Academic literature on the topic 'Β-diketone'

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Journal articles on the topic "Β-diketone"

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Korde, Nanda S., Ravindra S. Shinde та Prashant G. Kumdale. "ECO-FRIENDLY SYNTHESIS, CHARACTERIZATION AND ANTIMICROBIAL EVALUATION OF POTENTIALLY ACTIVE Β-DIKETONE LIGAND AND ITS TRANSITION METAL COMPLEXES". Journal of Advanced Scientific Research 12, № 04 Suppl 1 (2021): 117–21. http://dx.doi.org/10.55218/jasr.s1202112411.

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Diketones are key intermediates for the synthesis of core heterocycles such as isoxazole, pyrazole, flavones, triazole, pyrimidine and benzodiazepines. The β-diketone ligand and its transition metal complexes have been manufactured by ultrasound irradiation. The β-diketone is prepared by using Baker-Venkatraman rearrangement and characterized by physical, spectral and analytical data. The moieties β-diketone compound acts as bidentate ligand and co-ordinate with the transition metal atom through β-diketone system. The synthesized compounds have also been screened for in vitro antibacterial and
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Su, Biyun, Yifan Hou, Li Wang та ін. "The Syntheses, Characterization and Crystal Structures of a Series of Heterocyclic β-Diketones and Their Isoxazole Compounds". Current Organic Synthesis 16, № 8 (2020): 1174–84. http://dx.doi.org/10.2174/1570179416666191022113022.

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Background: In the field of coordination chemistry, the introduction of heterocyclic substituents into the structure of β-diketone enables ligand to produce multiple coordination sites. The adoption of small steric oxime group into the structure of heterocyclic β-diketone by Schiff-base condensation will further increase coordination sites and facilitate the generation of polynuclear structures. Objective: A series of β-diketones (2a-2c) containing different heterocycles such as pyridine, thiophene and furan and their corresponding isoxazole compounds (3a-3c) were synthesized. Materials and Me
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Tomachynski, L. A., V. Ya Chernii та S. V. Volkov. "Synthesis and spectral characterization of bis(β-diketonato)zirconium(IV) and -hafnium(IV) phthalocyaninates". Journal of Porphyrins and Phthalocyanines 06, № 02 (2002): 114–21. http://dx.doi.org/10.1142/s1088424602000154.

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The reaction of PcMCl 2 ( M = Zr , Hf ) with β-diketones is reported. 1 H NMR and elemental analysis suggest the substitution of two Cl atoms for two β-diketone fragments takes place as a result of this reaction and the complexes PcM(β-dik)2 are formed. All obtained complexes are stable and highly soluble in most organic solvents. The data from 1 H and 19 F NMR, and UV-vis spectroscopy suggest the coordination of two β-diketone ligands in a cis geometry about the central atom of the macrocycle. It was shown bis(β-diketonato)zirconium(IV) and hafnium(IV) phthalocyanines containing β-diketones w
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GROGAN, Gideon. "Emergent mechanistic diversity of enzyme-catalysed β-diketone cleavage". Biochemical Journal 388, № 3 (2005): 721–30. http://dx.doi.org/10.1042/bj20042038.

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The enzymatic cleavage of C–C bonds in β-diketones is, comparatively, a little studied biochemical process, but one that has important relevance to human metabolism, bioremediation and preparative biocatalysis. In recent studies, four types of enzymes have come to light that cleave C–C bonds in the β-diketone functionality using different chemical mechanisms. OPH [oxidized poly(vinyl alcohol) hydrolase from Pseudomonas sp. strain VM15C], which cleaves nonane-4,6-dione to butyrate and pentan-2-one is a serine-triad hydrolase. Dke1 (diketone-cleaving enzyme from Acinetobacter johnsonii) is a dio
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Liu, Yi-Wei, Satpal Singh Badsara, Yi-Chen Liu та Chin-Fa Lee. "K2S2O8/I2 promoted syntheses of α-thio-β-dicarbonyl compounds via oxidative C–S coupling reactions under transition metal-free and solvent-free conditions". RSC Advances 5, № 55 (2015): 44299–305. http://dx.doi.org/10.1039/c5ra07204b.

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K<sub>2</sub>S<sub>2</sub>O<sub>8</sub>/I<sub>2</sub> promoted C–S coupling reaction of β-diketone with disulfide has been described. The resulting α-thio-β-diketones compounds were obtained in good to excellent yields.
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Louis, Marine, Régis Guillot, Rémi Métivier та Clémence Allain. "β-Diketone derivatives: influence of the chelating group on the photophysical and mechanofluorochromic properties". Photochemical & Photobiological Sciences 17, № 6 (2018): 822–28. http://dx.doi.org/10.1039/c8pp00070k.

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A diphenyl-boron β-diketonate complex was synthesized and compared with the related β-diketone and difluoro-boron complex, showing that the three compounds display very distinct photophysical and mechanofluorochromic behaviors.
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Syed Ameen, Syed Tajudeen, Anbalagan Vilvanathan, Syed Zameer Ahmed Khader та Gayathri Mahalingam. "Microwave-assisted Green Synthesis of β-Diketone Hydrazone Derivatives and Evaluation of their Antioxidant and Antibacterial Activities". Current Microwave Chemistry 7, № 3 (2020): 222–29. http://dx.doi.org/10.2174/2213335607999200917145217.

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Background: A series of β-diketone hydrazones have been synthesized via condensation of isoniazid with series of β-diketone. The structures of the Schiff bases are established by elemental and spectroscopic techniques. The prepared compounds were screened for antibacterial and antioxidant potential by DPPH free-radical scavenging activity and Ferric reducing antioxidant power (FRAP) assays. Methods: β-diketone hydrazine derivatives were synthesized by simple condensation between various β-diketones and isoniazid. The titled compounds were synthesized following both conventional and microwave i
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Talbi, Soumaya, Mustapha Dib, Latifa Bouissane, Hafid Abderrafia, Souad Rabi, and Mostafa Khouili. "Recent Progress in the Synthesis of Heterocycles based on 1,3-diketones." Current Organic Synthesis 19, no. 2 (2022): 220–45. http://dx.doi.org/10.2174/1570179418666211011141428.

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: N,O-heterocycles containing the dicarbonyl ring play a significant role in heterocyclic and therapeutic chemistry. Since the discovery of 1,3-diketones, numerous research works have been achieved regarding the synthesis and its chemical reactivity. In this review, we have described the most relevant publications involving β-diketone compounds published during the period between 2018 to date. In addition, we include the 1,3-diketones-based heterocyclic compounds prepared by various synthetic methodologies.
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Baum, Bernard R., A. Pat Tulloch, and L. Grant Bailey. "Epicuticular waxes of the genus Hordeum: a survey of their chemical composition and ultrastructure." Canadian Journal of Botany 67, no. 11 (1989): 3219–26. http://dx.doi.org/10.1139/b89-401.

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This study was based on 148 accessions representing 39 species of Hordeum. SEM ultrastructural morphology of waxes was based on individual spikelets, whereas waxes' chemical composition was assessed from whole plants. When all the data, in the form of individual accessions, were subjected to various cluster analyses methods, no groupings were revealed. But when the data were first summarized by species and then subjected to clustering, two polythetic groups of species were detected. Group 1 is characterized by species with 40–60% average alcohol content and by the common presence of diketones,
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Grogan, Gideon. "β-Diketone hydrolases". Journal of Molecular Catalysis B: Enzymatic 19-20 (грудень 2002): 73–82. http://dx.doi.org/10.1016/s1381-1177(02)00153-4.

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Dissertations / Theses on the topic "Β-diketone"

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Borilović, Ivana. "Design and preparation of functional coordination compounds based on poly-β-diketone and polypyrazolyl ligands". Doctoral thesis, Universitat de Barcelona, 2018. http://hdl.handle.net/10803/665159.

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Combining the judiciously designed bis−β-diketone and polypyrazolyl scaffolds with the crystal field effects on the 3d metal ions, this manuscript exposes different methods of selective preparation of new heterometallic coordination compounds and the subtle modulation of their magnetic properties. Apart from their conventional magneto-structural relevance, special interest has been dedicated to develop the systems which exhibit strong ferromagnetic coupling and slow relaxation of the magnetization, even when incorporating exclusively isotropic metal ions. Moreover, synthetic strategy based on
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Shelton, Jennifer. "Epicuticular wax chemistry, morphology, and physiology in sand bluestem, andropogon gerardii ssp. hallii, and big bluestem, andropogon gerardii ssp. gerardii." Thesis, Kansas State University, 2012. http://hdl.handle.net/2097/14198.

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Master of Science<br>Department of Biology<br>Loretta Johnson<br>Plant epicuticular wax (ECW) isolates internal tissues from harsh external conditions increasing drought tolerance. Beta-diketone-rich ECW reflect light and result in a glaucous phenotype that may ameliorate the thermal environment of the leaf. The overall goal is to characterize the form and function of ECW in two closely related, but phenotypically divergent grasses. [italicized]Andropogon gerardii ssp. [italicized]gerardii, big bluestem, is a non-glaucous, agronomically and ecologically dominant grass in the United States whil
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Tessarolo, J. "Design and synthesis of metallo-supramolecular architectures towards advanced materials." Doctoral thesis, Università degli studi di Padova, 2017. http://hdl.handle.net/11577/3422402.

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Self-assembly is a key step to obtain functional supramolecular objects towards complex matter. With self-assembly of metal ions and well-designed polytopic ligands is possible to access a particular class of supramolecular functional materials: metal-organic polygons and polyhedra endowed with confined space, and functional properties deriving from the building blocks. Herein, firstly is presented a system that in solution self-assembles in a collection of Cu(II) based boxes: a rhomboid and a triangle in dynamic equilibrium. This system is a small constitutional dynamic library (CDL). The des
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Cassar, Kevin. "Coordination networks based on carboxylate and β-diketonate ligands". Thesis, University of Bath, 2007. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.437722.

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Katsumi, Shiho. "Multi-Stimuli Responsive β-Diketonate Derivatives, from Molecules to Self-Assemblies". Electronic Thesis or Diss., université Paris-Saclay, 2024. http://www.theses.fr/2024UPASF004.

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Les molécules fluorescentes multiréactives peuvent ajuster leurs propriétés de fluorescence en réponse à des stimuli externes tels que des changements de température, de pression et d'environnement chimique. Cette capacité d'adaptation pourrait orienter efficacement le développement des technologies de capteurs, d'affichage et d'imagerie, offrant ainsi de nombreuses applications. Le mécanofluorochromisme (MFC) est une propriété fascinante des systèmes multiréactifs, où les matériaux subissent des changements fluorescents sous l'effet de contraintes mécaniques telles que la compression, le cisa
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Lord, Rianne Michaela. "Synthesis of novel functionalised β-ketoiminate and β-diketonate metal complexes for their use in anti-cancer treatment". Thesis, University of Leeds, 2014. http://etheses.whiterose.ac.uk/6386/.

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This thesis is concerned with the synthesis, characterisation and evaluation of novel metal complexes for their application as anti-cancer agents. It contains the in vitro cell results, along with a range of other techniques to determine their biological relevance and their potential as anti-cancer agents. Chapter 1 contains an introduction to the project including a literature search, previously synthesised complexes and project aims Chapter 2 presents the synthesis and characterisation of novel β-diketonate and β-ketoiminate ligands. X-ray crystallographic data are analysed for some of the l
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Witt, Katarzyna. "Pochodne β-diketonów w roli przenośników jonów metali w polimerowych membranach inkluzyjnych (PIM)". Rozprawa doktorska, Uniwersytet Technologiczno-Przyrodniczy w Bydgoszczy, 2016. http://dlibra.utp.edu.pl/Content/935.

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Lerach, Jordan O. "Investigations into the Gas-Phase Rearrangements of Some Transition Metal β-Diketonate Complexes". Youngstown State University / OhioLINK, 2008. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1222114603.

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Collins, Stephen L. "Quenching of excited triplet states by Cr(III) and Co(III) β-diketonate complexes". Thesis, Loughborough University, 1987. https://dspace.lboro.ac.uk/2134/12100.

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Bimolecular rate constants for the quenching of up to 15 excited triplet aromatic hydrocarbons by eight S-diketonate complexes of Cr(III) and four of Co(III) have been obtained using nanosecond laser flash photolysis. The bimolecular rate constants have been plotted against donor energy and for those quenchers whose rate constants follow the available spectroscopic energy levels in the quencher, electronic energy transfer is established to be the mechanism of quenching. As the electrochemical reduction potential of the quencher is reduced by the introduction of trifluoromethyl groups into the
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Felouat, Abdellah. "Synthèse et études photophysiques de matériaux PI-conjugés - Complexes de difluorure de Bore des ligands Beta-dicétone à conjugaison PI-étendue." Thesis, Aix-Marseille, 2014. http://www.theses.fr/2014AIXM4036.

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Une nouvelle famille de complexes de difluorure de bore photosensibles est développée. Elle est basée sur des structures moléculaires contenant une unité β-dicétone à conjugaison électronique π.La grande variété de groupements aromatiques et la nature donneur ou accepteur d'électrons des différents substituants permet l'élaboration de systèmes électroniques donneur-accepteur-donneur d'électrons (D1-A-D1) et donneur-accepteur (D2-A).L'absorption électronique de cette famille de molécule se situe dans la partie visible du spectre électromagnétique et une partie du spectre ultraviolet, et est car
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Book chapters on the topic "Β-diketone"

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Carraher, E. C. "Bis-β-Diketone-Based Polymers." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145326.ch112.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of cerium(III) complex of heterocyclic-β-diketone." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-53974-3_629.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of neodymium(III) complex of heterocyclic-β-diketone." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-53974-3_644.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of samarium(III) complex of heterocyclic-β-diketone." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-53974-3_659.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of gadolinium(III) complex of heterocyclic-β-diketone." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-53974-3_669.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of dysprosium(III) complex of heterocyclic-β-diketone." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-53974-3_685.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of erbium(III) complex of heterocyclic-β-diketone." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-53974-3_691.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of oxovanadium(IV) complex with highly conjugated β-diketone." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54228-6_90.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of oxovanadium(IV) complex with highly conjugated β-diketone." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54228-6_91.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of oxovanadium(IV) complex with highly conjugated β-diketone." In Magnetic Properties of Paramagnetic Compounds. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54228-6_92.

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Conference papers on the topic "Β-diketone"

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Shi, Nai, Xiaochun Ding, Weijing Zhou, Yi Lu, Jinguang Wu та Guangxian Xu. "Preparation And IR Spectra On Some β-Diketone Complexes With Uranyl Ion". У Intl Conf on Fourier and Computerized Infrared Spectroscopy, редактор David G. Cameron. SPIE, 1989. http://dx.doi.org/10.1117/12.969436.

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Ma, Dongzhe, Yiqun Wu, Xin Jiang, Zhimin Chen та Xia Zuo. "Thermal and optical properties of rare earth metal β-Diketone Bipy complexes as optical recording materials". У Seventh International Symposium on Optical Storage (ISOS 2005), редактори Fuxi Gan та Lisong Hou. SPIE, 2005. http://dx.doi.org/10.1117/12.649798.

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Branković, Snežana, Radmila Glišić, Filip Grbović та ін. "INNOVATIVE APPROACH TO THE NEUTRALIZATION OF POLLUTANTS FROM SEWAGE SLUDGE USING OF ORGANIC β- DIKETONATE ON THE PLANT MODEL TRIFOLIUM PRATENSE L." У 53rd Annual Conference of the Serbian Water Pollution Control Society. SERBIAN WATER POLLUTION CONTROL SOCIETY, 2024. http://dx.doi.org/10.46793/voda24.305b.

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The aim of this study was to examine the possibility of applying an innovative approach to neutralization of sewage sludge pollutants, using a modified “sandwich” method with the use of β-diketonate. Sewage sludge was sampled at the Cvetojevac wastewater treatment plant in Kragujevac, treated with organic β-diketonate of different concentrations and used to test the germination of seeds of red clover (Trifolium pratense L.). Application of β- diketonate has a statistically significant effect on seed germination and root growth of the given species. The β-diketonate showed the ability to effect
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Branković, Snežana, Filip Grbović, Radmila Glišić та ін. "NEUTRALIZATION OF SEWAGE SLUDGE POLLUTANTS USING β-DIKETONATE". У 54. godišnja konferencija o aktuelnim problemima korišćenja i zaštite voda. Srpsko društvo za zaštitu voda, 2025. https://doi.org/10.46793/voda25.343b.

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This study explores the application of an innovative approach for the neutralization of pollutants from sewage sludge, sampled at the Cvetojevac Wastewater Treatment Plant in Kragujevac. The sludge was treated with β-diketonate at different concentrations (50, 100, and 200 mg/mL), and a bioassay method was applied using red clover seeds (Trifolium pratense L.) as a model for germination. The results indicate that the addition of hummus and treatment with synthesized β-diketonate significantly reduced the inhibitory effects of the sludge. The synthesized β-diketonate shows potential for polluta
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Priya, J., N. K. Gondia та S. K. Sharma. "Thermal analysis of tetrakis β-diketonate dysprosium complexes for OLED application". У 2018 3rd International Conference on Microwave and Photonics (ICMAP). IEEE, 2018. http://dx.doi.org/10.1109/icmap.2018.8354530.

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Frazer, Andrew, Alma R. Morales, Adam Woodward, Simon Tang та Kevin D. Belfield. "Novel Lysosomal Targeting Two-Photon Fluorescence Probe Based on Fluorene Difluoroboron β-diketonate". У Optical Molecular Probes, Imaging and Drug Delivery. OSA, 2013. http://dx.doi.org/10.1364/omp.2013.mth1c.3.

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Steinbacher, Andreas, Pramod Kumar Verma, Federico Koch, Patrick Nuernberger та Tobias Brixner. "Exploring the Ultrafast Excited-State Intramolecular Proton Transfer (ESIPT) of β-Diketones in the deep-UV". У International Conference on Ultrafast Phenomena. OSA, 2016. http://dx.doi.org/10.1364/up.2016.uth4a.13.

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Yamaguchi, Takeshi, Naoyuki Shibayama, Makoto Nakade, Yoshimoto Abe та Hironori Arakawa. "Development of new efficient Ru dyes having β-diketonate and terpyridine ligands for solar cells". У Photonic Devices + Applications, редактори Zakya H. Kafafi та Paul A. Lane. SPIE, 2007. http://dx.doi.org/10.1117/12.732807.

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