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1

Zhang, Yan, Li Yang, and Lin Wang. "Identification of Biflavones in Ethyl Acetate Fraction from Ethanol Extract of Selaginella doederleinii Hieron." Advanced Materials Research 550-553 (July 2012): 1862–65. http://dx.doi.org/10.4028/www.scientific.net/amr.550-553.1862.

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The chemical constituents were isolated from the ethyl acetate fraction from ethanol extract of Selaginella doederleinii Hieron by column chromatography on silica gel and Sephadex LH-20. The chemical structures of six biflavones were elucidated on the basis of physicochemical properties and spectroscopic data as amentoflavone (1), robustaflavone 7,4',7''-o-trimethyl ether (2), heveaflavone (3), podocarpusflavone A (4), robustaflavone 4',4'''-o-dimethyl ether (5) and robustaflavone 4'-o-methyl ether (6). Biflavones 2, 4 and 5 were obtained from Selaginella doederleinii Hieron for the first time
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2

Nguyen, Thien-Thao, Nguyen Ngoc Trai, and Nguyen Thi Thu Ha. "USING THE METAL ORGANIC FRAMEWORKS (CUOBA) AS A CATALYST FOR REACTION OF 2-ACETYL-1-NAPTHOL AND BENZYL ETHER." Journal of Southwest Jiaotong University 57, no. 6 (2022): 66–75. http://dx.doi.org/10.35741/issn.0258-2724.57.6.7.

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This study aimed to synthesize the compound of copper and 4,4'-oxysbisbenzoic acid (CuOBA), analyze its physical and chemical properties and employ it as a heterogeneous catalyst for the C-O coupling reaction of 2-acetyl-1-napthol and benzyl ether. The metal-organic framework material CuOBA was synthesized using the solvothermal method. The physicochemical characteristics of CuOBA were determined by several different analytical techniques, including X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), and
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3

Manohar, Murli, Prem P. Sharma, and Dukjoon Kim. "Intercalated Poly (2-acrylamido-2-methyl-1-propanesulfonic Acid) into Sulfonated Poly (1,4-phenylene ether-ether-sulfone) Based Proton Exchange Membrane: Improved Ionic Conductivity." Molecules 26, no. 1 (2020): 161. http://dx.doi.org/10.3390/molecules26010161.

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A series of hybrid proton exchange membranes were synthesized via in situ polymerization of poly (2-acrylamido-2-methyl-1-propanesulfonic acid) PMPS with sulfonated poly (1,4-phenylene ether-ether-sulfone) (SPEES). The insertion of poly (2-acrylamido-2-methyl-1-propanesulfonic acid) PMPS, between the rigid skeleton of SPEES plays a reinforcing role to enhance the ionic conductivity. The synthesized polymer was chemically characterized by fourier-transform infrared spectroscopy (FT-IR) and nuclear magnetic resonance 1H NMR spectroscopy to demonstrate the successful grafting of PMPS with the pen
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4

Yang, Wanying, Jiaqi Wang, Lingjiang Jia, Jingyi Li, and Shouxin Liu. "Stereo-Complex and Click-Chemical Bicrosslinked Amphiphilic Network Gels with Temperature/pH Response." Gels 9, no. 8 (2023): 647. http://dx.doi.org/10.3390/gels9080647.

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Stimulus-responsive hydrogels have been widely used in the field of drug delivery because of their three-dimensional pore size and the ability to change the drug release rate with the change in external environment. In this paper, the temperature-sensitive monomer 2-methyl-2-acrylate-2-(2-methoxyethoxy-ethyl) ethyl ester (MEO2MA) and oligoethylene glycol methyl ether methacrylate (OEGMA) as well as the pH-sensitive monomer N,N-Diethylaminoethyl methacrylate (DEAEMA) were used to make the gel with temperature and pH response. Four kinds of physicochemical double-crosslinked amphiphilic co-netwo
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5

Jin, Cuihong, and Xiuling Zhu. "Synthesis and physicochemical properties of sulfonated poly(aryl ether) PEMs containing phthalazinone and oxadiazole moieties." High Performance Polymers 30, no. 3 (2017): 274–82. http://dx.doi.org/10.1177/0954008317691585.

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In this work, 2,5-bis(4-fluorophenyl)-1,3,4-oxadiazole (2F-Oz) is synthesized and successfully polymerized with 4-(4-hydroxyaryl)-phthalazin-1-one (DHPZ) through polycondensation to produce poly(ether 1,3,4-oxidiazole) containing phthalazinone units (PPEO) with intrinsic viscosity 1.54 dL g−1. A series of sulfonated poly(ether-1,3,4-oxidiazole)s (SPPEOs) with different degrees of sulfonation are prepared via postsulfonation reaction. The chemical structure of PPEO and SPPEOs was characterized through FT-IR and proton nuclear magnetic resonance, respectively. SPPEOs have excellent film-forming
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6

Maulani, Tuti Rostianti, Hanifah Nuryani Lioe, Irma Isnafia Arief, and Harsi Dewantari Kusumaningrum. "Extraction and Physicochemical Characterization of Pectin from Noni (Morinda citrifolia) Fruit." Jurnal Kimia Valensi 10, no. 1 (2024): 11–19. http://dx.doi.org/10.15408/jkv.v10i1.37702.

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Noni (Morinda citrifolia) is a popular plant in Asian countries and has great potential as pectin source for thickening agents in food products. In general, ethanol has been widely used to precipitate pectin, but the proportion can affect the quality of the product. Therefore, this study aimed to characterize the physicochemical properties of pectin from noni fruit. Extraction was performed using 0.1 N HCl at pH 1.5 and heated at 80°C for 15 min, followed by precipitation with different proportions of 96% ethanol including A (1:1), B (1:2), and C (1:3) v/v, while commercial orange pectin was u
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7

Schifter, Isaac, Luis Diaz, Uriel Gonzalez, Carmen Gonzalez-Macias, and Isidro Mejía-Centeno. "The effects of addition of co-solvents on the physicochemical properties of gasoline–methanol blended fuels." International Journal of Engine Research 20, no. 5 (2018): 501–9. http://dx.doi.org/10.1177/1468087418757855.

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The scope of the work carried out is aimed to evaluate the effects of blending methanol in the gasoline pool, particularly octane number and Reid vapor pressure increase when methanol is substituting methyl-tertiary-butyl ether in the formulation of Regular and Premium base gasolines. Isopropyl alcohol and ethanol have been investigated and found to be a promising co-blending alcohol to be mixed in gasoline methanol blends. Isopropyl alcohol is most effective below 3 vol%. Ethanol has been found to be the most promising co-blending alcohol able to reduce the Reid vapor pressure increase by 1.4
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8

Pantelaiou, Michaila Akathi, Dimitrios Vagenas, Evangelos S. Karvelis, Georgios Rotas, and Stergios Pispas. "Co-Assembled Nanosystems Exhibiting Intrinsic Fluorescence by Complexation of Amino Terpolymer and Its Quaternized Analog with Aggregation-Induced Emission (AIE) Dye." Nanomaterials 14, no. 20 (2024): 1631. http://dx.doi.org/10.3390/nano14201631.

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Aggregation-induced emission dyes (AIEs) have gained significant interest due to their unique optical properties. Upon aggregation, AIEs can exhibit remarkable fluorescence enhancement. These systems are ideal candidates for applications in bioimaging, such as image-guided drug delivery or surgery. Encapsulation of AIEs in polymeric nanocarriers can result in biocompatible and efficient nanosystems. Herein, we report the fabrication of novel nanoaggregates formulated by amino terpolymer and tetraphenylethylene (TPE) AIE in aqueous media. Poly(di(ethylene glycol) methyl ether methacrylate-co-2-
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9

Timofeeva, Maria N., Valentina N. Panchenko, and Sung Hwa Jhung. "Insights into the Structure–Property–Activity Relationship of Zeolitic Imidazolate Frameworks for Acid–Base Catalysis." International Journal of Molecular Sciences 24, no. 5 (2023): 4370. http://dx.doi.org/10.3390/ijms24054370.

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Zeolitic imidazolate frameworks (ZIFs) have been extensively examined for their potential in acid–base catalysis. Many studies have demonstrated that ZIFs possess unique structural and physicochemical properties that allow them to demonstrate high activity and yield products with high selectivity. Herein, we highlight the nature of ZIFs in terms of their chemical formulation and the textural, acid–base, and morphological properties that strongly affect their catalytic performance. Our primary focus is the application of spectroscopic methods as instruments for analyzing the nature of active si
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10

Triantafyllopoulou, Efstathia, Dimitriοs Selianitis, Natassa Pippa, Maria Gazouli, Georgia Valsami, and Stergios Pispas. "Development of Hybrid DSPC:DOPC:P(OEGMA950-DIPAEMA) Nanostructures: The Random Architecture of Polymeric Guest as a Key Design Parameter." Polymers 15, no. 9 (2023): 1989. http://dx.doi.org/10.3390/polym15091989.

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Hybrid nanoparticles have gained a lot of attention due to their advantageous properties and versatility in pharmaceutical applications. In this perspective, the formation of novel systems and the exploration of their characteristics not only from a physicochemical but also from a biophysical perspective could promote the development of new nanoplatforms with well-defined features. In the current work, lipid/copolymer bilayers were formed in different lipid to copolymer ratios and examined via differential scanning calorimetry as a preformulation study to decipher the interactions between the
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11

Olubomehin, Oseyemi Omowunmi, Yisau Oluwatosin Atoyebi, and Nojeem Adesola Babarinde. "CHEMICAL ANALYSIS OF THE SEED OIL OF CANAVALIA ENSIFORMIS LINN. FOR NUTRITIONAL AND INDUSTRIAL QUALITIES." African Journal of Science and Nature 6 (July 23, 2020): 66. http://dx.doi.org/10.46881/ajsn.v6i0.143.

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The extensive demand for oils by man for consumption and industrial applications has led to an increasing search for oils from non-conventional sources to augment the available ones. Thus, the seed oil of Canavalia ensiformis Linn., a leguminous plant abundantly found in South-western Nigeria was extracted and analysed for its nutritional and industrial applications. Phytochemical screening and proximate analysis of the seeds along with physicochemical parameters of the oil using standard procedures were done. Different weights of the powdered seeds were extracted using a soxh let extractor wi
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12

Syaifie, Putri Hawa, Azza Hanif Harisna, Mochammad Arfin Fardiansyah Nasution, et al. "Computational Study of Asian Propolis Compounds as Potential Anti-Type 2 Diabetes Mellitus Agents by Using Inverse Virtual Screening with the DIA-DB Web Server, Tanimoto Similarity Analysis, and Molecular Dynamic Simulation." Molecules 27, no. 13 (2022): 3972. http://dx.doi.org/10.3390/molecules27133972.

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Propolis contains a wide range of pharmacological activities because of their various bioactive compounds. The beneficial effect of propolis is interesting for treating type-2 diabetes mellitus (T2DM) owing to dysregulation of multiple metabolic processes. In this study, 275 of 658 Asian propolis compounds were evaluated as potential anti-T2DM agents using the DIA-DB web server towards 18 known anti-diabetes protein targets. More than 20% of all compounds could bind to more than five diabetes targets with high binding affinity (<−9.0 kcal/mol). Filtering with physicochemical and pharmacokin
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13

Hundie, Ketema Beyecha. "Optimization of Biodiesel Production Parameters from Cucurbita maxima Waste Oil Using Microwave Assisted via Box-Behnken Design Approach." Journal of Chemistry 2022 (April 22, 2022): 1–12. http://dx.doi.org/10.1155/2022/8516163.

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The production of biodiesel from vegetables or fruits waste oils has high potential as renewable energy. The Cucurbita maxima wastes are massive source of oils, which are believed to indicate the possible sources of renewable energy whose biodiesel can be produced. Hence, the study explores the potential of the Cucurbita maxima wastes, for the production of biodiesel. In this study, the Soxhlet extraction method was used to extract Cucurbita maxima waste oil using an organic solvent. Through Box-Behnken design (BBD), the effects of methanol to oil molar ratio (6–10), catalyst concentration (2–
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14

Alotaibi, Khalid M., Abdurrahman A. Almethen, Abeer M. Beagan, et al. "Poly(oligo(ethylene glycol) methyl ether methacrylate) Capped pH-Responsive Poly(2-(diethylamino)ethyl methacrylate) Brushes Grafted on Mesoporous Silica Nanoparticles as Nanocarrier." Polymers 13, no. 5 (2021): 823. http://dx.doi.org/10.3390/polym13050823.

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In this paper, a new pH-responsive nanosystem based on mesoporous silica nanoparticles (MSNs) was developed for cancer therapy. Poly(2-(diethylamino) ethyl methacrylate) (PDEAEMA) was grafted on their outer surface and acts as a gatekeeper, followed by subsequent modification of the polymer by cysteine (MSN-PDEAEMA-Cys) and poly(oligo(ethylene glycol) methyl ether methacrylate) (MSN-PDEAEMA-Cys-POEGMEMA). The physicochemical properties of these nanocarriers were characterized using scanning and transmission electron microscopies (SEM and TEM), Fourier-transform infrared spectroscopy (FTIR), X-
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15

Majid, Mohd Faridzuan, and Hayyiratul Fatimah Mohd Zaid. "The Effect of Ionic Liquid@UiO-66 on the Ionic Conductivity and Physicochemical Properties of Composite PEO Electrolyte." PaperASIA 40, no. 6b (2024): 232–44. http://dx.doi.org/10.59953/paperasia.v40i6b.143.

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An inorganic nanofiller made from bis(trifluoromethanesulfonyl)imide-based ionic liquids (IL) and UiO-66, was incorporated into poly(ethylene oxide) (PEO) for the preparation of composite polymer electrolyte. Among various alkyl cations considered, 1-methyl-3-n-octylimidazolium bis(trifluoromethanesulfonyl)imide [OMIM][TFSI], with the longest alkyl chain, exhibited the most significant improvement in ionic conductivity, reaching 1.19 × 10-5 S cm-1 at room temperature. The impact of [OMIM][TFSI]@UiO-66 loading was further investigated, with the optimal loading achieved at 60% IL content. This l
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16

Gerardos, Angelica Maria, and Stergios Pispas. "Double Hydrophilic Hyperbranched Copolymer-Based Lipomer Nanoparticles: Copolymer Synthesis and Co-Assembly Studies." Polymers 16, no. 22 (2024): 3129. http://dx.doi.org/10.3390/polym16223129.

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Double hydrophilic, random, hyperbranched copolymers were synthesized via reversible addition–fragmentation chain transfer (RAFT) polymerization of oligo(ethylene glycol) methyl ether methacrylate (OEGMA) and 2-(dimethylamino)ethyl methacrylate (DMAEMA) utilizing ethylene glycol dimethacrylate (EGDMA) as the branching agent. The resulting copolymers were characterized in terms of their molecular weight and dispersity using size exclusion chromatography (SEC), and their chemical structure was confirmed using FT-IR and 1H-NMR spectroscopy techniques. The choice of the two hydrophilic blocks and
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17

Kafetzi, Martha, Stergios Pispas, Xiaoyan Bao, and Ping Yao. "Amphiphilic QP(DMAEMA-co-LMA)-b-POEGMA Random-Block Terpolymers as Nanocarriers for Insulin." Biomedicines 8, no. 10 (2020): 392. http://dx.doi.org/10.3390/biomedicines8100392.

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We report on the utilization of the amphiphilic poly[quaternized (2-(N,N-dimethylamino) ethyl methacrylate)]-co-(lauryl methacrylate))-b-poly[(oligo ethylene glycol) methyl ether methacrylate] QP(DMAEMA-co-LMA)-b-POEGMA cationic diblock terpolymer aggregates as nanocarriers for insulin delivery applications. QP(DMAEMA-co-LMA)-b-POEGMA random diblock terpolymer is derived from the chemical modification of the precursor amino diblock copolymer via quaternization, producing permanent positive charges on the macromolecular chain. The QP(DMAEMA-co-LMA)-b-POEGMA diblock terpolymer as well as its ami
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18

Tran, Van, Jitka Viktorova, Katerina Augustynkova, et al. "In Silico and In Vitro Studies of Mycotoxins and Their Cocktails; Their Toxicity and Its Mitigation by Silibinin Pre-Treatment." Toxins 12, no. 3 (2020): 148. http://dx.doi.org/10.3390/toxins12030148.

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Mycotoxins found in randomly selected commercial milk thistle dietary supplement were evaluated for their toxicity in silico and in vitro. Using in silico methods, the basic physicochemical, pharmacological, and toxicological properties of the mycotoxins were predicted using ACD/Percepta. The in vitro cytotoxicity of individual mycotoxins was determined in mouse macrophage (RAW 264.7), human hepatoblastoma (HepG2), and human embryonic kidney (HEK 293T) cells. In addition, we studied the bioavailability potential of mycotoxins and silibinin utilizing an in vitro transwell system with differenti
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19

Stampfer, Léopold, Cécile Bouilhac, Tiphaine Mérian, et al. "Investigation of the Reaction between a Homemade PEEK Oligomer and an Epoxy Prepolymer: Optimisation of Critical Parameters Using Physico–Chemical Methods." Polymers 16, no. 6 (2024): 764. http://dx.doi.org/10.3390/polym16060764.

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Several researchers have examined the interest in using a thermoplastic to increase thermoset polymers’ shock resistance. However, fewer studies have examined the nature of the mechanisms involved between both kinds of polymers. This was the objective of our work, which was carried out using a gradual approach. First, we describe the synthesis of a poly(ether ether ketone) oligomer (oPEEK) with hydroxyl terminations from the reaction of hydroquinone and 4,4′-difluorobenzophenone in N-methyl-2-pyrrolidone. Then, the main physicochemical properties of this oligomer were determined using differen
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20

Konishi, Yukako, Hisashi Kokubo, Seiji Tsuzuki, Ryoichi Tatara, and Kaoru Dokko. "Effects of Polymer Side Chains on Ion Transport Properties of Gel Electrolytes Containing High Concentration Li Salt Solution." ECS Meeting Abstracts MA2024-02, no. 67 (2024): 4467. https://doi.org/10.1149/ma2024-02674467mtgabs.

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Highly concentrated Li salt electrolyte solutions have attracted attention recently due to the unique physicochemical and electrochemical properties.1 Recently, our group reported that highly concentrated Li salt/sulfolane electrolytes exhibit Li+ ion hopping conduction mechanism.2 Gel electrolytes, which incorporate liquid electrolytes within polymer network generally maintain ion transport properties derived from liquid electrolytes. The gelation of liquid electrolytes can prevent the leakage of liquids and improve the safety of batteries. However, certain gel electrolytes containing high co
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21

Gomathi, G., T. Srinivasan, D. Velmurugan, and R. Gopalakrishnan. "A bluish-green emitting organic compound methyl 3-[(E)-(2-hydroxy-1-naphthyl)methylidene]carbazate: spectroscopic, thermal, fluorescence, antimicrobial and molecular docking studies." RSC Advances 5, no. 56 (2015): 44742–48. http://dx.doi.org/10.1039/c5ra04964d.

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Trivedi, Mahendra Kumar, Alice Branton, Dahryn Trivedi, and Gopal Nayak. "Physical, Thermal, and Spectroscopic Characterization of Biofield Energy Treated Methyl-2-Naphthyl Ether." Omics Publishing Group, September 20, 2015. https://doi.org/10.5281/zenodo.813952.

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Methyl-2-naphthyl ether (MNE) is an organic compound and used as the primary moiety for the synthesis of several antimicrobial and anti-inflammatory agents. This study was attempted to evaluate the impact of biofield energy treatment on the physical, thermal, and spectroscopic properties of MNE. The study was carried out in two groups i.e., control and treated. The treated group was subjected to Mr. Trivedi's biofield treatment. Afterward, the control and treated samples of MNE were evaluated using X-ray diffraction (XRD), surface area analyzer, differential scanning calorimetry (DSC), thermog
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23

"SYNTHESIS AND PROPERTIES OF THE METHYL ESTERS OF 3,5-DI-METHYLCYCLOALKYL-4-HYDROXYPHENYLPROPIONIC ACID." ChemChemTech 66, no. 6 (2023): 85–93. http://dx.doi.org/10.6060/ivkkt.20236606.6777.

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A study was carried out and a method was developed for the synthesis of sterically hindered phenols by cycloalkylation of methyl ester of 4-hydroxyphenylpropionic acid with 1-methylcyclopentene, 1- and 3-methylcyclohexene in the presence of a KU-23 catalyst (modification 10/60 (GOST 20298)) with a pore radius of 250-600 Å. The optimal conditions for cycloalkylation of methyl ester of 4-hydroxyphenylpropionic acid with methylcyclenes in the presence of a KU-23 catalyst (temperature 100-110 ºС, reaction time 5-6 h, molar ratio of ether to cyclene 1:2, amount of catalyst 10% per taken ester) were
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Sultana, Tamanna, Md Abdullah Al Fahad, Myeongki Park, Soon Ha Kwon, and Byong‐Taek Lee. "Physicochemical, in vitro and in vivo evaluation of VEGF loaded PCL‐mPEG and PDGF loaded PCL‐Chitosan dual layered vascular grafts." Journal of Biomedical Materials Research Part B: Applied Biomaterials, September 7, 2023. http://dx.doi.org/10.1002/jbm.b.35325.

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AbstractThe present study has attempted to evaluate the endothelialization and smooth muscle regeneration efficiency of a novel dual‐layer small‐diameter vascular graft. Two types of layers (PCL‐mPEG‐VEGF and PCL‐Chitosan‐PDGF) were fabricated to find out the best layer giving endothelialization support for the lumen and unique contractile function for outer layer of blood vessels. Platelet‐derived growth factor (PDGF) and chitosan were immobilized onto PCL surface by aminolysis‐based surface modification technique. Besides, Poly (ethylene glycol) methyl ether (mPEG) and vascular endothelial g
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Trivedi, Mahendra Kumar, Alice Branton, Dahryn Trivedi, Gopal Nayak, Khemraj Bairwa, and Snehasis Jana. "Physical, Thermal, and Spectroscopic Characterization of Biofield Energy Treated Methyl-2-Naphthyl Ether." Environmental Analytical Chemistry 2, no. 5 (2015). https://doi.org/10.4172/2380-2391.1000162.

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Methyl-2-naphthyl ether (MNE) is an organic compound and used as the primary moiety for the synthesis of several antimicrobial and anti-inflammatory agents. This study was attempted to evaluate the impact of biofield energy treatment on the physical, thermal, and spectroscopic properties of MNE. The study was carried out in two groups i.e., control and treated. The treated group was subjected to Mr. Trivedi’s biofield treatment. Afterward, the control and treated samples of MNE were evaluated using X-ray diffraction (XRD), surface area analyzer, differential scanning calorimetry (DSC), t
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Trivedi, Mahendra Kumar, Alice Branton, Dahryn Trivedi, Gopal Nayak, Khemraj Bairwa, and Snehasis Jana. "Physical, Thermal, and Spectroscopic Characterization of Biofield Energy Treated Methyl-2-Naphthyl Ether." Environmental Analytical Chemistry 2, no. 5 (2015). https://doi.org/10.5281/zenodo.167526.

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Methyl-2-naphthyl ether (MNE) is an organic compound and used as the primary moiety for the synthesis of several antimicrobial and anti-inflammatory agents. This study was attempted to evaluate the impact of biofield energy treatment on the physical, thermal, and spectroscopic properties of MNE. The study was carried out in two groups i.e., control and treated. The treated group was subjected to Mr. Trivedi’s biofield treatment. Afterward, the control and treated samples of MNE were evaluated using X-ray diffraction (XRD), surface area analyzer, differential scanning calorimetry (DSC), t
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