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Дисертації з теми "Hydrogen bonding"

Автор: Grafiati

Опубліковано: 4 червня 2021

Оновлено: 25 липня 2025

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1

Mitchell, John Blayney Owen. "Theoretical studies of hydrogen bonding." Thesis, University of Cambridge, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.358697.

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2

Mondal, Raju. "Systematic studies of hydrogen bonding." Thesis, Durham University, 2004. http://etheses.dur.ac.uk/2986/.

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This thesis deals with wider application and implications of the hydrogen bond in crystal engineering studies and beyond; in addition, it also highlights the Cambridge Structural Database (CSD) as the potential knowledge-mine for inorganic chemists. The content of this thesis covers mainly three areas, viz, the role of hydrogen bonding in crystal engineering studies, the bridging between mainstream crystal engineering studies and solvates via hydrogen bond, and CSD studies on metal coordination spheres. Chapter 2 deals with crystal structure prediction through understanding the driving forces

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3

Sagar, Rajeeve. "Self-assembly via hydrogen bonding." Thesis, University of Warwick, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.247352.

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4

Scott, Tianeka S. "Understanding Hydrogen Bonding in Photoenolization." University of Cincinnati / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1378196534.

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5

Howard, Daryl L., and n/a. "Hydrogen bonding in the near infrared." University of Otago. Department of Chemistry, 2006. http://adt.otago.ac.nz./public/adt-NZDU20060823.150321.

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OH-stretching spectra of various vapour phase species were recorded to investigate hydrogen bonding. The species studied include 1,2-ethanediol, 1,3-propanediol, 1,4-butanediol, acetylacetone, hexafluoroacetylacetone and the complex formed in the heterogeneous mixture of methanol and trimethylamine. The spectra range from the infrared, near infrared to visible wavelengths. The main focus of this study is in the near infrared region, in which the OH-stretching overtones are dominant. The near infrared and visible spectrum of formic acid has been recorded to investigate coupling across bonds,

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6

Biemond, Gerard Jan Eduard. "Hydrogen bonding in segmented block copolymers." Enschede : University of Twente, 2006. http://doc.utwente.nl/51102.

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7

Taylor, Russell Alan. "Hydrogen bonding effects in homogeneous catalysis." Thesis, Imperial College London, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.500138.

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8

Thomson, Patrick. "Extremely strong contiguous hydrogen bonding arrays." Thesis, University of Edinburgh, 2013. http://hdl.handle.net/1842/7856.

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When multiple hydrogen bonds lie in-plane and parallel to each other in close proximity, they experience additional positive or negative secondary electrostatic interactions. When a pair of molecules are arranged such that every hydrogen bond acceptor is on one molecule and every hydrogen bond donor is on another, the positive secondary electrostatic interactions are maximised, and thus the association constant of the complex is enhanced. This thesis will present the development of a family of quadruple hydrogen bonded complexes containing only positive secondary interactions, which confers un

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9

Locke, Christopher John. "Competitive hydrogen bonding in polymeric systems." Thesis, University of York, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.259805.

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10

Hayward, Owen David. "Hydrogen bonding in the crystalline state." Thesis, University of Bristol, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.391181.

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11

Maskery, James Samuel. "Intramolecular hydrogen bonding in polyhydroxynaphthoquinone dyes." Thesis, Bangor University, 2014. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.664530.

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Intra- and inter-molecular hydrogen bonding greatly affects both physical and chemical properties for a wide variety of important molecules. This study focuses on intramolecular hydrogen bonding in polyhydroxy-1 ,4-naphthoquinones. The little known "bond counting rule", dictates that the global minimum will be comprised of a maximum number of highly stabilizing interactions. Hydrogen bonding was chosen for this work as the energy of the bond is typically 20-40 kJ mol-1, which is larger than computational error, allowing statistically significant energy differences between conformers to be dete

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12

Luccarelli, James Walter. "Conformational control by intramolecular hydrogen bonding." Thesis, University of Oxford, 2013. http://ora.ox.ac.uk/objects/uuid:48b80a00-cad2-46be-9791-5acab5761ff2.

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Hydrogen bonds are directional, non-covalent interactions between hydrogen and electronegative atoms. Although generally weak, these interactions are critical to the stability of many biological systems including proteins and DNA. This dissertation explores small molecules in which an intramolecular hydrogen bond is the key determinant of conformation. Chapter 1 introduces the protein Grb2 SH3C, details its role in cancer signalling, and delineates the idea of peptidomimetics—small molecules which are functionalized to mimic the structure of a peptide and disrupt protein-protein interactions.

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13

Dominelli, Whiteley Nicholas. "Hydrogen-bonding and halogen-arene interactions." Thesis, University of Edinburgh, 2017. http://hdl.handle.net/1842/28824.

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Анотація:

Non-covalent interactions are fundamental to molecular recognition processes that underpin the structure and function of chemical and biological systems. Their study is often difficult due to the interplay of multiple interactions and solvent effects common in complex systems. Herein, chapter one provides some general background on the area before presenting a literature review of key, contemporary developments on the use of folding molecules for the quantification of non-covalent interactions. Chapter two investigates the magnitude and extent of energetic cooperativity in H-bond chains. Utili

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14

Ghafourian, Taravat. "Investigations of calculated hydrogen bonding parameters." Thesis, Liverpool John Moores University, 1996. http://researchonline.ljmu.ac.uk/5133/.

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15

Cornes, Stuart. "Halogen bonding, hydrogen bonding and Lewis acidic receptors for anion recognition." Thesis, University of Oxford, 2016. https://ora.ox.ac.uk/objects/uuid:0725f9c4-ff44-4158-b94e-9bcaf0fa3b4d.

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Анотація:

This thesis describes the preparation of acyclic, macrocyclic and interlocked receptors for the recognition of anions in competitive organic and aqueous solvent media. Chapter One introduces the field of anion supramolecular chemistry, with a particular focus on the non-covalent interactions used for anion recognition and the synthesis of mechanically interlocked molecules. Chapter Two discusses the preparation of halogen bonding and hydrogen bonding acyclic and interlocked pyridinium-based receptors. Investigations into their anion selectivity trends are undertaken using 1H NMR titration expe

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16

Chen, Xi. "Designing Acrylic Block Copolymers with Multiple Hydrogen Bonding or Multiple Ionic Bonding." Thesis, Virginia Tech, 2018. http://hdl.handle.net/10919/84961.

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The dynamic characteristics of hydrogen and ionic bonding contributes to the reversible properties of acrylic polymers, opening new avenues for designing materials with mechanical strength and processability. These non-covalent interactions function as physical crosslinks, which provide enhanced structural and mechanical integrity to acrylic block copolymers. The strong hydrogen bonding or ionic interaction also directs self-assembly to hierarchical microstructures, which enables many applications including thermoplastic elastomers and energy storage devices. Inspired by complementary hydrogen

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17

Cother, Lisa Dawn. "Hydrogen bonding in silanols and their adducts." Thesis, Imperial College London, 1998. http://hdl.handle.net/10044/1/11984.

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18

Häggman, Leif. "Chelating surfactants : analysis, hydrogen bonding and structures /." Uppsala : Dept. of Chemistry, Swedish Univ. of Agricultural Sciences, 2003. http://epsilon.slu.se/a384-ab.html.

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19

Cantalapiedra, Nuria Aboitiz. "Intramolecular hydrogen-bonding studies by NMR spectroscopy." Thesis, University of Liverpool, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.366715.

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20

Ê¿AÌ„rif, MuhÌ£ammad. "Strong hydrogen bonding in metal fluoride complexes." Thesis, King's College London (University of London), 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.324600.

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21

Pearson, Jem M. "Hydrogen-bonding motifs for non-covalent synthesis." Thesis, University of Oxford, 2013. http://ora.ox.ac.uk/objects/uuid:f0630898-35b4-4c74-bc31-dfd252c2ee26.

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This work describes the design and synthesis of a set of four organic molecules that are intended to hydrogen-bond to each other in a pairwise manner. The four hydrogen-bonding units, termed ‘A’, ‘B’, ‘C’ and ‘D’, when placed in solution together, are designed so that A binds only to B, and C binds only to D. Each unit does not bind to itself, nor to either of the other two units to which binding is not intended. For example, A binds to B, but not to A, C, or D. Each unit contains an array of four hydrogen-bonds for strong binding to its partner, is designed to be as rigid as possible, as non-

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22

Miller, Allan Harvey 1968. "Predicting the solubility of hydrogen bonding aromatics." Thesis, The University of Arizona, 1993. http://hdl.handle.net/10150/291667.

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The AQUAFAC (Aqueous Functional Group Activity Coefficients) method for predicting aqueous activity coefficients proposed by Myrdal et al. (1992) is expanded to include for hydrogen bonding groups: hydroxy, carboxy, nitro and amino. Activity coefficients can be used to estimate aqueous solubility. Using aqueous solubility data, from a number of sources, for a set of subsituted aromatic compounds, group or q values are derived. Group values have been generated for a number of substituents, none have included hydrogen bonding groups (Myrdal et al., 1992,1993). Q values are related to activity co

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23

Al-Mahamad, Lamia Lafta Ghashim. "Supramolecular hydrogels and discrete structures based on metal coordination and hydrogen bonding." Thesis, University of Newcastle upon Tyne, 2017. http://hdl.handle.net/10443/3981.

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The complexation of thiolated nucleosides and nucleobases with a range of group 11 metal ions (Au(I), Ag(I), Cu(I/II), was observed to lead to the formation of hydrogels by simple inversion tests. Atomic force and electron microscopy of the xerogels showed, in many cases, the presence of fibres with lengths in the micrometre range and above; this provided evidence for the formation of coordination polymers. This thesis is concerned with the preparation, characterisation and investigation of the physical properties, mainly photoluminescence and conductivity, of these coordination polymers. 2’-D

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24

Chen, Xi. "Exploring Multiple Hydrogen Bonding and Ionic Bonding in the Design of Supramolecular Polymers." Diss., Virginia Tech, 2020. http://hdl.handle.net/10919/98729.

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Supramolecular polymers represent a family of polymeric materials that are held together with dynamic, noncovalent interactions. In contrast to conventional functional polymers that usually have high melt-viscosity due to their covalent nature and chain entanglement, supramolecular polymers combine excellent physical properties with low melt-viscosity, allowing for less energy-intensive processability and recyclability. Dynamic bonding with multiple binding sites, such as multiple hydrogen bonding or multiple ionic bonding, exhibits much stronger binding strength compared to the counterparts c

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25

Schmidtmann, Marc. "Hydrogen transfer in hydrogen bonded solid state materials." Thesis, Connect to e-thesis, 2008. http://theses.gla.ac.uk/284/.

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Thesis (Ph.D.) - University of Glasgow, 2008.<br>Ph.D. thesis submitted to the Department of Chemistry, Faculty of Physical Sciences, University of Glasgow, 2008. Includes bibliographical references. Print version also available.

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26

Steinlin, Andreas. "Hydroxyquinolines : hydrogen bonding scaffolds for excited state reactions /." [S.l.] : [s.n.], 2008. http://opac.nebis.ch/cgi-bin/showAbstract.pl?sys=000286557.

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27

Rankin, Kathryn N. "A theoretical study of hydrogen bonding involving biomolecules." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2001. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/NQ66637.pdf.

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28

Brom, Coenraad Richard van den. "Aggregation of gold clusters by complementary hydrogen bonding." [S.l. : [Groningen : s.n.] ; University Library Groningen] [Host], 2006. http://irs.ub.rug.nl/ppn/292186150.

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29

Szymczak, Nathaniel Kolnik. "Coordination chemistry of dihydrogen and dihydrogen hydrogen-bonding /." view abstract or download file of text, 2007. http://proquest.umi.com/pqdweb?did=1400962351&sid=1&Fmt=2&clientId=11238&RQT=309&VName=PQD.

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Анотація:

Thesis (Ph. D.)--University of Oregon, 2007.<br>Typescript. Includes vita and abstract. Includes bibliographical references (leaves 307-324). Also available for download via the World Wide Web; free to University of Oregon users.

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30

Salzameda, Nicholas Thomas. "Syntheses and hydrogen bonding properties of dipyrrinone analogs /." abstract and full text PDF (free order & download UNR users only), 2006. http://0-gateway.proquest.com.innopac.library.unr.edu/openurl?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&res_dat=xri:pqdiss&rft_dat=xri:pqdiss:3250684.

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Анотація:

Thesis (Ph. D.)--University of Nevada, Reno, 2006.<br>"December, 2006." Includes bibliographical references (leaves 120-123). Online version available on the World Wide Web. Library also has microfilm. Ann Arbor, Mich. : ProQuest Information and Learning Company, [2006]. 1 microfilm reel ; 35 mm.

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31

Tossell, Katie Jayne. "Catalysis of phosphate ester hydrolysis through hydrogen bonding." Thesis, University of Sheffield, 2011. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.578696.

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This thesis describes the investigation of the effect of hydrogen bonding on the rate of phosphoryl transfer in the reaction of diethyl 8-dimethylamino-I-naphthyl phosphate 3 with a nucleophile. The study of the hydrolysis of triester 3 is in the literature; triester 3 is catalysed by the dimethylammonium general acid, with a rate acceleration of almost 106 in comparison to the hydrolysis of diethyl I-naphthyl phosphate. 58 To ascertain whether the reactivity of triester 3 is specific to this system, the methylation of the amine in triester 3 was altered. Triesters diethyl 8- amino-I-naphthyl

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32

Nieuwenhuyzen, Mark. "Crystal engineering and polymorphism : aspects of hydrogen bonding." Thesis, Queen's University Belfast, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.301029.

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33

Quinlan, D. J. "Hydrogen bonding in N-ligated copper(II) complexes." Thesis, University of Nottingham, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.262983.

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34

Mason, Pamela V. "Triazine hosts for metal coordination and hydrogen-bonding." Thesis, University of Nottingham, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.415866.

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35

Jones, Christopher Raymond. "Hydrogen bonding : from conformational control to asymmetric catalysis." Thesis, University of Cambridge, 2009. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.611778.

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36

Yang, Zhiyi. "Rheology of Miscible Polymer Blends with Hydrogen Bonding." University of Akron / OhioLINK, 2007. http://rave.ohiolink.edu/etdc/view?acc_num=akron1184881292.

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37

Willis, Joshua Jerome. "27th Immunoglobulin Domain: Fold Catastrophes and Hydrogen Bonding." Case Western Reserve University School of Graduate Studies / OhioLINK, 2012. http://rave.ohiolink.edu/etdc/view?acc_num=case1332855603.

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38

Steiger, Adam. "Effects of solvent composition on hydrogen bonding equilibria." Thesis, University of Sheffield, 2015. http://etheses.whiterose.ac.uk/8823/.

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39

Belhekar, A. A. "Conformational and hydrogen bonding behavior of complex molecules." Thesis(Ph.D.), CSIR-National Chemical Laboratory, Pune, 1990. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/2989.

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40

Snowden, Timothy Scott. "Hydrogen bond involvement in carbon acid pKa[subscript] shifts and intramolecular general catalysis /." Full text (PDF) from UMI/Dissertation Abstracts International, 2001. http://wwwlib.umi.com/cr/utexas/fullcit?p3008444.

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41

Gokcen, Taner. "Molecular engineering of trigonal octupolar materials based on 2,4,6-diarylamino-1,3,5-triazines." Link to electronic thesis, 2005. http://www.wpi.edu/Pubs/ETD/Available/etd-082405-155024/.

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42

Perera, Manomi Dharshika. "Hydrogen and halogen bonding in co-crystallization: from fundamentals to applications." Diss., Kansas State University, 2017. http://hdl.handle.net/2097/36209.

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Doctor of Philosophy<br>Department of Chemistry<br>Christer B. Aakeroy<br>The impact of the molecular electrostatic potential values (MEPs) in halogen and hydrogen bond interactions were explored using two acceptors with multiple acceptor sites with twelve hydrogen-bond donors, five halogen bond donors and four mixed halogen and hydrogen bond donors. The results suggested if the difference between the two acceptor sites is above 38 kJ/mol both hydrogen and halogen bond donors prefer the acceptor site with the highest MEP value and this selectivity was lost if the difference is below 26 kJ/mol.

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43

Arman, Hadi D. "Strategies for expanding the halogen bonding periodic table and designing complementary halogen/hydrogen bonding synthons." Connect to this title online, 2008. http://etd.lib.clemson.edu/documents/1219848304/.

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44

Cui, Lu. "Hydrogen Bonding and Cucurbituril Complexation as Self-Assembly Mechanisms." Scholarly Repository, 2009. http://scholarlyrepository.miami.edu/oa_dissertations/450.

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The supramolecular interactions of small organic molecules with different host molecules are investigated in this dissertation. Additionally, the author also describes the self-assembly mechanisms in hydrogen bonding motif. These studies were carried out by many techniques including, NMR, cyclic voltammetry, steady state voltammetry, mass spectroscopy, UV-visible spectroscopy and fluorescence spectroscopy. Chapter 1 introduces the science of supramolecular chemistry and the background of cucurbiturils, one of the most important host molecules studied in this research work. It describes the s

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45

Murguly, Elisa. "Programming supramolecular systems using hydrogen bonding and metal chelation." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2001. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/MQ60476.pdf.

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46

Li, Hui. "N-heteroaromatic acid adlayer structures under hydrogen bonding influence." College Park, Md. : University of Maryland, 2006. http://hdl.handle.net/1903/6649.

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Анотація:

Thesis (Ph. D.)--University of Maryland, College Park, 2006.<br>Thesis research directed by: Chemistry. Title from t.p. of PDF. Includes bibliographical references. Published by UMI Dissertation Services, Ann Arbor, Mich. Also available in paper.

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47

Maccallum, Peter Hugh. "Hydrogen bonding and the stability of the polypeptide backbone." Thesis, University of Glasgow, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.360133.

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48

Boissonnet, Michel-Franck. "Hydrogen-bonding ferrocene derivatives for molecular recognition and organocatalysis." Thesis, University of Birmingham, 2015. http://etheses.bham.ac.uk//id/eprint/6121/.

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The aim of this project was to prepare novel ferrocene-based Hydrogen-bonding receptors and to study them in the electrochemical sensing of neutral compounds and in organocatalysed transformations. The synthesis and characterisation of 2-ferrocenyl oxazoles via gold chemistry to access a new H-bonding motif for electrochemical sensing was successfully achieved. However the targeted structure bearing a secondary amine at the 4-position of the oxazole, was found to be highly unstable and unsuitable for sensing applications. Further studies on ferrocene-based H-bonding systems towards their appli

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49

Metteau, Laurent. "Redox properties of metal complexes with internal hydrogen bonding." Thesis, University of Edinburgh, 2008. http://hdl.handle.net/1842/15375.

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In this thesis we incorporate hydrogen bonding features NH<sub>2</sub> (Am), NHCH<sub>2</sub><sup>t</sup>Bu (Np), and NHCO<sup>t</sup>Bu (Piv) in the pyridine 6<sup>th</sup> position of the tripodal ligand TPA (tris(2-pyridylmethyl)amine, L). Thus, thirteen ligands L<sup>X-n</sup> (X = Am, Np, Piv; n = 0, 1, 2, 3) derived from and including TPA have been made. Also, one and two amino groups have been introduced in a similar position of the ligand <i>N,N</i>-Bis(2-pyridilmethyl)-<i>N</i>-(glycine)amine (BPG), (one amino group, APPG and two amino groups, BAPG) have been made. The structures of s

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50

Garfitt, Jason Michael. "Hydrogen bonding and covalent coupling in adsorbed molecular monolayers." Thesis, University of Nottingham, 2014. http://eprints.nottingham.ac.uk/27728/.

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This thesis examines multiple different molecular networks adsorbed on several different substrates, namely, highly oriented pyrolytic graphite (HOPG), Au(111) and graphene. STM investigations into hydrogen-bonded structures formed by closely related tetracarboxylic acid molecules were performed. The molecule pterphenyl-3,5,3,5-tetracarboxylic acid (TPTC), which is known to form random tiling networks, was observed on a graphene on copper substrate. The network formed from deposition of TPTC from nonanoic acid was examined statistically. Aqueous solutions of TPTC were also examined on HOPG whe

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