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Artigos de revistas sobre o assunto "Metal carbonyl compounds"

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Bond, Alan M., and Ray Colton. "Electrochemical studies of metal carbonyl compounds." Coordination Chemistry Reviews 166 (November 1997): 161–80. http://dx.doi.org/10.1016/s0010-8545(97)00022-2.

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Chandra, Mohan. "ROLE OF [W(CO)6] IN ORGANIC REACTIONS." International Journal of Education &Applied Sciences Research 1, no. 4 (2014): 94. https://doi.org/10.5281/zenodo.10685875.

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<strong>Abstract</strong> <em>The special interest attached to the chemistry of metal carbonyls arises&nbsp; from several causes. While quite distinct from&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; the metal carbonyls in the organometallic compounds, they&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; differ in Physical&nbsp; properties (e.g., volatility) from all other compounds of the transition metals. Chemically, they constitute a group of compounds in which the formal valency of the metal atoms is zero, and in this respect they are&nb
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Lee, Ha-Eun, Dopil Kim, Ahrom You, Myung Hwan Park, Min Kim та Cheoljae Kim. "Transition Metal-Catalyzed α-Position Carbon–Carbon Bond Formations of Carbonyl Derivatives". Catalysts 10, № 8 (2020): 861. http://dx.doi.org/10.3390/catal10080861.

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α-Functionalization of carbonyl compounds in organic synthesis has traditionally been accomplished via classical enolate chemistry. As α-functionalized carbonyl moieties are ubiquitous in biologically and pharmaceutically valuable molecules, catalytic α-alkylations have been extensively studied, yielding a plethora of practical and efficient methodologies. Moreover, stereoselective carbon–carbon bond formation at the α-position of achiral carbonyl compounds has been achieved by using various transition metal–chiral ligand complexes. This review describes recent advances—in the last 20 years an
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Araki, Shuki, Hirokazu Ito, and Yasuo Batsugan. "Cadmium metal-mediated allylation of carbonyl compounds." Journal of Organometallic Chemistry 347, no. 1-2 (1988): 5–9. http://dx.doi.org/10.1016/0022-328x(88)80263-8.

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Gibson, Dorothy H., and Yekhlef S. El-Omrani. "Selective reductions of carbonyl compounds with group 6 metal carbonyl hydrides." Organometallics 4, no. 8 (1985): 1473–75. http://dx.doi.org/10.1021/om00127a035.

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Chen, Hong, Zi-Chao Tang, Rong-Bin Huang, and Lan-Sun Zheng. "Photodissociation Mass Spectrometry of Trinuclear Carbonyl Clusters M3(CO)12 (M = Fe, Ru, Os)." European Journal of Mass Spectrometry 6, no. 1 (2000): 19–22. http://dx.doi.org/10.1255/ejms.301.

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Photodissociation of trinuclear carbonyl cluster compounds of Fe, Ru and Os was studied by recording the mass spectra produced from laser ablation of the cluster compounds. Under the experimental conditions, dissociation of the cluster compounds is very extensive, but the dissociation pathway of the osmium cluster is different from those of the iron and ruthenium clusters. The iron and ruthenium clusters not only lost their carbonyl ligands, but their cluster cores were also fragmented. As the osmium cluster dissociated, it ejected three pairs of oxygen atoms, in sequence, before losing the ca
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Jaitner, Peter, та Wolfgang Winder. "Reaction of α-Me2TeJ2 with metal carbonyl compounds". Inorganica Chimica Acta 134, № 2 (1987): 201–2. http://dx.doi.org/10.1016/s0020-1693(00)88080-9.

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Aucott, Benjamin J., Anne-Kathrin Duhme-Klair, Benjamin E. Moulton, et al. "Manganese Carbonyl Compounds Reveal Ultrafast Metal–Solvent Interactions." Organometallics 38, no. 11 (2019): 2391–401. http://dx.doi.org/10.1021/acs.organomet.9b00212.

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ALPER, H. "ChemInform Abstract: Metal-Catalyzed Routes to Carbonyl Compounds." ChemInform 26, no. 26 (2010): no. http://dx.doi.org/10.1002/chin.199526303.

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BOND, A. M., and R. COLTON. "ChemInform Abstract: Electrochemical Studies of Metal Carbonyl Compounds." ChemInform 29, no. 17 (2010): no. http://dx.doi.org/10.1002/chin.199817281.

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Teses / dissertações sobre o assunto "Metal carbonyl compounds"

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Taylor, Paul H. "Metal free-oxygenation of carbonyl compounds." Thesis, Cardiff University, 2010. http://orca.cf.ac.uk/54244/.

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The findings to date have contributed to the development of a novel and useful class of synthetic protocol and have resulted in a greatly enhanced understanding of the fundamental workings of the &agr;-oxygenation.
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Bojczuk, M. "Carbonyl exhange mechanisms in transition metal compounds." Thesis, University of Kent, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.372765.

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Lorusso, Patrizia. "Metal catalysed alkylation of carbonyl compounds with formaldehyde." Thesis, University of St Andrews, 2015. http://hdl.handle.net/10023/7823.

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Formaldehyde is a chemical used widely in the manufacture of building materials. A remarkable example is represented by the Lucite two-step Alpha technology for the large scale production of methyl methacrylate (MMA), the essential building block of all acrylic-based products. Esters and ketones are important intermediates in the manufacture of acrylate esters therefore α-hydroxymethylenation of carbonyl compounds using formaldehyde as a one carbon alkylating agent and subsequent dehydration to the corresponding methylenated derivatives has been explored in the current work. We report a novel
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Llewellyn, Simon. "Acyl carbonyl transition metal compounds : their homologation and hydrogenation." Thesis, University of Oxford, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.433556.

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洪若華 and Yeuk-wah Hung. "The chemistry of Osmium-Rhodium mixed-metal carbonyl clusters." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1998. http://hub.hku.hk/bib/B3121535X.

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Hung, Yeuk-wah. "The chemistry of Osmium-Rhodium mixed-metal carbonyl clusters /." Hong Kong : University of Hong Kong, 1998. http://sunzi.lib.hku.hk/hkuto/record.jsp?B19904988.

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Ladogana, Santino. "Kinetics and Mechanisms of Metal Carbonyls." Thesis, University of North Texas, 1998. https://digital.library.unt.edu/ark:/67531/metadc278709/.

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Pulsed laser flash photolysis with both visible and infrared detection has been applied to the study of the displacement of weakly coordinating ligands (Lw) by strongly "trapping" nucleophiles (Ls) containing either an olefinic functionality (Ls = 1-hexene, 1-decene, 1-tetradecene) or nitrogen (Ls = acetonitrile, hydrocinnamonitrile) from the photogenerated 16 electron pentacarbonylchromium (0) intermediate. 5-Chloropent-l-ene (Cl-ol), a potentially bidentate ligand, has been shown to form (ol-Cl) pentacarbonylchromium (0), in which Cl-ol is bonded to Cr via a lone pair on the chlorine, and is
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Mansour, Saber E. (Saber El-Sayed). "The Nature of Intermediates Produced Through Ligand-Substitution Reactions of Octahedral Metal Carbonyls." Thesis, North Texas State University, 1986. https://digital.library.unt.edu/ark:/67531/metadc331634/.

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Pulsed laser time-resolved ligand-substitution photochemistry for (DTO)W(CO)4, (DTN)W(CO)4, and (NP)Mo(CO)4 (DTO = 2,2,7,7-tetramethyl-3,6-diathiaoctane; DTN = 2,2,8,8- tetramethyl-3,7-diathianonane; NP = l-diethylamino-2- diphenylphosphinoethane) proceeds via initial fission of the W-S and Mo-P bonds, affording Cs and C4v five-coordinate intermediates for DTN and NP but largely Cs for DTO. The rates of reaction of these intermediates, via chelate ring closure and competitive bimolecular interaction with Lewis bases (= L, alkylphosphines and alkyl phosphites) for the Cs intermediates and via b
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王淑儀 and Shuk-yee Janet Wong. "The chemistry of osmium carbonyl clusters containing oxime and oxo ligands." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2003. http://hub.hku.hk/bib/B31244932.

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Ismail, Ashraf A. "Chalcocarbonyl chemistry : application in hormonal receptor determination, metalloporphyrins and metal-arene bond activation." Thesis, McGill University, 1985. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=72063.

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The reaction of ((eta)-Arene)Cr(CO)(,2)(CX) (X = S, Se) complexes with excess (RO)(,3)P (R = Me, Et, n-Bu, Ph) yields Cr(CO)(,2)(CX) (RO)(,3)P (,3), predominantly as the mer I isomer, in which a phosphite ligand is trans to CX. Arene displacement from ((eta)-C(,6)H(,6))Cr(CO)(,2)(CX) by tridentate phosphine ligands L-L-L L-L-L = (Me)C(CH(,2)P(Ph)(,2))(,3), (Ph(,2)PCH(,2)CH(,2))(,2)PhP gives fac-(L-L-L)Cr(CO)(,2)(CX) products. The molecular structures of Cr(CO)(,2)(CX) (MeO)(,3)P (,3) have been determined by single crystal X-ray diffraction. Intramolecular isomerization of these complexes as we
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Livros sobre o assunto "Metal carbonyl compounds"

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Kelly, Tracy A. Studies of mono- and diphosphine metal carbonyl complexes. University College Dublin, 1997.

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Scott, McIndoe J., ed. Transition metal carbonyl cluster chemistry. Gordon and Breach Science Publishers, 2000.

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Sellow, Khaled Ahmed F. Studies of the reactions of metal carbonyl complexes with phosphorus and nitrogen-containing ligands. University College Dublin, 1998.

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Malmvik, Ann-Charlotte. Structure and reactions of some complex metal hydride reagents used in reduction of carbonyl compounds: Asymmetric reductions, multinuclear NMR studies, computer modelling. Uppsala University?, 1985.

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Visnapuu, A. Recovery of critical metals by carbonyl processing. U.S. Dept. of the Interior, Bureau of Mines, 1987.

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1942-, Hartley F. R., ed. The chemistry of the metal-carbon bond. Wiley, 1987.

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Tatiana, Makarova, and Palacio Parada Fernando, eds. Carbon-based magnetism: An overview of the magnetism of metal free carbon-based compounds and materials. Elsevier, 2006.

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Behr, Arno. Carbon dioxide activation by metal complexes. VCH, 1988.

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1942-, Hartley F. R., and Patai Saul, eds. The Chemistry of the metal-carbon bond. Wiley, 1985.

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David, Morales-Morales, and Jensen Craig M. 1955-, eds. The chemistry of pincer compounds. Elsevier, 2007.

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Capítulos de livros sobre o assunto "Metal carbonyl compounds"

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Liu, Xin, John E. Ellis, Eugen F. Mesaros, et al. "Transition Metal Carbonyl Compounds." In Inorganic Syntheses. John Wiley & Sons, Inc., 2004. http://dx.doi.org/10.1002/0471653683.ch3.

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Ceriotti, Alessandro, Roberto Della Pergola, and Luigi Garlaschelli. "High-Nuclearity Carbonyl Metal Clusters." In Physics and Chemistry of Metal Cluster Compounds. Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-015-1294-7_2.

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Adams, Richard D., and István T. Horváth. "Novel Reactions of Metal Carbonyl Cluster Compounds." In Progress in Inorganic Chemistry. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470166345.ch3.

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Darcel, Christophe, Jean-Baptiste Sortais, Duo Wei, and Antoine Bruneau-Voisine. "Iron-, Cobalt-, and Manganese-Catalyzed Hydrosilylation of Carbonyl Compounds and Carbon Dioxide." In Non-Noble Metal Catalysis. Wiley-VCH Verlag GmbH & Co. KGaA, 2018. http://dx.doi.org/10.1002/9783527699087.ch10.

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Mews, Rüdiger. "Transition Metal Carbonyl Sulfur Dioxide and Thiazylfluoride Complexes: Reactions at the Metal Center and at the Ligand." In Efficient Preparations of Fluorine Compounds. John Wiley & Sons, Inc., 2012. http://dx.doi.org/10.1002/9781118409466.ch15.

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Calderoni, F., M. C. Iapalucci, and G. Longoni. "Compounds of Post-Transition Elements of Groups 12–14 Containing Fe(CO)4 and Related Iron Carbonyl Ligands." In Metal-Ligand Interactions. Springer Netherlands, 1996. http://dx.doi.org/10.1007/978-94-009-0155-1_4.

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Hu, Yang, and X. Peter Zhang. "Selective Olefination of Carbonyl Compounds via Metal-Catalyzed Carbene Transfer from Diazo Reagents." In Topics in Current Chemistry. Springer Berlin Heidelberg, 2012. http://dx.doi.org/10.1007/128_2012_319.

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Mcauliffe, C. A., and D. G. Kelly. "By Reaction with Transition- or Inner-Transition-Metal Carbonyl, Organometallic and Cluster Compounds." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145227.ch116.

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Newlands, M. J. "By Reaction of Vinyitin Compounds with Transition- or Inner Transition-Metal-Carbonyl Complexes." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145265.ch82.

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Newlands, M. J. "By Reaction of Aryltin Compound and Cyclopentadienyltin Compounds with Transition- or Inner Transition-Metal-Carbonyl and Other Complexes." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145265.ch84.

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Trabalhos de conferências sobre o assunto "Metal carbonyl compounds"

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Haskaj, Adelina, Musaj Pacarizi, Sonja Lepitkova, Berat Sinan, Bahri Sinani, and Elida Dreshaj. "THE POTENTIAL COMPLEXING IMPACT OF SOME ORGANIC COMPOUNDS AMINE AND CARBOXYL GROUPS ON TRANSITION METALS." In 24th SGEM International Multidisciplinary Scientific GeoConference 24. STEF92 Technology, 2024. https://doi.org/10.5593/sgem2024/4.1/s18.42.

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Environmental water chemistry is substantially aided by modern electrochemical research. Sensitive voltammetric techniques are much more useful for metal species in natural waters, where complexation with organic molecules predominates. Many environmental electrochemists are still interested in determining the stability constants of metal ion complexes with various ionic species found in natural waterways. The aim of this work is to investigate the possible influence of complexation of amine and carboxyl groups of some organic molecules (with EDTA, NTA and aniline, using differential pulse pol
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Little, Brenda, Patricia Wagner, Kevin Hart, et al. "The Role of Metal-Reducing Bacteria in Microbiologically Influenced Corrosion." In CORROSION 1997. NACE International, 1997. https://doi.org/10.5006/c1997-97215.

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Abstract Synthetic iron oxides (goethite, aFeO·OH; hematite, Fe2O3; and ferrihydrite, Fe(OH)3) were used as model compounds to simulate the mineralogy of passivating films on carbon steel. Dissolution of these oxides exposed to pure cultures of the metal-reducing bacterium, Shewanella putrefaciens, was followed by direct atomic absorption spectroscopy measurement of ferrous iron coupled with microscopic analyses using confocal laser scanning and environmental scanning electron microscopies. During an 8-day exposure the organism colonized mineral surfaces and reduced solid ferric oxides to solu
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Meenakshi, H. N., A. Anisha, R. Shyamala, R. Saratha, and S. Papavinasam. "Corrosion of Metals in Biodiesel from Pongamia Pinnata." In CORROSION 2010. NACE International, 2010. https://doi.org/10.5006/c2010-10076.

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Abstract Biodiesel is a suitable renewable alternative fuel that can be added to diesel derived from fossil fuel because their constituents match that of diesel. Tankers, storage tanks, pipes and pumping equipment are normally constructed using carbon steel, stainless steel or aluminium. It is known that biodiesel and biodiesel blends form sediments when in contact with metals. Natural or nitrile rubber compounds, polyethylene, polypropylene, and polyvinyl materials are also vulnerable to biodiesel. A review of literature on biofuels reveals that least work has been carried out on the corrosio
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Benn, Ernie, Simon Yuen, Andrea Weston, Michael J. Jirinec, George Y. Lai, and Mark Stoutamire. "Restoration of a Petroleum Refinery Vessel Using Weld Metal Overlay." In CORROSION 1998. NACE International, 1998. https://doi.org/10.5006/c1998-98581.

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Abstract An atmospheric crude tower was subjected to accelerated corrosion over a short period of time. The corrosion mechanism was due primarily to changes in the feed, with higher quantities of sulfur compounds being processed at higher operating temperatures. The corrosion damage extended over a height of 14ft (4.3m) between the medium gas oil and diesel zones in the carbon steel section of the tower. In view of the criticality of the vessel to the refinery’s operations, a decision was made to restore the vessel integrity using weld metal overlay. After a complete structural design review,
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Xin, Qin, and Heather D. Dettman. "Corrosivity Study of Sulfur Compounds and Naphthenic Acids under Refinery Conditions." In CORROSION 2016. NACE International, 2016. https://doi.org/10.5006/c2016-07392.

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Abstract The potential corrosivity of crude oils is a major concern for refineries. Plant experience has shown that current methods based on crude sulfur content and total acid number (TAN) do not reliably predict corrosion rates. In particular, a better understanding of the relative importance of sulfidic and naphthenic acid corrosion mechanisms, when both are present, is needed to better predict crude corrosivity. Previous work focused on the influence of organic acid structure on corrosivity. In this paper, the relative corrosivities of different types of sulfur species are explored. Four m
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Geng, G. Q., B. Q. Wang, and A. V. Levy. "Effect of Calcium Sulfate Particles on Erosion and Erosion-Corrosion of Carbon Steel." In CORROSION 1991. NACE International, 1991. https://doi.org/10.5006/c1991-91060.

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Abstract In laboratory erosion-corrosion (E-C) and corrosion experiments it was determined that calcium sulfate which occurs in FBC bed materials from the reaction of calcined limestone with the sulfur in the coal fuel can either protect the base metal against erosion-corrosion by aiding the formation of mixed calcium compound-iron oxide layers on the surface or promote its sulfidation, depending on the calcium sulfate content of the erodent particles and the test temperature, particle velocity, and duration. The reaction between calcium sulfate particles and metal substrates formed iron sulfi
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Geng, G. Q., B. Q. Wang, and Alan V. Levy. "The Effect of Fluidized Bed Combustor Bed Materials Compositions on the Erosion-Corrosion of Carbon Steel." In CORROSION 1990. NACE International, 1990. https://doi.org/10.5006/c1990-90290.

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Abstract The relative amounts of SiO2, CaO, CaCO3,CaSO4, and alkali compounds in the bed materials of circulating fluidized bed combustors determined the metal wastage of heat exchanger tubing alloys exposed to the particles. The ratio of SiO2 to CaO and to CaCO3 is especially important in determining the erosivity of the bed materials. It was found that increasing this ratio increased the metal wastage. A sharp transition ratio occurred on either side of which the metal wastages were linear. The slope of the linear curve was low for the lower sand content mixtures and higher for higher sand c
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Wehlmann, Anika, Wolfgang Hater, Florian Wolf, Rudolf Lunkenheimer, and Christophe Foret. "New Corrosion Inhibitors for Evaporative Cooling Systems." In CORROSION 2013. NACE International, 2013. https://doi.org/10.5006/c2013-02756.

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Abstract Corrosion of heat exchangers and installations in evaporative cooling systems is a serious problem of industry, as it may lead to increased maintenance effort, damages, up to plant shutdown causing high cost. Furthermore, there may be a high environmental impact due to the discharge of water containing heavy metals or hazardous compounds from leakages. State of the art corrosion inhibitor programs are based on phosphate, phosphonates, zinc and combinations thereof. Although generally satisfying control of corrosion can be achieved, all programs suffer environmental drawbacks, such as
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Agarwal, D. C., U. Brill, and Jutta Kloewer. "Recent Results on Metal Dusting of Nickel Base Alloys and Some Applications." In CORROSION 2001. NACE International, 2001. https://doi.org/10.5006/c2001-01382.

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Abstract In high temperature corrosion, besides oxygen attack, alloys frequently encounter attack by carbon species. This attack can take two forms namely carburization and metal dusting (some times refereed to as catastrophic carburization). Carburization generally occurs at carbon activities &amp;lt;1 and at temperatures &amp;gt; 800° C and results in alloy embrittlement due to formation of internal carbides. Metal Dusting on the other hand leads to rapid wastage, thinning and disintegration of alloys into graphite and metal particles and occurs in environments with carbon activities signifi
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Vera, Jose Rafael. "Physical and Chemical Effects of Crude Oil on CO2/H2S Metal Loss Corrosion: an Updated Review." In CORROSION 2015. NACE International, 2015. https://doi.org/10.5006/c2015-05672.

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Abstract The presence of crude oil in the oil and gas production may significantly reduce corrosion rates of carbon steel in CO2/H2S containing environments. The crude oil inhibition mechanisms can be combined into two main effects: 1) A chemical effect, related to inhibiting properties of compounds present in the crude oil; and 2) A physical effect, related to the capacity of the oil or some of its components to prevent the water from contacting the steel surface. This paper focuses on the work that has been performed during the last decade mainly addressing the physical effect of crude oil o
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Relatórios de organizações sobre o assunto "Metal carbonyl compounds"

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Kanner, Joseph, Mark Richards, Ron Kohen, and Reed Jess. Improvement of quality and nutritional value of muscle foods. United States Department of Agriculture, 2008. http://dx.doi.org/10.32747/2008.7591735.bard.

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Food is an essential to our existence but under certain conditions it could become the origin to the accumulative health damages. Technological processes as heating, chopping, mincing, grounding, promote the lipid oxidation process in muscle tissues and meat foodstuffs. Lipid oxidation occurred rapidly in turkey muscle, intermediate in duck, and slowest in chicken during frozen storage. Depletion of tocopherol during frozen storage was more rapid in turkey and duck compared to chicken. These processes developed from lipid peroxides produce many cytotoxic compounds including malondialdehyde (MD
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Jayatissa, Kuruppu. A Metal-Free Approach to Biaryl Compounds: Carbon-Carbon Bond Formation from Diaryliodonium Salts and Aryl Triolborates. Portland State University Library, 2000. http://dx.doi.org/10.15760/etd.2226.

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Wongpakdeea, Thinnapong, Karin Crenshaw, Hery Figueroa Wong, Duangjai Nacapricha, and Bruce McCord. Advancements in Analytical Techniques for Rapid Identification of Gunshot Residue and Low Explosives through Electrochemical Detection and Surface-Enhanced Raman Spectroscopy. Florida International University, 2024. https://doi.org/10.25148/gfjcsr.2024.7.

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This research focuses on developing two analytical methods for forensic investigations using electrochemical detection and surface-enhanced Raman spectroscopy. For electrochemical analysis, screen-printed carbon electrodes are used to detect metals and nitrate/nitrite compounds commonly found in gunshot residue. Gold electrodeposition and copper modification enhance sensitivity and catalytic activity, respectively. Additionally, a screen-printed gold electrode modified with gold nanoparticles enables surface-enhanced Raman spectroscopy, requiring only a single drop of sample solution. Testing
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Banin, Amos, Joseph Stucki, and Joel Kostka. Redox Processes in Soils Irrigated with Reclaimed Sewage Effluents: Field Cycles and Basic Mechanism. United States Department of Agriculture, 2004. http://dx.doi.org/10.32747/2004.7695870.bard.

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Resumo:
The overall objectives of the project were: (a) To measure and study in situ the effect of irrigation with reclaimed sewage effluents on redox processes and related chemical dynamics in soil profiles of agricultural fields. (b) To study under controlled conditions the kinetics and equilibrium states of selected processes that affect redox conditions in field soils or that are effected by them. Specifically, these include the effects on heavy metals sorption and desorption, and the effect on pesticide degradation. On the basis of the initial results from the field study, increased effort was de
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