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Rozprawy doktorskie na temat „Molybdenum”

Autor: Grafiati

Data publikacji: 4 czerwca 2021

Data aktualizacji: 25 lipca 2025

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1

Ellis, S. R. "Characterisation of molybdenum compounds relevant to the molybdenum cofactor of the oxo-molybdenum enzymes." Thesis, University of Manchester, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.376593.

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2

Rickman, Sarah. "Growth and characterization of molybdenum disulfide, molybdenum diselenide, and molybdenum(sulfide, selenide) formed between molybdenum and copper indium(sulfide, selenide) during growth." Access to citation, abstract and download form provided by ProQuest Information and Learning Company; downloadable PDF file 0.94 Mb., 85 p, 2006. http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&res_dat=xri:pqdiss&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&rft_dat=xri:pqdiss:1435848.

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3

Womiloju, Olusola Olumuyiwa. "(Pentamethylcyclopentadienyl)molybdenum oxides." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1999. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape7/PQDD_0017/NQ54601.pdf.

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4

Bancroft, Matthew N. "Molybdenum-sulfur chemistry." Thesis, University of Sheffield, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.301264.

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5

Paudel, Yadab Kumar. "Tribological properties of adaptive [molybdenum nitride/molybdenum sulfide/silver] nanocomposite coatings /." Available to subscribers only, 2008. http://proquest.umi.com/pqdweb?did=1597633321&sid=7&Fmt=2&clientId=1509&RQT=309&VName=PQD.

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6

Murugappan, Karthick. "Molybdenum trioxide and molybdenum carbide as promising hydrodeoxygenation catalysts for biomass conversion." Thesis, Massachusetts Institute of Technology, 2017. http://hdl.handle.net/1721.1/111404.

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Thesis: Ph. D., Massachusetts Institute of Technology, Department of Chemical Engineering, 2017.<br>Cataloged from PDF version of thesis.<br>Includes bibliographical references (pages 171-176).<br>Growing concerns due to rising CO2 emissions have made biomass an indispensable source of renewable fuels and chemicals. However, biomass inherently has high oxygen content, which translates to low energy density, thereby necessitating a deoxygenation step before being utilized as fuels. Recently, MoO3 and Mo2C have emerged as promising earth-abundant cheap catalysts that perform hydrodeoxygenation (

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7

Zhang, Liping. "Hydrodenitrogenation of organonitrogen compounds over nickel-molybdenum sulfide and Molybdenum nitride catalysts /." The Ohio State University, 1996. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487942739805674.

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8

Khanfar, Mohammad F. "Molybdenum-modified platinum electrodes /." Internet access available to MUN users only, 2003. http://collections.mun.ca/u?/theses,160874.

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9

Campbell, Selina. "New organo-molybdenum complexes." Thesis, University of Cambridge, 1993. https://www.repository.cam.ac.uk/handle/1810/272559.

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10

TRUJILLO, REBOLLO ANDRES. "SOLVENT EXTRACTION OF MOLYBDENUM." Diss., The University of Arizona, 1987. http://hdl.handle.net/10150/184009.

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The equilibrium and the kinetics of the reaction of Mo (VI) with 8-hydroxyquinoline; 8-hydroxyquinaldine; KELEX 100; LIX63; and LIX65N were studied by solvent extraction. From the equilibrium studies it was concluded that in weakly acidic solution (pH 5 to 6) the overall extraction reaction is (UNFORMATTED TABLE FOLLOWS) MoO₄²⁻ + 2H⁺ + 2HL(o) ↔ (K(ex)) MoO₂L ₂(o) + 2H₂O (TABLE ENDS) where HL is the monoprotic bidentate ligand, "(o)" refers to the organic phase, and K(,ex) is the extraction constant. It was concluded that the complexation reaction requires four protons to convert molybdate int

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11

Yu, Jenwei Roscoe. "Methane activation over molybdenum disulfide, molybdenum carbide, and silver(110). Molecular orbital theory." Case Western Reserve University School of Graduate Studies / OhioLINK, 1990. http://rave.ohiolink.edu/etdc/view?acc_num=case1059138320.

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12

Kjornrattanawanich, Benjawan. "Reflectance, optical properties, and stability of molybdenum/strontium and molybdenum/yttrium multilayer mirrors /." For electronic version search Digital dissertations database. Restricted to UC campuses. Access is free to UC campus dissertations, 2002. http://uclibs.org/PID/11984.

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13

Şahin, Engin Sözüer Topaloğlu Işıl. "Synthesis And Characterization Oxo-İmido [Tris (3,5-Dimethyl-Pyrazol) Borate] Molybdenum Complexes/." [s.l.]: [s.n.], 2004. http://library.iyte.edu.tr/tezler/master/kimya/T000444.rar.

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14

Sundaram, S. K. "Corrosion and electrochemical protection of molybdenum and molybdenum disilicide in molten silicate glass environments." Diss., Georgia Institute of Technology, 1994. http://hdl.handle.net/1853/18906.

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15

Walker, Gary Lawrence Patrick. "Studies in imido molybdenum chemistry." Thesis, Imperial College London, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.266639.

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16

Page, T. S. "Molybdenum independent nitrogenases in cyanobacteria." Thesis, Swansea University, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.638392.

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<I>Anabaena variabilis</I> ATCC 29413, <I>Anabaena cylindrica</I> CCAP 1403/2A, <I>Anabaena</I> sp. PCC 7120, <I>Anabaena</I> sp. UCSB26, <I>Microcoleus chthonoplastes</I> and <I>Calothrix</I> sp. PCC 7601 appear to possess Mo-independent nitrogenases. All of these cyanobacteria grew diazotrophically in the presence of 1 mM tungstate, as well as in medium from which Mo had been carefully removed, whether or not V had been added. In growth media lacking Mo they reduced C<SUB>2</SUB>H<SUB>2</SUB> to C<SUB>2</SUB>H<SUB>6</SUB> as well as C<SUB>2</SUB>H<SUB>4</SUB>. Nevertheless, growth and C<SUB>

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17

Forster, Glyn Daniel. "Dithiocarbamate stabilised molybdenum imido complexes." Thesis, University College London (University of London), 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.261809.

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18

Tuit, Caroline Beth 1973. "The marine biogeochemistry of molybdenum." Thesis, Massachusetts Institute of Technology, 2003. http://hdl.handle.net/1721.1/58369.

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Thesis (Ph. D.)--Joint Program in Marine Geology and Geophysics (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric and Planetary Sciences, and the Woods Hole Oceanographic Institution), 2003.<br>Includes bibliographical references.<br>Prevailing wisdom holds that the vertical distribution of molybdenum (Mo) in the open ocean is conservative, despite Mo's important biological role and association with Mn oxides and anoxic sediments. Mo is used in both nitrogenase, the enzyme responsible for N2 fixation, and nitrate reductase, which catalyzes assimilatory and dissimilatory nitra

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19

Rockett, Chris H. "Flexural Testing of Molybdenum-Silicon-Boron Alloys Reacted from Molybdenum, Silicon Nitride, and Boron Nitride." Thesis, Georgia Institute of Technology, 2007. http://hdl.handle.net/1853/16293.

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MoSiB alloys show promise as the next-generation turbine blade material due to their high-temperature strength and oxidation resistance afforded by a protective borosilicate surface layer. Powder processing and reactive synthesis of these alloys has proven to be a viable method and offers several advantages over conventional melt processing routes. Microstructures obtained have well-dispersed intermetallics in a continuous matrix of molybdenum solid-solution (Mo-ss). However, bend testing of pure Mo and Mo-ss samples has shown that, while the powder processing route can produce ductile Mo meta

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20

Ray, Charles David 1967. "Photoelectron spectroscopy of dimolybdenum tetracarboxylates: Probing the electronic nature of the molybdenum-molybdenum quadruple bond." Thesis, The University of Arizona, 1992. http://hdl.handle.net/10150/278093.

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Photoelectron spectroscopy is used to investigate the electronic structure of molybdenum-molybdenum quadruple bonds in dimolybdenum tetracarboxylates. The variable energy photoelectron spectra of the valence region of dimolybdenum tetraacetate are reported for a range of incident photon energies. The pi components of the metal-metal bond contain the most molybdenum 4d character. The sigma component has contribution from both the ligand and the molybdenum 4p orbitals on the adjoining molybdenum. The delta component has significant overlap with the ligand orbitals. A comparative gas phase and su

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21

Lee, Chee Kiat. "Microstructure evaluations and thermomechanical properties of spinel (MgAl₂O₄) dispersed molybdenum alloys." Morgantown, W. Va. : [West Virginia University Libraries], 2005. https://eidr.wvu.edu/etd/documentdata.eTD?documentid=4213.

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Thesis (M.S.)--West Virginia University, 2005.<br>Title from document title page. Document formatted into pages; contains vii, 42 p. : ill. (some col.). Includes abstract. Includes bibliographical references (p. 40-42).

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22

Mitra, Subhasis. "Studies on the chemistry of molybdenum." Thesis, University of North Bengal, 1993. http://hdl.handle.net/123456789/741.

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23

Boldt, Paul Henry. "Room temperature indentation of molybdenum disilicide." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape11/PQDD_0003/NQ42836.pdf.

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24

Fulstow, A. N. "Some adsorption properties of molybdenum disulphide." Thesis, University of Hull, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.375608.

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25

McKay, David. "Catalysis over molybdenum containing nitride materials." Thesis, University of Glasgow, 2008. http://theses.gla.ac.uk/174/.

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Reactions involving nitrogen transfer/ fixation are of great industrial interest, as novel processes could help industries meet their increasingly challenging economic and environmental targets. An example of this could be the direct synthesis of aniline from benzene, which would avoid the lengthy, uneconomic, and environmentally unfriendly process currently employed. This work explores the reactivity of bulk and supported transition metal nitride catalysts, with particular emphasis on the possible reactivity of lattice nitrogen within bulk nitride catalysts. The experimental work has focussed

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26

Hunter, Stuart Michael. "Molybdenum nitrides : structural and reactivity studies." Thesis, University of Glasgow, 2012. http://theses.gla.ac.uk/3221/.

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This thesis describes the preparation, structure and activity of a range of binary, ternary and quaternary molybdenum nitrides. It has been shown that all of the samples analysed can be formed through the reaction of the respective molybdate precursor with either ammonia or 3:1 H2/N2 gas mixture. The structures of the nitrides have been studied in detail. These structural findings were then linked to the activity potential of the materials to act as stores of activated nitrogen. The main body of work focused on the ternary molybdenum nitrides of cobalt, iron and nickel with a view to understan

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27

Wawata, Ibrahim. "Methanol oxidation on molybdenum oxide catalysts." Thesis, Cardiff University, 2015. http://orca.cf.ac.uk/74613/.

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28

Günyar, Alev Topaloğlu Sözüer Işıl. "Oxo-Imido molybdenum tripyrazolyl borate complexes/." [s.l.]: [s.n.], 2004. http://library.iyte.edu.tr/tezler/master/kimya/T000464.pdf.

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29

Varadarajan, Ashok. "Thermomechanical property evaluation of molybdenum alloys." Morgantown, W. Va. : [West Virginia University Libraries], 2004. https://etd.wvu.edu/etd/controller.jsp?moduleName=documentdata&jsp%5FetdId=3479.

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Thesis (M.S.)--West Virginia University, 2004.<br>Title from document title page. Document formatted into pages; contains ix, 76 p. : ill. (some col.). Vita. Includes abstract. Includes bibliographical references (p. 73-75).

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30

Howarth, Christopher. "Enyl and dienyl complexes of molybdenum." Thesis, University of Bath, 1995. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.307069.

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31

Willis, Colin R. "Molybdenum mediated carbon-carbon bond formation." Thesis, University of Bath, 1988. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.380889.

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32

Oloye, Femi Francis. "Synthesis and characterisation of zirconia supported molybdenum oxide and molybdenum carbide catalysts for hydroconversion of n-heptane." Thesis, University of Aberdeen, 2016. http://digitool.abdn.ac.uk:80/webclient/DeliveryManager?pid=230933.

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The current upgrading catalysts are mainly based on the use of expensive noble metals, which are subject to deactivation due to sintering and coking. An alternative would be to introduce a non-noble metal-based catalyst. In this work, supported molybdenum carbide based systems have been assessed for this purpose. These catalysts were formed by impregnation of zirconia (and zirconium hydroxide) and sulfated zirconia (and zirconium hydroxide) with different loadings of MoO3, with an aim of finding a balance between acid sites and metal-like sites (a site capable of performing dehydrogenation and

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33

Rempel, Kirsten U. "The solubility and speciation of molybdenum in aqueous liquid and vapour : an experimental study." Thesis, McGill University, 2008. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=115874.

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We have conducted an experimental investigation of the solubility and speciation of Mo in HCl-, NaCl-, and NaOH-bearing water vapour, and of the partitioning of Mo between coexisting aqueous liquid and vapour at 300 to 370°C and up to saturated pressure. Our results indicate that Mo concentration is enhanced in HCl-bearing water vapour at fHCl > 0.1 bar, and in NaOH-saturated water vapour, but is unaffected by the presence of NaCl. This suggests that Mo speciates as MoO3·nH2O in water vapour at equilibrium with NaCl or fHCl < 0.1 bar. The dependence of SigmafMo on fHCl at higher

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34

Recatalá, Ferrandis David. "Photoactive Materials Based on Molybdenum Cluster Sulfides." Doctoral thesis, Universitat Jaume I, 2015. http://hdl.handle.net/10803/296561.

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<p>Coordination Chemistry deals with the synthesis and study of the physicochemical properties of metal complexes. Cluster Chemistry is a subfield of Coordination Chemistry, which focuses on the functionalization of complexes in which two or more metal atoms are directly bonded. Over the past few years, Cluster Chemistry has attracted a growing interest among scientists from diverse areas, mainly due to the fascinating properties of these compounds. A historical evolution of the term cluster, as well as an outline of the role of coordinated ligands and structural types in the final properties

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35

Choudhary, Habib Ullah. "Anomalous behaviour of molybdenum in steel welds." Thesis, University of Cambridge, 1993. https://www.repository.cam.ac.uk/handle/1810/219195.

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The addition of molybdenum to steel welds in quite small concentrations leads to a variety of anomalous microstructural and mechanical property effects. In some cases, the effects manifest even when there are no obvious changes in microstructure at the resolution of a transmission electron microscope. There are two particular discrepancies. A quantitative analysis of molybdenum-containing steel welds indicates that there is a degree of strengthening which cannot be explained by the known solid solution or microstructural effects of molybdenum in steels. Secondly, in multirun welds, the additio

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36

Yang, Xiaofan. "Corrosion and passivation of molybdenum-bearing alloys." Thesis, University of Surrey, 1995. http://epubs.surrey.ac.uk/843256/.

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Molybdenum-bearing alloys are widely used in industry because of their excellent corrosion resistance. However, the role of molybdenum in passivation is a subject which has been a matter for discussion and controversy for many years. In the previous work carried out in this laboratory, Professor Castle and Dr Qiu suggested that molybdenum oxide might provide the nuclei for formation of the passive film. This hypothesis is the basis of the present work. In order to find out the evidence for the existence of the molybdenum oxide nuclei, furthermore, to establish a model of passivation for the mo

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37

Walker, Daniel James. "Fluorinations of tungsten and molybdenum carbonyl complexes." Thesis, University of Leicester, 1997. http://hdl.handle.net/2381/30011.

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The dimeric complexes (n5-C5H5)M(CO)3 2 (where M = W or Mo) and (H3C{ti5-C5H4})Mo(CO)3 2 have been treated with XeF2 in organic solvents. All three materials react to form air sensitive products which solid-phase IR studies show to contain highly oxidised metal carbonyl components. The product from the fluoridation of (H3C{T 5-C5H5})Mo(CO)3 2 is insufficiently stable in solution for it to be characterised further. 19F NMR studies show that (n5-C5H5)W(CO)3 2 reacts to form the new complex (T 5-C5H5)WF5, but that the molybdenum analogue reacts to form an unidentified product which, although it p

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38

Matei, L., R. Galea, K. Moore, et al. "Thermal separation of 99mTc from Molybdenum targets." Helmholtz-Zentrum Dresden - Rossendorf, 2015. http://nbn-resolving.de/urn:nbn:de:bsz:d120-qucosa-164746.

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Thermal separation is defined as a mass transfer process driven by molecular forces. The process involves the heat transfer between two phases with different composition. In general, thermal separation occurs when heat is generated in the system additionally to the already existing phases. In a second phase the mass is transferred in the system (adsorption) and at the end of this step the separation is completed. The thermal separation can be achieved in temperature or concentration gradient function of system configuration [1]. Thermo-chromatography is a process in which the separation occurs

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39

Bayerköhler, Frieder [Verfasser], and Philipp [Akademischer Betreuer] Kurz. "Iron-molybdenum sulphides as proton reduction catalysts." Freiburg : Universität, 2017. http://d-nb.info/1144148901/34.

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40

Short, Rick. "Incorporation of molybdenum in nuclear waste glasses." Thesis, University of Sheffield, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.444469.

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41

Critchley, David J. P. "Diazanaphthalenes as probes of molybdenum hydroxylase activity." Thesis, University of Bradford, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.277185.

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42

Kaye, Simon Peter. "Ion-assisted deposition of molybdenum disulphide films." Thesis, University of Salford, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.238835.

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43

Macpherson, I. "Some metallaborane chemistry of molybdenum and tungsten." Thesis, University of Leeds, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.376799.

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44

Shonfield, Peter K. A. "Molybdenum and tungsten complexes for moleular electronics." Thesis, University of Bristol, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.264635.

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45

Kassim, Mohammad B. "Studies of nitrosyl and oxo molybdenum complexes." Thesis, University of Bristol, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.274612.

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46

Liu, WenDi. "Optimization of Molybdenum Electrodes for Glass Melting." Digital WPI, 2015. https://digitalcommons.wpi.edu/etd-dissertations/208.

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The U.S. glass industry is a $28 billion enterprise and millions of tons of glasses are melted each day by different heating techniques, such as conventional oil fired furnaces or via electrical heating. The share of electrical heating is bound to rise steadily because it is cleaner and more energy efficient. Due to this situation molybdenum will play a significant role in electrical glass melting, since it is the most frequently used electrode material to deliver the electricity into the glass melts. Although it has a high melting point, high electrical and thermal conductivity and a low coef

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47

Octon, T. "Optoelectronic properties of two-dimensional molybdenum ditelluride." Thesis, University of Exeter, 2019. http://hdl.handle.net/10871/35713.

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In this thesis the layered, two-dimensional material MoTe2 is examined experimentally for its optoelectronic properties, using a field effect transistor device configuration. MoTe2 experiences a strong light matter interaction, which is highly dependent on the conditions of the measurement, and the wavelength of light used. Light is able to: produce a photocurrent in MoTe2, desorb adsorbates from the surface, and even controllably thin by a single layer at a time. A theoretical study on MoTe2 also provides insights on the source of some of these interesting light matter interactions. MoTe2 is

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48

Suwardiyanto. "Novel molybdenum/zeolite catalysts for methane dehydroaromatization." Thesis, University of Aberdeen, 2015. http://digitool.abdn.ac.uk:80/webclient/DeliveryManager?pid=228007.

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49

Turner, Nigel Arthur. "Studies on the molybdenum centre in enzymes." Thesis, University of Sussex, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.284106.

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50

Wang, Shanshan. "Synthesis and characterization of monolayer molybdenum disulphide." Thesis, University of Oxford, 2017. https://ora.ox.ac.uk/objects/uuid:182cdf51-c6e2-40bc-abf8-8057130bc2f5.

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Monolayer molybdenum disulphide (MoS<sub>2</sub>) is a semiconductor with a direct bandgap of &Tilde;1.9 eV. Much research attention has been attracted to its potential applications in nanoelectronics and optoelectronics recently, all of which are based upon a scalable production of high-quality monolayer MoS<sub>2</sub> and the in-depth comprehension of its fundamental properties. The PhD project focused on developing chemical vapour deposition (CVD) methods to grow monolayer MoS<sub>2</sub> and its related two-dimensional (2D) vertical heterostructures with an understanding of the growth mec

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