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1

Pererva, O. P., D. V. Klushin, A. V. Pankrushina, and O. P. Shumakova. "Computer simulation of static and dynamic modes of separation of products of direct synthesis of methyl chlorosilanes, using three-section column." Chemical Engineering 25, no. 12 (2024): 466–76. https://doi.org/10.31044/1684-5811-2024-25-12-466-476.

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Computer simulation of the primary separation of methylchlorosilanes direct synthesis products has been performed. The developed scheme for controlling process parameters with fluctuations in input flow parameters provides products of sustained quality, 99.963±0.004 wt% of methyl chloride in pure methyl chloride and 0.0475±0.0015 wt% of methyl chloride in crude methylchlorosilanes
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2

Blaser, Eugénie, Cécile Rosier, Michel Huet, Christophe Geantet, and Stéphane Loridant. "Catalytic cracking of CH3Cl on copper-based phases." Catalysis Science & Technology 12, no. 6 (2022): 2006–14. http://dx.doi.org/10.1039/d1cy02226a.

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CuCl and Cu are active phases for CH3Cl cracking, a side reaction of the methylchlorosilanes direct synthesis. In the presence of black carbon simulating coke, CuCl is reduced leading to Cu, inactive for the direct synthesis, and chlorinated coke.
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3

Clarke, Michael P. "The direct synthesis of methylchlorosilanes." Journal of Organometallic Chemistry 376, no. 2-3 (1989): 165–222. http://dx.doi.org/10.1016/0022-328x(89)85131-9.

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4

Kim, Jong Pal. "TPD study for direct synthesis of methylchlorosilanes." Korean Journal of Chemical Engineering 12, no. 4 (1995): 454–59. http://dx.doi.org/10.1007/bf02705810.

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5

Lorey, Lars, and Gerhard Roewer. "The direct synthesis of methylchlorosilanes: New aspects concerning its mechanism." Silicon Chemistry 1, no. 4 (2002): 299–308. http://dx.doi.org/10.1023/b:silc.0000018400.24117.89.

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6

Acker, Jörg, and Klaus Bohmhammel. "Thermodynamic assessment of the copper catalyzed direct synthesis of methylchlorosilanes." Journal of Organometallic Chemistry 693, no. 15 (2008): 2483–93. http://dx.doi.org/10.1016/j.jorganchem.2008.04.026.

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7

Okamoto, Masaki, Satoshi Onodera, Tomoki Okano, Eiichi Suzuki, and Yoshio Ono. "Intermediacy of surface silylene in the direct synthesis of methylchlorosilanes." Journal of Organometallic Chemistry 531, no. 1-2 (1997): 67–71. http://dx.doi.org/10.1016/s0022-328x(96)06713-7.

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8

Gordon, Alexander D., B. J. Hinch, and Daniel R. Strongin. "Effects of individual promoters on the Direct Synthesis of methylchlorosilanes." Journal of Catalysis 266, no. 2 (2009): 291–98. http://dx.doi.org/10.1016/j.jcat.2009.06.026.

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9

GASPERGALVIN, L. "Role of metallic promoters in the direct synthesis of methylchlorosilanes." Journal of Catalysis 128, no. 2 (1991): 468–78. http://dx.doi.org/10.1016/0021-9517(91)90304-m.

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10

Clarke, Michael P., and Iain M. T. Davidson. "The role of silylenes in the direct synthesis of methylchlorosilanes." Journal of Organometallic Chemistry 408, no. 2 (1991): 149–56. http://dx.doi.org/10.1016/0022-328x(91)86378-4.

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11

BANHOLZER, W. F., W. J. WARD, and A. RITZER. "ChemInform Abstract: Some Consideration of the Direct Synthesis of Methylchlorosilanes." ChemInform 25, no. 34 (2010): no. http://dx.doi.org/10.1002/chin.199434286.

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12

Wang, Chao, Tong Liu, Yunlong Huang, Guangrun Wang, and Jinfu Wang. "Promoter Effects of Zn and Sn in the Direct Synthesis of Methylchlorosilanes." Industrial & Engineering Chemistry Research 52, no. 15 (2013): 5282–86. http://dx.doi.org/10.1021/ie303515q.

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13

KIM, J. "The direct synthesis of methylchlorosilanes I. Steady-state and transient reaction kinetics." Journal of Catalysis 134, no. 1 (1992): 168–78. http://dx.doi.org/10.1016/0021-9517(92)90219-8.

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14

GASPER-GALVIN, L. D., D. M. SEVENICH, H. B. FRIEDRICH, and D. G. RETHWISCH. "ChemInform Abstract: Role of Metallic Promoters in the Direct Synthesis of Methylchlorosilanes." ChemInform 22, no. 26 (2010): no. http://dx.doi.org/10.1002/chin.199126081.

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15

de Cooker, M. G. R. T., and P. J. van Den Berg. "The direct synthesis of methylchlorosilanes: Kinetic measurements with a gas flow calorimeter." Recueil des Travaux Chimiques des Pays-Bas 94, no. 8 (2010): 192–95. http://dx.doi.org/10.1002/recl.19750940806.

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16

Voorhoeve, R. J. H., and J. C. Vlugter. "Tin and lead as selective catalysts in the direct synthesis of methylchlorosilanes." Recueil des Travaux Chimiques des Pays-Bas 82, no. 6 (2010): 605–15. http://dx.doi.org/10.1002/recl.19630820610.

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17

CLARKE, M. P., and I. M. T. DAVIDSON. "ChemInform Abstract: The Role of Silylenes in the Direct Synthesis of Methylchlorosilanes." ChemInform 22, no. 32 (2010): no. http://dx.doi.org/10.1002/chin.199132193.

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18

Seyferth, Dietmar. "Dimethyldichlorosilane and the Direct Synthesis of Methylchlorosilanes. The Key to the Silicones Industry†." Organometallics 20, no. 24 (2001): 4978–92. http://dx.doi.org/10.1021/om0109051.

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19

Wessel, T. J., and D. G. Rethwisch. "Activation of CuSi and CuZnSnSi contact masses for the direct synthesis of methylchlorosilanes." Reaction Kinetics & Catalysis Letters 58, no. 1 (1996): 7–12. http://dx.doi.org/10.1007/bf02071098.

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20

Floquet, N., S. Yilmaz, and J. L. Falconer. "Interaction of Copper Catalysts and Si(100) for the Direct Synthesis of Methylchlorosilanes." Journal of Catalysis 148, no. 1 (1994): 348–68. http://dx.doi.org/10.1006/jcat.1994.1216.

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21

LEWIS, K. M., R. A. CAMERON, and J. M. LARNERD. "ChemInform Abstract: Selection of Copper Formate Catalysts for the Direct Synthesis of Methylchlorosilanes." ChemInform 25, no. 34 (2010): no. http://dx.doi.org/10.1002/chin.199434287.

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22

Wessel, T. J., and D. G. Rethwisch. "Deactivation of CuSi and CuZnSnSi Due to Coke Formation during the Direct Synthesis of Methylchlorosilanes." Journal of Catalysis 161, no. 2 (1996): 861–66. http://dx.doi.org/10.1006/jcat.1996.0248.

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23

KIM, J. P., and D. G. RETHWISCH. "ChemInform Abstract: The Direct Synthesis of Methylchlorosilanes. Part 1. Steady-State and Transient Reaction Kinetics." ChemInform 23, no. 22 (2010): no. http://dx.doi.org/10.1002/chin.199222048.

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24

FLOQUET, N., S. YILMAZ, and J. L. FALCONER. "ChemInform Abstract: Interaction of Copper Catalysts and Si(100) for the Direct Synthesis of Methylchlorosilanes." ChemInform 25, no. 44 (2010): no. http://dx.doi.org/10.1002/chin.199444055.

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25

DORAISWAMY, L. K., and A. N. GOKARN. "ChemInform Abstract: Catalyst Preparation of the Direct Synthesis of Methylchlorosilanes: Practical, Theoretical, and Reactor Design Considerations." ChemInform 25, no. 34 (2010): no. http://dx.doi.org/10.1002/chin.199434288.

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26

Gordon, Alexander D., B. J. Hinch, and Daniel R. Strongin. "Effects of Multiple Promotion of the Direct Synthesis Contact Mass with P, Zn, and Sn on the Synthesis of Methylchlorosilanes." Catalysis Letters 133, no. 1-2 (2009): 14–22. http://dx.doi.org/10.1007/s10562-009-0172-z.

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27

Jiang, Yiqian, Weiguang Chen, Yanjun Liu, et al. "Synthesis of Trimethylchlorosilane by [BMIM]Cl−nAlCl3Ionic Liquids-Catalyzed Redistribution between Methyltrichlorosilane and Low-Boiling Products from the Direct Synthesis of Methylchlorosilanes." Industrial & Engineering Chemistry Research 50, no. 4 (2011): 1893–98. http://dx.doi.org/10.1021/ie1022207.

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28

Papernaya, L. K., A. A. Shatrova, A. I. Albanov, and G. G. Levkovskaya. "First example of the synthesis of bis(2-hydroxyethyl)dithioacetals from nitrobenzaldehydes and mercaptoethanol in the presence of methylchlorosilanes." Russian Journal of Organic Chemistry 47, no. 2 (2011): 300–301. http://dx.doi.org/10.1134/s1070428011020242.

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29

Watanabe, Hamao, Yoshinori Akutsu, Akihito Shinohara, et al. "Preparation of New Types of Organosilicon Polymers. Effective Utilization of Disilane Fraction Produced in the Direct Synthesis of Methylchlorosilanes." Chemistry Letters 17, no. 11 (1988): 1883–86. http://dx.doi.org/10.1246/cl.1988.1883.

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30

Papernaya, L. K., A. A. Shatrova, A. I. Albanov, and G. G. Levkovskaya. "ChemInform Abstract: First Example of the Synthesis of Bis(2-hydroxyethyl)dithioacetals from Nitrobenzaldehydes and Mercaptoethanol in the Presence of Methylchlorosilanes." ChemInform 42, no. 32 (2011): no. http://dx.doi.org/10.1002/chin.201132063.

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31

Sun, Dong-Hong, Brian E. Bent, Antony P. Wright, and Brian M. Naasz. "Chemistry of the direct synthesis of methylchlorosilanes. UHV study of the chemisorbed fragments methyl and chlorine on copper silicide and their desorption pathways." Journal of Molecular Catalysis A: Chemical 131, no. 1-3 (1998): 169–83. http://dx.doi.org/10.1016/s1381-1169(97)00264-1.

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32

Missaghi, Michael N., Christopher M. Downing, Mayfair C. Kung, and Harold H. Kung. "Synthesis of Organofunctional Silicon Hydride Halides from Methylchlorosilane." Organometallics 27, no. 23 (2008): 6364–66. http://dx.doi.org/10.1021/om8002625.

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33

WANG, Chao, Guangrun WANG, and Jinfu WANG. "A Bi-component Cu Catalyst for the Direct Synthesis of Methylchlorosilane from Silicon and Methyl Chloride." Chinese Journal of Chemical Engineering 22, no. 3 (2014): 299–304. http://dx.doi.org/10.1016/s1004-9541(14)60034-3.

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34

Luo, Wuxi, Guangrun Wang, and Jinfu Wang. "Effect of CuCl Particle Size on the Reduction Reaction by Silicon in Preparation of Contact Mass Used for Methylchlorosilane Synthesis." Industrial & Engineering Chemistry Research 45, no. 1 (2006): 129–33. http://dx.doi.org/10.1021/ie058044+.

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35

CLARKE, M. P. "ChemInform Abstract: The Direct Synthesis of Methylchlorosilanes." ChemInform 21, no. 7 (1990). http://dx.doi.org/10.1002/chin.199007341.

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36

Blaser, Eugénie, Fabien Baccot, and Cecile Rosier. "Activation of Metallic Copper in the Methylchlorosilanes Synthesis." SSRN Electronic Journal, 2024. http://dx.doi.org/10.2139/ssrn.4941292.

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37

Kalchauer, Wilfried, and Bernd Pachaly. "ChemInform Abstract: Mueller-Rochow Synthesis: The Direct Process to Methylchlorosilanes." ChemInform 40, no. 40 (2009). http://dx.doi.org/10.1002/chin.200940265.

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38

Lorey, L., and G. Roewer. "Reactivity of Doped Silicon in the Direct Synthesis of Methylchlorosilanes." ChemInform 36, no. 20 (2005). http://dx.doi.org/10.1002/chin.200520260.

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39

Zhang, Pan, Dan Zhang, Jipeng Dong, Guanghui Chen, and Jianlong Li. "Direct Synthesis of Methylchlorosilanes: Catalysts, Mechanisms, Reaction Conditions, and Reactor Designs." Organic Process Research & Development, July 12, 2022. http://dx.doi.org/10.1021/acs.oprd.2c00107.

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40

Lewis, Kenrick M., Yanjun Zhu, Abellard T. Mereigh, John Razzano, John D. Neely, and Donald Slick. "Slurry- Phase Direct Synthesis of Methylchlorosilanes and Allylchlorosilanes from Cyclone Fines." SSRN Electronic Journal, 2022. http://dx.doi.org/10.2139/ssrn.4127987.

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41

Riviere, Lucie, Eugénie Blaser, Cecile Rosier, Michel Huet, Christophe Geantet, and Stephane Loridant. "CH3Cl cracking and formation of coke during methylchlorosilanes synthesis: effect of promoters." SSRN Electronic Journal, 2024. http://dx.doi.org/10.2139/ssrn.4943325.

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42

Mahmoodinia, Mehdi, Francesca I. Bleken, Ingeborg-Helene Svenum, et al. "Role of Copper in the Formation of Carbon during Direct Synthesis of Methylchlorosilanes." SSRN Electronic Journal, 2022. http://dx.doi.org/10.2139/ssrn.4118708.

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43

Mahmoodinia, Mehdi, Hammad Farooq, Torbjørn Røe, Ingeborg-Helene Svenum, and Hilde J. Venvik. "Effect of Copper Catalyst Content and Zinc Promoter on Carbon Formation in the Direct Synthesis of Methylchlorosilanes." Industrial & Engineering Chemistry Research, December 9, 2023. http://dx.doi.org/10.1021/acs.iecr.3c02940.

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