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1

周向葛 and Xiangge Zhou. "Asymmetric reactions catalyzed by transition metal complexes containing binaphthyl schiff bases and chiral porphyrinato ligands." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1999. http://hub.hku.hk/bib/B31239833.

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Zhou, Xiangge. "Asymmetric reactions catalyzed by transition metal complexes containing binaphthyl schiff bases and chiral porphyrinato ligands /." Hong Kong : University of Hong Kong, 1999. http://sunzi.lib.hku.hk/hkuto/record.jsp?B21021363.

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3

Bassolino, Giovanni. "Tuning ultrafast chemical reaction dynamics in photoactive proteins." Thesis, University of Oxford, 2015. http://ora.ox.ac.uk/objects/uuid:42c19c5c-c6df-48e9-bb1c-8a7098eca8b4.

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This dissertation investigates the origins of tunable and efficient photochemistry in three different photoactive proteins, bacteriorhodopsin (BR), rhodopsin (RHO) and green fluorescent protein (GFP). In all cases, significant differences exist between the photoreactivity of model chromophores in solution and in the protein environment, in terms of excited state lifetime and efficiency of the primary photochemical process (opsin proteins) or the type of reaction (excited state proton transfer versus C=C double bond photoisomerisation for GFP). The work presented here investigates for each case
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4

Sidi, Boune Mohamed Vall. "Valorisation en synthèse organique des phytoconstituants (dérivés du gossypol) extraits de Cienfuegosia Digitata. Cav." Thesis, Normandie, 2019. http://www.theses.fr/2019NORMLH03/document.

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Cette thèse décrit une méthodologie innovante d’extraction et d’hémisynthèse simultanée, dénommée SECheM (Simultaneous Extraction and Chemical Modification) sur une plante mauritanienne le Cienfuegosia digitata Cav. Cette méthodologie présente plusieurs avantages : (a) elle permet d’éviter les étapes critiques au niveau de la séparation et de la purification du gossypol, un polyphénol instable isolé de la plante ciblée (b) elle permet de stabiliser le gossypol thermiquement en le transformant en base de Schiff beaucoup plus stable. (c) elle présente un avantage en termes de réduction du nombre
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Devoille, Aline M. J. "New cofacial binuclear complexes for the oxygen reduction reaction and selective anion binding." Thesis, University of Edinburgh, 2011. http://hdl.handle.net/1842/9963.

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This thesis describes the design, synthesis and reactivity of bimetallic complexes of doubly-pillared Schiff-base calixpyrrole ligands. Chapter One introduces the oxygen reduction reaction in light of the global energy scenario at present and in the future. Compounds and materials known to catalyse this reaction are discussed, with particular focus on transition metal complexes of pyrrole-containing macrocycles and the ability of these compounds to act as catalysts in redox reactions. Chapter Two describes the design and synthesis of several of the macrocyclic ligands developed during this pro
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Mugo, Jane Ngima. "Polymerization and oligomerization reactions mediated by metallodendrimers of zinc and palladium." Thesis, Stellenbosch : Stellenbosch University, 2012. http://hdl.handle.net/10019.1/20215.

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Djiele, Ngameni Patrice. "Phosphane and Phosphite Silver(I) Complexes: Synthesis, Reaction Chemistry and their Use as CVD Precursors." Doctoral thesis, [S.l. : s.n.], 2005. http://archiv.tu-chemnitz.de/pub/2005/0008.

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Sovdat, Tina. "Toward understanding speed, efficiency and selectivity in retinal photochemistry." Thesis, University of Oxford, 2014. http://ora.ox.ac.uk/objects/uuid:cfa19bb3-b399-4d26-9b9a-0ca1ff34dfa2.

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This Thesis describes the synthesis, structural, photochemical and photophysical studies of modified retinal protonated Schiff bases in solution. Ultrafast laser spectroscopy, NMR and circular dichroism studies were employed to investigate speed, yield and selectivity of photoisomerisation in these chromophores. <b>Chapter 1</b> introduces relevant biological, photophysical and photochemical aspects of retinal protonated Schiff base photoisomerisation. It includes an overview of synthetic approaches to modified retinal synthesis pertinent to this this work. <b>Chapter 2</b> discuses the invest
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Léon, Patrick. "Alkylation d'amines par les sels de sulfonium, reaction de type gabriel et synthese de polyamines." Paris 6, 1987. http://www.theses.fr/1987PA066488.

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Ramoroka, Morongwa Emmanuel. "Photophysics of Thiophenosalicylaldimine-functionalized G1-Polyprolyleniminato-Copper Telluride/Antimonide core-shell Nanomaterials." University of the Western Cape, 2018. http://hdl.handle.net/11394/6262.

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Magister Scientiae - MSc (Chemistry)<br>This work involves the synthesis of copper telluride-polypropylenimine tetra(5-(2-thienyl) salicylaldimine) (CuTe@PPI) and copper antimonide-polypropylenimine tetra(5-(2-thienyl) salicylaldimine) (CuSb@PPI) core-shell nanoparticles (NPs), using two-pots and one-pot synthesis methods, respectively. Their morphology was studied by X-ray diffraction spectroscopy (XRD), high resolution transmission electron microscopy (HRTEM) and high resolution scanning electron microscopy (HRSEM); while their structures were characterized by Fourier transform infrared spec
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11

Abbott, Mariana Pedrinha. "Modificações oxidativas em proteínas em presença de complexos de cobre(II)." Universidade de São Paulo, 2007. http://www.teses.usp.br/teses/disponiveis/46/46134/tde-24102007-104712/.

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Neste trabalho alguns complexos diimínicos de cobre(II) com ligantes do tipo base de Schiff, já estudados em nosso laboratório, além de um novo complexo de zinco foram sintetizados e caracterizados por análise elementar, espectroscopias UV/Vis, Infravermelho e de Ressonância Paramagnética Eletrônica (EPR). Estudos sobre a reatividade destes complexos de cobre(II) frente à oxidação de carboidratos por oxigênio molecular foram então realizados. Estes estudos envolveram várias etapas, com variação das concentrações do catalisador, do substrato e do tampão e variação do pH, verificando-se a influê
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12

Caldés, Melis Catalina. "Formación de bases de Schiff de análogos de aminofosfolípidos con compuestos glicantes y efecto competitivo de vitámeros B6." Doctoral thesis, Universitat de les Illes Balears, 2012. http://hdl.handle.net/10803/97354.

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La glicació no enzimàtica de biomolècules consisteix en la modificació irreversible dels seus grups amina per sucres reductors, i s’ha relacionat amb les complicacions patològiques de la diabetis. Una de les dianes de la glicació són els aminofosfolípids, encara que s’han realitzat pocs treballs sobre les seves reaccions. Aquesta tesi es centra en l’estudi de la primera etapa de la glicació (formació d’una base de Schiff) de composts anàlegs d’aminofosfolípids naturals amb composts carbonílics glicants i amb el 5’-fosfat de piridoxal (vitàmer B6 que actua com a inhibidor de la glicació). S’han
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13

Leblond, Jérôme. "Synthèse et application catalytique de cyclodextrines modifiées Water-soluble phosphane-substituted cyclodextrin as an effective bifunctional additive in hydroformylation of higher olefins New water-soluble Schiff base ligands based on β-cyclodextrin for aqueous biphasic hydroformylation reaction". Thesis, Artois, 2018. http://www.theses.fr/2018ARTO0404.

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L'utilisation de cyclodextrines (CDs) comme additifs interfaciaux en catalyse biphasique aqueuse s'est avérée être une méthode efficace pour la transformation de composés hydrophobes. Pour améliorer de façon significative la proximité entre le catalyseur organométallique hydrosoluble et le composé organique à transformer, deux nouvelles familles de récepteurs moléculaires à base de CDs ont été développées. Une première stratégie a consisté à greffer de façon covalente une phosphine sulfonée sur une CD (système CD-P). Le récepteur moléculaire ainsi obtenu a permis d'améliorer significativement
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14

Ourari, Ali. "Étude de deux réactions d'électrocatalyse : hydrogénation électrocatalytique sur des films de polymères contenant des microparticules de métaux nobles et activation de l'oxygène par des complexes Mn(III) - bases de Schiff." Université Joseph Fourier (Grenoble ; 1971-2015), 1995. http://www.theses.fr/1995GRE10171.

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Ce travail est relatif a l'etude de deux reactions d'electrocatalyse. La premiere partie concerne la mise au point de cathodes moleculaires, realisees par l'inclusion de microparticules de metaux nobles dans des films de polypyrrole fonctionnalise et a leur application en hydrogenation electrocatalytique. L'etude de l'hydrogenation de deux substrats test, le limonene et la carvone, a montre qu'il est possible d'orienter la selectivite de ces electrodes modifiees selon la nature du metal incorpore (pt, pd ou rh). Le resultat le plus significatif est que l'incorporation dans le meme film de poly
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15

Salvà, Salvà Antoni. "Estudio teórico de la reaccionabilidad de compuestos modelo de la vitamina B6 con aminas." Doctoral thesis, Universitat de les Illes Balears, 2006. http://hdl.handle.net/10803/9450.

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S'han realitzat càlculs PM3 i DFT (B3LYP/6-31+G*) per tal de descriure els perfils de reacció de la formació de la base de Schiff entre un compost anàlog del 5'-fosfat de piridoxal i una amina, i de la transiminació. Es descriu també un estudi de la topologia de la funció densitat de càrrega de les estructures DFT segons la teoria de Bader AIM.<br/> Els detalls dels mecanismes destaquen el paper fonamental de la molècula d'aigua i dels grups polars per a la formació d'estructures de transició concertades associades a transferències d'hidrogen i per proporcionar l'estabilització als intermedis
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16

Vincens, Hélène. "Synthèse et utilisation de nouveaux groupements nucléofuges : application à l'alkylation énantiosélective." Rouen, 1987. http://www.theses.fr/1987ROUES010.

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Synthèses d'alpha-aminoacides optiquement actifs, d'alpha-hydroxyacides et d'une nouvelle série d'agents d'alkylation : des benzènesulfonates porteurs d'une fonction éther sur la chaine latérale en ortho
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17

Bedioui, Fethi. "Etude électrochimique de complexes de métaux de transition (bases de Schiff et porphyrines) en solution et sous forme d'électrodes modifiées : application à la catalyse électroassistée de réactions organiques." Paris 6, 1986. http://www.theses.fr/1986PA066338.

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Les propriétés électrochimiques des complexes co-base de Schiff (phenylene-bis(salicylideneiminoto)-co, ou Co(II)saloph, et n-methylenepropylene-bis-(salicylideneiminoto)-co, ou co-selnmedpt) et de tetraphenylporphine-co, ou CoTPP, sont utilisées pour étudier la réduction électroassistée d'halogénures organiques, Rx, avec un catalyseur fixe sur support conducteur, en milieu organique. On étudie: 1) la réduction du chlorure de benzyle électrocatalysée par des électrodes de graphite modifiées par du co-saloph et 2) l'oxydation par l'oxygène moléculaire du di-tert-butylphenol, électrocatalysée pa
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18

Achi, Sabah Samira. "Nouvelle voie d'acces aux acides alpha -amines, par catalyse homogene a l'aide de complexes de metaux de transition, synthese de nouveaux complexes phosphores chiraux du tungstene pentacarbonyle." Paris 6, 1987. http://www.theses.fr/1987PA066227.

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19

Silveira, Vivian Chagas da. "Investigação da atividade biológica de complexos de cobre(II) com ligantes inspirados em biomoléculas." Universidade de São Paulo, 2009. http://www.teses.usp.br/teses/disponiveis/46/46134/tde-15062009-154840/.

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Neste trabalho, alguns novos complexos imínicos de cobre(II) com ligantes inspirados em biomoléculas como oxindóis, contendo grupos indólicos, imidazólicos ou pirrólicos com diferentes características estruturais, foram sintetizados e caracterizados por análise elementar, espectrometria ESI-MS e espectroscopias IV, UVNis e EPR. As possíveis interações desses complexos de cobre com a albumina humana (HSA) e com o plasma sanguíneo foram estudadas através das técnicas EPR, CD e SDS-PAGE, indicando que estas ocorrem principalmente no sítio N-terminal da proteína. Suas reatividades frente a compost
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20

Gaudin, Jean-Marc. "Synthèses sélectives à l'aide de complexes du Palladium(0) : élaboration de chaine latérale de stéroïde (glaucastérol), phéromones et alpha-amino esters d'intérêts biologiques." Paris 6, 1986. http://www.theses.fr/1986PA066536.

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Ce travail porte sur l'utilisation de complexe du palladium (0) en catalyse homogène pour la synthèse de molécules d'intérêts biologiques. Trois applications y sont décrites: - la synthèse d'une phéromone secrétée par la reine des abeilles et d'une hormone végétale : l'acide traumatique. La construction du squelette carbone de ces molécules est basée sur une double alkylation d'une bis (aryl sulfonyl) méthane, l'une d'entre elles faisant intervenir un complexe eta (3) allyl palladien fonctionnalisé ; - la synthèse d'alpha-amino esters susceptibles d'être utilisés comme inhibiteur d'enzyme. Cec
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21

Goodwin, John Alan. "Structures, reaction kinetics, and dioxygen chemistry of some pentacoordinate Schiff base copper complexes." Thesis, 1987. http://hdl.handle.net/1911/16145.

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Crystal structures of the Cu(I)/Cu(II) complexes of the pentadentate nitrogen-bonding Schiff-base ligand, $\{$bis-2,6- (1-(2-pyridin-2-ylethylimino)ethyl) pyridine$\}$, (Cu$\sp{\rm I/II}$(py)$\sb2$DAP) $\sp{\rm n+}$, 1, and of the similar ligand, $\{$bis-2,6- (1-(2-imidazol-4yl-ethylimino)ethyl) pyridine$\}$, (Cu$\sp{\rm I}$(imidH)$\sb2$DAP$\sp+$, 2, have been solved as the tetrafluorobrorate salts. The complexes are all pentacoordinate about the copper center. The crystal structure of the tetracoordinate isomer of 1, the Cu(I) complex of $\{$2- (1-(2-imidazol-4yl-ethylimino)ethyl) -6- ((1-tet
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22

(6565601), Nan Wang. "Ion/Ion Reaction Facilitated Mass Spectrometry and Front-End Method Development." Thesis, 2019.

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Mass spectrometry is a versatile analytical tool for chemical and biomolecule identification, quantitation, and structural analysis. Tandem mass spectrometry further expands the applications of mass spectrometry, making it more than a mere detector. With tandem mass spectrometry, the mass spectrometer is capable of probing reaction mechanisms, monitoring reaction processes, and performing fast analysis on complex samples. In tandem mass spectrometry, after activation the precursor ions fragment into small fragment ions through one or more pathways, which are affected by the ion’s inherit prope
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Lephoto, Mapudumo Lydia. "Synthesis, characterization and application of Schiff base cobalt and zinc complexes as catalysts for CO2 and epoxide copolymerization reaction." Thesis, 2013. http://hdl.handle.net/10210/8529.

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Wen-Chou, Hung, and 洪文周. "Synthesis and Characterization of Schiff Base Metal Complexes and Their Applications in Ring Opening Polymerizations and Suzuki Coupling Reactions." Thesis, 2004. http://ndltd.ncl.edu.tw/handle/74420072594123386368.

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謝長志. "Pyrazole-organonitrile coupling reaction activated by Ni(II) ions and syntheses and characterization of metal complexes with N2S-containing schiff base ligand." Thesis, 2009. http://ndltd.ncl.edu.tw/handle/61429581972511389660.

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碩士<br>國立彰化師範大學<br>化學系<br>97<br>Abstract By using the coupling reaction between pyrazole (HPz) and organic nitrile (RCN) mediated by Ni2+ ions, a series of pyrazolylamidinonickel complexes were synthesized. When four equivalent of HPz and one equivalent of [Ni(MeCN)6][X-] (X-= ClO4-, BF4- , or NO3-) were stirred in MeCN, complexes [Ni(MeCN)2(HPz)4][X-] (X-= ClO4- (1),BF4- (5),NO3- (9)) were obtained immediately, which serve as the intermediates for the coupling reaction. Although the isomerization of complexes 1 and 9 to complexes [Ni(HPz)2(HN=C(Me)Pz)2][X-] (X- = ClO4- (2), NO3- (10)) occurs s
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Wang, Cheng-Tsung, and 王承宗. "Synthesis and Characterization of Nickel and Zinc Complexes Supported by Pentadentate Schiff-Base : Their Application in the Reaction of Cyclohexene oxide and Carbon dioxide." Thesis, 2019. http://ndltd.ncl.edu.tw/handle/4amr3d.

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碩士<br>國立中興大學<br>化學系所<br>107<br>A series of extraordinary nickel and zinc complexes (1)-(7) supported by pentadentate Sciff-base ancillary ligands with various electronic effect of substituents (L1H, L2H, L3H) have been synthesized. These complexes have been structurally characterized by elemental analysis, UV-Vis spectroscopy, as well as NMR studies. X-ray structural studies reveal that znic complexes are ionic composed by a dinuclear cation [LZn2(OAc)2]+ and a variety of anions [Znx(OAc)y]n-. Structures of (5)-(7) show nickel complexes are neutral composed by a dinuclear compound [LNi2(OAc)(S
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Wang, Pei-Chin, and 王姵今. "Synthesis and Characterization of S,N,O-Tridentate Schiff Base Nickel and Zinc Complexes and Their Catalytic Studies in the Reaction of Epoxides with Carbon Dioxide." Thesis, 2018. http://ndltd.ncl.edu.tw/handle/886933.

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碩士<br>國立中興大學<br>化學系所<br>106<br>A series of novel nickel and zinc acetate complexes (1-9) supported by S,N,O-tridentate Schiff-base ancillary ligands bearing substituents with electronic or steric effect have been synthesized. The composition of complexes have been characterized by elemental analysis, FT-IR and LC/MS spectroscopy. Their physical properties were investigated using UV/Vis spectroscopy and a melting point analyzer. X-ray diffraction studies of 1、2b、4 and 7 indicate that these complexes have a variety of geometry such as pentanuclear five-coordinated nickel center, trinuclear six-c
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Yang, Meng-Hua, and 楊孟樺. "Synthesis and Characterization of Transition Metal(Ni, Co, Cu) Complexes Supported by S,N,O-Schiff Base Ligands for Reaction of Cyclohexene Oxide with Carbon Dioxide." Thesis, 2019. http://ndltd.ncl.edu.tw/handle/355eu8.

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碩士<br>國立中興大學<br>化學系所<br>107<br>A series of novel transition metal (Ni, Co, Cu) complexes bearing S,N,O-tridentate Schiff–base ligands have been synthesized with respect to various electronic and steric effect. The results of one-pot CHO/CO2 reaction carried out with ligand precusors and transition metals infer the active species in the reaction. The composition of complexes has been characterized by elemental analysis, FT-IR and EPR spectroscopy. Their physical properties were investigated using the melting point analyzer and UV/Vis spectroscopy. X-ray diffraction studies of the complex (1
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Hsu, Shao-Hsuan, and 徐紹軒. "Synthesis and Characterization of Zinc Complexes Supported by Schiff Base Ligands : Their Application in the Ring-Opening Polymerization of Cyclic Ester and the Reaction of Cyclohexane Oxide with Carbon Dioxide." Thesis, 2018. http://ndltd.ncl.edu.tw/handle/e525a3.

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碩士<br>國立中興大學<br>化學系所<br>106<br>A series of zinc complexes bearing NNO Schiff-base ligands [LxZnEt]2 (1a)-(7a) and LxHZnCl2(1b)-(7b) have been synthesized and characterized. Ring-Opening Polymerization (ROP) of L-Lactide (L-LA) catalyzed by (1a)-(7a) with BnOH as an initiator has been investigated. Experimental results show that these complexes are all active for ROP of L-Lactide with the electron-donating substitution groups enhancing the activity of zinc complexes and polymers obtained bear narrow polydispersity (PDI). Complexes (1b)-(7b) all show catalytic activity for the reaction of cycloh
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Wang, Wei-Chu, and 王偉竹. "Synthesis and Characterization of Zinc Complexes Supported by NNO-Tridentate Schiff-Base Ligands and Their Application in Ring-Opening Polymerization of L-Lactide and Reaction of Cyclohexene Oxide with Carbon Dioxide." Thesis, 2019. http://ndltd.ncl.edu.tw/handle/c5jf56.

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碩士<br>國立中興大學<br>化學系所<br>107<br>A series of novel zinc ethyl complexes [LZnEt] (1) - (9) bearing NNO-tridentate Schiff-base ligands with an N-pendant arm have been synthesized and used as catalysts for ring-opening polymerization of L-lactide and the reaction of cyclohexene oxide with carbon dioxide. These complexes were characterized as mono-nuclear species with respect to various electronic and steric effect. Ring-opening polymerization of L-lactide by [LZnEt] in the presence of BnOH and copolymerization of epoxides/CO2 were investigated. Experimental results reveal that the activity of these
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Katsiaouni, Stamatia. "Neuartige Pyrrol/Pyrazol-Bausteine für die Synthese von Hybrid-Makrozyklen, azyklischen Ligandsystemen und bimetallischen Komplexen." Doctoral thesis, 2007. http://hdl.handle.net/11858/00-1735-0000-0006-ACA0-A.

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