Academic literature on the topic 'Α-methylbenzylamine'

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Journal articles on the topic "Α-methylbenzylamine"

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Kour, M., R. Gupta, R. Saini та R. Bansal. "Diastereoselectivity in the Aza-Michael Reaction of Chiral α-Methylbenzylamines with α,β-Unsaturated Carbonyl Compounds". SynOpen 02, № 02 (2018): 0122–27. http://dx.doi.org/10.1055/s-0036-1591999.

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The aza-Michael reaction of (S)-(–)- and (R)-(+)-α-methylbenzylamines with trans-cinnamaldehyde and other α,β-unsaturated carbonyl compounds occurs with 52–98% diastereoselectivity (de); however, in the reaction with crotonaldehyde, the de is lower (20–38%). In the products obtained from the reaction with α,β-unsaturated aldehydes, the de could be determined on the basis of the relative intensities of the aldehydic protons of the two diastereomers. Theoretical investigations of the reaction of (S)-(–)-α-methylbenzylamine with trans-cinnamaldehyde at the DFT (B3LYP/6-31+G*) level reveal that th
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Kuang, Rui, Luyi Zheng, Yanhui Chi, Jingmin Shi, Xuexue Chen, and Chengcheng Zhang. "Highly efficient electrochemical recognition and quantification of amine enantiomers based on a guest-free homochiral MOF." RSC Advances 7, no. 19 (2017): 11701–6. http://dx.doi.org/10.1039/c7ra00205j.

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de Miranda, Amanda S., Rodrigo O. M. A. de Souza та Leandro S. M. Miranda. "Ammonium formate as a green hydrogen source for clean semi-continuous enzymatic dynamic kinetic resolution of (+/−)-α-methylbenzylamine". RSC Adv. 4, № 26 (2014): 13620–25. http://dx.doi.org/10.1039/c4ra00462k.

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The chemoenzymatic dynamic kinetic resolution of (+/−)-α-methylbenzylamine under continuous flow conditions in the presence of Pd/BaSO<sub>4</sub>as racemization catalyst and ammonium formate as reductant is described.
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Chapela, V. M., M. J. Percino, A. Jiménez, R. Ortega-Martı́nez, C. A. Escalante та C. Rodrı́guez de Barbarı́n. "The use of (R)-(+)-α-methylbenzylamine and (S)-(−)-α-methylbenzylamine as chiral moieties to obtain monomers for second harmonic generation crystals". Journal of Molecular Structure 648, № 1-2 (2003): 115–24. http://dx.doi.org/10.1016/s0022-2860(02)00708-1.

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Zhou, Chenyang, Ya Chu, Linlin Ma, et al. "Photoluminescence spectral broadening, chirality transfer and amplification of chiral perovskite materials (R-X-p-mBZA)2PbBr4 (X = H, F, Cl, Br) regulated by van der Waals and halogen atoms interactions." Physical Chemistry Chemical Physics 22, no. 30 (2020): 17299–305. http://dx.doi.org/10.1039/d0cp02530e.

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We introduced halogen-substituted chiral molecules as A-site cations to synthesize a series of novel organic–inorganic hybrid 2D chiral perovskite materials (R-X-p-mBZA)<sub>2</sub>PbBr<sub>4</sub> (X = H, F, Cl, Br; p: para-position; mBZA = α-methylbenzylamine).
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González-Fernández, Rebeca, Pascale Crochet, and Victorio Cadierno. "N-[(1R)-1-(4-Chlorophenyl)ethyl]-Cyanamide." Molbank 2021, no. 2 (2021): M1198. http://dx.doi.org/10.3390/m1198.

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The title compound was synthesized by electrophilic cyanation of commercially available (R)-4-chloro-α-methylbenzylamine with cyanogen bromide in diethyl ether, and isolated as a yellow oil in 84% yield. It was characterized by 1H and 13C{1H] NMR, IR, HRMS, and specific rotation measurements.
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Zgierski, Marek Z. "Theoretical study of photochromism of N-salicylidene-α-methylbenzylamine". Journal of Chemical Physics 115, № 18 (2001): 8351–58. http://dx.doi.org/10.1063/1.1411999.

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Park, Eul-Soo, та Jong-Shik Shin. "ω-Transaminase from Ochrobactrum anthropi Is Devoid of Substrate and Product Inhibitions". Applied and Environmental Microbiology 79, № 13 (2013): 4141–44. http://dx.doi.org/10.1128/aem.03811-12.

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ABSTRACTω-Transaminases display complicated inhibitions by ketone products and both enantiomers of amine substrates. Here, we report the first example of ω-transaminase devoid of such inhibitions. Owing to the lack of enzyme inhibitions, the ω-transaminase fromOchrobactrum anthropienabled efficient kinetic resolution of α-methylbenzylamine (500 mM) even without product removal.
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Patil, Mahesh D., Sanghan Yoon, Hyunwoo Jeon, et al. "Kinetic Resolution of Racemic Amines to Enantiopure (S)-amines by a Biocatalytic Cascade Employing Amine Dehydrogenase and Alanine Dehydrogenase." Catalysts 9, no. 7 (2019): 600. http://dx.doi.org/10.3390/catal9070600.

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Amine dehydrogenases (AmDHs) efficiently catalyze the NAD(P)H-dependent asymmetric reductive amination of prochiral carbonyl substrates with high enantioselectivity. AmDH-catalyzed oxidative deamination can also be used for the kinetic resolution of racemic amines to obtain enantiopure amines. In the present study, kinetic resolution was carried out using a coupled-enzyme cascade consisting of AmDH and alanine dehydrogenase (AlaDH). AlaDH efficiently catalyzed the conversion of pyruvate to alanine, thus recycling the nicotinamide cofactors and driving the reaction forward. The ee values obtain
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Fischer, Andrew T., Robert N. Compton та Richard M. Pagni. "Solvent Effects on the Optical Rotation of (S)-(−)-α-Methylbenzylamine". Journal of Physical Chemistry A 110, № 22 (2006): 7067–71. http://dx.doi.org/10.1021/jp0608527.

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Book chapters on the topic "Α-methylbenzylamine"

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Kondo, T., N. Ogasawara, S. Umegaki, and R. Ito. "Nonlinear Optical Properties of 2-(α-Methylbenzylamino)-5-nitropyridine." In Springer Proceedings in Physics. Springer Berlin Heidelberg, 1989. http://dx.doi.org/10.1007/978-3-642-93426-1_33.

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Taber, Douglass F. "The Carreira Synthesis of (–)-Dendrobine." In Organic Synthesis. Oxford University Press, 2015. http://dx.doi.org/10.1093/oso/9780190200794.003.0098.

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The tetracyclic alkaloid (–)-dendrobine 3 has at its core a cyclohexane that is substituted at each of its six positions, including one quaternary center. Erick M. Carreira of ETH Zürich chose (Angew. Chem. Int. Ed. 2012, 51, 3436) to assemble this ring by the Ireland-Claisen rearrangement of the lactone 1. The absolute configuration of the final product stemmed from the commercial enantiomerically pure acetonide 4, which was selectively converted to the Z-ester 5. Following the precedent of Costa, TBAF-mediated conjugate addition of 2-nitropropane to 5 proceeded with high diastereocontrol, to
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Conference papers on the topic "Α-methylbenzylamine"

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Kondo, T., N. Ogasawara, S. Umegaki та R. Ito. "Linear And Nonlinear Optical Properties Of 2-(α-Methylbenzylamino)-5-Nitropyridine". У 32nd Annual Technical Symposium, редактор Garo Khanarian. SPIE, 1988. http://dx.doi.org/10.1117/12.948218.

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Bourhill, G., F. Cruickshank, D. Pugh та ін. "The Linear and Nonlinear Optical Properties of the Organic Material (+)2-(α-methylbenzylamino)-5-nitropyridine (MBA-NP)". У Nonlinear Optics. Optica Publishing Group, 1992. http://dx.doi.org/10.1364/nlo.1992.md28.

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Nitropyridine derivatives have long been known as potential materials for nonlinear optical applications [1]. The chiral molecule (+)2-(α-methylbenzylamino)-5-nitropyridine (MBA-NP) was identified as a promising material by the powder technique [2]. MBA-NP possessed a powder efficiency 20 times that of a urea reference when the fundamental wavelength was 1064 nm. This value is in good agreement with that reported by other authors [3].
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Nayar, B. K., R. Kashyap, K. I. White та ін. "PHASE-MATCHED OPTICAL SECOND HARMONIC GENERATION IN THE ORGANIC CRYSTAL MBA-NP (−)2-(α-methylbenzylamino)-5-nitropyridine". У Advanced Solid State Lasers. OSA, 1987. http://dx.doi.org/10.1364/assl.1987.wf3.

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