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1
Singh, Jaswant. "Gas entrainment by liquid sprays." Thesis, University of Leeds, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.432173.
Повний текст джерела
2
Goodwin, Martin. "Transient liquid sheets and their relationship to GDI sprays." Thesis, Loughborough University, 2004. https://dspace.lboro.ac.uk/2134/14379.
Повний текст джерелаАнотація:
Developments m Gasoline Direct Injection, GDI, technology have enhanced the viability of long tenn SI engine development. Many automotive manufacturers are developing and offer production cars with first generation GDI engines. GDI fuel injection strategies provide power and effi ciency improvements, due to superior fuel metering, incylinder mixture preparation and the ability to run throttle-less under di fferent combustion modes depending on engine load. Although significant improvements in perfonnance and economy have been demonstrated, work is still required to optimise the GDI strategies fo r varying engine loads and emissions. Matching liquid fuel sheet break up and atomisation timescales to those of the charge motion occurring in the engine cylinder is essential. Many fundamental studies have investigated the mechanisms of liquid sheet break up, however, most have concentrated on steady state low pressure conditions. It is felt that little can be applied from these studies to analyse high pressure GDI sprays which produce an initial liquid sheet annulus then a complex hollow cone spray, transient in nature due to the cyclic behaviour of an SI engine. This experimental study assesses the liquid fuel sheet break up mechanism of a GDI pressure-swirl injector in the pressure range 10-50 bar. The fundamental study simplifies the problems associated with a 3-dimensional spray by considering a 2-dimensional transient liquid sheet and characterising the sheet wave structure and break up process. A unique rotary valve has been specifically designed and manufactured to allow the break up of a transient flat liquid sheet to be studi ed under an injection pressure range of 10-50 bar. A precursor to liquid sheet break up is the appearance of perforations in the sheet. The onset of perforations in the fl at sheet were measured as a function of distance downstream from the nozzle for a range of sheet velocities 12-36m/s; i.e. Reynolds number range 800 - 2400. This highlighted a peak in the perforation onset length between 20 and 25 bar injection pressure; i.e. sheet velocity of approximately 25m/s. Subsequent increases of sheet velocity lead to a reduction in the perforation onset length, strongly indicating that above 25rn/s, aerodynamic forces dominated the sheet break up process. Spreading the liquid laterally, introduced sheet stretching, which affected the position of the perfo ration onset by as much as 30% at higher injection pressures. Estimations of sheet thickness at the perforation location were calculated to be in the range 0.05-0. llrrun. Particle Image Velocimetry, PIV, and Laser Doppler Anemometry, LDA, was used to assess the liquid sheet velocity flow field, which indicated the presence of large velocity gradients in both the axial direction and across the sheet respectively.
3
Khan, Nazmul. "Sparse Lagrangian MMC-LES Combustion Modelling of Liquid Sprays." Thesis, The University of Sydney, 2017. https://vuir.vu.edu.au/39312/.
Повний текст джерелаАнотація:
This thesis provides a detailed investigation of turbulent combustion modelling of liquid sprays. Modelling of liquid sprays is a challenging task due to the existence of a wide range of complexities in both liquid and gas phases and their interaction in the spray and combustion process. In such multiphase flow, there is a need to address all physical processes involved in each individual phase and jointly in the interaction of phases. In a multiphase flow, there are physical processes with respect to flow, energy, chemical reactions, and flame propagation. In the liquid phase, the physical processes include dispersion, evaporation, volatile formation and exchange of heat and mass transfer with the gas phase. In the gas phase, there is turbulent flow, mixing and chemical reactions. The model that is derived and validated in this thesis extends the existing capabilities of liquid spray modelling by introducing a novel model for heat and mass transfer in the liquid phase that is coupled with the gas phase simulation. The model is comprised of an Eulerian LES model for the gas phase mass, momentum, and reference mixture fraction, a Lagrangian fuel particle (LFP) model for the dispersion, evaporation, heat and mass transfer and volatile formation, and a second Lagrangian stochastic particle model based on a multiple mapping conditioning (MMC) to represent the turbulent reacting chemistry. This study simulates three experimental validation cases from the University of Sydney combustion lab: non-reacting kerosene, evaporating acetone and reacting acetone. The axial and radial profiles of droplets, gas velocity and gas phase temperature are in good agreement with experimental measurements. Importantly the results of the finite volume and Lagrangian stochastic particle schemes are shown to be consistent with each other.
4
Khan, Nazmul. "Sparse Lagrangian MMC-LES Combustion Modelling of Liquid Sprays." Thesis, The University of Sydney, 2017. http://hdl.handle.net/2123/17689.
Повний текст джерелаАнотація:
This thesis provides a detailed investigation of turbulent combustion modelling of liquid sprays. Modelling of liquid sprays is a challenging task due to the existence of a wide range of complexities in both liquid and gas phases and their interaction in the spray and combustion process. In such multiphase flow, there is a need to address all physical processes involved in each individual phase and jointly in the interaction of phases. In a multiphase flow, there are physical processes with respect to flow, energy, chemical reactions, and flame propagation. In the liquid phase, the physical processes include dispersion, evaporation, volatile formation and exchange of heat and mass transfer with the gas phase. In the gas phase, there is turbulent flow, mixing and chemical reactions. The model that is derived and validated in this thesis extends the existing capabilities of liquid spray modelling by introducing a novel model for heat and mass transfer in the liquid phase that is coupled with the gas phase simulation. The model is comprised of an Eulerian LES model for the gas phase mass, momentum, and reference mixture fraction, a Lagrangian fuel particle (LFP) model for the dispersion, evaporation, heat and mass transfer and volatile formation, and a second Lagrangian stochastic particle model based on a multiple mapping conditioning (MMC) to represent the turbulent reacting chemistry. This study simulates three experimental validation cases from the University of Sydney combustion lab: non-reacting kerosene, evaporating acetone and reacting acetone. The axial and radial profiles of droplets, gas velocity and gas phase temperature are in good agreement with experimental measurements. Importantly the results of the finite volume and Lagrangian stochastic particle schemes are shown to be consistent with each other.
5
Shen, Jihua. "Formation and characteristics of sprays from annular viscous liquid jet breakup." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp02/NQ32723.pdf.
Повний текст джерела
6
Manin, Julien Luc. "ANALYSIS OF MIXING PROCESSES IN LIQUID AND VAPORIZED DIESEL SPRAYS THROUGH LIF AND RAYLEIGH SCATTERING MEASUREMENTS." Doctoral thesis, Universitat Politècnica de València, 2011. http://hdl.handle.net/10251/10189.
Повний текст джерелаАнотація:
Desde su introducción, los motores de combustión interna alternativos han sido desarrollados con el fin de reducir el consumo y mejorar el rendimiento y facilidad de conducción. Con el tiempo, la contaminación se ha convertido en un factor crítico para los gobiernos y como consecuencia se han introducido regulaciones para reducir las emisiones contaminantes de los motores.
Con el constante progreso tecnológico requerido por las normas contra la contaminación, la inyección directa se ha vuelto indispensable en cuanto a los motores Diesel. La introducción de combustible en la cámara de combustión permite un alto nivel de control sobre la liberación de energía del proceso de combustión. Con las novedosas estrategias de combustión empleadas, el proceso de inyección se ha convertido en el tema principal y el chorro es el factor principal.
El trabajo realizado a lo largo de este estudio para analizar el proceso de mezcla aire-combustible se basa en el desarrollo de técnicas láser de diagnóstico. Inicialmente, la inyección de Diesel se ha estudiado en una atmósfera isoterma para evitar la evaporación del combustible (dodecano) a través del uso de una iluminación estructurada para medir la distribución de la mezcla mediante el control de la dispersión de Mie. La aplicación de la dispersión de Rayleigh en la parte evaporada del chorro inyectado en una cámara a alta temperatura ha permitido la obtención de la distribución de combustible en una situación equivalente a la existente en un motor real.
El análisis y comparación de los distintos parámetros del chorro inyectado en condiciones de baja o alta temperatura da la posibilidad de entender mejor lo que es el proceso de mezcla en los motores Diesel. Por otra parte, según el estado del fluido inyectado, líquido o gaseoso, las condiciones experimentales tendrán diferentes efectos y la mezcla aire-combustible también tendrá un comportamiento distinto.Manin ., JL. (2011). ANALYSIS OF MIXING PROCESSES IN LIQUID AND VAPORIZED DIESEL SPRAYS THROUGH LIF AND RAYLEIGH SCATTERING MEASUREMENTS [Tesis doctoral no publicada]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/10189
Palancia
7
Palmero, David A. "Comparison of cyclic voltammetry and HPLC for the determination of phenol in over-the counter sore throat sprays /." View abstract, 1999. http://library.ctstateu.edu/ccsu%5Ftheses/1540.html.
Повний текст джерелаАнотація:
Thesis (M.S.)--Central Connecticut State University, 1999.Thesis advisor: James V. Arena, Ph. D. " ... in partial fulfillment of the requirements for the degree of Master of Science in Chemistry." Includes bibliographical references (leaf 48).
8
Hieber, Simone E. "An investigation of the mesh dependence of the stochastic discrete droplet model applied to dense liquid sprays." [Houghton, MI] : Michigan Technological University, 2001. http://e-collection.ethbib.ethz.ch/show?type=dipl&nr=105.
Повний текст джерела
9
Sushanta, Mitra. "Breakup Process of Plane Liquid Sheets and Prediction of Initial Droplet Size and Velocity Distributions in Sprays." Thesis, University of Waterloo, 2001. http://hdl.handle.net/10012/931.
Повний текст джерелаАнотація:
Spray models are increasingly becoming the principal tools in the design and development of gas turbine combustors. Spray modeling requires a knowledge of the liquid atomization process, and the sizes and velocities of subsequently formed droplets as initial conditions. In order to have a better understanding of the liquid atomization process,the breakup characteristics of plane liquid sheets in co-flowing gas streams are investigated by means of linear and nonlinear hydrodynamic instability analyses. The liquid sheet breakup process is studied for initial sinuous and varicose modes of disturbance. It is observed that the sheet breakup occurs at half-wavelength intervals for an initial sinuous disturbance and at full-wavelength intervals for an initial varicose disturbance. It is also found that under certain operating conditions, the breakup process is dictated by the initial varicose disturbance compare to its sinuous counterpart. Further, the breakup process is studied for the combined mode and it is found that the sheet breakup occurs at half- or full-wavelength intervals depending on the proportion of the individual sinuous and varicose disturbances. In general, the breakup length decreases with the increase in the Weber number, gas-to-liquid velocity and density ratios. A predictive model of the initial droplet size and velocity distributions for the subsequently formed spray is also formulated here. The present model incorporates the deterministic aspect of spray formation by calculating the breakup length and the mass-mean diameter and the stochastic aspect by statistical means through the maximum entropy principle based on Bayesian entropy. The two sub-models are coupled together by the various source terms signifying the liquid-gas interaction and a prior distribution based on instability analysis, which provides information regarding the unstable wave elements on the two liquid-gas interfaces. Experimental investigation of the breakup characteristics of the liquid sheet is performed by a high speed CCD camera and the measurement of the initial droplet size and distributions is conducted by phase-Doppler interferometry. Good agreement of the theoretical breakup length with the experiment is obtained for a planar, an annular and a gas turbine nozzle. The predicted initial droplet size and velocity distributions show reasonably satisfactory agreement with experimental data for all the three types of nozzles. Hence this spray model can be utilized to predict the initial droplet size and velocity distributions in sprays, which can then be implemented as a front-end subroutine to the existing computer codes.
10
Regan, Nicholas J. "The characterisation of liquid sprays injected from circular and non-circular nozzles into high speed subsonic cross-airstreams." Thesis, University of Sussex, 2012. http://sro.sussex.ac.uk/id/eprint/38645/.
Повний текст джерелаАнотація:
This study was motivated by a need to better understand the sprays that can develop when oil leaks occur in gas turbine engines. Current gas turbine engines incorporate an extensive network of oil distribution pipes which deliver lubrication oil to bearings and seals at various locations across the engine. Parts of the oil pipe network are situated in hot, high pressure engine cavities where an oil leak, from a fractured pipe or leaking seal, could ignite and lead to an engine fire. Oil leaks in gas turbine engines create liquid injection in cross-airstream situations, a subject which has been widely studied for combustion systems. However, previous studies are almost exclusively based on circular nozzle geometries. For a fractured oil pipe, the geometry through which the oil leaks approximates to a slot shape rather than a circular nozzle. Sprays which develop in cross-airstreams are most sensitive to the parameters of Weber number (Weg eq) and momentum flux ratio (q). A wide range for these parameters are considered to be possible in engine oil leak scenarios because of the variety of crack dimensions possible and range of airflow conditions across the different sections of the engine; from zero to in excess of We g eq = 4000 and q = 300 could be possible in extreme cases. The aim of this study was to generate and then characterise sprays in representative conditions. The main focus was the characterisation of the droplets which formed in the sprays, with the key objective of providing validation data for CFD codes. Droplet characterisation was performed using a phase Doppler particle analysis system. High speed video as well as pulsed laser sheet digital imaging were also used in the study to provide insight into upstream features of the spray field. A 0.5 x 5.38 mm slot shaped nozzle geometry was used in two orientations; perpendicular alignment ↓↓⦶ and parallel alignment ↓↓⦶ . Water was injected into a cross-airstream over a twelve point test matrix with momentum flux ratios (q) values within the range of 4 ≳ q ≳ 32 and Weber number (We g eq) values within the range of 300 ≳ We g eq ≳ 1600. The position of the spray was highly dependent on slot nozzle orientation. The spray was considerably further offset from the nozzle injection wall in parallel alignment ↓↓⦶ , compared to the perpendicular alignment ↓↓⦶. However, the centre-line distribution of Arithmetic Mean Diameter (AMD) was similar for both orientations, albeit offset further from the injection wall for the parallel slot nozzle. The underlying structure of droplet size distribution was consistent with results for sprays from circular nozzles. At low liquid injection pressures the sprays produced by the perpendicular aligned slot ↓↓⦶ exhibited impingement, producing large droplets in the near wall region. Where impingement was not present, the data showed that AMD was not significantly influenced by the orientation of the slot nozzle; with all tests generating results in the range of 16 μm ≳ AMD ≳ 80 μm.
11
Melo, Hugo Henrique Tinoco [UNESP]. "Análise dos sprays de jatos de injetores de motor foguete utilizando um sistema de processamento digital de imagens." Universidade Estadual Paulista (UNESP), 2011. http://hdl.handle.net/11449/97043.
Повний текст джерелаАнотація:
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A utilização de imagens digitais para extrair informações de objetos tem sido uma solução amplamente empregada em pesquisas científicas e em processos industriais. A contínua redução nos preços de equipamentos, a facilidade do uso de softwares e a simples integração com recursos de informática tem feito que muitos processos migrem para esta solução mais ágil, confiável e econômica. A indústria aeroespacial, que possui uma cadeia de produção não contínua e exige a avaliação de todos os seus componentes para obtenção de um nível de confiança elevado, encontra no emprego do processamento digital de imagens uma solução versátil e eficaz para análise das características de cada componente. Neste trabalho é apresentado um programa, desenvolvido em LabVIEW™, para medição dos sprays cônicos de jatos de injetores de motor foguete utilizando um sistema de processamento digital de imagens para sua análise. São apresentadas também as metodologias até então utilizadas para efetuar este tipo de medida. Os sprays dos jatos são desenvolvidos na saída do injetor, são exibidos visualmente durante o teste hidráulico a frio e tem influência direta no desempenho do motor foguete. A utilização desta nova ferramenta permitiu a realização desta medida de forma automática, com o fornecimento da incerteza de medição em níveis de confiança pré-estabelecido e mostrou-se ser mais exata e precisa que as metodologias anteriores
The usage of digital images to extract information from objects has been a solution widely used in scientific research and in industrial processes. The continued reduction in prices of equipment, the facility of software manipulation and the simple integration with computing resources has done many processes to migrate to this more flexible, reliable and economical solution. The aerospace industry, which has a chain of production that is not continuous and requires the evaluation of all its components to obtain a high confidence level, finds in the usage of digital image processing a versatile and effective solution for analysis of the characteristics of each component . This paper presents a program developed in LabVIEW™, to measure the rocket engine conic spray jet by using a digital image processing system for analysis. It is also presented the methodologies previously used to perform this type of measurement. The jet sprays are developed at the exit of the injector, are displayed visually during the cold hydraulic test and it has directly influences on the performance of the rocket engines. The usage of this new tool allowed us to make the measurement automatically with the supply of uncertainty together with a pre-established confidence level and it proved to be more accurate and precise than previous methodologies
12
Melo, Hugo Henrique Tinoco. "Análise dos sprays de jatos de injetores de motor foguete utilizando um sistema de processamento digital de imagens /." Guaratinguetá : [s.n.], 2011. http://hdl.handle.net/11449/97043.
Повний текст джерелаАнотація:
Orientador: Fernando de Azevedo SilvaBanca: João Zangrandi Filho
Banca: Silvana Aparecida Barbosa
Resumo: A utilização de imagens digitais para extrair informações de objetos tem sido uma solução amplamente empregada em pesquisas científicas e em processos industriais. A contínua redução nos preços de equipamentos, a facilidade do uso de softwares e a simples integração com recursos de informática tem feito que muitos processos migrem para esta solução mais ágil, confiável e econômica. A indústria aeroespacial, que possui uma cadeia de produção não contínua e exige a avaliação de todos os seus componentes para obtenção de um nível de confiança elevado, encontra no emprego do processamento digital de imagens uma solução versátil e eficaz para análise das características de cada componente. Neste trabalho é apresentado um programa, desenvolvido em LabVIEW™, para medição dos sprays cônicos de jatos de injetores de motor foguete utilizando um sistema de processamento digital de imagens para sua análise. São apresentadas também as metodologias até então utilizadas para efetuar este tipo de medida. Os sprays dos jatos são desenvolvidos na saída do injetor, são exibidos visualmente durante o teste hidráulico a frio e tem influência direta no desempenho do motor foguete. A utilização desta nova ferramenta permitiu a realização desta medida de forma automática, com o fornecimento da incerteza de medição em níveis de confiança pré-estabelecido e mostrou-se ser mais exata e precisa que as metodologias anteriores
Abstract: The usage of digital images to extract information from objects has been a solution widely used in scientific research and in industrial processes. The continued reduction in prices of equipment, the facility of software manipulation and the simple integration with computing resources has done many processes to migrate to this more flexible, reliable and economical solution. The aerospace industry, which has a chain of production that is not continuous and requires the evaluation of all its components to obtain a high confidence level, finds in the usage of digital image processing a versatile and effective solution for analysis of the characteristics of each component . This paper presents a program developed in LabVIEW™, to measure the rocket engine conic spray jet by using a digital image processing system for analysis. It is also presented the methodologies previously used to perform this type of measurement. The jet sprays are developed at the exit of the injector, are displayed visually during the cold hydraulic test and it has directly influences on the performance of the rocket engines. The usage of this new tool allowed us to make the measurement automatically with the supply of uncertainty together with a pre-established confidence level and it proved to be more accurate and precise than previous methodologies
Mestre
13
Viera, Sotillo Juan Pablo. "Experimental study of the effect of nozzle geometry on the performance of direct-injection diesel sprays for three different fuels." Doctoral thesis, Universitat Politècnica de València, 2017. http://hdl.handle.net/10251/81857.
Повний текст джерелаАнотація:
This thesis studies the influence of internal nozzle flow characteristics over a large spectrum of experimental conditions and diagnostics. Experiments were carried out for two nozzle geometries---cylindrical and conical single hole nozzles---and three different fuels. Two of the fuels are pure components---n-heptane and n-dodecane---while the third fuel consists of a three-component surrogate to better represent the physical and chemical properties of diesel fuel. Measurements include a complete hydraulic characterization consisting of instantaneous injection rate and spray momentum flux measurements; a high-speed visualization of isothermal liquid spray; a high-speed visualization of the evaporative inert spray, imaging liquid and vapor phases simultaneously and finally, a high-speed visualization of the high temperature reactive spray, imaging vapor phase and OH* chemiluminescence for each injection event. All high-temperature diagnostics were performed in a continuous flow test chamber that allows an accurate control on a wide range of thermodynamic conditions (up to 1000 K and 15 MPa).
The experimental findings from this work, and the large database obtained (available for download at: http://www.cmt.upv.es/DD01.aspx), could be used to validate CFD models that could help the community understand the fundamental driving mechanisms behind these observations.En esta tesis se estudia la influencia del flujo interno sobre un amplio espectro de condiciones y diagnósticos experimentales. Se realizaron experimentos para dos geometrías de tobera---toberas cilíndrica y cónica de un único orificio---y tres combustibles. Dos de los combustibles son puros---n-heptano y n-dodecano--- mientras el tercero es un combustible sustituto que consiste en una mezcla de tres componentes que busca representar mejor las propiedades físicas y químicas del diesel. Las medidas incluyen una caracterización hidráulica completa, compuesta por tasa de inyección y cantidad de movimiento instantáneas; una visualización de alta velocidad del chorro líquido isotermo; una visualización de alta velocidad del chorro inerte evaporativo, con captura simultánea de las fases líquida y vapor y, finalmente, una visualización del chorro reactivo a alta temperatura, con captura de la fase vapor y la quimioluminiscencia del radical OH* para cada evento de inyección. Todos los diagnósticos en condiciones de alta temperatura fueron realizados en una maqueta de alta presión y temperatura de flujo constante que permite controlar con precisión un rango amplio de condiciones termodinámicas (hasta 1000 K y 15 MPa). Los resultados experimentales y la gran base de datos obtenida en este trabajo (disponible en: http://www.cmt.upv.es/DD01.aspx), podrían ser utilizados para validar modelos CFD detallados que podrían ayudar a la comunidad científica a entender mejor los mecanismos fundamentales que producen los resultados observados.
Aquesta tesi estudia la influència del flux intern sobre un gran espectre de condicions i diagnòstics experimentals. Es van realitzar experiments per a dos geometries de tovera---toveres ci¿líndrica i cónica amb un únic orifici---i tres combustibles. Dos dels combustibles són purs---n-heptà i n-dodecà--- mentre el tercer combustible consisteix en una mescla de tres components que formen un combustible substitut que busca representar millor les propietats físiques i químiques del dièsel. Les mesures inclouen una caracterització hidràulica completa, composta per taxa d'injecció i quantitat de moviment instantanis; visualització d'alta velocitat del doll líquid isoterme; visualització d'alta velocitat del doll inert evaporatiu, capturant simultàniament les fases líquid i vapor i, finalment, una visualització del doll reactiu a alta temperatura, capturant la fase vapor i la quimioluminiscència del radical OH per a cada esdeveniment d'injecció. Tots els diagnòstics en condicions d'alta temperatura van ser realitzats en una insta¿lació d'alta pressió i temperatura amb flux constant que permet controlar amb precisió un ampli rang de condicions termodinàmiques (fins a 1000 K i 15 MPa). Els resultats experimentals i la gran base de dades obtinguda en aquest treball (disponible a la web en: http://www.cmt.upv.es/dd01.aspx), podrien ser utilitzats per tal de validar models CFD detallats que podrien ajudar a la comunitat científica a entendre millor els mecanismes fonamentals que produeixen aquestes observacions.
Viera Sotillo, JP. (2017). Experimental study of the effect of nozzle geometry on the performance of direct-injection diesel sprays for three different fuels [Tesis doctoral no publicada]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/81857
TESIS
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Savic, Sasha. "Liquid fuel spray characteristics." Thesis, University of Brighton, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.324470.
Повний текст джерела
15
Rajakaruna, Hobinanuwan Tikiri Banda. "A mathematical model for liquid fuel spray combustion." Thesis, De Montfort University, 1997. http://hdl.handle.net/2086/5207.
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16
Saeed, Muhammad Tariq. "Application of kinetic models to the design of liquid-liquid extraction spray columns." Thesis, Imperial College London, 1989. http://hdl.handle.net/10044/1/47638.
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Antipas, George. "A study of the spray forming of Al-Li alloys." Thesis, University of Surrey, 1995. http://epubs.surrey.ac.uk/843719/.
Повний текст джерелаАнотація:
The atomization and spray forming of liquid metals was studied. Melt break up algorithms were developed to predict the size distribution of the spray generated as well as secondary aspects of the atomization phenomena. In the model, which is based on the Surface Wave Formation (SWF) theory, the relative velocity between the gas and melt phase was thought to induce a sinusoidal disturbance on the surface of the melt column. Depending on the flow conditions such a disturbance could grow in amplitude and cause certain parts of the surface to be torn off the liquid column. A number of different approaches to the problem of drop disintegration were also considered. Based on experimental observations of the critical Weber number made by other authors, a criterion was formulated, which allowed the secondary break up of drops to be predicted. In addition, an analytical model originally presented by Wolf and Andersen (1965), which was intended to describe the stripping mode of secondary disintegration, was also revised and incorporated into a computer routine. Finally a comparison of the models was made against the predictions of the empirical Lubanska (1970) equation. High Speed Photography studies of a water column atomized by gas revealed that the formation of a surface wave was the prominent mechanism perturbing and finally disintegrating the column into a fine spray of drops. Phase Doppler Anemometry studies of the water/gas jet produced during the atomization of a water column indicated that there was a gradient of particle sizes across the spray. The finer fragments were found in the close proximity of the centre axis of the conical flow, with particles becoming larger in size as the distance from the centre increased. Vaporization of the water drops near the centre due to the high gas velocities should be taken into account when interpreting these results. The break up algorithms were tested against experimental data for a number of different A1 and Fe alloys with various solute elements, obtained using a close coupled atomization facility. Case studies were made for the effects of gas injection pressure, initial melt stream diameter, initial melt stream exit velocity and number of atomizing gas jets on the mean powder particle size produced. The algorithms could predict the distribution of drop sizes in space, a feature that enabled the simulation of spray forming runs and the direct comparison of the numerical predictions to experimental data. The shapes of the Al-1.6wt%Hf and the Al-1.6wt%Hf-3.2wt%Li alloy preforms and the particle distribution along the radial direction of the Al-1.6wt%Hf preform were calculated and compared favourably with experimental data. Microscopic observation of Al-1.6wt%Hf and Al-1.6wt%Hf-3.2wt%Li preforms indicated that there was a variance of particle size as well as grain size along the radial direction of the spray. The grain size was found to decrease with increasing distance from the central axis of the preform, while the radial distribution of drop diameters did not reveal a distinct trend.
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Gosselin, Valentin. "Etude expérimentale de la formation d'un spray à partir d'un film liquide annulaire cisaillé." Thesis, Toulouse, INPT, 2019. http://www.theses.fr/2019INPT0004.
Повний текст джерелаАнотація:
Un moyen d'accroître l'efficacité et de réduire la pollution dans les domaines du transport et de l'énergie consiste à concevoir des injecteurs de carburant produisant une meilleure atomisation. Au cours de cette thèse, des expériences ont été effectuées sur un injecteur airblast souvent utilisé dans les turbines à gaz. Pour réaliser ces expérimentations, un dispositif modèle en configuration annulaire a été créé afin d'étudier le cisaillement d'un film d'eau soumis à un écoulement d'air interne à forte vitesse. La technique d'imagerie rapide par ombroscopie a été utilisée pour analyser le développement du film liquide (fréquence et célérité des ondes) et l'atomisation de la nappe en sortie d'injecteur (modes de rupture). La modification des paramètres d'injection (vitesse des écoulements) a révélé un lien entre la topologie du film liquide et le régime d'atomisation primaire. Finalement, à titre exploratoire, l'influence de la géométrie de l'injecteur (longueur de préfilm) sur le mode d'atomisation primaire a également été mise en évidenceOne way to increase efficiency and reduce pollution in the transportation and energy domain is designing fuel injectors with better atomization. In this thesis, experiments were performed on a prefilming airblast atomizer often used in gas turbines. For this purpose, a model device with a cylindrical configuration was created to study the shearing of a film of water subjected to an internal high speed air flow. High speed shadowgraphy technique was used to analyse the development of the liquid film (frequency and wave celerity) and the atomization of the sheet at the injector outlet (breakup mode). The modification of the injection parameters (velocity of flows) revealed a link between the topology of the liquid film and the primary atomization regime. Finally,the influence of the geometry of the injector (prefilming length) about the mode of primary atomization was also highlighted with an exploratory study
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Elmedhem, Bashir A. "Modelling of liquid fuel combustion in furnaces." Thesis, University of Glasgow, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.325303.
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Heising, Raymond. "Effectiveness of pulsed spray combustion for suppression of combustion instabilities." Thesis, Georgia Institute of Technology, 1999. http://hdl.handle.net/1853/16682.
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Resende, de Azevedo Jacqueline. "Etude de la cristallisation d’une nouvelle molécule à efficacité cardiotonique dans un mélange liquide ionique - eau." Thesis, Ecole nationale des Mines d'Albi-Carmaux, 2014. http://www.theses.fr/2014EMAC0009/document.
Повний текст джерелаАнотація:
La cristallisation par effet anti-solvant, comme technique de production de micro/nanoparticules, présente certains inconvénients. En effet, pour des molécules nouvellement synthétisées ou découvertes, comme le LASSBio-294, les solubilités dans l'eau et dans les solvants organiques sont faibles ce qui limite l'application de cette opération. L'utilisation de solvants alternatifs ouvre de nouvelles perspectives de recristallisation de ce type de molécules. Dans ce travail, nous nous sommes intéressés à la cristallisation du LASSBio-294 en utilisant un liquide ionique comme solvant. Ce sont des sels organiques fondus à température ambiante, qui ont la particularité d’avoir une tension de vapeur nulle. Ils constituent une nouvelle classe de solvants non volatiles et ininflammables qui présentent des propriétés originales. Dans un premier temps, des liquides ioniques (LIs) dérivés du cation imidazolium ont été utilisés comme solvant alternatif. La solubilité a été mesurée dans 5 LIs,dans l’eau et dans des mélanges eau/LI. Dans l’eau pure la solubilité est très faible (5 ppm). En revanche, dans certains LIs, elle est supérieure à 200 mg/g solution. Les résultats de solubilité dans des mélanges eau/LI ont permis de choisir le rapport eau/LI pour l’obtention d’un bon rendement en solide. En complément, une étude de la stabilité du solide en suspension a été menée dans différents systèmes aqueux. Cette étude a montré sa possible hydrolyse. Dans un deuxième temps, la recristallisation a été réalisée avec le 1-éthyl-3-méthylimidazolium méthyl phosphonate [emim][CH3O(H)PO2] comme solvant et l’eau comme anti-solvant. Deux approches sont présentées en vue de favoriser le mélange : l'utilisation de dispositifs de mélange et l'introduction des ultrasons pendant le processus de cristallisation. L’influence de paramètres tels que le rapport anti-solvant/solvant, la concentration initiale et la présence d'additifs a été étudiée. Les solides formés puis séchés en étuve ont été caractérisés par granulométrie laser, microscopie électronique à balayage, diffractométrie de rayons X, calorimétrie différentielle à balayage et test de dissolution. Malgré une diminution de la taille des particules élémentaires, l'état d'agglomération des cristaux obtenus n'a pas permis une augmentation de la vitesse de dissolution. En modifiant le mode de séchage (séchage par atomisation), cette agglomération est réduite et la dissolution améliorée. De plus, la présence d'un polymère entérique en solution lors du séchage par atomisation des cristaux synthétisés a eu un effet notable sur la structure des agglomérats formés. Ces derniers peuvent se désagréger, se disperser et se dissoudre rapidementThe anti-solvent crystallization allows obtaining micro/nanoparticles, but it presents some disadvantages. In the case of new pharmaceutical molecules, as the LASSBio-294, the solubility in water or organic solvents is very low limiting the application of this operation. The use of Ionic Liquids (ILs) as alternative solvents opens new perspectives in pharmaceutical processing through anti-solvent crystallization process. Unlike conventional solvents, ILs are entirely composed of ions. ILs are organic salts, usually liquid at room temperature, and which are composed of a relatively large asymmetric organic cation and of an inorganic or organic anion. ILs derived from imidazolium cation are used as alternative solvents for this drug, water being used as anti-solvent. First, the solubility is measured in 5 ILs, in water and in water/IL mixtures. In pure water, the solubility is very low (5 ppm). However, for some ILs, it is greater than 200 mg/g solution. The results of solubility in water/IL mixtures permit to choose a water/IL ratio leading to a good solid theoretical yield. Then recrystallization is performed with 1-ethyl-3-methylimidazolium methyl phosphonate [emim][CH3O(H)PO2] as the preferred solvent. Antisolvent crystallization represents a class of process characterized by the mixing between a solution and an antisolvent to produce solid particles. The influence of solvent/anti-solvent ratio, initial concentration, and additives is studied. The solids formed and dried in an oven are characterized by laser granulometry, scanning electron microscopy, X-ray diffraction, differential scanning calorimetry, and dissolution test. Despite the decrease of elementary particles size, the agglomeration state of particles does not permit to improve the dissolution rate. The agglomeration is reduced and the dissolution improved by modifying the drying process (spray drying). Moreover, the presence of an enteric polymer during the spray drying process has a significant impact on the structure of the formed agglomerates. These are disaggregated, dispersed and dissolved very quickly
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Tambe, Samir B. "Liquid Jets in Subsonic Crossflow." University of Cincinnati / OhioLINK, 2004. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1100876702.
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Valha, Jan. "Interfacial instability and spray heat transfer problems of two phase flow." Thesis, Middlesex University, 1996. http://eprints.mdx.ac.uk/6408/.
Повний текст джерелаАнотація:
This thesis describes detailed investigations of two different problems in gas-liquid two-phase flow, namely, a study of interfacial stability in a partially filled cylinder subjected to vertical oscillations and a study of heat and mass transfer from hot spray droplets injected into an closed vessel. The interfacial instability study considers experimental data taken from the author's previous work. Cylinders of various diameters, partially filled with water, ethanol or glycerol were subjected to a sinusoidal vertical motion. The critical acceleration, causing the interfacial wave to grow unstable, was found to be approximately constant for a given cylinder diameter, independent on the amplitude of the forcing oscillations. The experiments also indicate that the critical Acceleration always decreases with increasing cylinder diameter. A mathematical analysis of the interfacial instability is based on a stability investigation of a Mathieu equation. It is shown that the experimental data fall into unstable regions for a single, first mode of oscillations. This finding is supported by the experimental analysis given by Cilliberto and Gollub. The analysis shows the effects of the liquid column height on the interfacial instability to be dependent on tanh (k..l.). This multiplier is equal to 1 for the column heights of 250mm, 500 mm and 750 mm, investigated, and a given cylinder diameter, thus having no effect on the results. Computational analysis of the interfacial problem is developed which is based on the simplified MAC method incorporating the Continuum Surface Force (CSF) model for simulating the effects of surface tension. Computational experiments were run for water and glycerol, the two liquids of significantly different properties. The results are presented in the form of time sequenced plots showing the interfacial positions and graphs relating the interfacial wave amplitude and time. Stability of the interface is found to be dependent on the initial surface disturbance. Growth of the interfacial wave is observed in some cases. In the range of situations investigated, surface tension effects are found to have only a small influence both on the stability and frequency of the interfacial oscillations. The period of interfacial oscillations with no forcing vibrations is found to be in good agreement with the period predicted by mathematical analysis. Influence of the initial disturbance profile was also investigated. The results indicate that the interfacial wave adopts oscillatory behaviour similar to the other cases. The oscillation frequency of the interfacial wave undergoing forcing vibrations is found to match the findings of the mathematical analysis. The wave oscillates with an angular velocity equal to the multiples of the half the forcing vibration angular velocity, co/2. In the second investigation a testing rig was constructed to investigate the heat and mass transfer processes in dense hot sprays injected into an enclosed cylindrical vessel. Heat and mass transfer rates were investigated indirectly from the measurements of the gas - vapour mixture pressure rise in the cylinder. The experiments covered different combinations of the parameters influencing the processes. The number and size of spray nozzles, the vessel volume, the type of gas and the initial pressure level in the cylinder were investigated. The experimental results indicate that, for the range of solid cone nozzles tested, the heat and mass transfer characteristics are, to a first approximation independent of the size of the nozzles. The results also show that the rise of spray chamber internal pressure is directly proportional to liquid temperature and flowrate. An analysis, based on energy balances for the whole cylinder, has yielded a new dimensionless group incorporating the important parameters of droplet heat transfer namely the droplet velocity and radius, spray chamber dimensions, gravity, conductivity and convectivity. A good match has been found between the analytical results and experimental findings. An improved analysis, incorporating the effect of evaporation from drops, is also presented. It is based on simultaneous solution of energy and mass balance equations for a single droplet. Again, good agreement with the experimental results is found. Both analyses indicate that, for this particular case of dense, evaporative spray, the Nusselt number tends to have a value equal to I.
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Aubignat, Emilie. "Contribution à la compréhension et à la maîtrise du procédé de projection plasma de suspensions céramiques." Thesis, Belfort-Montbéliard, 2014. http://www.theses.fr/2014BELF0238.
Повний текст джерелаАнотація:
La projection plasma de suspensions (SPS) est un procédé de revêtement de surface qui consiste à injecter une suspension (particules solides d’environ 1 μm ou moins, dispersées dans une phase liquide) dans un jet de plasma énergétique. Les particules sont chauffées, accélérées en direction d’un substrat, écrasées et soumises à une solidification très rapide (de l’ordre de 106 K.s-1). Couche après couche, un dépôt se forme en surface du substrat et lui apporte de nouvelles propriétés fonctionnelles. Cette variante de la projection plasma conventionnelle permet la fabrication de revêtements avec des épaisseurs plus fines de quelques dizaines de μm et une échelle microstructurale réduite, pouvant conduire à améliorer, par exemple, les performances de dureté ou de conductivité thermique des dépôts. Bien que ce procédé soit étudié depuis le milieu des années 1990 et connaisse un intérêt grandissant, les applications industrielles ne sont pas finalisées et leur développement nécessite d’être poursuivi. En effet, l’injection d’une suspension dans un jet thermique conduit à des phénomènes complexes tels que la fragmentation des gouttes de suspension ou encore l’évaporation de la phase liquide. A ce jour, ces mécanismes ne sont pas parfaitement compris et maîtrisés et méritent d’être étudiés pour comprendre les interactions de ces fines particules avec le plasma. Les travaux décrits dans ce mémoire s’intéressent au cas de la projection SPS de céramiques avec un atomiseur bi-fluide comme système d’injection. Deux matériaux ont été choisis : l’alumine, connue pour sa difficulté à être projetée conventionnellement et dont la formation de phases cristallines particulières constitue une source d’informations sur l’histoire thermique des particules, ainsi que l’yttrine, qui permet de confirmer les tendances observées pour l’alumine. Dans un premier temps, l’optimisation de l’injection de la suspension a été effectuée en travaillant sur deux axes. Le premier axe concerne la formulation des suspensions, qui a conduit à l’obtention, avec différentes phases liquides, de suspensions stables et dispersées, de propriétés parfaitement connues. De telles suspensions assurent une reproductibilité du procédé à ce niveau et limitent le bouchage du système d’injection. Le deuxième axe porte sur la conception mécanique en trois étapes d’un atomiseur pneumatique approprié au procédé SPS. Cette étude a commencé par la caractérisation d’une buse commerciale notamment par des tests d’injection de suspension dans le plasma. Les tests étant peu concluants, l’étude s’est poursuivie par la mise au point d’une nouvelle géométrie d’atomiseur inspirée du modèle commercial. Les essais ont conduit à la réalisation de cordons et de dépôts satisfaisants. Cette étude s’est terminée enfin par l’optimisation de sa géométrie grâce à la mise en évidence de l’influence de plusieurs paramètres-clé sur les caractéristiques du jet atomisé. Dans un second temps, des outils de diagnostic ont été mis en oeuvre pour mesurer la qualité de l’injection. Le jet de suspension a été caractérisé en termes de géométrie et de tailles de gouttes, respectivement par ombroscopie et diffraction laser. L’ombroscopie a été réutilisée pour l’optimisation de l’injection de la suspension dans le plasma en permettant le réglage en temps réel des pressions d’entrée de l’atomiseur. Les propriétés des particules en vol ont ensuite été étudiées grâce à des collectes de particules sur substrat et à la vélocimétrie par images de particules (PIV). Cet outil a apporté des informations complémentaires sur l’injection de la suspension. Enfin, les revêtements obtenus ont été caractérisés en termes de morphologie (MEB), taux de porosité (analyse d’images MEB et USAXS) et de phases cristallines (DRX et EBSD). Le couplage des informations obtenues entre ces différentes techniques a permis de faire ressortir le rôle de la phase liquide et de la charge massique sur la microstructureSuspension plasma spray (SPS) is a surface coating process that consists in injecting a suspension (solid particles of about 1 μm or less, dispersed in a liquid phase) in a high-energy plasma flow. Particles are heated, accelerated towards a substrate, flattened and submitted to a rapid solidification (order of 106 K.s-1). Layer after layer, a coating is formed on the substrate surface and brings new functional properties. This variation of the conventional plasma spray process allows the manufacturing of coatings with finer thickness of few tens of μm and a reduced structural scale that can lead to improved coating properties, like hardness or thermal conductivity. Even though this process has been studied since the middle of the 1990’S and known a fast-growing interest, industrial applications are not finalized and their development needs to be pursued. Indeed, the suspension injection in a thermal jet leads to complex phenomena such as suspension droplet fragmentation or liquid phase evaporation. Up to now, these mechanisms are not perfectly understood and controlled and deserve to be further studied to understand interactions between these fine particles and the plasma. This thesis focuses on the SPS process with ceramic suspensions and a twin-fluid nozzle as injection system. Two materials were chosen: alumina, known for its difficulty to be conventionally sprayed and whose crystalline phase formation represents a source of information about particle thermal history, and also yttria, in order to confirm the tendencies observed for alumina. Firstly, the suspension injection was optimized by working on two areas. The first area concerns suspension formulation. This led to obtain, with different liquid phases, stable and dispersed suspensions, whose properties are perfectly known. Such suspensions ensure reproducibility of the process at this level and limit the risk of injection system clogging. The second area is about the three-step mechanical conception of a pneumatic atomizer, adapted to the SPS process. This study began with the characterization of a commercial nozzle, in particular by testing the suspension injection into a plasma flow. Tests being little convincing, the study was carried on with the development of a new atomizer geometry, inspired from the commercial model. Trials drove to the manufacturing of satisfying spray beads and coatings. This study was finally completed with the optimization of this new geometry by highlighting the influence of several key parameters on the atomized jet features. Secondly, diagnostic tools were implemented to qualify the injection. Suspension jet was characterized in terms of geometry and droplet sizes, using respectively shadowgraphy and laser diffraction. Shadowgraphy was used again for optimizing the suspension injection into plasma by allowing the adjustment in real time of inlet atomizer pressures. In-flight particle properties were then studied thanks to particle collection onto a substrate and particle image velocimetry (PIV). This tool also provided additional information on the suspension injection. Finally, the resulting coatings were characterized in terms of morphology (SEM), porosity rate (SEM image analysis and USAXS) and crystalline phases (DRX and EBSD). The cross-checking of the information obtained with all these techniques brought out the role of the suspension liquid phase and of the mass load on the coating microstructure. These works contributed to enhance the knowledge about the SPS process and justified the use of a twin-fluid nozzle to obtain specific microstructures of coatings, whose functional characterizations have still to be done
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Merrill, Craig F. "Spray generation for liquid wall jets over smooth and rough surfaces." Thesis, Monterey, Calif. : Springfield, Va. : Naval Postgraduate School ; Available from National Technical Information Service, 1998. http://handle.dtic.mil/100.2/ADA354473.
Повний текст джерелаАнотація:
Dissertation (Ph.D. in Mechanical Engineering) Naval Postgraduate School, September 1998."September 1998." Dissertation supervisor(s): T. Sarpkaya. Includes bibliographical references (p. 171-176). Also available online.
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Gomaa, Hassan [Verfasser]. "Modeling of Liquid Dynamics in Spray Laden Compressor Flows / Hassan Gomaa." München : Verlag Dr. Hut, 2014. http://d-nb.info/1064560040/34.
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DeBerardinis, Jeffrey T. Whalen Stephen Charles. "Nitrogen mass balance for spray fields fertilized with liquid swine waste." Chapel Hill, N.C. : University of North Carolina at Chapel Hill, 2006. http://dc.lib.unc.edu/u?/etd,262.
Повний текст джерелаАнотація:
Thesis (M.S.)--University of North Carolina at Chapel Hill, 2006.Title from electronic title page (viewed Oct. 10, 2007). "... in partial fulfillment of the requirements for the degree of Masters of Science in the Department of Environmental Sciences and Engineering." Discipline: Environmental Sciences and Engineering; Department/School: Public Health.
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Rochaya, David. "Numerical simulation of spray combustion using bio-mass derived liquid fuels." Thesis, Cranfield University, 2007. http://hdl.handle.net/1826/2231.
Повний текст джерелаАнотація:
The main objective of this work is to create a robust model for two-phase liquid spray
combustion flow using vegetable oils, to investigate the flow structure generated by a
swirler array with different fuels, and secondly to assess and optimise the capability of
the CFD to predict accurately the results obtained experimentally and eventually
enhance CFD model development and simulation. Validation is achieved by
comparing the numerical results obtained with CFD with the experimental
measurements.
The purpose of this research is to increase the scientific understanding of the
fundamental mechanisms of the spray combustion process using a carbon neutral fuel
such as ethanol and biodiesel. In fact, very few numerical simulations of liquid
biomass fuels in gas turbine systems are available in the literature.
The flames are simulated using the commercial code FLUENT. The
combustion/turbulence interaction is modelled using the laminar flamelet approach
with detailed chemistry modelled using the OPPDIFF model from CHEMKIN.
While the experiments could be carried out only up to 3 atm, the simulations were
further extended to a maximum pressure of 10 atm. The FLUENT results were
assessed qualitatively and quantitatively between the experimental measurements and
the simulation. The cold flow features have been captured by the present simulations
with a good degree of accuracy. Effect of air preheating was investigated for the
biodiesel, and sensitivity to droplet size and spray angles variation were analysed.
Good agreement was obtained for ethanol except in the fuel lean region due to failure
of the FLUENT laminar flamelet model to capture local flame extinction while
biodiesel simulation resulted in a significant overprediction of the flame temperature
especially in the downstream region and satisfactory results further upstream. The
results show the importance of setting proper droplet initial conditions, since it will
significantly affect the structure of the flame.
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Colby, Jonathan A. "Flow Field Measurements in a Counter-Swirl Stabilized Liquid Combustor." Thesis, Georgia Institute of Technology, 2006. http://hdl.handle.net/1853/10470.
Повний текст джерелаАнотація:
To adhere to the current requirements for NOx and CO emissions in combustion systems, modern land and air based gas turbine engines often operate in the fuel lean regime. While operating near the lean blow out (LBO) limit does reduce some harmful emissions, combustor stability is sacrificed and extinction becomes a major concern. To fully understand the characteristics of lean operation, an experimental study was conducted to map the time averaged flow field in a typical industrial, counter-swirling, liquid fuel combustor. This study examined two steady-state operating conditions, both near the lean extinction limit for this swirl burner. Using an LDV/PDPA system, 2-D mean and fluctuating velocities, as well as Reynolds stresses, were measured throughout the combustor. These measurements were taken for both the non-reacting and reacting flow fields, enabling a direct analysis of the result of heat addition and increased load on a turbulent swirling flow field. To further understand the overall flow field, liquid droplet diameter measurements were taken to determine the fuel spray characteristics as a function of operating pressure and rated spray angle. Chemical composition at the combustor exit was also measured, with an emphasis on the concentrations of both CO and NOx emissions. This large database of aerodynamic and droplet measurements improves understanding of the swirling, reacting flow field and aids in the accurate prediction of lean blow-out events. With this understanding of the lean blow-out limit, increased fuel efficiency and decreased pollutant emissions can be achieved in industrial combustors, especially those used for thrust in the airline industry.
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Thawley, Scott. "Spatio-temporal Characteristics of a Spray from a Liquid Jet in Crossflow." Thesis, Virginia Tech, 2006. http://hdl.handle.net/10919/31276.
Повний текст джерелаАнотація:
A liquid jet in a crossflow is often used to as a fuel injection method for combustion systems. Parameters such as penetration and core trajectory are used as characterization for the spray and specification of design criteria for combustor geometry. In addition to penetration and core trajectory, mapping the mass flux in space and time is an important part of modeling evaporation and global equivalence ratio throughout the combustor. Accurate prediction of these spray characteristics allows for a stable and robust combustor design.
The break up of a liquid jet in a crossflow is an extremely complex phenomenon in both combination of mechanisms and variability of possible paths progressing from a liquid column to a distribution of individual droplets. In each region separate governing forces control the behavior of the liquid phase. Accordingly, different measurement techniques and different factors must be considered in each region.
Presented are the results of measurements using Phase Doppler Analyzer, PDA, and a time resolved, digital, particle imaging velocimetry system, TRDPIV. The measurements include instantaneous and time-averaged liquid phase velocity fields, spray penetration and core location in the near field and far field of the spray resulting from the liquid jet breakup.
With the TRDPIV system, the holistic properties of all three segments of a jet in crossflow were acquired with a single measurement. This allowed for comparison of system characteristics across not only individual pieces of one segment of the jet, for example PDA measurements of many droplets in one point of the far field spray, but characteristics across the entire system including the liquid column, near field spray, and far field spray simultaneously in a fashion that allowed for direct comparison between the different segments.Master of Science
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Youssef, Rageey M. "Modeling the effect of a spray on a liquid film on a heated surface." Morgantown, W. Va. : [West Virginia University Libraries], 2007. https://eidr.wvu.edu/etd/documentdata.eTD?documentid=5074.
Повний текст джерелаАнотація:
Thesis (Ph. D.)--West Virginia University, 2007.Title from document title page. Document formatted into pages; contains xv, 136 p. : ill. (some col.). Vita. Includes abstract. Includes bibliographical references (p. 100-105).
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Dung, Nguyen Ngoc. "Study on ignition and combustion of gas-jet and liquid-spray fuels." Kyoto University, 2009. http://hdl.handle.net/2433/126416.
Повний текст джерелаАнотація:
Kyoto University (京都大学)0048
新制・課程博士
博士(エネルギー科学)
甲第14967号
エネ博第210号
新制||エネ||46(附属図書館)
27405
UT51-2009-M881
京都大学大学院エネルギー科学研究科エネルギー変換科学専攻
(主査)教授 塩路 昌宏, 教授 石山 拓二, 准教授 川那辺 洋
学位規則第4条第1項該当
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Mackrory, Andrew John. "Characterization of Black Liquor Sprays for Application to Entrained-Flow Processes." Diss., CLICK HERE for online access, 2006. http://contentdm.lib.byu.edu/ETD/image/etd1593.pdf.
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Mandumpala, devassy Bejoy. "Atomization modeling of liquid jets using an Eulerian-Eulerian model and a surface density approach." Thesis, Aix-Marseille, 2013. http://www.theses.fr/2013AIXM4701/document.
Повний текст джерелаАнотація:
Dans les moteurs à combustion interne, l'injection de carburant est une phase essentielle pour la préparation du mélange et la combustion. En effet, la structure du jet liquide joue un rôle essentiel pour la qualité du mélange du combustible avec le gaz. Le présent travail porte sur les phénomènes d'atomisation de jet liquides dans les conditions opératoires des moteurs diesel. Dans ces conditions, la morphologie du jet liquide comprend une phase liquide séparée (c'est à dire un noyau liquide) et une phase liquide dispersée (c'est à dire un spray). Ce manuscrit décrit les étapes de développement d'un nouveau modèle d'atomisation, pour un jet liquide à grande vitesse, basée sur une approche eulérienne diphasique. Le phénomène d'atomisation est modélisée par des équations définissant une densité de surface pour le noyau liquide en plus de celle des gouttelettes du spray. Ce nouveau modèle a été couplé avec un système d'équations diphasique et turbulent de type Baer-Nunziato. Le processus de rupture des ligaments et son éclatement subséquent en gouttelettes sont modélisés en utilisant des connaissances rassemblées à partir des expériences disponibles et des simulations numériques précises. Dans la région dense du jet de liquide, l'atomisation primaire est modélisée comme un processus de dispersion en raison de l'étirement turbulent de l'interface, à partir du côté du liquide en plus du côté du gaz. Différents cas tests académiques ont été effectués afin de vérifier la mise en œuvre numérique du modèle dans le code IFP-C3D. Enfin, le modèle est validé avec les résultats DNS récemment publiés dans des conditions typiques de moteurs Diesel à injection directeIn internal combustion engines, the liquid fuel injection is an essential step for the air/fuel mixture preparation and the combustion process. Indeed, the structure of the liquid jet coming out from the injector plays a key role in the proper mixing of the fuel with the gas in the combustion chamber. The present work focuses on the liquid jet atomization phenomena under Diesel engine conditions. Under these conditions, liquid jet morphology includes a separate liquid phase (i.e. a liquid core) and a dispersed liquid phase (i.e. a spray). This manuscript describes the development stages of a new atomization model, for a high speed liquid jet, based on an eulerian two-phase approach. The atomization phenomenon is modeled by defining different surface density equations, for the liquid core and the spray droplets. This new model has been coupled with a turbulent two-phase system of equations of Baer-Nunziato type. The process of ligament breakup and its subsequent breakup into droplets are handled with respect to available experiments and high fidelity numerical simulations. In the dense region of the liquid jet, the atomization is modeled as a dispersion process due to the turbulent stretching of the interface, from the side of liquid in addition to the gas side. Different academic test cases have been performed in order to verify the numerical implementation of the model in the IFP-C3D software. Finally, the model is validated with the recently published DNS results under typical conditions of direct injection Diesel engines
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Durand, Corinne. "Atomisation de gouttes liquides sur une cible tournante microstructurée." Thesis, Grenoble, 2014. http://www.theses.fr/2014GRENI035.
Повний текст джерелаАнотація:
L’objectif de ce travail est de concevoir un outil d’atomisation adapté à la production de poudres de carburede tungstène dans l’entreprise Technogenia, située à Saint-Jorioz (74). Plus généralement, nous avons étudiéune nouvelle conception d’atomiseur rotatif pour lequel les surfaces d’atomisation sont orientées selon un angled’incidence non nul. Une telle orientation permet alors d’exploiter de façon plus efficace la fréquence de rotationde l’atomiseur ainsi que les forces de centrifugation et de Coriolis. A partir de cette base de réflexion, troisgéométries de surface d’atomisation ont été étudiées : des surfaces lisses, des surfaces pourvues de structurationsde long de leur bord de fuite et des surfaces matricées de perforations.Les différents modes de déstabilisation des écoulements liquides ont été observés grâce à l’acquisition de vidéosultra-rapides des différentes étapes de l’impact d’une goutte unique sur les différentes géométries de surfacesd’atomisation étudiées. Les processus d’atomisation peuvent ainsi varier entre la rupture de jets liquides régulierscausée par des instabilités de type Rayleigh-Plateau et la rupture de nappes liquides causée par des instabilitésde type Rayleigh-Taylor et/ou l’initiation de perforations au coeur des nappes et films liquides. Les vidéos dessprays aqueux ainsi que l’observation au microscope des poudres métalliques nous permettent de caractériser lessprays produits. Sur l’ensemble de nos expériences nous observons que la finesse de l’atomisation s’améliore àmesure que la fréquence de rotation augmente ; ce qui constitue l’objectif prioritaire du procédé développé dans lathèse. Cependant, les surfaces texturées, certes compatibles avec les liquides classiques (aqueux ou organiques),ne le sont plus avec les contraintes induites par du métal à haute température de fusion, tel le carbure detungstène fondu objet de la thèse. En conséquence, seules les surfaces lisses sont aujourd’hui retenues et fontl’objet de développements dans le cadre de la production de poudres métalliques au sein de TechnogeniaThe aim of this work is to design a spray tool for the production of tungsten carbide powder for the companyTechnogenia, located in Saint-Jorioz (74). Thus, we have studied a new design of rotary atomizer based onatomization surface oriented at a non-zero incidence angle. Such an orientation can then allow to use moreeffectively the rotation frequency of the atomizer and the centrifugal and Coriolis forces. From this base reflection,three geometries of atomization surface were studied : smooth surfaces, surfaces with serrated structurationsalong their trailing edge and multi-perforated surfaces.The different destabilization modes of liquid flows were observed through high-speed videos of the different stagesof the single drop impact on each atomization surfaces. The atomization process can thus vary between liquid jetbreakup caused by Rayleigh-Plateau instabilities and liquid sheet breakup caused by Rayleigh-Taylor instabilitiesand/or initiating of holes in liquid films or sheets. Videos of aqueous sprays and microscopic observation of metalpowders allow us to characterize sprays. On all of our experiments, we observe that the atomisation gets better(producing finer spray), as the frequency of rotation increases. Although the textured surfaces are compatiblewith usual liquids (aqueous or organical), they can’t stand the constraints imposed by metal with a high meltingtemperature such as tungsten carbide, the object of this thesis. Therefore, only the smooth surfaces are nowthe subject of an industrial development to produce metallic powder with Technogenia company
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Sharma, Arvindh R. "Liquid Jet in Oscillating Crossflow: Characterization of Near-Field and Far-Field Spray Behavior." University of Cincinnati / OhioLINK, 2015. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1439281517.
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Gomes, Pimentel Rogério. "Measurement and prediction of droplet size distribution in sprays." Doctoral thesis, Université Laval, 2006. http://hdl.handle.net/20.500.11794/18194.
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Sescu, Carmen. "Experimental and Computational Study on Liquid Atomization by Slinger Injector." University of Toledo / OhioLINK, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=toledo1310163402.
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Blanchard, Ghislain Emmanuel. "Modélisation et simulation multi-échelles de l'atomisation d'une nappe liquide cisaillée." Thesis, Toulouse, ISAE, 2014. http://www.theses.fr/2014ESAE0043/document.
Повний текст джерелаАнотація:
Émissions polluantes, les motoristes souhaitent contrôler au mieux l’atomisation du carburant, injecté généralement sous forme de jets ou de nappes liquides. Les essais étant long et coûteux, leur remplacement par un outil numérique capable de simuler le processus d’atomisation permettrait non seulement une réduction des coûts importante mais faciliterait également la phase de conception. Toutefois, en raison du caractère multi-échelle du phénomène, il est difficile de le décrire dans son ensemble avec les approches habituellement utilisées en mécanique des fluides numérique.L’objectif de cette thèse est de concevoir une nouvelle approche qui permettra à terme de simuler l’atomisation pour une configuration industrielle complète. Celle-ci consiste à coupler deux types de modèles. Le premier, dit modèle bifluide, est un modèle à deux fluides compressibles basé sur les équations de Navier-Stokes diphasiques. Celui-ci permet de décrire les grandes échelles du phénomène d’atomisation correspondant à la formation de ligaments et d’amas liquides dans la zone proche de l’injecteur. Le second, dit modèle de spray, est basé sur une équation cinétique. Dans la zone située en aval de l’injecteur, ce dernier permet de décrire de manière statistique l’évolution du brouillard de gouttelettes issues de la fragmentation primaire du jet de carburant. Le point délicat, à la fois sur le plan de la modélisation et sur celui de l’algorithmique, réside dans le couplage des deux modèles. Celui ci a été réalisé grâce à l’introduction de deux modèles auxiliaires permettant de traiter le transfert de liquide entre le modèle bifluide et le modèle de spray par atomisation ou ré-impact.L’approche proposée a été appliquée à la simulation numérique de nappes liquides cisaillées. Les comparaisons entre les résultats numériques et des résultats expérimentaux montrent que le modèle bifluide permet de prévoir l’influence de la géométrie et des conditions d’injection sur l’atomisation primaire de la nappe liquide. Le modèle d’atomisation permet quant à lui, de reproduire le caractère instationnaire des mécanismes de production de gouttes lors du transfert de la phase liquide depuis le modèle bifluide vers celui de spray. Des cas de ré-impact valident également la robustesse et la généralité de la méthodologie de couplageIn order to improve efficiency of aircraft combustion chambers and reduce polluting emissions,engine manufacturers try to achieve a better control on fuel atomization, which is usually injectedas a jet or liquid sheet. As experiments are expensive and time consuming, a numerical tool able to simulate atomization would be a powerful asset in engine conception design. However, simulation ofthe whole atomization process with commonly used approach in computational fluid dynamics is still prohibitive due to the multi-scale nature of the phenomenon.The objective of this thesis is to develop a new approach allowing the simulation of the spray formation for a industrial configuration in the near future. This involves coupling of two types of models.The first one, called two-fluid model, is based on the Navier-Stokes equations for two immiscible compressible fluids. This one is used to describe the large scales of the atomization mechanism corresponding to the formation of ligaments and liquids blobs in the near-injector area. The second one,called spray model, is based on a kinetic equation. Further downstream from the injector, this model describes statistically the evolution of the droplet cloud produced by the primary fragmentation of liquid jet. The main difficulty, in terms of both modeling and algorithmic, is the coupling of these twomodels.This has been achieved by introducing an atomization and an impact models which ensure liquid transfer between the two-fluid model and the spray model.This new approach was applied to the numerical simulation of sheared liquid sheets. Comparisons between numerical and experimental results show how the two-fluid model predicts the influence of injector geometry and injection conditions on the primary atomization of the liquid sheet. Concerning droplets production, the atomization model is able to reproduce the unsteady nature of this mechanism when transferring liquid phase from the two-fluid model to the spray model. Test cases for the impact model also validate the robustness and generality of the coupling approach
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Ganvir, Ashish. "Microstructure and Thermal Conductivity of Liquid Feedstock Plasma Sprayed Thermal Barrier Coatings." Licentiate thesis, Högskolan Väst, Avd för tillverkningsprocesser, 2016. http://urn.kb.se/resolve?urn=urn:nbn:se:hv:diva-9061.
Повний текст джерелаАнотація:
Thermal barrier coating (TBC) systems are widely used on gas turbine components to provide thermal insulation and oxidation protection. TBCs, incombination with advanced cooling, can enable the gas turbine to operate at significantly higher temperatures even above the melting temperature of the metallic materials. There is a permanent need mainly of environmental reasons to increase the combustion turbine temperature, hence new TBC solutions are needed.By using a liquid feedstock in thermal spraying, new types of TBCs can be produced. Suspension plasma/flame or solution precursor plasma spraying are examples of techniques that can be utilized for liquid feedstock thermal spraying.This approach of using suspension and solution feedstock, which is an alternative to the conventional solid powder feed stock spraying, is gaining increasing research interest, since it has been shown to be capable of producing coatings with superior coating performance.The objective of this research work was to explore relationships between process parameters, coating microstructure, thermal diffusivity and thermal conductivity in liquid feedstock thermal sprayed TBCs. A further aim was to utilize this knowledge to produce a TBC with lower thermal diffusivity and lower thermal conductivity compared to state-of-the-art in industry today, i.e. solid feed stock plasma spraying. Different spraying techniques, suspension high velocity oxy fuel,solution precursor plasma and suspension plasma spraying (with axial and radialfeeding) were explored and compared with solid feedstock plasma spraying.A variety of microstructures, such as highly porous, vertically cracked and columnar, were obtained. It was shown that there are strong relationships between the microstructures and the thermal properties of the coatings.Specifically axial suspension plasma spraying was shown as a very promising technique to produce various microstructures as well as low thermal diffusivity and low thermal conductivity coatings.
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Siegert, Roberto. "A novel process for the liquid feedstock plasma spray of ceramic coatings with nanostructural features." [S.l.] : [s.n.], 2005. http://deposit.ddb.de/cgi-bin/dokserv?idn=980671728.
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Hinsberg, Nils Paul van. "Investigation of drop and spray impingement on a thin liquid layer accounting for the wall film topology." Aachen Shaker, 2009. http://d-nb.info/1000840115/04.
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Marty, Sylvain. "Contribution à l’étude de l’atomisation assistée d’un liquide : instabilité de cisaillement et génération du spray." Thesis, Université Grenoble Alpes (ComUE), 2015. http://www.theses.fr/2015GREAI122/document.
Повний текст джерелаАнотація:
L’atomisation assistée est un procédé de formation d’un spray de gouttelettes issu d’une nappe liquide sous l’action d’un courant gazeux à forte vitesse dans un injecteur. Ce procédé est très utilisé dans de nombreuses applications industrielles. Nous étudions la succession d’instabilités hydrodynamiques qui génère les gouttes du spray à l’aide d’une méthode LIF pour mesurer la fréquence des vagues et d’une sonde optique pour la granulométrie des gouttes. Nous validons expérimentalement un nouveau modèle de stabilité linéaire inviscide pour l’instabilité de cisaillement, intégrant un profil de vitesse avec déficit à l’injection. Des simulations numériques et un modèle spatio-temporel de stabilité linéaire sont utilisés pour mettre en avant de nouveaux mécanismes de déstabilisation, de croissance des vagues et de création de gouttes. Les lois d’échelles connues prédictives du diamètre moyen des gouttes en fonction du Weber gaz sont testées pour de nouvelles variables d’étudeAssisted atomization is a process used to form a spray of droplets. A slow liquid phase is strippedby the action of a strong gas current in order to generate the spray. This process is used in manyindustrial applications. We study the succession of hydrodynamic instabilities generating dropletsby means of a LIF method to measure the frequency and growthrate of waves, and with an opticalprobe to measure drop size and velocity. We validate experimentally a model including an interfacialvelocity deficit in the inviscid stability analysis. Experiments are compared to numerical simulationsand spatiotemporal stability analysis results : the confrontation of these three approaches is used tobring forward new mechanisms of destabilization, growth of waves and creation of drops. We assessthe influence of liquid thickness and dynamic pressure ratio on the dependency of the mean dropletdiameter with the Weber number
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Dressler, Daniel. "An experimental investigation of Newtonian and non-Newtonian spray interaction with a moving surface." Thesis, University of British Columbia, 2006. http://hdl.handle.net/2429/71.
Повний текст джерелаАнотація:
As a logical extension of previous work conducted into viscoelastic atomization, initially motivated by the need to improve spray coating transfer efficiencies, an experimental investigation into the spray-surface interaction for a number of Newtonian and non-Newtonian substitute test liquids is presented. Three model elastic liquids of varying polymer molecular weight and three inelastic liquids of varying shear viscosity were sprayed upon a moving surface to isolate the effect of elasticity and shear viscosity, respectively, on spray impaction behavior. In addition, two liquids exhibiting shear thinning behavior and an industrial top of rail liquid friction modifier, KELTRACK, for use in the railroad industry, were included in the spray tests. High-speed photography was used to examine the impingement of these liquids on the surface.
Ligaments, formed as a consequence of a liquid’s viscoelasticity, were observed impacting the surface for 300K PEO, 1000K PEO, and KELTRACK. These ligaments were broadly classified into four groups, based on their structure. Splashing of elastic liquid ligaments and droplets led to filamentary structures being expelled from the droplet periphery, which were then carried away by the atomizing air jet, leading to reductions in transfer efficiency. The effect of increasing elasticity amongst the three varying molecular weight elastic solutions was shown to increase the splash threshold; a similar effect was noted with increasing shear viscosity.
Attempts were made at quantifying a critical splash-deposition limit for all test liquids however due to imaging system limitations, no quantitative conclusions could be made.
For KELTRACK, both droplets and ligaments spread and deposited on the rail surface upon impact, with no observed splash or rebound. Splash was only noted when droplets impinged directly on a previously deposited liquid film and even then, splashing was well contained. Thus, KELTRACK’s current rheological formulation proved to be very effective in ensuring high coating transfer efficiencies.
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Leboissetier, Anthony. "Simulation numérique directe de l'atomisation primaire d'un jet liquide à haute vitesse." Paris 6, 2002. http://www.theses.fr/2002PA066492.
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Dalla, Francesca Kevin. "Exfoliation du graphène par voie liquide en vue d'une application aux contacts électriques." Thesis, Université Paris-Saclay (ComUE), 2016. http://www.theses.fr/2016SACLS134/document.
Повний текст джерелаАнотація:
Le graphène est un matériau carboné exceptionnel de par ses propriétés électriques (mobilité électronique à température ambiante de 200 000 cm²V-¹s-¹), mécaniques (module d'Young de 1,5 TPA) et sa capacité à protéger un substrat de l’atmosphère. Cela en fait un candidat idéal comme revêtement de protection pour les dispositifs de connexion dont la partie active (le contact électrique) peut subir des dégradations sévères au cours du temps.. Un tel revêtement de protection doit en effet avoir des propriétés de robustesse et de conduction la plupart du temps antinomiques. La première étape de ce travail a consisté à mettre en œuvre un procède d’exfoliation en phase liquide afin de produire des suspensions de graphène ou de matériaux de type graphène. Différents type de caractérisations structurelles et électriques à l’échelle microscopique ont permis de déterminer des conditions d’exfoliation favorables en variant la nature du solvant et les conditions de sonication. Il s’est agi ensuite d’évaluer différents modes de dépôts permettant d’obtenir un revêtement de protection à partir de feuillets individuels. Les méthodes de trempé, évaporation, spray et filtration ont été caractérisées et ont montré leurs avantages et inconvénients. La méthode de filtration donne les films les plus couvrants mais pose le problème du transfert vers la surface à protéger : on a mis en évidence une contamination résiduelle difficile à éliminer. Les premiers résultats avec une méthode de spray industriel sans buse ont montré une grande réduction du frottement mais aussi la complexité des mécanismes régissant la qualité des dépôts. Les limites des différentes méthodes de dépôt pourraient être dépassées par l’utilisation de films composites polymère-graphèneGraphene is a special carbon material due to its electrical properties (electron mobility at room temperature 200 000 cm²V-¹s-¹), mechanical (Young modulus of 1.5 TPA) and ability to protect a substrate of atmosphere. This makes it an ideal candidate as a protective coating for connecting devices including the active portion (electrical contact) may suffer severe damage over time .. Such a protective coating must indeed have properties and robustness conducting most of the contradictory time. The first step of this work was to implement an exfoliation proceeds in the liquid phase to produce suspensions of graphene and graphene-like materials.Different types of structural and electrical properties at the microscopic scale have determined favorable conditions for exfoliation by varying the nature of the solvent and conditions of sonication. He then acted deposits evaluate different methods to obtain a protective coating from individual sheets. The methods of dip coating, drop casting, spray and filtration have been characterized and have shown their advantages and disadvantages. The filtration method gives the most covering films, but the problem of the transfer to the surface to be protected: it showed residual contamination difficult to remove. The first results with an industrial spray without nozzle method showed a large reduction in friction but also the complexity of the mechanisms governing the quality of deposits. Limitations of different deposit methods could be exceeded by the use of graphene-polymer composite films
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Marmottant, Philippe. "Atomisation d'un jet liquide par un courant gazeux." Phd thesis, Grenoble INPG, 2001. http://www.theses.fr/2001INPG0139.
Повний текст джерелаАнотація:
La fragmentation d'un jet liquide en un spray de gouttelettes est étudiée lorsque sa surface est soumise à un fort courant de gaz parallèle au jet. La visualisation du jet révèle qu'une étape transitoire précédant la formation des gouttelettes est la croissance de ligaments liquides à partir de la surface. En effet la surface est la croissance de ligaments liquides à partir de la surface. En effet la surface est instable vis-à-vis du cisaillement imposé par le courant gazeux. Initialement lisse elle est soumise à des ondulations axisymétriques grandissantes, dont la longueur d'onde est déterminée par l'épaisseur de la couche limite gazeuse. Les crêtes de ces ondulations présentent des modulations transverses dont l'espacement résulte d'une compétition entre les forces capillaires et l'inertie du gaz. L'allongement de ces modulations dans le courant gazeux crée les ligaments de liquide. Le devenir des ligaments est étroitement lié à l'espacement des modulations transverses. Leur brisure, qui se produit lorsque les forces capillaires les fragmentent, est l'acte de naissance de gouttes dont la taille moyenne est proportionnelle à cet espacement. Les tailles sont largement réparties autour de cette moyenne et un modèle basé sur l'interaction des tailles pendant la brisure rend compte de leur distribution. Le spray de gouttelettes qui résulte des brisures des ligaments présente aussi un large éventail de diamètres. Leur répartition est telle que le nombre de gouttelettes d'un diamètre donné décroît exponentiellement avec le diamètre. Le diamètre moyen est aussi proportionné à l'espacement transverse, il est inversement proportionnel à la vitesse du courant de gaz.
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Mead, Ryan M. "Analysis of Flow in a Spray Nozzle With Emphasis on Exiting Jet Free Surface." [Tampa, Fla.] : University of South Florida, 2003. http://purl.fcla.edu/fcla/etd/SFE0000138.
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Vernay, Clara. "Déstabilisation de nappes liquides d'émulsions diluées." Thesis, Montpellier, 2015. http://www.theses.fr/2015MONTS199/document.
Повний текст джерелаАнотація:
Le phénomène de dérive constitue un enjeu environnemental et sanitaire majeur lors de la pulvérisation de solutions phytosanitaires sur les surfaces agricoles. Sous l'action du vent, des gouttelettes peuvent dériver loin des champs ciblés et être source de pollution. Une stratégie pour limiter la dérive est de contrôler la distribution de taille des gouttes de spray, en réduisant la proportion de petites gouttes. Dans ce but, des additifs anti-dérives, tels que des émulsions diluées d'huile dans l'eau, ont été développés. Bien que largement étudiés, les effets de ces émulsions ne sont pas encore bien compris. L'objectif de cette thèse est d'élucider les mécanismes à l'origine de l'augmentation de la taille des gouttes de spray à base d'émulsions.La pulvérisation implique la fragmentation d'un flux de liquide par une buse hydraulique. A la sortie de la buse, une nappe libre de liquide est formée, puis déstabilisée en gouttes. Afin d'élucider les mécanismes à l'origine des effets anti-dérives des émulsions, nous étudions l'influence de ces émulsions sur les mécanismes de déstabilisation des nappes liquides. Une expérience modèle basée sur la collision d'une goutte de solution sur une cible solide est utilisée pour produire et visualiser des nappes liquides. Lors de l'impact, la goutte s'aplatit en une nappe qui s'étend radialement dans l'air, bordée par un bourrelet plus épais. Différents mécanismes de déstabilisation sont observés en fonction des propriétés des fluides. Une nappe d'eau pure s'étale radialement puis se rétracte par effet de la tension de surface ; simultanément, le bourrelet est déstabilisé en gouttes. Pour une émulsion diluée d'huile dans l'eau, le mécanisme de déstabilisation dominant est considérablement modifié: les nappes sont déstabilisées par la nucléation de trous qui perforent le film liquide lors de son expansion; les trous grandissent jusqu'à la formation d'un réseau de ligaments, qui est ensuite déstabilisé en gouttes.Une étude systématique de l'influence des paramètres physico-chimiques de l'émulsion, tels que la concentration en huile et la distribution de taille de gouttelettes d'huile, sur le mécanisme de perforation est conduite. Nous établissons une corrélation entre le nombre d'évènements de perforations observés dans les nappes modèles et la distribution de taille de gouttes de sprays formés avec des buses de pulvérisation agricoles. Ce résultat démontre la pertinence expérimentale de notre expérience modèle pour comprendre les mécanismes d'actions des formulations anti-dérives. Nous montrons ainsi que le mécanisme à l'origine de l'augmentation de la taille des gouttes de spray à base d'émulsion est un mécanisme de perforation.Pour comprendre les mécanismes à l'origine de la perforation, nous développons une technique optique permettant de mesurer le champ d'épaisseur de nappes liquides. Nous constatons que la formation d'un trou dans la nappe est systématiquement précédée par un amincissement local du film liquide. Nous montrons que cet amincissement est le résultat de l'entrée puis de l'étalement par effet Marangoni de gouttelettes d'huile à l'interface air/eau. L'amincissement du film liquide conduit in fine à sa rupture.Nous proposons un mécanisme de perforation en deux étapes: les gouttelettes d'huile (i) entrent à l'interface air/eau, et (ii) s'étalent à l'interface. La formulation de l'émulsion est un paramètre critique pour contrôler le processus de perforation. L'addition de sels ou de copolymères amphiphiles à des émulsions stabilisées par des tensio-actifs ioniques peut soit déclencher, soit inhiber le mécanisme de perforation. Nous montrons que l'entrée de gouttes d'huile à l'interface air/eau est l'étape limitante de ce mécanisme. Les interactions répulsives de nature stérique et/ou électrostatique entre les gouttelettes d'huile et l'interface stabilisent le film liquide, empêchant les gouttelettes d'entrer à l'interface, et ainsi inhibent le processus de perforationOne of the major environmental issues related to spraying of pesticides on cultivated crops is the drift phenomenon. Because of the wind, small droplets may drift away from the targeted crop and cause contamination. One way to reduce the drift is to control the spray drop size distribution and reduce the proportion of small drops. In this context, anti-drift additives have been developed, including dilute oil-in-water emulsions. Although being documented, the effects of oil-in-water emulsions on spray drop size distribution are not yet understood. The objective of this thesis is to determine the mechanisms at the origin of the changes of the spray drop size distribution for emulsion-based sprays.Agricultural spraying involves atomizing a liquid stream through a hydraulic nozzle. At the exit of the nozzle, a free liquid sheet is formed, which is subsequently destabilized into droplets. In order to elucidate the mechanisms causing the changes of the spray drop size distribution, we investigate the influence of emulsions on the destabilization mechanisms of liquid sheets. Model single-tear experiments based on the collision of one tear of liquid on a small solid target are used to produce and visualize liquid sheets with a fast camera. Upon impact, the tear flattens into a sheet radially expanding in the air bounded by a thicker rim. Different destabilization mechanisms of the sheet are observed depending on the fluid properties. A pure water sheet spreads out radially and then retracts due to the effect of surface tension. Simultaneously, the rim corrugates forming radial ligaments, which are subsequently destabilized into droplets. The destabilization mechanism is drastically modified when a dilute oil-in-water emulsion is used. Emulsion-based liquid sheets are destabilized through the nucleation of holes within the sheet that perforate the sheet during its expansion. The holes grow until they merge together and form a web of ligaments, which are then destabilized into drops.The physical-chemical parameters of the emulsion, such as emulsion concentration and emulsion droplet size distribution, are modified to rationalize their influence on the perforation mechanism. We correlate the size distribution of drops issued from conventional agricultural spray with the amount of perforation events in single-tear experiments, demonstrating that the single-tear experiment is an appropriate model experiment to investigate the physical mechanisms governing the spray drop size distribution of anti-drift formulations. We show that the relevant mechanism causing the increase of drops size in the emulsion-based spray is a perforation mechanism.To gain an understanding of the physical mechanisms at the origin of the perforation events, we develop an optical technique that allows the determination of the time and space-resolved thickness of the sheet. We find that the formation of a hole in the sheet is systematically preceded by a localized thinning of the liquid film. We show that the thinning results from the entering and Marangoni-driven spreading of emulsion oil droplet at the air/water interface. The localized thinning of the liquid film ultimately leads to the rupture of the film. We propose the perforation mechanism as a sequence of two necessary steps: the emulsion oil droplets (i) enter the air/water interface, and (ii) spread at the interface. We show that the formulation of the emulsion is a critical parameter to control the perforation. The addition of salt or amphiphilic copolymers can trigger or completely inhibit the perforation mechanism. We show that the entering of oil droplets at the air/water interface is the limiting step of the mechanism. Thin-film forces such as electrostatic or steric repulsion forces stabilize the thin film formed between the interface and the approaching oil droplets preventing the entering of oil droplets at the interface and so inhibit the perforation process
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Farah, Ali M. (Ali Muhamed). "Liquid dynamic compaction spray deposition of commercial and modified 3003 Al-alloy : process application and materials characterization." Thesis, Massachusetts Institute of Technology, 1996. http://hdl.handle.net/1721.1/41394.
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