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1

Sun, Fang, Zhiyuan Tan, Zhengguang Hu, et al. "Ultrathin Silicon Nanowires Produced by a Bi-Metal-Assisted Chemical Etching Method for Highly Stable Lithium-Ion Battery Anodes." Nano 15, no. 06 (2020): 2050076. http://dx.doi.org/10.1142/s1793292020500769.

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Silicon is widely studied as a high-capacity lithium-ion battery anode. However, the pulverization of silicon caused by a large volume expansion during lithiation impedes it from being used as a next generation anode for lithium-ion batteries. To overcome this drawback, we synthesized ultrathin silicon nanowires. These nanowires are 1D silicon nanostructures fabricated by a new bi-metal-assisted chemical etching process. We compared the lithium-ion battery properties of silicon nanowires with different average diameters of 100[Formula: see text]nm, 30[Formula: see text]nm and 10[Formula: see t
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2

Boone, Donald C. "Quantum Mechanical Comparison between Lithiated and Sodiated Silicon Nanowires." Applied Nano 5, no. 2 (2024): 48–57. http://dx.doi.org/10.3390/applnano5020005.

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This computational research study will compare the specific charge capacity (SCC) between lithium ions inserted into crystallized silicon (c-Si) nanowires with that of sodium ions inserted into amorphous silicon (a-Si) nanowires. It will be demonstrated that the potential energy V(r) within a lithium–silicon nanowire supports a coherent energy state model with discrete electron particles, while the potential energy of a sodium–silicon nanowire will be discovered to be essentially zero, and, thus, the electron current that travels through a sodiated silicon nanowire will be modeled as a free el
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3

Li, Wenhan. "Performance of Li-ion battery with silicon nanowire in anode." Journal of Physics: Conference Series 2355, no. 1 (2022): 012071. http://dx.doi.org/10.1088/1742-6596/2355/1/012071.

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Abstract Li-ion batteries are extensively used in electronic devices, cell phones, new energy vehicle batteries, and other sectors, and they have a lot of promise in electric cars and other domains. With the development of the times, batteries with carbon as anode material can no longer meet the demand of electric vehicles and other fields for battery energy density. Silicon, one of the most potential anode materials, demonstrates extremely high theoretical battery energy density. In the past few years, research on silicon nanostructures, especially silicon nanowires, has effectively solved th
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4

Vlad, Alexandru, Arava Leela Mohana Reddy, Anakha Ajayan, et al. "Roll up nanowire battery from silicon chips." Proceedings of the National Academy of Sciences 109, no. 38 (2012): 15168–73. http://dx.doi.org/10.1073/pnas.1208638109.

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Here we report an approach to roll out Li-ion battery components from silicon chips by a continuous and repeatable etch-infiltrate-peel cycle. Vertically aligned silicon nanowires etched from recycled silicon wafers are captured in a polymer matrix that operates as Li+ gel-electrolyte and electrode separator and peeled off to make multiple battery devices out of a single wafer. Porous, electrically interconnected copper nanoshells are conformally deposited around the silicon nanowires to stabilize the electrodes over extended cycles and provide efficient current collection. Using the above dev
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5

Keller, Caroline, Yassine Djezzar, Jingxian Wang, et al. "Easy Diameter Tuning of Silicon Nanowires with Low-Cost SnO2-Catalyzed Growth for Lithium-Ion Batteries." Nanomaterials 12, no. 15 (2022): 2601. http://dx.doi.org/10.3390/nano12152601.

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Silicon nanowires are appealing structures to enhance the capacity of anodes in lithium-ion batteries. However, to attain industrial relevance, their synthesis requires a reduced cost. An important part of the cost is devoted to the silicon growth catalyst, usually gold. Here, we replace gold with tin, introduced as low-cost tin oxide nanoparticles, to produce a graphite–silicon nanowire composite as a long-standing anode active material. It is equally important to control the silicon size, as this determines the rate of decay of the anode performance. In this work, we demonstrate how to contr
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6

Tang, Jiajun. "Progress in the application of silicon-based anode nanotechnology in lithium batteries." E3S Web of Conferences 553 (2024): 01007. http://dx.doi.org/10.1051/e3sconf/202455301007.

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With the development of technology, graphite materials in traditional lithium batteries can no longer meet people’s needs due to their relatively low specific capacity, limited charging and discharging rates, and poor safety. Silicon has a very high theoretical specific capacity, far exceeding traditional graphite negative electrode materials, making silicon nanoparticles an ideal choice for improving the energy density of lithium-ion batteries. In this paper, we first introduce the silicon nanoparticle anode and its preparation methods: mechanical ball milling, and thermal cracking, and intro
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7

Boone, Donald C. "Density Functional Theory Analysis that Explains the Volume Expansion in Prelithiated Silicon Nanowires." European Journal of Applied Physics 6, no. 2 (2024): 31–35. http://dx.doi.org/10.24018/ejphysics.2024.6.2.305.

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This research is a theoretical study that simulates the volume expansion of a prelithiated silicon nanowire during lithium-ion insertion and the application of an electric current. Utilizing density functional theory (DFT) the ground state energy Eg (x) of prelithiated silicon (LixSi) is defined as a function of the lithium-ion (Li+) concentration (x). As the Li+ are increased, Eg (x) become increasingly stable from x = 1.00 through x = 2.415 and decrease in stability as the lithium-ion concentration becomes x > 2.415 until full lithiation of the silicon nanowire is reached at x = 3.75. Aft
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8

Yan, Zheng. "Applications and Improving Methods of Silicon Nanowires in Lithium-ion Batteries." Highlights in Science, Engineering and Technology 32 (February 12, 2023): 199–205. http://dx.doi.org/10.54097/hset.v32i.5088.

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Silicon has been considered as a crucial electrode material for the gradually adaptation of lithium-ion batteries into electrical-vehicle market and further utilizations of the next generation batteries, since silicon anodes can provide both commercial-friendly energy density and excellent cycle stability. Although much progress has been made in the research on silicon nano-negative electrodes, there is a lack of concentrated discussion on the development status and problems of silicon nanowires, especially in consideration of the fact that the 1-D nanowire structure presents an excellent prop
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9

Li, Yunsong. "Preparation method and application of silicon nanowires." Highlights in Science, Engineering and Technology 32 (February 12, 2023): 237–44. http://dx.doi.org/10.54097/hset.v32i.5172.

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In recent years, silicon nanowires have become a hot spot in the new material industry. As a kind of nanomaterial, silicon nanowires have excellent physical and chemical properties. However, the preparation method of silicon nanowires is not mature enough, which limits its further application. This paper mainly analyses the mechanism, advantages and disadvantages of several mainstream silicon nanowires preparation methods, and discusses the application of silicon nanowires and the future development direction. The results show that the chemical vapor deposition method can be used for large-sca
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10

Santa Maria, Luigi Jacopo, M. Zain Bin Amjad, Dominika Capkova, Hugh Geaney, and Abinaya M. Sankaran. "Influence of Tin (Sn) Dispersion on the Synthesis of Silicon Nanowires on Graphite Substrates for Li-Ion Batteries Anodes." ECS Meeting Abstracts MA2023-02, no. 8 (2023): 3390. http://dx.doi.org/10.1149/ma2023-0283390mtgabs.

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In recent years, because of a more prominent power electrification, lithium-ion batteries (LIBs) have attracted more and more interest in the scientific community. The desire to increase the battery performance, capacity, and power density has led to the development of new electrode materials. Silicon has emerged as a prominent anode material for next-generation lithium-ion batteries because of its high capacity [1] (10 times higher than graphite) and energy density. However, its utilization is limited by poor electronic conductivity and significant volume changes (up to 400%) observed during
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11

Hennessy, Aaron, Mei Li, Hugh Geaney, and Kevin M. Ryan. "Lithium Trapping in Silicon Nanowire Anodes for Lithium-Ion Batteries." ECS Meeting Abstracts MA2023-02, no. 65 (2023): 3057. http://dx.doi.org/10.1149/ma2023-02653057mtgabs.

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Silicon has long been considered a prospective anode material for lithium-ion batteries (LIBs) due to its high theoretical specific capacity and natural abundance. However, silicon is known to suffer from significant volumetric expansion (~ 400%) during lithiation and de-lithiation. The induced mechanical stress leads to pulverization of silicon as well as electrolyte consumption, which results in poor coulombic efficiency, high irreversible capacity loss and cell failure(1-3). Nanostructured silicon in the form of nanoparticles, nanowires, nanotubes, and nanoporous silicon has demonstrated hi
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12

Boone, Donald C. "Second Harmonic Generation in Lithiated Silicon Nanowires: Derivations and Computational Methods." European Journal of Applied Physics 3, no. 6 (2021): 36–46. http://dx.doi.org/10.24018/ejphysics.2021.3.6.130.

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This research will examine the computational methods to calculate the nonlinear optical process of second harmonic generation (SHG) that will be hypothesized to be present during lithium ion insertion into silicon nanowires. First it will be determined whether the medium in which SHG is conveyed is non-centrosymmetric or whether the medium is inversion symmetric where SHG as a part of the second-order nonlinear optical phenomenon does not exist. It will be demonstrated that the main interaction that determines SHG is multiphoton absorption on lithium ions. The quantum harmonic oscillator (QHO)
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13

Nugroho, Andika Pandu, Naufal Hanif Hawari, Bagas Prakoso, et al. "Vertically Aligned n-Type Silicon Nanowire Array as a Free-Standing Anode for Lithium-Ion Batteries." Nanomaterials 11, no. 11 (2021): 3137. http://dx.doi.org/10.3390/nano11113137.

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Due to its high theoretical specific capacity, a silicon anode is one of the candidates for realizing high energy density lithium-ion batteries (LIBs). However, problems related to bulk silicon (e.g., low intrinsic conductivity and massive volume expansion) limit the performance of silicon anodes. In this work, to improve the performance of silicon anodes, a vertically aligned n-type silicon nanowire array (n-SiNW) was fabricated using a well-controlled, top-down nano-machining technique by combining photolithography and inductively coupled plasma reactive ion etching (ICP-RIE) at a cryogenic
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14

Zhang, Baoguo, Ling Tong, Lin Wu, et al. "Design of ultrafine silicon structure for lithium battery and research progress of silicon-carbon composite negative electrode materials." Journal of Physics: Conference Series 2079, no. 1 (2021): 012005. http://dx.doi.org/10.1088/1742-6596/2079/1/012005.

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Abstract As demand for high-performance electric vehicles, portable electronic equipment, and energy storage devices increases rapidly, the development of lithium-ion batteries with higher specific capacity and rate performance has become more and more urgent. As the main body of lithium storage, negative electrode materials have become the key to improving the performance of lithium batteries. The high specific capacity and low lithium insertion potential of silicon materials make them the best choice to replace traditional graphite negative electrodes. Pure silicon negative electrodes have h
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15

Xu, Wanli, and John C. Flake. "Composite Silicon Nanowire Anodes for Secondary Lithium-Ion Cells." Journal of The Electrochemical Society 157, no. 1 (2010): A41. http://dx.doi.org/10.1149/1.3251341.

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16

Xu, Wanli, Sri Sai S. Vegunta, and John C. Flake. "Surface-modified silicon nanowire anodes for lithium-ion batteries." Journal of Power Sources 196, no. 20 (2011): 8583–89. http://dx.doi.org/10.1016/j.jpowsour.2011.05.059.

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17

Karki, Khim, Eric Epstein, Jeong-Hyun Cho, et al. "Lithium-Assisted Electrochemical Welding in Silicon Nanowire Battery Electrodes." Nano Letters 12, no. 3 (2012): 1392–97. http://dx.doi.org/10.1021/nl204063u.

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18

Ruffo, Riccardo, Seung Sae Hong, Candace K. Chan, Robert A. Huggins, and Yi Cui. "Impedance Analysis of Silicon Nanowire Lithium Ion Battery Anodes." Journal of Physical Chemistry C 113, no. 26 (2009): 11390–98. http://dx.doi.org/10.1021/jp901594g.

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19

Chockla, Aaron M., Justin T. Harris, Vahid A. Akhavan, et al. "Silicon Nanowire Fabric as a Lithium Ion Battery Electrode Material." Journal of the American Chemical Society 133, no. 51 (2011): 20914–21. http://dx.doi.org/10.1021/ja208232h.

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20

Hwang, Chihyun, Kangmin Lee, Han-Don Um, Yeongdae Lee, Kwanyong Seo, and Hyun-Kon Song. "Conductive and Porous Silicon Nanowire Anodes for Lithium Ion Batteries." Journal of The Electrochemical Society 164, no. 7 (2017): A1564—A1568. http://dx.doi.org/10.1149/2.1241707jes.

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21

Tao, Jinming, Xintong Li, Jinye Li, et al. "Compact, High Extinction Ratio, and Low-Loss Polarization Beam Splitter on Lithium-Niobate-On-Insulator Using a Silicon Nitride Nanowire Assisted Waveguide and a Grooved Waveguide." Photonics 9, no. 10 (2022): 779. http://dx.doi.org/10.3390/photonics9100779.

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We propose a compact, high extinction ratio, and low-loss polarization beam splitter (PBS) on a lithium-niobate-on-insulator (LNOI) platform, based on an asymmetrical directional coupler and using a silicon nitride nanowire assisted waveguide (WG) and a grooved WG. By properly designing nanowires and grooved LN WGs, TE polarization meets the phase matching condition, while significant mismatching exists for TM polarization. Numerical simulations show that the PBS has an ultra-high extinction ratio (ER) of and (larger than 40 dB and 50 dB, respectively). The device extinction ratios are larger
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22

Hu, Mengqi, Yuhao Wang, and Diwen Ye. "A Timely Review of Lithium-ion Batteries in Electric Vehicles: Progress, Future Opportunities, and Challenges." E3S Web of Conferences 308 (2021): 01015. http://dx.doi.org/10.1051/e3sconf/202130801015.

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Energy plays an important role in human society. With the development of science and technology, the increasing demand for new energy like electric energy cannot be ignored. The battery is the key component of electric vehicles which are the centers of future development. Lithium-ion batteries have great advantages in electric vehicle applications for their excellent performance. We need to find ways to improve lithium-ion batteries to promote the development of electric vehicles fundamentally. The high specific energy, low self-discharge, good cycling performance, no memory effect, and other
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23

Song, Hucheng, Sheng Wang, Xiaoying Song, et al. "A bottom-up synthetic hierarchical buffer structure of copper silicon nanowire hybrids as ultra-stable and high-rate lithium-ion battery anodes." Journal of Materials Chemistry A 6, no. 17 (2018): 7877–86. http://dx.doi.org/10.1039/c8ta01694a.

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24

Lin, Kuan-Jiuh. "Preparation of high-efficiency anti-reflective oxide electrodes and their application in biomedical testing and thin-film lithium batteries." Impact 2022, no. 3 (2022): 6–8. http://dx.doi.org/10.21820/23987073.2022.3.6.

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Nanomaterials hold great potential in the development of lithium-ion microbatteries and could assist in developing ever smaller and more reliable power sources to facilitate 21st Century life. Professor Kuan-Jiuh Lin is based in the Department of Chemistry, National Chung Hsing University, Taiwan, and runs the Interfacial Optical-Electronic (IOE) Lab. He and his team leader Dr Wen-Yin Ko are working to address gaps in nanotechnology, including how to conquer the strong interfacial coupling between the porous semiconductor membrane and the electro-plasmon metal-surface film. Their research is e
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25

Schneier, Dan, Nimrod Harpak, Svetlana Menkin, et al. "Analysis of Scale-up Parameters in 3D Silicon-Nanowire Lithium-Battery Anodes." Journal of The Electrochemical Society 167, no. 5 (2020): 050511. http://dx.doi.org/10.1149/1945-7111/ab6f5a.

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26

Cho, Jeong-Hyun, and S. Tom Picraux. "Silicon Nanowire Degradation and Stabilization during Lithium Cycling by SEI Layer Formation." Nano Letters 14, no. 6 (2014): 3088–95. http://dx.doi.org/10.1021/nl500130e.

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Huang, Rui, and Jing Zhu. "Silicon nanowire array films as advanced anode materials for lithium-ion batteries." Materials Chemistry and Physics 121, no. 3 (2010): 519–22. http://dx.doi.org/10.1016/j.matchemphys.2010.02.017.

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28

Xu, Wanli, Sri S. Vegunta, and J. C. Flake. "Modified Solid Electrolyte Interphase of Silicon Nanowire Anodes for Lithium-Ion Batteries." ECS Transactions 33, no. 23 (2019): 55–61. http://dx.doi.org/10.1149/1.3557700.

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Schneier, Dan, Nimrod Harpak, Svetlana Menkin, et al. "Analysis of Scale-up Parameters in 3D Silicon-Nanowire Lithium-Battery Anodes." ECS Meeting Abstracts MA2020-02, no. 2 (2020): 358. http://dx.doi.org/10.1149/ma2020-022358mtgabs.

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Xie, Yuanyuan, Ming Qiu, Xianfeng Gao, Dongsheng Guan, and Chris Yuan. "Phase field modeling of silicon nanowire based lithium ion battery composite electrode." Electrochimica Acta 186 (December 2015): 542–51. http://dx.doi.org/10.1016/j.electacta.2015.11.022.

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31

Wu, Zheshan, and Defei Kong. "Comparative life cycle assessment of lithium-ion batteries with lithium metal, silicon nanowire, and graphite anodes." Clean Technologies and Environmental Policy 20, no. 6 (2018): 1233–44. http://dx.doi.org/10.1007/s10098-018-1548-9.

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32

Krause, Andreas, Olga Tkacheva, Ahmad Omar, et al. "In Situ Raman Spectroscopy on Silicon Nanowire Anodes Integrated in Lithium Ion Batteries." Journal of The Electrochemical Society 166, no. 3 (2019): A5378—A5385. http://dx.doi.org/10.1149/2.0541903jes.

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Huang, Rui, Xing Fan, Wanci Shen, and Jing Zhu. "Carbon-coated silicon nanowire array films for high-performance lithium-ion battery anodes." Applied Physics Letters 95, no. 13 (2009): 133119. http://dx.doi.org/10.1063/1.3238572.

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Keller, Caroline, Saravanan Karuppiah, Praveen Kumar, et al. "Silicon Nanowire-Graphite Composites As High Energy Anode Materials for Lithium Ion Batteries." ECS Meeting Abstracts MA2020-01, no. 2 (2020): 386. http://dx.doi.org/10.1149/ma2020-012386mtgabs.

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Kohandehghan, Alireza, Peter Kalisvaart, Martin Kupsta, et al. "Magnesium and magnesium-silicide coated silicon nanowire composite anodes for lithium-ion batteries." J. Mater. Chem. A 1, no. 5 (2013): 1600–1612. http://dx.doi.org/10.1039/c2ta00769j.

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Wang, Fenfen, Xianfeng Gao, Lulu Ma, Tao Li, and Chris Yuan. "Sustainability Analysis of Silicon Nanowire Fabrication for High Performance Lithium Ion Battery Anode." Procedia Manufacturing 7 (2017): 151–56. http://dx.doi.org/10.1016/j.promfg.2016.12.040.

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Chakrapani, Vidhya, Florencia Rusli, Micheal A. Filler, and Paul A. Kohl. "Quaternary Ammonium Ionic Liquid Electrolyte for a Silicon Nanowire-Based Lithium Ion Battery." Journal of Physical Chemistry C 115, no. 44 (2011): 22048–53. http://dx.doi.org/10.1021/jp207605w.

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Cho, Jeong-Hyun, and S. Tom Picraux. "Enhanced Lithium Ion Battery Cycling of Silicon Nanowire Anodes by Template Growth to Eliminate Silicon Underlayer Islands." Nano Letters 13, no. 11 (2013): 5740–47. http://dx.doi.org/10.1021/nl4036498.

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Wang, Fenfen, Yelin Deng, and Chris Yuan. "Comparative Life Cycle Assessment of Silicon Nanowire and Silicon Nanotube Based Lithium Ion Batteries for Electric Vehicles." Procedia CIRP 80 (2019): 310–15. http://dx.doi.org/10.1016/j.procir.2019.01.004.

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Collins, Gearoid A., Seamus Kilian, Hugh Geaney, and Kevin M. Ryan. "A Nanowire Nest Structure Comprising Copper Silicide and Silicon Nanowires for Lithium‐Ion Battery Anodes with High Areal Loading." Small 17, no. 34 (2021): 2102333. http://dx.doi.org/10.1002/smll.202102333.

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Boles, Steven T., Andreas Sedlmayr, Oliver Kraft, and Reiner Mönig. "In situcycling and mechanical testing of silicon nanowire anodes for lithium-ion battery applications." Applied Physics Letters 100, no. 24 (2012): 243901. http://dx.doi.org/10.1063/1.4729145.

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Cai, Wudi, Hairong He, Lili Miao, and Chujun Zhao. "Modelling the broadband mid-infrared dispersion compensator with hybrid silicon and lithium niobate nanowire." OSA Continuum 1, no. 2 (2018): 736. http://dx.doi.org/10.1364/osac.1.000736.

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43

Wang, Jiantao, Hui Wang, Bingchang Zhang, Yao Wang, Shigang Lu, and Xiaohong Zhang. "A Stable Flexible Silicon Nanowire Array as Anode for High-Performance Lithium-ion Batteries." Electrochimica Acta 176 (September 2015): 321–26. http://dx.doi.org/10.1016/j.electacta.2015.07.001.

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44

Cho, Jeong-Hyun, Xianglong Li, and S. Tom Picraux. "The effect of metal silicide formation on silicon nanowire-based lithium-ion battery anode capacity." Journal of Power Sources 205 (May 2012): 467–73. http://dx.doi.org/10.1016/j.jpowsour.2012.01.037.

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Wang, Wei, Miao Tian, Yujie Wei, Se-Hee Lee, Yung-Cheng Lee, and Ronggui Yang. "Binder-free three-dimensional silicon/carbon nanowire networks for high performance lithium-ion battery anodes." Nano Energy 2, no. 5 (2013): 943–50. http://dx.doi.org/10.1016/j.nanoen.2013.03.015.

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46

Zheng, Hao, Shan Fang, Zhenkun Tong, et al. "Stabilized titanium nitride nanowire supported silicon core–shell nanorods as high capacity lithium-ion anodes." Journal of Materials Chemistry A 3, no. 23 (2015): 12476–81. http://dx.doi.org/10.1039/c5ta02259b.

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3D TiN@Si core–shell nanorod array electrodes have been successfully prepared by a controllable RF magnetron sputtering method. TiN@Si NR electrodes exhibit high capacity and good rate performance due to the superior mechanical stability and electrical conductivity of TiN NWs.
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Wang, Xin, Lanyan Huang, Yongguang Zhang, et al. "Novel silicon nanowire film on copper foil as high performance anode for lithium-ion batteries." Ionics 24, no. 2 (2017): 373–78. http://dx.doi.org/10.1007/s11581-017-2219-2.

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48

Schmerling, Marcus, Daniela Fenske, Fabian Peters, Julian Schwenzel, and Matthias Busse. "Lithiation Behavior of Silicon Nanowire Anodes for Lithium-Ion Batteries: Impact of Functionalization and Porosity." ChemPhysChem 19, no. 1 (2017): 123–29. http://dx.doi.org/10.1002/cphc.201700892.

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Chan, Candace K., Riccardo Ruffo, Seung Sae Hong, and Yi Cui. "Surface chemistry and morphology of the solid electrolyte interphase on silicon nanowire lithium-ion battery anodes." Journal of Power Sources 189, no. 2 (2009): 1132–40. http://dx.doi.org/10.1016/j.jpowsour.2009.01.007.

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Zhou, Hui, Jagjit Nanda, Surendra K. Martha, et al. "Role of Surface Functionality in the Electrochemical Performance of Silicon Nanowire Anodes for Rechargeable Lithium Batteries." ACS Applied Materials & Interfaces 6, no. 10 (2014): 7607–14. http://dx.doi.org/10.1021/am500855a.

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