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Relevant bibliographies by topics / 1.5.7-triazabicyclo[4.4.0]dec-5-ene

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Dissertations / Theses

Academic literature on the topic '1.5.7-triazabicyclo[4.4.0]dec-5-ene'

Author: Grafiati

Published: 4 June 2021

Last updated: 16 February 2022

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Journal articles on the topic "1.5.7-triazabicyclo[4.4.0]dec-5-ene"

1

Lu, Shiyao, та Kai Wang. "Kinetic study of TBD catalyzed δ-valerolactone polymerization using a gas-driven droplet flow reactor". Reaction Chemistry & Engineering 4, № 7 (2019): 1189–94. http://dx.doi.org/10.1039/c9re00046a.

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Raunio, J., J. Mannoja, T. Nguyen, et al. "Base catalysed N-functionalisation of boroxazolidones." RSC Advances 7, no. 33 (2017): 20620–27. http://dx.doi.org/10.1039/c7ra03266h.

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3

Moins, S., C. Henoumont, J. De Winter та ін. "Reinvestigation of the mechanism of polymerization of β-butyrolactone from 1,5,7-triazabicyclo[4.4.0]dec-5-ene". Polymer Chemistry 9, № 14 (2018): 1840–47. http://dx.doi.org/10.1039/c8py00206a.

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4

García-Argüelles, Sara, Carolina García, María C. Serrano, María C. Gutiérrez, M. Luisa Ferrer та Francisco del Monte. "Near-to-eutectic mixtures as bifunctional catalysts in the low-temperature-ring-opening-polymerization of ε-caprolactone". Green Chemistry 17, № 6 (2015): 3632–43. http://dx.doi.org/10.1039/c5gc00348b.

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5

Tassi, Marco, Elena Bartollini, Peter Adriaensens, et al. "Synthesis, characterization and catalytic activity of novel large network polystyrene-immobilized organic bases." RSC Advances 5, no. 130 (2015): 107200–107208. http://dx.doi.org/10.1039/c5ra21140a.

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In view of searching for efficient solid catalysts to be used in environmentally friendly reaction conditions, novel gel-type cross-linked polystyrenes functionalized with diethylamine and 1,5,7-triazabicyclo[4.4.0]dec-5-ene, have been prepared.

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Shimomura, Osamu, Suguru Sasaki, Kaori Kume, Atsushi Ohtaka та Ryôki Nomura. "Temperature-Dependent Enhancement Effects for TBD (1,5,7-Triazabicyclo[4.4.0]dec-5-ene) with 2-Methylimidazole-Intercalated α-Zirconium Phosphate as a Latent Thermal Initiator in the Reaction of Glycidyl Phenyl Ether". Inorganics 7, № 7 (2019): 83. http://dx.doi.org/10.3390/inorganics7070083.

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The catalytic effects of 1,1,3,3-Tetramethylguanidine (TMG), 1,5,7-Triazabicyclo[4.4.0]dec-5-ene (TBD), 7-Methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene (MTBD), 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU), and 1,5-diazabicyclo[4.3.0]non-5-ene (DBN) in the reaction with glycidyl phenyl ether (GPE) at 40 °C were investigated. For the reaction, the %conversion of GPE was only 11%, carried out at 40 °C over 14 days in the presence of TBD.Additionally, there was little catalytic activity for the same reaction performed under typical storage conditions at 25 °C. The effect of TBD with 2-methylimidazole-int

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7

Ye, Weiping, Junye Xu, Chin-Tong Tan, and Choon-Hong Tan. "1,5,7-Triazabicyclo[4.4.0]dec-5-ene (TBD) catalyzed Michael reactions." Tetrahedron Letters 46, no. 40 (2005): 6875–78. http://dx.doi.org/10.1016/j.tetlet.2005.08.010.

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8

Turočkin, Aleksej. "1,5,7-Triazabicyclo[4.4.0]dec-5-ene (TBD) as a Lewis Base." Synlett 25, no. 06 (2014): 894–95. http://dx.doi.org/10.1055/s-0033-1340852.

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9

Moins, Sébastien, Sébastien Hoyas, Vincent Lemaur, et al. "Stereoselective ROP of rac- and meso-Lactides Using Achiral TBD as Catalyst." Catalysts 10, no. 6 (2020): 620. http://dx.doi.org/10.3390/catal10060620.

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1,5,7-Triazabicyclo[4.4.0]dec-5-ene (TBD) polymerizes rac-lactide (rac-LA) to form highly isotactic polylactide (PLA) with a Pm = 0.88, while meso-LA yields heterotactic PLA (Pm ~ 0.8) at −75 °C. The stereocontrol of the cryogenic-based ring-opening polymerization comes from a perfect imbrication of both chiral LA and the propagating chiral end-group interacting with the achiral TBD catalyst.

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10

Binkowska, Iwona, and Arnold Jarczewski. "Kinetic and equilibrium study of the deprotonation of 4-nitrophenyl[bis(ethylsulphonyl)]methane by organic bases in acetonitrile in the presence of common cation BH+ and tetrabutylammonium perchlorate." Open Chemistry 2, no. 4 (2004): 648–59. http://dx.doi.org/10.2478/bf02482728.

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AbstractThe results of kinetic and equilibrium experiments with the set of reaction of proton abstraction from 4-nitrophenyl[bis(ethylsulphonyl)]methane in acetonitrile are reported. Two strong organic bases are used: 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) and 7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene (MTBD).The rates of proton transfer reaction have been measured by T-jump method in the presence of perchlorate of the appropriate base as a common cation BH+ and supporting electrolyte-tetrabutylammonium perchlorate (TBAP) in the temperature range between 20–40°C are: kH=1.32×107−2.00×107

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Dissertations / Theses on the topic "1.5.7-triazabicyclo[4.4.0]dec-5-ene"

1

Touhtouh, Samira. "Réaction d'échange alcool / ester : alcoolyse : application aux polymères." Thesis, Saint-Etienne, 2011. http://www.theses.fr/2011STET4004.

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Cette étude porte sur l’élaboration de polymères greffés à base de poly(éthylène alcool vinylique) (EVOH) et de la polycaprolactone (PCL). La réaction de greffage a lieu par la réaction d’alcoolyse entre les groupements ester de la polycaprolactone et les groupements alcools le long des chaînes d’EVOH. L’étude catalytique et cinétique par des études GC/MS très détaillées, facilitées par l’utilisation de réactions modèles avec le 1-dodécyl benzoate et le 2-dodécanol, montre la possibilité de la synthèse par extrusion réactive. L’activité catalytique de 1.5.7-triazabicyclo[4.4.0]dec-5-ene pour l

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2

Mohammad, Adil. "Achiral and chiral, C2-symmetric bicyclic guanidinates based on 1,5,7-triazabicyclo[4.4.0.]dec-5-ene as ligands in high- and mid-valent early transition metal chemistry." Diss., University of Iowa, 2010. https://ir.uiowa.edu/etd/714.

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The syntheses of achiral and chiral, C2-symmetric bicyclic guanidine derivatives of 1,5,7-triazabicylo[4.4.0]dec-5-ene (hppH) are described. Quantum mechanical MO calculations based on Spartan were performed in order to study the effects (electronic and steric) of substituents on the basicity of hppH derivatives. These calculations showed that substituting only one methyl group on each carbon next to the bridgehead nitrogen of hppH gives high basicity. Based on these calculations, syntheses of achiral (hpp*H, with four methyl groups) and chiral C2-symmetric (hpp'H, with two methyl groups) deri

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