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Статті в журналах з теми "Hydrolytic dissolution"

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Pichugina, A., and V. Lutsik. "Investigation of the mechanism of hydrolytic dissolution of nickel sulfide in dilute sulfuric acid." Bulletin of Science and Practice, no. 12 (December 11, 2017): 84–89. https://doi.org/10.5281/zenodo.1101165.

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The paper presents the results a study of the hydrolytic mechanism of dissolution of Nickel sulfide in dilute solutions of sulfuric acid. According to the obtained mathematical model of sulfide dissolution are established modes of interaction, determined by the details of the mechanism of the studied processes. Proposed relevant observable kinetic dependences reasonable schemes of interaction. Received rentgenospektralny spectra and STM images of the surface of Nickel sulfide. A mechanism is hydrolytic. The process is not accompanied by oxidation of sulfide sulfur. The limiting stage of hydrol
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Sari, Rita Kartika, Fadilah Fitrianum, Muhammad Iqbal Maulana, et al. "Hydrolytic Stability of Sengon-Oriented Strand Board Bonded with Hybrid Phenol-Formaldehyde/Polymeric Methylene Diphenyl Diisocyanate Adhesives." Jurnal Sylva Lestari 12, no. 3 (2024): 818–31. http://dx.doi.org/10.23960/jsl.v12i3.987.

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The hydrolytic stability of oriented strand board (OSB) is critical to guarantee good performance in humid conditions over the long term. The adhesive system impacts hydrolytic stability in addition to the wood strands. This study aims to investigate the hydrolytic stability of OSB bonded with a hybrid adhesive based on phenol-formaldehyde (PF) and polymeric methylene diphenyl diisocyanate (pMDI) modified with NaOH and CaCO3 catalyst. PF was mixed with each catalyst at approximately 1% of the PF solids content. The pMDI was added to the mixture at 2.5% and 5% of the PF solid content. The hybri
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Pichugina, A., S. Gortsevich, and V. Lutsik. "Kinetics of millerite and heazlewoodite dissolution in solutions of nitric acid." Bulletin of Science and Practice 456, no. 11 (12) (2016): 106–11. https://doi.org/10.5281/zenodo.166791.

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The paper presents the results of a study of the kinetics of hydrolytic and oxidative dissolution of Nickel sulfides in nitric acid. Dependences of specific speed of dissolution of copper cations (W, mol/sm2s) from concentration of hydrogen peroxide (Cn, mol/dm3), рН, temperatures (T, K), frequencies of rotation disk (ω, c−1) and durations of interaction (τ, c) are studied. The mechanisms of the interaction of millerite and heazlewoodite. The values of apparent activation energy and sulfides dissolution rate constant are calculated. Interaction modes are established, probable limiting stages o
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Krauklis, Gagani, and Echtermeyer. "Long-Term Hydrolytic Degradation of the Sizing-Rich Composite Interphase." Coatings 9, no. 4 (2019): 263. http://dx.doi.org/10.3390/coatings9040263.

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Glass fiber-reinforced composites are exposed to hydrolytic degradation in subsea and offshore applications. Fiber-matrix interphase degradation was observed after the matrix was fully saturated with water and typical water absorption tests according to ASTM D5229 were stopped. Due to water-induced dissolution, fiber-matrix interphase flaws were formed, which then lead to increased water uptake. Cutting sample plates from a larger laminate, where the fibers were running parallel to the 1.5 mm long short edge, allowed the hydrolytic degradation process to be studied. The analysis is based on a
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Pichugina, A., and S. Gortsevich. "Fluorimetric determination of nickel and copper in the study of hydrolytic and oxidative dissolution." Bulletin of Science and Practice 4, no. 12 (2018): 85–88. https://doi.org/10.5281/zenodo.2254222.

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The paper presents the results of the study of the kinetics of oxidative dissolution of Nickel and copper. We have investigated the dependence of the metal passed into solution from the flow time of the dissolution process. The most efficient method for the determination of metals to study the kinetics. The main parameters of the fluorescent analysis method were selected, and the optical densities of the samples were determined.
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Väisänen, Saija, Harri Kosonen, Matti Ristolainen, and Tapani Vuorinen. "Cellulose dissolution in aqueous NaOH–ZnO: effect of pulp pretreatment at macro and molecular levels." Cellulose 28, no. 7 (2021): 4385–96. http://dx.doi.org/10.1007/s10570-021-03779-w.

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AbstractThis paper discusses the effect of hydrolytic pretreatments on pulp dissolution in the aqueous NaOH–ZnO solvent system. Eight samples were studied. They consisted of a never-dried softwood kraft pulp that was hydrolyzed under seven different conditions as well as the pulp without hydrolysis as a reference. The dissolution of the pulps was evaluated both at the macro level as well as at the molecular level based on their reactivity with 4-acetamido-2,2,6,6-tetramethylpiperidine-1-oxo-piperidium (4-AcNH-TEMPO+). The fiber properties (i.e. the extent of fibrillation, amount of fines and f
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YUKHIN, YU M., E. S. KOLEDOVA, A. S. DAMINOV, E. V. TIMAKOVA, V. A. KUZNETSOV, and O. D. SHEINA. "OBTAINING BISMUTH AND ITS HIGH-PURITY COMPOUNDS." Chemistry for Sustainable Development 32, no. 5 (2024): 687–96. https://doi.org/10.15372/csd2024604.

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The process of metal bismuth dissolution in nitric acid was studied, and a comparison was made over environmentally friendly methods of obtaining bismuth nitrate solutions by the preliminary oxidation of bismuth, as well as by its dissolution in the presence of urea or ammonium nitrate. It has been shown that the dissolution of bismuth in the presence of ammonium nitrate at a molar ratio of ammonium nitrate to bismuth equal to 1.5-3.5 and a temperature of 70±5 °C allows eliminating the release of nitrogen oxides into the gas phase and obtaining a solution with a high concentration of bismuth.
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Ramirez, S., D. Righi, and S. Petit. "Alteration of smectites induced by hydrolytic exchange." Clay Minerals 40, no. 1 (2005): 15–24. http://dx.doi.org/10.1180/0009855054010152.

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AbstractHydrolytic exchange was performed experimentally on four smectitic clays to evaluate the extent of clay alteration induced by this process and the associated ‘auto-transformation’ of H+ clays. Clay samples were Na-saturated and submitted to 10, 50 and 100 wetting-drying (WD) cycles and characterized after treatment using X-ray diffraction (XRD), infrared spectroscopy (FTIR) and cation exchange capacity analysis. Evidence for hydrolytic exchange was given by increasing amounts of exchangeable Mg2+ and precipitation of Na soluble salts for samples subjected to 100 WD cycles. Results indi
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Chen, Jiahao, Shihu Liu, Yingmu Wang, Wei Huang, and Jian Zhou. "Effect of different hydrolytic enzymes pretreatment for improving the hydrolysis and biodegradability of waste activated sludge." Water Science and Technology 2017, no. 2 (2018): 592–602. http://dx.doi.org/10.2166/wst.2018.185.

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Abstract In this study, the effects of lysozyme, protease and α-amylase pretreatments for improving the hydrolysis and biodegradability of waste activated sludge (WAS) were investigated. The results showed that lysozyme was more effective in increasing the soluble chemical oxygen demand (SCOD) concentration in the liquid phase of sludge and improving the release of protein and carbohydrate from sludge flocculation to enhance sludge hydrolysis. After 8 h hydrolysis, the net SCOD increase in a reactor with lysozyme was 2.23 times and 2.15 times that of the reactors with protease and α-amylase, r
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Smith, David C., Meinhard Simon, Alice L. Alldredge, and Farooq Azam. "Intense hydrolytic enzyme activity on marine aggregates and implications for rapid particle dissolution." Nature 359, no. 6391 (1992): 139–42. http://dx.doi.org/10.1038/359139a0.

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Дисертації з теми "Hydrolytic dissolution"

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Wang, Ying. "Cellulose fiber dissolution in sodium hydroxide solution at low temperature dissolution kinetics and solubility improvement /." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2008. http://hdl.handle.net/1853/26632.

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Thesis (Ph.D)--Chemical Engineering, Georgia Institute of Technology, 2009.<br>Committee Chair: Deng, Yulin; Committee Member: Banerjee, Sujit; Committee Member: Frederick, James; Committee Member: Hsieh, Jeffery; Committee Member: Ragauskas, Arthur J.. Part of the SMARTech Electronic Thesis and Dissertation Collection.
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Molis, Elisabeth. "Dissolution en suspension et en position d'intercalation des formes hydrolysées de l'aluminium en interaction avec des ligands organiques." Vandoeuvre-les-Nancy, INPL, 1996. http://www.theses.fr/1996INPL123N.

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Les études concernant l'évolution chimique et structurale d'espèces d'aluminium en présence de salicylate ont été menées en combinant plusieurs méthodes d'analyses telles que l'électrophorèse, les spectroscopies infrarouges et RMN, les méthodes thermiques et de diffusion de rayonnement. Dans les cas étudiés, les agrégats d'Al13, la gibbsite et la montmorillonite intercalée par l'Al13, ces méthodes nous ont permis de mettre en évidence des changements structuraux important, du à la dissolution de l'aluminium en fonction de la concentration en ligand organique. L’interaction entre les espèces d'
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Iwalewa, Tajudeen. "Coupling source term, mineral reactivity and flow in radionuclide transport." Thesis, University of Cambridge, 2017. https://www.repository.cam.ac.uk/handle/1810/265633.

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The focus of this work is to investigate the dissolution of MW25, a non-radioactive simulant of UK high-level nuclear waste borosilicate glass, and to predict its performance in the near field of a geological repository. A single-pass flow-through (SPFT) experimental system was used to measure the forward dissolution rates of MW25. Experiments were conducted in two parts. Experiment Part 1 considers the dissolution of the waste glass in deionised water at 40 and 90 oC and circum-neutral pH. Experiment Part 2 considers the dissolution of the waste glass in simulant groundwaters, with similar co
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Κοφινά, Αικατερίνη-Κανέλλα. "Ανάκτηση ανόργανων φωσφορικών από υδατικά διαλύματα". Thesis, 2006. http://nemertes.lis.upatras.gr/jspui/handle/10889/1468.

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Η δέσμευση του P με την μορφή του στρουβίτη θεωρείται από τις εναλλακτικές μεθόδους ανάκτησης του P από τα υγρά απόβλητα. Ο στρουβίτης χρησιμοποιείται ως αργά αποδεσμευόμενο λίπασμα, ως υλικό για την σταθεροποίηση αμμωδών εδαφών και συμβάλλει στην αειφόρο ανάπτυξη. Η καταβύθιση του στρουβίτη σε υπέρκορα διαλύματά του υπό σταθερή θερμοκρασία εξαρτάται από τον υπερκορεσμό και από την παρουσία ξένων ιόντων ή ουσιών. Στόχος της παρούσας διατριβής, ήταν η μελέτη της κινητικής της καταβύθισης του στρουβίτη σε συνθήκες σύστασης αντίστοιχες των αστικών αποβλήτων. Η θερμοδυναμική ανάλυση γίνεται με μον
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Частини книг з теми "Hydrolytic dissolution"

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Meretoja, Ville V., Sudhir Paul, and Stephanie A. Planque. "Hydrolysis and Dissolution of Amyloids by Catabodies." In Natural Antibodies. Springer New York, 2017. http://dx.doi.org/10.1007/978-1-4939-7180-0_9.

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Meretoja, Ville V., Sudhir Paul, and Stephanie A. Planque. "Erratum to: Hydrolysis and Dissolution of Amyloids by Catabodies." In Natural Antibodies. Springer New York, 2017. http://dx.doi.org/10.1007/978-1-4939-7180-0_16.

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Moynihan, Humphrey A., and Abina M. Crean. "Pharmaceutical Solutions." In The Physicochemical Basis of Pharmaceuticals. Oxford University Press, 2009. http://dx.doi.org/10.1093/hesc/9780199232840.003.0002.

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This chapter discusses the main concepts relating to the dissolution and solubility of pharmaceutical compounds. Solubility and solutions are of key importance pharmaceutically as drug molecules need to be in solution in the biological fluids surrounding the site of action to achieve a therapeutic effect. Common expressions of solubility for pharmaceutical uses include mole fractions, molarity, molality, percentages, parts per million, and equivalents. Two types of solvent medium exist in the body: water-based and lipid-based. During the dissolution process, solute molecules leave their previo
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Kreua-ongarjnukool, Narumol, Nopparuj Soomherun, Saowapa Thumsing Niyomthai, and Sorayouth Chumnanvej. "Aliphatic Polyester Nanoparticles for Drug Delivery Systems." In Smart Drug Delivery [Working Title]. IntechOpen, 2021. http://dx.doi.org/10.5772/intechopen.100977.

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Drug delivery systems using aliphatic polyester nanoparticles are usually prepared via an emulsion process. These nanoparticles can control drug release and improve pharmacokinetics. Aliphatic polyesters are linear polymers containing ester linkages, showing sensitivity to hydrolytic degradation. The byproducts then promote autocatalytic degradation. These byproducts could enter the Krebs cycle and be eliminated from the body, resulting in the high biocompatibility of these nanoparticles. The properties of these polyesters are linked to the drug release rate due to biodegradation, i.e., polyme
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Howard, Alan G. "Dissolution and deposition processes." In Aquatic Environmental Chemistry. Oxford University Press, 1998. http://dx.doi.org/10.1093/hesc/9780198502838.003.0006.

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This chapter assesses dissolution and deposition processes. Some of the solid matter which is suspended in a natural water, or deposited to make up the top layers of the bottom sediments, is material which has been recently deposited from solution. This may arise from a purely chemical process such as precipitation or colloidal aggregation, or may result from the production of solid biomass, such as that which results from the photosynthetic activity of algae. Some of this solid material will be rapidly returned to the dissolved phase by changes in solution chemistry or bacterially-assisted de
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Dong, Yue, Jana Holm, and Ulla Lassi. "Dissolution and Hydrolysis of Lignocellulosic Biomass using Tailored Ionic Liquids." In Ionic Liquids - Current State of the Art. InTech, 2015. http://dx.doi.org/10.5772/59049.

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Obodovych, Oleksandr, and Oleksandr Solovey. "REALITIES AND PROSPECTS FOR INTENSIFICATION OF BIOETHANOL PRODUCTION DUE TO THE USE OF DISCRETE-PULSE ENERGY INPUT." In Integration of traditional and innovation processes of development of modern science. Publishing House “Baltija Publishing”, 2020. http://dx.doi.org/10.30525/978-9934-26-021-6-37.

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The development of the biofuel industry and the production of bioethanol and using it as a fuel in the world in general and in Ukraine in particular are analyzed in the paper. Bioethanol is mostly produced from sugar- and starch-containing raw materials. It is noted that bioethanol is obtained mainly from molasses in Ukraine. Molasses is a by-product of sugar beet production. The prospects of second-generation bioethanol production made from unfit for human consumption lignocellulosic biomass such as agricultural by-products, forestry residues, municipal waste are considered. Pretreatment of l
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Juo, Anthony S. R., and Kathrin Franzluebbers. "Soil Formation and Classification." In Tropical Soils. Oxford University Press, 2003. http://dx.doi.org/10.1093/oso/9780195115987.003.0010.

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Soil is the superficial layer of the land area of the Earth and contains weathered inorganic materials, organic matter, air, and water. The branch of soil science that studies the formation and classification of soils is termed pedology. For both scientific and technical purposes, soils around the world are organized into various categories on the basis of their differences and similarities. There are two types of soil classification schemes: (i) the scientific or pedological classification schemes which group soils on the basis of morphological, physical, chemical, and mineralogical propertie
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Bunker, Bruce C., and William H. Casey. "Oxide Films in Metal Corrosion: Oxide Defect Chemistry." In The Aqueous Chemistry of Oxides. Oxford University Press, 2016. http://dx.doi.org/10.1093/oso/9780199384259.003.0019.

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Most metals used by our society corrode, from the mild tarnish on silver to the green patina that coats our copper statues and electrical wiring to the red rust on our cars and iron bridges (Fig. 12.1, Plate 17). Metal corrosion often involves the conversion of metals into either oxides or their soluble hydrolysis products. The metals we use in our structures, as well as in electronic and magnetic devices, are destroyed as a result of this conversion. It has been estimated that the annual cost of metallic corrosion to the U.S. economy is hundreds of billions of dollars (5% of the gross nationa
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Тези доповідей конференцій з теми "Hydrolytic dissolution"

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Prian, L., and A. Barkatt. "Chemical, Thermochemical, and Mechanical Studies of FRP Degradation in Corrosive Environments." In CORROSION 1998. NACE International, 1998. https://doi.org/10.5006/c1998-98455.

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Abstract Extensive measurements on E-glass/vinylester rods exposed to air, water, and ammonia solutions at temperatures between 23°C and 80°C for 7 to 224 days showed that integration of the chemical, thermochemical, and mechanical data is necessary for developing useful models of FRP degradation. For instance, fiber dissolution is a major mechanism in basic environments while resin hydrolysis is most pronounced in acidic environments1,2. Dramatic increases in degradation rates may be observed in some cases of environmental exposure after a certain induction period, even at relatively low temp
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Buchheit, R. G., J. P. Moran, and G. E. Stoner. "The Role of Hydrolysis in the Crevice Corrosion of Aluminum-Lithium-Copper Alloys." In CORROSION 1990. NACE International, 1990. https://doi.org/10.5006/c1990-90093.

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Abstract The hydrolytic behavior of cations plays an important role in the crevice corrosion of aluminum and its alloys. Hydrolysis equilibrium reactions can either consume or produce H+ thereby altering pH. An external cathode electrolytically coupled to a crevice can also influence the pH developed in a crevice. In this study, simulated crevice experiments were performed with pure aluminum, solution heat treated (SHT) Al-3Li and SHT Al-3Cu to determine the effects of Al3+, Li+ and Cu2+ hydrolysis on steady state pH. Simulated crevice experiments were carried out with aerated bulk solutions,
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Chang, Kelvin Y., and Suresh Patel. "A Mechanistic Study of Phosphinocarboxylic Acid for Boiler Deposit Control." In CORROSION 1995. NACE International, 1995. https://doi.org/10.5006/c1995-95476.

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Abstract A laboratory study has been carried out to identify the key properties of phosphinocarboxylic acid polymers to control boiler water deposits. These multifunctional properties are its ability to: transport iron, disperse boiler water sludge that contains iron oxide, silica and calcium phosphate and dissolution of deposits. The thermal and hydrolytic stability of the phosphinocarboxylic acid polymers was investigated in autoclave studies up to 1500 psig. The post-autoclave samples were analyzed by Nuclear Magnetic Resonance Spectroscopy and Aqueous Gel Permeation Chromotography to ascer
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Engelhardt, G. R., and D. D. Macdonald. "Modeling of Corrosion Fatigue Chemistry in Sensitized Stainless Steel in Boiling Water Reactor Environments." In CORROSION 2000. NACE International, 2000. https://doi.org/10.5006/c2000-00227.

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Abstract A simplified method is proposed for modeling the chemistry and potential distribution in a corrosion fatigue crack in sensitized stainless steel in boiling water reactor (BWR) coolant environments. Mass transport by diffusion, ion migration and convection due to movement of crack walls was considered. Anodic and cathodic processes, hydrolysis, oxide solubility, and water dissociation have been included in the model. The model takes into account transport processes in the external environment and recognizes that the specific rate (rate per unit area) of metal dissolution at the crack t
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van Ooij, W. J. "Study of Paint-Metal Interfaces by Static and Imaging Sims." In CORROSION 1989. NACE International, 1989. https://doi.org/10.5006/c1989-89615.

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Abstract The interfaces between phosphated galvanized steel and paint films have been characterized by static and imaging SIMS, in addition to analyses by SEM/EDX and XPS, in an attempt to detect the first stages of interfacial changes during atmospheric corrosion of painted automotive precoated steels. At about 500 μm ahead of the corrosion propagation, SIMS detected an extensive degree of hydrolysis of the phosphate-paint interface. Farther away from the scribe only minor changes were detected suggesting, however, a weakening of the paint-phosphate bond possibly caused by dissolution of wate
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Engelhardt, G. R., and D. D. Macdonald. "Modeling Corrosion Fatigue Crack Propagation." In CORROSION 2001. NACE International, 2001. https://doi.org/10.5006/c2001-01115.

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Abstract A mathematical model is proposed for modeling the chemistry and the potential distribution in a corrosion fatigue crack, along with the crack propagation rate, in sensitized stainless steel in boiling water reactor (BWR) coolant environments. Mass transport by diffusion, ion migration, and convection (due to movement of crack walls) was considered. Anodic and cathodic processes, hydrolysis, oxide solubility, and water dissociation are included in the model. The model takes into account oxygen transport and depletion in the crack and transport processes in the external environment, and
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Lyublinskii, E. Ya. "Physico-Chemical Antifouling Protection." In CORROSION 1995. NACE International, 1995. https://doi.org/10.5006/c1995-95216.

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Abstract Physico-chemical antifouling protection consists of either the hydrolysis of sea water to produce chlorine and other chemical species, the dissolution of a copper anode to produce copper ions, or a combination of both of these. These methods offer advantages over conventional antifouling paint-type coatings, including the ability to protect surfaces some distance away, control of antifouling properties to suit the conditions, and 5 to 10 times the useful life. Operating parameters are discussed for physico-chemical systems which provide effective fouling protection without excessive m
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Montoya, R., A. Ortiz-Ozuna, and J. Genesca. "The Transient pH Distribution of the Electrolyte During Mg Galvanic Corrosion." In CONFERENCE 2024. AMPP, 2024. https://doi.org/10.5006/c2024-20878.

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Abstract To better understand the Mg galvanic corrosion, a gel electrolyte was employed. The gel electrolyte was doped with a pH indicator, serving to unveil and monitor the development of alkaline fronts that evolve in parallel with the evolution of H2. Using RGB (Red, Green, Blue) image processing as a semi-quantitative technique, it became feasible to generate transient 2D maps with proper detail regarding the pH evolution into the electrolyte and to provide new information about the galvanic corrosion of Mg. Findings revealed a significant pH decrease in regions where Mg dissolution was mo
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Watson, M. K., and J. Postlethwaite. "Numerical Simulation of Crevice Corrosion." In CORROSION 1990. NACE International, 1990. https://doi.org/10.5006/c1990-90156.

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Abstract The process of crevice corrosion consists of anodic metal dissolution from the alloy to the crevice solution, cathodic reduction of oxygen on the bold surface of the metal outside the crevice, metal ion hydrolysis reactions, and mass transfer between the crevice solution and the bulk solution. The mass transfer process mechanisms are ionic migration and diffusion. An improved mathematical model has been developed for the numerical simulation of the incubation period of crevice corrosion. The model utilizes a new equation for the transport processes, which includes both ionic migration
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Ghanbari, Elmira, Alireza Saatchi, and Digby D. Macdonald. "The Role of Al Interstitials on the Passivation of AA2098-T851 Based on the Mixed Potential Model." In CORROSION 2018. NACE International, 2018. https://doi.org/10.5006/c2018-11026.

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Abstract In this paper, the electrochemical behavior of the third-generation Al-Li alloy 2098 was investigated with a fundamental approach, where experimental results were theoretically analyzed in terms of the Point Defect Model (PDM). For this purpose, the AA2098-T851 was tested in NaHCO3 solution under a CO2 atmosphere to investigate the kinetics of formation and breakdown of the protective passive film. Experiments were performed at potentials where both metal dissolution and the hydrogen evolution reaction (HER) occur. Electrochemical impedance spectroscopy (EIS) was conducted at potentia
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