." Coatings 11, no. 10 (2021): 1186. http://dx.doi.org/10.3390/coatings11101186.

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As one of the promising thermal barrier coating (TBC) candidates, stoichiometric (La0.8Gd0.2)2Ce2O7 (LGC) coatings were prepared by atmospheric plasma spraying (APS), using (La0.8Gd0.2)2Ce2.5O8 as a spray powder and optimized spray parameters. It was found that spray distance and spray power both play an important role in the phase composition and microstructure of the coating. The LGC coating exhibited lower thermal conductivities than that of La2Ce2O7 (LC) coating, which is ~0.67 W/m·K at 1200 °C. Double-ceramic-layer (DCL) optimum (La0.8Gd0.2)2Ce2O7/YSZ (LGC/YSZ) thermal barrier coating was

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29

Wang, Yurui, Lin Li, Fuhua Xu, Shuang Li, Yixiang Shi, and Ningsheng Cai. "Enhancing diesel steam reforming activity by oxygen vacancy on La2Ce2O7 pyrochlore carrier." Fuel 373 (October 2024): 132296. http://dx.doi.org/10.1016/j.fuel.2024.132296.

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30

Besikiotis, Vasileios, Christopher S. Knee, Istaq Ahmed, Reidar Haugsrud, and Truls Norby. "Crystal structure, hydration and ionic conductivity of the inherently oxygen-deficient La2Ce2O7." Solid State Ionics 228 (November 2012): 1–7. http://dx.doi.org/10.1016/j.ssi.2012.08.023.

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31

Gao, Lihua, Hongbo Guo, Shengkai Gong, and Huibin Xu. "Plasma-sprayed La2Ce2O7 thermal barrier coatings against calcium–magnesium–alumina–silicate penetration." Journal of the European Ceramic Society 34, no. 10 (2014): 2553–61. http://dx.doi.org/10.1016/j.jeurceramsoc.2014.02.031.

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32

Mantry, S., A. Mandal, D. K. Mishra, B. B. Jha, B. K. Mishra, and M. Chakraborty. "Microstructure and Thermal Characterization of Plasma-Sprayed Nanostructured La2Ce2O7-Doped YSZ Coatings." Journal of Thermal Spray Technology 23, no. 7 (2014): 1073–80. http://dx.doi.org/10.1007/s11666-014-0070-9.

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33

Shi, Shikao, Lina Wang, Ming Fang, et al. "Blue-light excitable La2Ce2O7:Eu3+ red phosphors for white light-emitting diodes." Journal of Alloys and Compounds 814 (January 2020): 152226. http://dx.doi.org/10.1016/j.jallcom.2019.152226.

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34

Zamudio-García, Javier, Lucía dos Santos-Gómez, José Manuel Porras-Vázquez, Enrique R. Losilla, and David Marrero-López. "Doping effects on the structure and electrical properties of La2Ce2O7 proton conductors." Journal of Alloys and Compounds 816 (March 2020): 152600. http://dx.doi.org/10.1016/j.jallcom.2019.152600.

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35

Zhang, Qingping, Xiao Zheng, Jun Jiang, and Wei Liu. "Structural Stability of La2Ce2O7 as a Proton Conductor: A First-Principles Study." Journal of Physical Chemistry C 117, no. 40 (2013): 20379–86. http://dx.doi.org/10.1021/jp403660y.

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36

Besikiotis, Vasileios, Chris S. Knee, Istaq Ahmed, Reidar Haugsrud, and Truls Norby. "Crystal structure, hydration, and ionic conductivity of the inherently oxygen-deficient La2Ce2O7." Solid State Ionics 228 (August 29, 2012): 1–7. https://doi.org/10.1016/j.ssi.2012.08.023.

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The crystal structure, hydration and ionic conductivity of the inherently oxygen deficient La2Ce2O7 system have been investigated. On the basis of Rietveld analysis of neutron diffraction data, the material is found to adopt a cation disordered oxygen-deficient fluorite structure. Impedance spectroscopy, performed in the temperature range 1000-200 °C and as a function of water vapour and oxygen partial pressure, suggests that oxide ion conductivity dominates at high temperatures, while protons are the main charge carrier at temperatures below approximately 450 °C. Proton conductivity was confi

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37

Zeng, Shenghao, Zhoufu Wang, Yan Ma, Hao Liu, and Zhenghuang Quan. "Effect of LaPO4 on thermal expansion coefficient and fracture toughness of La2Ce2O7 ceramics." Journal of Alloys and Compounds 1012 (January 2025): 178544. https://doi.org/10.1016/j.jallcom.2025.178544.

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38

Bai, Y., W. Fan, K. Liu, Y. X. Kang, Y. Gao, and F. Ma. "Gradient La2Ce2O7/YSZ thermal barrier coatings tailored by synchronous dual powder feeding system." Materials Letters 219 (May 2018): 55–58. http://dx.doi.org/10.1016/j.matlet.2018.02.050.

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39

Liu, X. Y., H. Yi, J. W. Che, and G. Y. Liang. "Phase, compositional, structural, and chemical stability of La2Ce2O7 after high temperature heat treatment." Ceramics International 45, no. 4 (2019): 5030–35. http://dx.doi.org/10.1016/j.ceramint.2018.11.204.

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40

Tu, Taiping, Jian Liu, and Kaiping Peng. "Preparation and performance of Na-doped La2Ce2O7 electrolytes for protonic ceramic fuel cells." Ceramics International 43, no. 18 (2017): 16384–90. http://dx.doi.org/10.1016/j.ceramint.2017.09.013.

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41

Zhang, Mohan, Di Wang, Lina Miao, Zongzi Jin, Kuan Dong, and Wei Liu. "A series of alkali metal elements doped La2Ce2O7 electrolytes for solid oxide fuel cells." Electrochemistry Communications 126 (May 2021): 107026. http://dx.doi.org/10.1016/j.elecom.2021.107026.

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42

Sharma, Jai Kumar, Ritu Raj, Sateesh Kumar, Ratan Kumar Jain, and Mukesh Pandey. "Finite element modelling of Lanthanum Cerate (La2Ce2O7) coated piston used in a diesel engine." Case Studies in Thermal Engineering 25 (June 2021): 100865. http://dx.doi.org/10.1016/j.csite.2021.100865.

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43

Liu, Ying, Yu Bai, Enbo Li, et al. "Preparation and characterization of SrZrO3–La2Ce2O7 composite ceramics as a thermal barrier coating material." Materials Chemistry and Physics 247 (June 2020): 122904. http://dx.doi.org/10.1016/j.matchemphys.2020.122904.

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44

Wang, Yue, Chunjie Wang, Chao Li, Yongliang Cheng, and Feng Chi. "Influence of different surfactants on crystal growth behavior and sinterability of La2Ce2O7 solid solution." Ceramics International 40, no. 3 (2014): 4305–10. http://dx.doi.org/10.1016/j.ceramint.2013.08.096.

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45

Guo, Hongbo, Yi Wang, Lu Wang, and Shengkai Gong. "Thermo-Physical Properties and Thermal Shock Resistance of Segmented La2Ce2O7/YSZ Thermal Barrier Coatings." Journal of Thermal Spray Technology 18, no. 4 (2009): 665–71. http://dx.doi.org/10.1007/s11666-009-9350-1.

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46

Hong-song, Zhang, Chen Xiao-ge, Li Gang, Wang Xin-Li, and Dang Xu-dan. "Influence of Gd2O3 addition on thermophysical properties of La2Ce2O7 ceramics for thermal barrier coatings." Journal of the European Ceramic Society 32, no. 14 (2012): 3693–700. http://dx.doi.org/10.1016/j.jeurceramsoc.2012.06.003.

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47

Wang, Yi, Hongbo Guo, and Shengkai Gong. "Thermal shock resistance and mechanical properties of La2Ce2O7 thermal barrier coatings with segmented structure." Ceramics International 35, no. 7 (2009): 2639–44. http://dx.doi.org/10.1016/j.ceramint.2009.02.025.

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48

Yang, Chunli, Jun Li, Wei Yao, Lei Wang, Yanru Liang, and Kai Wang. "Alkaline earth metal-doped La2Ce2O7 mixed-conductors: optimization of hydrogen permeation and environmental stability." Journal of Membrane Science 734 (October 2025): 124420. https://doi.org/10.1016/j.memsci.2025.124420.

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49

Lakshya, Annu Kumar, Lakshaman Kumar, Kundan Kumar, and Anirban Chowdhury. "Crucial dependence of ‘trivial’ processing factors on the texture-electrical resistivity relationship of La2Ce2O7 ceramic." Materials Letters 314 (May 2022): 131858. http://dx.doi.org/10.1016/j.matlet.2022.131858.

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50

Dong, Shujuan, Fengning Zhang, Neng Li, et al. "Thermal radiation and cycling properties of (Ca, Fe) or (Sr, Mn) co-doped La2Ce2O7 coatings." Journal of the European Ceramic Society 40, no. 5 (2020): 2020–29. http://dx.doi.org/10.1016/j.jeurceramsoc.2020.01.012.

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