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Готові списки джерел за темами / Cation hydronium / Статті в журналах

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Статті в журналах з теми "Cation hydronium"

Автор: Grafiati

Опубліковано: 3 червня 2025

Оновлено: 31 липня 2025

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1

Wallace, Sonjae, Lulu Huang, Chérif F. Matta, Lou Massa, and Ivan Bernal. "New structures of hydronium cation clusters." Comptes Rendus Chimie 15, no. 8 (2012): 700–707. http://dx.doi.org/10.1016/j.crci.2012.04.010.

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2

Akbari, Saeed, Mohammad Taghi Hamed Mosavian, Fatemeh Moosavi, and Ali Ahmadpour. "Elucidating the morphological aspects and proton dynamics in a hybrid perfluorosulfonic acid membrane for medium-temperature fuel cell applications." Physical Chemistry Chemical Physics 20, no. 47 (2018): 29778–89. http://dx.doi.org/10.1039/c8cp05377d.

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3

Ma, Jun, Shinichi Yamashita, Yusa Muroya, Yosuke Katsumura, and Mehran Mostafavi. "Deciphering the reaction between a hydrated electron and a hydronium ion at elevated temperatures." Physical Chemistry Chemical Physics 17, no. 35 (2015): 22934–39. http://dx.doi.org/10.1039/c5cp04293c.

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4

Yoo, Suhwan, Sejin Park, and Yun Jeong Hwang. "Exploring the Impact of Excess Cations in Acidic CO₂ Reduction Reaction." ECS Meeting Abstracts MA2024-02, no. 61 (2024): 4134. https://doi.org/10.1149/ma2024-02614134mtgabs.

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Анотація:

To anticipate high performance in the electrocatalytic reactions, a comprehensive understanding of the electric double layer (EDL) is essential. Experimental, spectroscopic, and computational studies of the EDL have been reported for understanding the performance in electrocatalytic reactions such as the hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and CO2 reduction reaction (CO2RR). Notably, in the CO2RR, previous studies have revealed the accumulation of cations near the outer Helmholtz plane (OHP) significantly has an impact on the reaction performance, product select

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5

Bialonska, Agata, and Ivan Bernal. "A new cyclic hydronium di-cation of composition H18O82+." Comptes Rendus Chimie 10, no. 3 (2007): 232–33. http://dx.doi.org/10.1016/j.crci.2006.10.005.

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6

Escamilla-Roa, Elizabeth, Fernando Nieto, and C. Ignacio Sainz-Díaz. "Stability of the Hydronium Cation in the Structure of Illite." Clays and Clay Minerals 64, no. 4 (2016): 413–24. http://dx.doi.org/10.1346/ccmn.2016.0640406.

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7

Chênevert, Robert, Daniel Chamberland, Michel Simard, and François Brisse. "The crystal and molecular structures of two isostructural complexes: [(H3O•18-crown-6)2(ZnCl4)] and [(H3O•18-crown-6)2(MnCl4)]." Canadian Journal of Chemistry 68, no. 6 (1990): 797–803. http://dx.doi.org/10.1139/v90-127.

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New macrocycle polyether 18-crown-6 complexes of stoichiometry [(H3O+•18-crown-6)2(MC42−)] have been synthesized for M = Zn and Mn. The two complexes are isostructural and crystallize in the monoclinic system, space group C2/c. The unit cell dimensions are as follows: a = 16.229(9), b = 11.535(3), c = 20.134(8) Å, β = 97.55(4)° and a = 16.255(6), b = 11.625(3), c = 20.122(8) Å, β = 96.54(3)° for the Zn and Mn complexes respectively. In both crystal structures (final Rw = 0.048 with 1817 reflections for Zn and Rw = 0.074 with 728 reflections for Mn), the crown ether molecule and the H3O+ cation

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8

Mendes, Ricardo F., Nutalapati Venkatramaiah, João P. C. Tomé, and Filipe A. Almeida Paz. "Crystal structure of a compact three-dimensional metal–organic framework based on Cs+and (4,5-dicyano-1,2-phenylene)bis(phosphonic acid)." Acta Crystallographica Section E Crystallographic Communications 72, no. 12 (2016): 1794–98. http://dx.doi.org/10.1107/s2056989016016765.

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A new metal–organic framework compound, poly[[μ7-dihydrogen (4,5-dicyano-1,2-phenylene)diphosphonato](oxonium)caesium], [Cs(C8H4N2O6P2)(H3O)]n(I), based on Cs+and the organic linker 4,5-dicyano-1,2-phenylene)bis(phosphonic acid, (H4cpp), containing two distinct coordinating functional groups, has been prepared by a simple diffusion method and its crystal structure is reported. The coordination polymeric structure is based on a CsO8N2complex unit comprising a monodentate hydronium cation, seven O-atom donors from two phosphonium groups of the (H2cpp)2−ligand, and two N-atom donors from bridging

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9

Kolesnikov, Alexander V., and Egor I. Ageenko. "Discharge of hydronium ions on metal cathodes in the presence of pyridine." Butlerov Communications 63, no. 8 (2020): 58–63. http://dx.doi.org/10.37952/roi-jbc-01/20-63-8-58.

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In this work, studies have been carried out on the electrochemical reduction of hydrogen (hydronium ion) from acidic aqueous solutions in the presence of an organic substance – pyridine. Electrolysis was carried out in an electrolyte with a sulfuric acid content (0.18; 0.36 M) with a pyridine additions of 8.4·10-3 M. Potentiostatic studies were carried out on a Potentiostat P-30Jcom Elins potentiostat using a three-electrode cell. Working electrodes (cathodes) were made of M1 copper with an area (S) of 0.09 cm2; aluminum (AD1) S – 0.125 cm2, zinc (Ts0A) S – 0.35 cm2, lead (Cl) S – 0.20 cm2, au

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10

Poyraz, Altug S., Jianping Huang, Bingjie Zhang, Amy C. Marschilok, Kenneth J. Takeuchi, and Esther S. Takeuchi. "Synthesis of Cation and Water Free Cryptomelane Type OMS-2 Cathode Materials: The Impact of Tunnel Water on Electrochemistry." MRS Advances 2, no. 7 (2017): 407–12. http://dx.doi.org/10.1557/adv.2017.68.

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ABSTRACTCryptomelane type manganese dioxides (α-MnO2, OMS-2) are interesting potential cathode materials due to the ability of their one dimensional (1D) tunnels to reversibly host various cations including Li+ and an accessible stable 3+/4+ redox couple. Here, we synthesized metal cation free OMS-2 materials where the tunnels were occupied by only water and hydronium ions. Water was subsequently removed from the tunnels. Cation free OMS-2 and Dry-OMS-2 were used as cathodes in Li based batteries to investigate the role of tunnel water on their electrochemistry. The initial discharge capacity

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11

GUO, JING-DONG, and M. STANLEY WHITTINGHAM. "TUNGSTEN OXIDES AND BRONZES: SYNTHESIS, DIFFUSION AND REACTIVITY." International Journal of Modern Physics B 07, no. 23n24 (1993): 4145–64. http://dx.doi.org/10.1142/s0217979293003607.

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The tungsten oxides and bronzes have been extensively studied since their discovery in the last century, because of their brilliant colors and high electrical conductivity. More recently the driving interest resulted from their potential use in electrochromic displays and other electrochemical systems. Their crystalline structures are generally based on the corner sharing of WO 6 octahedra giving tunnels of variable size and shape leading to exciting intercalation chemistry. These structures readily undergo redox reactions, and in the last quarter century these reactions have often involved so

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12

Sukiasyan, R. P., A. A. Danghyan, R. A. Apreyan, N. S. Gharibyan, and A. K. Atanesyan. "(H₃O)Li₂(IO₃)₃: crystal structure and IR spectrum." Journal of Instrumentation 19, no. 04 (2024): C04018. http://dx.doi.org/10.1088/1748-0221/19/04/c04018.

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Abstract The synthesis, IR spectroscopy, thermal and UV-Vis transmittance of the new lithium iodate crystal: (H3O)Li2(IO3)3, were studied. The crystal structure of (H3O)+·2(Li)+· 3(IO3)- was determined by single-crystal X-Ray diffraction analysis at 100(2) K. It crystallizes in the monoclinic system (P21/n) with the parameters: a = 8.3266(12) Å, b = 10.9893(17) Å, c = 11.2472(17) Å, α = γ = 90°, β = 111.360(4)° and Z(Z') = 4(1). The structure contains a hydronium cation (H3O)+, three crystallographic independent trigonal pyramidal IO3 anions, and two independent cations (Li)+ coordinated each

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13

Lin, M. F., N. Singh, S. Liang, et al. "Imaging the short-lived hydroxyl-hydronium pair in ionized liquid water." Science 374, no. 6563 (2021): 92–95. http://dx.doi.org/10.1126/science.abg3091.

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Capturing OH(H 3 O + ) in ionized water Recent advances in liquid-phase ultrafast electron diffraction techniques make it possible to observe what has only been theoretically presumed to occur at short times upon interaction of ionizing radiation with liquid water. Lin et al . provide direct evidence for capturing the short-lived radical-cation pair OH(H 3 O + ), which has been hypothesized for years to form after ionization of liquid water but was not structurally resolved previously (see the Perspective by Cao et al .). The authors trace dissociation and subsequent nonradiative structural re

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14

Takeoka, S., A. Kitada, K. Fukami, and K. Murase. "An Ionic Liquid Consisting of Crown Ether - Coordinated Hydronium Cation and Amide Anion." ECS Transactions 75, no. 15 (2016): 239–44. http://dx.doi.org/10.1149/07515.0239ecst.

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15

Córdova-Mateo, Esther, Oscar Bertran, Carlos A. Ferreira, and Carlos Alemán. "Transport of hydronium ions inside poly(styrene-co-divinyl benzene) cation exchange membranes." Journal of Membrane Science 428 (February 2013): 393–402. http://dx.doi.org/10.1016/j.memsci.2012.10.048.

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16

Jones, J., та A. J. Kresge. "Vinyl ether hydrolysis XXVIII. The mechanism of reaction of methyl α-(2,6-dimethoxyphenyl)vinyl ether". Canadian Journal of Chemistry 71, № 1 (1993): 38–41. http://dx.doi.org/10.1139/v93-006.

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The acid-catalyzed hydrolysis of methyl α-(2,6-dimethoxyphenyl)vinyl ether in aqueous solution at 25 °C occurs with the hydronium ion catalytic coefficient [Formula: see text] and gives the solvent isotope effect [Formula: see text] this indicates that reaction occurs by rate-determining proton transfer from the catalyst to the substrate to generate an alkoxycarbocation intermediate. An oxygen-18 tracer study shows further that, despite the steric hindrance provided by its two ortho substituents, this cation then reacts by addition of water to the cationic carbon atom to generate a hemiacetal,

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17

Zhou, Chao, Chunda Ji, Yuchen Nie, Jingfa Yang, and Jiang Zhao. "Poly(ethylene oxide) Is Positively Charged in Aqueous Solutions." Gels 8, no. 4 (2022): 213. http://dx.doi.org/10.3390/gels8040213.

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There have been controversies about the binding of cations to poly(ethylene oxide) (PEO) chains in aqueous solutions. In the current study, single molecular evidence of charging PEO chains by cation binding in aqueous solutions is provided. From the adoption of the photon-counting histogram method, it is discovered that the local pH value at the vicinity of the PEO chain is higher than the bulk solution, showing that the PEO chain is positively charged. Such a situation exists with and without the presence of salt (NaCl) in the solution, presumably due to the binding of cations, such as hydron

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18

Bernal, Ivan, Uday Mukhopadhyay, Alexander V. Virovets, Vladimir P. Fedin, and William Clegg. "A previously unrecognised hydronium di-cation in the crystal structure of a cucurbituril derivative." Chemical Communications, no. 30 (2005): 3791. http://dx.doi.org/10.1039/b505641c.

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19

Shingaya, Y., and M. Ito. "Coordination number and molecular orientation of hydronium cation/bisulfate anion adlayers on Pt(111)." Surface Science 368, no. 1-3 (1996): 318–23. http://dx.doi.org/10.1016/s0039-6028(96)01069-2.

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20

Pichugina, A., and V. Lutsik. "Investigation of the mechanism of hydrolytic dissolution of nickel sulfide in dilute sulfuric acid." Bulletin of Science and Practice, no. 12 (December 11, 2017): 84–89. https://doi.org/10.5281/zenodo.1101165.

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The paper presents the results a study of the hydrolytic mechanism of dissolution of Nickel sulfide in dilute solutions of sulfuric acid. According to the obtained mathematical model of sulfide dissolution are established modes of interaction, determined by the details of the mechanism of the studied processes. Proposed relevant observable kinetic dependences reasonable schemes of interaction. Received rentgenospektralny spectra and STM images of the surface of Nickel sulfide. A mechanism is hydrolytic. The process is not accompanied by oxidation of sulfide sulfur. The limiting stage of hydrol

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21

Berger, Raphael J. F. "The Smallest “Aurophilic Species”." Zeitschrift für Naturforschung B 64, no. 4 (2009): 388–94. http://dx.doi.org/10.1515/znb-2009-0405.

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The existence of the C2v symmetric closed-shell di[gold(I)]hydronium cation [Au2H]+ (1), is predicted. It is shown that 1 is the smallest possible molecular species containing aurophilic contacts. Equilibrium structural parameters, vibrational frequencies and formation energies of 1 from Au+ and AuH, have been calculated, employing a series of highly correlated but available standard relativistic ab initio methods up to CCSD(T) level of theory and all-electron basis sets of quadruple-ζ quality with double polarizations. Relativistic effects have been taken into account by employing pseudorelat

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22

Mumah, S. N., and H.F. Nwafulugo F.U. &. Alexander S. Akande. "PARTIAL PRESSURE, VISCOSITY AND DENSITY CORELLATIONS FOR AQUEOUS HYDROCHLORIC ACID FOR VARIOUS TEMPERATURES AND PRESSURES." Nigerian Journal of Renewable Energy Research 1, no. 3 (2025): 163–78. https://doi.org/10.5281/zenodo.15030700.

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<em>A comprehensive thermodynamic model is developed for the HCl-H<sub>2</sub>O binary system based on the electrolyte nonrandom two-liquid activity coefficient model. Partial dissociation of electrolyte HCl to hydronium cation and chloride anion is incorporated to account for the true species in solution. Regressed from extensive thermodynamic data, the model parameters include molecule-molecule and molecule-electrolyte binary interactions parameters, as well as the chemical equilibrium constant parameters of the partial dissociation solution chemistry. The model accurately calculates all pha

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23

Dyer, A., S. Amini, H. Enamy, H. A. El-Naggar, and M. W. Anderson. "Cation-exchange in synthetic zeolite L: The exchange of hydronium and ammonium ions by alkali metal and alkaline earth cations." Zeolites 13, no. 4 (1993): 281–90. http://dx.doi.org/10.1016/0144-2449(93)90007-p.

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24

Park, Man, Hong-Jin Kim, Kwang Seop Kim, Owen W. Duckworth, and Sridhar Komarneni. "Hydronium-Promoted Equilibrium Mechanism for the Alkali Metal Cation Exchange Reaction in Na-4-Mica." Journal of Physical Chemistry C 116, no. 35 (2012): 18678–83. http://dx.doi.org/10.1021/jp300759n.

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25

Paek, Mi-Jeong, Tae Woo Kim, and Seong-Ju Hwang. "Effects of hydronium intercalation and cation substitution on the photocatalytic performance of layered titanium oxide." Journal of Physics and Chemistry of Solids 69, no. 5-6 (2008): 1444–46. http://dx.doi.org/10.1016/j.jpcs.2007.09.012.

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26

Huang, Lulu, Chérif F. Matta, Sonjae Wallace, Lou Massa, and Ivan Bernal. "A unique trapping by crystal forces of a hydronium cation displaying a transition state structure." Comptes Rendus Chimie 18, no. 5 (2015): 511–15. http://dx.doi.org/10.1016/j.crci.2014.10.008.

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27

Roszak, S. "An ab initio configuration interaction study of deprotonation and dehydrogenation pathways of the hydronium cation." Chemical Physics Letters 250, no. 2 (1996): 187–91. http://dx.doi.org/10.1016/0009-2614(95)01452-7.

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28

Crugeiras, Juan, and Howard Maskill. "The 4,4'-dimethoxytrityl carbenium ion by ionization of 4,4'-dimethoxytrityl alcohol in acetonitrile - aqueous perchloric and nitric acids containing electrolytes: kinetics, equilibria, and ion-pair formation." Canadian Journal of Chemistry 77, no. 5-6 (1999): 530–36. http://dx.doi.org/10.1139/v99-003.

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We have studied the equilibration shown in eq. [3] of 4,4prime-dimethoxytrityl alcohol in aqueous perchloric and nitric acids containing low proportions of acetonitrile using stopped-flow kinetics techniques. The rate constants for the overall progress to equilibrium, kobs, have been resolved into forward and reverse components using the equilibrium UV absorbance and a value for the molar absorptivity of the 4,4prime-dimethoxytrityl carbenium ion determined in concentrated aqueous perchloric acid. The forward reaction (rate constant kf) is first order in both the alcohol and the acid concentra

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29

Pfriem, Niklas, Peter H. Hintermeier, Sebastian Eckstein, et al. "Role of the ionic environment in enhancing the activity of reacting molecules in zeolite pores." Science 372, no. 6545 (2021): 952–57. http://dx.doi.org/10.1126/science.abh3418.

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Tailoring the molecular environment around catalytically active sites allows for the enhancement of catalytic reactivity through a hitherto unexplored pathway. In zeolites, the presence of water creates an ionic environment via the formation of hydrated hydronium ions and the negatively charged framework aluminum tetrahedra. The high density of cation-anion pairs determined by the aluminum concentration of a zeolite induces a high local ionic strength that increases the excess chemical potential of sorbed and uncharged organic reactants. Charged transition states (carbocations for example) are

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30

Gui, Daxiang, Wanchun Duan, Jie Shu, et al. "Persistent Superprotonic Conductivity in the Order of 10−1 S·cm−1 Achieved Through Thermally Induced Structural Transformation of a Uranyl Coordination Polymer." CCS Chemistry 1, no. 2 (2019): 197–206. http://dx.doi.org/10.31635/ccschem.019.20190004.

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Despite tremendous efforts having been made in the exploration of new high-performance proton-conducting materials, systems with superprotonic conductivity higher than 10−1 S·cm−1 are scarcely reported. We show here the utilization of bridging uranyl oxo atoms, traditionally termed cation–cation interaction (CCI), as the hydrogen bond acceptor to build a dense and ordered hydrogen bond network, affording a unique uranyl-based proton-conducting coordination polymer (H3O)4UO2(PO4)2 (HUP-1). This compound contains a densely connected hydronium network that is substantially stabilized by uranyl ox

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31

Buek, Connor, Qiang Sun, Fan Yang, et al. "In-Operando Electrochemical Impedance Spectroscopy Response to Cation Poisoning in Proton Exchange Membrane Water Electrolyzers." ECS Meeting Abstracts MA2025-01, no. 38 (2025): 1811. https://doi.org/10.1149/ma2025-01381811mtgabs.

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Proton exchange membrane water electrolysis (PEMWE) is a promising technology for the efficient production of hydrogen, a clean and sustainable energy carrier along with multiple industrial applications. One of the most critical issues that can arise during the electrochemical production of green hydrogen is cation contamination in the membrane electrode assembly (MEA). Some sources of contamination include impurities from feed water, corrosion of system, leaching of ionic species in stack components, and contaminates introduced during manufacturing. Typically, the solid electrolyte contains s

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32

Demes, Sándor, François Lique, Alexandre Faure, Floris F. S. van der Tak, Claire Rist, and Pierre Hily-Blant. "Rotational excitation of H3O+ cations by para-H2: improved collisional data at low temperatures." Monthly Notices of the Royal Astronomical Society 509, no. 1 (2021): 1252–61. http://dx.doi.org/10.1093/mnras/stab3015.

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ABSTRACT The hydronium cation plays a crucial role in interstellar oxygen and water chemistry. While its spectroscopy was extensively investigated earlier, the collisional excitation of H3O+ is not well studied yet. In this work, we present state-to-state collisional data for the rotational de-excitation of both ortho- and para-H3O+ due to para-H2 impact. The cross sections are calculated within the close-coupling formalism using our recent, highly accurate, rigid-rotor potential energy surface for this collision system. The corresponding thermal rate coefficients are computed up to 100 K. For

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33

Tao, Fu-Ming, and Yuh-kang Pan. "Theoretical study of the protonated hydronium radical cation H40+ as a rydberg molecule. The ground state." Chemical Physics 136, no. 1 (1989): 95–103. http://dx.doi.org/10.1016/0301-0104(89)80131-4.

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34

Kennedy, Alan R., Linda K. Conway, Jennifer B. A. Kirkhouse, et al. "Monosulfonated Azo Dyes: A Crystallographic Study of the Molecular Structures of the Free Acid, Anionic and Dianionic Forms." Crystals 10, no. 8 (2020): 662. http://dx.doi.org/10.3390/cryst10080662.

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Crystallographic studies of monosulfonated azo dyes have concentrated on the salt forms that contain the azo anion. Here we present a study that compares the structures of these anions with protonated free acid forms and with doubly deprotonated dianion forms. To this end, the new single crystal diffraction structures of 13 systematically related free acid forms of monosulfonated azo dyes are presented, together with three new structures of doubly deprotonated forms and two new structures of Na salt forms of azo anions. No structures of dideprotonated monosulfonated azo dyes have previously be

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35

Mason, Kyle A., Adam C. Pearcy, Ahmed M. Hamid, and M. Samy El-Shall. "Structures of benzonitrile dimer radical cation and the protonated dimer: Observation of hydronium ion core solvated by benzonitrile molecules." Journal of Chemical Physics 150, no. 12 (2019): 124303. http://dx.doi.org/10.1063/1.5094648.

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36

Zelovich, Tamar, and Mark E. Tuckerman. "(Invited) First-Principles Molecular Dynamics Investigations of Proton and Hydroxide Transport in Model Anion-Exchange- and Proton-Exchange Membranes in Nanoconfined, Low-Hydration Environments." ECS Meeting Abstracts MA2023-01, no. 45 (2023): 2473. http://dx.doi.org/10.1149/ma2023-01452473mtgabs.

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Fuel cell-based anion-exchange membranes (AEMs) and proton exchange membranes (PEMs) have considerable potential as cost-effective, clean energy conversion devices. However, a fundamental atomistic understanding of the hydroxide and hydronium diffusion mechanisms in AEM and PEM environments is an ongoing challenge. In recent years, nano-confined structures have been exploited in the study of cost-effective and reliable polymer architectures for electrochemical devices. In this study, first-principles molecular dynamics simulations are employed to investigate the influence of the water distribu

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37

MIURA, Yasuyuki, Hirokazu OHNO, and Tomozo KOH. "Ion chromatographic determination of acetic, valeric, lactic and formic acids by means of decrease in their conductivity with cation-exchange micro membrane suppressor in hydronium form." Bunseki kagaku 43, no. 10 (1994): 745–49. http://dx.doi.org/10.2116/bunsekikagaku.43.745.

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38

Durán Caballero, Laura, Christoph Schran, Fabien Brieuc, and Dominik Marx. "Neural network interaction potentials for para-hydrogen with flexible molecules." Journal of Chemical Physics 157, no. 7 (2022): 074302. http://dx.doi.org/10.1063/5.0100953.

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The study of molecular impurities in para-hydrogen ( pH2) clusters is key to push forward our understanding of intra- and intermolecular interactions, including their impact on the superfluid response of this bosonic quantum solvent. This includes tagging with only one or very few pH2, the microsolvation regime for intermediate particle numbers, and matrix isolation with many solvent molecules. However, the fundamental coupling between the bosonic pH2 environment and the (ro-)vibrational motion of molecular impurities remains poorly understood. Quantum simulations can, in principle, provide th

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39

Kulikov, Vladislav, and Gerd Meyer. "Dihydronium tetrachromate(VI), (H3O)2Cr4O13." Acta Crystallographica Section E Structure Reports Online 69, no. 2 (2013): i13. http://dx.doi.org/10.1107/s1600536813001608.

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The crystal structure of (H3O)2Cr4O13is isotypic with K2Cr4O13. The finite tetrachromate anion in the title structure consists of four vertex-sharing CrO4tetrahedra and exhibits a typical zigzag arrangement. The crystal packing is stabilized by hydrogen bonds between these anions and hydronium cations. The two different hydronium cations are surrounded by nine O atoms of tetrachromate anions, with O...O distances ranging between 2.866 (8) and 3.282 (7) Å.

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40

Bunge, A. L., and C. J. Radke. "The Origin of Reversible Hydroxide Uptake on Reservoir Rock." Society of Petroleum Engineers Journal 25, no. 05 (1985): 711–18. http://dx.doi.org/10.2118/11798-pa.

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Abstract When reservoir solids reversibly consume hydroxide, the impact on alkaline-waterflood performance can be significant. Only recently has this reaction been recognized as a principal factor influencing oil recovery rates and chemical-pulse depletion. This paper considers the origin of the reversible hydroxide uptake to be ion exchange of sodium for hydrogen ions. Using a simple, mass-action equilibrium model, we describe the alkali exchange isotherm. Because hydronium and hydroxide concentrations in water are never zero, hydroxide uptake must be reported relative to a reference pH and s

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41

Somoza, Fernando, Jiwen Cai, and Ivan Bernal. "K(H9O4)[CIS-DINITRO-Co(TRANS-N, N-GLYCINATO)2]2 (I)—A NOVEL CLASS OF HYDRONIUM ION TRAPS, OF WHICH (I) CONTAINS AN UNUSUAL FORM OF THE H9O4 +CATION." Journal of Coordination Chemistry 43, no. 2-3 (1998): 187–91. http://dx.doi.org/10.1080/00958979808022666.

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42

Zelovich, Tamar, and Mark E. Tuckerman. "OH− and H3O+ Diffusion in Model AEMs and PEMs at Low Hydration: Insights from Ab Initio Molecular Dynamics." Membranes 11, no. 5 (2021): 355. http://dx.doi.org/10.3390/membranes11050355.

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Fuel cell-based anion-exchange membranes (AEMs) and proton exchange membranes (PEMs) are considered to have great potential as cost-effective, clean energy conversion devices. However, a fundamental atomistic understanding of the hydroxide and hydronium diffusion mechanisms in the AEM and PEM environment is an ongoing challenge. In this work, we aim to identify the fundamental atomistic steps governing hydroxide and hydronium transport phenomena. The motivation of this work lies in the fact that elucidating the key design differences between the hydroxide and hydronium diffusion mechanisms wil

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43

Duong, Chinh H., Nan Yang, Patrick J. Kelleher, et al. "Tag-Free and Isotopomer-Selective Vibrational Spectroscopy of the Cryogenically Cooled H9O4+Cation with Two-Color, IR–IR Double-Resonance Photoexcitation: Isolating the Spectral Signature of a Single OH Group in the Hydronium Ion Core." Journal of Physical Chemistry A 122, no. 48 (2018): 9275–84. http://dx.doi.org/10.1021/acs.jpca.8b08507.

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44

Wu, Jintao, Imri Atlas, Amit N. Shocron, and Matthew Suss. "Spatial Variations of pH in Electrodialysis Stacks: Theory." ECS Meeting Abstracts MA2022-01, no. 46 (2022): 1972. http://dx.doi.org/10.1149/ma2022-01461972mtgabs.

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Electrodialysis (ED) is a well-known electrochemical water desalination technology investigated since the 1950s. In an ED stack, desalination is driven by an applied voltage, which results in selective salt ion electromigration through alternating cation and anion exchange membranes. Transport of hydronium and hydroxide ions during water treatment, together with water dissociation, can lead to unfavorable product acidity or alkalinity, compromise the membrane charge, or enhance scaling. Conversely, pH deviations can also be leveraged to tune the speciation of weak acid/base electrolytes to enh

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45

Baer, Marcel, Dominik Marx, and Gerald Mathias. "Theoretical Messenger Spectroscopy of Microsolvated Hydronium and Zundel Cations." Angewandte Chemie International Edition 49, no. 40 (2010): 7346–49. http://dx.doi.org/10.1002/anie.201001672.

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46

Bernal, Ivan. "Nature as a crystal engineer: Trapping hydronium cations inside crystalline lattices – three heretofore unknown hydronium cations, two of which are geometrical isomers." Comptes Rendus Chimie 11, no. 8 (2008): 942–44. http://dx.doi.org/10.1016/j.crci.2008.01.011.

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47

Nazarchuk, Evgeny V., Yuri A. Ikhalaynen, Dmitri O. Charkin, et al. "Effect of solution acidity on the structure of amino acid-bearing uranyl compounds." Radiochimica Acta 107, no. 4 (2019): 311–25. http://dx.doi.org/10.1515/ract-2018-3050.

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Abstract A series of uranyl sulfates and selenates templated by protonated forms of amino acids (glycine, α- and β-alanine, threonine, nicotinic, and isonicotinic acid) has been prepared via isothermal evaporation of strongly acidic solutions. Their structures have been refined by the direct methods and can be classified as inorganic [(UO2)m(TO4)n (H2O)k] (T=S6+, Se6+) moieties combined with the protonated amino acid cations, water molecules and hydronium ions. Their overall motifs demonstrate common features with related structures templated by organic amines. The role of carboxylic acid grou

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48

Hua, Wei, Dominique Verreault, and Heather C. Allen. "Relative Order of Sulfuric Acid, Bisulfate, Hydronium, and Cations at the Air–Water Interface." Journal of the American Chemical Society 137, no. 43 (2015): 13920–26. http://dx.doi.org/10.1021/jacs.5b08636.

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49

Ismail, W. M. I. W., N. S. W. Zulkefeli, and M. N. Masri. "A Sight of Zinc Corrosion in Various Alkaline Media." Journal of Tropical Resources and Sustainable Science (JTRSS) 4, no. 2 (2021): 95–97. http://dx.doi.org/10.47253/jtrss.v4i2.614.

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This review concentrates on corrosion properties that expose to zinc by various alkaline media. The assumption has been advanced that zinc corrodes electrochemically in the first stage of exposition, but the chemical corrosion prevails after a longer time. Different types of electrolyte had been tested on zinc such as sodium chloride, sodium hydroxide and potassium hydroxide. Each of alkaline media can produced corrosion product such as zinc hydroxide chloride, zinc hydroxide carbonate, zinc oxide, and zinc hydroxide. The production of corrosion products is depending on the carbon dioxide cont

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50

Kalousová, Jaroslava, Jiří Votinský, Ludvík Beneš, Klára Melánová, and Vítězslav Zima. "Vanadyl Phosphate and Its Intercalation Reactions. A Review." Collection of Czechoslovak Chemical Communications 63, no. 1 (1998): 1–19. http://dx.doi.org/10.1135/cccc19980001.

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The structure of the layered αI-VOPO4, VOPO4·2H2O, and their intercalation reactions are discussed. These reactions are divided into two groups. The first includes intercalation reactions of molecular guests which proceed as acid-base processes between the host layered lattice (Lewis acid) and a donor atom of the guest (base). Interaction of water molecules, alcohols, amines, carboxylic acids and their derivatives, heterocyclic N- and S-donors, and complex compounds with vanadyl phosphates is discussed. Vanadyl phosphate, in particular vanadyl phosphate dihydrate can also undergo the second ty

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