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Статті в журналах з теми "Adsorption induced deformation"

Автор: Grafiati

Опубліковано: 26 квітня 2025

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1

Fomkin, A. A., A. V. Shkolin, A. L. Pulin, I. E. Men’shchikov, and E. V. Khozina. "Adsorption-Induced Deformation of Adsorbents." Colloid Journal 80, no. 5 (September 2018): 578–86. http://dx.doi.org/10.1134/s1061933x18050083.

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2

Gor, Gennady Yu, and Alexander V. Neimark. "Adsorption-Induced Deformation of Mesoporous Solids." Langmuir 26, no. 16 (August 17, 2010): 13021–27. http://dx.doi.org/10.1021/la1019247.

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3

Kolesnikov, A. L., Yu A. Budkov, and G. Y. Gor. "Models of adsorption-induced deformation: ordered materials and beyond." Journal of Physics: Condensed Matter 34, no. 6 (November 22, 2021): 063002. http://dx.doi.org/10.1088/1361-648x/ac3101.

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Анотація:

Abstract Adsorption-induced deformation is a change in geometrical dimensions of an adsorbent material caused by gas or liquid adsorption on its surface. This phenomenon is universal and sensitive to adsorbent properties, which makes its prediction a challenging task. However, the pure academic interest is complemented by its importance in a number of engineering applications with porous materials characterization among them. Similar to classical adsorption-based characterization methods, the deformation-based ones rely on the quality of the underlying theoretical framework. This fact stimulates the recent development of qualitative and quantitative models toward the more detailed description of a solid material, e.g. account of non-convex and corrugated pores, calculations of adsorption stress in realistic three-dimension solid structures, the extension of the existing models to new geometries, etc. The present review focuses on the theoretical description of adsorption-induced deformation in micro and mesoporous materials. We are aiming to cover recent theoretical works describing the deformation of both ordered and disordered porous bodies.

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4

Morak, Roland, Stephan Braxmeier, Lukas Ludescher, Florian Putz, Sebastian Busch, Nicola Hüsing, Gudrung Reichenauer, and Oskar Paris. "Quantifying adsorption-induced deformation of nanoporous materials on different length scales." Journal of Applied Crystallography 50, no. 5 (September 14, 2017): 1404–10. http://dx.doi.org/10.1107/s1600576717012274.

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A newin situsetup combining small-angle neutron scattering (SANS) and dilatometry was used to measure water-adsorption-induced deformation of a monolithic silica sample with hierarchical porosity. The sample exhibits a disordered framework consisting of macropores and struts containing two-dimensional hexagonally ordered cylindrical mesopores. The use of an H2O/D2O water mixture with zero scattering length density as an adsorptive allows a quantitative determination of the pore lattice strain from the shift of the corresponding diffraction peak. This radial strut deformation is compared with the simultaneously measured macroscopic length change of the sample with dilatometry, and differences between the two quantities are discussed on the basis of the deformation mechanisms effective at the different length scales. It is demonstrated that the SANS data also provide a facile way to quantitatively determine the adsorption isotherm of the material by evaluating the incoherent scattering contribution of H2O at large scattering vectors.

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5

Brochard, Laurent, Matthieu Vandamme, Roland J. M. Pellenq, and Teddy Fen-Chong. "Adsorption-Induced Deformation of Microporous Materials: Coal Swelling Induced by CO2–CH4 Competitive Adsorption." Langmuir 28, no. 5 (January 23, 2012): 2659–70. http://dx.doi.org/10.1021/la204072d.

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6

Zou, Jie, Chunyan Fan, Junfang Zhang, Xiu Liu, Wen Zhou, Liang Huang, and Hao Xu. "Effect of Adsorbent Properties on Adsorption-Induced Deformation." Langmuir 37, no. 51 (December 15, 2021): 14813–22. http://dx.doi.org/10.1021/acs.langmuir.1c02512.

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7

Shkolin, A. V., A. A. Fomkin, A. L. Pulin, and V. Yu Yakovlev. "A technique for measuring an adsorption-induced deformation." Instruments and Experimental Techniques 51, no. 1 (January 2008): 150–55. http://dx.doi.org/10.1134/s0020441208010211.

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8

Gor, Gennady Y., Patrick Huber, and Noam Bernstein. "Adsorption-induced deformation of nanoporous materials—A review." Applied Physics Reviews 4, no. 1 (March 2017): 011303. http://dx.doi.org/10.1063/1.4975001.

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9

Kowalczyk, Piotr, Sylwester Furmaniak, Piotr A. Gauden, and Artur P. Terzyk. "Carbon Dioxide Adsorption-Induced Deformation of Microporous Carbons." Journal of Physical Chemistry C 114, no. 11 (February 25, 2010): 5126–33. http://dx.doi.org/10.1021/jp911996h.

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10

Bakhshian, Sahar, and Seyyed A. Hosseini. "Prediction of CO2 adsorption-induced deformation in shale nanopores." Fuel 241 (April 2019): 767–76. http://dx.doi.org/10.1016/j.fuel.2018.12.095.

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11

Shkolin, A. V., A. A. Fomkin, and V. A. Sinitsyn. "Adsorption-induced deformation of AUK microporous carbon adsorbent in adsorption of n-pentane." Protection of Metals and Physical Chemistry of Surfaces 47, no. 5 (September 2011): 555–61. http://dx.doi.org/10.1134/s2070205111050157.

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12

Shkolin, A. V., A. A. Fomkin, I. E. Men’shchikov, A. L. Pulin, and V. Yu Yakovlev. "Adsorption-Induced and Thermal Deformation of Microporous Carbon Adsorbent upon n-Octane Adsorption." Colloid Journal 81, no. 6 (November 2019): 797–803. http://dx.doi.org/10.1134/s1061933x19060188.

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13

Shkolin, Andrey, Il’ya Men’shchikov, Elena Khozina, and Anatolii Fomkin. "In Situ Dilatometry Measurements of Deformation of Microporous Carbon Induced by Temperature and Carbon Dioxide Adsorption under High Pressures." Colloids and Interfaces 7, no. 2 (June 13, 2023): 46. http://dx.doi.org/10.3390/colloids7020046.

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Анотація:

Adsorption-based carbon dioxide capture, utilization, and storage technologies aim to mitigate the accumulation of anthropogenic greenhouse gases that cause climate change. It is assumed that porous carbons as adsorbents are able to demonstrate the effectiveness of these technologies over a wide range of temperatures and pressures. The present study aimed to investigate the temperature-induced changes in the dimensions of the microporous carbon adsorbent Sorbonorit 4, as well as the carbon dioxide adsorption, by using in situ dilatometry. The nonmonotonic changes in the dimensions of Sorbonorit 4 under vacuum were found with increasing temperature from 213 to 573 K. At T > 300 K, the thermal linear expansion coefficient of Sorbonorit 4 exceeded that of a graphite crystal, reaching 5 × 10−5 K at 573 K. The CO2 adsorption onto Sorbonorit 4 gave rise to its contraction at low temperatures and pressures or to its expansion at high temperatures over the entire pressure range. An inversion of the temperature dependence of the adsorption-induced deformation (AID) of Sorbonorit-4 was observed. The AID of Sorbonorit-4 and differential isosteric heat of CO2 adsorption plotted as a function of carbon dioxide uptake varied within the same intervals of adsorption values, reflecting the changes in the state of adsorbed molecules caused by contributions from adsorbate–adsorbent and adsorbate–adsorbate interactions. A simple model of nanoporous carbon adsorbents as randomly oriented nanocrystallites interconnected by a disordered carbon phase is proposed to represent the adsorption- and temperature-induced deformation of nanocrystallites with the macroscopic deformation of the adsorbent granules.

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14

Ludescher, Lukas, Roland Morak, Stephan Braxmeier, Florian Putz, Nicola Hüsing, Gudrun Reichenauer, and Oskar Paris. "Hierarchically organized materials with ordered mesopores: adsorption isotherm and adsorption-induced deformation from small-angle scattering." Physical Chemistry Chemical Physics 22, no. 22 (2020): 12713–23. http://dx.doi.org/10.1039/d0cp01026j.

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Apparent strain artifacts resulting from the evaluation of small-angle X-ray scattering data superimpose the actual adsorption induced deformation in silica with hierarchical porosity. These artifacts can be corrected for by detailed modelling.

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15

Zhang, Zun-Guo, Shu-Gang Cao, Yong Li, Ping Guo, Hongyun Yang, and Tao Yang. "Effect of moisture content on methane adsorption- and desorption-induced deformation of tectonically deformed coal." Adsorption Science & Technology 36, no. 9-10 (September 26, 2018): 1648–68. http://dx.doi.org/10.1177/0263617418800905.

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Intermolecular forces that act between moisture and the atoms of the coal structure have a significant influence on methane adsorption- and desorption-induced deformation in coal. After analyzing the porous characteristics and existing forms of moisture in coal, both the adsorption-induced swelling and the desorption-induced shrinkage deformation experiments were carried out under the conditions of varying moisture content, constant temperature, and variable equilibrium pressure. Both the swelling and shrinkage volumetric strains with different coal moisture contents were fitted by Langmuir-type equations in which the fitting coefficients were functions of the moisture content. It was found that there is a lag between the swelling curve and the corresponding shrinkage curve, and a variable known as the hysteresis rate was defined to illustrate this characteristic. A mathematical model of swelling and shrinkage deformation that considers the effect of moisture content was established based on the experimental results and analysis.

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16

Kolesnikov, A. L., Yu A. Budkov, and G. Y. Gor. "Adsorption-induced deformation of mesoporous materials with corrugated cylindrical pores." Journal of Chemical Physics 153, no. 19 (November 21, 2020): 194703. http://dx.doi.org/10.1063/5.0025473.

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17

Yang, Kan, Xiancai Lu, Yangzheng Lin, and Alexander V. Neimark. "Deformation of Coal Induced by Methane Adsorption at Geological Conditions." Energy & Fuels 24, no. 11 (November 18, 2010): 5955–64. http://dx.doi.org/10.1021/ef100769x.

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18

Shkolin, A. V., and A. A. Fomkin. "Deformation of AUK microporous carbon adsorbent induced by methane adsorption." Colloid Journal 71, no. 1 (February 2009): 119–24. http://dx.doi.org/10.1134/s1061933x09010153.

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19

Potapov, S. V., A. V. Shkolin, and A. A. Fomkin. "Deformation of AUK microporous carbon adsorbent induced by krypton adsorption." Colloid Journal 76, no. 3 (May 2014): 351–57. http://dx.doi.org/10.1134/s1061933x14020069.

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20

Shkolin, A. V., S. V. Potapov, and A. A. Fomkin. "Deformation of AUK microporous carbon adsorbent induced by xenon adsorption." Colloid Journal 77, no. 6 (November 2015): 812–20. http://dx.doi.org/10.1134/s1061933x15060204.

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21

Kowalczyk, Piotr, Alina Ciach, and Alexander V. Neimark. "Adsorption-Induced Deformation of Microporous Carbons: Pore Size Distribution Effect." Langmuir 24, no. 13 (July 2008): 6603–8. http://dx.doi.org/10.1021/la800406c.

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22

Li, He, Fangyuan Guo, Jun Hu, Changjun Peng, Hualin Wang, Honglai Liu, and Jing Li. "“Induced-Fit Suction” effect: a booster for biofuel storage and separation." Journal of Materials Chemistry A 7, no. 39 (2019): 22353–58. http://dx.doi.org/10.1039/c9ta06723j.

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23

Zhang, Beining, Weiguo Liang, Pathegama Ranjith, Wei He, Zhigang Li, and Xiaogang Zhang. "Effects of Coal Deformation on Different-Phase CO2 Permeability in Sub-Bituminous Coal: An Experimental Investigation." Energies 11, no. 11 (October 26, 2018): 2926. http://dx.doi.org/10.3390/en11112926.

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Coal deformation is one of the leading problems for carbon dioxide (CO2) sequestration in coal seams especially with respect to different-phase CO2 injection. In this paper, a series of core flooding tests were conducted under different confining stresses (8–20 MPa), injection pressures (1–15 MPa), and downstream pressures (0.1–10 MPa) at 50 °C temperature to investigate the effects of coal deformation induced by adsorption and effective stress on sub-critical, super-critical, and mixed-phase CO2 permeability. Due to the linear relationship between the mean flow rate and the pressure gradient, Darcy Law was applied on different-phase CO2 flow. Experimental results indicate that: (1) Under the same effective stress, sub-critical CO2 permeability > mixed-phase CO2 permeability > super-critical CO2 permeability. (2) For sub-critical CO2 flow, the initial volumetric strain is mainly attributed to adsorption-induced swelling. A temporary drop in permeability was observed. (3) For super-critical CO2 flow, when the injection pressure is over 10 MPa, effective-stress-generated deformation is dominant over the adsorption-induced strain and mainly contributes to the volumetric strain change. Thus, there is a linear increase of the volumetric strain with mean pore pressure and super-critical CO2 permeability increased with volumetric strain. (4) For mixed-phase CO2 flow, coupling effects of adsorption-induced swelling and effective stress on the volumetric strain were observed but effective stress made more of a contribution. CO2 permeability consistently increased with the volumetric strain. This paper reveals the swelling mechanism of different-phase CO2 injections and its effect on coal permeability.

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24

Gor, Gennady Y., and Noam Bernstein. "Revisiting Bangham's law of adsorption-induced deformation: changes of surface energy and surface stress." Physical Chemistry Chemical Physics 18, no. 14 (2016): 9788–98. http://dx.doi.org/10.1039/c6cp00051g.

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25

Kowalczyk, Piotr, Alina Ciach, Artur P. Terzyk, Piotr A. Gauden, and Sylwester Furmaniak. "Effects of Critical Fluctuations on Adsorption-Induced Deformation of Microporous Carbons." Journal of Physical Chemistry C 119, no. 11 (March 5, 2015): 6111–20. http://dx.doi.org/10.1021/acs.jpcc.5b00226.

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26

Coasne, Benoit, Coralie Weigel, Alain Polian, Mathieu Kint, Jérome Rouquette, Julien Haines, Marie Foret, René Vacher, and Benoit Rufflé. "Poroelastic Theory Applied to the Adsorption-Induced Deformation of Vitreous Silica." Journal of Physical Chemistry B 118, no. 49 (November 25, 2014): 14519–25. http://dx.doi.org/10.1021/jp5094383.

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27

Wang, Kai, Qichao Fu, Xiang Zhang, and Hengyi Jia. "Experimental Investigation on Strain Changes during CO2 Adsorption of Raw Coal Sample: Temperature and Effective Stress." Energies 14, no. 3 (January 30, 2021): 717. http://dx.doi.org/10.3390/en14030717.

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Анотація:

Through laboratory simulation experiments, this paper studies the influence of different temperature and stress conditions on strain changes of raw coal samples induced by the CO2 adsorption with tri-axial creep-seepage and adsorption-desorption experimental system. Comparing and analyzing the experimental results, the study shows that: (1) within a certain time, the axial and radial strain of the raw coal sample induced by CO2 adsorption both show a growing trend as the adsorption time increases and the strain of the raw coal sample for CO2 adsorption is obvious anisotropy; (2) at the same point in time, the greater the axial effective stress, the smaller the axial strain increasing rate of the loaded coal sample during CO2 adsorption process and the smaller the value of axial deformation; (3) during the adsorption process, the volume strain of raw coal sample decreases with the increasing of temperature, namely, the adsorption capacity of raw coal sample decreases with the increasing of temperature.

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28

Men’shchikov, Ilya, Andrey Shkolin, Elena Khozina, and Anatoly Fomkin. "Peculiarities of Thermodynamic Behaviors of Xenon Adsorption on the Activated Carbon Prepared from Silicon Carbide." Nanomaterials 11, no. 4 (April 9, 2021): 971. http://dx.doi.org/10.3390/nano11040971.

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An activated carbon prepared from silicon carbide by thermochemical synthesis and designated as SiC-AC was studied as an adsorbent for xenon. The examination of textural properties of the SiC-AC adsorbent by nitrogen vapor adsorption measurements at 77 K, powder X-ray diffraction, and scanning electron microscopy revealed a relatively homogeneous microporous structure, a low content of heteroatoms, and an absence of evident transport macropores. The study of xenon adsorption and adsorption-induced deformation of the Si-AC adsorbent over the temperature range of 178 to 393 K and pressures up to 6 MPa disclosed the contraction of the material up to −0.01%, followed by its expansion up to 0.49%. The data on temperature-induced deformation of Si-AC measured within the 260 to 575 K range was approximated by a linear function with a thermal expansion factor of (3 ± 0.15) × 10−6 K−1. These findings of the SiC-AC non-inertness taken together with the non-ideality of an equilibrium xenon gaseous phase allowed us to make accurate calculations of the differential isosteric heats of adsorption, entropy, enthalpy, and heat capacity of the Xe/SiC-AC adsorption system from the experimental adsorption data over the temperature range from 178 to 393 K and pressures up to 6 MPa. The variations in the thermodynamic state functions of the Xe/SiC-AC adsorption system with temperature and amount of adsorbed Xe were attributed to the transitions in the state of the adsorbate in the micropores of SiC-AC from the bound state near the high-energy adsorption sites to the molecular associates.

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29

Zhang, Chi, Mingyang Chen, Dominique Derome, and Jan Carmeliet. "Moisture-induced deformations of wood and shape memory." Journal of Physics: Conference Series 2069, no. 1 (November 1, 2021): 012012. http://dx.doi.org/10.1088/1742-6596/2069/1/012012.

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Abstract Wood is known to swell substantially during moisture adsorption and shrink during desorption. These deformations may lead to wood damage in the form of cracking and disjoining of wooden components in e.g. floor or windows. Two swelling mechanisms may be distinguished: reversible swelling/shrinkage and moisture-induced shape memory effect. In the latter, wood is deformed in the wet state and afterward dried under maintained deformation, in order that wood retains its deformed shape even after the removal of the mechanical loading, called fixation. When wood is wetted again, it loses its fixation, partially regains its original shape, called recovery. These two mechanisms have their origin at the nanoscale and are modelled here using atomistic simulation and after upscaled to continuum level allowing finite element modelling. Hysteretic sorption and swelling are explained at nanoscale by the opening and closing of sorption sites in ad-and desorption, where in desorption water molecules preferentially remained bonded at sorption sites. The moisture-induced shape memory is explained by the moisture-induced activation of the interfaces between the reinforcing crystalline cellulose fibres and its matrix at nanoscale, referred to as a molecular switch. Our work aims to highlight that the understanding of sorption-induced reversible deformation and moisture-induced shape memory may play an important role in wood engineering and in building physics applications.

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30

Gor, Gennady Yu, and Alexander V. Neimark. "Adsorption-Induced Deformation of Mesoporous Solids: Macroscopic Approach and Density Functional Theory." Langmuir 27, no. 11 (June 7, 2011): 6926–31. http://dx.doi.org/10.1021/la201271p.

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31

Diao, Rui, Chunyan Fan, D. D. Do, and D. Nicholson. "Monte Carlo Simulation of Adsorption-Induced Deformation in Finite Graphitic Slit Pores." Journal of Physical Chemistry C 120, no. 51 (December 15, 2016): 29272–82. http://dx.doi.org/10.1021/acs.jpcc.6b10135.

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32

Diao, Rui, Chunyan Fan, D. D. Do, and D. Nicholson. "Adsorption induced deformation in graphitic slit mesopores: A Monte Carlo simulation study." Chemical Engineering Journal 328 (November 2017): 280–92. http://dx.doi.org/10.1016/j.cej.2017.07.013.

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33

CHENG, YUAN, ZUOQI ZHANG, and ZHISHIUN TEO. "DEFORMATION OF GRAPHENE INDUCED BY ADSORPTION OF PEPTIDES: A MOLECULAR DYNAMICS STUDY." International Journal of Applied Mechanics 05, no. 01 (March 2013): 1350007. http://dx.doi.org/10.1142/s1758825113500075.

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Graphene has potential applications in a variety of fields including electronics, photonics and chemical-biosensing. In this study, we perform molecular dynamics (MD) simulations to study the interactions between graphene sheets and biomolecules. The bending behavior of graphene induced by adsorption of peptides is investigated. The influence of peptide size, number, and alignment on the deflection of graphene sheets is studied in detail. The van der Waals (VDW) interaction plays a dominant role in the interaction between peptides and graphene. Our study provides valuable information for the experimental design of nanodevices incorporating graphene with biomolecules.

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34

Tanaka, Hideki, and Minoru T. Miyahara. "Free energy calculations for adsorption-induced deformation of flexible metal–organic frameworks." Current Opinion in Chemical Engineering 24 (June 2019): 19–25. http://dx.doi.org/10.1016/j.coche.2019.01.001.

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35

Huang, Yingying, Hanlin Li, Liuyuan Zhu, Yongshun Song, and Haiping Fang. "Metal-Cation-Induced Tiny Ripple on Graphene." Nanomaterials 14, no. 19 (October 2, 2024): 1593. http://dx.doi.org/10.3390/nano14191593.

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Ripples on graphene play a crucial role in manipulating its physical and chemical properties. However, producing ripples, especially at the nanoscale, remains challenging with current experimental methods. In this study, we report that tiny ripples in graphene can be generated by the adsorption of a single metal cation (Na+, K+, Mg2+, Ca2+, Cu2+, Fe3+) onto a graphene sheet, based on the density functional theory calculations. We attribute this to the cation–π interaction between the metal cation and the aromatic rings on the graphene surface, which makes the carbon atoms closer to metal ions, causing deformation of the graphene sheet, especially in the out-of-plane direction, thereby creating ripples. The equivalent pressures applied to graphene sheets in out-of-plane direction, generated by metal cation–π interactions, reach magnitudes on the order of gigapascals (GPa). More importantly, the electronic and mechanical properties of graphene sheets are modified by the adsorption of various metal cations, resulting in opened bandgaps and enhanced rigidity characterized by a higher elastic modulus. These findings show great potential for applications for producing ripples at the nanoscale in graphene through the regulation of metal cation adsorption.

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36

Wang, Huping, Zhao Wang, Haikui Yin, Chao Jin, Xiaogang Zhang, and Langtao Liu. "CO2 Flow Characteristics in Macro-Scale Coal Sample: Effect of CO2 Injection Pressure and Buried Depth." Sustainability 15, no. 10 (May 14, 2023): 8002. http://dx.doi.org/10.3390/su15108002.

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Анотація:

Experimental studies have confirmed the permeability reduction of coal samples upon the adsorption of CO2. However, these studies were carried out under limited experimental conditions. In this study, CO2 flow behaviors in a macro-scale coal sample were numerically simulated using a coupled gas flow, mechanical deformation, and sorption-induced deformation finite element model. The simulation results show that the effect of the reduction of effective stress on the enhancement of permeability is greater than the negative effect of permeability reduction due to CO2 adsorption for low injection pressures. CO2 pressure development in the sample increases with increasing injection pressure due to the enhanced advection flux for sub-critical CO2 injections, while for super-critical CO2 injections, CO2 pressure development, as well as concentrations in the sample, decreases compared to sub-critical CO2 injections because of greater density and viscosity of super-critical CO2 as well as coal matrix swelling induced by the adsorption of super-critical CO2. Increasing axial stress (buried depth) obstructs CO2 migration in the sample due to the increased effective stress, and this effect is more influential for low injection pressures, which indicates that high CO2 injection pressures are preferred for CO2 sequestration in deep coal seams.

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37

Li, Chao Jun, and Ji Li Feng. "Finite Poroelasticity with Surface Effect." Applied Mechanics and Materials 670-671 (October 2014): 646–50. http://dx.doi.org/10.4028/www.scientific.net/amm.670-671.646.

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This paper presents a consistent theoretical framework for describing the finite poroelasticity with surface effect. The underlying concept of additional pressure that is thought of as an equivalent thermodynamic pressure applying on the pore surface is used to detail the pore pressure. A nonlinear porosity laws is proposed for the finite deformation of porous material. With surface effect consideration, the corresponding constitutive equations are developed. The present model for both the swelling of the matrix and the permeability change of coal induced by adsorption of CO2 and CH4 are presented under different pressure conditions. It is shown that the predictions from the model are good agreement with the experimental data of sorption-induced deformation of coals.

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38

Balzer, Christian, Anna M. Waag, Stefan Gehret, Gudrun Reichenauer, Florian Putz, Nicola Hüsing, Oskar Paris, Noam Bernstein, Gennady Y. Gor, and Alexander V. Neimark. "Adsorption-Induced Deformation of Hierarchically Structured Mesoporous Silica—Effect of Pore-Level Anisotropy." Langmuir 33, no. 22 (May 26, 2017): 5592–602. http://dx.doi.org/10.1021/acs.langmuir.7b00468.

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39

Cornette, Valeria, J. C. Alexandre de Oliveira, Víctor Yelpo, Diana Azevedo, and Raúl H. López. "Binary gas mixture adsorption-induced deformation of microporous carbons by Monte Carlo simulation." Journal of Colloid and Interface Science 522 (July 2018): 291–98. http://dx.doi.org/10.1016/j.jcis.2018.03.026.

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40

Zeng, Yonghong, Lumeng Liu, Han Zhang, D. D. Do, and D. Nicholson. "A Monte Carlo study of adsorption-induced deformation in wedge-shaped graphitic micropores." Chemical Engineering Journal 346 (August 2018): 672–81. http://dx.doi.org/10.1016/j.cej.2018.04.076.

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41

Liu, Huihui, Baiquan Lin, and Wei Yang. "Theoretical models for gas adsorption‐induced coal deformation under coal seam field conditions." Energy Science & Engineering 7, no. 5 (July 9, 2019): 1504–13. http://dx.doi.org/10.1002/ese3.393.

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42

Li-wei, Chen, Wang Lin, Yang Tian-hong, and Yang Hong-min. "Deformation and swelling of coal induced from competitive adsorption of CH4/CO2/N2." Fuel 286 (February 2021): 119356. http://dx.doi.org/10.1016/j.fuel.2020.119356.

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43

Wang, Ran, Xianbo Su, Shiyao Yu, Linan Su, Jie Hou, and Qian Wang. "Experimental Investigation of the Thermal Expansion Characteristics of Anthracite Coal Induced by Gas Adsorption." Adsorption Science & Technology 2023 (February 22, 2023): 1–7. http://dx.doi.org/10.1155/2023/5201794.

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Анотація:

The coal matrix can expand after gas adsorption, thus reducing the permeability of coal reservoirs and further affecting the coalbed methane production. Whether the heat released by coal adsorbing gas is a cause of the coal expansion has not yet been determined. Therefore, the anthracite coal with high gas adsorption capacity was used; under the conditions of 35°C and 1-6 MPa, the adsorption capacity and the adsorption heat of coal adsorbing CO2 and CH4 were tested. The specific heat capacity and thermal expansion coefficient of coal at 35°C were tested. The temperature change of the coal after being heated was calculated by combining the absorption heat and specific heat capacity; also, the thermal expansion rate was calculated by combining the temperature change and expansion coefficient. In addition, the cube law was used to calculate the permeability change of coal before and after the adsorption expansion. The results show that the changes in the gas adsorption capacity and adsorption heat of the coal obey the Langmuir equation, and those to CO2 are both higher than to CH4. The temperature of coal increases after the heat is released in the process of CO2 and CH4 adsorption, and the temperature change of coal adsorbing CO2 and CH4 reaches 102°C and 72°C, respectively, at 6 MPa. The thermal expansion rate of coal adsorbing CO2 and CH4 reaches 5.40% and 3.81%, at 6 MPa, respectively. It is found that a higher gas pressure could lead to a higher temperature change, a higher thermal expansion rate, as well as a higher thermal expansion and coal deformation. After the adsorption of CO2 and CH4, the coal permeability is reduced by 20.43% and 14.66%, respectively, at 6 MPa. Both the thermal expansion rate and the permeability change with the gas adsorption pressure obey the Langmuir equation. Therefore, the adsorption expansion of coal may be thermal expansion caused by the heat released by coal adsorbing gas.

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44

Perrier, L., F. Plantier, and D. Grégoire. "A novel experimental setup for simultaneous adsorption and induced deformation measurements in microporous materials." Review of Scientific Instruments 88, no. 3 (March 2017): 035104. http://dx.doi.org/10.1063/1.4977595.

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45

Neimark, Alexander V., and Ivan Grenev. "Adsorption-Induced Deformation of Microporous Solids: A New Insight from a Century-Old Theory." Journal of Physical Chemistry C 124, no. 1 (December 5, 2019): 749–55. http://dx.doi.org/10.1021/acs.jpcc.9b10053.

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46

Zhou, Yinbo, Zenghua Li, Yongliang Yang, Mian Wang, Fanjun Gu, and Huaijun Ji. "Effect of adsorption-induced matrix deformation on coalbed methane transport analyzed using fractal theory." Journal of Natural Gas Science and Engineering 26 (September 2015): 840–46. http://dx.doi.org/10.1016/j.jngse.2015.07.013.

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47

Wei, Mingyao, Jishan Liu, Derek Elsworth, Shaojun Li, and Fubao Zhou. "Influence of gas adsorption induced non-uniform deformation on the evolution of coal permeability." International Journal of Rock Mechanics and Mining Sciences 114 (February 2019): 71–78. http://dx.doi.org/10.1016/j.ijrmms.2018.12.021.

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48

Takasaki, Yuichi, and Satoshi Takamizawa. "Reversible crystal deformation of a single-crystal host of copper(ii) 1-naphthoate—pyrazine through crystal phase transition induced by methanol vapor sorption." Chemical Communications 51, no. 24 (2015): 5024–27. http://dx.doi.org/10.1039/c4cc09948f.

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49

Ao, Xiang, Baobao Wang, Yuxi Rao, Lang Zhang, Yu Wang, and Hongkun Tang. "Effect of CO2 Corrosion and Adsorption-Induced Strain on Permeability of Oil Shale: Numerical Simulation." Energies 16, no. 2 (January 9, 2023): 780. http://dx.doi.org/10.3390/en16020780.

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Анотація:

Permeability is a crucial parameter for enhancing shale oil recovery through CO2 injection in oil-bearing shale. After CO2 is injected into the shale reservoir, CO2 corrosion and adsorption-induced strain can change the permeability of the oil shale, affecting the recovery of shale oil. This study aimed to explore the influence of CO2 corrosion and adsorption-induced strain on the permeability of oil shale. The deformation of the internal pore diameter of oil shale induced by CO2 corrosion under different pressures was measured by low-pressure nitrogen gas adsorption in the laboratory, and the corrosion model was fitted using the experimental data. Following the basic definitions of permeability and porosity, a dynamic mathematical model of porosity and permeability was obtained, and a fluid–solid coupling mathematical model of CO2-containing oil shale was established according to the basic theory of fluid–solid coupling. Then the effects of adsorption expansion strain and corrosion compression strain on permeability evolution were considered to improve the accuracy of the oil shale permeability model. The numerical simulation results showed that adsorption expansion strain, corrosion compression strain, and confining pressure are the important factors controlling the permeability evolution of oil shale. In addition, adsorption expansion strain and corrosion compression strain have different effects under different fluid pressures. In the low-pressure zone, the adsorption expansion strain decreases the permeability of oil shale with increasing pressure. In the high-pressure zone, the increase in pressure decreases the influence of expansion strain while permeability gradually recovers. The compressive strain increases slowly with increasing pressure in the low-pressure zone, slowly increasing oil shale permeability. However, in the high-pressure area, the increase in pressure gradually weakens the influence of corrosion compressive strain, and the permeability of oil shale gradually recovers.

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50

Azizi, Ali, and Sadollah Ebrahimi. "Uniaxial-Strain Effects in the Paclitaxel Drug Molecule Adsorption on Nitrogen-Doped Graphene." International Journal of Nanoscience 16, no. 02 (August 15, 2016): 1650027. http://dx.doi.org/10.1142/s0219581x16500277.

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It has been recently investigated [A. Azizi and S. Ebrahimi, Nano 9, 1450088 (2004).] the Paclitaxel (PTX) anticancer drug molecule adsorption on nitrogen doped graphene (NG). However, the surface strain effect on adsorption is not considered in the literature. In this study, using molecular dynamics (MD) simulation, we show that the PTX molecule adsorption can be tuned by exploiting the rippling effect of the strained NG. The dependence of the nitrogen concentration in the presence of ripples on the surface, arising due to thermal fluctuations, is examined. We have also considered the connection between the average distance of PTX from NG surface and the maximum induced deformation on the surface structure. It is demonstrated that the average distance of PTX from NG is increased with increasing the strain until a critical value is reached, and then it has remained almost constant. To this end, the dependence of the degree of ripple-type distortion of the surface on the PTX adsorption is investigated.

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