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Artykuły w czasopismach na temat "Truxene based supramolecular cages":

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Benchohra, Amina, Simon Séjourné, Antoine Labrunie, Liam Miller, Enzo Charbonneau, Vincent Carré, Frédéric Aubriet, Magali Allain, Marc Sallé i Sébastien Goeb. "Controlling Chiral Self-Sorting in Truxene-Based Self-Assembled Cages". Inorganics 10, nr 7 (19.07.2022): 103. http://dx.doi.org/10.3390/inorganics10070103.

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Coordination driven self-assembly of achiral components, i.e., hexa-alkylated truxene ligands (L) with bis-metallic complexes (M2), afforded three chiral face-rotating stereoisomer polyhedra (M6L2). By tuning the length of the alkyl chains as well as the distance between both ligands facing each other in the self-assemblies (M6L2), one can control the diastereomeric distribution between the expected homo- and hetero-chiral structures.
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Raee, Ehsan, Yuqing Yang i Tianbo Liu. "Supramolecular structures based on metal-organic cages". Giant 5 (marzec 2021): 100050. http://dx.doi.org/10.1016/j.giant.2021.100050.

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Ling, Qing-Hui, Jun-Long Zhu, Yi Qin i Lin Xu. "Naphthalene diimide- and perylene diimide-based supramolecular cages". Materials Chemistry Frontiers 4, nr 11 (2020): 3176–89. http://dx.doi.org/10.1039/d0qm00540a.

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Kniazeva, Mariia V., Alexander S. Ovsyannikov, Aida I. Samigullina, Daut R. Islamov, Aidar T. Gubaidullin, Pavel V. Dorovatovskii, Vladimir A. Lazarenko, Svetlana E. Solovieva, Igor S. Antipin i Sylvie Ferlay. "Impact of flexible succinate connectors on the formation of tetrasulfonylcalix[4]arene based nano-sized polynuclear cages: structural diversity and induced chirality study". CrystEngComm 24, nr 3 (2022): 628–38. http://dx.doi.org/10.1039/d1ce01482j.

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The formation of three types of supramolecular coordination cages is described. Tetrasulfonylcalixarene, combined with metallic salts (Ni, Co and Zn) and the flexible succinate ligand, led to cages. H bonded induced chirality was observed for both isomorphous cages.
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Yadav, Sarita, Palanisamy Kannan i Guanyinsheng Qiu. "Cavity-based applications of metallo-supramolecular coordination cages (MSCCs)". Organic Chemistry Frontiers 7, nr 18 (2020): 2842–72. http://dx.doi.org/10.1039/d0qo00681e.

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This review describes cavity-based applications of cage-like SCCs such as molecular recognition and separation, stabilization of reactive species by encapsulation, as drug delivery systems and as molecular flasks.
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Zhang, Hai-Xia, Xiaodong Yan, Yu-Xin Chen, Shu-Heng Zhang, Tao Li, Wang-Kang Han, Ling-Yu Bao, Rui Shen i Zhi-Guo Gu. "A zeolite supramolecular framework with LTA topology based on a tetrahedral metal–organic cage". Chemical Communications 55, nr 8 (2019): 1120–23. http://dx.doi.org/10.1039/c8cc08965e.

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Decker, Gerald E., Gregory R. Lorzing, Meaghan M. Deegan i Eric D. Bloch. "MOF-mimetic molecules: carboxylate-based supramolecular complexes as molecular metal–organic framework analogues". Journal of Materials Chemistry A 8, nr 8 (2020): 4217–29. http://dx.doi.org/10.1039/c9ta12497g.

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Taylor, Christopher G. P., Jerico R. Piper i Michael D. Ward. "Binding of chemical warfare agent simulants as guests in a coordination cage: contributions to binding and a fluorescence-based response". Chemical Communications 52, nr 37 (2016): 6225–28. http://dx.doi.org/10.1039/c6cc02021f.

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Lu, Hui-Shu, Wang-Kang Han, Xiaodong Yan, Ya-Xin Xu, Hai-Xia Zhang, Tao Li, Yu Gong, Qing-Tao Hu i Zhi-Guo Gu. "Supramolecular assemblies based on Fe8L12 cubic metal–organic cages: synergistic adsorption and spin-crossover properties". Dalton Transactions 49, nr 14 (2020): 4220–24. http://dx.doi.org/10.1039/d0dt00353k.

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Liu, Wen-Fang, Qi-Ming Qiu, Mo Zhang, Zhao-Min Su, Qingqing An, Hongjin Lv, Zhiyu Jia i Guo-Yu Yang. "Two new Cu-based borate catalysts with cubic supramolecular cages for efficient catalytic hydrogen evolution". Dalton Transactions 49, nr 29 (2020): 10156–61. http://dx.doi.org/10.1039/d0dt01994a.

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Two new copper-based borates with supramolecular cages were synthesized under hydrothermal condition. As new copper complexes, they exhibit photocatalytic activity. The experimental results show borates have potential applications as water reduction catalysts (WRCs).

Rozprawy doktorskie na temat "Truxene based supramolecular cages":

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Allain, Magali. "Études structurales par diffraction des rayons X appliquées à des cages supramoléculaires et à des conducteurs moléculaires". Electronic Thesis or Diss., Rennes 1, 2022. http://www.theses.fr/2022REN1S081.

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Les structures discrètes auto-assemblées dirigées par les métaux sont des édifices de grande taille qui cristallisent difficilement et se décomposent rapidement. De plus, la résolution de ces structures est compliquée par des données de diffraction de moyenne qualité. Différentes techniques de sélection de cristaux et une méthode d’affinement de structure, appliquée aux cages, sont discutées avec notamment l’utilisation détaillée du programme Squeeze qui permet de supprimer la contribution des atomes et molécules désordonnés ou non visibles dans ces grandes structures. Deux types de cages isolées et entrelacées sont décrites structuralement. Dans la deuxième partie, une série de nouveaux matériaux conducteurs organiques à base de TMTSF et de dérivés du TTF, et incorporant un nouvel anion fluorotantalate, est décrite et les relations structure-propriétés de conduction sont discutées. La première phase de Bechgaard avec l’anion magnétique hexafluoro-rhénate a été caractérisée et différentes études de stabilité en température et de conduction sont présentées. Le TMTSF et le BEDT-TTF ont été associés à plusieurs anions mixtes hexafluorés de tantale, de rhénium et de phosphore pour former de nouveaux alliages conducteurs. Ces synthèses ont également générées des matériaux avec des anions originaux. Deux méthodes de détermination de la charge sur les TMTSF ont été comparées sur plusieurs conducteurs organiques, issus de ce travail ou d’une base de données cristallographiques
The discrete self-assembled metal assisted structures are big size edifices which do not crystallize easily and decompose rapidly. Moreover, the resolution of these structures is difficult because of the medium quality of the diffraction data sets. Different crystals selection techniques and a refinement method, applied to the supramolecular cages, are discussed, with a particular focus on the use of the Squeeze program which allows the suppression of the disordered atoms and molecules contributions. Two types of isolated and interlocked cages are structurally described. In the second part, a series of new organic conducting materials based on TMTSF and on TTF derivatives, incorporating a novel fluoro-tantalate anion, is described. The structure-conducting properties relationship is discussed. The first Bechgaard phase with a magnetic anion, namely hexafluororhenate, is described, together with its temperature dependent stability and conducting properties. TMTSF and BEDT-TTF have been associated to several mixed tantalum, rhenium or phosphorous hexafluoro anions to provide new conducting alloys. These syntheses also afforded crystalline materials with original anions. Two methods to estimate the oxydation state of the TMTSF donors are compared for several radical cation salts, either prepared during this PhD work or selected from a crystallographic data base
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Versäumer, Marina. "Supramolecular coordination cages based on bispyridyl-ligands with redox properties". Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2016. http://hdl.handle.net/11858/00-1735-0000-002B-7C2F-E.

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Zhu, Rongmei. "Control over assembly and interpenetration of Pd-based coordination cages". Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2017. http://hdl.handle.net/11858/00-1735-0000-0023-3DF1-8.

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Löffler, Susanne. "Host-Guest Chemistry of Acridone-based Coordiantion Cages". Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2018. http://hdl.handle.net/11858/00-1735-0000-002E-E415-6.

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Versäumer, Marina [Verfasser], Guido [Akademischer Betreuer] [Gutachter] Clever i Franc [Gutachter] Meyer. "Supramolecular coordination cages based on bispyridyl-ligands with redox properties / Marina Versäumer ; Gutachter: Guido Clever, Franc Meyer ; Betreuer: Guido Clever". Göttingen : Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2016. http://d-nb.info/1116709775/34.

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Hsu, Chia-Hui, i 徐佳慧. "Synthesis and Properites of C3-symmetric Truxene-Based Derivates and Their Application in Supramolecular Chemistry". Thesis, 2012. http://ndltd.ncl.edu.tw/handle/40910775741093405794.

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碩士
國立臺灣大學
化學研究所
100
In our previous studies, we developed an unique 3D skeleton based on truxene moiety. With incorporating various functional structures onto C5, C10, and C15 position of the truxene core, the successful synthetical strategy giving intriguing molecules through orthogonally and distinguishably modify active sites provides us an efficient way to further inspect on the diversity of its 3D derivatives. As a result, via involving the 3D truxene core, the thesis extend the applications of these various derivatives in supramolecular chemistry. Herein, we synthesized newly 3D organic gelator TDMDA which constructed by amide groups with long hydrocarbon chains. The morphology of TDMDA was found in fibrillar and globular morphology when dissolved in cyclohexane and methanol respectively and are characterized by SEM and TEM for close view. Moreover, gelator TDMDA incorporating amphipathic groups whose self-assembly display in-situ reversible transformation of aggregate morphology between fibrillar and globular upon exposure to different solvent. On the other hand, we also develope halide anion receptors TPTB and TDMTB from click chemistry. Accroding to NMR titration experiment, we found both of them have the best affinity to chloride due to the proper size of inner cavity. At last, we functionalized pyrene moiety onto the 3D architecture to achieve TPTHP and TDMTHP as C60 receptors, expecting it has good affinity with C60 via donor-acceptor and π-π interaction.
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Hsu, Ting-Wei, i 許庭瑋. "Self-Assembly of Functional Metallo-Supramolecular Cages Using Tritopic Terpyridine-Based Ligands". Thesis, 2015. http://ndltd.ncl.edu.tw/handle/56541699435939278943.

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碩士
國立臺灣大學
化學研究所
104
In supramolecular chemistry, constructing a well-defined three-dimensional cage has attracted more and more attention. Herein, we explore the possibility of exterior functionalization for the self-assembled cages. A series of tritopic terpyridine-based ligands with various exterior functionalities was used to construct metallo-supramolecular cages. To investigate the self-assembly behavior of the predesigned tritopic ligand system, ligands with simple hydroxyl and alkyl substituents were synthesized and complexed with Cd(II) and Zn(II) ions to give supramolecular cubic cages that were well characterized by 1H-NMR, ESI-MS, and electron microscopes. Besides, changing connected positions between the terpyridine moieties and the central core to generate a bent version of the tritopic ligand was successfully used for constructing a smaller supramolecular structure, demonstrating a simple method to build variant metallo-supramolecular structures. To date, the polymer solar cells (PSCs) with P3HT and PCBM as an active layer suffer from a severe lifetime problem, which is partly caused by the macrophase separation from the aggregation of PCBM with time. Based on our new findings, the tritopic terpyridine-based ligand decorated with pendant fullerene groups was successfully synthesized and self-assembled into a functional metallocage via coordination. In addition, the fullerene-functionalized cage was used as a supramolecular crosslinker to alleviate the macrophase aggregation caused by the migration of the C60 acceptor, which significantly improved the stability of organic photovoltaics.
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Wang, Yun-Chi, i 王允齊. "Self-Assembly of 3D Metallo-Supramolecular Cages from Terpyridine-Based Ligands with Crown Ethers as Central Units". Thesis, 2015. http://ndltd.ncl.edu.tw/handle/49257698248297914021.

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Streszczenie:
碩士
國立臺灣大學
化學研究所
104
Molecular self-assembly using metal-ligand coordinative interaction has drawn much attention in recent years. Utilizing non-covalent interactions provides a facile way to construct large and complicated 2D/3D structures in contrast with the conventional organic chemistry. Moreover, incorporation of orthogonal host-guest and metal-coordination interactions into supramolecular structures will enhance their structural complexity and impart additional functions. In this research, we designed and synthesized a series of metallo-supramolecular cages possessing multiple (tpy = terpyridine) connections and ion–dipole interaction sites (i.e., crown ethers), which functioned orthogonally to each other. It was found that a decrease in the size of crown ethers leaded to a decrease in the flexibility, and thus various thermodynamic products were formed. To further study these metallo-supramolecular cages, we investigated the interactions between the crown ethers and the predesigned secondary ammonium ions. The 1:1 inclusion complex formed by the cage assembly and the multivalent ammonium salt was successfully achieved in MeCN and further characterized by NMR spectroscopy and ESI mass spectrometry. The formation of a metallo-supramolecular rotaxane based on the inclusion compound was explored as well.

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