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1

Velázquez, Josian Luciano, and Sonia J. Bailón-Ruiz. "Generation of ZnS Nanostructures with Modified Chemical Surface." MRS Advances 4, no. 38-39 (2019): 2095–102. http://dx.doi.org/10.1557/adv.2019.226.

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ABSTRACTSemiconductor nanomaterials like zinc sulphide have interesting potential applications, consequent to their size-dependent optical properties. These nanostructures can be used on optoelectronic, photocatalysis, solar cells, and fluorescence microscopy, among others. Due to the great use of these nanoparticles in society, there is great concern in the scientific community about the potential negative interaction of these nanomaterials in aquatic environments. The present research was conducted on generation of nanostructures of ZnS with modified surface. This work had three goals: 1) mo
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Chatterjee, Nilanjana, and Baibaswata Bhattacharjee. "An Analytic Contemplation of the Conspicuous Vicissitudes in the Histomorphology of Corpuscles of Stannius of a Freshwater CatfishMystus tengara(Hamilton, 1822) due to the Exposure of ZnS Nanoparticles." Scientifica 2015 (2015): 1–7. http://dx.doi.org/10.1155/2015/697053.

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Enhanced surface photooxidation property associated with the ZnS nanoparticles caused the reduction of dissolved oxygen content in water in a dose dependent manner, when ZnS nanoparticles of different sizes are exposed to the water in various concentrations. This property was more prominent for ZnS nanoparticles with smaller sizes.Mystus tengara, exposed to ZnS nanoparticles, responded to hypoxia with varied behavioural, physiological, and cellular responses in order to maintain homeostasis and organ function in an oxygen-depleted environment. The histomorphology of corpuscles of Stannius of t
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3

Huang, Hsin-Liang, H. Paul Wang, Edward M. Eyring, and Juu-En Chang. "Recovery of nanosize zinc from phosphor wastes with an ionic liquid." Environmental Chemistry 6, no. 3 (2009): 268. http://dx.doi.org/10.1071/en08098.

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Environmental context. Very fine phosphor ashes are discharged from particulate collection systems (such as bag houses) in the cathode ray tube or television disassembling processes. Effective recovery of ZnO and ZnS nanoparticles from the phosphor ash can be achieved by extraction with a room temperature ionic liquid. By synchrotron radiation X-ray absorption spectroscopy, the obtained molecular scale data turn out to be very useful in revealing speciation of zinc in the extraction process, which also facilitates the development of a simple nanoparticle recovery method. Abstract. An effective
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4

Mirnaya, Tatiana, Galina Yaremchuk, and Alexander Kosheliev. "SYNTHESIS AND OPTICAL PROPERTIES OF MESOMORPHIC GLASSY NANOCOMPOSITES BASED ON CADMIUM CAPRYLATE WITH CdSe / ZnS HETERONANOPARTICLES." Ukrainian Chemistry Journal 85, no. 1 (2019): 13–18. http://dx.doi.org/10.33609/0041-6045.85.1.2019.13-18.

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The paper presents on the synthesis and optical properties of mesomorphic composites, based on a glassy liquid-crystalline caprylate matrix, with CdSе/ZnS hetero-nanoparticles. The synthesis of complex core-shell semiconductor nanoparticles was carried out by fusing together a cadmium caprylate composite with CdSе nanoparticles and zinc caprylate composite with ZnS nanoparticles. The cadmium and zinc chalcogenide nanoparticles have been synthesized in molten cadmium caprylate and zinc caprylate respectively.
 It has been found by optical spectroscopy that the have hetero-nanoparticles a c
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5

Hu, Siyi, Yu Ren, Yue Wang, et al. "Surface plasmon resonance enhancement of photoluminescence intensity and bioimaging application of gold nanorod@CdSe/ZnS quantum dots." Beilstein Journal of Nanotechnology 10 (January 3, 2019): 22–31. http://dx.doi.org/10.3762/bjnano.10.3.

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Biological applications of core/shell near-infrared quantum dots (QDs) have attracted broad interest due to their unique optical and chemical properties. Additionally, the use of multifunctional nanomaterials with near-infrared QDs and plasmonic functional nanoparticles are promising for applications in electronics, bioimaging, energy, and environmental-related studies. In this work, we experimentally demonstrate how to construct a multifunctional nanoparticle comprised of CdSe/ZnS QDs and gold nanorods (GNRs) where the GNRs were applied to enhance the photoluminescence (PL) of the CdSe/ZnS QD
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6

Bhattacharjee, Baibaswata, Nilanjana Chatterjee, and Chung-Hsin Lu. "Harmful Impact of ZnS Nanoparticles on Daphnia sp. in the Western Part (Districts of Bankura and Purulia) of West Bengal, India." ISRN Nanomaterials 2013 (September 16, 2013): 1–7. http://dx.doi.org/10.1155/2013/207239.

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ZnS nanoparticles of different sizes are synthesized employing a simple wet chemical method. These nanoparticles are used to study their impact on the Daphnia sp. through traditional toxicity tests. The percentage of mortality is found to increase initially with increasing nanoparticle concentration or exposure time and is finally found to saturate for higher concentrations or exposure times. Mortality is found to be higher for smaller particles. Hopping frequency and heart rate are also found to increase with increasing nanoparticle exposure time for a fixed nanoparticle concentration. These
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7

Vasan, R., F. Gao, M. O. Manasreh, and C. D. Heyes. "Investigation of charge transport between nickel oxide nanoparticles and CdSe/ZnS alloyed nanocrystals." MRS Advances 2, no. 51 (2017): 2935–41. http://dx.doi.org/10.1557/adv.2017.488.

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ABSTRACTCharge transport between nickel oxide nanoparticles and CdSe/ZnS alloyed core/shell nanocrystals is investigated. The crystal structure and composition of the nickel oxide nanoparticles are evaluated using X-ray diffraction, Raman and X-ray photoelectron spectroscopies. The nanoparticles are near-stoichiometric with very low defect densities. The optical properties of the materials are studied by measuring the absorbance and time resolved photoluminescence spectra. The band gap of the nickel oxide nanoparticles is around 4.42 eV. The CdSe/ZnS nanocrystals exhibit shorter average lifeti
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8

I. Korsunskiy, Vladimir, Reinhard B. Neder, Andreas Hofmann, Sofia Dembski, Christina Graf, and Eckart Rühl. "Aspects of the modelling of the radial distribution function for small nanoparticles." Journal of Applied Crystallography 40, no. 6 (2007): 975–85. http://dx.doi.org/10.1107/s0021889807038174.

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An approach to modelling radial distribution functions (RDFs) of nanoparticle samples over a wide range of interatomic distances is presented. Two different types of contribution to the model RDF are calculated. The first explicitly reflects the structure of the nanoparticle parts with more or less crystalline atomic structure. It can be calculated precisely and contains comparatively sharp peaks, which are produced by the set of discrete interatomic distances. The second includes RDF contributions from distances between weakly correlated atoms positioned within different nanoparticles or with
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9

Sunatkari, Swarnalata. "Study of structural and spectroscopic characterization of co-doped ZnS Nanoparticles capped with L-Arginine." Journal of Physics: Conference Series 2426, no. 1 (2023): 012036. http://dx.doi.org/10.1088/1742-6596/2426/1/012036.

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Abstract The aim of the present study was to prepare ZnS nanoparticles co-doped with Li+-Cs+, were synthesized using a chemical co-precipitation method. The ZnS-(Li+-Cs+) nanoparticle’s were capped with L- Arginine and reduced using sodium sulphide. The main advantage of this method is to synthesized semiconductor nanomaterial with wide band gap and nanoparticles are chemically stable over a long time. The as prepared nanoparticles were characterised by X-Ray Diffraction technique for phase analysis of the sample. Particle size is found in the range of 2 to 4 nm calculated by Debye Scherer met
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10

Rai, S., and R. Kothari. "Synthesis and Spectroscopic Characterization of Zinc Sulphide nanoparticles using Microwave irradiation of Zinc complex of Thiosemicarbazone ligand as a Single Molecular precursor : Pharmacological activities." Digest Journal of Nanomaterials and Biostructures 18, no. 1 (2023): 31–45. http://dx.doi.org/10.15251/djnb.2023.181.31.

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Single molecular precursors are appropriate starting materials for synthesis of semiconductor nanoparticles (NPs), which allow for the control of atomic ratio, monodispersity, composition and particle size of nanoscaled metallic sulfide nanoparticles. In the present study, we have reported the synthesis of nanostructured chalcogenides pharmacologically active active zinc sulfide nanoparticles (ZnS NPs) using Zn (II) ion inserted thiosemicarbazone ligand as a single molecular precursor .The precursors were thermally pyrolysized using high energy microwave radiations to obtain very fine ZnS nano
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11

Maswanganye, Mpho W., Guy L. Kabongo, and Mokhotjwa S. Dhlamini. "Modulating Charge Mobility in Microwave Synthesized Ti-doped ZnS Nanoparticles for Potential Photoanode Applications." Nanomaterials 13, no. 1 (2022): 77. http://dx.doi.org/10.3390/nano13010077.

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Doping ZnS nanoparticles with different metal and/or non-metal ions is one of the ways to improve their properties. That is because dopants introduce strain into the lattice of the ZnS nanoparticles. The influence of Ti on the ZnS nanoparticles was investigated on the structural properties, optical properties, and also electrical impedance spectroscopy (EIS). The presence of Ti in the crystal lattice of the ZnS introduced strain into the crystal structure, hence causing a lattice expansion and reducing the crystallite sizes of the ZnS nanoparticles. Ti doping was observed to increase the energ
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12

Roberts, Charlotte. "Thermoplastic Polymer Compounding with ZnS Nanostructures: Innovations and Applications." Asia Pacific Journal of Energy and Environment 7, no. 2 (2020): 121–28. http://dx.doi.org/10.18034/apjee.v7i2.756.

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This study investigates the compounding of thermoplastic polymers with ZnS nanostructures, focusing on innovative synthesis methods and applications. The principal objective was to enhance the mechanical, thermal, and electrical properties of thermoplastic polymers by incorporating well-characterized ZnS nanoparticles. Utilizing a chemical precipitation method, ZnS nanoparticles with controlled size and high purity were synthesized. Characterization techniques, including XRD, SEM, TEM, EDS, and FTIR, confirmed the crystalline structure and elemental composition of the nanoparticles. Three comp
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13

KAREEM, T. ABDUL, and A. ANU KALIANI. "I-V characteristics and the synthesis of ZnS nanoparticles by glow discharge at the metal–ionic liquid interface." Journal of Plasma Physics 78, no. 2 (2011): 189–97. http://dx.doi.org/10.1017/s0022377811000560.

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AbstractA plasma chamber was constructed for the synthesis of ZnS nanoparticles in ionic liquid by glow discharge electrolysis method. Current and voltage (I-V) characteristics of the discharge at the metal–ionic liquid interface showed that the curve follows Ohm's law up to a particular voltage only so that the ZnS nanoparticle preparation was performed after the critical voltage. X-ray diffraction and energy dispersive spectral analysis showed that the samples contain ZnS nanoparticles and also found that tungsten from the metal electrode dissolved in the BMIM[BF4] ionic liquid under plasma
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14

Manjulavalli, T. E., and A. G. Kannan. "Structural and Optical Characterization of Pure and Mn2+ -Doped ZnS Nanoparticles Prepared by Solvothermal Method." Advanced Materials Research 678 (March 2013): 61–66. http://dx.doi.org/10.4028/www.scientific.net/amr.678.61.

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ZnS and Mn2+doped ZnS nanoparticles are synthesized through a simple solvothermal method. The structural and optical properties of pure and doped ZnS nanoparticles were studied using X-ray powder diffraction (XRD), scanning electron microscopy (SEM), UV-vis absorption and photoluminescence spectroscopy (PL). X-ray diffraction analysis reveals that undoped and Mn2+doped ZnS crystallizes in cubic structures. The average grain size of the nanoparticles lies in the range of 2.2 to 4.8 nm. The SEM image shows that pure and doped nanoparticles are in spherical shape. The optical absorption spectrum
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15

Muhammad Iqbal, Zeeshan Mahmood, Waseem Sajjad Tahir, et al. "CHEMICAL COPRECIPITATION SYNTHESIS AND ENHANCED PHOTOCATALYTIC CHARACTERISTICS OF NICKEL-DOPED ZINC SULFIDE NANOPARTICLES." Kashf Journal of Multidisciplinary Research 2, no. 02 (2025): 18–29. https://doi.org/10.71146/kjmr263.

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Metal sulfide semiconductors having wide bandgap like ZnS experience a significant decrease in band gap when transition metal ions like Ni2⁺ are doped. This alteration creates new composite materials with various uses in photonics, solar cells, optoelectronic devices, and spintronic devices. These modifications have led to improvements in ZnS nanoparticle production techniques. Nickel-doped zinc sulfide nanoparticles are synthesized by using a simple chemical coprecipitation method. Ni-doped ZnS nanoparticles have been characterized using UV-visible spectra and Fourier-transform infrared spect
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16

Расмагин, С. И., та И. К. Новиков. "Оптические свойства наночастиц CdSe/ZnS в пленках термообработанного поливинилхлорида". Журнал технической физики 53, № 4 (2019): 508. http://dx.doi.org/10.21883/ftp.2019.04.47450.9016.

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AbstractComposites based on polyvinylchloride with incorporated CdSe/ZnS nanoparticles are produced. The optical and electrical properties of the polymer composites containing CdSe/ZnS nanoparticles are studied. The absorption and photoluminescence spectra of the composites are recorded, and their bulk resistivities are measured. The CdSe nanoparticle dimensions are determined. It is established that, upon short-term heat treatment, the photoluminescence intensity increases, whereas upon heating for a long time, the photoluminescence intensity substantially decreases.
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17

ANAND, K. VIJAI, R. MOHAN, R. MOHAN KUMAR, M. KARL CHINNU, and R. JAYAVEL. "CONTROLLED SYNTHESIS AND CHARACTERIZATION OF CERIUM-DOPED ZnS NANOPARTICLES IN HMTA MATRIX." International Journal of Nanoscience 10, no. 03 (2011): 487–93. http://dx.doi.org/10.1142/s0219581x11008253.

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Cerium-doped ZnS nanoparticles have been synthesized through hydrothermal method. The nanoparticles were stabilized using hexamethylenetetramine (HMTA) as surfactant in aqueous solution. The average particle size of the prepared samples is about 2 nm. The structure of the as-prepared ZnS nanoparticles is cubic (zinc blende) as demonstrated by X-ray powder diffraction (XRD) and selected area electron diffraction (SAED) analysis. TEM results showed that the synthesized nanoparticles were uniformly dispersed in the HMTA matrix without aggregation. The UV–Vis absorption spectra of the prepared ZnS
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18

Fan, Xiao Hui, Hong Juan Liu, Yan Ming Chen, and Ting Sun. "Synthesis and Characterization of ZnS Nanoparticles by Using Polyvinylpyrrolidone as Stabilizer." Advanced Materials Research 625 (December 2012): 269–72. http://dx.doi.org/10.4028/www.scientific.net/amr.625.269.

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A simple synthesis method of PVP (polyvinylpyrrolidone) coated ZnS QDS has been developed. The optical properties and morphology for the as-synthesized ZnS nanoparticles were characterized by UV-Vis absorption spectroscopies and transmission electron microscopy (TEM). The results show that PVP could act as a better stabilizer for the formation of ZnS nanoparticles in N, N-dimethylformamide. The obtained ZnS nanoparticles have spherical morphology and a narrow size distribution. ZnS nanoparticles could give an apparent extionic absorption peaks and quantum confinement effects.
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19

Wang, H. Y., Yi Yang Zhao, Z. Y. Li, Xiao Feng Lu, C. Wang, and Yen Wei. "Preparation and Characterization of Poly(Vinyl Alcohol) Nanofibers Containing ZnS Nanopaticles via Electrospinning." Solid State Phenomena 121-123 (March 2007): 641–44. http://dx.doi.org/10.4028/www.scientific.net/ssp.121-123.641.

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Poly(vinyl alcohol) (PVA) nanofibers containing functional ZnS nanoparticles have been successfully prepared by electrospinning technique. The ZnS/PVA mixture solution for electrospinning was obtained by reacting Zn(Ac)2 with Na2S in the PVA aqueous solution. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD) analyses revealed that the morphology of the ZnS/PVA nanofibers consists of the dispersion of ZnS nanopaticles with cubic structure in PVA nanofibers. The coordinations between –OH and Zn2+ were characterized by infrared spectroscopy. T
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20

Gopalakrishnan, M., Issac P. Nelson, and Solomon Jeevaraj A. Kingson. "Synthesis and Characterization of Pure and Mn Doped Zinc Sulphide Nanoparticles and Nanofluids." Advanced Materials Research 1086 (February 2015): 101–6. http://dx.doi.org/10.4028/www.scientific.net/amr.1086.101.

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In this work, pure ZnS and Mn doped ZnS nanoparticles are synthesized by simple chemical precipitation method. The structure of pure zinc sulphide and Mn doped zinc sulphide sample are analyzed by X-ray diffraction technique. The morphological structure of zinc sulphide and Mn2+doped zinc sulphide nanoparticles are studied using scanning electron microscope (SEM). The average particle sizes of pure ZnS nanoparticles are determined to be from 29 nm to 44 nm and Mn doped ZnS nanoparticles are determined to be from 99 nm to 135 nm. The optical properties of pure and Mn doped ZnS nanoparticles hav
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21

Murali, G., D. Amaranatha Reddy, R. P. Vijayalakshmi, and R. Venugopal. "Structural and Optical Characteristics of Ni Doped ZnS Nanoparticles." Advanced Materials Research 678 (March 2013): 159–62. http://dx.doi.org/10.4028/www.scientific.net/amr.678.159.

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Nanocrystalline ZnS and Ni doped ZnS powders were synthesized by a simple chemical co-precipitation method at room temperature using sodium sulfide and acetates of Zinc and Nickel. 2-Mercapto ethanol is used as a capping agent. Structural and optical properties of as prepared samples were characterized using X-Ray diffraction (XRD), Scanning electron microscopy (SEM), Energy Dispersive Analysis using X-rays (EDAX) and Photoluminescence studies (PL). EDAX measurements confirmed the presence of Zn, Ni and S in the prepared samples. XRD analysis reveals that the Zn1-xNixS (x= 0.00 and 0.01) nanop
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22

L, Priya. "Synthesis and Characterization of Photoluminescent PVA/ZnS: Mn2+ Nanocomposites." Mapana - Journal of Sciences 12, no. 1 (2013): 31–37. http://dx.doi.org/10.12723/mjs.24.4.

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A ZnS nanoparticle doped with Mn2+ is synthesized in aqueous media and PVA using chemical co-precipitation method. This colloid was analyzed using uv-vis spectrophotometry. It is observed that the absorption peak blue shifts as compared to the bulk absorption of ZnS suggesting the nanoparticle formation. The energy gaps of these nanoparticles were calculated from the uv-vis spectra. The average particle size analysis is carried out using XRD. Photoluminescence of PVA/ ZnS:Mn2+ is studied. It is observed that the composite sample exhibits an orange emission peak as is reported for pure ZnS: Mn2
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23

Salman, Elaf Kareem, and Ghaida Salman Muhammed. "Study of Some Structural and Optical Properties for Synthesized Graphene/Polyaniline/Zns Nanocomposite." Iraqi Journal of Physics 22, no. 4 (2024): 53–66. https://doi.org/10.30723/ijp.v22i4.1244.

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Hybrid graphene (GR)/ polyaniline (PANI) based composites incorporating zinc sulfide (ZnS) nanoparticles were synthesized using the drop-casting method. The weight percentage of ZnS was varied from 0.01 to 0.05%. The optical, structural, and morphological characteristics of the nanocomposite were examined utilizing X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), Atomic Force Microscopic (AFM), and UV-Vis spectroscopy. The qualities and dimensions of the GR, PANI, and ZnS NPs and nanoparticle morphology resulting from the nanocomposite process were examined. Utilizing energy disper
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Panthi, Gopal, and Arun Gyawali. "PdS-ZnS-Doped Electrospun Polymer Nanofibers as Effective Photocatalyst for Hydrogen Evolution." Hydrogen 5, no. 3 (2024): 403–13. http://dx.doi.org/10.3390/hydrogen5030023.

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Poly(vinyl acetate) nanofibers doped with PdS-ZnS nanoparticles (PdS-ZnS/PVAc nanofibers) were fabricated via an electrospinning technique. PdS-ZnS nanoparticles were in situ synthesized by adding (NH4)2S solution to poly(vinyl acetate)/zinc acetate/palladium acetate solution. Electrospinning of the formed colloidal solution led to the formation of poly(vinyl acetate) nanofibers containing uniformly distributed PdS-ZnS nanoparticles. The prepared samples were characterized by field emission scanning electron microscopy, X-ray diffraction, transmission electron microscopy and Fourier transform
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K. Valliyammal and R. Sakthi Sudar Saravanan. "Photocatalytic Degradation of Transition Metal (Ni) Doped ZnS Nanoparticles Synthesized via Simple Solvothermal Route." Journal of Environmental Nanotechnology 13, no. 3 (2024): 115–22. http://dx.doi.org/10.13074/jent.2024.09.242772.

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Ni doped ZnS nanoparticles were obtained using the simple Solvothermal Microwave Irradiation (SMI) method in this research. This technique is cost-effective and results in a high level of uniformity in particle size. The sample's structural characteristics were examined utilizing XRD Technique, FESEM image, Elemental analysis of the as prepared sample obtained from EDX spectrum and their optical characteristics analysed by using UV-Visible absorption study. The XRD pattern of Ni doped ZnS nanoparticles were to obtain their crystallite size (D), lattice constant (a), and volume of the unit cell
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Kovář, Petr, Petr Praus, Miroslav Pospísil, and Richard Dvorský. "Molecular modelling of zinc sulphide nanoparticles stabilized by cetyltrimethylammonium bromide." Journal of the Serbian Chemical Society 79, no. 12 (2014): 1545–59. http://dx.doi.org/10.2298/jsc131115050k.

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ZnS nanoparticles stabilized by cetyltrimethylammonium bromide (CTAB) were modelled in the Materials Studio environment. Four types of models with different distances between ZnS nanoparticles and different amounts of CTA cations without water and in water environment were built and characterized by calculated sublimation energies. The results of molecular modelling without water showed that the most favourable model consisted of two ZnS nanoparticles with a distance of 8-9 nm separated without immersing of CTAs. On the contrary, the most favourable model in water environment was composed of Z
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Wang, Zhen-Hua, Dian-Yu Geng, Da Li, and Zhi-Dong Zhang. "Cluster spin-glasslike behavior in nanoparticles of diluted magnetic semiconductors ZnS:Mn." Journal of Materials Research 22, no. 9 (2007): 2376–83. http://dx.doi.org/10.1557/jmr.2007.0317.

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Zn1−xMnxS nanoparticles with x = 0.08, 0.16, and 0.32 were synthesized by a coprecipitation reaction between nitrate and sodium sulfide at room temperature in air. The magnetic properties of the Zn1−xMnxS nanoparticles were investigated by alternating-current (ac) susceptibility and direct-current (dc) magnetization measurements. The Mn3O4 phase was observed to exist in the Zn1−xMnxS nanoparticles as x ⩾ 0.16. The actual concentrations (x) of Mn-doped ZnS nanoparticles were determined by energy-dispersive x-ray analysis (EDAX) to be 0.06, 0.11, and 0.20, respectively, corresponding to the init
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Ali I . Khaleel, Khalaf F. Al-Samarrai, and Marwan A. mahmood. "Analytical Study of Zinc Sulphide Electrode Prepared from Nano material." Tikrit Journal of Pure Science 21, no. 6 (2023): 61–66. http://dx.doi.org/10.25130/tjps.v21i6.1080.

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Zinc Sulphide nanoparticles (NPs) has been prepared from raw material by microwave method. ZnS NPs were characterized by X-ray Diffraction (XRD) and Scanning Electron Microscopy (SEM), The size of ZnS NPs were about (3.15nm) calculated from the Scherer formula from the most intense XRD peak, The calculated product for ZnS was about 94.4%.Zn2+-selective electrode based on poly vinyl chloride (PVC) was prepared by using ZnS Nanoparticles (NPs) powders and di-butyl phthalate, and were compared The analytical specifications of ZnS NPs and ZnS Microparticles (Non- NPs ) electrode. ZnS NPs electrode
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Sabah, A., S. Javed, and M. Nazir. "Green One Step Microwave Assisted Synthesis of ZnS Nanoparticles." Nucleus 52, no. 4 (2015): 165–68. https://doi.org/10.71330/thenucleus.2015.634.

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Microwave radiations are used to synthesize zinc sulphide (ZnS, cubic phase) nanoparticles by using single precursor at different synthesis temperature and irradiation time. Absorption peaks of ZnS nanoparticles of size ~15 nm are found within the range of 250-320 nm by UV-Visible spectroscopy. The band gap energies of prepared ZnS nanoparticles are higher than the bulk value of ZnS. The blue shift of UV absorption peak gives evidence of decrease in particle size. Aggregates of large number of small sized spherical nanoparticles are observed by scanning electron microscope (SEM).
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Othman, Razhan S., Rebaz A. Omar, Karzan A. Omar, et al. "Synthesis of Zinc Sulfide Nanoparticles by Chemical Coprecipitation Method and its Bactericidal Activity Application." Polytechnic Journal 9, no. 2 (2019): 156–60. http://dx.doi.org/10.25156/ptj.v9n2y2019.pp156-160.

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A particle of zinc sulfide (ZnS) was synthesized by the chemical coprecipitation method using zinc sulfate heptahydrate (ZnSO4), ammonium sulfate (NH4)2SO4 as a reactant, and thiourea as a stabilizer and capping agent. The optioned product characterized by electron dispersive X-ray spectroscopy that exhibits the presence of Zn and S elements. The average particle size of the ZnS nanoparticles determined using X-ray diffraction is about 4.9 nm. The ultraviolet–visible spectroscopy showed the blue shift in wavelength and the band gap was 4.33 eV, the surface morphology of the synthesized ZnS nan
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T. Shobana, T. Venkatesan, R. Sakthi Sudar Saravanan, D. Kathirvel, and K. Valliyammal. "Facile Synthesis and Characterization of Pure and Bi-doped ZnS Nanoparticles for Photocatalytic Application." Journal of Environmental Nanotechnology 13, no. 3 (2024): 108–14. http://dx.doi.org/10.13074/jent.2024.09.243870.

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In the present research, a simple solvothermal microwave irradiation (SMI) method has been adopted for the preparation and synthesis of pure and Bi doped ZnS nanoparticles using zinc acetate, bismuth acetate, thiourea and ethylene glycol were utilized as precursors. As-synthesized pure and Bi doped ZnS nanoparticles were characterized by X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDAX), ultraviolet-visible (UV-vis) spectroscopy and Field emission scanning electron microscopy (FESEM). From the XRD and EDAX studies, crystallite size, lattice parameter and analysis of the elem
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Tang, Luping, Chen Liao, Yingqing Guo, and Yangyang Zhang. "Controllable Preparation of Ag-SiO2 Composite Nanoparticles and Their Applications in Fluorescence Enhancement." Materials 16, no. 1 (2022): 201. http://dx.doi.org/10.3390/ma16010201.

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Metal nanoparticles have attracted a great deal of interest due to their unique properties of surface plasmon resonance. Metal nanoparticles can enhance the fluorescence emission intensity of quantum dots (QDs) through the local surface plasmon resonance effect, which is mainly determined by the distance between them. Therefore, it is very important to achieve controllable distance between metal and QDs, and study fluorescence enhancement. In this work, the controllable adjustment of the distance between metal nanoparticles and QDs was successfully realized by controlling the thickness of the
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Chatterjee, Nilanjana, and Baibaswata Bhattacharjee. "Revelation of ZnS Nanoparticles Induces Follicular Atresia and Apoptosis in the Ovarian Preovulatory Follicles in the CatfishMystus tengara(Hamilton, 1822)." Scientifica 2016 (2016): 1–7. http://dx.doi.org/10.1155/2016/3927340.

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Important physicochemical characteristics of water like dissolved oxygen content, pH, and so forth were found to change in a dose dependent manner, showing a negative correlation with the nanoparticle concentration, when ZnS nanoparticle (NP) was exposed to water. This observation could be attributed to the enhanced photooxidation property associated with ZnS in its NP form. Under this situation, the catfishMystus tengarawas forced to live in hypoxia in its habitat. This condition was found to hamper the natural oogenesis process of the fish. Due to exposure at relatively lower concentration o
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34

Vijai Anand, K., G. Vinitha, M. Karl Chinnu, R. Mohan, and R. Jayavel. "Enhanced third-order nonlinear optical properties of high purity ZnS nanoparticles." Journal of Nonlinear Optical Physics & Materials 24, no. 02 (2015): 1550016. http://dx.doi.org/10.1142/s0218863515500162.

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This paper reports on the preparation of high purity ZnS nanoparticles by a facile single step solvent-free route via thermal decomposition of zinc acetate dihydrate and thiourea in air atmosphere. The third-order optical nonlinearity of the prepared ZnS nanoparticles were measured by Z-scan technique using continuous wave 532-nm diode pumped Nd:YAG laser. From nonlinear optical (NLO) measurements, the prepared ZnS nanoparticles possess negative nonlinearity i.e., self-defocusing. Open aperture Z-scan measurement shows saturable absorption within the medium. These results show that the prepare
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35

Xaba, Thokozani. "Green synthesis of ZnS nanoparticles and fabrication of ZnS–chitosan nanocomposites for the removal of Cr(vi) ion from wastewater." Green Processing and Synthesis 10, no. 1 (2021): 374–83. http://dx.doi.org/10.1515/gps-2021-0026.

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Abstract A modified homogeneous precipitation method has been used to synthesize ZnS nanoparticles. Starch and polyvinyl alcohol (PVA) were utilized as capping molecules, and later, the ZnS–PVA-capped nanoparticles were then incorporated with chitosan to form ZnS–chitosan nanocomposites for the removal of Cr(vi) ion from wastewater. The optical measurements of the synthesized ZnS nanoparticles showed the band gap which was blue-shifted when compared with the bulk ZnS material. The crystalline structures were determined by X-ray diffraction, and the crystalline sizes were estimated from the Sch
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Nair, Reeja Gopalakrishnan. "Synthesis and Characterization of LaFeO3@ZnS Core-Shell Nanocomposites as Photocatalyst for the Degradation of Methylene Blue Dye." Asian Journal of Chemistry 37, no. 1 (2024): 61–68. https://doi.org/10.14233/ajchem.2025.32829.

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A two-step process involving hydrothermal and co-precipitation methods was used to synthesize core-shell nanoparticles of lanthanum ferrite @zinc sulphide (LaFeO3@ZnS), which were then characterized. The X-ray diffraction (XRD) patterns exhibiting distinct diffraction peaks corresponding to both LaFeO3 and ZnS components confirmed the synthesis of the nanocomposite. Transmission electron microscopy (TEM) images confirmed that the nanocomposite exhibited a core-shell structure. The photoluminescence quenching in LaFeO3@ZnS nanoparticles indicates a decrease in the recombination of photogenerate
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Gayou, V. L., B. Salazar-Hernández, M. Rojas-López, C. Zúñiga Islas, and Jorge Antonio Ascencio. "Study of Fluorescence of Yttrium Doped Zinc Sulfide Nanoparticles." Journal of Nano Research 9 (February 2010): 139–43. http://dx.doi.org/10.4028/www.scientific.net/jnanor.9.139.

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Doped ZnS nanocrystals have attracted attention since 1994. Previous results suggest that doped semiconductor nanocrystals form a new class of luminescent materials, which have a wide range of applications in displays, lighting, sensors and lasers. In this work we synthesized Y3+ doped ZnS nanoparticles by a chemical precipitation method. The reaction was performed with ZnSO4, Na2S, phosphates and Yttrium acetate in aqueous solution. Fluorescence (FL) studies of these nanoparticles have been carried out. FL analysis reveals that the incorporation of Yttrium and phosphates to colloidal solution
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Poornaprakash, B., P. T. Puneetha, M. S. P. Reddy, and Y. L. Kim. "Structural, optical, and photocatalytic activity of ZnS:Er nanoparticles." Chalcogenide Letters 20, no. 2 (2023): 85–90. http://dx.doi.org/10.15251/cl.2023.202.85.

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ZnS and Er (2 at%) doped ZnS nanoparticles (NPs) were synthesized through coprecipitation process. EDAX analysis confirmed that the presence of Er (III) ions in the prepared sample with an anticipated stoichiometry. TEM analyses displayed that the prepared NPs showed near spheroid shapes with an average size ranging from 4.8 to 5.2 nm. XRD measurements confirmed the authentic incorporation of Er (III) ions in the ZnS lattice. DRS measurements certified that Er (III) doping declines the ZnS bandgap from 3.72 to 3.56 eV. Magnetic measurements revealed that the Er-doped ZnS NPs displayed soft fer
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Mane, Sagar M., Komal S. Wagh, Aviraj M. Teli, Sonali A. Beknalkar, Jae Cheol Shin, and Jaewoong Lee. "One-Pot Facile Synthesis of a Cluster of ZnS Low-Dimensional Nanoparticles for High-Performance Supercapacitor Electrodes." Micromachines 15, no. 2 (2024): 251. http://dx.doi.org/10.3390/mi15020251.

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To maximize the use of ZnS low-dimensional nanoparticles as high-performance supercapacitor electrodes, this work describes a simple one-pot synthesis method for producing a cluster of these particles. The ZnS nanoparticles fabricated in this work exhibit a cluster with unique low-dimensional (0D, 1D, and 2D) characteristics. Structural, morphological, and electrochemical investigations are all part of the thorough characterization of the produced materials. An X-ray diffraction pattern of clustered ZnS nanoparticles reflects the phase formation with highly stable cubic blende sphalerite polym
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Asadi, Asadollah, and Arash Abdolmaleki. "Toxicity and Teratogenic Effects of Zinc Sulfide Nanoparticles on Chick Embryo and Chick Fibroblast Cell Culture." Quarterly of the Horizon of Medical Sciences 25, no. 4 (2019): 270–81. http://dx.doi.org/10.32598/hms.25.4.270.

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Aims Nanoparticles (particles with a diameter of 10-500 nm) are currently used in the cosmetics industry as well as for pharmaceuticals, diagnostic imaging, and tissue engineering. Since these nanoparticles are used in industry and drug delivery, they can also be used by pregnant women. Thus, the current study investigated the teratogenic and cytotoxic effects of Zinc Sulfide (ZnS) nanoparticles on the embryo and their fibroblastic cell culture. Methods & Materials Zinc sulfide (ZnS) nanoparticles were synthesized. Then, nanoparticles at the concentrations of 5, 10, 15, 30, and 40 mg/mL/eg
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Chen, Wei, Zhanguo Wang, Zhaojun Lin, and Lanying Lin. "Thermoluminescence of ZnS nanoparticles." Applied Physics Letters 70, no. 11 (1997): 1465–67. http://dx.doi.org/10.1063/1.118563.

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Giradkar, Lukesh D. "Enhanced Optical and Structural Properties of ZnS Nanoparticles via Co-Precipitation." International Journal for Research in Applied Science and Engineering Technology 12, no. 6 (2024): 1685–90. http://dx.doi.org/10.22214/ijraset.2024.63391.

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Abstract: Pure Zinc Sulphide (ZnS) Nanoparticles were prepared using the co-precipitation method with sodium sulphide and zinc acetate dihydrate at a temperature of 100°C. The structural, electrical, and optical properties of the ZnS Nanoparticles were studied using various characterization techniques, including X-ray diffraction (XRD), UV-Vis spectroscopy, and Fouriertransform infrared (FTIR) spectroscopy analysis. XRD revealed that the ZnS nanoparticles have a cubic crystal structure with particle sizes ranging from 2.84 nm to 6.41 nm. UV-Vis spectroscopy determined the optical band gap to b
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Praus, Petr, Richard Dvorský, Petr Kovář, and Ladislav Svoboda. "Agglomeration of ZnS nanoparticles without capping additives at different temperatures." Open Chemistry 12, no. 3 (2014): 312–17. http://dx.doi.org/10.2478/s11532-013-0385-2.

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AbstractZnS nanoparticles were precipitated in diluted aqueous solutions of zinc and sulphide ions without capping additives at a temperature interval of 0.5–20°C. ZnS nanoparticles were arranged in large flocs that were disaggregated into smaller agglomerates with hydrodynamic sizes of 70–150 nm depending on temperature. A linear relationship between hydrodynamic radius (R a) and temperature (T) was theoretically derived as R a =652 - 2.11 T.The radii of 1.9–2.2 nm of individual ZnS nanoparticles were calculated on the basis of gap energies estimated from their UV absorption spectra. Low zeta
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Xu, Xiaojie, Linfeng Hu, Nan Gao, et al. "Controlled Growth from ZnS Nanoparticles to ZnS-CdS Nanoparticle Hybrids with Enhanced Photoactivity." Advanced Functional Materials 25, no. 3 (2014): 445–54. http://dx.doi.org/10.1002/adfm.201403065.

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S, Farhat Afsar, Chandra Prabha MN, Hari Krishna Rajan, and Bhargavi Vadappi. "Synthesis, Characterization of Nano Zinc Sulphide and Evaluation of DNA Binding Interactions." ECS Transactions 107, no. 1 (2022): 15999–6007. http://dx.doi.org/10.1149/10701.15999ecst.

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In recent years Bio-Nanotechnology is a new multidisciplinary field of research and development that has offered wide spectrum of potential applications in the medical field. Several hyperproliferative diseases such as cancer are treated by inhibiting DNA synthesis. For the innovative design and implementation of DNA applications in biological systems, it is extremely important to understand how DNA interacts with nanoparticles or small molecules. The ZnS NPs have been synthesized by solvothermal approach by refluxing an aqueous solution of zinc nitrate and Thiourea in presence of EDTA as chel
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Amaranatha Reddy, D., G. Murali, N. Madhusudhana Rao, R. P. Vijayalakshmi, and B. K. Reddy. "Synthesis and Optical Properties of Annealed Cr Doped ZnS Nanoparticles." Advanced Materials Research 678 (March 2013): 163–67. http://dx.doi.org/10.4028/www.scientific.net/amr.678.163.

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Undoped and Cr doped ZnS nanoparticles with Cr concentrations of 3.0 at.% were prepared by a chemical co-precipitation method for the fist time, using 2-Mercaptoethanol as the capping agent and annealed the synthesized particles at 600°C for 3h in air. The effect of annealing on morphological, structural and optical properties of ZnS and ZnS:Cr have been studied and compared with as prepared samples. EDAX measurements confirmed the presence of Cr in the ZnS lattice and it also confirms the conversion of ZnS into ZnO after annealed at 600 0C/3h. Surface morphologies of all samples were characte
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Huang, Hua, Hai Hu Yu, Ling De Zhou, Er Dan Gu, and De Sheng Jiang. "Preparation and Characterization of Hybrid Graphene-ZnS Nanoparticles." Materials Science Forum 663-665 (November 2010): 894–97. http://dx.doi.org/10.4028/www.scientific.net/msf.663-665.894.

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Hybrid Graphene-ZnS nanopaticles (G-ZnS NPs) were prepared by using a solvothermal method. A dispersion of graphite oxide (GO) and zinc acetate dihydrate (Zn(CH3COO)2.2H2O) in dimethl sulfoxide (DMSO) reacted at 180 °C for 12 h in a Telfon-lined stainless steel autoclave. In the reaction, DMSO serves as a sulphide source as well as a reducing agent, resulting formation of the hybrid G-ZnS NPs in one-step. Hybrid G-ZnS NPs were characterized by using a powder X-ray diffractometer, a Fourier-transform infrared spectrometer, a transmission electron microscope, a UV-vis spectrophotometer and a flu
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Naughton, Matt S., Vivek Kumar, Yolanda Bonita, Kishori Deshpande, and Paul J. A. Kenis. "High temperature continuous flow synthesis of CdSe/CdS/ZnS, CdS/ZnS, and CdSeS/ZnS nanocrystals." Nanoscale 7, no. 38 (2015): 15895–903. http://dx.doi.org/10.1039/c5nr04510j.

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Gayou, V. L., B. Salazar Hernández, R. Delgado Macuil, G. Zavala, P. Santiago, and A. I. Oliva. "Structural Studies of ZnS Nanoparticles by High Resolution Transmission Electron Microscopy." Journal of Nano Research 9 (February 2010): 125–32. http://dx.doi.org/10.4028/www.scientific.net/jnanor.9.125.

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Zinc sulfide (ZnS), a representative of wide band gap semiconductor nanocrystals, has an excitonic Bohr radius (aBZnS ) of 2.5 nm. It makes ZnS nanoparticles (ZnS NP) having such size very interesting as small biomolecular probes for fluorescence and laser scanning microscopy. To date, ZnS NP of diameters larger than aBZnS has been subject of extensive experimental and theoretical studies. However many questions remain open concerning the synthesis of undoped and uncapped ZnS NP of diameters less than 2.5 nm. To further probe into the physical properties of undoped and uncapped ZnS NP, in this
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Lin Foo, Evon Y., and Sabar Derita Hutagalung. "Crystallite Size of Chitosan Capped Zinc Sulfide Nanoparticles Synthesized via Wet Chemical Route." Advanced Materials Research 173 (December 2010): 161–66. http://dx.doi.org/10.4028/www.scientific.net/amr.173.161.

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The effect of chitosan as a capping agent on the synthesis of ZnS nanoparticles via wet chemical route was studied. The used of chitosan as a capping agent for ZnS nanoparticles had allow the synthesis to be carried out in water which is a more simple and environmental friendly. In dilute acetic acid, the amines in the chitosan will protonated to become NH3+ ions. The positive charges around the ZnS nanoparticles are then used to disperse the nanoparticles via electrostatic repulsion. Chitosan also has an effect on the size of produced nanoparticles. From the X-ray analysis found that the crys
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