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Готові списки джерел за темами / Organic-Inorganic complexes / Статті в журналах

Щоб переглянути інші типи публікацій з цієї теми, перейдіть за посиланням: Organic-Inorganic complexes.

Статті в журналах з теми "Organic-Inorganic complexes"

Автор: Grafiati

Опубліковано: 28 травня 2022

Оновлено: 31 липня 2025

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1

Jing, Benxin, Jie Qiu, and Yingxi Zhu. "Organic–inorganic macroion coacervate complexation." Soft Matter 13, no. 28 (2017): 4881–89. http://dx.doi.org/10.1039/c7sm00955k.

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2

Allain, Clémence, Sophie Favette, Lise‐Marie Chamoreau, Jacqueline Vaissermann, Laurent Ruhlmann, and Bernold Hasenknopf. "Hybrid Organic–Inorganic Porphyrin–Polyoxometalate Complexes." European Journal of Inorganic Chemistry 2008, no. 22 (2008): 3433–41. http://dx.doi.org/10.1002/ejic.200701331.

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3

Kolachi, Nida F., Tasneem G. Kazi, Hassan I. Afridi, et al. "Development of Extraction Methods for Speciation Analysis of Selenium in Aqueous Extracts of Medicinal Plants." Journal of AOAC INTERNATIONAL 94, no. 4 (2011): 1069–75. http://dx.doi.org/10.1093/jaoac/94.4.1069.

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Анотація:

Abstract Advanced extraction methods have been developed for direct speciation of dissolved inorganic and organic selenium (Se) species in aqueous extracts of medicinal plants (MPs). The inorganic species of Se (SeIV and SeVI) were separated from organic forms by adsorbing inorganic Se on alumina, while the organic Se was not retained. The retained inorganic Se species was eluted with 10 mL 0.2 M HCl. The total inorganic Se species was determined after prereduction of SeVI into SeIV with concentrated HCl. The SeIV in the eluent and total inorganic Se species were then complexed with diethyldit

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4

Marr, J. CA, J. Lipton, D. Cacela, J. A. Hansen, J. S. Meyer, and H. L. Bergman. "Bioavailability and acute toxicity of copper to rainbow trout (Oncorhynchus mykiss) in the presence of organic acids simulating natural dissolved organic carbon." Canadian Journal of Fisheries and Aquatic Sciences 56, no. 8 (1999): 1471–83. http://dx.doi.org/10.1139/f99-089.

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Copper bioavailability and toxicity to early life stage rainbow trout (Oncorhynchus mykiss) were evaluated by laboratory toxicity testing performed using organic acid mixtures. Geochemical modeling was used to design exposure solutions that simulate dissolved organic carbon (DOC) of a natural aquatic system and to determine the fractions of total Cu present as inorganic species (e.g., Cu2+) and as individual Cu-organic complexes. Failure time modeling indicated that mortality was best predicted by a combination of total inorganic Cu and distinct Cu-organic complexes. The Cu-organic complexes t

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5

Day, Peter. "Co-ordination complexes as organic–inorganic layer magnets." Journal of the Chemical Society, Dalton Transactions, no. 5 (1997): 701–6. http://dx.doi.org/10.1039/a607182a.

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6

Bezombes, Jean-Philippe, Claude Chuit, Robert R. J. Corriu, and Catherine Reyé. "Organic–inorganic hybrid materials containing metal phosphine complexes." Journal of Organometallic Chemistry 643-644 (February 2002): 453–60. http://dx.doi.org/10.1016/s0022-328x(01)01489-9.

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7

Liu, Yi, Zhiguo Gui, and Jialei Liu. "Research Progress of Light Wavelength Conversion Materials and Their Applications in Functional Agricultural Films." Polymers 14, no. 5 (2022): 851. http://dx.doi.org/10.3390/polym14050851.

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As new fluorescent materials, light wavelength conversion materials (light conversion agents) have attracted increasing attention from scientific researchers and agricultural materials companies due to their potential advantages in efficiently utilizing solar energy and increasing crop yield. According to the material properties, the light conversion agents can be divided into fluorescent dyes, organic rare-earth complexes, and inorganic rare-earth complexes. The current researches indicates that the fluorescent dyes have relatively high production costs, poor light stability, difficult degrad

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8

Sun, Xiao-Long, Yuan Wang, Hao-Qin Xiong, et al. "The Role of Surface Functional Groups of Iron Oxide, Organic Matter, and Clay Mineral Complexes in Sediments on the Adsorption of Copper Ions." Sustainability 15, no. 8 (2023): 6711. http://dx.doi.org/10.3390/su15086711.

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Heavy metal pollution is a global problem affecting the environment and human health. Sediment is the source sink of heavy metals in water. Under certain circumstances, the migration of heavy metals will cause water pollution. Therefore, it is of great significance to study sediment composition and composite complexes in the migration and transformation of heavy metals. To understand the adsorption mechanisms of composite complexes and improve the theoretical understanding of adsorption in multi-component complex systems, this study explored the characteristics and rules of Cu adsorption to or

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9

Cañón-Mancisidor, Walter, Matias Zapata-Lizama, Patricio Hermosilla-Ibáñez, Carlos Cruz, Diego Venegas-Yazigi, and Guillermo Mínguez Espallargas. "Hybrid organic–inorganic mononuclear lanthanoid single ion magnets." Chemical Communications 55, no. 99 (2019): 14992–95. http://dx.doi.org/10.1039/c9cc07868a.

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Анотація:

The plasticity of the coordination chemistry of lanthanoid ions has allowed the design and synthesis for the first time of a family of mononuclear hybrid organic–inorganic lanthanoid complexes with slow relaxation of the magnetization.

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10

Saha, Bapan, Rinkumani Deka, Anjali Das та Pradip Kr Bhattacharyya. "On the formation of sandwich and multidecker complexes via π⋯π interaction: a DFT study". New Journal of Chemistry 42, № 24 (2018): 19924–33. http://dx.doi.org/10.1039/c8nj04470h.

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11

Lazić, Vesna, and Jovan M. Nedeljković. "Photocatalytic Reactions over TiO2-Based Interfacial Charge Transfer Complexes." Catalysts 14, no. 11 (2024): 810. http://dx.doi.org/10.3390/catal14110810.

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Анотація:

The present review is related to the novel approach for improvement of the optical properties of wide bandgap metal oxides, in particular TiO2, based on the formation of the inorganic–organic hybrids that display absorption in the visible spectral range due to the formation of interfacial charge transfer (ICT) complexes. We outlined the property requirements of TiO2-based ICT complexes for efficient photo-induced catalytic reactions, emphasizing the simplicity of the synthetic procedure, the possibility of the fine-tuning of the optical properties supported by the density functional theory (DF

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12

Mikhailov, Oleg V. "Foreword from the Editor of Special Issue “Advanced Metal Chelate Complexes: Quantum-Chemical Consideration”." Materials 14, no. 3 (2021): 500. http://dx.doi.org/10.3390/ma14030500.

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The objects of the given Special Issue of Materials—coordination compounds or complexes, represent a kind of “boundary zone” between two main classes of chemical substances, inorganic and organic, and therefore differ in a significantly greater variety of their structural and physicochemical characteristics in comparison with both inorganic and organic compounds [...]

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13

Xue, Xiaonan, Huarui Wang, Yanbing Han, and Hongwei Hou. "Photoswitchable nonlinear optical properties of metal complexes." Dalton Transactions 47, no. 1 (2018): 13–22. http://dx.doi.org/10.1039/c7dt03989a.

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14

Shang, Xiaolei, Xiaoling Men, Qifeng Kuang, Shaojie Li, Da Li, and Zhidong Zhang. "Controllable Connection of Fe2Se3 Double Chains and Fe(dien)2 Complexes for Organic–Inorganic Hybrid Ferrimagnet with A Large Coercivity." Nanomaterials 13, no. 3 (2023): 487. http://dx.doi.org/10.3390/nano13030487.

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Анотація:

Organic–inorganic hybrid materials built by inorganic and organic building units have attracted intensive interest in the past decades due to unique chemical and physical properties. However, rare organic–inorganic hybrid materials show excellent permanent magnetic properties. Here, we develop a facile chemical solution method to bottom-up synthesize a new hybrid (Fe2Se3)2[Fe(dien)2]0.9. This hybrid phase with the space group P21/c (14) possesses a rodlike shape with a diameter of 100–2000 nm and a length of 5–50 µm. The hybrid rods are ferrimagnetic with a Curie temperature (TC) of 11 K. They

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15

Zapata-Lizama, Matias, Patricio Hermosilla-Ibáñez, Diego Venegas-Yazigi, et al. "A systematic study of the optical properties of mononuclear hybrid organo–inorganic lanthanoid complexes." Inorganic Chemistry Frontiers 7, no. 17 (2020): 3049–62. http://dx.doi.org/10.1039/d0qi00232a.

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Mononuclear organic–inorganic hybrid lanthanoid complexes show that the combination of both types of ligands improves the optical response compared to the inorganic analogue, thus having potential optical applications due to their thermal response.

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16

PAGÉ, F., and C. R. DE KIMPE. "DISSOLUTION DES COMPOSÉS FERRUGINEUX ET ALUMINEUX DES HORIZONS B PODZOLIQUES DE SOLS DU QUÉBEC PAR LE DITHIONITE-CITRATE-BICARBONATE, L'OXALATE, LE PYROPHOSPHATE ET LE TÉTRABORATE." Canadian Journal of Soil Science 69, no. 3 (1989): 451–59. http://dx.doi.org/10.4141/cjss89-047.

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Organic matter, Fe and Al were determined in dithionite-citrate-bicarbonate (d), oxalate (o), pyrophosphate (p) and tetraborate (t) extracts from Quebec Podzolic B horizons in order to evaluate the ability of these reagents to extract the organo-metallic complexes as well as inorganic oxides and hydroxides, and to verify the appropriateness of soil classification criteria. Dithionite solubilized most of the Fe whereas oxalate extracted most of the Al compounds; the ability of the same reagents to extract Al and Fe, respectively, was directly related to the amount of organo-metallic complexes.

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17

Lanoë, Pierre-Henri, Jonny Chan, Antoine Groué, et al. "Cyclometalated N-heterocyclic carbene iridium(iii) complexes with naphthalimide chromophores: a novel class of phosphorescent heteroleptic compounds." Dalton Transactions 47, no. 10 (2018): 3440–51. http://dx.doi.org/10.1039/c7dt04369d.

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18

Basova, Tamara. "Organic/Inorganic Nanocomposites Based on ‘Three Pillars’ (Organic Compounds, Metal Nanoparticles, and Carbon Nanomaterials)." International Journal of Molecular Sciences 26, no. 14 (2025): 6578. https://doi.org/10.3390/ijms26146578.

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Анотація:

A wide variety of organic molecules, ranging from simple aromatic molecules to complexes with organic ligands and polymers, offer the possibility of creating both simple and complex structures with diverse physicochemical properties [...]

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19

Chorazy, Szymon, Tomasz Charytanowicz, Junhao Wang, Shin-ichi Ohkoshi, and Barbara Sieklucka. "Hybrid organic–inorganic connectivity of NdIII(pyrazine-N,N′-dioxide)[CoIII(CN)6]3− coordination chains for creating near-infrared emissive Nd(iii) showing field-induced slow magnetic relaxation." Dalton Transactions 47, no. 24 (2018): 7870–74. http://dx.doi.org/10.1039/c8dt01464g.

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20

Fedotov, P. S., R. Kh Dzhenloda, A. A. Drozdov, and V. K. Karandashev. "METAL-ORGANIC COMPLEXES IN ENVIRONMENTAL SOLID SAMPLES: ON THE SELECTIVITY OF PYROPHOSPHATE EXTRACTION." Industrial laboratory. Diagnostics of materials 85, no. 6 (2019): 5–10. http://dx.doi.org/10.26896/1028-6861-2019-85-6-5-10.

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Sequential extraction procedures (SEP) have been widely used for the fractionation of trace elements in soils according to their physicochemical mobility and bioaccessibility. Potassium/sodium pyrophosphate in alkaline medium may be considered as the most appropriate extracting reagent for the recovery of amorphous metal-organic complexes, which play a very important role in biological, physical, and chemical processes in soil. However, the selectivity of pyrophosphate has been poorly studied. In the present work the ability of pyrophosphate to attack mineral inorganic phases of environmental

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21

Hu, Yang-Yang, Ting-Ting Zhang, Xiao Zhang, et al. "New organic–inorganic hybrid compounds constructed from polyoxometalates and transition metal mixed-organic-ligand complexes." Dalton Transactions 45, no. 6 (2016): 2562–73. http://dx.doi.org/10.1039/c5dt04413h.

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22

Wlaźlak, Ewelina, Justyna Kalinowska-Tłuścik, Dawid Przyczyna, Piotr Zawal, and Konrad Szaciłowski. "Bismuth triiodide complexes: structure, spectroscopy, electronic properties, and memristive properties." Journal of Materials Chemistry C 8, no. 18 (2020): 6136–48. http://dx.doi.org/10.1039/d0tc00679c.

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23

Matozzo, Paola, Alessia Colombo, Claudia Dragonetti, et al. "A Chiral Bis(salicylaldiminato)zinc(II) Complex with Second-Order Nonlinear Optical and Luminescent Properties in Solution." Inorganics 8, no. 4 (2020): 25. http://dx.doi.org/10.3390/inorganics8040025.

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Whereas there is an increasing amount of reports on the second-order nonlinear optical (NLO) and luminescence properties of tetradentate [N2O2] Schiff base–zinc complexes, the study of zinc complexes having two bidentate [NO] Schiff-base ligands is relatively unexplored from an NLO point of view. This work puts in evidence that the known chiral bis{2-[(R)-(+)-1-phenylethyliminomethyl]phenolato-N,O}zinc(II) complex is a fascinating multifunctional molecular inorganic–organic hybrid material characterized by interesting second-order NLO and luminescent properties in solution. The emissive proper

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24

Zhang, Ao, Yinmin Zhang, and Zhiling Zhu. "Thermal properties of Halloysite nanotubes (HNTs) intercalation complexes-A review." E3S Web of Conferences 131 (2019): 01055. http://dx.doi.org/10.1051/e3sconf/201913101055.

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The organic/inorganic intercalated complexes have attracted more interests in past. This paper reviewed the layered structure of halloysite nanotubes (HNTs) intercalated by dimethyl sulfoxide (DMSO), potassium acetate (KAc), N-methylformamide (NMF), urea and acrylamide (AM). The microstructure and model of halloysite intercalated complexes were investigated. The research difficulties and application fields of halloysite intercalated complexes were proposed.

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25

Stevens, Nathan, Diana Samaroo, and Daniel L. Akins. "Nonlinear optical switching properties of dye-doped inorganic/organic nanocomposite films." Journal of Nonlinear Optical Physics & Materials 26, no. 02 (2017): 1750015. http://dx.doi.org/10.1142/s0218863517500151.

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The sol–gel method has been employed in the fabrication of composite films consisting of nanometer size self-assembled organic mesostructures surrounded by a silica framework. The hydrophobic domains within the mesostructures make these films an excellent host matrix for the donor/acceptor energy transfer complexes. Time-resolved fluorescence and transient absorption studies revealed that these complexes exhibit ultrafast nonlinear optical responses as a result of the energy transfer process. The optical properties of these composite films may make them suitable for use as the photonic film in

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26

Ma, Le, Feifan Guo, and Jian-Fang Ma. "Two Cu(i)-based inorganic–organic complexes assembled with polyoxometalate and thiacalix[4]arene for efficient catalytic reactions." New Journal of Chemistry 46, no. 15 (2022): 6995–7002. http://dx.doi.org/10.1039/d2nj00290f.

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27

Wang, Yang, Yun Zhang, Chen Hou, Fu He, and Mingzhu Liu. "Facile one-pot assembly of adhesive phenol/FeIII/PEI complexes for preparing magnetic hybrid microcapsules." New Journal of Chemistry 40, no. 1 (2016): 781–88. http://dx.doi.org/10.1039/c5nj02254a.

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28

Xiao, Li-Na, Chun-Xiang Zhao, Xiao-Ming Shi, Hao Zhang, Wen Wu, and Xiao-Bing Cui. "Three new compounds based on similar molybdenum–vanadium clusters and several types of copper complexes." CrystEngComm 20, no. 7 (2018): 969–77. http://dx.doi.org/10.1039/c7ce01908d.

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29

Horiuchi, Shinnosuke. "(Invited) Luminescent Coordination Complexes as a Molecular Probe in Supramolecular Organic-Inorganic Assemblies." ECS Meeting Abstracts MA2024-01, no. 13 (2024): 1055. http://dx.doi.org/10.1149/ma2024-01131055mtgabs.

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Анотація:

Guest molecules entrapped in a confined space can show unusual chemical and physical properties because their behaviors are manipulated by multiple noncovalent interactions from the interiors of the space. Thus, it is important to understand the local environment in the confined space and noncovalent interactions between the guest molecule and the interiors for establishing a new molecular system based on the unusual chemical and physical phenomena from the trapped molecules. Photophysical properties of coordination complexes are easily adjusted by variation of metal ions and organic ligands,

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30

Wang, Yuan, Pengtao Ma, and Jingyang Niu. "Organic–inorganic hybrid rare earth complexes based on polymolybdates with intrinsic photosensitive properties." Dalton Transactions 44, no. 10 (2015): 4679–82. http://dx.doi.org/10.1039/c4dt02967d.

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A series of organic–inorganic hybrid rare earth complexes based on the {Mo<sub>36</sub>} isopolyanion have been obtained, and their photosensitive and photoluminescence properties have been investigated.

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31

Travis, Will, Caroline E. Knapp, Christopher N. Savory, et al. "Hybrid Organic–Inorganic Coordination Complexes as Tunable Optical Response Materials." Inorganic Chemistry 55, no. 7 (2016): 3393–400. http://dx.doi.org/10.1021/acs.inorgchem.5b02749.

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32

Fonseca, António M., Carlos J. R. Silva, Natércia Nunes, and Isabel C. Neves. "Organic–inorganic hybrid matrix doped with alkenyldiazenido complexes of molybdenum." Journal of Alloys and Compounds 454, no. 1-2 (2008): 72–77. http://dx.doi.org/10.1016/j.jallcom.2006.12.085.

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33

Mohammadkazemi, Fatemeh, Reihaneh Khademi Barangenani, and Mojtaba Koosha. "Development of organic–inorganic oxidized bacterial cellulose nanobiocomposites: ternary complexes." Cellulose 26, no. 10 (2019): 6009–22. http://dx.doi.org/10.1007/s10570-019-02514-w.

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34

Lan, Qing, Ying Lu, Yang-Guang Li, Hua-Qiao Tan, Ding Liu, and En-Bo Wang. "Organic–inorganic hybrid complexes based on a Keggin-type polyoxoanion." Transition Metal Chemistry 37, no. 5 (2012): 445–51. http://dx.doi.org/10.1007/s11243-012-9608-1.

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35

Dai, Limei, Wansheng You, Lihua Chen, Liqiang Chen, Lihong Liu, and Honghui Gai. "Organic–inorganic hybrids based on polyoxometalates and copper coordination complexes." Transition Metal Chemistry 41, no. 8 (2016): 909–15. http://dx.doi.org/10.1007/s11243-016-0094-8.

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36

Adima, Augustin, Jo�l J. E. Moreau, and Michel Wong Chi Man. "Immobilization of rhodium complexes in chiral organic-inorganic hybrid materials." Chirality 12, no. 5-6 (2000): 411–20. http://dx.doi.org/10.1002/(sici)1520-636x(2000)12:5/6<411::aid-chir21>3.0.co;2-x.

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37

Escobosa, Alma Carolina, and Thomas A. Manz. "How well do various QM-derived net atomic charges reproduce the electrostatic potential surrounding a material across multiple geometric conformations?" RSC Advances 15, no. 29 (2025): 23223–65. https://doi.org/10.1039/d4ra07900k.

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This article compares the accuracy of various atomic charge schemes for reproducing the electrostatic potential surrounding organic, inorganic, and heterodiatomic molecules, transition metal complexes, and nanoporous solids.

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38

Fornaro, Teresa, Malgorzata Biczysko, Susanna Monti, and Vincenzo Barone. "Dispersion corrected DFT approaches for anharmonic vibrational frequency calculations: nucleobases and their dimers." Phys. Chem. Chem. Phys. 16, no. 21 (2014): 10112–28. http://dx.doi.org/10.1039/c3cp54724h.

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Toward a comprehensive and robust computational protocol for simulation of fully anharmonic vibrational (IR) spectra of nucleic acid base complexes and their adsorption on solid supports (organic/inorganic).

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39

S., JENA, and C. DASH K. "Organometallic Chemistry - Challenges and Opportunities." Journal of Indian Chemical Society Vol. 73, Oct 1996 (1996): 558–63. https://doi.org/10.5281/zenodo.5910760.

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Department of Chemistry, Utkal University, Vani Vihar, Bhubaneswar-751 004 <em>Manuscript received 24 November 1993. revised 26 October 1994, accepted 2 March  1995</em> Organometallic chemistry, starting as a branch of organic chemistry later incorporated coordination chemistry and has developed into a true multidisciplinary science. It is not only acting as a bridge between the two conventional branches of chemistry—inorganic and organic, but is also assuming tremendous importance from the point of view of industrial, biological and environmental aspects. It sa

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40

Abdullayeva, Rayhon Aminovna Ataullayev Zokir Makhsudovich. "DETERMINATION OF THE AMOUNT OF IRON IONS USING ORGANIC REAGENTS." THEORETICAL ASPECTS IN THE FORMATION OF PEDAGOGICAL SCIENCES 2, no. 2 (2023): 188–89. https://doi.org/10.5281/zenodo.7565394.

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Currently, in colorimetric analysis, the concentration of Mn ion is determined using its characteristic color. However, few metal ions produce such strong colors, especially at low concentrations. Many colored complexes can be formed from metal ions and organic or inorganic complexing agents. These complexes are the result of interaction between Lewis acid (metal ion) and Lewis base (complex former) [1]. An ideal color-forming reagent requires that it be stable and selective (even specific) and that it reacts rapidly to form soluble, highly colored complexes.

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41

Cai, Jiwen, Cai-Hong Chen, Cheng-Zhu Liao, Xiao-Long Feng, and Xiao-Ming Chen. "Solid-state structures of group 1 and group 2 metal 1,5-naphthalenedisulfonates: systematic investigation of lamellar three-dimensional networks constructed by metal arenedisulfonate." Acta Crystallographica Section B Structural Science 57, no. 4 (2001): 520–30. http://dx.doi.org/10.1107/s010876810100862x.

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Анотація:

Seven Group 1 and Group 2 1,5-naphthalenedisulfonates (1,5-nds) have been synthesized and structurally characterized by single-crystal X-ray diffraction, IR spectroscopy and thermal gravimetric analysis. For Group 1 metal complexes, with M = Li+ (1), Na+ (2) and K+ (3), all crystallize in the same space group (P21/c) with the same composition, [M 2(1,5-nds)(H2O)2]. They adopt similar three-dimensional packing arrangements with the metal–sulfonate inorganic layers pillared by naphthalene rings. However, the coordination behavior of three metal cations toward the SO_3^- group and water molecule

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42

Díaz, Urbano, Mercedes Boronat, and Avelino Corma. "Hybrid organic–inorganic structured materials as single-site heterogeneous catalysts." Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences 468, no. 2143 (2012): 1927–54. http://dx.doi.org/10.1098/rspa.2012.0066.

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Catalyst selectivity is associated with well-defined homogeneous active sites. Transition metal complexes and organocatalysts are highly active and selective in the homogeneous phase, and their heterogenization by incorporating them into inorganic solid materials allows combining their excellent catalytic activity with improved separation, recovering and recycling properties. In this article, we present the structural characteristics and catalytic properties of hybrid organic–inorganic materials in which the molecular catalysts are part of the inorganic structure, emphasizing the possibilities

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Lee, Jin Hee, Yu Jung Park, Jung Hwa Seo, and Bright Walker. "Hybrid Lead-Halide Polyelectrolytes as Interfacial Electron Extraction Layers in Inverted Organic Solar Cells." Polymers 12, no. 4 (2020): 743. http://dx.doi.org/10.3390/polym12040743.

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A series of lead-halide based hybrid polyelectrolytes was prepared and used as interfacial layers in organic solar cells (OSCs) to explore their effect on the energy band structures and performance of OSCs. Nonconjugated polyelectrolytes based on ethoxylated polyethylenimine (PEIE) complexed with PbX2 (I, Br, and Cl) were prepared as polymeric analogs of the perovskite semiconductors CH3NH3PbX3. The organic/inorganic hybrid composites were deposited onto Indium tin oxide (ITO) substrates by solution processing, and ultraviolet photoelectron spectroscopy (UPS) measurements confirmed that the po

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Yin, Hong-Ju, Zhong-Gui Xiao, Yansong Feng, and Chang-Jiang Yao. "Recent Progress in Photonic Upconversion Materials for Organic Lanthanide Complexes." Materials 16, no. 16 (2023): 5642. http://dx.doi.org/10.3390/ma16165642.

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Organic lanthanide complexes have garnered significant attention in various fields due to their intriguing energy transfer mechanism, enabling the upconversion (UC) of two or more low-energy photons into high-energy photons. In comparison to lanthanide-doped inorganic nanoparticles, organic UC complexes hold great promise for biological delivery applications due to their advantageous properties of controllable size and composition. This review aims to provide a summary of the fundamental concept and recent developments of organic lanthanide-based UC materials based on different mechanisms. Fur

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Chen, Jihua. "Advanced Electron Microscopy of Nanophased Synthetic Polymers and Soft Complexes for Energy and Medicine Applications." Nanomaterials 11, no. 9 (2021): 2405. http://dx.doi.org/10.3390/nano11092405.

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After decades of developments, electron microscopy has become a powerful and irreplaceable tool in understanding the ionic, electrical, mechanical, chemical, and other functional performances of next-generation polymers and soft complexes. The recent progress in electron microscopy of nanostructured polymers and soft assemblies is important for applications in many different fields, including, but not limited to, mesoporous and nanoporous materials, absorbents, membranes, solid electrolytes, battery electrodes, ion- and electron-transporting materials, organic semiconductors, soft robotics, op

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Xu, Xiaolin, Mengna Ding, Shiwen Yu, et al. "Co–HOAT Complexes Change Their Antibacterial and Physicochemical Properties with Morphological Evolution." Catalysts 14, no. 3 (2024): 173. http://dx.doi.org/10.3390/catal14030173.

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Antibacterial coordination compounds have attracted tremendous attention ascribed to their excellent designability. However, how the morphological evolution of these complexes influences their antibacterial and physicochemical properties has never been investigated based on proposed mechanisms. Thus, a series of Co–HOAT coordination compounds synthesized from inorganic to organic cobalt sources were prepared. We propose that with the same HOAT ligand, inorganic Co–HOAT nanosheets possess higher sterilization rates compared with organic Co–HOAT nanoparticles. This is explained by the different

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Arenholt-Bindslev, Dorthe, and Gorm Danscher. "Effects of Organic and Inorganic Selenium on Mercury Accumulation in Cultures of Normal Human Epithelial Cells." Alternatives to Laboratory Animals 16, no. 3 (1989): 253–56. http://dx.doi.org/10.1177/026119298901600308.

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Cultures of normal human epithelial cells were exposed to methylmercury alone or in combination with organic or inorganic selenium. The resulting subcellular distribution of mercury accumulation was demonstrated cytochemically by the silver enhancement method. With this method, accumulation of mercury-selenide complexes is visualised at both the light microscope and electron microscope levels. Substantially more mercury complexes were found in cultures exposed to mercury and selenite than in cultures exposed to mercury and selenomethionine. All visualised mercury-complexes were localised in ly

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Gao, Rui, Suanny Mosquera-Romero, Eleftheria Ntagia, Xiaofei Wang, Korneel Rabaey, and Luiza Bonin. "Review—Electrochemical Separation of Organic and Inorganic Contaminants in Wastewater." Journal of The Electrochemical Society 169, no. 3 (2022): 033505. http://dx.doi.org/10.1149/1945-7111/ac51f9.

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High energy input and chemicals additions are typically needed to deal with persistent pollutants, organic and inorganic, and organometallic complexes in wastewater. Particularly, organometallic complexes decrease the removal efficiency for other pollutants being treated with conventional technologies, which can lead to high operational costs and residues formation. The improperly treated wastewater contains nutrients (nitrogen and phosphorus), heavy metals, and persistent organics, which should be removed or recovered before discharging. Electrochemical technologies can achieve concomitant re

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Badea, Mihaela, Valentina Uivarosi, and Rodica Olar. "Improvement in the Pharmacological Profile of Copper Biological Active Complexes by Their Incorporation into Organic or Inorganic Matrix." Molecules 25, no. 24 (2020): 5830. http://dx.doi.org/10.3390/molecules25245830.

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Every year, more Cu(II) complexes are proven to be biologically active species, but very few are developed as drugs or entered in clinical trials. This is due to their poor water solubility and lipophilicity, low stability as well as in vivo inactivation. The possibility to improve their pharmacological and/or oral administration profile by incorporation into inorganic or organic matrix was studied. Most of them are either physically encapsulated or conjugated to the matrix via a moiety able to coordinate Cu(II). As a result, a large variety of species were developed as delivery carriers. The

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Beloglazkina, Elena K., Anna A. Moiseeva, Sergey A. Tsymbal, et al. "The Copper Reduction Potential Determines the Reductive Cytotoxicity: Relevance to the Design of Metal–Organic Antitumor Drugs." Molecules 29, no. 5 (2024): 1032. http://dx.doi.org/10.3390/molecules29051032.

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Copper–organic compounds have gained momentum as potent antitumor drug candidates largely due to their ability to generate an oxidative burst upon the transition of Cu2+ to Cu1+ triggered by the exogenous-reducing agents. We have reported the differential potencies of a series of Cu(II)–organic complexes that produce reactive oxygen species (ROS) and cell death after incubation with N-acetylcysteine (NAC). To get insight into the structural prerequisites for optimization of the organic ligands, we herein investigated the electrochemical properties and the cytotoxicity of Cu(II) complexes with

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