Academic literature on the topic 'Π-stacked polymer'

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Journal articles on the topic "Π-stacked polymer"

1

Maeda, Hazuki, Mayu Kameda, Takuji Hatakeyama та Yasuhiro Morisaki. "π-Stacked Polymer Consisting of a Pseudo–meta–[2.2]Paracyclophane Skeleton". Polymers 10, № 10 (2018): 1140. http://dx.doi.org/10.3390/polym10101140.

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A novel π-stacked polymer based on a pseudo–meta–linked [2.2]paracyclophane moieties was synthesized by Sonogashira-Hagihara coupling. The UV-vis absorption spectra of the synthesized polymer and model compounds revealed an extension of the conjugation length owing to the through-space conjugation. The optical properties of the π-stacked dimer with the pseudo–meta–linked [2.2]paracyclophane unit were compared with those of the corresponding dimers with the pseudo–ortho– and pseudo–para–linked [2.2]paracyclophane units.
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2

Tiwari, Madhu, Sandeep Gupta, and Rajiv Prakash. "One pot synthesis of coordination polymer 2,5-dimercapto-1,3,4-thiadiazole–gold and its application in voltammetric sensing of resorcinol." RSC Adv. 4, no. 49 (2014): 25675–82. http://dx.doi.org/10.1039/c4ra02983f.

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The synthesized coordination polymer DMTD–Au has a layered structure, in which the layers are stacked via π–π stacking and hydrophobic interaction. It facilitates electron transfer kinetics, which has been utilized in the ultra trace sensing of resorcinol.
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3

Li, Huanhuan, Zhixiang Wang, Chao Song та ін. "Manipulating charge transport in a π-stacked polymer through silicon incorporation". J. Mater. Chem. C 2, № 34 (2014): 6946–53. http://dx.doi.org/10.1039/c4tc00486h.

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4

Uemura, Takashi, Noriyuki Uchida, Atsushi Asano та ін. "Highly Photoconducting π-Stacked Polymer Accommodated in Coordination Nanochannels". Journal of the American Chemical Society 134, № 20 (2012): 8360–63. http://dx.doi.org/10.1021/ja301903x.

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5

Liu, Yue, та Xinping Zhang. "Mobility of Small Molecules in Solid Polymer Film for π-Stacked Crystallization". Crystals 11, № 9 (2021): 1022. http://dx.doi.org/10.3390/cryst11091022.

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Crystallization or π-stacked aggregation of small molecules is an extensively observed phenomenon which favors charge transport along the crystal axis and is important for the design of organic optoelectronic devices. Such a process has been reported for N,N’-Bis(1-ethylpropyl)-3,4,9,10-perylenebis(dicarboximide) (EPPTC). However, the π-stacking mechanism requires solution–air or solution–solid interfaces. The crystallization or aggregation of molecules doped in solid films is generally thought to be impossible, since the solid environment surrounding the small molecules does not allow them to aggregate together into π-stacked crystals. In this work, we demonstrate that the movement of the EPPTC molecules becomes possible in a solid polymer film when it is heated to above the glass transition temperature of the polymer. Thus, crystal particles can be produced as a doped matrix in a thin solid film. The crystallization process is found to be strongly dependent on the annealing temperature and the annealing time. Both the microscopic and spectroscopic evaluations verify such discoveries and characterize the related properties of these crystals.
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6

Sugino, Hiroyoshi, Yasuhito Koyama та Tamaki Nakano. "A high triplet-energy polymer: synthesis and photo-physical properties of a π-stacked vinyl polymer having a xanthone moiety in the side chain". RSC Advances 5, № 27 (2015): 21310–15. http://dx.doi.org/10.1039/c4ra16023a.

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Poly(xanthon-3-yl methacrylate) having a π-stacked conformation efficiently harvests photo excitation energy for sky blue phosphorescent emission of iridium bis[(4,6-difluorophenyl)pyridinato-N,C<sup>2</sup>]picolinate (FIrpic) in solution and in film.
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7

Nageh, Hassan, Yue Wang та Tamaki Nakano. "Cationic polymerization of dibenzofulvene leading to a π-stacked polymer". Polymer 144 (травень 2018): 51–56. http://dx.doi.org/10.1016/j.polymer.2018.04.042.

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8

Hart, Lewis R., Ngoc A. Nguyen, Josephine L. Harries, Michael E. Mackay, Howard M. Colquhoun та Wayne Hayes. "Perylene as an electron-rich moiety in healable, complementary π–π stacked, supramolecular polymer systems". Polymer 69 (липень 2015): 293–300. http://dx.doi.org/10.1016/j.polymer.2015.03.028.

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9

Watanabe, Kento, Takeshi Sakamoto, Makoto Taguchi, Michiya Fujiki та Tamaki Nakano. "A chiral π-stacked vinyl polymer emitting white circularly polarized light". Chemical Communications 47, № 39 (2011): 10996. http://dx.doi.org/10.1039/c1cc13711e.

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10

Ma, Yunlong, Dongdong Cai, Shuo Wan та ін. "Control over π-π stacking of heteroheptacene-based nonfullerene acceptors for 16% efficiency polymer solar cells". National Science Review 7, № 12 (2020): 1886–95. http://dx.doi.org/10.1093/nsr/nwaa189.

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Abstract Nonfullerene acceptors are being investigated for use in polymer solar cells (PSCs), with their advantages of extending the absorption range, reducing the energy loss and therefore enhancing the power conversion efficiency (PCE). However, to further boost the PCE, mobilities of these nonfullerene acceptors should be improved. For nonfullerene acceptors, the π–π stacking distance between cofacially stacked molecules significantly affects their mobility. Here, we demonstrate a strategy to increase the mobility of heteroheptacene-based nonfullerene acceptors by reducing their π–π stacking distances via control over the bulkiness of lateral side chains. Incorporation of 2-butyloctyl substituents into the nonfullerene acceptor (M36) leads to an increased mobility with a reduced π–π stacking distance of 3.45 Å. Consequently, M36 affords an enhanced PCE of 16%, which is the highest among all acceptor-donor-acceptor-type nonfullerene acceptors to date. This strategy of control over the bulkiness of side chains on nonfullerene acceptors should aid the development of more efficient PSCs.
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