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Bibliografias temáticas / Schiff base ligands

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Literatura científica selecionada sobre o tema "Schiff base ligands"

Autor: Grafiati

Publicado: 4 de junho de 2021

Última modificação: 25 de julho de 2025

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Artigos de revistas sobre o assunto "Schiff base ligands"

1

Biswas, Arpita. "A Brief Review on Homo-/Hetero-nuclear Co-ordination Compounds Derived from Some Single Compartmentl Acyclic Schiff Base Ligands having N-,O-Donor Centres." Oriental Journal Of Chemistry 38, no. 4 (2022): 957–66. http://dx.doi.org/10.13005/ojc/380417.

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Tetradentate acyclic compartmental Schiff base ligand with N2O2 compartment afford suitable coordination environment for large variety of metal ions. This type of ligands can easily be synthesized by [2+1] condensation of a carbonyl compounds with a diamine. Several metal complexes have been reported from the single- and double-compartment acyclic Schiff base ligands which are the [2+1] condensation products of salicylaldehyde, 2-hydroxyacetophenone, 3-methoxysalicylaldehyde, 3-ethoxysalicylaldehyde and a diamine; The diamine counterpart in these ligands are ethylenediamine, 1,3-diaminopropane

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2

Abbasova, G. G., A. A. Medjidov, R. H. Ismayilov, A. M. Pashajanov, and P. A. Fatullayeva. "Synthesis and characterization of rare earth metal complexes with novel Schiff base." Fine Chemical Technologies 20, no. 1 (2025): 47–54. https://doi.org/10.32362/2410-6593-2025-20-1-47-54.

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Objectives. The work set out to synthesize Schiff base ligands containing a hydrazone moiety of (Z)-2-((E)-1-hydroxyethylidene)hydrazineylidene)-2-phenylacetic acid, as well as their praseodymium, samarium, europium, and gadolinium complexes, and to study their structure.Methods. The structure of ligands was identified by infrared (IR), ultraviolet (UV), and nuclear magnetic resonance (NMR) spectroscopy. The structure of the complexes was confirmed by elemental analysis, IR and UV spectroscopy, and thermogravimetric analysis.Results. The Schiff base ligands containing a hydrazone moiety of (Z)

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3

Haruna, A., I. T. Sirajo, M. M. Rumah, and Y. Albashir. "Synthesis, Characterization, Biological Properties, ADMET and Drug-likeness Analysis of Mn (II) complexes with Schiff Bases Derived from Sulphathiazole and 4-diethylaminosalicyaldehyde/Salicyaldehyde." Journal for Research in Applied Sciences and Biotechnology 2, no. 6 (2023): 58–68. http://dx.doi.org/10.55544/jrasb.2.6.10.

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Mn (II) complexes were synthesized with the Schiff base ligand obtained by the condensation of sulfathiazole with 4-diethylaminosalicyaldehyde/Salicyaldehyde. Their characterization was performed by elemental analysis, molar conductance, melting points, magnetic susceptibility, infrared, and UV–Vis spectral analysis. The results suggest that the Schiff bases and their complex are synthesized in excellent yield, molar conductance studies on the complexes indicated they were non-electrolytic. The IR data indicated that the Schiff base ligand is tridentate coordinated to the metallic ion with two

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4

Odularu, Ayodele Temidayo. "Manganese Schiff Base Complexes, Crystallographic Studies, Anticancer Activities, and Molecular Docking." Journal of Chemistry 2022 (August 24, 2022): 1–19. http://dx.doi.org/10.1155/2022/7062912.

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Choice of ligands is significant to successful synthesis of metal complexes (coordination compounds). This study reports the use of Schiff base as the right ligand to control the poor bioavailability and neurodegenerative toxicity challenges of manganese ion. In line with this study, document analysis was used as the methodological approach to evaluate the significance of Schiff base ligands in easing these manganese’s challenges and aligning the resultant coordination compounds (manganese Schiff base complexes) as therapeutic agents in anticancer studies. Report also involves crystallographic

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5

El‐Boraey, Hanaa A., Randa M. Abdel‐Rahman, Ensaf M. Atia, and Ohyla A. EL‐Gammal. "Synthesis, spectral and thermal studies of new Schiff base copper(II) complexes with their biological effect on Entomopathogenic nematodes." Vietnam Journal of Chemistry 60, no. 2 (2022): 140–56. http://dx.doi.org/10.1002/vjch.202100080.

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AbstractNew Schiff base ligands; (Z)‐1,5‐diphenyl‐2‐((thiophen‐2‐ylmethylene)amino)‐1H‐pyrrole‐3‐carbonitrile (L1); or (Z)‐2‐((2,4‐dihydroxybenzylidene)amino)‐1,5‐diphenyl‐1H‐pyrrole‐3‐carbonitrile (H2L2) and their Cu(II) complexes have been isolated and characterized using elemental analysis, spectral (FT‐IR, 1H NMR, UV/vis, EPR), molar conductivity and magnetic moment measurements, in addition to thermal techniques. FT‐IR spectra established that the Schiff base L1 coordinates as neutral bidentate or tridentate ligand. While the Schiff base H2L2 ligates as neutral or monobasic bidentate liga

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6

Ayuba, Isiyaku, Tajo Siraj Ibrahim, Umar Maigari Aishatu, and Magaji Buhari. "Synthesis, characterization and anti-bacterial activity of Schiff Base and its mixed ligand complexes of Cr (II) and Co (II) containing vanillin and 2-aminophenol." Dutse Journal of Pure and Applied Sciences 7, no. 4a (2022): 98–104. http://dx.doi.org/10.4314/dujopas.v7i4a.11.

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Schiff Base are organic ligand that contained azomethine linkage (-HC=N-) which shows biological importance. Schiff Base from vanillin and 2-aminophenol was synthesized in 1:1 mole ratio. The complexes of Cr (II) and Co (II) from Schiff Base in 1:2 mole ratio metal-ligand (M-L) and the mixed ligand complexes from Schiff Base and 2-aminophenol in 1:1:1 mole ratio ligand-metal-ligand(L-M-L) were synthesized and characterized based on solubility, melting point, conductivity, Fourier transform infrared spectroscopy (FTIR) and ultraviolet (UV). The solubility result shows that, dimethyl sulfoxide(D

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7

Osypiuk, Dariusz, Agata Bartyzel, and Beata Cristóvão. "Coordination Polymers of Vanadium and Selected Metal Ions with N,O-Donor Schiff Base Ligands—Synthesis, Crystal Structure, and Application." Molecules 30, no. 5 (2025): 1104. https://doi.org/10.3390/molecules30051104.

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This review provides an overview of the synthesis, characterization and application of coordination polymers based on N,O-donor Schiff base ligands. The coordination polymers (CPs) represent a novel class of inorganic–organic hybrid materials with tunable compositions and fascinating structures. They are composed of metal ions and organic ligands. Therefore, the nature of the metal ion and type of organic ligand is the most significant factor in constructing targeted coordination polymers with the desired properties. Due to the versatile coordination modes, N,O-donor Schiff base ligands are al

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8

Hari, S. Yadav, and L. Kumawat Gopal. "Synthesis, Spectroscopic, Biological, and Theoretical Evaluation of Novel Zirconium (IV) N, O Donor Amino Acid Schiff Base Complexes." Chemistry Research Journal 8, no. 1 (2023): 12–22. https://doi.org/10.5281/zenodo.11296500.

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<strong>Abstract </strong>A series of<strong> </strong>novel dichlorozirconium (IV) Schiff bases complexes [ZrCl<sub>2</sub> (L)<sub>2</sub>] (LH = N, O donor Schiff base derived by the condensation of 2-Acetyl-5-methylfuran & 2-acetyl-4-methyl thiophene with amino acids) were synthesized by the reaction of zirconium (IV) chloride and sodium salt of an N, O donor Schiff base ligand and characterized. The authenticity of all the synthesized ligands and their Zr (IV) complexes had been elucidated by microanalysis, various spectroscopic techniques like FT-IR, <sup>1</sup>H NMR, <sup>13</sup>C

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9

Hsu, Chiao-Yin, Hsi-Ching Tseng, Jaya Kishore Vandavasi та ін. "Investigation of the dinuclear effect of aluminum complexes in the ring-opening polymerization of ε-caprolactone". RSC Advances 7, № 31 (2017): 18851–60. http://dx.doi.org/10.1039/c7ra02136d.

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Al complexes bearing hydrazine-bridging Schiff base ligands showed the best catalytic activity, approximately 3- to 11-fold higher than that of dinuclear Al complexes bearing Salen ligands and mononuclear Al complexes bearing Schiff base ligands.

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10

D. T. Sakhare. "Synthesis, Spectroscopic Characterization, In-Vitro and Antimicrobial Activities of Some Metal (II) Complexes of 5-choloro-2-(((4,6-Dimethoxypyrimidin-2-yl) Imino) Methyl) Phenol." International Journal of Scientific Research in Chemistry 9, no. 6 (2024): 01–09. https://doi.org/10.32628/ijsrch24961.

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The novel Schiff base ligand has been synthesized by the condensation of 5-chlorosalicylaldehyde and 2-amino-4,6-dimethoxypyrimidine. Metal complexes of the Schiff base were prepared by the reaction of the Schiff base and Iron nitrate in ethanol solution. The complexes isolated, washed and dried. The Schiff base is pale yellow, while Cu(II) and Mn(II) complexes is light yellow.The synthesized compounds have been characterized by FT-IR, 1H-NMR and UV-Vis techniques for the ligands and FT-IR, UV-Vis, all reactions monitored by TLC, molar conductivity and magnetic susceptibility measurements for

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Mais fontes

Teses / dissertações sobre o assunto "Schiff base ligands"

1

Najera, Blanca A. "Schiff base macrocyclic ligands and their complexes." Thesis, University of Sheffield, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.301827.

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2

Archibald, Stephen James. "Complexes of tripodal and macrocyclic Schiff base ligands." Thesis, University of Edinburgh, 1995. http://hdl.handle.net/1842/14781.

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The synthesis, structures and physical properties of tripodal and macrocyclic Schiff base ligands and their complexes are described. All ligands are synthesised by the condensation of amines with 2,6-diformyl- or 2,6-diacetyl-phenols. The synthesis of a novel dodecadentate tripodal Schiff base ligand, L<SUP>1</SUP>H<SUB>3</SUB>, is described. Reaction of L<SUP>1</SUP>H<SUB>3</SUB> with Ln(ClO<SUB>4</SUB>)<SUB>3</SUB> where Ln=La, Pr gives complexes of the form [Ln(L<SUP>1</SUP>H<SUB>3</SUB>)(H<SUB>2</SUB>O)](CIO<SUB>4</SUB>)<SUB>3</SUB> and where Ln=Y, [Y(L<SUP>1</SUP>H<SUB>3</SUB>)](CIO<SUB>4

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3

Crook, B. V. "A study of homobinuclear and heterobinuclear Schiff base complexes." Thesis, University of East Anglia, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.376081.

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4

Jakubovic, David Andrew. "Metal complexes of water-soluble multidentate Schiff base ligands." Thesis, Imperial College London, 1989. http://hdl.handle.net/10044/1/47487.

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5

Marrs, Deborah Jane. "Macrocycles, macrobicycles : a study." Thesis, Open University, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.257447.

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6

Low, May Lee. "Synthèse, caractérisation et bioactivité de ligands issus de bases de Schiff dérivées de dithiocarbazate et de leurs complexes métalliques." Thesis, Paris 6, 2014. http://www.theses.fr/2014PA066148/document.

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Il y a de nos jours un besoin urgent de découvrir de nouveaux médicaments pour relever le défi de la multirésistance dans le traitement des infections bactériennes et le cancer. Dans cette perspective, des bases de Schiff dérivées de dithiocarbazates et leurs complexes métalliques correspondants sont des candidats intéressants puisqu'ils peuvent être facilement synthétisés et permettent une grande diversité de coordination. Dans cette étude, des complexes tetradentes et bidente ont été préparés. Les ligands et complexes synthétisés ont été entièrement caractérisés par différentes méthodes spec

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7

Zhang, Zhi-Yong. "Synthèse, propriétés structurales, magnétiques et redox de complexes polynucléaires du manganèse avec des ligands à sites donneurs N2O3." Toulouse 3, 1994. http://www.theses.fr/1994TOU30102.

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Les travaux realises au cours de cette these ont pour but de modeliser le centre actif de la metalloproteine a manganese du photosysteme ii vegetal. Pour ce faire, nous avons prepare et etudie deux familles de complexes incorporant des bases de schiff pentadentees a sites donneurs n#2o#3 comme ligands binucleants. Parmi les dix neuf complexes prepares, nous avons determine la structure moleculaire d'un complexe dinucleaire du mn(iii), de trois complexes tetranucleaires mn(ii)#2mn(iii)#2 et d'un complexe tetranucleaire mn(iii)#4, par diffraction des rx. Dans la premiere partie de notre travail,

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8

Pop, Mihaela Diana. "Symmetrical and asymmetrical Salen-type Schiff-base ligands and their transition metal complexes." Thesis, University College London (University of London), 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.408061.

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9

Solanki, Nayan Kumar. "The copper chemistry of substituted 2,6-Bis pyrazolyl pyridines and schiff base ligands." Thesis, University of Cambridge, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.621813.

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10

Bowman, Gary Raymond, University of Western Sydney, of Science Technology and Environment College, and of Science Food and Horticulture School. "Studies of Titanium(IV)complexes of mixed nitrogen and oxygen donor macrocycles and related schiff base ligands." THESIS_CSTE_SFH_Bowman_G.xml, 2002. http://handle.uws.edu.au:8081/1959.7/410.

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This work investigated the use of large tetradentate mixed nitrogen and oxygen donor macrocycles as potential ligands for titanium(IV).These large ligands are capable of encapsulating the metal ion, thereby protecting it from reacting further. In addition, titanium complexes of this type had not been reported previously.Molecular modelling was utilised to evaluate and predict the coordinating potential of the macrocycles investigated.An alternative synthetic strategy was needed to achieve coordination complexes with titanium. This involved the use of a benzene based solvent system and rigorous

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Mais fontes

Livros sobre o assunto "Schiff base ligands"

1

Haynes, M. Manganese schift base N202 donor ligand complexescontainingbranched carboxylates, as models for the water-oxidizingcomplexinphotosystem II. UMIST, 1994.

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2

Sommerer, Shaun O. A synthetic, structural and theoretical investigation of pentadentate Schiff base ligands. 1991.

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3

Schiff Base Ligands and its Metal Complexes for Bio-medical Applications [Working Title]. IntechOpen, 2018. http://dx.doi.org/10.5772/intechopen.75733.

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4

Tabaczynski, Walter A. Structure determination of Schiff base ligands and complexes by modern NMR techniques: A thesis in Chemistry. 1991.

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5

Qian, Keping. Synthesis and characterization of the compounds with the derivatives of pyridine or schiff bases. 1991.

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Capítulos de livros sobre o assunto "Schiff base ligands"

1

Kassim, Karimah, and Muhamad Faridz Osman. "Conductivity studies of schiff base ligands derived from phenylenediamine derivatives." In Bioresources Technology in Sustainable Agriculture. Apple Academic Press, 2018. http://dx.doi.org/10.1201/9781315365961-19.

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2

Vieira, Rafael Pinto, and Heloisa Beraldo. "Design of Schiff Base-derived Ligands: Applications in Therapeutics and Medical Diagnosis." In Ligand Design in Medicinal Inorganic Chemistry. John Wiley & Sons, Ltd, 2014. http://dx.doi.org/10.1002/9781118697191.ch7.

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3

Matsushita, Takayuki. "Reactions of KMnO4 with Various Schiff Base Ligands in Aprotic Solvents." In The Activation of Dioxygen and Homogeneous Catalytic Oxidation. Springer US, 1993. http://dx.doi.org/10.1007/978-1-4615-3000-8_61.

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4

Pardasani, R. T., and P. Pardasani. "Magnetic properties of copper(II) complex of bis-tetradentate Schiff-base ligands." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-53974-3_315.

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5

Pardasani, R. T., and P. Pardasani. "Magnetic properties of copper(II) complex of bis-tetradentate Schiff-base ligands." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-53974-3_316.

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6

Pardasani, R. T., and P. Pardasani. "Magnetic properties of nickel(II) complex with tetradentate Schiff-base azide ligands." In Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 7. Springer Berlin Heidelberg, 2023. http://dx.doi.org/10.1007/978-3-662-65895-6_248.

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7

Pardasani, R. T., and P. Pardasani. "Magnetic properties of iron complex with Schiff base and o-benzoquinone ligands." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2015. http://dx.doi.org/10.1007/978-3-662-45972-0_321.

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8

Swami, Summan, and Rahul Shrivastava. "Acyclic and Macrocyclic Schiff Base-Based Chelating Ligands for Uranyl Ion (Uo2 2+) Complexation." In Research Methodology in Chemical Sciences. Apple Academic Press, 2017. http://dx.doi.org/10.1201/9781315366616-8.

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9

Pardasani, R. T., and P. Pardasani. "Magnetic properties of mixed ligand copper(II) complex of bis-tetradentate Schiff-base and azide ligands." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-53974-3_317.

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10

Pardasani, R. T., and P. Pardasani. "Magnetic properties of tetranuclear copper(II) complex with Schiff-base and dipyrazolate ligands." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54237-8_579.

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Trabalhos de conferências sobre o assunto "Schiff base ligands"

1

Jurowska, Anna, Janusz Szklarzewicz, Maciej Hodorowicz, Ennio Zangrando, and Ghodrat Mahmoudi. "Ionic Derivatives of Insulin-Mimetic Vanadium(V) Complexes with Schiff Base Ligands." In ECMC 2022. MDPI, 2022. http://dx.doi.org/10.3390/ecmc2022-13167.

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2

Murphy-Jolly, Makeba B., Samuel B. Owens, Gary M. Gray, Christopher M. Lawson, and David P. Shelton. "Synthesis, Crystal Structure and Hyper Rayleigh Scattering Measurements of Phosphite-Substituted Schiff Base Ligands." In Nonlinear Optics: Materials, Fundamentals and Applications. OSA, 2009. http://dx.doi.org/10.1364/nlo.2009.jwa19.

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3

Sheikhshoaie, Iran, and Walter Fabian. "A Quantum Chemical Study of Second Order Nonlinear Optical Properties of Assymetric Bidentate Schiff Base Ligands." In The 8th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2004. http://dx.doi.org/10.3390/ecsoc-8-01965.

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4

Harmošová, Michaela, Martin Kello, Mária Vilková, Erika Samoľová, and Ivan Potočňák. "Synthesis, structure and anticancer activity of Zr(IV) complexes with Schiff bases derived from 8-hydroxyquinoline." In 2nd International Conference on Chemo and Bioinformatics. Institute for Information Technologies, University of Kragujevac, 2023. http://dx.doi.org/10.46793/iccbi23.439h.

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The Schiff base 2-{[(2-hydroxyphenyl)imino]methyl}quinolin-8-ol (HLH) and its 5,7-dibromo- (HBrLH) and 5,7-diiodo-derivatives (HILH), which were prepared by multi-step organic synthesis, were used to synthesize [Zr(L)2]·2DMF (1), [Zr(BrL)2]·DMF (2), and [Zr(IL)2]·2DMF (3) complexes. The prepared products were characterized by elemental analysis, IR and NMR spectroscopy, which also monitored the stability of the prepared substances in DMSO, and in the case of HBrLH, HILH and 3, also by single crystal X-ray structural analysis. In the complex 3, two IL ligands are tetradentately bound to the cen

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5

Catikkas, Berna. "DFT INVESTIGATION ABOUT ELECTRONIC AND VIBRATIONAL PROPERTIES OF CHROMONE SCHIFF BASE LIGANDS WITH METAL COMPLEXES, SQM ANALYSIS." In 2022 International Symposium on Molecular Spectroscopy. University of Illinois at Urbana-Champaign, 2022. http://dx.doi.org/10.15278/isms.2022.wa07.

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6

Jaya, NM, NH Ismail, ALM Low, et al. "Schiff base ligands derived from phenylenediamine and its metal complexes as enhancer against two mechanisms of antibiotic resistance." In 67th International Congress and Annual Meeting of the Society for Medicinal Plant and Natural Product Research (GA) in cooperation with the French Society of Pharmacognosy AFERP. © Georg Thieme Verlag KG, 2019. http://dx.doi.org/10.1055/s-0039-3400408.

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7

Vázquez-Fernández, M., M. Fernández, B. Fernández, A. González-Noya, M. Maneiro, and M. Rodríguez-Doutón. "Synthesis of Multidentate Schiff Base Ligands. Crystal Structure of (N-N’-BIS(3-Ethoxysalicylidene)-1,3-Diamino-2,2-Dimethylpropane." In The 12th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2008. http://dx.doi.org/10.3390/ecsoc-12-01225.

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8

KURODA, TAKAYOSHI. "SPIN CROSSOVER PROPERTIES OF IRON(II) COMPLEXES WITH A N4O2 DONOR SET BY EXTENDED Π-CONJUGATED SCHIFF-BASE LIGANDS". У Symposium on Quantum Information and Quantum Computing. WORLD SCIENTIFIC, 2012. http://dx.doi.org/10.1142/9789814425223_0011.

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9

Cocu, Maria, Paulina Bourosh, Victor Kravtsov, Olga Danilescu, and Ion Bulhac. "Mononuclear nickel(ii) and copper(ii) complexes with schiff base ligands derived from quinoline-8-aledehyde and S-methylisothiosemicarbazones." In Scientific seminar "Advanced materials to reduce the impact of toxic chemicals on the environment and health". Institute of Chemistry, Republic of Moldova, 2023. http://dx.doi.org/10.19261/admateh.2023.ab27.

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10

Fernández, M., M. Rodríguez-Doutón, M. Maneiro, A. González-Noya, B. Fernández, and M. Vázquez- Fernández. "SYNTHESIS OF DICOMPARTIMENTAL SCHIFF BASE LIGANDS. CRYSTAL STRUCTURE OF (N-N'-BIS(3- METHOXY or 3-ETHOXYSALICYLIDENE)-1,2-DIAMINE-2-METHYLPROPANE." In The 14th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2010. http://dx.doi.org/10.3390/ecsoc-14-00437.

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