Relevant bibliographies by topics / 1-Azabicyclo [5

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Academic literature on the topic '1-Azabicyclo [5'

Author: Grafiati
Published: 4 June 2021
Last updated: 3 February 2022

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Journal articles on the topic "1-Azabicyclo [5"

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Krow, Grant R., Fang Yu, Matthew Sender, et al. "Introduction of C(5/6) side chains onto 2-azabicyclo[2.1.1]hexanes via a 6-anti-bromo-5-anti-hydroxy derivative." Canadian Journal of Chemistry 90, no. 1 (2012): 121–30. http://dx.doi.org/10.1139/v11-112.

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Oxidation of the title bromoalcohol provided the strained ketone, 5-bromo-6-oxo-2-azabicyclo[2.1.1]hexane. Additions of nucleophiles to either this or the debrominated ketone have been used to introduce 5(6)-syn-alkyl and aryl groups, 5(6)-alkylidene linkages, and 5(6)-anti-alkyl and acyl substituents. Facial selectivity is for additions to the 6-bromo-5-ketone and 5-alkylidene azabicycles to occur from the face syn to the nitrogen atom. The bromine atom of the title alcohol has also been replaced by a 6-anti-(1-hydroxyethyl) substituent using a directed radical addition process. The stereosel
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2

Svoboda, Jiří, and Jaroslav Paleček. "New Method for Preparation of 1-Azabicyclo[2.2.2]octane-4-carbonitrile and 1-Azabicyclo[3.2.2]nonane-5-carbonitrile." Collection of Czechoslovak Chemical Communications 60, no. 9 (1995): 1536–40. http://dx.doi.org/10.1135/cccc19951536.

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The title compounds were prepared from pyridine-4-carboxamide. Its alkylation with 2-chloroethanol or 3-chloropropanol, followed by hydrogenation gave 1-substituted piperidine-4-carboxamides IIIa and IIIb, respectively, which on treatment with thionyl chloride were converted into the respective 1-substituted halogenoalkylpiperidine-4-carbonitriles IVa and IVb. On cyclization, compounds IVa and IVb afforded 1-azabicyclo[2.2.2]octane-4-carbonitrile and 1-azabicyclo[3.2.2]nonane-5-carbonitrile, respectively.
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3

Fortunato, Milene, Filipa Siopa, and Carlos Afonso. "(1R,4S,5S)-5-((3-Hydroxypropyl)amino)-4-((1-methyl-1H-tetrazol-5-yl)thio)cyclopent-2-en-1-ol." Molbank 2021, no. 2 (2021): M1199. http://dx.doi.org/10.3390/m1199.

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Using environmentally friendly conditions, the nucleophilic ring-opening reaction of 6-azabicyclo[3.1.0]hex-3-en-2-ol with 1-methyl-1H-tetrazole-5-thiol provided a novel thiol-incorporated aminocyclopentitol, (1R,4S,5S)-5-((3-hydroxypropyl)amino)-4-((1-methyl-1H-tetrazol-5-yl)thio)cyclopent-2-en-1-ol, in excellent yield (95%). The newly synthesized compound was analyzed and characterized via 1H, 13C-NMR, HSQC, and mass spectral data.
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Matsumoto, Yukiharu, Mituru Oka, and Ryoichi Unno. "The Novel Synthesis of 5-Cyano-1-azabicyclo[3.3.0]octane." HETEROCYCLES 45, no. 8 (1997): 1447. http://dx.doi.org/10.3987/com-97-7845.

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5

SVOBODA, J., and J. PALECEK. "ChemInform Abstract: New Method for Preparation of 1-Azabicyclo(2.2.2)octane-4-carbonitrile and 1-Azabicyclo(3.2.2)nonane-5-carbonitrile." ChemInform 27, no. 8 (2010): no. http://dx.doi.org/10.1002/chin.199608156.

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6

Fawcett, Alexander. "Recent advances in the chemistry of bicyclo- and 1-azabicyclo[1.1.0]butanes." Pure and Applied Chemistry 92, no. 5 (2020): 751–65. http://dx.doi.org/10.1515/pac-2019-1007.

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AbstractBicyclo[1.1.0]- and 1-azabicyclo[1.1.0]butanes are structurally unique compounds that exhibit diverse chemistry. Bicyclo[1.1.0]butane is a four-membered carbocycle with a bridging C(1)-C(3) bond and 1-azabicyclo[1.1.0]butane is an analog of bicyclo[1.1.0]butane featuring a nitrogen atom at one bridgehead. These structures are highly strained, allowing them to participate in a range of strain-releasing reactions which typically cleave the central, strained bond to deliver cyclobutanes or azetidines. However, despite these molecules being discovered in the 1950s and 1960s, and possessing
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Matsumoto, Yukiharu, Mitsuru Oka, Kunihisa Baba, and Tomoo Suzuki. "The Novel Preparation Methods of 5-Substituted Methyl-1-azabicyclo-[3.3.0]octane." HETEROCYCLES 45, no. 12 (1997): 2317. http://dx.doi.org/10.3987/com-97-7971.

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8

Wheeler, Kraig A. "(\pm)-5-(4-Methoxyphenylaminocarbonyl)-1-azabicyclo[3.3.0]octan-2-one benzene solvate." Acta Crystallographica Section C Crystal Structure Communications 59, no. 5 (2003): o231—o233. http://dx.doi.org/10.1107/s0108270103006097.

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9

Sonar, Vijayakumar N., M. Venkataraj, Sean Parkin, and Peter A. Crooks. "(Z)-2-(1,3-Benzodioxol-5-ylmethylene)-1-azabicyclo[2.2.2]octan-3-one." Acta Crystallographica Section E Structure Reports Online 62, no. 12 (2006): o5742—o5744. http://dx.doi.org/10.1107/s160053680604894x.

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10

Zoorob, Hanafi H., Wafaa S. Hamama, Osama M. Abd El-Magid, and Mamdoh S. Soliman. "Intermolecular double Michael reaction to construct 4-benzyl-5-imino-3-phenyl-6-oxa-1-aza-tricyclo[6.2.2.02,7]dodec-2(7)-ene-4-carbonitrile." Journal of Chemical Research 2005, no. 10 (2005): 669–72. http://dx.doi.org/10.3184/030823405774663075.

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1-azabicyclo[2.2.2]octan-3-one. HCl (1) reacts with ylidene nitrile through photo- thermal reaction conditions to give 4-benzyl-5-imino-3-phenyl-6-oxa-1-aza-tricyclo[6.2.2.02,7]dodec-2(7)-ene-4-carbonitrile. (3) via intermolecular double Micheal reaction, whereas, 5-imino-3-phenyl-6-oxa-1-azatricyclo[6.2.2.02,7]dodec-2(7)-ene-4-carbonitrile (4) was achieved via thermal conditions only.
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Dissertations / Theses on the topic "1-Azabicyclo [5"

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Riston, Jose Roberto. "Estudos visando a sintese estereosseletiva do alcaloide 275A." [s.n.], 2006. http://repositorio.unicamp.br/jspui/handle/REPOSIP/249249.

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Orientador: Ronaldo Aloise Pilli<br>Dissertação (mestrado) - Universidade Estadual de Campinas, Instituto de Química<br>Made available in DSpace on 2018-08-08T12:16:22Z (GMT). No. of bitstreams: 1 Riston_JoseRoberto_M.pdf: 1975890 bytes, checksum: 83dd322a0b88c53adac5195340f43a5f (MD5) Previous issue date: 2006<br>Resumo: Este trabalho trata de estudos visando à síntese estereosseletiva do alcalóide 275A (18, Figura 1). Esse alcalóide foi isolado por Daly e colaboradores da pele de pequenas rãs venenosas neotropicais da família Dendrobatidae em 1986. Sua estrutura possui um núcleo 1-azabicic
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2

Mehmandoust, Maryam. "Synthèse de dihydro-1, 2 pyridines et d'équivalents de sels de dihydro-2, 5 pyridinium à partir d'amines primaires chirales : application à la synthèse énantiosélective de dérivés d'isoquinuclidines et de pipéridines 2-substituées." Paris 11, 1989. http://www.theses.fr/1989PA112254.

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Une méthode générale de synthèse des sels de pyridinium N-substitués par différents auxiliaires chiraux, une application de la réaction de Zincke, à partir des amines primaires chirales correspondantes, est décrite. Par réduction au borohydrure de sodium en milieu alcalin, ces sels de pyridinium conduisent aux dihydro-1,2 pyridines correspondantes dont les réactions de cycloaddition avec l'acrylate de méthyle ont été étudiées. Des composés azabicyclo[2. 2. 2]octane (isoquinuclidines), dont la configuration absolue a été établie, sont obtenus avec des e. D. De 20 à 33% et une bonne pureté optiq
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Book chapters on the topic "1-Azabicyclo [5"

1

"5-Ethyl-3,7-dioxa-1-azabicyclo[3.3.0]octan." In Gesundheitsschädliche Arbeitsstoffe. Wiley-VCH Verlag GmbH & Co. KGaA, 2005. http://dx.doi.org/10.1002/3527603441.ch34.

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2

"2-Oxa-4-azabicyclo[3.3.0]oct-3-ene to 3,7-Diferrabicyclo[3.3.0]oct-1(5)-ene." In Substance Index, edited by Backes, Fröhlich, and Padeken. Georg Thieme Verlag, 2000. http://dx.doi.org/10.1055/b-0035-114015.

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